{"artifacts":{"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii":{"artifact":"table","caption":"Values for enthalpy differences measured by Satoh31 on samples in the Cr-N and MO-N systems, listed together with values calculated in the present work. The calculated values are listed in italics. All values are given in J/mol of atoms.","label":"II","page":8}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CR","MO","N"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0364-5916(91)90028-i":{"authors":["Karin Frisk"],"citation":"Karin Frisk, A thermodynamic evaluation of the Cr-N, Fe-N, Mo-N and Cr-Mo-N systems, Calphad 15, 79-106 (1991).","container":"Calphad","doi":"10.1016/0364-5916(91)90028-i","doi_url":"https://doi.org/10.1016/0364-5916(91)90028-i","id":"doi:10.1016/0364-5916(91)90028-i","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"20c4aebfdd28e7fc","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"A thermodynamic evaluation of the Cr-N, Fe-N, Mo-N and Cr-Mo-N systems","year":1991}},"part":1,"parts":1,"records":[{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(373K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":373.0,"before":null,"evidence":{"printed":"Hm(373K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-ICCDUKY4GL","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-ICCDUKY4GL","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-ICCDUKY4GL; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2192 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-ICCDUKY4GL","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2192 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-ICCDUKY4GL (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-Q3RUUX4I4Y.7ac486","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(373K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":109.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2192.0,"value_printed":2192},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(784K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":784.0,"before":null,"evidence":{"printed":"Hm(784K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-CRS4IFQH3D","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-CRS4IFQH3D","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-CRS4IFQH3D; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13520 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-CRS4IFQH3D","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13520 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-CRS4IFQH3D (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-Q3RUUX4I4Y.9f0f3f","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(784K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":676.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13520.0,"value_printed":13520},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(599K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":599.0,"before":null,"evidence":{"printed":"Hm(599K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-X27FBJ7AZG","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-X27FBJ7AZG","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-X27FBJ7AZG; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8278 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-X27FBJ7AZG","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8278 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-X27FBJ7AZG (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-Q3RUUX4I4Y.ec2c0b","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(599K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":413.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8278.0,"value_printed":8278},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(599K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":599.0,"before":null,"evidence":{"printed":"Hm(599K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-ZYP6LBOQPV","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-ZYP6LBOQPV","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-ZYP6LBOQPV; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8086 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-ZYP6LBOQPV","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8086 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-ZYP6LBOQPV (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-6DOS2OUYR5.6c2f98","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":2},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(599K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":404.3},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8086.0,"value_printed":8086},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(373K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":373.0,"before":null,"evidence":{"printed":"Hm(373K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-S55VX4WYZ5","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-S55VX4WYZ5","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-S55VX4WYZ5; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2345 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-S55VX4WYZ5","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2345 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-S55VX4WYZ5 (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-6DOS2OUYR5.92f4d0","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":2},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(373K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":117.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2345.0,"value_printed":2345},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(784K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":784.0,"before":null,"evidence":{"printed":"Hm(784K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-FTHEJKDPKG","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-FTHEJKDPKG","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-FTHEJKDPKG; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13305 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-FTHEJKDPKG","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13305 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-FTHEJKDPKG (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-6DOS2OUYR5.bdb6f3","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":2},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(784K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":665.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13305.0,"value_printed":13305},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(373K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":373.0,"before":null,"evidence":{"printed":"Hm(373K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-BIUQAGQWQS","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-BIUQAGQWQS","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-BIUQAGQWQS; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2677 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-BIUQAGQWQS","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2677 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-BIUQAGQWQS (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-NGZSF32GU7.88cac8","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(373K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":133.85},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2677.0,"value_printed":2677},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(599K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":599.0,"before":null,"evidence":{"printed":"Hm(599K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-NXOTWJVEIH","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-NXOTWJVEIH","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-NXOTWJVEIH; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8157 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-NXOTWJVEIH","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8157 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-NXOTWJVEIH (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-NGZSF32GU7.d3db43","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(599K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":407.85},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8157.0,"value_printed":8157},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(784K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":784.0,"before":null,"evidence":{"printed":"Hm(784K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-YQIIHSSZPV","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-YQIIHSSZPV","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-YQIIHSSZPV; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13196 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-YQIIHSSZPV","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13196 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-YQIIHSSZPV (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-NGZSF32GU7.e1d87c","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(784K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":659.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13196.0,"value_printed":13196},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(599K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":599.0,"before":null,"evidence":{"printed":"Hm(599K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-2APFWHCORC","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-2APFWHCORC","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-2APFWHCORC; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 7927 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-2APFWHCORC","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 7927 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-2APFWHCORC (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-WC7EA7LMAJ.693a8e","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":4},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(599K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":396.35},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":7927.0,"value_printed":7927},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(373K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":373.0,"before":null,"evidence":{"printed":"Hm(373K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-IAAZTW3HDA","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-IAAZTW3HDA","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-IAAZTW3HDA; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2331 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-IAAZTW3HDA","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2331 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-IAAZTW3HDA (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-WC7EA7LMAJ.b2f035","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":4},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(373K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":116.55},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2331.0,"value_printed":2331},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(784K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":784.0,"before":null,"evidence":{"printed":"Hm(784K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-CWACYVQLA3","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-CWACYVQLA3","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-CWACYVQLA3; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 12740 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-CWACYVQLA3","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 12740 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-CWACYVQLA3 (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-WC7EA7LMAJ.e84a67","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":4},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(784K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":637.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":12740.0,"value_printed":12740},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(373K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":373.0,"before":null,"evidence":{"printed":"Hm(373K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-M3WOLWCZVY","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-M3WOLWCZVY","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-M3WOLWCZVY; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2723 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-M3WOLWCZVY","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2723 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-M3WOLWCZVY (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-MNP6QSZXME.0f5c02","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":5},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(373K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":136.15},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2723.0,"value_printed":2723},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(599K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":599.0,"before":null,"evidence":{"printed":"Hm(599K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-XCGTJJAWRR","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-XCGTJJAWRR","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-XCGTJJAWRR; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8301 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-XCGTJJAWRR","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 8301 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-XCGTJJAWRR (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-MNP6QSZXME.754840","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":5},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(599K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":415.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8301.0,"value_printed":8301},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(784K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":784.0,"before":null,"evidence":{"printed":"Hm(784K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-JN36LJPX2N","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-JN36LJPX2N","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-JN36LJPX2N; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13052 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-JN36LJPX2N","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 13052 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-JN36LJPX2N (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-MNP6QSZXME.fb60f9","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":5},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(784K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":652.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13052.0,"value_printed":13052},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(784K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":784.0,"before":null,"evidence":{"printed":"Hm(784K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-VUYOAIDE2O","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-VUYOAIDE2O","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-VUYOAIDE2O; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 12685 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-VUYOAIDE2O","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 12685 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-VUYOAIDE2O (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-S5TPZJEOOI.9edf09","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(784K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":634.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":12685.0,"value_printed":12685},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(373K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":373.0,"before":null,"evidence":{"printed":"Hm(373K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-6VYX5SX75H","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-6VYX5SX75H","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-6VYX5SX75H; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2334 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-6VYX5SX75H","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 2334 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-6VYX5SX75H (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-S5TPZJEOOI.a71fc7","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(373K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":116.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2334.0,"value_printed":2334},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(599K)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":599.0,"before":null,"evidence":{"printed":"Hm(599K)-Hm(273K)"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"after":"ORC-5UKV7SB5H5","before":null,"evidence":{"class":"composition","decision":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","decision_file":"composition_t032.json","doi":"10.1016/0364-5916(91)90028-i","kept_id":"ORC-5UKV7SB5H5","pdf_page":8,"pdf_sha256":"20c4aebfdd28e7fc43ff5989a0a23ed0db0e585876d8d49e45f651a6166fa773","printed":"","rationale":"Same printed cell as ORC-5UKV7SB5H5; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"II","table_key":"t032"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 7909 J/mol of atoms","verdict":"confirmed"}}],"duplicate_of":"ORC-5UKV7SB5H5","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Same printed cell; the per-cell record (rows 9-32) is kept: T basis printed, one record per cell; this row-group reading (T as quantity_label) is the alias.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"value 7909 J/mol of atoms","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-5UKV7SB5H5 (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"heat_content_base_temperature_K":273.0,"id":"ORC-S5TPZJEOOI.ab56f7","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(599K)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":395.45},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":7909.0,"value_printed":7909},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-ICCDUKY4GL","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":9},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"printed","temperature_printed":"T=373K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":109.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2192.0,"value_printed":2192.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-X27FBJ7AZG","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":10},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"printed","temperature_printed":"T=599K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":413.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8278.0,"value_printed":8278.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-CRS4IFQH3D","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":11},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"printed","temperature_printed":"T=784K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":676.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13520.0,"value_printed":13520.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-S55VX4WYZ5","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":12},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"printed","temperature_printed":"T=373K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":117.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2345.0,"value_printed":2345.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-ZYP6LBOQPV","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":13},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"printed","temperature_printed":"T=599K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":404.3},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8086.0,"value_printed":8086.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-FTHEJKDPKG","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":14},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"printed","temperature_printed":"T=784K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":665.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13305.0,"value_printed":13305.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-BIUQAGQWQS","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":15},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"printed","temperature_printed":"T=373K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":133.85},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2677.0,"value_printed":2677.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-NXOTWJVEIH","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":16},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"printed","temperature_printed":"T=599K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":407.85},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8157.0,"value_printed":8157.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-YQIIHSSZPV","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":17},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"printed","temperature_printed":"T=784K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":659.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13196.0,"value_printed":13196.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-IAAZTW3HDA","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":18},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"printed","temperature_printed":"T=373K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":116.55},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2331.0,"value_printed":2331.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-2APFWHCORC","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":19},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"printed","temperature_printed":"T=599K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":396.35},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":7927.0,"value_printed":7927.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-CWACYVQLA3","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":20},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"printed","temperature_printed":"T=784K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":637.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":12740.0,"value_printed":12740.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-M3WOLWCZVY","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":21},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"printed","temperature_printed":"T=373K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":136.15},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2723.0,"value_printed":2723.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-XCGTJJAWRR","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":22},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"printed","temperature_printed":"T=599K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":415.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":8301.0,"value_printed":8301.0},{"chemical_system":"CR-MO-N","cited_sources":[{"first_author":"Satoh","kind":"unknown","label":"31","reference":"S.Satoh, Sc.Pap.InstPhys.Chem.Res., 34 (819) (1938) 1001.","status":"resolved","year":"1938"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-JN36LJPX2N","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":23},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"printed","temperature_printed":"T=784K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":652.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":13052.0,"value_printed":13052.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-6VYX5SX75H","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":24},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":373.0,"temperature_basis":"printed","temperature_printed":"T=373K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":116.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":2334.0,"value_printed":2334.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-5UKV7SB5H5","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":25},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":599.0,"temperature_basis":"printed","temperature_printed":"T=599K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":395.45},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":7909.0,"value_printed":7909.0},{"chemical_system":"CR-MO-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"HEAT_CONTENT_FROM_BASE_T","before":"HEAT_CONTENT","evidence":{"base_temperature_K":273.0,"printed":"Hm(T)-Hm(273K)"},"field":"property","gate":"R3","rule":"heat_content_base_temperature","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["heat_content_base_not_298","composition_misread_on_page"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"heat_content_base_not_298","detail":"H(T) - H(273 K): the base temperature is not 298.15 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"515d6845ffcdf96dca4c04db57f619807b2406073a538c046a4fb3af91824c55","page":13,"pdf_sha256_prefix":"e6593a3a2358cb3e","seen":"Column header H_T - H_700 (J/g at.): base 700 K, not 298 K.","verdict":"rule_confirmed"}},{"code":"composition_misread_on_page","detail":"Samples printed as Cr-7.72%N, Cr-15.67%N, Cr-19.76%N in wt% (Cr-N system); stored {MO:0,N:0} in CR-MO-N is meaningless. Page gives wt% only; a mole-fraction value needs a conversion the page does not state.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (composition, t032)","image_sha256":"01d8d84d4498779bf6e563e7eac41bcaee87a15ab32b5f1cd1b9f4fa30c17c8f","page":8,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Composition(wt%) column: Cr-7.72%N / Cr-15.67%N / Cr-19.76%N","verdict":"confirmed"}}],"heat_content_base_temperature_K":273.0,"id":"ORC-VUYOAIDE2O","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii","row":26},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"MO":0.0,"N":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p8/tab-ii/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HEAT_CONTENT_FROM_BASE_T","property_code_before_gates":"HEAT_CONTENT","property_group":"heat capacity / entropy / enthalpy","property_printed":"Hm(T)-Hm(273K)","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CR-MO-N","system":"CR-MO-N","temperature_K":784.0,"temperature_basis":"printed","temperature_printed":"T=784K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":634.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","sigma_method":{"reason":"no method floor defined for property HEAT_CONTENT_FROM_BASE_T","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol of atoms","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol of atoms","unit_printed":"J/mol of atoms","value":12685.0,"value_printed":12685.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CR-MO-N"}