{"artifacts":{"doi:10.1016/j.calphad.2010.01.005/p2/tab-1":{"artifact":"table","caption":"First-principles results of the pure elements and compounds in the Cs–In system.","label":"1","page":2}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CS","IN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0022-5088(84)90331-x":{"authors":["K.A. Tschuntonow","S.P. Yatsenko","Yu.N. Hryn","Ya.P. Yarmolyuk","A.N. Orlow"],"citation":"K.A. Tschuntonow, S.P. Yatsenko, Yu.N. Hryn, Ya.P. Yarmolyuk, A.N. Orlow, Die Kristallstruktur von CsIn3, Journal of the Less Common Metals 99, 15-21 (1984).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(84)90331-x","doi_url":"https://doi.org/10.1016/0022-5088(84)90331-x","id":"doi:10.1016/0022-5088(84)90331-x","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Die Kristallstruktur von CsIn3","year":1984},"doi:10.1016/0022-5088(85)90228-0":{"authors":["S.P. Yatsenko","K.A. Tschuntonow","A.N. Orlow","Ya.P. Yarmolyuk","Yu.N. Hryn"],"citation":"S.P. Yatsenko, K.A. Tschuntonow, A.N. Orlow, Ya.P. Yarmolyuk, Yu.N. Hryn, Kristallstruktur von Cs2In3, Journal of the Less Common Metals 108, 339-343 (1985).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(85)90228-0","doi_url":"https://doi.org/10.1016/0022-5088(85)90228-0","id":"doi:10.1016/0022-5088(85)90228-0","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Kristallstruktur von Cs2In3","year":1985},"doi:10.1016/j.calphad.2010.01.005":{"authors":["Sung Hoon Lee","Zi-Kui Liu"],"citation":"Sung Hoon Lee, Zi-Kui Liu, First-principles calculations and thermodynamic modeling of Cs–In system, Calphad 34, 134-137 (2010).","container":"Calphad","doi":"10.1016/j.calphad.2010.01.005","doi_url":"https://doi.org/10.1016/j.calphad.2010.01.005","id":"doi:10.1016/j.calphad.2010.01.005","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"6db4eba9d9172657","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"First-principles calculations and thermodynamic modeling of Cs–In system","year":2010}},"part":1,"parts":1,"records":[{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"CsIn3","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}},{"after":{"phase":"CsIn3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}},{"after":"ORC-BDA54TMTYR.472f53","before":null,"evidence":{"decision_file":"dup1_t112.json","kept_id":"ORC-BDA54TMTYR.472f53","paper":"doi:10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","rationale":"same printed cell (CsIn3 This work, c (Å) 17.109): placeholder ORC-75E3EQ2C6C.a4cecf (ph UNKNOWN) is a second reading of ORC-BDA54TMTYR.472f53; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","report_id":"ORCHID-Y10-20261027-v1","table_key":"t112"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"255baac0610cf26132b8deaa700ae03060ef4e77b760123997a35c4591e3c483","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"same printed cell (CsIn3 This work, c (Å) 17.109): placeholder ORC-75E3EQ2C6C.a4cecf (ph UNKNOWN) is a second reading of ORC-BDA54TMTYR.472f53; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-BDA54TMTYR.472f53","evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-75E3EQ2C6C.a4cecf","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"this_work+caption_names_dft_only","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"CsIn3","label_source":"printed_source_page"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"CsIn3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1711,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1711},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":17.109,"value_stored":17.109},{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"CsIn3","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}},{"after":{"phase":"CsIn3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}},{"after":"ORC-BDA54TMTYR.27fb3d","before":null,"evidence":{"decision_file":"dup1_t112.json","kept_id":"ORC-BDA54TMTYR.27fb3d","paper":"doi:10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","rationale":"same printed cell (CsIn3 This work, a (Å) 7.197): placeholder ORC-75E3EQ2C6C.c76fbb (ph UNKNOWN) is a second reading of ORC-BDA54TMTYR.27fb3d; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","report_id":"ORCHID-Y10-20261027-v1","table_key":"t112"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"255baac0610cf26132b8deaa700ae03060ef4e77b760123997a35c4591e3c483","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"same printed cell (CsIn3 This work, a (Å) 7.197): placeholder ORC-75E3EQ2C6C.c76fbb (ph UNKNOWN) is a second reading of ORC-BDA54TMTYR.27fb3d; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-BDA54TMTYR.27fb3d","evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-75E3EQ2C6C.c76fbb","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"this_work+caption_names_dft_only","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"CsIn3","label_source":"printed_source_page"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"CsIn3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07197,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07197},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.197,"value_stored":7.197},{"chemical_system":"CS-IN","cited_sources":[{"doi":"10.1016/0022-5088(84)90331-x","first_author":"Tschuntonow","kind":"unknown","label":"14","paper":"doi:10.1016/0022-5088(84)90331-x","reference":"K.A. Tschuntonow, S.P. Yatsenko, Yu N. Hryn, Ya P. Yarmolyuk, A.N. Orlow, J. Less-Common Met. 99 (1) (1984) 15–21.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"CsIn3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-KYL3KWUIBI.9aa2f3","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"IN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"CsIn3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"CsIn3","space_group":"I-4m2"},"system":"CS-IN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.007},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03697,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03697},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.007},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":16.803},{"chemical_system":"CS-IN","cited_sources":[{"doi":"10.1016/0022-5088(84)90331-x","first_author":"Tschuntonow","kind":"unknown","label":"14","paper":"doi:10.1016/0022-5088(84)90331-x","reference":"K.A. Tschuntonow, S.P. Yatsenko, Yu N. Hryn, Ya P. Yarmolyuk, A.N. Orlow, J. Less-Common Met. 99 (1) (1984) 15–21.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"CsIn3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-KYL3KWUIBI.dd5d17","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"IN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"CsIn3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"CsIn3","space_group":"I-4m2"},"system":"CS-IN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.004},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0155,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0155},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.004},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":7.047},{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"Cs2In3","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}},{"after":{"phase":"Cs2In3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}},{"after":"ORC-3WQRMVZJZO.6a74f3","before":null,"evidence":{"decision_file":"dup1_t112.json","kept_id":"ORC-3WQRMVZJZO.6a74f3","paper":"doi:10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","rationale":"same printed cell (Cs2In3 This work, a (Å) 7.062): placeholder ORC-FZWVLKETHW.41fbf6 (ph UNKNOWN) is a second reading of ORC-3WQRMVZJZO.6a74f3; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","report_id":"ORCHID-Y10-20261027-v1","table_key":"t112"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"255baac0610cf26132b8deaa700ae03060ef4e77b760123997a35c4591e3c483","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"same printed cell (Cs2In3 This work, a (Å) 7.062): placeholder ORC-FZWVLKETHW.41fbf6 (ph UNKNOWN) is a second reading of ORC-3WQRMVZJZO.6a74f3; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-3WQRMVZJZO.6a74f3","evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-FZWVLKETHW.41fbf6","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"this_work+caption_names_dft_only","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"Cs2In3","label_source":"printed_source_page"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"Cs2In3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07062,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07062},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.062,"value_stored":7.062},{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"Cs2In3","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}},{"after":{"phase":"Cs2In3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies phase, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}},{"after":"ORC-3WQRMVZJZO.34e368","before":null,"evidence":{"decision_file":"dup1_t112.json","kept_id":"ORC-3WQRMVZJZO.34e368","paper":"doi:10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","rationale":"same printed cell (Cs2In3 This work, c (Å) 16.824): placeholder ORC-FZWVLKETHW.6e394b (ph UNKNOWN) is a second reading of ORC-3WQRMVZJZO.34e368; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","report_id":"ORCHID-Y10-20261027-v1","table_key":"t112"},"field":"duplicate_of","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"Original TD rendered-page decision reconciled by Codex against committed 7ac9ca9f18 on 2026-10-27; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"255baac0610cf26132b8deaa700ae03060ef4e77b760123997a35c4591e3c483","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"same printed cell (Cs2In3 This work, c (Å) 16.824): placeholder ORC-FZWVLKETHW.6e394b (ph UNKNOWN) is a second reading of ORC-3WQRMVZJZO.34e368; natural alias and kept record are both EXCL (table-context batch), pair left unchanged","verdict":"confirmed_by_original_page_decision"}}],"duplicate_of":"ORC-3WQRMVZJZO.34e368","evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation","independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"gate_failures":[{"code":"human_review_residual_concern","detail":"This later-pass alias is now guardable after TC/TD integration; full duplicate graph and release invariant tests remain required before 2026.10.1 integration.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-FZWVLKETHW.6e394b","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"this_work+caption_names_dft_only","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"Cs2In3","label_source":"printed_source_page"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"Cs2In3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1682,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1682},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":16.824,"value_stored":16.824},{"chemical_system":"CS-IN","cited_sources":[{"doi":"10.1016/0022-5088(85)90228-0","first_author":"Yatsenko","kind":"assessment","label":"15","paper":"doi:10.1016/0022-5088(85)90228-0","reference":"S.P. Yatsenko, K.A. Tschuntonow, A.N. Orlow, Ya P. Yarmolyuk, Yu N. Hryn, J. Less-Common Met. 108 (2) (1985) 339–343. 137","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"Cs2In3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-M255UGUYHG.14fd5c","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"IN":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"Cs2In3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"Cs2In3","space_group":"I-4m2"},"system":"CS-IN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.007},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03655,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03655},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.007},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":16.612},{"chemical_system":"CS-IN","cited_sources":[{"doi":"10.1016/0022-5088(85)90228-0","first_author":"Yatsenko","kind":"assessment","label":"15","paper":"doi:10.1016/0022-5088(85)90228-0","reference":"S.P. Yatsenko, K.A. Tschuntonow, A.N. Orlow, Ya P. Yarmolyuk, Yu N. Hryn, J. Less-Common Met. 108 (2) (1985) 339–343. 137","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"Cs2In3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-M255UGUYHG.6103e3","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"IN":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"Cs2In3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"Cs2In3","space_group":"I-4m2"},"system":"CS-IN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.003},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0152,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0152},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.003},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":6.91},{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"CsIn3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-BDA54TMTYR.27fb3d","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":10},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"CsIn3","model_phase":"CSIN3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"CsIn3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07197,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07197},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.197,"value_stored":7.197},{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"CsIn3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"CsIn3 | I4̄m2 | a 7.197, 7.047(4); c 17.109, 16.803(7) (This work / Exp [14])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6,7,10],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"CsIn3 group, 2 printed lines; r6 is a placeholder second reading of r10 (7.197/17.109, This work); ends before Cs2In3","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-BDA54TMTYR.472f53","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":10},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"CsIn3","model_phase":"CSIN3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"CsIn3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1711,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1711},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":17.109,"value_stored":17.109},{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cs2In3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-3WQRMVZJZO.34e368","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":11},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"Cs2In3","model_phase":"CS2IN3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"Cs2In3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1682,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1682},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":16.824,"value_stored":16.824},{"chemical_system":"CS-IN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"Cs2In3","space_group":"I-4m2"},"before":null,"evidence":{"batch":"table_context_batch_06","doi":"10.1016/j.calphad.2010.01.005","pdf_page":2,"pdf_sha256":"6db4eba9d9172657f3948f07afc591f52a2cd4d788bcaefecac76b39ef66e9f0","printed":"Cs2In3 | I4̄m2 | a 7.062, 6.910(3); c 16.824, 16.612(7) (This work / Exp [15])","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[8,9,11],"table":"1","table_key":"t112"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 06","image_sha256":"cd5144fd7fb1eb10c1304e1cb889d5c6477dd0f2fc321b691ac89655ac2b237c","page":2,"pdf_sha256_prefix":"6db4eba9d9172657","seen":"Cs2In3 group, 2 printed lines; r8 is a placeholder second reading of r11 (7.062/16.824); last group of the table","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":1,"id":"ORC-3WQRMVZJZO.6a74f3","locator":{"ref":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1","row":11},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2010.01.005","own_work_of_paper":true},"overall_composition":{"IN":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2010.01.005","paper_id":"doi:10.1016/j.calphad.2010.01.005","phases":[{"label":"Cs2In3","model_phase":"CS2IN3"}],"pid":"doi:10.1016/j.calphad.2010.01.005/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CS-IN","structure":{"phase":"Cs2In3","space_group":"I-4m2"},"system":"CS-IN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07062,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07062},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.062,"value_stored":7.062}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CS-IN"}