{"artifacts":{"doi:10.1016/j.calphad.2009.04.001/p1/text-21":{"artifact":"text_passage","label":"page 1, passage 21","page":1},"doi:10.1016/j.calphad.2009.04.001/p2/tab-1":{"artifact":"table","caption":"Crystalline structures, lattice parameters and atomic positions of Cu–Dy intermetallic compounds. Results from first principles calculations are also reported.","label":"1","page":2},"doi:10.1016/j.calphad.2009.04.001/p5/tab-3":{"artifact":"table","caption":"Calculated and experimental invariant reactions for the Cu–Dy system.","label":"3","page":5},"doi:10.1016/j.jallcom.2008.03.007/p2/text-16":{"artifact":"text_passage","label":"page 2, passage 16","page":2},"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3":{"artifact":"table","caption":"Invariant reactions in the Cu–Dy system","label":"3","page":3},"sha256:ad0bb5fd8807b797/p4/tab-2":{"artifact":"table","caption":"Comparison between experimental and ab initio values (calculated with both GGA and PBE potentials) for the enthalpy of formation for some Cu–RE compounds.","label":"2","page":4}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["CU","DY"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M008e26a7":{"catalog_entry":{"license":"CC BY 4.0","name":"CuDy-09Zha.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Alloys Compd., 470, 214-17(2009).","model_doi":"10.1016/j.jallcom.2008.03.007","reproduced_by_calculation":false,"tdb":"CuDy-09Zha.tdb","tdb_path":"databases/sgte-binary/CuDy-09Zha.tdb","tdb_sha256":"6c6f9d652328ae39e78168af5c1d977a941f960619e30791dd2d5145706d0513"},"M89337928":{"catalog_entry":{"license":"CC BY 4.0","name":"CuDy-09Zha.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Alloys Compd., 470, 214-17(2009).","model_doi":"10.1016/j.jallcom.2008.03.007","reproduced_by_calculation":true,"tdb":"CuDy-09Zha.tdb","tdb_path":"databases/sgte-binary/CuDy-09Zha.tdb","tdb_sha256":"6c6f9d652328ae39e78168af5c1d977a941f960619e30791dd2d5145706d0513"},"Mcc0d57d6":{"catalog_entry":{"license":"CC BY 4.0","name":"CuDy-09Pal.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Calphad, 33, 511-16(2009).","model_doi":"10.1016/j.calphad.2009.04.001","reproduced_by_calculation":false,"tdb":"CuDy-09Pal.tdb","tdb_path":"databases/sgte-binary/CuDy-09Pal.tdb","tdb_sha256":"12983d67968493e1939437762ceab1854ecc9793431c3041baeb645535d8ede2"},"Mde8ca388":{"catalog_entry":{"license":"CC BY 4.0","name":"CuDy-09Pal.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Calphad, 33, 511-16(2009).","model_doi":"10.1016/j.calphad.2009.04.001","reproduced_by_calculation":true,"tdb":"CuDy-09Pal.tdb","tdb_path":"databases/sgte-binary/CuDy-09Pal.tdb","tdb_sha256":"12983d67968493e1939437762ceab1854ecc9793431c3041baeb645535d8ede2"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0022-5088(69)90189-1":{"authors":["K.H.J. Buschow","A.S. Van Der Goot","J. Birkhan"],"citation":"K.H.J. Buschow, A.S. Van Der Goot, J. Birkhan, Rare-earth copper compounds with AuBe5 structure, Journal of the Less Common Metals 19, 433-436 (1969).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(69)90189-1","doi_url":"https://doi.org/10.1016/0022-5088(69)90189-1","id":"doi:10.1016/0022-5088(69)90189-1","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Rare-earth copper compounds with AuBe5 structure","year":1969},"doi:10.1016/0022-5088(82)90092-3":{"authors":["Enrico Franceschi"],"citation":"Enrico Franceschi, On the Dy-Cu system, Journal of the Less Common Metals 87, 249-256 (1982).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(82)90092-3","doi_url":"https://doi.org/10.1016/0022-5088(82)90092-3","id":"doi:10.1016/0022-5088(82)90092-3","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"On the Dy-Cu system","year":1982},"doi:10.1016/0022-5088(83)90235-7":{"authors":["M.M. Carnasciali","S. Cirafici","E. Franceschi"],"citation":"M.M. Carnasciali, S. Cirafici, E. Franceschi, On the Gd-Cu system, Journal of the Less Common Metals 92, 143-147 (1983).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(83)90235-7","doi_url":"https://doi.org/10.1016/0022-5088(83)90235-7","id":"doi:10.1016/0022-5088(83)90235-7","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"On the Gd-Cu system","year":1983},"doi:10.1016/0038-1098(71)90407-8":{"authors":["M. Belakhovsky","J. Pierre"],"citation":"M. Belakhovsky, J. Pierre, Mössbauer study of dysprosium equiatomic compounds with copper, silver, zinc and rhodium, Solid State Communications 9, 1409-1415 (1971).","container":"Solid State Communications","doi":"10.1016/0038-1098(71)90407-8","doi_url":"https://doi.org/10.1016/0038-1098(71)90407-8","id":"doi:10.1016/0038-1098(71)90407-8","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Mössbauer study of dysprosium equiatomic compounds with copper, silver, zinc and rhodium","year":1971},"doi:10.1016/j.calphad.2009.04.001":{"authors":["M. Palumbo","L. Battezzati","A. Pasturel","S. Gottlieb-Schönmeyer","W. Assmus"],"citation":"M. Palumbo, L. Battezzati, A. Pasturel, S. Gottlieb-Schönmeyer, W. Assmus, Thermodynamic and ab initio investigation of the Cu–Dy system, Calphad 33, 511-516 (2009).","container":"Calphad","doi":"10.1016/j.calphad.2009.04.001","doi_url":"https://doi.org/10.1016/j.calphad.2009.04.001","id":"doi:10.1016/j.calphad.2009.04.001","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"ad0bb5fd8807b797","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic and ab initio investigation of the Cu–Dy system","year":2009},"doi:10.1016/j.jallcom.2004.08.062":{"authors":["S.V. Meschel","O.J. Kleppa"],"citation":"S.V. Meschel, O.J. Kleppa, Thermochemistry of some binary alloys of copper with the lanthanide metals by high-temperature direct synthesis calorimetry, Journal of Alloys and Compounds 388, 91-97 (2005).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2004.08.062","doi_url":"https://doi.org/10.1016/j.jallcom.2004.08.062","id":"doi:10.1016/j.jallcom.2004.08.062","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermochemistry of some binary alloys of copper with the lanthanide metals by high-temperature direct synthesis calorimetry","year":2005},"doi:10.1016/j.jallcom.2008.03.007":{"authors":["L.G. Zhang","G.X. Huang","H.Y. Qi","B.R. Jia","L.B. Liu","Z.P. Jin"],"citation":"L.G. Zhang, G.X. Huang, H.Y. Qi, B.R. Jia, L.B. Liu, Z.P. Jin, Thermodynamic assessment of the Cu–Dy binary system, Journal of Alloys and Compounds 470, 214-217 (2009).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2008.03.007","doi_url":"https://doi.org/10.1016/j.jallcom.2008.03.007","id":"doi:10.1016/j.jallcom.2008.03.007","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"0d195493423dfe7a","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Cu–Dy binary system","year":2009},"doi:10.1016/s0022-4596(03)00187-7":{"authors":["R. Černý","L. Guénée","R. Wessicken"],"citation":"R. Černý, L. Guénée, R. Wessicken, A single crystal X-ray and HRTEM study of new series of compounds DyCux (x=4.5, 4 and 3.5), Journal of Solid State Chemistry 174, 125-131 (2003).","container":"Journal of Solid State Chemistry","doi":"10.1016/s0022-4596(03)00187-7","doi_url":"https://doi.org/10.1016/s0022-4596(03)00187-7","id":"doi:10.1016/s0022-4596(03)00187-7","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"A single crystal X-ray and HRTEM study of new series of compounds DyCux (x=4.5, 4 and 3.5)","year":2003},"doi:10.1063/1.1713089":{"authors":["C. C. Chao","H. L. Luo","P. Duwez"],"citation":"C. C. Chao, H. L. Luo, P. Duwez, CsCl-Type Compounds in Binary Alloys of Rare-Earth Metals with Zinc and Copper, Journal of Applied Physics 35, 257-258 (1964).","container":"Journal of Applied Physics","doi":"10.1063/1.1713089","doi_url":"https://doi.org/10.1063/1.1713089","id":"doi:10.1063/1.1713089","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"CsCl-Type Compounds in Binary Alloys of Rare-Earth Metals with Zinc and Copper","year":1964},"doi:10.1107/s0365110x6100276x":{"authors":["N. C. Baenziger","J. L. Moriarty"],"citation":"N. C. Baenziger, J. L. Moriarty, Gadolinium and dyprosium intermetallic phases. II. Laves phases and other structure types, Acta Cryst 14, 948-950 (1961).","container":"Acta Cryst","doi":"10.1107/s0365110x6100276x","doi_url":"https://doi.org/10.1107/s0365110x6100276x","id":"doi:10.1107/s0365110x6100276x","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Gadolinium and dyprosium intermetallic phases. II. Laves phases and other structure types","year":1961},"doi:10.1107/s0365110x6300181x":{"authors":["A. R. Storm","K. E. Benson"],"citation":"A. R. Storm, K. E. Benson, Lanthanide–copper intermetallic compounds having the CeCu<sub>2</sub>and AlB<sub>2</sub>structure, Acta Cryst 16, 701-702 (1963).","container":"Acta Cryst","doi":"10.1107/s0365110x6300181x","doi_url":"https://doi.org/10.1107/s0365110x6300181x","id":"doi:10.1107/s0365110x6300181x","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Lanthanide–copper intermetallic compounds having the CeCu<sub>2</sub>and AlB<sub>2</sub>structure","year":1963},"doi:10.1107/s0567740871003558":{"authors":["K. H. J. Buschow","A. S. van der Goot"],"citation":"K. H. J. Buschow, A. S. van der Goot, Composition and crystal structure of hexagonal Cu-rich rare earth–copper compounds, Acta Crystallogr B Struct Crystallogr Cryst Chem 27, 1085-1088 (1971).","container":"Acta Crystallogr B Struct Crystallogr Cryst Chem","doi":"10.1107/s0567740871003558","doi_url":"https://doi.org/10.1107/s0567740871003558","id":"doi:10.1107/s0567740871003558","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Composition and crystal structure of hexagonal Cu-rich rare earth–copper compounds","year":1971},"ref:2bc6c2ad198c257f":{"citation":"M. Copeland, H. Kato, Physics and Materials Problems of Reactor Control Rods, International Atomic Energy Agency, Vienna, Austria, 1964, pp. 295–317.","id":"ref:2bc6c2ad198c257f","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1964},"ref:55cba08bc9b661d6":{"citation":"C.S. Cheng, G.X. Xu, Acta Phys. Sinica 31 (1982) 807–809.","id":"ref:55cba08bc9b661d6","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1982}},"part":1,"parts":1,"records":[{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1107/s0567740871003558","first_author":"Buschow","kind":"unknown","label":"15","paper":"doi:10.1107/s0567740871003558","reference":"K.H.J. Buschow, A.S. van der Goot, Acta Crystallogr. B 27 (6) (1971) 1085.","status":"resolved","year":"1971"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-372GGS5C7Z.0bcebb","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu7Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP8","prototype":"Cu7Tb"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01085,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01085},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.932,"value_stored":0.4932},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1107/s0567740871003558","first_author":"Buschow","kind":"unknown","label":"15","paper":"doi:10.1107/s0567740871003558","reference":"K.H.J. Buschow, A.S. van der Goot, Acta Crystallogr. B 27 (6) (1971) 1085.","status":"resolved","year":"1971"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-372GGS5C7Z.4dab3e","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu7Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP8","prototype":"Cu7Tb"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009143,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009143},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.156,"value_stored":0.4156},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-ANK3JUAYDR.8d8bdf","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu7Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP8","prototype":"Cu7Tb","space_group_number":191},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04922,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04922},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.922,"value_stored":0.4922},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-ANK3JUAYDR.f867ac","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu7Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP8","prototype":"Cu7Tb","space_group_number":191},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04148,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04148},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.148,"value_stored":0.4148},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(69)90189-1","first_author":"Buschow","kind":"unknown","label":"16","paper":"doi:10.1016/0022-5088(69)90189-1","reference":"K.H.J. Buschow, A.S. van der Goot, J. Birkhan, J. Less-Common Met. 19 (1969) 433.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-XES5QQ6JRI","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"α-Cu5Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cF24","prototype":"AuBe5"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01546,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01546},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.027,"value_stored":0.7027},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"cF24","phase":"α-Cu5Dy","prototype":"AuBe5"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"α-Cu5Dy | cF24 (AuBe5) | F43m (no. 216) | 0.7027 [16]; 0.7022 [8]; 0.70058 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[4],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"α-Cu5Dy merged cell over three rows; space group printed without overbar, kept as printed","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-BRRXI2EJVV","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"α-Cu5Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cF24","phase":"α-Cu5Dy","prototype":"AuBe5"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01545,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01545},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.022,"value_stored":0.7022},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-FTDBTYFX36","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"α-Cu5Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cF24","prototype":"AuBe5","space_group_number":216},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07006,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07006},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.0058,"value_stored":0.70058},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(83)90235-7","first_author":"Carnasciali","kind":"unknown","label":"11","paper":"doi:10.1016/0022-5088(83)90235-7","reference":"M.M. Carnasciali, G.A. Costa, E.A. Franceschi, J. Less-Common Met. 92 (1983) 143.","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-CJCVAJCDHS.12e477","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"β-Cu5Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP6","prototype":"CaCu5"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008976,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008976},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.08,"value_stored":0.408},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(83)90235-7","first_author":"Carnasciali","kind":"unknown","label":"11","paper":"doi:10.1016/0022-5088(83)90235-7","reference":"M.M. Carnasciali, G.A. Costa, E.A. Franceschi, J. Less-Common Met. 92 (1983) 143.","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-CJCVAJCDHS.785cd8","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"β-Cu5Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP6","prototype":"CaCu5"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01104,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01104},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.02,"value_stored":0.502},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-AE37GNTMMQ.0e89f4","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"β-Cu5Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP6","prototype":"CaCu5","space_group_number":191},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04984,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04984},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.9839,"value_stored":0.49839},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-AE37GNTMMQ.54c050","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"β-Cu5Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"hP6","prototype":"CaCu5","space_group_number":191},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04094,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04094},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0939,"value_stored":0.40939},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-LPTHP32CQ6.2b30c3","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.2},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu4Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"space_group":"P1"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06239,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.06239},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":28.36,"value_stored":2.836},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-LPTHP32CQ6.b60767","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.2},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu4Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"space_group":"P1"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06241,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.06241},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":28.37,"value_stored":2.837},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-LPTHP32CQ6.f7dda7","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.2},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu4Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"space_group":"P1"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05645,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.05645},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":25.658,"value_stored":2.5658},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"},{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-6TQBDUHFYN.89043d","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.181818},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu9Dy2"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"mC7448","space_group":"C2"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.109,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.109},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":49.55,"value_stored":4.955},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"},{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-6TQBDUHFYN.b64b21","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.181818},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu9Dy2"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"mC7448","space_group":"C2"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1019,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.1019},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":46.33,"value_stored":4.633},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"},{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-6TQBDUHFYN.f5bd12","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.181818},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu9Dy2"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"mC7448","space_group":"C2"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.109,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.109},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":49.56,"value_stored":4.956},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-QH5UTC666I.0093f0","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu7Dy2"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"mC7448","space_group":"P1"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04684,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04684},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.29,"value_stored":2.129},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-QH5UTC666I.773d7d","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu7Dy2"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"mC7448","space_group":"P1"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0416,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0416},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":18.91,"value_stored":1.891},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/s0022-4596(03)00187-7","first_author":"Cerny","kind":"unknown","label":"3","paper":"doi:10.1016/s0022-4596(03)00187-7","reference":"R. Černý, L. Guénée, R. Wessicken, J. Solid State Chem. 174 (2003) 125.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-QH5UTC666I.fc36b0","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu7Dy2"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"mC7448","space_group":"P1"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04693,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04693},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.33,"value_stored":2.133},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1107/s0365110x6300181x","first_author":"Storm","kind":"unknown","label":"32","paper":"doi:10.1107/s0365110x6300181x","reference":"A.R. Storm, K.E. Benson, Acta Crystallogr. 16 (1963) 701.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-JH6NZ2IVV6.181675","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","prototype":"CeCu2"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01494,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01494},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.792,"value_stored":0.6792},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1107/s0365110x6300181x","first_author":"Storm","kind":"unknown","label":"32","paper":"doi:10.1107/s0365110x6300181x","reference":"A.R. Storm, K.E. Benson, Acta Crystallogr. 16 (1963) 701.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-JH6NZ2IVV6.2a9a7d","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","prototype":"CeCu2"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01606},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.3,"value_stored":0.73},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1107/s0365110x6300181x","first_author":"Storm","kind":"unknown","label":"32","paper":"doi:10.1107/s0365110x6300181x","reference":"A.R. Storm, K.E. Benson, Acta Crystallogr. 16 (1963) 701.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-JH6NZ2IVV6.a0b896","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","prototype":"CeCu2"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00946},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3,"value_stored":0.43},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"oI12","phase":"Cu2Dy","prototype":"CeCu2","space_group":"Imma"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"Cu2Dy | oI12 (CeCu2) | Imma (no.74) | rows 0.43 0.6792 0.73 [32]; 0.4303 0.6802 0.7289 [8]; 0.42488 0.6767 0.7281 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"Cu2Dy label centred over the rows from 0.43 to 0.42488, below the Cu7Dy2 row (2.133 2.129 1.891); the Cu2Dy-like values (oI12 cell) confirm the boundary","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-RIOJQYZNND.3ae87d","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","phase":"Cu2Dy","prototype":"CeCu2","space_group":"Imma"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01604,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01604},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.289,"value_stored":0.7289},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"oI12","phase":"Cu2Dy","prototype":"CeCu2","space_group":"Imma"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"Cu2Dy | oI12 (CeCu2) | Imma (no.74) | rows 0.43 0.6792 0.73 [32]; 0.4303 0.6802 0.7289 [8]; 0.42488 0.6767 0.7281 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"Cu2Dy label centred over the rows from 0.43 to 0.42488, below the Cu7Dy2 row (2.133 2.129 1.891); the Cu2Dy-like values (oI12 cell) confirm the boundary","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-RIOJQYZNND.65d8d4","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","phase":"Cu2Dy","prototype":"CeCu2","space_group":"Imma"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009467,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009467},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.303,"value_stored":0.4303},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"oI12","phase":"Cu2Dy","prototype":"CeCu2","space_group":"Imma"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"Cu2Dy | oI12 (CeCu2) | Imma (no.74) | rows 0.43 0.6792 0.73 [32]; 0.4303 0.6802 0.7289 [8]; 0.42488 0.6767 0.7281 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"Cu2Dy label centred over the rows from 0.43 to 0.42488, below the Cu7Dy2 row (2.133 2.129 1.891); the Cu2Dy-like values (oI12 cell) confirm the boundary","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-RIOJQYZNND.b2aff9","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","phase":"Cu2Dy","prototype":"CeCu2","space_group":"Imma"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01496,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01496},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.802,"value_stored":0.6802},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-RNO2BJI3JZ.1372e3","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","prototype":"CeCu2","space_group_number":74},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06767,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06767},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.767,"value_stored":0.6767},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-RNO2BJI3JZ.9b0d5b","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","prototype":"CeCu2","space_group_number":74},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07281,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07281},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.281,"value_stored":0.7281},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-RNO2BJI3JZ.d28ea7","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oI12","prototype":"CeCu2","space_group_number":74},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04249,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04249},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.2488,"value_stored":0.42488},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1107/s0365110x6100276x","first_author":"Baenziger","kind":"unknown","label":"33","paper":"doi:10.1107/s0365110x6100276x","reference":"N.C. Baenziger, J.L. Moriarty Jr., Acta Crystallogr. 14 (1961) 948.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"before":{"pearson_symbol":"cP2","prototype":"CsCl"},"evidence":{"class":"phase","decision_file":"phase_t184.json","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | cP2 (CsCl) | Pm3m (no.221) | 0.3461 [33] ... 0.34789 Ab initio; this work","rationale":"Same merged structure cell as the EXCL siblings r18-r22 (patched with cP2/CsCl); without it these two CuDy records cannot be told apart from the oP8 CuDy.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t184"},"field":"structure","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"077e1c161561622e4562ed645a8d0adf578015dfae348567bc5a0ad444ddaf93","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"r17 a 0.3461 [33] (first row) and r24 a 0.34789 (Ab initio, last row) lie inside the CsCl-type CuDy merged cell, like the already-patched r18-r22.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-KM54O27532","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007614,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007614},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.461,"value_stored":0.3461},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1063/1.1713089","first_author":"Chao","kind":"unknown","label":"34","paper":"doi:10.1063/1.1713089","reference":"C.C. Chao, H.L. Luo, P. Duwez, J. Appl. Phys. 35 (1964) 257.","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | cP2 (CsCl) | Pm3m (no.221) | 0.3461 [33], 0.346 [34], 0.3444 [35], 0.3461 [36], 0.3455 [37], 0.3455 [8], 0.34789 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[18,19,20,21,22],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"CuDy (CsCl) merged cell over seven rows, ends before CuDy oP8 (BFe) row; space group printed without overbar","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-3A7NX5URD7","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":18},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007612,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007612},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.46,"value_stored":0.346},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Pierre","kind":"unknown","label":"35","reference":"J. Pierre, R. Pauthenet, C.R. Hebd. Seances Acad. Sci. 260 (1965) 2739.","status":"resolved","year":"1965"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | cP2 (CsCl) | Pm3m (no.221) | 0.3461 [33], 0.346 [34], 0.3444 [35], 0.3461 [36], 0.3455 [37], 0.3455 [8], 0.34789 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[18,19,20,21,22],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"CuDy (CsCl) merged cell over seven rows, ends before CuDy oP8 (BFe) row; space group printed without overbar","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-WOABP2V7KP","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":19},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007577,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007577},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.444,"value_stored":0.3444},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Dwight","kind":"unknown","label":"36","reference":"A.E. Dwight, R.A. Conner Jr., J.W. Downey, in: Proc. 5th Rare Earth Res. Conf. Aug. 30–Sept. 1, 1965, Ames, LA, vol. 5, 1965, p. 35.","status":"resolved","year":"1965"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | cP2 (CsCl) | Pm3m (no.221) | 0.3461 [33], 0.346 [34], 0.3444 [35], 0.3461 [36], 0.3455 [37], 0.3455 [8], 0.34789 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[18,19,20,21,22],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"CuDy (CsCl) merged cell over seven rows, ends before CuDy oP8 (BFe) row; space group printed without overbar","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-3MPKHKP6S5","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":20},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007614,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007614},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.461,"value_stored":0.3461},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0038-1098(71)90407-8","first_author":"Belakhovsky","kind":"unknown","label":"37","paper":"doi:10.1016/0038-1098(71)90407-8","reference":"M. Belakhovsky, J. Pierre, Solid State Commun. 9 (1971) 1409.","status":"resolved","year":"1971"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | cP2 (CsCl) | Pm3m (no.221) | 0.3461 [33], 0.346 [34], 0.3444 [35], 0.3461 [36], 0.3455 [37], 0.3455 [8], 0.34789 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[18,19,20,21,22],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"CuDy (CsCl) merged cell over seven rows, ends before CuDy oP8 (BFe) row; space group printed without overbar","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-GADGBGBHC7","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":21},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007601,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007601},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.455,"value_stored":0.3455},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | cP2 (CsCl) | Pm3m (no.221) | 0.3461 [33], 0.346 [34], 0.3444 [35], 0.3461 [36], 0.3455 [37], 0.3455 [8], 0.34789 Ab initio","rationale":"Printed table context for this group supplies pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[18,19,20,21,22],"table":"1","table_key":"t184"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"385cce6b14c78888489ba05f6d6e3d36bb428ccbdd1e7255b31d6d2ad772e0b4","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"CuDy (CsCl) merged cell over seven rows, ends before CuDy oP8 (BFe) row; space group printed without overbar","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-KHAYXZGJ7P","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":22},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"system":"CU-DY","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007601,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007601},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.455,"value_stored":0.3455},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"before":{"pearson_symbol":"cP2","prototype":"CsCl","space_group_number":221},"evidence":{"class":"phase","decision_file":"phase_t184.json","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | cP2 (CsCl) | Pm3m (no.221) | 0.3461 [33] ... 0.34789 Ab initio; this work","rationale":"Same merged structure cell as the EXCL siblings r18-r22 (patched with cP2/CsCl); without it these two CuDy records cannot be told apart from the oP8 CuDy.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t184"},"field":"structure","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"077e1c161561622e4562ed645a8d0adf578015dfae348567bc5a0ad444ddaf93","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"r17 a 0.3461 [33] (first row) and r24 a 0.34789 (Ab initio, last row) lie inside the CsCl-type CuDy merged cell, like the already-patched r18-r22.","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"id":"ORC-AHBCEQBABB","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":24},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"cP2","phase":"CuDy","prototype":"CsCl"},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03479,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.03479},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.4789,"value_stored":0.34789},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"pearson_symbol":"oP8","phase":"CuDy","prototype":"BFe","space_group":"Pnma"},"before":{"pearson_symbol":"oP8","prototype":"BFe","space_group_number":62},"evidence":{"class":"phase","decision_file":"phase_t184.json","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | oP8 (BFe) | Pnma (no.62) | 0.7087 | 0.4449 | 0.5346 | −27.1 | Ab initio; this work","rationale":"The printed phase name is 'CuDy' for both rows, so the label stays as printed; the printed structure (oP8, BFe, Pnma) is what distinguishes this ab initio orthorhombic CuDy from CsCl-type CuDy. Structure in the batch convention {phase, pearson_symbol, prototype} plus the clean space group.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t184"},"field":"structure","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"077e1c161561622e4562ed645a8d0adf578015dfae348567bc5a0ad444ddaf93","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"Last table row, own Phase/Pearson/space-group cells; r25 a 0.7087 b 0.4449 c 0.5346.","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Label 'CuDy' is shared with the CsCl-type phase; ab initio 0 K value of a (possibly hypothetical) BFe-type structure; consumers must use structure to tell the two apart.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-6TVNZJ264B.1abeca","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oP8","phase":"CuDy","prototype":"BFe","space_group":"Pnma"},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07087,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07087},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.087,"value_stored":0.7087},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"pearson_symbol":"oP8","phase":"CuDy","prototype":"BFe","space_group":"Pnma"},"before":{"pearson_symbol":"oP8","prototype":"BFe","space_group_number":62},"evidence":{"class":"phase","decision_file":"phase_t184.json","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | oP8 (BFe) | Pnma (no.62) | 0.7087 | 0.4449 | 0.5346 | −27.1 | Ab initio; this work","rationale":"The printed phase name is 'CuDy' for both rows, so the label stays as printed; the printed structure (oP8, BFe, Pnma) is what distinguishes this ab initio orthorhombic CuDy from CsCl-type CuDy. Structure in the batch convention {phase, pearson_symbol, prototype} plus the clean space group.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t184"},"field":"structure","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"077e1c161561622e4562ed645a8d0adf578015dfae348567bc5a0ad444ddaf93","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"Last table row, own Phase/Pearson/space-group cells; r25 a 0.7087 b 0.4449 c 0.5346.","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Label 'CuDy' is shared with the CsCl-type phase; ab initio 0 K value of a (possibly hypothetical) BFe-type structure; consumers must use structure to tell the two apart.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-6TVNZJ264B.8b8569","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oP8","phase":"CuDy","prototype":"BFe","space_group":"Pnma"},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05346,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.05346},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.346,"value_stored":0.5346},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"pearson_symbol":"oP8","phase":"CuDy","prototype":"BFe","space_group":"Pnma"},"before":{"pearson_symbol":"oP8","prototype":"BFe","space_group_number":62},"evidence":{"class":"phase","decision_file":"phase_t184.json","doi":"10.1016/j.calphad.2009.04.001","pdf_page":2,"pdf_sha256":"ad0bb5fd8807b797ce794a4cd45dcce006dce0d701305202db9ae1f605e1ee50","printed":"CuDy | oP8 (BFe) | Pnma (no.62) | 0.7087 | 0.4449 | 0.5346 | −27.1 | Ab initio; this work","rationale":"The printed phase name is 'CuDy' for both rows, so the label stays as printed; the printed structure (oP8, BFe, Pnma) is what distinguishes this ab initio orthorhombic CuDy from CsCl-type CuDy. Structure in the batch convention {phase, pearson_symbol, prototype} plus the clean space group.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t184"},"field":"structure","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"077e1c161561622e4562ed645a8d0adf578015dfae348567bc5a0ad444ddaf93","page":2,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"Last table row, own Phase/Pearson/space-group cells; r25 a 0.7087 b 0.4449 c 0.5346.","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Label 'CuDy' is shared with the CsCl-type phase; ab initio 0 K value of a (possibly hypothetical) BFe-type structure; consumers must use structure to tell the two apart.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-6TVNZJ264B.97317f","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-DY","structure":{"pearson_symbol":"oP8","phase":"CuDy","prototype":"BFe","space_group":"Pnma"},"system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04449,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04449},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.449,"value_stored":0.4449},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.166667,"ER":0.0,"GD":0.0},"phases":["Cu5Dy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-LYRIXQAQTR","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":1},"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.166667,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu5Dy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.97},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-19.4,"value_printed":-19.4,"value_stored":-19400.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.166667,"ER":0.0,"GD":0.0},"phases":["Cu5Dy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-YZA6XQC6W2","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":2},"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.166667,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu5Dy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.94},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-18.8,"value_printed":-18.8,"value_stored":-18800.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/j.jallcom.2004.08.062","first_author":"Meschel","kind":"unknown","label":"21","paper":"doi:10.1016/j.jallcom.2004.08.062","reference":"S.V. Meschel, O.J. Kleppa, J. Alloys Compounds 388 (2005) 91.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.166667,"ER":0.0,"GD":0.0},"phases":["Cu5Dy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-6YBX53BGH7","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.166667},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.166667,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu5Dy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.785},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-15.7,"value_printed":-15.7,"value_stored":-15700.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.333333,"ER":0.0,"GD":0.0},"phases":["Cu2Dy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZXR2SCNQAJ","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":4},"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.333333,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.395},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-27.9,"value_printed":-27.9,"value_stored":-27900.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.333333,"ER":0.0,"GD":0.0},"phases":["Cu2Dy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-EARUEDH2OR","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":5},"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.333333,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.305},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-26.1,"value_printed":-26.1,"value_stored":-26100.0},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Sommer","kind":"assessment","label":"20","reference":"F. Sommer, J. Schott, B. Predel, J. Less-Common Met. 125 (1986) 175. 516 M. Palumbo et al. / CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry 33 (2009) 511–516","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.333333,"ER":0.0,"GD":0.0},"phases":["Cu2Dy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ITUAKEDPX5","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":6},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.333333,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.82},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-16.4,"value_printed":-16.4,"value_stored":-16400.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/j.jallcom.2004.08.062","first_author":"Meschel","kind":"unknown","label":"21","paper":"doi:10.1016/j.jallcom.2004.08.062","reference":"S.V. Meschel, O.J. Kleppa, J. Alloys Compounds 388 (2005) 91.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.333333,"ER":0.0,"GD":0.0},"phases":["Cu2Dy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-NUVJUGFJ2O","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":7},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.333333,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"Cu2Dy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.22},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-24.4,"value_printed":-24.4,"value_stored":-24400.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.5,"ER":0.0,"GD":0.0},"phases":["CuDy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-3JSGL7B2UN","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":8},"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.5,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.355},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-27.1,"value_printed":-27.1,"value_stored":-27100.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.5,"ER":0.0,"GD":0.0},"phases":["CuDy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-W3COO6M77J","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":9},"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.5,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.275},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-25.5,"value_printed":-25.5,"value_stored":-25500.0},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Sommer","kind":"assessment","label":"20","reference":"F. Sommer, J. Schott, B. Predel, J. Less-Common Met. 125 (1986) 175. 516 M. Palumbo et al. / CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry 33 (2009) 511–516","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.5,"ER":0.0,"GD":0.0},"phases":["CuDy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JAKQWTU62G","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":10},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.5,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-12.5,"value_printed":-12.5,"value_stored":-12500.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/j.jallcom.2004.08.062","first_author":"Meschel","kind":"unknown","label":"21","paper":"doi:10.1016/j.jallcom.2004.08.062","reference":"S.V. Meschel, O.J. Kleppa, J. Alloys Compounds 388 (2005) 91.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"CU-DY","before":"CU-DY-ER-GD","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.5,"ER":0.0,"GD":0.0},"phases":["CuDy"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BZMXE37WAA","locator":{"ref":"sha256:ad0bb5fd8807b797/p4/tab-2","row":11},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"DY":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.5,"ER":0.0,"GD":0.0},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phases":[{"label":"CuDy"}],"pid":"sha256:ad0bb5fd8807b797/p4/tab-2/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"reference_state_stored":{"CU":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"DY":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"ER":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"},"GD":{"phase":"printed:pure solid elements in their stable phases at 298.15 K"}},"source_system":"CU-DY-ER-GD","system":"CU-DY","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.2},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-24.0,"value_printed":-24.0,"value_stored":-24000.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OOFG32TAO7","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":1},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.0},"composition_source":"printed","phase":"Cu fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.085},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu fcc + Cu7Dy","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1126.0,"temperature_printed":"1126","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1126.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-SYLELY6QYX","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.0},"composition_source":"printed","phase":"Cu fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.1},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu fcc + Cu7Dy","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1128.0,"temperature_printed":"1128","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1128.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-NFXBFPEKGC","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":3},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.09},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu5Dy","model_phase":"CU5DY"},{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid + Cu5Dy -> Cu7Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1134.0,"temperature_printed":"1134","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1134.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-MS3FGGHHFY","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.102},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu5Dy","model_phase":"CU5DY"},{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid + Cu5Dy -> Cu7Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1165.0,"temperature_printed":"1165","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1165.0},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"unknown","label":"10","reference":"C.S. Cheng, G.-X. Xu, Acta Phys. Sinica 31 (6) (1982) 807.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-4X55SKTOTU","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.102},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu5Dy","model_phase":"CU5DY"},{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid + Cu5Dy -> Cu7Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1133.0,"temperature_printed":"1133","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1133.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-D6FSZSKN2S","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":6},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.0},"composition_source":"printed","phase":"Cu fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"}],"phases":[{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"Cu fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy","model_phase":"CU5DY"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy -> Cu fcc + Cu5Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1048.0,"temperature_printed":"1048","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1048.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-WTPLRUS4HH","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.0},"composition_source":"printed","phase":"Cu fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"}],"phases":[{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"Cu fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy","model_phase":"CU5DY"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy -> Cu fcc + Cu5Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1048.0,"temperature_printed":"1048","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1048.0},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"unknown","label":"10","reference":"C.S. Cheng, G.-X. Xu, Acta Phys. Sinica 31 (6) (1982) 807.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-VYC63ANMJ3","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.0},"composition_source":"printed","phase":"Cu fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"}],"phases":[{"label":"Cu7Dy","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"Cu fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy","model_phase":"CU5DY"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy -> Cu fcc + Cu5Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1121.0,"temperature_printed":"1121","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1121.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5LISXH2IMI","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":9},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.162},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy","model_phase":"CU5DY"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid + Cu9Dy2 -> Cu5Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1236.0,"temperature_printed":"1236","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1236.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JUTVDA7GKE","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.167},"composition_source":"printed","phase":"Cu5Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.162},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy","model_phase":"CU5DY"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid + Cu9Dy2 -> Cu5Dy"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1238.0,"temperature_printed":"1238","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1238.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UCATDCD4EC","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":11},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu9Dy2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1242.0,"temperature_printed":"1242","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1242.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-MT2FODR5MJ","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu9Dy2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1243.0,"temperature_printed":"1243","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1243.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UPCFFOPWA6","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":13},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.231},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy2","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid + Cu9Dy2 -> Cu7Dy2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1208.0,"temperature_printed":"1208","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1208.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-2PSFT42JAF","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.258},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy2","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid + Cu9Dy2 -> Cu7Dy2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1178.0,"temperature_printed":"1178","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-TVCUDS4ART","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":15},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.276},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu7Dy2","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy2 -> liquid + Cu9Dy2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1127.0,"temperature_printed":"1127","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1127.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-65GWUOVURX","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.287},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu7Dy2","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy2 -> liquid + Cu9Dy2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1128.0,"temperature_printed":"1128","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1128.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-36I3D3D4VM","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":17},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.278},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu2Dy","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu9Dy2 + Cu2Dy","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1120.0,"temperature_printed":"1120","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1120.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UCI5OXBKHF","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.29},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu9Dy2","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu2Dy","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu9Dy2 + Cu2Dy","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1118.0,"temperature_printed":"1118","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1118.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PX7KWH47JA","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":19},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu2Dy","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu2Dy","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1156.0,"temperature_printed":"1156","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1156.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CRILC3KA5M","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":20},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu2Dy","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu2Dy","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1163.0,"temperature_printed":"1163","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1163.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BAWGNIOGVX","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":21},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.391},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu2Dy","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"CuDy","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu2Dy + CuDy","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1121.0,"temperature_printed":"1121","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1121.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-SACNNMGHPQ","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":22},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.395},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Cu2Dy","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"CuDy","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> Cu2Dy + CuDy","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1113.0,"temperature_printed":"1113","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1113.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-65XSBPJ32H","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":23},"model":"Mde8ca388","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"CuDy","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> CuDy","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1227.0,"temperature_printed":"1227","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1227.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-4FTAKVFKOZ","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":24},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"CuDy","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> CuDy","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1228.0,"temperature_printed":"1228","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1228.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"DY":1.0},"before":{"DY":0.01},"evidence":{"printed_row":"69.1|70, 50, 1"},"field":"phase_compositions[Dy bcc]","gate":"A1","rule":"composition_read_from_page","visual_check":{"checked":"2026-10-24","image_sha256":"605e636f97fcfbc81a6d398f815b80a0dc5d4cd7b8806efc45b791ef13c0b7e0","page":5,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"p5 (printed 515) Table 3 Cu-Dy 'Compositions of the respective phases (at.% Dy)': liquid <-> CuDy + Dy bcc prints 69.1 / 50 / 1 and 70 / 50 / 1; the Dy bcc cell '1' is a fraction (pure Dy); set x(Dy)=1.0.","verdict":"corrected"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_phase_permutation_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OPRZYSXO2T","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":25},"model":"Mcc0d57d6","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.calphad.2009.04.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":1.0},"composition_source":"printed","composition_stored":{"DY":0.01},"phase":"Dy bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.691},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"CuDy","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"Dy bcc","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> CuDy + Dy bcc","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1020.0,"temperature_printed":"1020","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1020.0},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"DY":1.0},"before":{"DY":0.01},"evidence":{"printed_row":"69.1|70, 50, 1"},"field":"phase_compositions[Dy bcc]","gate":"A1","rule":"composition_read_from_page","visual_check":{"checked":"2026-10-24","image_sha256":"605e636f97fcfbc81a6d398f815b80a0dc5d4cd7b8806efc45b791ef13c0b7e0","page":5,"pdf_sha256_prefix":"ad0bb5fd8807b797","seen":"p5 (printed 515) Table 3 Cu-Dy 'Compositions of the respective phases (at.% Dy)': liquid <-> CuDy + Dy bcc prints 69.1 / 50 / 1 and 70 / 50 / 1; the Dy bcc cell '1' is a fraction (pure Dy); set x(Dy)=1.0.","verdict":"corrected"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_phase_permutation_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UQBQD6CQWH","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3","row":26},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":1.0},"composition_source":"printed","composition_stored":{"DY":0.01},"phase":"Dy bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"DY":0.7},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"CuDy","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"Dy bcc","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.calphad.2009.04.001/p5/tab-3/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liquid -> CuDy + Dy bcc","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1063.0,"temperature_printed":"1063","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1063.0},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.426,"dx":{"Cu7Dy":0.0,"L":0.0001},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-PAEYUIA46Y","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":1},"model":"M89337928","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.088},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.0},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Fcc","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Fcc + Cu7Dy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1157,"temperature_printed":"1157","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1157},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"experimental","label":"12","reference":"C.S. Cheng, G.X. Xu, Acta Phys. Sinica 31 (1982) 807–809.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-4.426,"dx":{"Cu7Dy":0.0,"L":-0.0139},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-LC53Q6V3UG","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:55cba08bc9b661d6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.074},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.0},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Fcc","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r02#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Fcc + Cu7Dy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1153,"temperature_printed":"1153","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1153},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.152,"dx":{"Cu5Dy.L":-0.0837,"Cu7Dy":0.0,"L":-0.0005},"fail_reason":"composition","model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-QI3H2HYBZS","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":3},"model":"M008e26a7","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.102},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"},{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"},{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r03#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Cu5Dy.L ↔ Cu7Dy","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1174,"temperature_printed":"1174","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1174},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"experimental","label":"12","reference":"C.S. Cheng, G.X. Xu, Acta Phys. Sinica 31 (1982) 807–809.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-9.152,"dx":{"Cu5Dy.L":-0.0837,"Cu7Dy":0.0},"model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-BRNAAKDJAY","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:55cba08bc9b661d6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"},{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"},{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r04#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Cu5Dy.L ↔ Cu7Dy","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1165,"temperature_printed":"1165","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1165},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-41.152,"dx":{"Cu5Dy.L":-0.0837,"Cu7Dy":0.0,"L":-0.0005},"model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-EURYJMW5LX","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.102},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"},{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"},{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r05#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Cu5Dy.L ↔ Cu7Dy","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1133,"temperature_printed":"1133","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1133},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.103,"dx":{"Cu5Dy.L":-0.0837,"Cu7Dy":0.0},"fail_reason":"composition","model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-DWE4PNTZDM","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":6},"model":"M008e26a7","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction","composition":{"DY":0.0},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"}],"phases":[{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"Fcc","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r06#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy ↔ Fcc + Cu5Dy.L","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1054,"temperature_printed":"1054","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1054},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-6.103,"dx":{"Cu5Dy.L":-0.0837,"Cu7Dy":0.0},"model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-7H7W54MND4","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction","composition":{"DY":0.0},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"}],"phases":[{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"Fcc","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r07#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy ↔ Fcc + Cu5Dy.L","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1048,"temperature_printed":"1048","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1048},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"experimental","label":"12","reference":"C.S. Cheng, G.X. Xu, Acta Phys. Sinica 31 (1982) 807–809.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":66.897,"dx":{"Cu5Dy.L":-0.0837,"Cu7Dy":0.0},"model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-2YZFVTKP5I","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:55cba08bc9b661d6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.125},"composition_source":"printed","phase":"Cu7Dy"},{"basis":"mole_fraction","composition":{"DY":0.0},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"}],"phases":[{"label":"Cu7Dy","mapping_confidence":"confirmed","model_phase":"CU7DY","pearson_symbol":"hP8","prototype":"Cu7Tb","structure_basis":"mapped_model_phase"},{"label":"Fcc","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r08#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy ↔ Fcc + Cu5Dy.L","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1121,"temperature_printed":"1121","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1121},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.145,"dx":{"Cu5Dy.L":-0.0837,"Cu9Dy2":0.0002,"L":0.0003},"fail_reason":"composition","model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-55BWHL7QJJ","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":9},"model":"M008e26a7","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.156},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_D2D"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r09#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Cu9Dy2 ↔ Cu5Dy.L","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1235,"temperature_printed":"1235","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1235},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":2.855,"dx":{"Cu5Dy.L":-0.0837,"Cu9Dy2":0.0002,"L":0.0063},"fail_reason":"composition","model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-L6A3XGPZHK","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.162},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction","composition":{"DY":0.083},"composition_source":"printed","phase":"Cu5Dy.L"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu5Dy.L","mapping_confidence":"proposed","model_phase":"CU5DY_D2D"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r10#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Cu9Dy2 ↔ Cu5Dy.L","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1238,"temperature_printed":"1238","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1238},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-SNTH5BSH7J","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":11},"model":"M008e26a7","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.166667},"composition_source":"stoichiometric_model_phase","phase":"Cu5Dy.H"},{"basis":"mole_fraction","composition":{"DY":0.166667},"composition_source":"stoichiometric_model_phase","phase":"CuDy.L"}],"phases":[{"label":"Cu5Dy.H","mapping_confidence":"proposed","model_phase":"CU5DY_D2D"},{"label":"CuDy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r11#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Cu5Dy.H ↔ CuDy.L","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1203,"temperature_printed":"1203","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-MJHRYYLL3P","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":12},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.166667},"composition_source":"stoichiometric_model_phase","phase":"Cu5Dy.H"},{"basis":"mole_fraction","composition":{"DY":0.166667},"composition_source":"stoichiometric_model_phase","phase":"CuDy.L"}],"phases":[{"label":"Cu5Dy.H","mapping_confidence":"proposed","model_phase":"CU5DY_D2D"},{"label":"CuDy.L","mapping_confidence":"proposed","model_phase":"CU5DY_C15B"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r12#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Cu5Dy.H ↔ CuDy.L","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1203,"temperature_printed":"1203","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-6LU4UTBUYR","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":13},"model":"M008e26a7","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.1818181818},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.1818181818},"composition_source":"stoichiometry","phase":"Cu9Dy2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r13#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ Cu9Dy2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1243,"temperature_printed":"1243","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1243},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-QNOMAIPWI5","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":14},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.1818181818},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.1818181818},"composition_source":"stoichiometry","phase":"Cu9Dy2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r14#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ Cu9Dy2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1245,"temperature_printed":"1245","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1245},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.787,"dx":{"Cu7Dy2":-0.0002,"Cu9Dy2":0.0002,"L":0.0002},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-ZNHLCXVRKJ","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":15},"model":"M89337928","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.258},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy2","mapping_confidence":"confirmed","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r15#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Cu9Dy2 ↔ Cu7Dy2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1172,"temperature_printed":"1172","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1172},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":5.213,"dx":{"Cu7Dy2":-0.0002,"Cu9Dy2":0.0002},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-QNCLJZSGZL","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu7Dy2","mapping_confidence":"confirmed","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r16#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Cu9Dy2 ↔ Cu7Dy2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1178,"temperature_printed":"1178","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.858,"dx":{"Cu7Dy2":-0.0002,"Cu9Dy2":0.0002,"L":0.0003},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-6BSZDW4UXE","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":17},"model":"M89337928","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"},{"basis":"mole_fraction","composition":{"DY":0.278},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"}],"phases":[{"label":"Cu7Dy2","mapping_confidence":"confirmed","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r17#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy2 ↔ L + Cu9Dy2","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1131,"temperature_printed":"1131","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Catatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1131},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-3.858,"dx":{"Cu7Dy2":-0.0002,"Cu9Dy2":0.0002},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-DXV2XBIF2I","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.222},"composition_source":"printed","phase":"Cu7Dy2"},{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"}],"phases":[{"label":"Cu7Dy2","mapping_confidence":"confirmed","model_phase":"CU7DY2","pearson_symbol":"mC*","prototype":"(Cu7Dy2)","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r18#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Cu7Dy2 ↔ L + Cu9Dy2","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1128,"temperature_printed":"1128","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Catatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1128},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.095,"dx":{"Cu2Dy":-0.0003,"Cu9Dy2":0.0002,"L":0.0003},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-ZK3UESFCRR","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":19},"model":"M89337928","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.282},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r19#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Cu9Dy2 + Cu2Dy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1123,"temperature_printed":"1123","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1123},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-5.095,"dx":{"Cu2Dy":-0.0003,"Cu9Dy2":0.0002,"L":0.0083},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-M5BMLBFA6A","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":20},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.29},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r20#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Cu9Dy2 + Cu2Dy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1118,"temperature_printed":"1118","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1118},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"experimental","label":"12","reference":"C.S. Cheng, G.X. Xu, Acta Phys. Sinica 31 (1982) 807–809.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":14.905,"dx":{"Cu2Dy":-0.0003,"Cu9Dy2":0.0002},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-J6HCN2B46U","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":21},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:55cba08bc9b661d6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.182},"composition_source":"printed","phase":"Cu9Dy2"},{"basis":"mole_fraction","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu9Dy2","mapping_confidence":"confirmed","model_phase":"CU9DY2","pearson_symbol":"t** or mC*","prototype":"(Cu9Dy2)","structure_basis":"mapped_model_phase"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r21#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Cu9Dy2 + Cu2Dy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1138,"temperature_printed":"1138","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1138},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-K6AXRTQ5JX","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":22},"model":"M008e26a7","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.3333333333},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.3333333333},"composition_source":"stoichiometry","phase":"Cu2Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r22#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ Cu2Dy","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1150,"temperature_printed":"1150","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1150},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Copeland","kind":"unknown","label":"14","reference":"M. Copeland, H. Kato, Physics and Materials Problems of Reactor Control Rods, International Atomic Energy Agency, Vienna, Austria, 1964, pp. 295–317.","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-JZMPOWFHNZ","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":23},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:2bc6c2ad198c257f","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.3333333333},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.3333333333},"composition_source":"stoichiometry","phase":"Cu2Dy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r23#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ Cu2Dy","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1163,"temperature_printed":"1163","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1163},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.688,"dx":{"Cu2Dy":-0.0003,"CuDy":0.0,"L":0.0002},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-GLKYJDOVQJ","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":24},"model":"M89337928","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.39},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r24#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Cu2Dy + CuDy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1120,"temperature_printed":"1120","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1120},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-7.688,"dx":{"Cu2Dy":-0.0003,"CuDy":0.0,"L":0.0052},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-BUEOC6LP6K","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":25},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.395},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r25#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Cu2Dy + CuDy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1113,"temperature_printed":"1113","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1113},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"experimental","label":"12","reference":"C.S. Cheng, G.X. Xu, Acta Phys. Sinica 31 (1982) 807–809.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-7.688,"dx":{"Cu2Dy":-0.0003,"CuDy":0.0},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-A5GXLL43TI","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":26},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:55cba08bc9b661d6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.333},"composition_source":"printed","phase":"Cu2Dy"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Cu2Dy","mapping_confidence":"confirmed","model_phase":"CU2DY","pearson_symbol":"oI12","prototype":"Hg2K","structure_basis":"mapped_model_phase"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r26#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Cu2Dy + CuDy","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1113,"temperature_printed":"1113","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1113},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-6FIE2H2FNJ","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":27},"model":"M008e26a7","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"stoichiometry","phase":"CuDy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r27#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ CuDy","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1220,"temperature_printed":"1220","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1220},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-AHRRT5KDMP","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":28},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"stoichiometry","phase":"CuDy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r28#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ CuDy","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1228,"temperature_printed":"1228","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1228},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.863,"dx":{"Bcc":0.0096,"CuDy":0.0,"L":-0.0003},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-HC3KTPBCLC","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":29},"model":"M89337928","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.654},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction","composition":{"DY":0.775},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"Bcc","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r29#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ CuDy + Bcc","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1063,"temperature_printed":"1063","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1063},{"chemical_system":"CU-DY","cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"experimental","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.863,"dx":{"CuDy":0.0,"L":0.0457},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-ICNRH4FV3K","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":30},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.7},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"Bcc","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r30#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ CuDy + Bcc","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1063,"temperature_printed":"1063","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1063},{"chemical_system":"CU-DY","cited_sources":[{"first_author":"Cheng","kind":"experimental","label":"12","reference":"C.S. Cheng, G.X. Xu, Acta Phys. Sinica 31 (1982) 807–809.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":17.137,"dx":{"CuDy":0.0,"L":0.0867},"model":"CuDy-09Zha.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-KQAKBYBTAV","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":31},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:55cba08bc9b661d6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.741},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"Bcc","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r31#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ CuDy + Bcc","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":1081,"temperature_printed":"1081","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1081},{"chemical_system":"CU-DY","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.017,"dx":{"Bcc":-0.0005,"CuDy":0.0,"Hcp":-0.0004},"model":"CuDy-09Zha.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-IOWK77NHR3","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3","row":32},"model":"M89337928","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.03.007","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phase_compositions":[{"basis":"mole_fraction","composition":{"DY":0.832},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction","composition":{"DY":0.5},"composition_source":"printed","phase":"CuDy"},{"basis":"mole_fraction","composition":{"DY":0.879},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Bcc","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"CuDy","mapping_confidence":"confirmed","model_phase":"CUDY_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"Hcp","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p3/tab-3/r32#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Bcc ↔ CuDy + Hcp","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"CU-DY","system":"CU-DY","temperature_K":803,"temperature_printed":"803","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":803},{"chemical_system":"CU-DY","citations_printed":["14"],"cited_sources":[{"first_author":"Copeland","kind":"unknown","label":"14","reference":"M. Copeland, H. Kato, Rare-earth-rich alloys, in: Physics and Materials Problems of Reactor Control Rods, International Atomic Energy Agency, Vienna, Austria, 1964, p. 295.","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-LS3T3EMXRK.a34286","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p1/text-21"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","pid":"doi:10.1016/j.calphad.2009.04.001/p1/text-21/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"They found a lower value (1048 K) for the eutectic temperature between liquid, CuDy and hcp Dy with respect to Franceschi (1063 K).","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CU-DY","system":"CU-DY","temperature_K":1048.0,"temperature_printed":"1048","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1048.0},{"chemical_system":"CU-DY","citations_printed":["8"],"cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"8","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-LS3T3EMXRK.abe3ea","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2009.04.001/p1/text-21"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2009.04.001","paper_id":"doi:10.1016/j.calphad.2009.04.001","pid":"doi:10.1016/j.calphad.2009.04.001/p1/text-21/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"They found a lower value (1048 K) for the eutectic temperature between liquid, CuDy and hcp Dy with respect to Franceschi (1063 K).","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CU-DY","system":"CU-DY","temperature_K":1063.0,"temperature_printed":"1063","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1063.0},{"chemical_system":"CU-DY","citations_printed":["13"],"cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-CJQCDMOMHP.19517e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","pid":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Franceschi [13] also found four eutectics: Cu-Cu7 Dy (855 ◦ C, 10 at.% Dy), Cu9 Dy2 -Cu2 Dy (845 ◦ C, 29 at.% Dy), Cu2 Dy-CuDy (840 ◦ C, 39.5 at.% Dy), CuDy-Dy (790 ◦ C, 70 at.% Dy).","quote_page":2,"reaction":{"printed":"eutectic","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CU-DY","system":"CU-DY","temperature_K":1128.15,"temperature_printed":"855 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1128.15},{"chemical_system":"CU-DY","citations_printed":["13"],"cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-CJQCDMOMHP.9bd648","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","pid":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Franceschi [13] also found four eutectics: Cu-Cu7 Dy (855 ◦ C, 10 at.% Dy), Cu9 Dy2 -Cu2 Dy (845 ◦ C, 29 at.% Dy), Cu2 Dy-CuDy (840 ◦ C, 39.5 at.% Dy), CuDy-Dy (790 ◦ C, 70 at.% Dy).","quote_page":2,"reaction":{"printed":"eutectic","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CU-DY","system":"CU-DY","temperature_K":1113.15,"temperature_printed":"840 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1113.15},{"chemical_system":"CU-DY","citations_printed":["13"],"cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-CJQCDMOMHP.dee998","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","pid":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Franceschi [13] also found four eutectics: Cu-Cu7 Dy (855 ◦ C, 10 at.% Dy), Cu9 Dy2 -Cu2 Dy (845 ◦ C, 29 at.% Dy), Cu2 Dy-CuDy (840 ◦ C, 39.5 at.% Dy), CuDy-Dy (790 ◦ C, 70 at.% Dy).","quote_page":2,"reaction":{"printed":"eutectic","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CU-DY","system":"CU-DY","temperature_K":1063.15,"temperature_printed":"790 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1063.15},{"chemical_system":"CU-DY","citations_printed":["13"],"cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-CJQCDMOMHP.e5f13e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","pid":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Franceschi [13] also found four eutectics: Cu-Cu7 Dy (855 ◦ C, 10 at.% Dy), Cu9 Dy2 -Cu2 Dy (845 ◦ C, 29 at.% Dy), Cu2 Dy-CuDy (840 ◦ C, 39.5 at.% Dy), CuDy-Dy (790 ◦ C, 70 at.% Dy).","quote_page":2,"reaction":{"printed":"eutectic","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CU-DY","system":"CU-DY","temperature_K":1118.15,"temperature_printed":"845 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1118.15},{"chemical_system":"CU-DY","citations_printed":["13"],"cited_sources":[{"doi":"10.1016/0022-5088(82)90092-3","first_author":"Franceschi","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(82)90092-3","reference":"E. Franceschi, J. Less-Common Met. 87 (1982) 249–256.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-QJGBBOHRHQ","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(82)90092-3","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.03.007","paper_id":"doi:10.1016/j.jallcom.2008.03.007","phases":[{"label":"Cu5 Dy"}],"pid":"doi:10.1016/j.jallcom.2008.03.007/p2/text-16/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"He found a thermal effect at 930 ◦ C corresponding to the stoichiometry of Cu5 Dy.","quote_page":2,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CU-DY","system":"CU-DY","temperature_K":1203.15,"temperature_printed":"930 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CU-DY"}