{"artifacts":{"doi:10.1016/0364-5916(91)90028-i/p6/tab-i":{"artifact":"table","caption":"Comparison between measured and calculated values for the heat of formation and the entropy of formation of the CrN phase, the E (Cr,N) phase and the MoN phase.","label":"I","page":6}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CR","N"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0364-5916(91)90028-i":{"authors":["Karin Frisk"],"citation":"Karin Frisk, A thermodynamic evaluation of the Cr-N, Fe-N, Mo-N and Cr-Mo-N systems, Calphad 15, 79-106 (1991).","container":"Calphad","doi":"10.1016/0364-5916(91)90028-i","doi_url":"https://doi.org/10.1016/0364-5916(91)90028-i","id":"doi:10.1016/0364-5916(91)90028-i","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"20c4aebfdd28e7fc","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"A thermodynamic evaluation of the Cr-N, Fe-N, Mo-N and Cr-Mo-N systems","year":1991}},"part":1,"parts":1,"records":[{"chemical_system":"CR-N","cited_sources":[{"first_author":"Chase","kind":"assessment","label":"66","reference":"M.W.Chase, C.A.Davies, J.R.Downey, DJ.Frurip, R.A.McDonald and A.N.Syvemd, JANAF Thermochemical Tables, 3rd ed., in J. Phys. Chem. Ref. Data, 14, suppl.1 (1985). 104 K. FRISK Appendix: List of parameters describing the thermodynamic propetties of the Cr-N, Mo-N, Fe-N and Cr-Mo-N systems. ‘lhe parameters evaluated in the present work are denoted with +. The superscript h in fmnt of the phase name i","status":"resolved","year":1985,"year_basis":"printed_parenthesised_year","year_read":"1811"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298 K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-N","before":"CR-MO-N","evidence":{"basis":"phase_formula","overall_composition":{"MO":0.0,"N":0.333333},"phases":["ε(Cr2N)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["unsigned_in_print"],"review_state":"extracted","system_is_state_subsystem":true,"unsigned_in_print":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"unsigned_in_print","detail":"minus sign absent in print","effect":"not_espei_ready","gate":"G3"}],"id":"ORC-E4DHBOCKS5","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i","row":5},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"N":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"MO":0.0,"N":0.333333},"paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"ε(Cr2N)"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Heat of Formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"reference_state_stored":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"MO":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"source_system":"CR-MO-N","system":"CR-N","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.09},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":41.8,"value_printed":41.8,"value_stored":41800.0},{"chemical_system":"CR-N","cited_sources":[{"first_author":"Chase","kind":"assessment","label":"66","reference":"M.W.Chase, C.A.Davies, J.R.Downey, DJ.Frurip, R.A.McDonald and A.N.Syvemd, JANAF Thermochemical Tables, 3rd ed., in J. Phys. Chem. Ref. Data, 14, suppl.1 (1985). 104 K. FRISK Appendix: List of parameters describing the thermodynamic propetties of the Cr-N, Mo-N, Fe-N and Cr-Mo-N systems. ‘lhe parameters evaluated in the present work are denoted with +. The superscript h in fmnt of the phase name i","status":"resolved","year":1985,"year_basis":"printed_parenthesised_year","year_read":"1811"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1173.0,"before":null,"evidence":{"printed":"1173K"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_not_stored","visual_check":{"checked":"2026-10-24","image_sha256":"3156734fb3bdea77b293312c911cb2bba59f6a7b7caacff186601073c42ca856","page":6,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Row temperature printed (CrN at 1173 K; SiP at melting 1443 K) but not stored.","verdict":"rule_confirmed"}},{"after":"CR-N","before":"CR-MO-N","evidence":{"basis":"phase_formula","overall_composition":{"MO":0.0,"N":0.5},"phases":["CrN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-UEW4XK4I2V","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"N":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"MO":0.0,"N":0.5},"paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"CrN","model_phase":"FCC_A1"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Heat of Formation","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"reference_state_stored":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"MO":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"source_system":"CR-MO-N","system":"CR-N","temperature_K":1173.0,"temperature_basis":"row_temperature_printed","temperature_printed":"1173K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.93},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-58.6,"value_printed":-58.6,"value_stored":-58600.0},{"chemical_system":"CR-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298 K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-N","before":"CR-MO-N","evidence":{"basis":"phase_formula","overall_composition":{"MO":0.0,"N":0.333333},"phases":["ε(Cr2N)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-X5DNFQO4Z2","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i","row":7},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"N":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"MO":0.0,"N":0.333333},"paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"ε(Cr2N)"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Heat of Formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"reference_state_stored":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"MO":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"source_system":"CR-MO-N","system":"CR-N","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.155},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-43.1,"value_printed":-43.1,"value_stored":-43100.0},{"chemical_system":"CR-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":1173.0,"before":null,"evidence":{"printed":"1173K"},"field":"temperature_K","gate":"R3","rule":"temperature_printed_not_stored","visual_check":{"checked":"2026-10-24","image_sha256":"3156734fb3bdea77b293312c911cb2bba59f6a7b7caacff186601073c42ca856","page":6,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Row temperature printed (CrN at 1173 K; SiP at melting 1443 K) but not stored.","verdict":"rule_confirmed"}},{"after":"CR-N","before":"CR-MO-N","evidence":{"basis":"phase_formula","overall_composition":{"MO":0.0,"N":0.5},"phases":["CrN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-JPD7Y6YZHI","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i","row":8},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"N":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"MO":0.0,"N":0.5},"paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"CrN","model_phase":"FCC_A1"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Heat of Formation","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"reference_state_stored":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"MO":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"source_system":"CR-MO-N","system":"CR-N","temperature_K":1173.0,"temperature_basis":"row_temperature_printed","temperature_printed":"1173K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.865},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-57.3,"value_printed":-57.3,"value_stored":-57300.0},{"chemical_system":"CR-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-N","before":"CR-MO-N","evidence":{"basis":"phase_formula","overall_composition":{"MO":0.0,"N":0.333333},"phases":["ε(Cr2N)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-XOXS4E4OI6","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i","row":10},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"N":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"MO":0.0,"N":0.333333},"paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"ε(Cr2N)"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Entropy of Formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"reference_state_stored":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"MO":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"source_system":"CR-MO-N","system":"CR-N","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.285},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol of atoms","value":-25.7,"value_printed":-25.7},{"chemical_system":"CR-N","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-N","before":"CR-MO-N","evidence":{"basis":"phase_formula","overall_composition":{"MO":0.0,"N":0.5},"phases":["CrN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-LLLEMUND23","locator":{"ref":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i","row":11},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90028-i","own_work_of_paper":true},"overall_composition":{"N":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"MO":0.0,"N":0.5},"paper":"doi:10.1016/0364-5916(91)90028-i","paper_id":"doi:10.1016/0364-5916(91)90028-i","phases":[{"label":"CrN","model_phase":"FCC_A1"}],"pid":"doi:10.1016/0364-5916(91)90028-i/p6/tab-i/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Entropy of Formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"reference_state_stored":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"MO":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"N":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_N2(G)","phase_before_quality_fix":"1"}},"source_system":"CR-MO-N","system":"CR-N","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.13},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol of atoms","value":-42.6,"value_printed":-42.6}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CR-N"}