{"artifacts":{"sha256:f9ce77d73011da3e/p3/tab-1":{"artifact":"table","caption":"Calculated and experimental lattice parameters of the SER structures. Symbols a and c stand for lattice constants, V at is the atomic volume and 1 shows the relative difference between the calculated and experimental atomic volume.","label":"1","page":3},"sha256:f9ce77d73011da3e/p3/tab-2":{"artifact":"table","caption":"Equilibrium structural parameters of the C14, C15 and C36 Laves phases found in this work. Symbols a and c stand for lattice constants, z , x and y are the internal structural parameters and V at is the atomic volume.","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CR","HF","TI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.calphad.2010.03.003":{"authors":["J. Pavlů","J. Vřešt’ál","M. Šob"],"citation":"J. Pavlů, J. Vřešt’ál, M. Šob, Thermodynamic modeling of Laves phases in the Cr–Hf and Cr–Ti systems: Reassessment using first-principles results, Calphad 34, 215-221 (2010).","container":"Calphad","doi":"10.1016/j.calphad.2010.03.003","doi_url":"https://doi.org/10.1016/j.calphad.2010.03.003","id":"doi:10.1016/j.calphad.2010.03.003","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"Thermodynamic modeling of Laves phases in the Cr–Hf and Cr–Ti systems: Reassessment using first-principles results","year":2010},"doi:10.1103/physrevb.47.3255":{"authors":["E. G. Moroni","T. Jarlborg"],"citation":"E. G. Moroni, T. Jarlborg, Electronic structure, ordering effects, phase stability, and magnetism in<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=\"normal\">Fe</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mi mathvariant=\"normal\">−</mml:mi><mml:mi mathvariant=\"italic\">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=\"normal\">Cr</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant=\"italic\">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>systems, Phys. Rev. B 47, 3255-3267 (1993).","container":"Phys. Rev. B","doi":"10.1103/physrevb.47.3255","doi_url":"https://doi.org/10.1103/physrevb.47.3255","id":"doi:10.1103/physrevb.47.3255","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Electronic structure, ordering effects, phase stability, and magnetism in<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=\"normal\">Fe</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mi mathvariant=\"normal\">−</mml:mi><mml:mi mathvariant=\"italic\">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=\"normal\">Cr</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant=\"italic\">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>systems","year":1993}},"part":1,"parts":1,"records":[{"chemical_system":"CR-HF-TI","cited_sources":[{"doi":"10.1103/physrevb.47.3255","first_author":"Moroni","kind":"unknown","label":"23","paper":"doi:10.1103/physrevb.47.3255","reference":"E.G. Moroni, T. Jarlborg, Phys. Rev. B 47 (1993) 3255.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":1,"id":"ORC-4QUVFKYJ6A.23ae0f","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006333,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006333},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8787,"value_stored":287.87},{"chemical_system":"CR-HF-TI","cited_sources":[{"doi":"10.1103/physrevb.47.3255","first_author":"Moroni","kind":"unknown","label":"23","paper":"doi:10.1103/physrevb.47.3255","reference":"E.G. Moroni, T. Jarlborg, Phys. Rev. B 47 (1993) 3255.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":1,"id":"ORC-4QUVFKYJ6A.290fbd","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006333,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006333},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8787,"value_stored":287.87},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-VLOGX6GLGA.98691f","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006281,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006281},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8548,"value_stored":285.48},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-VLOGX6GLGA.a4cb3d","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006281,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006281},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8548,"value_stored":285.48},{"chemical_system":"CR-HF-TI","cited_sources":[{"doi":"10.1103/physrevb.47.3255","first_author":"Moroni","kind":"unknown","label":"23","paper":"doi:10.1103/physrevb.47.3255","reference":"E.G. Moroni, T. Jarlborg, Phys. Rev. B 47 (1993) 3255.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Structure column label 'AFM BCC Cr' spanning its Exp./Relax. lines","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t075"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"d95598ba16f9e5b63daf27361ca213cd840604acc97d1adccd801f366932b14d","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading (placeholder phase) of the AFM BCC Cr lines: Exp. 287.87/287.87/1.19281 and Relax. 285.48/285.48/1.16327; matches sibling records labelled 'AFM BCC Cr'","verdict":"confirmed"}},{"after":"ORC-4QUVFKYJ6A.290fbd","before":null,"evidence":{"decision_file":"dup1_t075.json","kept_id":"ORC-4QUVFKYJ6A.290fbd","paper":"doi:10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","rationale":"same printed cell (AFM BCC Cr Exp. [23] line, LATTICE_A 287.87 pm): placeholder r7 is a second reading of phased r1; natural alias ORC-3XY4GAER2L.6fa1a0 is EXCL, pair left unchanged; kept ORC-4QUVFKYJ6A.290fbd is not worse (same value/T, real printed phase), so no flip","report_id":"ORCHID-Y10-20261027-v1","table_key":"t075"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"b6f86d68b726e8598dea76b5a86d46695d46dfa6ee8ef3cb326bc863706033f7","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"same printed cell (AFM BCC Cr Exp. [23] line, LATTICE_A 287.87 pm): placeholder r7 is a second reading of phased r1; natural alias ORC-3XY4GAER2L.6fa1a0 is EXCL, pair left unchanged; kept ORC-4QUVFKYJ6A.290fbd is not worse (same value/T, real printed phase), so no flip","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-4QUVFKYJ6A.290fbd","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-3XY4GAER2L.6fa1a0","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006333,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006333},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8787,"value_stored":287.87},{"chemical_system":"CR-HF-TI","cited_sources":[{"doi":"10.1103/physrevb.47.3255","first_author":"Moroni","kind":"unknown","label":"23","paper":"doi:10.1103/physrevb.47.3255","reference":"E.G. Moroni, T. Jarlborg, Phys. Rev. B 47 (1993) 3255.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Structure column label 'AFM BCC Cr' spanning its Exp./Relax. lines","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t075"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"d95598ba16f9e5b63daf27361ca213cd840604acc97d1adccd801f366932b14d","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading (placeholder phase) of the AFM BCC Cr lines: Exp. 287.87/287.87/1.19281 and Relax. 285.48/285.48/1.16327; matches sibling records labelled 'AFM BCC Cr'","verdict":"confirmed"}},{"after":"ORC-4QUVFKYJ6A.23ae0f","before":null,"evidence":{"decision_file":"dup1_t075.json","kept_id":"ORC-4QUVFKYJ6A.23ae0f","paper":"doi:10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","rationale":"same printed cell (AFM BCC Cr Exp. [23] line, LATTICE_C 287.87 pm): placeholder r7 is a second reading of phased r1; natural alias ORC-3XY4GAER2L.c87910 is EXCL, pair left unchanged; kept ORC-4QUVFKYJ6A.23ae0f is not worse (same value/T, real printed phase), so no flip","report_id":"ORCHID-Y10-20261027-v1","table_key":"t075"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"b6f86d68b726e8598dea76b5a86d46695d46dfa6ee8ef3cb326bc863706033f7","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"same printed cell (AFM BCC Cr Exp. [23] line, LATTICE_C 287.87 pm): placeholder r7 is a second reading of phased r1; natural alias ORC-3XY4GAER2L.c87910 is EXCL, pair left unchanged; kept ORC-4QUVFKYJ6A.23ae0f is not worse (same value/T, real printed phase), so no flip","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-4QUVFKYJ6A.23ae0f","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-3XY4GAER2L.c87910","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006333,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006333},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8787,"value_stored":287.87},{"chemical_system":"CR-HF-TI","cited_sources":[{"doi":"10.1103/physrevb.47.3255","first_author":"Moroni","kind":"unknown","label":"23","paper":"doi:10.1103/physrevb.47.3255","reference":"E.G. Moroni, T. Jarlborg, Phys. Rev. B 47 (1993) 3255.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Structure column label 'AFM BCC Cr' spanning its Exp./Relax. lines","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t075"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"d95598ba16f9e5b63daf27361ca213cd840604acc97d1adccd801f366932b14d","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading (placeholder phase) of the AFM BCC Cr lines: Exp. 287.87/287.87/1.19281 and Relax. 285.48/285.48/1.16327; matches sibling records labelled 'AFM BCC Cr'","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-3XY4GAER2L.f9196c","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V_ATOM","property_code_raw":"LATTICE_V_AT","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006441,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.003722,0.019682],"class":"unknown","entry":"value_types/VOLUME/classes/unknown","floor":0.0054,"floor_unit":"relative (fraction of the value)","n_pairs":43,"prior_source":"orchid_assumed","value":0.006441},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"10^7 pm^3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"10^7 pm^3","value":1.19281},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Structure column label 'AFM BCC Cr' spanning its Exp./Relax. lines","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t075"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"d95598ba16f9e5b63daf27361ca213cd840604acc97d1adccd801f366932b14d","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading (placeholder phase) of the AFM BCC Cr lines: Exp. 287.87/287.87/1.19281 and Relax. 285.48/285.48/1.16327; matches sibling records labelled 'AFM BCC Cr'","verdict":"confirmed"}},{"after":"ORC-VLOGX6GLGA.98691f","before":null,"evidence":{"decision_file":"dup1_t075.json","kept_id":"ORC-VLOGX6GLGA.98691f","paper":"doi:10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","rationale":"same printed cell (AFM BCC Cr Relax. line, LATTICE_C 285.48 pm): placeholder r8 is a second reading of phased r2; natural alias ORC-MYGV625N6C.446c32 is EXCL, pair left unchanged; kept ORC-VLOGX6GLGA.98691f is not worse (same value/T, real printed phase), so no flip","report_id":"ORCHID-Y10-20261027-v1","table_key":"t075"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"b6f86d68b726e8598dea76b5a86d46695d46dfa6ee8ef3cb326bc863706033f7","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"same printed cell (AFM BCC Cr Relax. line, LATTICE_C 285.48 pm): placeholder r8 is a second reading of phased r2; natural alias ORC-MYGV625N6C.446c32 is EXCL, pair left unchanged; kept ORC-VLOGX6GLGA.98691f is not worse (same value/T, real printed phase), so no flip","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-VLOGX6GLGA.98691f","evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-MYGV625N6C.446c32","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006281,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006281},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8548,"value_stored":285.48},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Structure column label 'AFM BCC Cr' spanning its Exp./Relax. lines","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t075"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"d95598ba16f9e5b63daf27361ca213cd840604acc97d1adccd801f366932b14d","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading (placeholder phase) of the AFM BCC Cr lines: Exp. 287.87/287.87/1.19281 and Relax. 285.48/285.48/1.16327; matches sibling records labelled 'AFM BCC Cr'","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-MYGV625N6C.dcf7f9","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V_ATOM","property_code_raw":"LATTICE_V_AT","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006282,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.003722,0.019682],"class":"unknown","entry":"value_types/VOLUME/classes/unknown","floor":0.0054,"floor_unit":"relative (fraction of the value)","n_pairs":43,"prior_source":"orchid_assumed","value":0.006282},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"10^7 pm^3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"10^7 pm^3","value":1.16327},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Structure column label 'AFM BCC Cr' spanning its Exp./Relax. lines","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t075"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"d95598ba16f9e5b63daf27361ca213cd840604acc97d1adccd801f366932b14d","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading (placeholder phase) of the AFM BCC Cr lines: Exp. 287.87/287.87/1.19281 and Relax. 285.48/285.48/1.16327; matches sibling records labelled 'AFM BCC Cr'","verdict":"confirmed"}},{"after":"ORC-VLOGX6GLGA.a4cb3d","before":null,"evidence":{"decision_file":"dup1_t075.json","kept_id":"ORC-VLOGX6GLGA.a4cb3d","paper":"doi:10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","rationale":"same printed cell (AFM BCC Cr Relax. line, LATTICE_A 285.48 pm): placeholder r8 is a second reading of phased r2; natural alias ORC-MYGV625N6C.e3f2e8 is EXCL, pair left unchanged; kept ORC-VLOGX6GLGA.a4cb3d is not worse (same value/T, real printed phase), so no flip","report_id":"ORCHID-Y10-20261027-v1","table_key":"t075"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"b6f86d68b726e8598dea76b5a86d46695d46dfa6ee8ef3cb326bc863706033f7","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"same printed cell (AFM BCC Cr Relax. line, LATTICE_A 285.48 pm): placeholder r8 is a second reading of phased r2; natural alias ORC-MYGV625N6C.e3f2e8 is EXCL, pair left unchanged; kept ORC-VLOGX6GLGA.a4cb3d is not worse (same value/T, real printed phase), so no flip","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-VLOGX6GLGA.a4cb3d","evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-MYGV625N6C.e3f2e8","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"AFM BCC Cr","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006281,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006281},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":2.8548,"value_stored":285.48},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"Cr2Cr (C36)","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C36 (header row \"Structure ... C36\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9],"table":"2","table_key":"t003"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C36 block","verdict":"confirmed"}},{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C36 (header row \"Structure ... C36\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C36 block","verdict":"confirmed"}},{"after":"ORC-TDZ65XBF4Y.cf35e6","before":null,"evidence":{"decision_file":"dup1_t003.json","kept_id":"ORC-TDZ65XBF4Y.cf35e6","paper":"doi:10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","rationale":"same printed cell: placeholder-row r9 LATTICE_C=15.2311 is a second reading of phased row r40 (Cr2Cr (C36)); natural alias ORC-JAJPUSNKB2.45aaf1 and kept ORC-TDZ65XBF4Y.cf35e6 are both EXCL (table-context batch), pair left unchanged","report_id":"ORCHID-Y10-20261027-v1","table_key":"t003"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"b6f86d68b726e8598dea76b5a86d46695d46dfa6ee8ef3cb326bc863706033f7","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"same printed cell: placeholder-row r9 LATTICE_C=15.2311 is a second reading of phased row r40 (Cr2Cr (C36)); natural alias ORC-JAJPUSNKB2.45aaf1 and kept ORC-TDZ65XBF4Y.cf35e6 are both EXCL (table-context batch), pair left unchanged","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-TDZ65XBF4Y.cf35e6","evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-JAJPUSNKB2.45aaf1","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":9},"merged_ids":["ORC-WGYSWMRD7R.4f6a7d"],"merged_pids":["sha256:f9ce77d73011da3e/p3/tab-2/r23#structural_property"],"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03351,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03351},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":15.2311,"value_stored":1523.11},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"Cr2Cr (C36)","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C36 (header row \"Structure ... C36\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9],"table":"2","table_key":"t003"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C36 block","verdict":"confirmed"}},{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C36 (header row \"Structure ... C36\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C36 block","verdict":"confirmed"}},{"after":"ORC-TDZ65XBF4Y.a66c86","before":null,"evidence":{"decision_file":"dup1_t003.json","kept_id":"ORC-TDZ65XBF4Y.a66c86","paper":"doi:10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","rationale":"same printed cell: placeholder-row r9 LATTICE_A=4.6511 is a second reading of phased row r40 (Cr2Cr (C36)); natural alias ORC-JAJPUSNKB2.fa4b0c and kept ORC-TDZ65XBF4Y.a66c86 are both EXCL (table-context batch), pair left unchanged","report_id":"ORCHID-Y10-20261027-v1","table_key":"t003"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"b6f86d68b726e8598dea76b5a86d46695d46dfa6ee8ef3cb326bc863706033f7","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"same printed cell: placeholder-row r9 LATTICE_A=4.6511 is a second reading of phased row r40 (Cr2Cr (C36)); natural alias ORC-JAJPUSNKB2.fa4b0c and kept ORC-TDZ65XBF4Y.a66c86 are both EXCL (table-context batch), pair left unchanged","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-TDZ65XBF4Y.a66c86","evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-JAJPUSNKB2.fa4b0c","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":9},"merged_ids":["ORC-WGYSWMRD7R.46f27b"],"merged_pids":["sha256:f9ce77d73011da3e/p3/tab-2/r23#structural_property"],"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01023,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01023},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.6511,"value_stored":465.11},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"Cr2Cr (C14)","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C14 (header row \"Structure ... C14\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"2","table_key":"t003"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C14 block","verdict":"confirmed"}},{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C14 (header row \"Structure ... C14\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C14 block","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-DAWXXE5NOW.308ac9","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":16},"merged_ids":["ORC-QC6Y3XS5XM.48ffaf"],"merged_pids":["sha256:f9ce77d73011da3e/p3/tab-2/r02#structural_property"],"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01686,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01686},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":7.6632,"value_stored":766.32},{"chemical_system":"CR-HF-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"Cr2Cr (C14)","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C14 (header row \"Structure ... C14\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"2","table_key":"t003"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C14 block","verdict":"confirmed"}},{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row label Cr2Cr under the printed structure column group C14 (header row \"Structure ... C14\")","rationale":"Printed table context for this group supplies phase, strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"second reading of the row (placeholder phase); values match the printed Cr2Cr row in the C14 block","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-DAWXXE5NOW.8b23dc","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":16},"merged_ids":["ORC-QC6Y3XS5XM.2a5e5a"],"merged_pids":["sha256:f9ce77d73011da3e/p3/tab-2/r02#structural_property"],"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)","label_source":"printed_source_page"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01021,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01021},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.6409,"value_stored":464.09},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C14","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[30],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C14 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-XAZKHH6FQZ.035c51","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":30},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_6H_X","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_6H_X","sigma_method":{"reason":"no method floor defined for property LATTICE_6H_X","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.8289},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C14","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[30],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C14 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-XAZKHH6FQZ.339dad","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":30},"merged_ids":["ORC-XAZKHH6FQZ.424e71"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07663,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07663},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":7.6632,"value_stored":766.32},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C14","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[30],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C14 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-XAZKHH6FQZ.395d5a","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":30},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_6H_Y","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_6H_Y","sigma_method":{"reason":"no method floor defined for property LATTICE_6H_Y","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.6578},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C14","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[30],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C14 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-XAZKHH6FQZ.47e017","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":30},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_4F_Z","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_4F_Z","sigma_method":{"reason":"no method floor defined for property LATTICE_4F_Z","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.0464},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C14","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[30],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C14 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-XAZKHH6FQZ.548db0","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":30},"merged_ids":["ORC-XAZKHH6FQZ.59eaaa"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V_ATOM","property_code_raw":"LATTICE_VAT","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03574,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":0.03574},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"10^7 pm^3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"10^7 pm^3","value":1.19117},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C14","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[30],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C14 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-XAZKHH6FQZ.e8d08a","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":30},"merged_ids":["ORC-XAZKHH6FQZ.fd358d"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C14)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C14)","strukturbericht":"C14"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04641,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04641},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.6409,"value_stored":464.09},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C15)","strukturbericht":"C15"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C15","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[31],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C15 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-UIXXP7FW7J.4a8c11","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":31},"merged_ids":["ORC-UIXXP7FW7J.89557e"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C15)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V_ATOM","property_code_raw":"LATTICE_VAT","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C15)","strukturbericht":"C15"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03562,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":0.03562},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"10^7 pm^3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"10^7 pm^3","value":1.18726},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C15)","strukturbericht":"C15"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C15","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[31],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C15 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-UIXXP7FW7J.996f75","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":31},"merged_ids":["ORC-UIXXP7FW7J.ea83ff"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C15)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C15)","strukturbericht":"C15"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0658,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0658},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.5804,"value_stored":658.04},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.02176a","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_4F_Z_2","property_code_raw":"LATTICE_4F_Z_2_","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_4F_Z_2","sigma_method":{"reason":"no method floor defined for property LATTICE_4F_Z_2","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.1236},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.066cd4","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_6H_X","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_6H_X","sigma_method":{"reason":"no method floor defined for property LATTICE_6H_X","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.1623},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.23295c","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_6H_Y","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_6H_Y","sigma_method":{"reason":"no method floor defined for property LATTICE_6H_Y","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.3247},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.2af452","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_4E_Z","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_4E_Z","sigma_method":{"reason":"no method floor defined for property LATTICE_4E_Z","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.1003},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.a66c86","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"merged_ids":["ORC-TDZ65XBF4Y.e58e5d"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04651,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04651},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.6511,"value_stored":465.11},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.cf35e6","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"merged_ids":["ORC-TDZ65XBF4Y.f9c3c9"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1523,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1523},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":15.2311,"value_stored":1523.11},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.d4484f","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"merged_ids":["ORC-TDZ65XBF4Y.fb0ad3"],"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V_ATOM","property_code_raw":"LATTICE_VAT","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03567,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":0.03567},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"10^7 pm^3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"10^7 pm^3","value":1.18893},{"chemical_system":"CR-HF-TI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2010.03.003","pdf_page":3,"pdf_sha256":"f9ce77d73011da3ec91d99b0692118fb9bdbe795a9138ce1c5718f2a6fb6d42f","printed":"Row Cr2Cr under the printed structure column group C36","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[40],"table":"2","table_key":"t003"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"f3bffd129d311fd00ba958e3c748e98adb12bc2e83a6c9da0cc32463d5af18f4","page":3,"pdf_sha256_prefix":"f9ce77d73011da3e","seen":"phase label already set; block header prints C36 for the group","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":1,"id":"ORC-TDZ65XBF4Y.deefae","locator":{"ref":"sha256:f9ce77d73011da3e/p3/tab-2","row":40},"method":"first-principles (this work)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.03.003","own_work_of_paper":true},"overall_composition":{"HF":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.03.003","paper_id":"doi:10.1016/j.calphad.2010.03.003","phases":[{"label":"Cr2Cr (C36)"}],"pid":"sha256:f9ce77d73011da3e/p3/tab-2/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_4F_Z_1","property_code_raw":"LATTICE_4F_Z_1_","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-HF-TI","structure":{"phase":"Cr2Cr (C36)","strukturbericht":"C36"},"system":"CR-HF-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property LATTICE_4F_Z_1","sigma_method":{"reason":"no method floor defined for property LATTICE_4F_Z_1","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.8485}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CR-HF-TI"}