{"artifacts":{"doi:10.1007/s11669-010-9753-1/p4/tab-2":{"artifact":"table","caption":"Calculated invariant reactions in the Mo-Ce system compared with available literature data","label":"2","page":4},"doi:10.1007/s11669-010-9753-1/p4/tab-3":{"artifact":"table","caption":"Calculated solubility of Mo in liquid Ce for the Mo-Ce system compared with available literature data","label":"3","page":4}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CE","MO"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M3c181aa6":{"catalog_entry":{"license":"CC BY 4.0","name":"CeMo-10Cha.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib. Diffus., 31, 414-20(2010).","model_doi":"10.1007/s11669-010-9753-1","reproduced_by_calculation":true,"tdb":"CeMo-10Cha.tdb","tdb_path":"databases/sgte-binary/CeMo-10Cha.tdb","tdb_sha256":"faf1991c7387bbb6a125cd08e5cb168fe4d719a2f2b477061890f50a091a8b34"},"M92de17c5":{"catalog_entry":{"license":"CC BY 4.0","name":"CeMo-10Cha.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib. Diffus., 31, 414-20(2010).","model_doi":"10.1007/s11669-010-9753-1","reproduced_by_calculation":false,"tdb":"CeMo-10Cha.tdb","tdb_path":"databases/sgte-binary/CeMo-10Cha.tdb","tdb_sha256":"faf1991c7387bbb6a125cd08e5cb168fe4d719a2f2b477061890f50a091a8b34"},"Mf4cfdc3e":{"catalog_entry":{"license":"CC BY 4.0","name":"CeMo-10Cha.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"J. Phase Equilib. Diffus., 31, 414-20(2010).","model_doi":"10.1007/s11669-010-9753-1","tdb":"CeMo-10Cha.tdb","tdb_path":"databases/sgte-binary/CeMo-10Cha.tdb","tdb_sha256":"faf1991c7387bbb6a125cd08e5cb168fe4d719a2f2b477061890f50a091a8b34"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02648371":{"citation":"A. Palenzona and S. Cirafici, The Ce-Mo (Cerium-Molybdenum) System, J. Phase Equilb., 1996, 17, p 57-59","doi":"10.1007/bf02648371","doi_url":"https://doi.org/10.1007/bf02648371","id":"doi:10.1007/bf02648371","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1007/s11669-010-9753-1":{"authors":["Wren Chan","Michael C. Gao","Ömer N. Doğan","Paul King"],"citation":"Wren Chan, Michael C. Gao, Ömer N. Doğan, Paul King, Thermodynamic Assessment of Mo-Ce and Mo-Y Systems, J. Phase Equilib. Diffus. 31, 414-420 (2010).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-010-9753-1","doi_url":"https://doi.org/10.1007/s11669-010-9753-1","id":"doi:10.1007/s11669-010-9753-1","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"a57326fa5bc10df9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessment of Mo-Ce and Mo-Y Systems","year":2010}},"part":1,"parts":1,"records":[{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Gaume-Mahn","kind":"unknown","label":"9","reference":"F. Gaume-Mahn and M. Blanchard, Chimie Minerale— Attaque Du Molybdene Par Le Cerium Liquide, Comptes 420 Rendus Hebdomadaires Des Seances De L Academie Des Sciences, 1962, 254, p 1082","status":"resolved","year":"1962"},{"first_author":"Gaume-Mahn","kind":"unknown","label":"10","reference":"F. Gaume-Mahn and C. Madèj, The Rare Earth MetalRefractory Metal Systems and Their Applications, Progr. Sci. Technol. Rare Earth, 1968, 3, p 515-537","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-6254STCMTY","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999984,"MO":1.6e-05},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999984,"MO":1.6e-05},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1073.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-JZEICUQMMF","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":2},"model":"Mf4cfdc3e","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999999,"MO":1e-06},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999999,"MO":1e-06},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1073.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Gaume-Mahn","kind":"unknown","label":"9","reference":"F. Gaume-Mahn and M. Blanchard, Chimie Minerale— Attaque Du Molybdene Par Le Cerium Liquide, Comptes 420 Rendus Hebdomadaires Des Seances De L Academie Des Sciences, 1962, 254, p 1082","status":"resolved","year":"1962"},{"first_author":"Gaume-Mahn","kind":"unknown","label":"10","reference":"F. Gaume-Mahn and C. Madèj, The Rare Earth MetalRefractory Metal Systems and Their Applications, Progr. Sci. Technol. Rare Earth, 1968, 3, p 515-537","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-KXMWRDDCVV","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":3},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999964,"MO":3.6e-05},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999964,"MO":3.6e-05},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1173.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-WI4RJ5LPA6","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":4},"model":"Mf4cfdc3e","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999995,"MO":5e-06},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999995,"MO":5e-06},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1173.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Gaume-Mahn","kind":"unknown","label":"9","reference":"F. Gaume-Mahn and M. Blanchard, Chimie Minerale— Attaque Du Molybdene Par Le Cerium Liquide, Comptes 420 Rendus Hebdomadaires Des Seances De L Academie Des Sciences, 1962, 254, p 1082","status":"resolved","year":"1962"},{"first_author":"Gaume-Mahn","kind":"unknown","label":"10","reference":"F. Gaume-Mahn and C. Madèj, The Rare Earth MetalRefractory Metal Systems and Their Applications, Progr. Sci. Technol. Rare Earth, 1968, 3, p 515-537","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-YVKEZTZFRG","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999781,"MO":0.000219},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999781,"MO":0.000219},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1373.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-W5PBJ2ZQPU","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":6},"model":"Mf4cfdc3e","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999922,"MO":7.8e-05},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999922,"MO":7.8e-05},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1373.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Gaume-Mahn","kind":"unknown","label":"9","reference":"F. Gaume-Mahn and M. Blanchard, Chimie Minerale— Attaque Du Molybdene Par Le Cerium Liquide, Comptes 420 Rendus Hebdomadaires Des Seances De L Academie Des Sciences, 1962, 254, p 1082","status":"resolved","year":"1962"},{"first_author":"Gaume-Mahn","kind":"unknown","label":"10","reference":"F. Gaume-Mahn and C. Madèj, The Rare Earth MetalRefractory Metal Systems and Their Applications, Progr. Sci. Technol. Rare Earth, 1968, 3, p 515-537","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-PFALVZRPXU","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":7},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999744,"MO":0.000256},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999744,"MO":0.000256},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-QNASE64RS2","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":8},"model":"Mf4cfdc3e","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999758,"MO":0.000242},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999758,"MO":0.000242},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Daane","kind":"unknown","label":"13","reference":"A.H. Daane and F.H. Spedding, Quarterly Summary Research Report in Chemistry for July, August and September 1954, U.S. At. Energy Comm. ISC-530, 1954","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-R72IEV4EH2","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":9},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.99708,"MO":0.00292},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.99708,"MO":0.00292},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":2,"id":"ORC-HW35254GH3","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-3","row":10},"model":"Mf4cfdc3e","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999345,"MO":0.000655},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CE":0.999345,"MO":0.000655},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-3/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Brewer","kind":"unknown","label":"12","reference":"L. Brewer, R.H. Lamoreaux, R. Ferro, R. Marazza, and K. Girgis, Molybdenum: Physico-Chemical Properties of its Compounds and Alloys, International Atomic Energy Agency, Vienna, 1980","status":"resolved","year":"1980"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-WQKHBLJVZF","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":1},"observation_type":"invariant_reaction","origin":{"basis":"caption_names_calc_only_but_row_cites_work","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.933},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.32},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.997},"composition_source":"printed","phase":"Mo"}],"phases":[{"label":"L2","model_phase":"LIQUID"},{"label":"L1","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 <-> L1 + Mo"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":2800.15,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2800.15},{"chemical_system":"CE-MO","cited_sources":[{"doi":"10.1007/bf02648371","first_author":"Palenzona","kind":"assessment","label":"7","paper":"doi:10.1007/bf02648371","reference":"A. Palenzona and S. Cirafici, The Ce-Mo (Cerium-Molybdenum) System, J. Phase Equilb., 1996, 17, p 57-59","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-MZ5DXT5PA4","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":2},"observation_type":"invariant_reaction","origin":{"basis":"caption_names_calc_only_but_row_cites_work","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.905},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.24},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.996},"composition_source":"printed","phase":"Mo"}],"phases":[{"label":"L2","model_phase":"LIQUID"},{"label":"L1","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 <-> L1 + Mo"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":2800.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2800.15},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"6","reference":"T.B. Massalski, P.R. Subramanian, H. Okamoto, and L. Kacprzak, Binary Alloy Phase Diagrams, Vol 1–3, 2nd ed., ASM International, Materials Park, OH, 1990","status":"resolved","year":"1990"},{"doi":"10.1007/bf02648371","first_author":"Palenzona","kind":"assessment","label":"7","paper":"doi:10.1007/bf02648371","reference":"A. Palenzona and S. Cirafici, The Ce-Mo (Cerium-Molybdenum) System, J. Phase Equilb., 1996, 17, p 57-59","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-5EAZ4GXAJQ","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":3},"observation_type":"invariant_reaction","origin":{"basis":"caption_names_calc_only_but_row_cites_work","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.905},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.32},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.996},"composition_source":"printed","phase":"Mo"}],"phases":[{"label":"L2","model_phase":"LIQUID"},{"label":"L1","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 <-> L1 + Mo"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":2800.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2800.15},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-AQHCJ2N24E","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":4},"model":"M3c181aa6","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.9274},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.3235},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.9969},"composition_source":"printed","phase":"Mo"}],"phases":[{"label":"L2","model_phase":"LIQUID"},{"label":"L1","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 <-> L1 + Mo"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":2805.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2805.15},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Brewer","kind":"unknown","label":"12","reference":"L. Brewer, R.H. Lamoreaux, R. Ferro, R. Marazza, and K. Girgis, Molybdenum: Physico-Chemical Properties of its Compounds and Alloys, International Atomic Energy Agency, Vienna, 1980","status":"resolved","year":"1980"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":["L","Mo","δCe"],"before":["L","Mo"],"evidence":{"added":["δCe"],"printed":"L + Mo <-> δCe"},"field":"phases","gate":"R3I","rule":"phases_from_printed_reaction"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phases_added_from_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"gate_failures":[{"code":"phases_added_from_printed_reaction","detail":"phases ['δCe'] read from the printed reaction; not mapped to model phases","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-MK5Z7IYKSJ","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":5},"observation_type":"invariant_reaction","origin":{"basis":"caption_names_calc_only_but_row_cites_work","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0007},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"δCe","label_source":"printed_reaction"}],"phases_stored":[{"label":"L","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Mo <-> δCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1071.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1071.15},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"6","reference":"T.B. Massalski, P.R. Subramanian, H. Okamoto, and L. Kacprzak, Binary Alloy Phase Diagrams, Vol 1–3, 2nd ed., ASM International, Materials Park, OH, 1990","status":"resolved","year":"1990"},{"doi":"10.1007/bf02648371","first_author":"Palenzona","kind":"assessment","label":"7","paper":"doi:10.1007/bf02648371","reference":"A. Palenzona and S. Cirafici, The Ce-Mo (Cerium-Molybdenum) System, J. Phase Equilb., 1996, 17, p 57-59","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":["L","Mo","δCe"],"before":["L","Mo"],"evidence":{"added":["δCe"],"printed":"L + Mo <-> δCe"},"field":"phases","gate":"R3I","rule":"phases_from_printed_reaction"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phases_added_from_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"gate_failures":[{"code":"phases_added_from_printed_reaction","detail":"phases ['δCe'] read from the printed reaction; not mapped to model phases","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-H2S3EG5YWI","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":6},"observation_type":"invariant_reaction","origin":{"basis":"caption_names_calc_only_but_row_cites_work","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"δCe","label_source":"printed_reaction"}],"phases_stored":[{"label":"L","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Mo <-> δCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1071.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1071.15},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-BOUI3Q6SCS","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":7},"model":"M92de17c5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":1.0},"composition_source":"printed","phase":"Mo"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"δCe"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"δCe","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Mo <-> δCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1072.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1072.15},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"6","reference":"T.B. Massalski, P.R. Subramanian, H. Okamoto, and L. Kacprzak, Binary Alloy Phase Diagrams, Vol 1–3, 2nd ed., ASM International, Materials Park, OH, 1990","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-KTZZ4G4KP4","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":8},"observation_type":"invariant_reaction","origin":{"basis":"cited_evaluation_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"δCe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":1.0},"composition_source":"printed","phase":"Mo"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"γCe"}],"phases":[{"label":"δCe","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γCe","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δCe + Mo <-> γCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":999.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":999.15},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-AICG25OWGZ","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":9},"model":"M92de17c5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"δCe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":1.0},"composition_source":"printed","phase":"Mo"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"γCe"}],"phases":[{"label":"δCe","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γCe","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δCe + Mo <-> γCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":1000.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1000.15},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"6","reference":"T.B. Massalski, P.R. Subramanian, H. Okamoto, and L. Kacprzak, Binary Alloy Phase Diagrams, Vol 1–3, 2nd ed., ASM International, Materials Park, OH, 1990","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"βCe","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-YFMAF2FE5L","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":10},"observation_type":"invariant_reaction","origin":{"basis":"cited_evaluation_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"γCe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":1.0},"composition_source":"printed","phase":"Mo"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"βCe"}],"phases":[{"label":"γCe","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βCe","model_phase_rejected":{"model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γCe <-> Mo + βCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":334.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":334.15},{"chemical_system":"CE-MO","cited_sources":[{"first_author":"Gschneidner","kind":"unknown","label":"17","reference":"K.A. Gschneidner, Jr, and V.K. Pecharsky, The Standard State of Cerium, J. Phase Equilb., 1999, 20, p 612-614 Journal of Phase Equilibria and Diffusion Vol. 31 No. 5 2010","status":"resolved","year":"2010"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":["γCe","Mo","βCe"],"before":["γCe","Mo"],"evidence":{"added":["βCe"],"printed":"γCe <-> Mo + βCe"},"field":"phases","gate":"R3I","rule":"phases_from_printed_reaction"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phases_added_from_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"gate_failures":[{"code":"phases_added_from_printed_reaction","detail":"phases ['βCe'] read from the printed reaction; not mapped to model phases","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-5TIF24HIXD","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":11},"observation_type":"invariant_reaction","origin":{"basis":"caption_names_calc_only_but_row_cites_work","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phases":[{"label":"γCe","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βCe","label_source":"printed_reaction"}],"phases_stored":[{"label":"γCe","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W"}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γCe <-> Mo + βCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":283.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":283.15},{"chemical_system":"CE-MO","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"βCe","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-LJT3ZMNPHB","locator":{"ref":"doi:10.1007/s11669-010-9753-1/p4/tab-2","row":12},"model":"M92de17c5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-010-9753-1","own_work_of_paper":true},"paper":"doi:10.1007/s11669-010-9753-1","paper_id":"doi:10.1007/s11669-010-9753-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"γCe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":1.0},"composition_source":"printed","phase":"Mo"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MO":0.0},"composition_source":"printed","phase":"βCe"}],"phases":[{"label":"γCe","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Mo","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βCe","model_phase_rejected":{"model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/s11669-010-9753-1/p4/tab-2/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γCe <-> Mo + βCe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CE-MO","system":"CE-MO","temperature_K":283.15,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":283.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CE-MO"}