{"artifacts":{"doi:10.1016/j.calphad.2015.12.007/p36/tab-2":{"artifact":"table","caption":"Calculated DFT elastic stiffness constants and various properties of the end-members of B2 and γ’ compared to experimental data and calculations available in the literature. Stable end- members CoAl, NiAl, and Ni 3 Al are bolded while mechanically unstable CoNi and Cr 3 Al are italicized.","label":"2","page":36},"doi:10.1016/j.calphad.2015.12.007/p38/tab-4":{"artifact":"table","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Experiments and calculations at various temperatures, including 298 K, are included for comparison; experimental temperature information is given in the second column when available. Mechanically unstable end-members have 0 K enthalpies of formation shown in italics. Asterisks denote data from","label":"4","page":38},"doi:10.1016/j.calphad.2015.12.007/p40/tab-6":{"artifact":"table","caption":"Calculated enthalpies of mixing for A2 from DFT. The results are based on binary and ternary SQS calculations at 0 K with reference states taken as bcc-A2 for Al, Co, and Cr, and Ni.","label":"6","page":40},"doi:10.1016/j.calphad.2015.12.007/p41/tab-7":{"artifact":"table","caption":"Calculated enthalpies of mixing for γ from DFT. These calculations are based on binary and ternary SQS calculations at 0 K with references taken as fcc-γ for Al, Co, and Cr, and Ni. γ' end-members with the same reference states are also shown. Energies for mechanically unstable ordered structures are shown in italics.","label":"7","page":41},"doi:10.1016/j.calphad.2015.12.007/p42/tab-8":{"artifact":"table","caption":"Calculated enthalpies of mixing for B2 from DFT. The results are based on ternary SQS calculations at 0 K with reference states taken as bcc-A2 for Al, Co, and Cr, and Ni. Energies for mechanically unstable binary ordered structures are shown in italics. Values for Al-Co, Al-Cr, Co-Cr, and Al-Co-Cr and adapted from previous work [5] and are indicated with an asterisk *.","label":"8","page":42},"doi:10.1016/j.calphad.2015.12.007/p43/tab-9":{"artifact":"table","caption":"Calculated enthalpies of mixing for γ’ from DFT. The results are based on ternary SQS calculations at 0 K with reference states taken as fcc-γ for Al, Co, and Cr, and Ni. Energies for mechanically unstable binary ordered structures are shown in italics.","label":"9","page":43},"doi:10.1016/j.calphad.2021.102268/p10/text-01":{"artifact":"text_passage","label":"page 10, passage 1","page":10},"doi:10.1016/j.calphad.2021.102268/p11/text-01":{"artifact":"text_passage","label":"page 11, passage 1","page":11},"doi:10.1016/j.calphad.2021.102268/p12/text-01":{"artifact":"text_passage","label":"page 12, passage 1","page":12},"doi:10.1016/j.calphad.2021.102268/p13/text-01":{"artifact":"text_passage","label":"page 13, passage 1","page":13},"doi:10.1016/j.calphad.2021.102268/p16/text-01":{"artifact":"text_passage","label":"page 16, passage 1","page":16},"doi:10.1016/j.calphad.2021.102268/p18/text-01":{"artifact":"text_passage","label":"page 18, passage 1","page":18},"doi:10.1016/j.calphad.2021.102268/p8/text-02":{"artifact":"text_passage","label":"page 8, passage 2","page":8},"doi:10.1016/s0364-5916(01)00049-9/p10/tab-2":{"artifact":"table","caption":"Calculated Invariant Reaction in the Sub-System A1Ni-Cr-Ni.","label":"2","page":10},"sha256:0415723946a6e106/p4/tab-1":{"artifact":"table","caption":"Heat of mixing D mix H SQS , for binary to quinary systems at the equiatomic composition, using non-collinear spin polarization NCSP SQS-DFT calculations","label":"1","page":4}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CR","NI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s11669-021-00922-9":{"authors":["Guillaume Bracq","Jean-Claude Crivello","Mathilde Laurent-Brocq","Jean-Marc Joubert","Ivan Guillot"],"citation":"Guillaume Bracq, Jean-Claude Crivello, Mathilde Laurent-Brocq, Jean-Marc Joubert, Ivan Guillot, What is the Enthalpy Contribution to the Stabilization of the Co–Cr–Fe–Mn–Ni Faced-centered Cubic Solid Solution?, J. Phase Equilib. Diffus. 42, 561-570 (2021).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-021-00922-9","doi_url":"https://doi.org/10.1007/s11669-021-00922-9","id":"doi:10.1007/s11669-021-00922-9","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"0415723946a6e106","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"What is the Enthalpy Contribution to the Stabilization of the Co–Cr–Fe–Mn–Ni Faced-centered Cubic Solid Solution?","year":2021},"doi:10.1016/0364-5916(82)90018-9":{"authors":["Staffan Hertzman","Bo Sundman"],"citation":"Staffan Hertzman, Bo Sundman, A thermodynamic analysis of the fe-cr system, Calphad 6, 67-80 (1982).","container":"Calphad","doi":"10.1016/0364-5916(82)90018-9","doi_url":"https://doi.org/10.1016/0364-5916(82)90018-9","id":"doi:10.1016/0364-5916(82)90018-9","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"109b8bb6914c4784","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"A thermodynamic analysis of the fe-cr system","year":1982},"doi:10.1016/0364-5916(91)90030-n":{"authors":["A.T. Dinsdale"],"citation":"A.T. Dinsdale, SGTE data for pure elements, Calphad 15, 317-425 (1991).","container":"Calphad","doi":"10.1016/0364-5916(91)90030-n","doi_url":"https://doi.org/10.1016/0364-5916(91)90030-n","id":"doi:10.1016/0364-5916(91)90030-n","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"SGTE data for pure elements","year":1991},"doi:10.1016/j.calphad.2015.12.007":{"authors":["Xuan L. Liu","Greta Lindwall","Thomas Gheno","Zi-Kui Liu"],"citation":"Xuan L. Liu, Greta Lindwall, Thomas Gheno, Zi-Kui Liu, Thermodynamic modeling of Al–Co–Cr, Al–Co–Ni, Co–Cr–Ni ternary systems towards a description for Al–Co–Cr–Ni, Calphad 52, 125-142 (2016).","container":"Calphad","doi":"10.1016/j.calphad.2015.12.007","doi_url":"https://doi.org/10.1016/j.calphad.2015.12.007","id":"doi:10.1016/j.calphad.2015.12.007","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"f987d95279d67c64","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of Al–Co–Cr, Al–Co–Ni, Co–Cr–Ni ternary systems towards a description for Al–Co–Cr–Ni","year":2016},"doi:10.1016/j.calphad.2021.102268":{"authors":["Liangyan Hao","Andrei Ruban","Wei Xiong"],"citation":"Liangyan Hao, Andrei Ruban, Wei Xiong, CALPHAD modeling based on Gibbs energy functions from zero kevin and improved magnetic model: A case study on the Cr–Ni system, Calphad 73, 102268 (2021).","container":"Calphad","doi":"10.1016/j.calphad.2021.102268","doi_url":"https://doi.org/10.1016/j.calphad.2021.102268","id":"doi:10.1016/j.calphad.2021.102268","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"fa1f9d709d911f4a","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"CALPHAD modeling based on Gibbs energy functions from zero kevin and improved magnetic model: A case study on the Cr–Ni system","year":2021},"doi:10.1016/s0364-5916(01)00049-9":{"authors":["N. Dupin","I. Ansara","B. Sundman"],"citation":"N. Dupin, I. Ansara, B. Sundman, Thermodynamic re-assessment of the ternary system Al-Cr-Ni, Calphad 25, 279-298 (2001).","container":"Calphad","doi":"10.1016/s0364-5916(01)00049-9","doi_url":"https://doi.org/10.1016/s0364-5916(01)00049-9","id":"doi:10.1016/s0364-5916(01)00049-9","kind":"cited_work","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work"],"title":"Thermodynamic re-assessment of the ternary system Al-Cr-Ni","year":2001},"doi:10.1098/rspa.1963.0045":{"authors":["J. Crangle","G. C. Hallam"],"citation":"J. Crangle, G. C. Hallam, The magnetization of face-centred cubic and body-centred cubic iron + nickel alloys, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences 272, 119-132 (1963).","container":"Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences","doi":"10.1098/rspa.1963.0045","doi_url":"https://doi.org/10.1098/rspa.1963.0045","id":"doi:10.1098/rspa.1963.0045","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The magnetization of face-centred cubic and body-centred cubic iron + nickel alloys","year":1963}},"part":1,"parts":1,"records":[{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.5,"NI":0.5},"phases":["B2 CrNi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-IKVOK7HGUY","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p36/tab-2","row":15},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"B2 CrNi"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p36/tab-2/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"V0","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.60875},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.3653,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":0.3653},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å3/atom","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3/atom","unit_basis":"column_header","unit_printed":"Å3/atom","value":12.175,"value_printed":12.175},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.75,"NI":0.25},"phases":["γ'-L12 Cr3Ni"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-D4NDOFFZFN","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p36/tab-2","row":33},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12 Cr3Ni"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p36/tab-2/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"V0","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.572},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.3432,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":0.3432},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å3/atom","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3/atom","unit_basis":"column_header","unit_printed":"Å3/atom","value":11.44,"value_printed":11.44},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.25,"NI":0.75},"phases":["γ'-L12 Ni3Cr"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZEG2HDHCIO","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p36/tab-2","row":34},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12 Ni3Cr"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p36/tab-2/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"V0","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.56305},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.3378,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":0.3378},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å3/atom","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3/atom","unit_basis":"column_header","unit_printed":"Å3/atom","value":11.261,"value_printed":11.261},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfG298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.5,"NI":0.5},"phases":["B2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JE3KL3TAG6.643118","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":11},"merged_ids":["ORC-JE3KL3TAG6.669aba"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"B2","label_variants":["CrNi (B2)"],"model_phase":"BCC_B2"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔfG298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.12485},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/GM_FORM","floor":7.2,"floor_unit":"kJ/mol-atom","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":22.497,"value_printed":22.497,"value_stored":22497.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfS298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.5,"NI":0.5},"phases":["B2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JE3KL3TAG6.66aaf4","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":11},"merged_ids":["ORC-JE3KL3TAG6.cacb37"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"B2","label_variants":["CrNi (B2)"],"model_phase":"BCC_B2"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.29625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/SM_FORM","floor":1.0,"floor_unit":"J/K/mol-atom","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"column_header","unit_printed":"J/mol-atom/K","value":5.925,"value_printed":5.925},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfH298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.5,"NI":0.5},"phases":["B2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JE3KL3TAG6.6e3c2e","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":11},"merged_ids":["ORC-JE3KL3TAG6.b6f501"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"B2","label_variants":["CrNi (B2)"],"model_phase":"BCC_B2"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.2131},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":24.262,"value_printed":24.262,"value_stored":24262.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfS298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.75,"NI":0.25},"phases":["γ'-L12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CYR5RW36IJ.0c4c49","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":31},"merged_ids":["ORC-CYR5RW36IJ.5c8bc3"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12","label_variants":["Cr3Ni (γ'-L12)"],"model_phase":"L12_FCC"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.11455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/SM_FORM","floor":1.0,"floor_unit":"J/K/mol-atom","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"column_header","unit_printed":"J/mol-atom/K","value":2.291,"value_printed":2.291},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfG298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.75,"NI":0.25},"phases":["γ'-L12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CYR5RW36IJ.88127f","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":31},"merged_ids":["ORC-CYR5RW36IJ.b8f373"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12","label_variants":["Cr3Ni (γ'-L12)"],"model_phase":"L12_FCC"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔfG298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.68045},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/GM_FORM","floor":7.2,"floor_unit":"kJ/mol-atom","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":13.609,"value_printed":13.609,"value_stored":13609.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfH298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.75,"NI":0.25},"phases":["γ'-L12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CYR5RW36IJ.b01bef","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":31},"merged_ids":["ORC-CYR5RW36IJ.ea077f"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12","label_variants":["Cr3Ni (γ'-L12)"],"model_phase":"L12_FCC"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.71455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":14.291,"value_printed":14.291,"value_stored":14291.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfH298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.25,"NI":0.75},"phases":["γ'-L12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-IZ6H4R6V52.352a19","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":32},"merged_ids":["ORC-IZ6H4R6V52.d41b92"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12","label_variants":["Ni3Cr (γ'-L12)"],"model_phase":"L12_FCC"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.03595},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-0.719,"value_printed":-0.719,"value_stored":-719.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfG298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.25,"NI":0.75},"phases":["γ'-L12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-IZ6H4R6V52.4d97a4","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":32},"merged_ids":["ORC-IZ6H4R6V52.30a22f"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12","label_variants":["Ni3Cr (γ'-L12)"],"model_phase":"L12_FCC"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔfG298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0133},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/GM_FORM","floor":7.2,"floor_unit":"kJ/mol-atom","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-0.266,"value_printed":-0.266,"value_stored":-266.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"dft","before":"model","evidence":{"basis":"caption_names_only_a_first_principles_calculation","caption":"Calculated enthalpies, entropies and Gibbs energies of formation of B2 and γ’ end- members at 298 K with respect to the standard reference states from DFT. Expe","method":null,"printed":"ΔfS298"},"field":"evidence_class","gate":"R3","rule":"first_principles_value_coded_model","visual_check":{"checked":"2026-10-24","image_sha256":"c66d3ced425424a13bc0862f9fb97ee82629025c30d50ee101ec71677a232969","page":6,"pdf_sha256_prefix":"fa9c11d530e12e09","seen":"First-principles values stored as model: ErBi2 (VASP PAW GGA-PBE, section 3), Cr-Zr Laves a (relaxed, this work), SiSr GGA [17], Ti3Be ab initio (FLAPW-GGA WIEN2k), UAl3 Wien2k.","verdict":"rule_confirmed"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"CO":0.0,"CR":0.25,"NI":0.75},"phases":["γ'-L12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-IZ6H4R6V52.890469","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4","row":32},"merged_ids":["ORC-IZ6H4R6V52.1d6626"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","class_gate":"dft","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"CO":0.0,"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'-L12","label_variants":["Ni3Cr (γ'-L12)"],"model_phase":"L12_FCC"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p38/tab-4/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"},"CO":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"CR":{"fixed_state_variables":{"T":298.15},"phase":"BCC_A2"},"NI":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.076},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/SM_FORM","floor":1.0,"floor_unit":"J/K/mol-atom","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"column_header","unit_printed":"J/mol-atom/K","value":-1.52,"value_printed":-1.52},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.75,"NI":0.25},"phases":["A2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ECXY5ARLCL","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6","row":16},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"A2"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"reference_state_stored":{"AL":{"phase":"BCC_A2"},"CO":{"phase":"BCC_A2"},"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.501},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":10.02,"value_printed":10.02,"value_stored":10020.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.5,"NI":0.5},"phases":["A2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-4AVGOLDRYY.862ddc","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6","row":17},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"A2"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"reference_state_stored":{"AL":{"phase":"BCC_A2"},"CO":{"phase":"BCC_A2"},"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4575},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":9.15,"value_printed":9.15,"value_stored":9150.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.5,"NI":0.5},"phases":["B2-β"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'B2-β'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-4AVGOLDRYY.d5c876","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6","row":17},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"B2-β"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH B2-β","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"reference_state_stored":{"AL":{"phase":"BCC_A2"},"CO":{"phase":"BCC_A2"},"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.006},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":20.12,"value_printed":20.12,"value_stored":20120.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.25,"NI":0.75},"phases":["A2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-NNQH4SF765","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6","row":18},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"A2"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p40/tab-6/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"reference_state_stored":{"AL":{"phase":"BCC_A2"},"CO":{"phase":"BCC_A2"},"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.249},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":4.98,"value_printed":4.98,"value_stored":4980.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.75,"NI":0.25},"phases":["γ'"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) L12-γ’","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-BJCC23KTCK.568105","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7","row":16},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH L12-γ'","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.694},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-13.88,"value_printed":-13.88,"value_stored":-13880.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.75,"NI":0.25},"phases":["γ"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'γ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BJCC23KTCK.7c92d8","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7","row":16},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.6345},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-12.69,"value_printed":-12.69,"value_stored":-12690.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.75,"NI":0.25},"phases":["L12-γ’"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) γ'","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-BJCC23KTCK.cb1de8","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7","row":16},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"L12-γ’"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH L12-γ’","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.694},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-13.88,"value_printed":-13.88,"value_stored":-13880.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.5,"NI":0.5},"phases":["γ"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'γ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-XYCE5GPHM6","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7","row":17},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4515},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-9.03,"value_printed":-9.03,"value_stored":-9030.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.25,"NI":0.75},"phases":["γ"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'γ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CG6B7EHP2R.127230","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7","row":18},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.2895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-5.79,"value_printed":-5.79,"value_stored":-5790.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.25,"NI":0.75},"phases":["L12-γ’"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) γ'","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-CG6B7EHP2R.be88a2","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7","row":18},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"L12-γ’"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH L12-γ’","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.5015},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-10.03,"value_printed":-10.03,"value_stored":-10030.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.25,"NI":0.75},"phases":["γ'"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) L12-γ’","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-CG6B7EHP2R.d87371","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7","row":18},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ'"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p41/tab-7/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH L12-γ'","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.5015},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-10.03,"value_printed":-10.03,"value_stored":-10030.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.5,"NI":0.5},"phases":["B2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-326E3OHRXX","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p42/tab-8","row":25},"merged_ids":["ORC-UCJDYNGNJV"],"merged_pids":["doi:10.1016/j.calphad.2015.12.007/p42/tab-8/r24#equilibrium_property"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"B2"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p42/tab-8/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"reference_state_stored":{"AL":{"phase":"BCC_A2"},"CO":{"phase":"BCC_A2"},"CR":{"phase":"BCC_A2"},"NI":{"phase":"BCC_A2"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.006},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":20.12,"value_printed":20.12,"value_stored":20120.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.25,"NI":0.75},"phases":["γ’"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'γ’'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-7BZ4YFYJFR","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p43/tab-9","row":22},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.25,"NI":0.75},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ’"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p43/tab-9/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.5015},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-10.03,"value_printed":-10.03,"value_stored":-10030.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"AL-CO-CR-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.75,"NI":0.25},"phases":["γ’"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'γ’'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BSYOVSRLCW","locator":{"ref":"doi:10.1016/j.calphad.2015.12.007/p43/tab-9","row":27},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2015.12.007","own_work_of_paper":true},"overall_composition":{"CR":0.75,"NI":0.25},"paper":"doi:10.1016/j.calphad.2015.12.007","paper_id":"doi:10.1016/j.calphad.2015.12.007","phases":[{"label":"γ’"}],"pid":"doi:10.1016/j.calphad.2015.12.007/p43/tab-9/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔHmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"AL":{"phase":"FCC_A1"},"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"AL-CO-CR-NI","system":"CR-NI","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.694},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-13.88,"value_printed":-13.88,"value_stored":-13880.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CR-NI","before":"CO-CR-FE-MN-NI","evidence":{"basis":"printed_overall_composition","overall_composition":{"CR":0.5,"NI":0.5},"phases":["fcc"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-NYY5VGMVQQ.0cb658","locator":{"ref":"sha256:0415723946a6e106/p4/tab-1","row":7},"merged_ids":["ORC-NYY5VGMVQQ.32cd15"],"method":"NCSP SQS-DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-021-00922-9","own_work_of_paper":true},"overall_composition":{"CR":0.5,"NI":0.5},"paper":"doi:10.1007/s11669-021-00922-9","paper_id":"doi:10.1007/s11669-021-00922-9","phases":[{"label":"fcc"}],"pid":"sha256:0415723946a6e106/p4/tab-1/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔmixH^SQS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CR":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"reference_state_stored":{"CO":{"phase":"FCC_A1"},"CR":{"phase":"FCC_A1"},"FE":{"phase":"FCC_A1"},"MN":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"}},"source_system":"CO-CR-FE-MN-NI","system":"CR-NI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.48595},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.2,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/H_MIX_PARTIAL","floor":7.2,"floor_unit":"kJ/mol","value":7.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J/mol-at","unit_stored":"J/mol-atom","value":-9.719,"value_printed":-9719,"value_stored":-9719.0},{"chemical_system":"CR-NI","cited_sources":[{"kind":"unknown","label":"52Tay","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-EFWCMI7JUR","locator":{"ref":"doi:10.1016/s0364-5916(01)00049-9/p10/tab-2","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(01)00049-9","paper_id":"doi:10.1016/s0364-5916(01)00049-9","phases":[{"label":"liq.","model_phase":"LIQUID"},{"label":"γ'","model_phase":"L12_FCC","pearson_symbol":"cP4","prototype":"AuCu3","structure_basis":"mapped_model_phase"},{"label":"β","model_phase":"B2_BCC","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(01)00049-9/p10/tab-2/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq. + γ' -> γ + β"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-NI","system":"CR-NI","temperature_K":1613.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1613.0},{"chemical_system":"CR-NI","cited_sources":[{"kind":"unknown","label":"52Tay","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-NDH2VKFXKW","locator":{"ref":"doi:10.1016/s0364-5916(01)00049-9/p10/tab-2","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(01)00049-9","paper_id":"doi:10.1016/s0364-5916(01)00049-9","phases":[{"label":"γ","model_phase":"L12_FCC","pearson_symbol":"cP4","prototype":"AuCu3","structure_basis":"mapped_model_phase"},{"label":"β","model_phase":"B2_BCC","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"α"}],"pid":"doi:10.1016/s0364-5916(01)00049-9/p10/tab-2/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γ + β -> γ' + α"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-NI","system":"CR-NI","temperature_K":1273.0,"temperature_printed":"1273 K","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1273.0},{"chemical_system":"CR-NI","cited_sources":[{"kind":"unknown","label":"82Tu","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-4VTB4FD2XH","locator":{"ref":"doi:10.1016/s0364-5916(01)00049-9/p10/tab-2","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(01)00049-9","paper_id":"doi:10.1016/s0364-5916(01)00049-9","phases":[{"label":"γ","model_phase":"L12_FCC","pearson_symbol":"cP4","prototype":"AuCu3","structure_basis":"mapped_model_phase"},{"label":"β","model_phase":"B2_BCC","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"α"}],"pid":"doi:10.1016/s0364-5916(01)00049-9/p10/tab-2/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γ + β -> γ' + α"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CR-NI","system":"CR-NI","temperature_K":1263.0,"temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1263.0},{"chemical_system":"CR-NI","citations_printed":["97"],"cited_sources":[{"first_author":"Umino","kind":"unknown","label":"97","reference":"S. Umino, On the latent heat of fusion of several metals and their specific heats at high temperatures, Sci. Rep. Tôhuku Univ. 15 (1926) 597–617.","status":"resolved","year":"1926"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-NBHY3W7ARD","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p10/text-01"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","pid":"doi:10.1016/j.calphad.2021.102268/p10/text-01/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The heat capacity data above 1873 K in the study of Umino [97] are less reliable since the purity of the sample is low (95.39 wt.%), and the melting point of bcc Cr is highly underestimated (1873 K).","quote_page":10,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":1873.0,"temperature_printed":"1873 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1873.0},{"chemical_system":"CR-NI","citations_printed":["9"],"cited_sources":[{"doi":"10.1016/0364-5916(91)90030-n","first_author":"Dinsdale","kind":"assessment","label":"9","paper":"doi:10.1016/0364-5916(91)90030-n","reference":"A.T. Dinsdale, SGTE data for pure elements, Calphad. 15 (1991) 317–425. https://doi.org/10.1016/0364-5916(91)90030-N.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-IWJQKFRNDH","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p10/text-01"},"observation_type":"equilibrium_property","origin":{"class":"model_value","measured_in":"doi:10.1016/0364-5916(91)90030-n","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","pid":"doi:10.1016/j.calphad.2021.102268/p10/text-01/s13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"OTHER","property_group":"other property","property_printed":"magnetic moment","quote":"According to the SGTE database [9], fcc Cr is antiferromagnetic with a Néel temperature of 367 K and a magnetic moment of 0.82 μB.","quote_page":10,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":367.0,"temperature_printed":"367 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":0.082},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property OTHER","sigma_method":{"reason":"no method floor defined for property OTHER","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"unspecified","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"unspecified","value":0.82},{"chemical_system":"CR-NI","citations_printed":["114"],"cited_sources":[{"doi":"10.1098/rspa.1963.0045","first_author":"Crangle","kind":"unknown","label":"114","paper":"doi:10.1098/rspa.1963.0045","reference":"J. Crangle, G.C. Hallam, The magnetization of face-centred cubic and body-centred cubic iron + nickel alloys, Proc. R. Soc. Lond. A. 272 (1963) 119–132. https://doi.org/10.1098/rspa.1963.0045.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-XJ6BSXJZ4T","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p11/text-01"},"method":"magnetization vs. T curve","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"fcc"}],"pid":"doi:10.1016/j.calphad.2021.102268/p11/text-01/s10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"From the magnetization vs. T curve, Crangle and Hallam [114] extrapolated the Curie temperature of fcc Ni as 633 K.","quote_page":11,"reaction":{"type":"magnetic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":633.0,"temperature_printed":"633 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"magnetic","transition_kind_printed":"magnetic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/T_TRANSITION/classes/experimental_unspecified","floor":10.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":633.0},{"chemical_system":"CR-NI","citations_printed":["151"],"cited_sources":[{"first_author":"Chan","kind":"assessment","label":"151","reference":"K.S. Chan, Y.M. Pan, Y. Der Lee, Computation of Ni-Cr phase diagram via a combined first-priciples quantum mechanical and CALPHAD approach, Metall. Mater. Trans. A Phys. Metall. Mater. Sci. 37 (2006) 2039–2050. https://doi.org/10.1007/BF02586124.","status":"resolved","year":2006,"year_basis":"printed_parenthesised_year","year_read":"2039"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-FWFLDARLZM.cef5da","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p12/text-01"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"CrNi2"}],"pid":"doi:10.1016/j.calphad.2021.102268/p12/text-01/s20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"However, the predicted formation temperatures of the CrNi2 phase (807 K and 820 K in the work [150] and [151], respectively) are inconsistent due to the difference in the calculated formation energy.","quote_page":12,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":820.0,"temperature_printed":"820 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":820.0},{"chemical_system":"CR-NI","citations_printed":["150"],"cited_sources":[{"first_author":"Turchi","kind":"assessment","label":"150","reference":"P.E.A. Turchi, L. Kaufman, Z.K. Liu, Modeling of Ni-Cr-Mo based alloys: Part I-phase stability, Calphad. 30 (2006) 70–87. https://doi.org/10.1016/j.calphad.2005.10.003.","status":"resolved","year":2006,"year_basis":"printed_parenthesised_year","year_read":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-FWFLDARLZM.fbcce2","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p12/text-01"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"CrNi2"}],"pid":"doi:10.1016/j.calphad.2021.102268/p12/text-01/s20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"However, the predicted formation temperatures of the CrNi2 phase (807 K and 820 K in the work [150] and [151], respectively) are inconsistent due to the difference in the calculated formation energy.","quote_page":12,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":807.0,"temperature_printed":"807 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":807.0},{"chemical_system":"CR-NI","citations_printed":["156"],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-AJ4EQOMP2O","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p13/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102268","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"CrNi2"}],"pid":"doi:10.1016/j.calphad.2021.102268/p13/text-01/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The predicted peritectic temperature (611 K) is in accordance with that evaluated by Nash [156].","quote_page":13,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":611.0,"temperature_printed":"611 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":611.0},{"chemical_system":"CR-NI","citations_printed":["157"],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-J5GDEOEL6S","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p13/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102268","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","pid":"doi:10.1016/j.calphad.2021.102268/p13/text-01/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Meanwhile, because of the magnetic transition, a Nishizawa horn [157] appears at 257 K in Fig. 12.","quote_page":13,"reaction":{"type":"magnetic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":257.0,"temperature_printed":"257 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"magnetic","transition_kind_printed":"magnetic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":257.0},{"chemical_system":"CR-NI","citations_printed":["158","159","12"],"cited_sources":[{"first_author":"Jenkins","kind":"unknown","label":"158","reference":"C.H.M. Jenkins, E.H. Bucknall, C.R. Austin, G.A. Mellor, Some alloys for use at high temperatures IV: The constitution of the alloys of nickel, chromium and iron, J. Iron Steel Inst. 136 (1937) 187–220.","status":"resolved","year":"1937"},{"first_author":"Svechnikov","kind":"unknown","label":"159","reference":"V.N. Svechnikov, V.M. Pan, Characteristics of the equilibrium diagram and processes of solution and precipitation in the Cr− Ni system, Sb. Nauchn. Rab. Inst. Met. Akad. Nauk. Ukr. SSR. 15 (1962) 164–178.","status":"resolved","year":"1962"},{"doi":"10.1016/0364-5916(82)90018-9","first_author":"Hertzman","kind":"assessment","label":"12","paper":"doi:10.1016/0364-5916(82)90018-9","reference":"S. Hertzman, B. Sundman, A thermodynamic analysis of the Fe-Cr system, Calphad. 6 (1982) 67–80. https://doi.org/10.1016/0364-5916(82)90018-9.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-SV7H3CNRYS","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p13/text-01"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"liquid"},{"label":"bcc"},{"label":"fcc"}],"pid":"doi:10.1016/j.calphad.2021.102268/p13/text-01/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"From Fig. 12, it is obvious that the Cr-Ni phase diagram is characterized by a eutectic reaction that occurs at 1618 K [158,159]. The equilibrium composition for the liquid, bcc, and fcc phases are 0.46, 0.38, and 0.50 at.% Ni, respectively [12].","quote_page":13,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":1618.0,"temperature_printed":"1618 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1618.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-42HR6B6LUU.0028e2","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p16/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102268","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"liquid"}],"pid":"doi:10.1016/j.calphad.2021.102268/p16/text-01/s10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"From the calculated lattice stabilities of Cr by the second-generation and third-generation databases, as shown in Fig. 3, it can be observed that the melting point of Cr is changed from 2180 K to 2136 K in this work, based on the reason mentioned in Section 4.1.1.","quote_page":16,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":2136.0,"temperature_printed":"2136 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2136.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-42HR6B6LUU.3bf076","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p16/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102268","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"liquid"}],"pid":"doi:10.1016/j.calphad.2021.102268/p16/text-01/s10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"From the calculated lattice stabilities of Cr by the second-generation and third-generation databases, as shown in Fig. 3, it can be observed that the melting point of Cr is changed from 2180 K to 2136 K in this work, based on the reason mentioned in Section 4.1.1.","quote_page":16,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":2180.0,"temperature_printed":"2180 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2180.0},{"chemical_system":"CR-NI","citations_printed":["97"],"cited_sources":[{"first_author":"Umino","kind":"unknown","label":"97","reference":"S. Umino, On the latent heat of fusion of several metals and their specific heats at high temperatures, Sci. Rep. Tôhuku Univ. 15 (1926) 597–617.","status":"resolved","year":"1926"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-2M4FWURZF3","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p16/text-01"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"bcc"},{"label":"liquid"}],"pid":"doi:10.1016/j.calphad.2021.102268/p16/text-01/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"These two data points from the work of Umino [97] are not reliable since the melting point of Cr was highly underestimated as 1873 K.","quote_page":16,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":1873.0,"temperature_printed":"1873 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1873.0},{"chemical_system":"CR-NI","citations_printed":["158","159"],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-PJ5A4D3V6I","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p18/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102268","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","pid":"doi:10.1016/j.calphad.2021.102268/p18/text-01/s11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated eutectic temperature is 1618 K, which agrees with the reported value in literature [158,159].","quote_page":18,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":1618.0,"temperature_printed":"1618 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1618.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-FWWPHXWR5Z","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p18/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102268","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"CrNi2"}],"pid":"doi:10.1016/j.calphad.2021.102268/p18/text-01/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"According to our calculation, the CrNi2 phase forms from a peritectoid reaction at 863 K.","quote_page":18,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":863.0,"temperature_printed":"863 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":863.0},{"chemical_system":"CR-NI","citations_printed":["9","47"],"cited_sources":[{"doi":"10.1016/0364-5916(91)90030-n","first_author":"Dinsdale","kind":"assessment","label":"9","paper":"doi:10.1016/0364-5916(91)90030-n","reference":"A.T. Dinsdale, SGTE data for pure elements, Calphad. 15 (1991) 317–425. https://doi.org/10.1016/0364-5916(91)90030-N.","status":"resolved","year":"1991"},{"first_author":"Gurvich","kind":"unknown","label":"47","reference":"L. V. Gurvich, I. V. Veits, V.A. Medvedev, Calculations of Thermodynamic Properties, Nauka, Moscow, 1982.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-XBIQHO5JWX","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p8/text-02"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0364-5916(91)90030-n","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"liquid"}],"pid":"doi:10.1016/j.calphad.2021.102268/p8/text-02/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The SGTE database [9] accepted the melting point of Cr to be 2180 K, as recommended by Gurvich et al. [47].","quote_page":8,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":2180.0,"temperature_printed":"2180 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2180.0},{"chemical_system":"CR-NI","citations_printed":["37","52"],"cited_sources":[{"first_author":"Hultgren","kind":"unknown","label":"37","reference":"R. Hultgren, Selected values of the thermodynamic properties of the elements, American Society for Metals, Ohio, 1973.","status":"resolved","year":"1973"},{"first_author":"Baker","kind":"assessment","label":"52","reference":"H. Baker, H. Okamoto, ASM Handbook: Volume 3: Alloy Phase Diagrams, ASM International: Materials Park, Ohio, 1992.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":5,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-UWNYLPUNSF","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p8/text-02"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"liquid"}],"pid":"doi:10.1016/j.calphad.2021.102268/p8/text-02/s11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Therefore, they suggested to adopt a lower value, 2136 K [37,52], for the melting point of Cr.","quote_page":8,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":2136.0,"temperature_printed":"2136 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2136.0},{"chemical_system":"CR-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-O24YICU5WD","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102268/p8/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102268","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102268","paper_id":"doi:10.1016/j.calphad.2021.102268","phases":[{"label":"bcc"},{"label":"liquid"}],"pid":"doi:10.1016/j.calphad.2021.102268/p8/text-02/s15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"To better reproduce experimental phase equilibria data in Cr-containing binary or even high-order systems during future thermodynamic assessments, the value 2136 K was adopted as the melting point for bcc Cr in this work.","quote_page":8,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CR-NI","system":"CR-NI","temperature_K":2136.0,"temperature_printed":"2136 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2136.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CR-NI"}