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[17] (i.e. 725 ± 5 K), and the data of Hoekstra [25] (737 K), Salmon and Caillet [29] (749 K), and Spitsyn and Kuleshov [26] (767 K).","quote_page":7,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CS-MO","system":"CS-MO","temperature_K":732.5,"temperature_printed":"732.5 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":732.5},{"chemical_system":"CS-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WMXCSB3TZ7","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p7/text-35"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","pid":"doi:10.1016/j.calphad.2021.102350/p7/text-35/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The congruent melting of Cs2 Mo3 O10 is calculated at 812.3 K, which is again in between the data of Smith et al. [17] (i.e. 806 ± 5 K) and that of Hoekstra [25] (820 K), Salmon and Caillet [29] (823 K), and Spitsyn and Kuleshov [26] (818 K).","quote_page":7,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CS-MO","system":"CS-MO","temperature_K":812.3,"temperature_printed":"812.3 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 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[17] selected for the optimization.","quote_page":8,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CS-MO","system":"CS-MO","temperature_K":836.2,"temperature_printed":"836.2 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":836.2},{"chemical_system":"CS-MO","citations_printed":["17"],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-FBXBAYYP62.89a942","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2021.102350/p8/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2021.102350","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2021.102350","paper_id":"doi:10.1016/j.calphad.2021.102350","pid":"doi:10.1016/j.calphad.2021.102350/p8/text-04/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Finally, the calculated peritectic decompositions of Cs2 Mo5 O16 and Cs2 Mo7 O22 (i.e. 808.7 K and 836.2 K, respectively) are in very good agreement with the data of Smith et al. 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