{"artifacts":{"sha256:8dc0ef42ead7e268/p26/tab-5":{"artifact":"table","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CE","DY","GD","LA","ND","PR","SM","TI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.calphad.2021.102357":{"authors":["Arkapol Saengdeejing","Ying Chen","Osamu Takeda","Masanori Enoki","Satoshi Sugimoto","Hiroshi Ohtani","Abe Taichi"],"citation":"Arkapol Saengdeejing, Ying Chen, Osamu Takeda, Masanori Enoki, Satoshi Sugimoto, Hiroshi Ohtani et al., Sm–Ti binary thermodynamic database and phase diagram, Calphad 75, 102357 (2021).","container":"Calphad","doi":"10.1016/j.calphad.2021.102357","doi_url":"https://doi.org/10.1016/j.calphad.2021.102357","id":"doi:10.1016/j.calphad.2021.102357","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"8dc0ef42ead7e268","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Sm–Ti binary thermodynamic database and phase diagram","year":2021}},"part":1,"parts":1,"records":[{"chemical_system":"CE-DY-GD-LA-ND-PR-SM-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"before":[{"label":"other"}],"evidence":{"doi":"10.1016/j.calphad.2021.102357","locator":{"artifact":"table","asset":"sha256:8dc0ef42ead7e268/p26/tab-5","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26,"row":1},"pdf_page":26,"pdf_sha256":"8dc0ef42ead7e268240d7cbde1f27843cf52ccb672331820ce19bcdd0147ca61","printed_phase_text":"L; L1; L2","rationale":"Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","rendered_page_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","report_id":"ORCHID-PR-20261027-v1","review_group":81,"table":"5"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":26,"pdf_sha256_prefix":"8dc0ef42ead7e268","seen":"L; L1; L2","verdict":"confirmed"}},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:composition","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-RJJK5HBOI3","locator":{"ref":"sha256:8dc0ef42ead7e268/p26/tab-5","row":1},"observation_type":"phase_transition","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2021.102357","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102357","paper_id":"doi:10.1016/j.calphad.2021.102357","phases":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"pid":"sha256:8dc0ef42ead7e268/p26/tab-5/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"La-Ti","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-DY-GD-LA-ND-PR-SM-TI","system":"CE-DY-GD-LA-ND-PR-SM-TI","temperature_K":2056.15,"temperature_basis":"printed","temperature_printed":"1783","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2056.15},{"chemical_system":"CE-DY-GD-LA-ND-PR-SM-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"before":[{"label":"other"}],"evidence":{"doi":"10.1016/j.calphad.2021.102357","locator":{"artifact":"table","asset":"sha256:8dc0ef42ead7e268/p26/tab-5","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26,"row":2},"pdf_page":26,"pdf_sha256":"8dc0ef42ead7e268240d7cbde1f27843cf52ccb672331820ce19bcdd0147ca61","printed_phase_text":"L; L1; L2","rationale":"Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","rendered_page_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","report_id":"ORCHID-PR-20261027-v1","review_group":81,"table":"5"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":26,"pdf_sha256_prefix":"8dc0ef42ead7e268","seen":"L; L1; L2","verdict":"confirmed"}},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:composition","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-GORW43PHTN","locator":{"ref":"sha256:8dc0ef42ead7e268/p26/tab-5","row":2},"observation_type":"phase_transition","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2021.102357","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102357","paper_id":"doi:10.1016/j.calphad.2021.102357","phases":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"pid":"sha256:8dc0ef42ead7e268/p26/tab-5/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ce-Ti","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-DY-GD-LA-ND-PR-SM-TI","system":"CE-DY-GD-LA-ND-PR-SM-TI","temperature_K":1923.15,"temperature_basis":"printed","temperature_printed":"1650","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1923.15},{"chemical_system":"CE-DY-GD-LA-ND-PR-SM-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"before":[{"label":"other"}],"evidence":{"doi":"10.1016/j.calphad.2021.102357","locator":{"artifact":"table","asset":"sha256:8dc0ef42ead7e268/p26/tab-5","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26,"row":3},"pdf_page":26,"pdf_sha256":"8dc0ef42ead7e268240d7cbde1f27843cf52ccb672331820ce19bcdd0147ca61","printed_phase_text":"L; L1; L2","rationale":"Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","rendered_page_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","report_id":"ORCHID-PR-20261027-v1","review_group":81,"table":"5"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":26,"pdf_sha256_prefix":"8dc0ef42ead7e268","seen":"L; L1; L2","verdict":"confirmed"}},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:composition","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-JIUSBGTCEK","locator":{"ref":"sha256:8dc0ef42ead7e268/p26/tab-5","row":3},"observation_type":"phase_transition","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2021.102357","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102357","paper_id":"doi:10.1016/j.calphad.2021.102357","phases":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"pid":"sha256:8dc0ef42ead7e268/p26/tab-5/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pr-Ti","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-DY-GD-LA-ND-PR-SM-TI","system":"CE-DY-GD-LA-ND-PR-SM-TI","temperature_K":2073.15,"temperature_basis":"printed","temperature_printed":"∼1800","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2073.15},{"chemical_system":"CE-DY-GD-LA-ND-PR-SM-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"before":[{"label":"other"}],"evidence":{"doi":"10.1016/j.calphad.2021.102357","locator":{"artifact":"table","asset":"sha256:8dc0ef42ead7e268/p26/tab-5","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26,"row":4},"pdf_page":26,"pdf_sha256":"8dc0ef42ead7e268240d7cbde1f27843cf52ccb672331820ce19bcdd0147ca61","printed_phase_text":"L; L1; L2","rationale":"Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","rendered_page_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","report_id":"ORCHID-PR-20261027-v1","review_group":81,"table":"5"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":26,"pdf_sha256_prefix":"8dc0ef42ead7e268","seen":"L; L1; L2","verdict":"confirmed"}},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:composition","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-JDTKGIRHKC","locator":{"ref":"sha256:8dc0ef42ead7e268/p26/tab-5","row":4},"observation_type":"phase_transition","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2021.102357","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102357","paper_id":"doi:10.1016/j.calphad.2021.102357","phases":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"pid":"sha256:8dc0ef42ead7e268/p26/tab-5/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Nd-Ti","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-DY-GD-LA-ND-PR-SM-TI","system":"CE-DY-GD-LA-ND-PR-SM-TI","temperature_K":2123.15,"temperature_basis":"printed","temperature_printed":"∼1850","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2123.15},{"chemical_system":"CE-DY-GD-LA-ND-PR-SM-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"before":[{"label":"other"}],"evidence":{"doi":"10.1016/j.calphad.2021.102357","locator":{"artifact":"table","asset":"sha256:8dc0ef42ead7e268/p26/tab-5","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26,"row":5},"pdf_page":26,"pdf_sha256":"8dc0ef42ead7e268240d7cbde1f27843cf52ccb672331820ce19bcdd0147ca61","printed_phase_text":"L; L1; L2","rationale":"Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","rendered_page_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","report_id":"ORCHID-PR-20261027-v1","review_group":81,"table":"5"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":26,"pdf_sha256_prefix":"8dc0ef42ead7e268","seen":"L; L1; L2","verdict":"confirmed"}},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:composition","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-D3NMGVUIN3","locator":{"ref":"sha256:8dc0ef42ead7e268/p26/tab-5","row":5},"observation_type":"phase_transition","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2021.102357","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102357","paper_id":"doi:10.1016/j.calphad.2021.102357","phases":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"pid":"sha256:8dc0ef42ead7e268/p26/tab-5/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Sm-Ti","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-DY-GD-LA-ND-PR-SM-TI","system":"CE-DY-GD-LA-ND-PR-SM-TI","temperature_K":2273.15,"temperature_basis":"printed","temperature_printed":"∼2000*","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2273.15},{"chemical_system":"CE-DY-GD-LA-ND-PR-SM-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"before":[{"label":"other"}],"evidence":{"doi":"10.1016/j.calphad.2021.102357","locator":{"artifact":"table","asset":"sha256:8dc0ef42ead7e268/p26/tab-5","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26,"row":6},"pdf_page":26,"pdf_sha256":"8dc0ef42ead7e268240d7cbde1f27843cf52ccb672331820ce19bcdd0147ca61","printed_phase_text":"L; L1; L2","rationale":"Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","rendered_page_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","report_id":"ORCHID-PR-20261027-v1","review_group":81,"table":"5"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":26,"pdf_sha256_prefix":"8dc0ef42ead7e268","seen":"L; L1; L2","verdict":"confirmed"}},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:composition","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-GRU3R3MWHX","locator":{"ref":"sha256:8dc0ef42ead7e268/p26/tab-5","row":6},"observation_type":"phase_transition","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2021.102357","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102357","paper_id":"doi:10.1016/j.calphad.2021.102357","phases":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"pid":"sha256:8dc0ef42ead7e268/p26/tab-5/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Gd-Ti","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-DY-GD-LA-ND-PR-SM-TI","system":"CE-DY-GD-LA-ND-PR-SM-TI","temperature_K":1773.15,"temperature_basis":"printed","temperature_printed":"∼1500","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1773.15},{"chemical_system":"CE-DY-GD-LA-ND-PR-SM-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"before":[{"label":"other"}],"evidence":{"doi":"10.1016/j.calphad.2021.102357","locator":{"artifact":"table","asset":"sha256:8dc0ef42ead7e268/p26/tab-5","caption":"Maximum temperature of liquid miscibility in Ln-Ti series[10, 11, 12, 13, 14, 16].","label":"5","page":26,"row":7},"pdf_page":26,"pdf_sha256":"8dc0ef42ead7e268240d7cbde1f27843cf52ccb672331820ce19bcdd0147ca61","printed_phase_text":"L; L1; L2","rationale":"Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","rendered_page_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","report_id":"ORCHID-PR-20261027-v1","review_group":81,"table":"5"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"d22e42eb286666a31029e7e316854d9230a011675e7bc643101a1107662fefcb","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":26,"pdf_sha256_prefix":"8dc0ef42ead7e268","seen":"L; L1; L2","verdict":"confirmed"}},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:composition","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table 5 liquid-miscibility maxima and adjacent explicit L to L1+L2 description. Sm-Ti value is predicted; critical endpoint interpretation still requires downstream review.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-RXSX74KW47","locator":{"ref":"sha256:8dc0ef42ead7e268/p26/tab-5","row":7},"observation_type":"phase_transition","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2021.102357","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102357","paper_id":"doi:10.1016/j.calphad.2021.102357","phases":[{"label":"L","label_source":"printed_source_page"},{"label":"L1","label_source":"printed_source_page"},{"label":"L2","label_source":"printed_source_page"}],"pid":"sha256:8dc0ef42ead7e268/p26/tab-5/r07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Dy-Ti","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-DY-GD-LA-ND-PR-SM-TI","system":"CE-DY-GD-LA-ND-PR-SM-TI","temperature_K":1713.15,"temperature_basis":"printed","temperature_printed":"1440","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1713.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CE-DY-GD-LA-ND-PR-SM-TI"}