{"artifacts":{"doi:10.1016/j.calphad.2015.02.004/p6/tab-4":{"artifact":"table","caption":"Temperature and phases involved in invariant transitions in the ternary systems according to the present description.","label":"4","page":6}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CR","GE","MN","SI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.calphad.2015.02.004":{"authors":["A. Berche","J.C. Tédenac","P. Jund"],"citation":"A. Berche, J.C. Tédenac, P. Jund, Ab-initio calculations and CALPHAD description of Cr–Ge–Mn and Cr–Ge–Si, Calphad 49, 50-57 (2015).","container":"Calphad","doi":"10.1016/j.calphad.2015.02.004","doi_url":"https://doi.org/10.1016/j.calphad.2015.02.004","id":"doi:10.1016/j.calphad.2015.02.004","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"6e94c1245ff7c144","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Ab-initio calculations and CALPHAD description of Cr–Ge–Mn and Cr–Ge–Si","year":2015}},"part":1,"parts":1,"records":[{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-5CXXGF3FTN","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Diamond"},{"label":"B20"},{"label":"Mn11Ge8"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":998.0,"temperature_printed":"998","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":998.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-QEZZVGBHPO","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"B20"},{"label":"Mn11Ge8"},{"label":"D88"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1072.0,"temperature_printed":"1072","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1072.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-FYE6ASFWFJ","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Mn3Ge"},{"label":"σ"},{"label":"Mn5Ge2"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1143.5,"temperature_printed":"1143.5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1143.5},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-RCUWKIQMW3","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Mn3Ge"},{"label":"σ"},{"label":"Fcc_A1"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1146.0,"temperature_printed":"1146","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1146.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-X7AQPYC777","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"σ"},{"label":"B20"},{"label":"Mn5Ge2"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1151.0,"temperature_printed":"1151","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1151.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-WFCQP2BQV7","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"B20"},{"label":"Mn2Ge"},{"label":"Mn5Ge2"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1153.5,"temperature_printed":"1153.5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1153.5},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-QHPDMIE3IN","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"diamond"},{"label":"B20"},{"label":"Mn11Si19"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1166.0,"temperature_printed":"1166","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1166.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-OKTDJ4IURU","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"B20"},{"label":"Mn2Ge"},{"label":"D88"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1210.0,"temperature_printed":"1210","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1210.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-DTI6YF4WAI","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"A15"},{"label":"B20"},{"label":"σ"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1347.0,"temperature_printed":"1347","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1347.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-CT4XT4KIFC","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Cub_A13"},{"label":"σ"},{"label":"Fcc_A1"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1378.0,"temperature_printed":"1378","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-RY2IQJG6SZ","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Cub_A13"},{"label":"Bcc_A2"},{"label":"Fcc_A1"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1385.0,"temperature_printed":"1385","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1385.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-ODRJTTDMYE","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":12},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Cub_A13"},{"label":"Bcc_A2"},{"label":"σ"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1386.0,"temperature_printed":"1386","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1386.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-N23U67JS74","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":13},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Mn11Ge8"},{"label":"B20"},{"label":"D8m"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1453.0,"temperature_printed":"1453","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1453.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-HLQ7FB4F7G","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":14},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"A15"},{"label":"Bcc_A2"},{"label":"σ"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1499.0,"temperature_printed":"1499","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1499.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-Q6SLQ3PCC4","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":15},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"A15"},{"label":"B20"},{"label":"D8m"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1510.0,"temperature_printed":"1510","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1510.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-3SA6K4RHPM","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":16},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Diamond"},{"label":"D8m"},{"label":"B20"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1180.0,"temperature_printed":"1180","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1180.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-QV4ZZY6KGJ","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":17},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Diamond"},{"label":"D8m"},{"label":"Mn11Si19"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1179.0,"temperature_printed":"1179","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1179.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-TXNI7WKF2P","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":18},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"B20"},{"label":"D8m"},{"label":"Mn11Si19"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1216.0,"temperature_printed":"1216","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1216.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-SUHF6KNJJG","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":19},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"Diamond"},{"label":"CrSi2"},{"label":"B20"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1228.0,"temperature_printed":"1228","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1228.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-ESATGJIKBR","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":20},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"B20"},{"label":"D8m"},{"label":"Mn11Ge8"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1281.0,"temperature_printed":"1281","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1281.0},{"chemical_system":"CR-GE-MN-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-T2PHQQFPYK","locator":{"ref":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4","row":21},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2015.02.004","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2015.02.004","paper_id":"doi:10.1016/j.calphad.2015.02.004","phases":[{"label":"Liquid"},{"label":"A15"},{"label":"D8m"},{"label":"D88"}],"pid":"doi:10.1016/j.calphad.2015.02.004/p6/tab-4/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-GE-MN-SI","system":"CR-GE-MN-SI","temperature_K":1817.0,"temperature_printed":"1817","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1817.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CR-GE-MN-SI"}