{"artifacts":{"sha256:9ce403d6580e9b80/p3/tab-2":{"artifact":"table","caption":"Crystal structure for the solid phases in the Cd–X (X ¼Sn, Mn, Fe) systems.","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CD","FE","MN","SN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0001-6160(54)90197-2":{"authors":["G.V Raynor","J.A Lee"],"citation":"G.V Raynor, J.A Lee, The tin-rich intermediate phases in the alloys of tin with cadmium, indium and mercury, Acta Metallurgica 2, 616-620 (1954).","container":"Acta Metallurgica","doi":"10.1016/0001-6160(54)90197-2","doi_url":"https://doi.org/10.1016/0001-6160(54)90197-2","id":"doi:10.1016/0001-6160(54)90197-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The tin-rich intermediate phases in the alloys of tin with cadmium, indium and mercury","year":1954},"doi:10.1016/j.calphad.2014.06.006":{"authors":["Aning Qin","Rong Wang","Yaru Wang","Jiong Wang","Shuhong Liu","Kaiming Cheng","Yong Du","Bosse Sundman"],"citation":"Aning Qin, Rong Wang, Yaru Wang, Jiong Wang, Shuhong Liu, Kaiming Cheng et al., Thermodynamic assessment of the Cd–X (X=Sn, Mn, Fe) systems, Calphad 47, 83-91 (2014).","container":"Calphad","doi":"10.1016/j.calphad.2014.06.006","doi_url":"https://doi.org/10.1016/j.calphad.2014.06.006","id":"doi:10.1016/j.calphad.2014.06.006","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"9ce403d6580e9b80","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Cd–X (X=Sn, Mn, Fe) systems","year":2014}},"part":1,"parts":1,"records":[{"chemical_system":"CD-FE-MN-SN","cited_sources":[{"first_author":"King","kind":"assessment","label":"49","reference":"H. King, Crystal structures of the elements at 25 1C, J. Phase Equilib. 2 (1981) 401–402.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":0,"id":"ORC-3453QTED6G.5e323a","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"FE":0.0,"MN":0.0,"SN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"(Cd)"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"hP2","prototype":"Mg"},"system":"CD-FE-MN-SN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02294,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02294},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":2.9788,"value_stored":0.29788},{"chemical_system":"CD-FE-MN-SN","cited_sources":[{"first_author":"King","kind":"assessment","label":"49","reference":"H. King, Crystal structures of the elements at 25 1C, J. Phase Equilib. 2 (1981) 401–402.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":0,"id":"ORC-3453QTED6G.ffc415","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"FE":0.0,"MN":0.0,"SN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"(Cd)"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"hP2","prototype":"Mg"},"system":"CD-FE-MN-SN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04325,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04325},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.6167,"value_stored":0.56167},{"chemical_system":"CD-FE-MN-SN","cited_sources":[{"doi":"10.1016/0001-6160(54)90197-2","first_author":"Raynor","kind":"unknown","label":"48","paper":"doi:10.1016/0001-6160(54)90197-2","reference":"G. Raynor, J. Lee, The tin-rich intermediate phases in the alloys of tin with cadmium, indium and mercury, Acta Metall. 2 (1954) 616–620. 91","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":0,"id":"ORC-2E6Y6N7GT2.3f1be6","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"β"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"hP2","prototype":"Mg"},"system":"CD-FE-MN-SN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007112,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007112},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.2328,"value_stored":0.32328},{"chemical_system":"CD-FE-MN-SN","cited_sources":[{"doi":"10.1016/0001-6160(54)90197-2","first_author":"Raynor","kind":"unknown","label":"48","paper":"doi:10.1016/0001-6160(54)90197-2","reference":"G. Raynor, J. Lee, The tin-rich intermediate phases in the alloys of tin with cadmium, indium and mercury, Acta Metall. 2 (1954) 616–620. 91","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":0,"id":"ORC-2E6Y6N7GT2.a77fd9","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"β"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"hP2","prototype":"Mg"},"system":"CD-FE-MN-SN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006605,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006605},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.0023,"value_stored":0.30023}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CD-FE-MN-SN"}