{"artifacts":{"doi:10.1016/j.calphad.2021.102350/p7/tab-7":{"artifact":"table","caption":"Invariant equilibria calculated in this work compared to the literature data.","label":"7","page":7},"sha256:22fe4fa42e763c4f/p3/tab-1":{"artifact":"table","caption":"Structural data for the ternary phases in the Cs–Mo–O system (1 Å = 0.1 nm). Uncertainties relative to the last digits are given in parenthesis.","label":"1","page":3},"sha256:22fe4fa42e763c4f/p4/tab-2":{"artifact":"table","caption":"Thermodynamic data reported on the cesium polymolybdates.","label":"2","page":4},"sha256:22fe4fa42e763c4f/p4/tab-3":{"artifact":"table","caption":"Re-calculated enthalpies of formation of the cesium polymolybdates based on an uncer- tainty of 1% on the enthalpy of formation of MoO 3 (cr) involved in the thermochemical cycles of the solution calorimetry measurements. The values selected for the present assessment are marked in bold.","label":"3","page":4},"sha256:22fe4fa42e763c4f/p7/tab-8":{"artifact":"table","caption":"Enthalpies of formation and standard entropies of the ternary cesium molybdates optimized in this work.","label":"8","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CS","MO","O"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0020-1650(73)80013-3":{"authors":["Henry R. Hoekstra"],"citation":"Henry R. Hoekstra, The Cs2MoO4MoO3 system, Inorganic and Nuclear Chemistry Letters 9, 1291-1301 (1973).","container":"Inorganic and Nuclear Chemistry Letters","doi":"10.1016/0020-1650(73)80013-3","doi_url":"https://doi.org/10.1016/0020-1650(73)80013-3","id":"doi:10.1016/0020-1650(73)80013-3","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Cs2MoO4MoO3 system","year":1973},"doi:10.1016/0021-9614(74)90260-2":{"authors":["Darrell W Osborne","Howard E Flotow","Henry R Hoekstra"],"citation":"Darrell W Osborne, Howard E Flotow, Henry R Hoekstra, Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K, The Journal of Chemical Thermodynamics 6, 179-183 (1974).","container":"The Journal of Chemical Thermodynamics","doi":"10.1016/0021-9614(74)90260-2","doi_url":"https://doi.org/10.1016/0021-9614(74)90260-2","id":"doi:10.1016/0021-9614(74)90260-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K","year":1974},"doi:10.1016/j.calphad.2021.102350":{"authors":["A.L. Smith","T.N. Pham Thi","C. Guéneau","J.-C. Dumas","E. Epifano","W. van Burik","N. Dupin"],"citation":"A.L. Smith, T.N. Pham Thi, C. Guéneau, J.-C. Dumas, E. Epifano, W. van Burik et al., Thermodynamic modelling assessment of the ternary system Cs-Mo-O, Calphad 75, 102350 (2021).","container":"Calphad","doi":"10.1016/j.calphad.2021.102350","doi_url":"https://doi.org/10.1016/j.calphad.2021.102350","id":"doi:10.1016/j.calphad.2021.102350","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"22fe4fa42e763c4f","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modelling assessment of the ternary system Cs-Mo-O","year":2021},"doi:10.1016/j.jct.2018.01.016":{"authors":["A.L. Smith","M.-C. Pignié","L. van Eijck","J.-C. Griveau","E. Colineau","R.J.M. Konings"],"citation":"A.L. Smith, M.-C. Pignié, L. van Eijck, J.-C. Griveau, E. Colineau, R.J.M. Konings, Thermodynamic study of Cs3Na(MoO4)2: Determination of the standard enthalpy of formation and standard entropy at 298.15 K, The Journal of Chemical Thermodynamics 120, 205-216 (2018).","container":"The Journal of Chemical Thermodynamics","doi":"10.1016/j.jct.2018.01.016","doi_url":"https://doi.org/10.1016/j.jct.2018.01.016","id":"doi:10.1016/j.jct.2018.01.016","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermodynamic study of Cs3Na(MoO4)2: Determination of the standard enthalpy of formation and standard entropy at 298.15 K","year":2018},"doi:10.1016/j.jssc.2014.04.003":{"authors":["Gilles Wallez","Philippe E. Raison","Anna L. Smith","Nicolas Clavier","Nicolas Dacheux"],"citation":"Gilles Wallez, Philippe E. Raison, Anna L. Smith, Nicolas Clavier, Nicolas Dacheux, High-temperature behavior of dicesium molybdate Cs2MoO4: Implications for fast neutron reactors, Journal of Solid State Chemistry 215, 225-230 (2014).","container":"Journal of Solid State Chemistry","doi":"10.1016/j.jssc.2014.04.003","doi_url":"https://doi.org/10.1016/j.jssc.2014.04.003","id":"doi:10.1016/j.jssc.2014.04.003","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"High-temperature behavior of dicesium molybdate Cs2MoO4: Implications for fast neutron reactors","year":2014},"doi:10.1016/j.jssc.2017.05.032":{"authors":["A.L. Smith","G. Kauric","L. van Eijck","K. Goubitz","G. Wallez","J.-C. Griveau","E. Colineau","N. Clavier","R.J.M. Konings"],"citation":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau et al., Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, Journal of Solid State Chemistry 253, 89-102 (2017).","container":"Journal of Solid State Chemistry","doi":"10.1016/j.jssc.2017.05.032","doi_url":"https://doi.org/10.1016/j.jssc.2017.05.032","id":"doi:10.1016/j.jssc.2017.05.032","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors","year":2017},"doi:10.1016/j.tca.2020.178825":{"authors":["A.L. Smith","J. Vlieland","M.-C. Pignié","M. Abbink","G. Mikaelian","P. Benigni"],"citation":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochimica Acta 696, 178825 (2021).","container":"Thermochimica Acta","doi":"10.1016/j.tca.2020.178825","doi_url":"https://doi.org/10.1016/j.tca.2020.178825","id":"doi:10.1016/j.tca.2020.178825","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system","year":2021},"doi:10.1021/acs.jced.0c00210":{"authors":["Pierre Benigni","Georges Mikaelian","Elise Ruiz","Carine Perrin-Pellegrino","Jacques Rogez"],"citation":"Pierre Benigni, Georges Mikaelian, Elise Ruiz, Carine Perrin-Pellegrino, Jacques Rogez, Calorimetric Determination of the Formation Enthalpies of Cs Polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65, 3875-3883 (2020).","container":"J. Chem. Eng. Data","doi":"10.1021/acs.jced.0c00210","doi_url":"https://doi.org/10.1021/acs.jced.0c00210","id":"doi:10.1021/acs.jced.0c00210","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Calorimetric Determination of the Formation Enthalpies of Cs Polymolybdates at 298.15 K and 0.1 MPa","year":2020},"doi:10.1107/s0108270195004811":{"authors":["J. Marrot","J. M. Savariault"],"citation":"J. Marrot, J. M. Savariault, Two Original Infinite Chains in the New Caesium Tetramolybdate Compound Cs2Mo4O13, Acta Crystallogr C Cryst Struct Commun 51, 2201-2205 (1995).","container":"Acta Crystallogr C Cryst Struct Commun","doi":"10.1107/s0108270195004811","doi_url":"https://doi.org/10.1107/s0108270195004811","id":"doi:10.1107/s0108270195004811","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Two Original Infinite Chains in the New Caesium Tetramolybdate Compound Cs2Mo4O13","year":1995},"doi:10.1134/s1066362211040035":{"authors":["A. S. Pakhomova","D. V. Spiridonova","S. V. Krivovichev"],"citation":"A. S. Pakhomova, D. V. Spiridonova, S. V. Krivovichev, Crystal structure of β-Cs2Mo4O13, Radiochemistry 53, 358-360 (2011).","container":"Radiochemistry","doi":"10.1134/s1066362211040035","doi_url":"https://doi.org/10.1134/s1066362211040035","id":"doi:10.1134/s1066362211040035","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Crystal structure of β-Cs2Mo4O13","year":2011}},"part":1,"parts":1,"records":[{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SR6R2V4X2A.00a8fc","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pnma"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":8e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.002544,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.002544},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":8e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.15623},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SR6R2V4X2A.42f251","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pnma"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001868,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001868},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.84906},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SR6R2V4X2A.993ccb","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pnma"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":90.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SR6R2V4X2A.fcbc7c","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pnma"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001439,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001439},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.65406},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2014.04.003","first_author":"Wallez","kind":"unknown","label":"13","paper":"doi:10.1016/j.jssc.2014.04.003","reference":"G. Wallez, P.E. Raison, A.L. Smith, N. Clavier, N. Dacheux, J. Solid State Chem. 215 (2014) 225–230.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-XJEJBR6UNY.02a1ef","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P6_3/mmc"},"system":"CS-MO-O","temperature_K":948.0,"temperature_basis":"printed","temperature_printed":"948 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0002},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001975,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001975},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0002},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.8977},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2014.04.003","first_author":"Wallez","kind":"unknown","label":"13","paper":"doi:10.1016/j.jssc.2014.04.003","reference":"G. Wallez, P.E. Raison, A.L. Smith, N. Clavier, N. Dacheux, J. Solid State Chem. 215 (2014) 225–230.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-XJEJBR6UNY.36ec02","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P6_3/mmc"},"system":"CS-MO-O","temperature_K":948.0,"temperature_basis":"printed","temperature_printed":"948 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":90.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2014.04.003","first_author":"Wallez","kind":"unknown","label":"13","paper":"doi:10.1016/j.jssc.2014.04.003","reference":"G. Wallez, P.E. Raison, A.L. Smith, N. Clavier, N. Dacheux, J. Solid State Chem. 215 (2014) 225–230.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-XJEJBR6UNY.749e6b","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P6_3/mmc"},"system":"CS-MO-O","temperature_K":948.0,"temperature_basis":"printed","temperature_printed":"948 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001505,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001505},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0001},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.684},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2014.04.003","first_author":"Wallez","kind":"unknown","label":"13","paper":"doi:10.1016/j.jssc.2014.04.003","reference":"G. Wallez, P.E. Raison, A.L. Smith, N. Clavier, N. Dacheux, J. Solid State Chem. 215 (2014) 225–230.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-XJEJBR6UNY.87e34c","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P6_3/mmc"},"system":"CS-MO-O","temperature_K":948.0,"temperature_basis":"printed","temperature_printed":"948 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001505,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001505},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0001},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.684},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ITHEJVR7WF.15af98","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P2_1/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0002},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.003423,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.003423},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0002},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.556},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ITHEJVR7WF.9fc6b1","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P2_1/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.007},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.007},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":90.12},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ITHEJVR7WF.acea8b","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P2_1/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00334,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00334},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0001},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.5184},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ITHEJVR7WF.fead74","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"P2_1/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":7e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001589,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001589},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.72244},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-UNQRY2XNYT.1364ca","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pbcm"},"system":"CS-MO-O","temperature_K":683.0,"temperature_basis":"printed","temperature_printed":"683 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.1e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.003407,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.003407},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.1e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-07},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.548597},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-UNQRY2XNYT.c66350","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pbcm"},"system":"CS-MO-O","temperature_K":683.0,"temperature_basis":"printed","temperature_printed":"683 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":90.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-UNQRY2XNYT.cf1bbe","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pbcm"},"system":"CS-MO-O","temperature_K":683.0,"temperature_basis":"printed","temperature_printed":"683 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.1e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001594,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001594},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.1e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-07},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.724613},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-UNQRY2XNYT.daa6d9","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"β-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"Pbcm"},"system":"CS-MO-O","temperature_K":683.0,"temperature_basis":"printed","temperature_printed":"683 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.1e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001758,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001758},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.1e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-07},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.799136},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-5HFMZZEXQG.2bad49","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0002},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.003184,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.003184},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0002},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.4472},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-5HFMZZEXQG.44b12f","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.006},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.006},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":97.731},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-5HFMZZEXQG.9f04b4","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.002082,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.002082},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0001},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.9464},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-5HFMZZEXQG.fbf9fe","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001849,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001849},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0001},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.8404},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1134/s1066362211040035","first_author":"Pakhomova","kind":"unknown","label":"24","paper":"doi:10.1134/s1066362211040035","reference":"A.S. Pakhomova, D.V. Spiridonova, S.V. Krivovichev, Crystal structure of 𝛽-Cs2Mo4O13, Radiochemistry 53 (2011) 358–360.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"before":null,"evidence":{"batch":"table_context_batch_11","doi":"10.1016/j.calphad.2021.102350","pdf_page":3,"pdf_sha256":"22fe4fa42e763c4fc2894b24d1003b0caecda780ad48da4f3a8cd5c284e69148","printed":"Cs2Mo4O13 | Triclinic | P − 1 | 0.8396(5) | 0.8655(5) | 1.0413(5) | see c [24]; footnote c: α = 106.158(5), β = 103.686(5), γ = 109.761(5)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6],"table":"1","table_key":"t211"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 11","image_sha256":"cd23d5f343672a78500ea0594471062953bb1d9855e632126454ff07650baf49","page":3,"pdf_sha256_prefix":"22fe4fa42e763c4f","seen":"single row (triclinic Cs2Mo4O13, ref [24]); the next row is the monoclinic C2/c Cs2Mo4O13 [28], already carrying C2/c","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-VTHZOLAIVO.1fec26","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001904,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001904},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0005},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.8655},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1134/s1066362211040035","first_author":"Pakhomova","kind":"unknown","label":"24","paper":"doi:10.1134/s1066362211040035","reference":"A.S. Pakhomova, D.V. Spiridonova, S.V. Krivovichev, Crystal structure of 𝛽-Cs2Mo4O13, Radiochemistry 53 (2011) 358–360.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"before":null,"evidence":{"batch":"table_context_batch_11","doi":"10.1016/j.calphad.2021.102350","pdf_page":3,"pdf_sha256":"22fe4fa42e763c4fc2894b24d1003b0caecda780ad48da4f3a8cd5c284e69148","printed":"Cs2Mo4O13 | Triclinic | P − 1 | 0.8396(5) | 0.8655(5) | 1.0413(5) | see c [24]; footnote c: α = 106.158(5), β = 103.686(5), γ = 109.761(5)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6],"table":"1","table_key":"t211"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 11","image_sha256":"cd23d5f343672a78500ea0594471062953bb1d9855e632126454ff07650baf49","page":3,"pdf_sha256_prefix":"22fe4fa42e763c4f","seen":"single row (triclinic Cs2Mo4O13, ref [24]); the next row is the monoclinic C2/c Cs2Mo4O13 [28], already carrying C2/c","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-VTHZOLAIVO.2cb6d6","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_ALPHA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.005},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":106.158},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1134/s1066362211040035","first_author":"Pakhomova","kind":"unknown","label":"24","paper":"doi:10.1134/s1066362211040035","reference":"A.S. Pakhomova, D.V. Spiridonova, S.V. Krivovichev, Crystal structure of 𝛽-Cs2Mo4O13, Radiochemistry 53 (2011) 358–360.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"before":null,"evidence":{"batch":"table_context_batch_11","doi":"10.1016/j.calphad.2021.102350","pdf_page":3,"pdf_sha256":"22fe4fa42e763c4fc2894b24d1003b0caecda780ad48da4f3a8cd5c284e69148","printed":"Cs2Mo4O13 | Triclinic | P − 1 | 0.8396(5) | 0.8655(5) | 1.0413(5) | see c [24]; footnote c: α = 106.158(5), β = 103.686(5), γ = 109.761(5)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6],"table":"1","table_key":"t211"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 11","image_sha256":"cd23d5f343672a78500ea0594471062953bb1d9855e632126454ff07650baf49","page":3,"pdf_sha256_prefix":"22fe4fa42e763c4f","seen":"single row (triclinic Cs2Mo4O13, ref [24]); the next row is the monoclinic C2/c Cs2Mo4O13 [28], already carrying C2/c","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-VTHZOLAIVO.31c01a","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001847,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001847},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0005},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.8396},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1134/s1066362211040035","first_author":"Pakhomova","kind":"unknown","label":"24","paper":"doi:10.1134/s1066362211040035","reference":"A.S. Pakhomova, D.V. Spiridonova, S.V. Krivovichev, Crystal structure of 𝛽-Cs2Mo4O13, Radiochemistry 53 (2011) 358–360.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"before":null,"evidence":{"batch":"table_context_batch_11","doi":"10.1016/j.calphad.2021.102350","pdf_page":3,"pdf_sha256":"22fe4fa42e763c4fc2894b24d1003b0caecda780ad48da4f3a8cd5c284e69148","printed":"Cs2Mo4O13 | Triclinic | P − 1 | 0.8396(5) | 0.8655(5) | 1.0413(5) | see c [24]; footnote c: α = 106.158(5), β = 103.686(5), γ = 109.761(5)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6],"table":"1","table_key":"t211"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 11","image_sha256":"cd23d5f343672a78500ea0594471062953bb1d9855e632126454ff07650baf49","page":3,"pdf_sha256_prefix":"22fe4fa42e763c4f","seen":"single row (triclinic Cs2Mo4O13, ref [24]); the next row is the monoclinic C2/c Cs2Mo4O13 [28], already carrying C2/c","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-VTHZOLAIVO.322725","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.005},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":103.686},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1134/s1066362211040035","first_author":"Pakhomova","kind":"unknown","label":"24","paper":"doi:10.1134/s1066362211040035","reference":"A.S. Pakhomova, D.V. Spiridonova, S.V. Krivovichev, Crystal structure of 𝛽-Cs2Mo4O13, Radiochemistry 53 (2011) 358–360.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"before":null,"evidence":{"batch":"table_context_batch_11","doi":"10.1016/j.calphad.2021.102350","pdf_page":3,"pdf_sha256":"22fe4fa42e763c4fc2894b24d1003b0caecda780ad48da4f3a8cd5c284e69148","printed":"Cs2Mo4O13 | Triclinic | P − 1 | 0.8396(5) | 0.8655(5) | 1.0413(5) | see c [24]; footnote c: α = 106.158(5), β = 103.686(5), γ = 109.761(5)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6],"table":"1","table_key":"t211"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 11","image_sha256":"cd23d5f343672a78500ea0594471062953bb1d9855e632126454ff07650baf49","page":3,"pdf_sha256_prefix":"22fe4fa42e763c4f","seen":"single row (triclinic Cs2Mo4O13, ref [24]); the next row is the monoclinic C2/c Cs2Mo4O13 [28], already carrying C2/c","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-VTHZOLAIVO.4b4a2a","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.002291,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.002291},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0005},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.0413},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1134/s1066362211040035","first_author":"Pakhomova","kind":"unknown","label":"24","paper":"doi:10.1134/s1066362211040035","reference":"A.S. Pakhomova, D.V. Spiridonova, S.V. Krivovichev, Crystal structure of 𝛽-Cs2Mo4O13, Radiochemistry 53 (2011) 358–360.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"before":null,"evidence":{"batch":"table_context_batch_11","doi":"10.1016/j.calphad.2021.102350","pdf_page":3,"pdf_sha256":"22fe4fa42e763c4fc2894b24d1003b0caecda780ad48da4f3a8cd5c284e69148","printed":"Cs2Mo4O13 | Triclinic | P − 1 | 0.8396(5) | 0.8655(5) | 1.0413(5) | see c [24]; footnote c: α = 106.158(5), β = 103.686(5), γ = 109.761(5)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6],"table":"1","table_key":"t211"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 11","image_sha256":"cd23d5f343672a78500ea0594471062953bb1d9855e632126454ff07650baf49","page":3,"pdf_sha256_prefix":"22fe4fa42e763c4f","seen":"single row (triclinic Cs2Mo4O13, ref [24]); the next row is the monoclinic C2/c Cs2Mo4O13 [28], already carrying C2/c","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-VTHZOLAIVO.e92347","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"crystal_system":"Triclinic","phase":"Cs2Mo4O13","space_group":"P-1"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.005},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":109.761},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1107/s0108270195004811","first_author":"Marrot","kind":"unknown","label":"28","paper":"doi:10.1107/s0108270195004811","reference":"J. Marrot, J.M. Savariault, Acta Crystallogr. C 51 (1995) 2201–2205.","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SEHCWOKNIV.569fe0","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0101,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0101},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.005},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":4.592},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1107/s0108270195004811","first_author":"Marrot","kind":"unknown","label":"28","paper":"doi:10.1107/s0108270195004811","reference":"J. Marrot, J.M. Savariault, Acta Crystallogr. C 51 (1995) 2201–2205.","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SEHCWOKNIV.a1d349","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0003},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.002292,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.002292},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0003},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.0418},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1107/s0108270195004811","first_author":"Marrot","kind":"unknown","label":"28","paper":"doi:10.1107/s0108270195004811","reference":"J. Marrot, J.M. Savariault, Acta Crystallogr. C 51 (1995) 2201–2205.","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SEHCWOKNIV.ca46e5","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0008},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001743,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001743},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0008},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.7923},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1107/s0108270195004811","first_author":"Marrot","kind":"unknown","label":"28","paper":"doi:10.1107/s0108270195004811","reference":"J. Marrot, J.M. Savariault, Acta Crystallogr. C 51 (1995) 2201–2205.","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SEHCWOKNIV.ca79f0","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.05},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":92.94},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-DVN5UNWIEX.302ba7","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.003155,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.003155},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0001},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.4339},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-DVN5UNWIEX.3cc751","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.005},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":122.735},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-DVN5UNWIEX.aa2fa0","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0002},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.004718,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.004718},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0002},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":2.1444},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-DVN5UNWIEX.f8835e","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001223,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001223},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4e-05},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.556},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZSCU63UGQW.2a4b2f","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.003},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.003},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":122.744},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZSCU63UGQW.2bf275","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.001218,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.001218},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":0.55385},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZSCU63UGQW.91fe93","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00474,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00474},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0001},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":2.1546},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZSCU63UGQW.d3331f","locator":{"ref":"sha256:22fe4fa42e763c4f/p3/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","structure":{"space_group":"C2/c"},"system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":9e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.004162,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.004162},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":9e-05},"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"not_printed","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"not_printed","value":1.89179},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"31","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates. I. standard enthalpy of formation of cesium molybdate (Cs2MoO4), J. Chem. Thermodyn. 5 (1973) 851–856.","status":"resolved","year":"1973"},{"doi":"10.1016/0021-9614(74)90260-2","first_author":"Osborne","kind":"unknown","label":"35","paper":"doi:10.1016/0021-9614(74)90260-2","reference":"D.W. Osborne, H.E. Flotow, H.R. Hoekstra, Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K, J. Chem. Thermodyn. 6 (2) (1974) 179–183.","status":"resolved","year":"1974"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.1428571429,"before":1.0,"evidence":{"divisor":7.0,"sigma_printed":1.0,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-FDJUNXIPO3.2aff22","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.1428571429},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.1429},"sigma_reading":{"basis":"last_printed_digit","value":0.007143},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":1.0},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-216.3571429,"value_printed":-1514.5,"value_stored":-216357.1429},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"31","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates. I. standard enthalpy of formation of cesium molybdate (Cs2MoO4), J. Chem. Thermodyn. 5 (1973) 851–856.","status":"resolved","year":"1973"},{"doi":"10.1016/0021-9614(74)90260-2","first_author":"Osborne","kind":"unknown","label":"35","paper":"doi:10.1016/0021-9614(74)90260-2","reference":"D.W. Osborne, H.E. Flotow, H.R. Hoekstra, Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K, J. Chem. Thermodyn. 6 (2) (1974) 179–183.","status":"resolved","year":"1974"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.04285714286,"before":0.3,"evidence":{"divisor":7.0,"sigma_printed":0.3,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'α-Cs2MoO4'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-FDJUNXIPO3.53d3e9","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.04285714286},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.04286},"sigma_reading":{"basis":"last_printed_digit","value":0.0007143},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":0.3},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":35.47857143,"value_printed":248.35},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"31","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates. I. standard enthalpy of formation of cesium molybdate (Cs2MoO4), J. Chem. Thermodyn. 5 (1973) 851–856.","status":"resolved","year":"1973"},{"doi":"10.1016/0021-9614(74)90260-2","first_author":"Osborne","kind":"unknown","label":"35","paper":"doi:10.1016/0021-9614(74)90260-2","reference":"D.W. Osborne, H.E. Flotow, H.R. Hoekstra, Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K, J. Chem. Thermodyn. 6 (2) (1974) 179–183.","status":"resolved","year":"1974"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.02142857143,"before":0.15,"evidence":{"divisor":7.0,"sigma_printed":0.15,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["unit not given by readers"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-FDJUNXIPO3.d7bd91","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"C°p,m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.02142857143},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02143,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","reason":"unit 'unknown' not convertible to J/K/mol","value":null},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.02143},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"unknown","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":0.15},"unit":"unknown","value":148.67,"value_printed":148.67},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jct.2018.01.016","first_author":"Smith","kind":"unknown","label":"33","paper":"doi:10.1016/j.jct.2018.01.016","reference":"A.L. Smith, M.-C. Pignié, L. van Eijck, J.-C. Griveau, E. Colineau, R.J.M. Konings, Thermodynamic study of Cs3Na(MoO4)2: Determination of the standard enthalpy of formation and standard entropy at 298.15 K, J. Chem. Thermodyn. 120 (2018) 205–216.","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.22,"before":1.54,"evidence":{"divisor":7.0,"sigma_printed":1.54,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-C3K2DUTL77","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":2},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.22},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.22},"sigma_reading":{"basis":"last_printed_digit","value":0.0007143},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":1.54},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-216.3842857,"value_printed":-1514.69,"value_stored":-216384.2857},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.1585714286,"before":1.11,"evidence":{"divisor":7.0,"sigma_printed":1.11,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-5MIFXWX3RY","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.1585714286},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.1586},"sigma_reading":{"basis":"last_printed_digit","value":0.0007143},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":1.11},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-216.2228571,"value_printed":-1513.56,"value_stored":-216222.8571},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"32","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates V. Standard enthaly of formation of cesium dimolybdate, J. Chem. Thermodyn. 7 (1975) 279–284.","status":"resolved","year":"1975"},{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.1909090909,"before":2.1,"evidence":{"divisor":11.0,"sigma_printed":2.1,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-SBRG56PJJC.1f222d","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":4},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.1909090909},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.1909},"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":2.1},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-209.3090909,"value_printed":-2302.4,"value_stored":-209309.0909},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"32","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates V. Standard enthaly of formation of cesium dimolybdate, J. Chem. Thermodyn. 7 (1975) 279–284.","status":"resolved","year":"1975"},{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.1909090909,"before":2.1,"evidence":{"divisor":11.0,"sigma_printed":2.1,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["unit not given by readers"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-SBRG56PJJC.c74d34","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":4},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"C°p,m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.1909090909},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1909,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","reason":"unit 'unknown' not convertible to J/K/mol","value":null},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.1909},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"unknown","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":2.1},"unit":"unknown","value":211.9,"value_printed":211.9},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"32","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates V. Standard enthaly of formation of cesium dimolybdate, J. Chem. Thermodyn. 7 (1975) 279–284.","status":"resolved","year":"1975"},{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.3909090909,"before":4.3,"evidence":{"divisor":11.0,"sigma_printed":4.3,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'α-Cs2Mo2O7'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SBRG56PJJC.e589da","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":4},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.3909090909},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.3909},"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":4.3},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":28.85454545,"value_printed":317.4},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.2154545455,"before":2.37,"evidence":{"divisor":11.0,"sigma_printed":2.37,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-DZO2AKUFUP","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":5},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.2154545455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.2155},"sigma_reading":{"basis":"last_printed_digit","value":0.0004545},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":2.37},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-209.2581818,"value_printed":-2301.84,"value_stored":-209258.1818},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.4272727273,"before":4.7,"evidence":{"divisor":11.0,"sigma_printed":4.7,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-Y6H4ATJXYG","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":6},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.4272727273},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.4273},"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":4.7},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-209.2363636,"value_printed":-2301.6,"value_stored":-209236.3636},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.2313333333,"before":3.47,"evidence":{"divisor":15.0,"sigma_printed":3.47,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-FCUMTYYQOQ","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":7},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":15.0,"phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.2313333333},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.2313},"sigma_reading":{"basis":"last_printed_digit","value":0.0003333},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":3.47},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-205.1446667,"value_printed":-3077.17,"value_stored":-205144.6667},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.4333333333,"before":6.5,"evidence":{"divisor":15.0,"sigma_printed":6.5,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-4JYFKDEKYZ","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":8},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":15.0,"phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.4333333333},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.4333},"sigma_reading":{"basis":"last_printed_digit","value":0.003333},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":6.5},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-205.04,"value_printed":-3075.6,"value_stored":-205040.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.2591304348,"before":5.96,"evidence":{"divisor":23.0,"sigma_printed":5.96,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-BR3MXRRG4M","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":9},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":23.0,"phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.2591304348},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.2591},"sigma_reading":{"basis":"last_printed_digit","value":0.002174},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":5.96},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-200.073913,"value_printed":-4601.7,"value_stored":-200073.913},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.2835483871,"before":8.79,"evidence":{"divisor":31.0,"sigma_printed":8.79,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-4PRPIXFB6Y","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-2","row":10},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":31.0,"phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-2/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Δf H°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.2835483871},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.2835},"sigma_reading":{"basis":"last_printed_digit","value":0.0001613},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":8.79},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-196.36,"value_printed":-6087.16,"value_stored":-196360.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"31","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates. I. standard enthalpy of formation of cesium molybdate (Cs2MoO4), J. Chem. Thermodyn. 5 (1973) 851–856.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.064285714,"before":7.45,"evidence":{"divisor":7.0,"sigma_printed":7.45,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-DLZBZMMWJQ","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":1},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.064285714},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.064},"sigma_reading":{"basis":"last_printed_digit","value":0.007143},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":7.45},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-216.3571429,"value_printed":-1514.5,"value_stored":-216357.1429},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.jssc.2017.05.032","first_author":"Smith","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2017.05.032","reference":"A.L. Smith, G. Kauric, L. van Eijck, K. Goubitz, G. Wallez, J.-C. Griveau, E. Colineau, N. Clavier, R.J.M. Konings, Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors, J. Solid State Chem. 253 (2017) 89–102.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.077142857,"before":7.54,"evidence":{"divisor":7.0,"sigma_printed":7.54,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-KUSMOPRYMX","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":2},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.077142857},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.077},"sigma_reading":{"basis":"last_printed_digit","value":0.0007143},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":7.54},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-216.3842857,"value_printed":-1514.69,"value_stored":-216384.2857},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.074285714,"before":7.52,"evidence":{"divisor":7.0,"sigma_printed":7.52,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-NG7CE6ENUV","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":3},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.074285714},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.074},"sigma_reading":{"basis":"last_printed_digit","value":0.0007143},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":7.52},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-216.2228571,"value_printed":-1513.56,"value_stored":-216222.8571},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Cordfunke","kind":"unknown","label":"23","reference":"E.H.P. Cordfunke, R.J.M. Konings, Thermochemical Data for Reactor Materials and Fission Products, Elsevier Science Publishers B. V., Amsterdam, North-Holland, 1990.","status":"resolved","year":"1990"},{"first_author":"OHare","kind":"unknown","label":"32","reference":"P.A.G. O’Hare, H.R. Hoekstra, Thermochemistry of molybdates V. Standard enthaly of formation of cesium dimolybdate, J. Chem. Thermodyn. 7 (1975) 279–284.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.354545455,"before":14.9,"evidence":{"divisor":11.0,"sigma_printed":14.9,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-PSQWMPCE3S","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":5},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.354545455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.355},"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":14.9},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-209.3090909,"value_printed":-2302.4,"value_stored":-209309.0909},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.37,"before":15.07,"evidence":{"divisor":11.0,"sigma_printed":15.07,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-Z6R7MNZ43B","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":6},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.37},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.37},"sigma_reading":{"basis":"last_printed_digit","value":0.0004545},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":15.07},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-209.2581818,"value_printed":-2301.84,"value_stored":-209258.1818},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.409090909,"before":15.5,"evidence":{"divisor":11.0,"sigma_printed":15.5,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-ITFSKMKX4O","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":7},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.409090909},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.409},"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":15.5},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-209.2363636,"value_printed":-2301.6,"value_stored":-209236.3636},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.49,"before":22.35,"evidence":{"divisor":15.0,"sigma_printed":22.35,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-QUO36F2QIZ","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":9},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":15.0,"phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.49},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.49},"sigma_reading":{"basis":"last_printed_digit","value":0.0003333},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":22.35},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-205.1446667,"value_printed":-3077.17,"value_stored":-205144.6667},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.54,"before":23.1,"evidence":{"divisor":15.0,"sigma_printed":23.1,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-KLKDOJY7RQ","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":10},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":15.0,"phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.54},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.54},"sigma_reading":{"basis":"last_printed_digit","value":0.003333},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":23.1},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-205.04,"value_printed":-3075.6,"value_stored":-205040.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.619565217,"before":37.25,"evidence":{"divisor":23.0,"sigma_printed":37.25,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-65GEBSSIXG","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":12},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":23.0,"phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.619565217},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.62},"sigma_reading":{"basis":"last_printed_digit","value":0.002174},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":37.25},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-200.073913,"value_printed":-4601.7,"value_stored":-200073.913},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1021/acs.jced.0c00210","first_author":"Benigni","kind":"unknown","label":"34","paper":"doi:10.1021/acs.jced.0c00210","reference":"P. Benigni, G. Mikaelian, E. Ruiz, C. Perrin-Pellegrino, J. Rogez, Calorimetric determination of the formation enthalpies of Cs polymolybdates at 298.15 K and 0.1 MPa, J. Chem. Eng. Data 65 (8) (2020) 3875–3883.","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.682580645,"before":52.16,"evidence":{"divisor":31.0,"sigma_printed":52.16,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-OG46CHWRY7","locator":{"ref":"sha256:22fe4fa42e763c4f/p4/tab-3","row":13},"method":"solution calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":31.0,"phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p4/tab-3/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:cr, 298.15 K"},"MO":{"phase":"printed:cr, 298.15 K"},"O":{"phase":"printed:cr, 298.15 K"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.682580645},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.683},"sigma_reading":{"basis":"last_printed_digit","value":0.0001613},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":52.16},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-196.36,"value_printed":-6087.16,"value_stored":-196360.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-OIMQNJKWY5.e2faec","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:none"},"MO":{"phase":"printed:none"},"O":{"phase":"printed:none"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":10.84142857},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.007143},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-216.8285714,"value_printed":-1517.8,"value_stored":-216828.5714},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-OIMQNJKWY5.e7fbfd","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.767857143},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.007143},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":35.35714286,"value_printed":247.5},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":0.04285714286,"before":0.3,"evidence":{"divisor":7.0,"sigma_printed":0.3,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-CXQU6ADXNW","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.142857,"O":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":7.0,"phases":[{"label":"α-Cs2MoO4"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.04285714286},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.04286},"sigma_reading":{"basis":"last_printed_digit","value":0.0007143},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":0.3},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":35.47857143,"value_printed":248.35},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-OJNKBXOLZS.0f0578","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.434545455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":28.69090909,"value_printed":315.6},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-OJNKBXOLZS.247ce0","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:none"},"MO":{"phase":"printed:none"},"O":{"phase":"printed:none"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":10.46454545},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-209.2909091,"value_printed":-2302.2,"value_stored":-209290.9091},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":0.3909090909,"before":4.3,"evidence":{"divisor":11.0,"sigma_printed":4.3,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-XOTSA4CHXU","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.181818,"O":0.636364},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":11.0,"phases":[{"label":"α-Cs2Mo2O7"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":0.3909090909},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.3909},"sigma_reading":{"basis":"last_printed_digit","value":0.004545},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":4.3},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":28.85454545,"value_printed":317.4},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-GIHY2VBLH3.73f9b0","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":15.0,"phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.382666667},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.003333},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":27.65333333,"value_printed":414.8},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-GIHY2VBLH3.d1afbc","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.2,"O":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":15.0,"phases":[{"label":"Cs2Mo3O10"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:none"},"MO":{"phase":"printed:none"},"O":{"phase":"printed:none"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":10.2},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.003333},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-204.0,"value_printed":-3060.0,"value_stored":-204000.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-NVBN5ZONE2.6f9f7b","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":19.0,"phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.241052632},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.002632},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":24.82105263,"value_printed":471.6},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-NVBN5ZONE2.87e63d","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.210526,"O":0.684211},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":19.0,"phases":[{"label":"Cs2Mo4O13"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:none"},"MO":{"phase":"printed:none"},"O":{"phase":"printed:none"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":10.07263158},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.002632},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-201.4526316,"value_printed":-3827.6,"value_stored":-201452.6316},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-55N4K2ORKO.0484e7","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":23.0,"phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:none"},"MO":{"phase":"printed:none"},"O":{"phase":"printed:none"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":9.967826087},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.002174},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-199.3565217,"value_printed":-4585.2,"value_stored":-199356.5217},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-55N4K2ORKO.c9d025","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.217391,"O":0.695652},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":23.0,"phases":[{"label":"Cs2Mo5O16"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.176304348},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.002174},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":23.52608696,"value_printed":541.1},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-F4SW7LX7K6.2acd47","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":31.0,"phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"CS":{"phase":"printed:none"},"MO":{"phase":"printed:none"},"O":{"phase":"printed:none"}},"source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":9.82},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.001613},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ·mol−1","unit_stored":"J/mol-atom","value":-196.4,"value_printed":-6088.4,"value_stored":-196400.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-F4SW7LX7K6.f4d623","locator":{"ref":"sha256:22fe4fa42e763c4f/p7/tab-8","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"overall_composition":{"MO":0.225806,"O":0.709677},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","per_formula_unit_divisor":31.0,"phases":[{"label":"Cs2Mo7O22"}],"pid":"sha256:22fe4fa42e763c4f/p7/tab-8/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°m (298.15 K)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.108064516},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.001613},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J·K−1·mol−1","value":22.16129032,"value_printed":687.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β-Cs2Mo2O7","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-B5ZC3XRH6Q","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":12},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"α-Cs2MoO4","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"β-Cs2Mo2O7","model_phase_rejected":{"model_phase":"BCC_A2","reason":"greek_or_compound_label_mapped_to_element_structure"}}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = α-Cs2MoO4 + β-Cs2Mo2O7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":732.2,"temperature_printed":"732.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":732.2},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/0020-1650(73)80013-3","first_author":"Hoekstra","kind":"unknown","label":"25","paper":"doi:10.1016/0020-1650(73)80013-3","reference":"H.R. Hoekstra, Cs2MoO4-MoO3 system, Inorg. Nucl. Chem. Lett. 9 (1973) 1291–1301.","status":"resolved","year":"1973"},{"first_author":"Spitsyn","kind":"unknown","label":"26","reference":"V.I. Spitsyn, I.M. Kuleshov, J. Gen. Chem. USSR 21 (1951) 1493.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β-Cs2Mo2O7","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-XJY5LQSXMI","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":13},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"α-Cs2MoO4","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"β-Cs2Mo2O7","model_phase_rejected":{"model_phase":"BCC_A2","reason":"greek_or_compound_label_mapped_to_element_structure"}}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = α-Cs2MoO4 + β-Cs2Mo2O7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":731.0,"temperature_printed":"731","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":731.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Salmon","kind":"unknown","label":"29","reference":"R. Salmon, P. Caillet, Polymolybdates et polytungstates de rubidium ou de cesium anhydres, Bull. Soc. Chim. Fr. 5 (1969) 1569–1573.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β-Cs2Mo2O7","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-MC4BKZEEW4","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"α-Cs2MoO4","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"β-Cs2Mo2O7","model_phase_rejected":{"model_phase":"BCC_A2","reason":"greek_or_compound_label_mapped_to_element_structure"}}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = α-Cs2MoO4 + β-Cs2Mo2O7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":733.0,"temperature_printed":"733","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":733.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β-Cs2Mo2O7","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-6KJBCKFBH7","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":24},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"β-Cs2Mo2O7","model_phase_rejected":{"model_phase":"BCC_A2","reason":"greek_or_compound_label_mapped_to_element_structure"}},{"label":"Cs2Mo3O10"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = β-Cs2Mo2O7 + Cs2Mo3O10","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":732.5,"temperature_printed":"732.5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":732.5},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/0020-1650(73)80013-3","first_author":"Hoekstra","kind":"unknown","label":"25","paper":"doi:10.1016/0020-1650(73)80013-3","reference":"H.R. Hoekstra, Cs2MoO4-MoO3 system, Inorg. Nucl. Chem. Lett. 9 (1973) 1291–1301.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β-Cs2Mo2O7","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-7JLD2MTTBU","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":25},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"β-Cs2Mo2O7","model_phase_rejected":{"model_phase":"BCC_A2","reason":"greek_or_compound_label_mapped_to_element_structure"}},{"label":"Cs2Mo3O10"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = β-Cs2Mo2O7 + Cs2Mo3O10","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":736.0,"temperature_printed":"736","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":736.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Salmon","kind":"unknown","label":"29","reference":"R. Salmon, P. Caillet, Polymolybdates et polytungstates de rubidium ou de cesium anhydres, Bull. Soc. Chim. Fr. 5 (1969) 1569–1573.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β-Cs2Mo2O7","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-7D556JT4L6","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":26},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"β-Cs2Mo2O7","model_phase_rejected":{"model_phase":"BCC_A2","reason":"greek_or_compound_label_mapped_to_element_structure"}},{"label":"Cs2Mo3O10"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = β-Cs2Mo2O7 + Cs2Mo3O10","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":736.0,"temperature_printed":"736","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":736.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-7HGJSYS7QJ","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":32},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = Cs2Mo3O10 + Cs2Mo5O16","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":793.2,"temperature_printed":"793.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":793.2},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/0020-1650(73)80013-3","first_author":"Hoekstra","kind":"unknown","label":"25","paper":"doi:10.1016/0020-1650(73)80013-3","reference":"H.R. Hoekstra, Cs2MoO4-MoO3 system, Inorg. Nucl. Chem. Lett. 9 (1973) 1291–1301.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-KH7OONCYEH","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":33},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r33#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = Cs2Mo3O10 + Cs2Mo5O16","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":798.0,"temperature_printed":"798","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":798.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Spitsyn","kind":"unknown","label":"26","reference":"V.I. Spitsyn, I.M. Kuleshov, J. Gen. Chem. USSR 21 (1951) 1493.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-H4M6T572QY","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":34},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r34#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = Cs2Mo3O10 + Cs2Mo5O16","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":796.0,"temperature_printed":"796","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":796.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Salmon","kind":"unknown","label":"29","reference":"R. Salmon, P. Caillet, Polymolybdates et polytungstates de rubidium ou de cesium anhydres, Bull. Soc. Chim. Fr. 5 (1969) 1569–1573.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-3ONKAJZJNP","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":35},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Liq.","model_phase":"LIQUID"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r35#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq. = Cs2Mo3O10 + Cs2Mo5O16","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":792.0,"temperature_printed":"792","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":792.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-APXMVNZ4S3","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":36},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r36#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo4O13 = Cs2Mo3O10 + Cs2Mo5O16","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":783.9,"temperature_printed":"783.9","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":783.9},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/0020-1650(73)80013-3","first_author":"Hoekstra","kind":"unknown","label":"25","paper":"doi:10.1016/0020-1650(73)80013-3","reference":"H.R. Hoekstra, Cs2MoO4-MoO3 system, Inorg. Nucl. Chem. Lett. 9 (1973) 1291–1301.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-KSZL5J3NVV","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":37},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r37#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo4O13 = Cs2Mo3O10 + Cs2Mo5O16","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":776.0,"temperature_printed":"776","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":776.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Salmon","kind":"unknown","label":"29","reference":"R. Salmon, P. Caillet, Polymolybdates et polytungstates de rubidium ou de cesium anhydres, Bull. Soc. Chim. Fr. 5 (1969) 1569–1573.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-FIGTRF2HKT","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":38},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r38#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo4O13 = Cs2Mo3O10 + Cs2Mo5O16","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":797.0,"temperature_printed":"797","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":797.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-HARO5QORDA","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":39},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r39#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo4O13 = Cs2Mo3O10 + Cs2Mo5O16","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":781.0,"temperature_printed":"781 ± 10 b","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":781.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-PAWX6A2GJF","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":40},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo4O13"},{"label":"Cs2Mo3O10"},{"label":"Cs2Mo5O16"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r40#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo4O13 = Cs2Mo3O10 + Cs2Mo5O16","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":787.0,"temperature_printed":"787 ± 10 b","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":787.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZAWDONUCWQ","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":41},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"},{"label":"Cs2Mo7O22"},{"label":"Liq.","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r41#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo5O16 = Cs2Mo7O22 + Liq.","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":808.7,"temperature_printed":"808.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":808.7},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-ID32CS2HDB","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":42},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"},{"label":"Cs2Mo7O22"},{"label":"Liq.","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r42#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo5O16 = Cs2Mo7O22 + Liq.","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":810.0,"temperature_max_K":813.0,"temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":810.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/0020-1650(73)80013-3","first_author":"Hoekstra","kind":"unknown","label":"25","paper":"doi:10.1016/0020-1650(73)80013-3","reference":"H.R. Hoekstra, Cs2MoO4-MoO3 system, Inorg. Nucl. Chem. Lett. 9 (1973) 1291–1301.","status":"resolved","year":"1973"},{"first_author":"Spitsyn","kind":"unknown","label":"26","reference":"V.I. Spitsyn, I.M. Kuleshov, J. Gen. Chem. USSR 21 (1951) 1493.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-LC4DURYLTC","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":43},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"},{"label":"Cs2Mo7O22"},{"label":"Liq.","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r43#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo5O16 = Cs2Mo7O22 + Liq.","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":823.0,"temperature_printed":"823","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":823.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Salmon","kind":"unknown","label":"29","reference":"R. Salmon, P. Caillet, Polymolybdates et polytungstates de rubidium ou de cesium anhydres, Bull. Soc. Chim. Fr. 5 (1969) 1569–1573.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-RP34HYG22S","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":44},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"},{"label":"Cs2Mo7O22"},{"label":"Liq.","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r44#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo5O16 = Cs2Mo7O22 + Liq.","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":818.0,"temperature_printed":"818","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":818.0},{"chemical_system":"CS-MO-O","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-4G3VK5H633","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":45},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"},{"label":"MoO3","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"Liq","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r45#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo7O22 = MoO3 + Liq","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":836.2,"temperature_printed":"836.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":836.2},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-5SZJMA2EXP","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":46},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"},{"label":"MoO3","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"Liq","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r46#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo7O22 = MoO3 + Liq","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":835.0,"temperature_max_K":836.0,"temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":835.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Spitsyn","kind":"unknown","label":"26","reference":"V.I. Spitsyn, I.M. Kuleshov, J. Gen. Chem. USSR 21 (1951) 1493.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-36FJRGBUZS","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":47},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"},{"label":"MoO3","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"Liq","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r47#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo7O22 = MoO3 + Liq","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":848.0,"temperature_printed":"848","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":848.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/0020-1650(73)80013-3","first_author":"Hoekstra","kind":"unknown","label":"25","paper":"doi:10.1016/0020-1650(73)80013-3","reference":"H.R. Hoekstra, Cs2MoO4-MoO3 system, Inorg. Nucl. Chem. Lett. 9 (1973) 1291–1301.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-FDDXIRNBHK","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":48},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"},{"label":"MoO3","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"Liq","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r48#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo7O22 = MoO3 + Liq","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":846.0,"temperature_printed":"846","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":846.0},{"chemical_system":"CS-MO-O","cited_sources":[{"first_author":"Salmon","kind":"unknown","label":"29","reference":"R. Salmon, P. Caillet, Polymolybdates et polytungstates de rubidium ou de cesium anhydres, Bull. Soc. Chim. Fr. 5 (1969) 1569–1573.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-VDFWVM4VHW","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":49},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"},{"label":"MoO3","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"Liq","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r49#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo7O22 = MoO3 + Liq","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":837.0,"temperature_printed":"837","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":837.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-KYDIQBRWBR","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":52},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo5O16"},{"label":"Cs2Mo7O22"},{"label":"Liq.","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r52#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo5O16 = Cs2Mo7O22 + Liq.","type":"peritectic"},"reader_agreement":"single_reader_text_layer","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":813.0,"temperature_printed":"810a/813b ± 5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":813.0},{"chemical_system":"CS-MO-O","cited_sources":[{"doi":"10.1016/j.tca.2020.178825","first_author":"Smith","kind":"unknown","label":"17","paper":"doi:10.1016/j.tca.2020.178825","reference":"A.L. Smith, J. Vlieland, M.-C. Pignié, M. Abbink, G. Mikaelian, P. Benigni, New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system, Thermochim. Acta 696 (2021) 178825.","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-4SSVLZQH6Y","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/tab-7","row":53},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","phases":[{"label":"Cs2Mo7O22"},{"label":"MoO3","model_phase":"MOO3","pearson_symbol":"oP16","prototype":"alpha-MoO3","structure_basis":"mapped_model_phase"},{"label":"Liq","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2021.102350/p7/tab-7/r53#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cs2Mo7O22 = MoO3 + Liq","type":"peritectic"},"reader_agreement":"single_reader_text_layer","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"invariant_table","source_system":"CS-MO-O","system":"CS-MO-O","temperature_K":836.0,"temperature_printed":"835a/836b ± 5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":836.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CS-MO-O"}