{"artifacts":{"doi:10.1007/s11664-009-0875-3/p7/tab-iii":{"artifact":"table","caption":"Invariant Reactions Involving the Liquid Phase in the Cd-Te System","label":"III","page":7},"doi:10.1016/0364-5916(95)00038-g/p1/text-15":{"artifact":"text_passage","label":"page 1, passage 15","page":1},"doi:10.1016/0364-5916(95)00038-g/p7/text-85":{"artifact":"text_passage","label":"page 7, passage 85","page":7},"sha256:a6e1d0c026673f50/p13/tab-4":{"artifact":"table","caption":"Comparison of the enthalpies of formation of the compounds CdTe and HgTe at 298.15K and standard entropies at 298.15K as proposed by Yu and Brebrick and evaluated in this study.","label":"4","page":13}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CD","TE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"Maaabc56b":{"catalog_entry":{"license":"CC BY 4.0","name":"CdTe-09Liu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_doi":"10.1007/s11664-009-0875-3","reproduced_by_calculation":true,"tdb":"CdTe-09Liu.tdb","tdb_path":"databases/sgte-binary/CdTe-09Liu.tdb","tdb_sha256":"0716dba9e0a2962655788a0808e2aa2b71bbffc2bb9c7bbfc97626ab92ce8b35"},"Mcd72b7e2":{"catalog_entry":{"license":"CC BY 4.0","name":"CdTe-09Liu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_doi":"10.1007/s11664-009-0875-3","reproduced_by_calculation":false,"tdb":"CdTe-09Liu.tdb","tdb_path":"databases/sgte-binary/CdTe-09Liu.tdb","tdb_sha256":"0716dba9e0a2962655788a0808e2aa2b71bbffc2bb9c7bbfc97626ab92ce8b35"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/zaac.19100690102":{"authors":["Matsusuke Kobayashi"],"citation":"Matsusuke Kobayashi, Über die Legierungen des Tellurs mit Cadmium und Zinn, Z. Anorg. Chem. 69, 1-9 (1911).","container":"Z. Anorg. Chem.","doi":"10.1002/zaac.19100690102","doi_url":"https://doi.org/10.1002/zaac.19100690102","id":"doi:10.1002/zaac.19100690102","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Über die Legierungen des Tellurs mit Cadmium und Zinn","year":1911},"doi:10.1007/s11664-009-0875-3":{"authors":["Yajun Liu","Lijun Zhang","Di Yu"],"citation":"Yajun Liu, Lijun Zhang, Di Yu, Thermodynamic Descriptions for the Cd-Te, Pb-Te, Cd-Pb and Cd-Pb-Te Systems, Journal of Elec Materi 38, 2033-2045 (2009).","container":"Journal of Elec Materi","doi":"10.1007/s11664-009-0875-3","doi_url":"https://doi.org/10.1007/s11664-009-0875-3","id":"doi:10.1007/s11664-009-0875-3","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"e940a6c72724b91a","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Descriptions for the Cd-Te, Pb-Te, Cd-Pb and Cd-Pb-Te Systems","year":2009},"doi:10.1016/0022-3697(59)90110-6":{"authors":["W.D. Lawson","S. Nielsen","E.H. Putley","A.S. Young"],"citation":"W.D. Lawson, S. Nielsen, E.H. Putley, A.S. Young, Preparation and properties of HgTe and mixed crystals of HgTe-CdTe, Journal of Physics and Chemistry of Solids 9, 325-329 (1959).","container":"Journal of Physics and Chemistry of Solids","doi":"10.1016/0022-3697(59)90110-6","doi_url":"https://doi.org/10.1016/0022-3697(59)90110-6","id":"doi:10.1016/0022-3697(59)90110-6","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Preparation and properties of HgTe and mixed crystals of HgTe-CdTe","year":1959},"doi:10.1016/0022-3697(62)90151-8":{"authors":["M.R. Lorenz"],"citation":"M.R. Lorenz, Phase equilibria in the system Cd—Te∗, Journal of Physics and Chemistry of Solids 23, 939-947 (1962).","container":"Journal of Physics and Chemistry of Solids","doi":"10.1016/0022-3697(62)90151-8","doi_url":"https://doi.org/10.1016/0022-3697(62)90151-8","id":"doi:10.1016/0022-3697(62)90151-8","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase equilibria in the system Cd—Te∗","year":1962},"doi:10.1016/0364-5916(95)00038-g":{"authors":["Yang Jianrong","N.J. Silk","A. Watson","A.W. Bryant","B.B. Argent"],"citation":"Yang Jianrong, N.J. Silk, A. Watson, A.W. Bryant, B.B. Argent, Thermodynamic and phase diagram assessment of the Cd-Te and Hg-Te systems, Calphad 19, 399-414 (1995).","container":"Calphad","doi":"10.1016/0364-5916(95)00038-g","doi_url":"https://doi.org/10.1016/0364-5916(95)00038-g","id":"doi:10.1016/0364-5916(95)00038-g","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"a6e1d0c026673f50","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic and phase diagram assessment of the Cd-Te and Hg-Te systems","year":1995},"doi:10.1149/1.2407297":{"citation":"J. Steininger, A.J. Strauss, and R.F. Brebrick, J. Appl. Phys. 117, 1305 (1970).","doi":"10.1149/1.2407297","doi_url":"https://doi.org/10.1149/1.2407297","id":"doi:10.1149/1.2407297","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"ref:3d7eab9ebff87a42":{"citation":"S.D. Gromakov, I.V. Zoroatskaya, Z.M. Latypov, M.A. Chvala, E.A. Eidelman, L.I. Badysina, and L.G. Zaripova, Z. Neorg. Khim. 9, 2485 (1964).","id":"ref:3d7eab9ebff87a42","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1964},"ref:3e4bba03fe88cacc":{"citation":"B.M. Kulwicki (Ph.D. thesis, The University of Michigan, Ann Arbor, Michigan, USA, 1963).","id":"ref:3e4bba03fe88cacc","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1963},"ref:4321f974aeddb9ca":{"citation":"D.R. Mason and D.F. O’Kane, Preparation and Properties of Some Peritectic Semiconducting Compounds (New York, NY: Academic Press, 1961).","id":"ref:4321f974aeddb9ca","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1961},"ref:aced1e30c31c59d3":{"citation":"D. DeNobel, Philips Res. Rep. 14, 361 (1959).","id":"ref:aced1e30c31c59d3","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1959},"ref:d5a13113fb2e2cad":{"citation":"L.A. Sysoev, E.K. Raiskin, and V.R. Gur¢ev, Izv. Akad. Nauk SSSR, Neorg. Mater. 3, 390 (1967).","id":"ref:d5a13113fb2e2cad","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1967}},"part":1,"parts":1,"records":[{"chemical_system":"CD-TE","cited_sources":[{"kind":"unknown","label":"13","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"CD-TE","before":"CD-HG-TE","evidence":{"basis":"printed_overall_composition","overall_composition":{"HG":0.0,"TE":0.5},"phases":["CdTe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-S6377M3I2P.3353ab","locator":{"ref":"sha256:a6e1d0c026673f50/p13/tab-4","row":1},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"TE":0.5},"overall_composition_stored":{"HG":0.0,"TE":0.5},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","phases":[{"label":"CdTe"}],"pid":"sha256:a6e1d0c026673f50/p13/tab-4/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_MIX","property_group":"mixing / partial","property_printed":"S°298(CdTe)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CD":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"reference_state_stored":{"CD":{"phase":"printed:none"},"HG":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"source_system":"CD-HG-TE","system":"CD-TE","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.77},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/S_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"J/K/mol","n_pairs":0,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"column_header","unit_printed":"J/mol.K","value":95.4,"value_printed":95.4},{"chemical_system":"CD-TE","cited_sources":[{"kind":"unknown","label":"13","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"CD-TE","before":"CD-HG-TE","evidence":{"basis":"printed_overall_composition","overall_composition":{"HG":0.0,"TE":0.5},"phases":["CdTe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-S6377M3I2P.af4895","locator":{"ref":"sha256:a6e1d0c026673f50/p13/tab-4","row":1},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"TE":0.5},"overall_composition_stored":{"HG":0.0,"TE":0.5},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","phases":[{"label":"CdTe"}],"pid":"sha256:a6e1d0c026673f50/p13/tab-4/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°(CdTe)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CD":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"reference_state_stored":{"CD":{"phase":"printed:none"},"HG":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"source_system":"CD-HG-TE","system":"CD-TE","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.03315},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"J/mol","unit_stored":"J/mol (basis unstated)","value":-100.663,"value_printed":-100663,"value_stored":-100663.0},{"chemical_system":"CD-TE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CD-TE","before":"CD-HG-TE","evidence":{"basis":"printed_overall_composition","overall_composition":{"HG":0.0,"TE":0.5},"phases":["CdTe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-D3QUZ7OGYZ.d1f8fc","locator":{"ref":"sha256:a6e1d0c026673f50/p13/tab-4","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(95)00038-g","own_work_of_paper":true},"overall_composition":{"TE":0.5},"overall_composition_stored":{"HG":0.0,"TE":0.5},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","phases":[{"label":"CdTe"}],"pid":"sha256:a6e1d0c026673f50/p13/tab-4/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°(CdTe)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CD":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"reference_state_stored":{"CD":{"phase":"printed:none"},"HG":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"source_system":"CD-HG-TE","system":"CD-TE","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.0354},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.8,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"scaled_for_unstated_basis":2,"value":7.8},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"J/mol","unit_stored":"J/mol (basis unstated)","value":-100.708,"value_printed":-100708,"value_stored":-100708.0},{"chemical_system":"CD-TE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CD-TE","before":"CD-HG-TE","evidence":{"basis":"printed_overall_composition","overall_composition":{"HG":0.0,"TE":0.5},"phases":["CdTe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-D3QUZ7OGYZ.d7c0c2","locator":{"ref":"sha256:a6e1d0c026673f50/p13/tab-4","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(95)00038-g","own_work_of_paper":true},"overall_composition":{"TE":0.5},"overall_composition_stored":{"HG":0.0,"TE":0.5},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","phases":[{"label":"CdTe"}],"pid":"sha256:a6e1d0c026673f50/p13/tab-4/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_MIX","property_group":"mixing / partial","property_printed":"S°298(CdTe)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CD":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"reference_state_stored":{"CD":{"phase":"printed:none"},"HG":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"source_system":"CD-HG-TE","system":"CD-TE","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.665},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_MIX_PARTIAL","floor":1.0,"floor_unit":"J/K/mol","n_pairs":14,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"column_header","unit_printed":"J/mol.K","value":93.3,"value_printed":93.3},{"chemical_system":"CD-TE","cited_sources":[{"doi":"10.1016/0022-3697(59)90110-6","first_author":"Lawson","kind":"assessment","label":"13","paper":"doi:10.1016/0022-3697(59)90110-6","reference":"W.D. Lawson, S. Nielsen, E.H. Putley, and A.S. Young, J. Phys. Chem. Solids 9, 325 (1959).","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-MRL67CKBNG","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":5},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1016/0022-3697(59)90110-6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-0997b966#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1379,"temperature_printed":"1379","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1379},{"chemical_system":"CD-TE","cited_sources":[{"doi":"10.1002/zaac.19100690102","first_author":"Kobayashi","kind":"assessment","label":"12","paper":"doi:10.1002/zaac.19100690102","reference":"M. Kobayashi, Z. Anorg. Chem. 69, 1 (1911).","status":"resolved","year":"1911"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-7.837,"dx":{"liq":-0.0008},"model":"CdTe-09Liu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-RUOGI76S7U","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":13},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1002/zaac.19100690102","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.98},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"stoichiometric_model_phase","phase":"hex"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"hex","mapping_confidence":"proposed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-2e8824f8#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> hex + CdTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":710,"temperature_printed":"710","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":710},{"chemical_system":"CD-TE","cited_sources":[{"first_author":"Kulwicki","kind":"assessment","label":"16","reference":"B.M. Kulwicki (Ph.D. thesis, The University of Michigan, Ann Arbor, Michigan, USA, 1963).","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":2.163,"dx":{"liq":0.0092},"model":"CdTe-09Liu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-54H5OHNIE2","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:3e4bba03fe88cacc","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.99},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"stoichiometric_model_phase","phase":"hex"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"hex","mapping_confidence":"proposed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-315186cf#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> hex + CdTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":720,"temperature_printed":"720","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":720},{"chemical_system":"CD-TE","cited_sources":[{"first_author":"Mason","kind":"unknown","label":"20","reference":"D.R. Mason and D.F. O’Kane, Preparation and Properties of Some Peritectic Semiconducting Compounds (New York, NY: Academic Press, 1961).","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-WN5VKWJSAR","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":9},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:4321f974aeddb9ca","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-5141bc09#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1371,"temperature_printed":"1371","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1371},{"chemical_system":"CD-TE","cited_sources":[{"first_author":"Gromakov","kind":"unknown","label":"21","reference":"S.D. Gromakov, I.V. Zoroatskaya, Z.M. Latypov, M.A. Chvala, E.A. Eidelman, L.I. Badysina, and L.G. Zaripova, Z. Neorg. Khim. 9, 2485 (1964).","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-IDQ7VPPQ3A","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":10},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:3d7eab9ebff87a42","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-6db1dc80#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1333,"temperature_printed":"1333","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1333},{"chemical_system":"CD-TE","cited_sources":[{"doi":"10.1002/zaac.19100690102","first_author":"Kobayashi","kind":"assessment","label":"12","paper":"doi:10.1002/zaac.19100690102","reference":"M. Kobayashi, Z. Anorg. Chem. 69, 1 (1911).","status":"resolved","year":"1911"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-3I4TLIGYS7","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1002/zaac.19100690102","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-7aa06302#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1315,"temperature_printed":"1315","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1315},{"chemical_system":"CD-TE","cited_sources":[{"first_author":"DeNobel","kind":"unknown","label":"14","reference":"D. DeNobel, Philips Res. Rep. 14, 361 (1959).","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-WAZIKNNMTQ","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":6},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:aced1e30c31c59d3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-7dfe2c27#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1363,"temperature_printed":"1363","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1363},{"chemical_system":"CD-TE","cited_sources":[{"doi":"10.1149/1.2407297","first_author":"Steininger","kind":"assessment","label":"17","paper":"doi:10.1149/1.2407297","reference":"J. Steininger, A.J. Strauss, and R.F. Brebrick, J. Appl. Phys. 117, 1305 (1970).","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-AC42BQSHTE","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":8},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1149/1.2407297","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-9ff7f2f0#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1365,"temperature_printed":"1365","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1365},{"chemical_system":"CD-TE","cited_sources":[{"doi":"10.1002/zaac.19100690102","first_author":"Kobayashi","kind":"assessment","label":"12","paper":"doi:10.1002/zaac.19100690102","reference":"M. Kobayashi, Z. Anorg. Chem. 69, 1 (1911).","status":"resolved","year":"1911"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-GV6UOZTTWM","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1002/zaac.19100690102","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.0},"composition_source":"stoichiometric_model_phase","phase":"Cd"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cd","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-c4821bf9#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> Cd + CdTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":594,"temperature_printed":"594","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":594},{"chemical_system":"CD-TE","cited_sources":[{"doi":"10.1016/0022-3697(62)90151-8","first_author":"Lorenz","kind":"unknown","label":"15","paper":"doi:10.1016/0022-3697(62)90151-8","reference":"M.R. Lorenz, J. Phys. Solids 23, 939 (1962).","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-P6LPGYUWOE","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":7},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-3697(62)90151-8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-dbe99a6c#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1365,"temperature_printed":"1365","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1365},{"chemical_system":"CD-TE","cited_sources":[{"first_author":"Sysoev","kind":"unknown","label":"22","reference":"L.A. Sysoev, E.K. Raiskin, and V.R. Gur¢ev, Izv. Akad. Nauk SSSR, Neorg. Mater. 3, 390 (1967).","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-3O2HLZTJRX","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":11},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:d5a13113fb2e2cad","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"congruent_same_composition","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r-unplaced-e31204af#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1372,"temperature_printed":"1372","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1372},{"chemical_system":"CD-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-IGPIY3GP3B","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":1},"model":"Mcd72b7e2","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11664-009-0875-3","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.000182},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.0},"composition_source":"stoichiometric_model_phase","phase":"Cd"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cd","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> Cd + CdTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":594.13,"temperature_printed":"594.13","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":594.13},{"chemical_system":"CD-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-7CNJIIXQLI","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":3},"model":"Mcd72b7e2","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11664-009-0875-3","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r03#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"liq -> CdTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":1371,"temperature_printed":"1371","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1371},{"chemical_system":"CD-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.037,"dx":{"liq":0.0002},"model":"CdTe-09Liu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-2C3U3WQLAW","locator":{"ref":"doi:10.1007/s11664-009-0875-3/p7/tab-iii","row":12},"model":"Maaabc56b","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11664-009-0875-3","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11664-009-0875-3","paper_id":"doi:10.1007/s11664-009-0875-3","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.981},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"stoichiometric_model_phase","phase":"hex"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"CdTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"hex","mapping_confidence":"proposed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"},{"label":"CdTe","mapping_confidence":"proposed","model_phase":"ZINCBLENDE_B3"}],"pid":"doi:10.1007/s11664-009-0875-3/p7/tab-iii/r12#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> hex + CdTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CD-TE","system":"CD-TE","temperature_K":717.8,"temperature_printed":"717.8","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":717.8},{"chemical_system":"CD-TE","citations_printed":["12"],"cited_sources":[{"kind":"unknown","label":"12","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-NRDIIUXCVA.47f9fe","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(95)00038-g/p1/text-15"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","phases":[{"label":"CdTe"}],"pid":"doi:10.1016/0364-5916(95)00038-g/p1/text-15/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Their assessment predicts 1098'C for the melting point of CdTe compared with the mean experimental value of 1094°C.","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CD-TE","system":"CD-TE","temperature_K":1371.15,"temperature_printed":"1098'C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1371.15},{"chemical_system":"CD-TE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/0364-5916(95)00038-g"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-NRDIIUXCVA.e7c812","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(95)00038-g/p1/text-15"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/0364-5916(95)00038-g","own_work_of_paper":true},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","phases":[{"label":"CdTe"}],"pid":"doi:10.1016/0364-5916(95)00038-g/p1/text-15/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Their assessment predicts 1098'C for the melting point of CdTe compared with the mean experimental value of 1094°C.","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CD-TE","system":"CD-TE","temperature_K":1367.15,"temperature_printed":"1094°C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1367.15},{"chemical_system":"CD-TE","citations_printed":["19","20","21","25","26","27","28","64"],"cited_sources":[{"kind":"unknown","label":"19","status":"unresolved"},{"kind":"unknown","label":"20","status":"unresolved"},{"kind":"unknown","label":"21","status":"unresolved"},{"kind":"unknown","label":"25","status":"unresolved"},{"kind":"unknown","label":"26","status":"unresolved"},{"kind":"unknown","label":"27","status":"unresolved"},{"kind":"unknown","label":"28","status":"unresolved"},{"kind":"unknown","label":"64","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-4RO6YUHHJ2.7dadd8","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(95)00038-g/p7/text-85"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","pid":"doi:10.1016/0364-5916(95)00038-g/p7/text-85/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The melting point of CdTe is 1095°C and in excellent agreement with the mean of the experimental results (19,20, 21,25,26,27, 28, 64) 1093.6*7 \"C, if the low values of Kobayashi (18) and Gromakov et al. (29) are rejected.","quote_page":7,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CD-TE","system":"CD-TE","temperature_K":1366.75,"temperature_printed":"1093.6*7 \"C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1366.75},{"chemical_system":"CD-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-4RO6YUHHJ2.b60346","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(95)00038-g/p7/text-85"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/0364-5916(95)00038-g","own_work_of_paper":true},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","pid":"doi:10.1016/0364-5916(95)00038-g/p7/text-85/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The melting point of CdTe is 1095°C and in excellent agreement with the mean of the experimental results (19,20, 21,25,26,27, 28, 64) 1093.6*7 \"C, if the low values of Kobayashi (18) and Gromakov et al. (29) are rejected.","quote_page":7,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CD-TE","system":"CD-TE","temperature_K":1368.15,"temperature_printed":"1095°C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1368.15},{"chemical_system":"CD-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-B3YCIOM2LM","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(95)00038-g/p7/text-85"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/0364-5916(95)00038-g","own_work_of_paper":true},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","pid":"doi:10.1016/0364-5916(95)00038-g/p7/text-85/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Our optimisations indicate 447°C and 99 at% Te on the tellurium side and 32l.l\"C on the cadmium side; in both cases within 1°C of Sharma and Chang's assessment (12).","quote_page":7,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CD-TE","system":"CD-TE","temperature_K":720.15,"temperature_printed":"447°C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":720.15},{"chemical_system":"CD-TE","citations_printed":["13"],"cited_sources":[{"kind":"unknown","label":"13","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-DXMFA7XDBG","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(95)00038-g/p7/text-85"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/0364-5916(95)00038-g","paper_id":"doi:10.1016/0364-5916(95)00038-g","pid":"doi:10.1016/0364-5916(95)00038-g/p7/text-85/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Yu and Brebrick (13) indicate 446.6'C and 98.8 at% Te.","quote_page":7,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CD-TE","system":"CD-TE","temperature_K":719.75,"temperature_printed":"446.6'C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":719.75}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CD-TE"}