{"artifacts":{"sha256:adc465912b1c609d/p6/tab-iv":{"artifact":"table","caption":"A2/B2 Transition and Equilibrium Compositions of the Cu-Sn-Mn System Determined by the Diffusion Couple Method","label":"IV","page":6}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1007/s11661-004-0073-0":{"context_id":"context:source-doi-10-1007-s11661-004-0073-0","items":[{"applies_to":"alloys","extraction_accepted":false,"id":"ORC-MMCNNPXKTR","method":"chemical analysis and energy-dispersive","page":1,"quote":"The compositions of the alloys were determined by chemical analysis and energy-dispersive VOLUME 35A, JUNE 2004-1641","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-G4CSK4THOQ","label":"Binary Cu-Sn and ternary Cu-Sn-Mn alloys","page":1,"purity":"electrolytic copper (99.99 pct), manganese (99.9 pct pure), and tin (99.97 pct pure)","quote":"Binary Cu-Sn and ternary Cu-Sn-Mn alloys were prepared in alumina crucibles by melting electrolytic copper (99.99 pct), manganese (99.9 pct pure), and tin (99.97 pct pure) in a high-frequency induction furnace under an argon atmosphere.","second_reader_agrees":false,"synthesis":"melting electrolytic copper (99.99 pct), manganese (99.9 pct pure), and tin (99.97 pct pure) in a high-frequency induction furnace under an argon atmosphere","type":"sample"}],"paper":"doi:10.1007/s11661-004-0073-0","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"methods_heading"}},"elements":["CU","MN","SN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s11661-004-0073-0":{"authors":["X. J. Liu","R. Kainuma","C. P. Wang","I. Ohnuma","K. Ishida"],"citation":"X. J. Liu, R. Kainuma, C. P. Wang, I. Ohnuma, K. Ishida, Experimental investigation and thermodynamic calculation of the phase equilibria in the Cu-Sn and Cu-Sn-Mn systems, Metall Mater Trans A 35, 1641-1654 (2004).","container":"Metall Mater Trans A","doi":"10.1007/s11661-004-0073-0","doi_url":"https://doi.org/10.1007/s11661-004-0073-0","id":"doi:10.1007/s11661-004-0073-0","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"adc465912b1c609d","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental investigation and thermodynamic calculation of the phase equilibria in the Cu-Sn and Cu-Sn-Mn systems","year":2004}},"part":1,"parts":1,"records":[{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-TOCHS4NOQE","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":1},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.799,"MN":0.049,"SN":0.152},"composition_source":"printed","phase":"Bcc (A2/B2 transition)"}],"phases":[{"label":"Bcc (A2/B2 transition)"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-VHJXPNMIYK","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":2},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.884,"MN":0.047,"SN":0.069},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.828,"MN":0.051,"SN":0.121},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":973.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-GEN2YFYOES","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":3},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.766,"MN":0.074,"SN":0.16},"composition_source":"printed","phase":"Bcc (A2/B2 transition)"}],"phases":[{"label":"Bcc (A2/B2 transition)"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":973.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-LBW7E7T3C4","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":4},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.853,"MN":0.089,"SN":0.058},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.79,"MN":0.099,"SN":0.111},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":973.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-25CX6UOMNA","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":5},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"SN":0.155},"composition_source":"printed","phase":"Bcc (A2/B2 transition)"}],"phases":[{"label":"Bcc (A2/B2 transition)"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":963.15,"temperature_basis":"printed","temperature_printed":"690","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-ZLJCBVVHE6","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":6},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.805,"MN":0.045,"SN":0.15},"composition_source":"printed","phase":"Bcc (A2/B2 transition)"}],"phases":[{"label":"Bcc (A2/B2 transition)"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":923.15,"temperature_basis":"printed","temperature_printed":"650","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-5ZFWJNBIXP","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":7},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"SN":0.073},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.818,"MN":0.054,"SN":0.128},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":923.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-YQDZAC4U3K","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":8},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.563,"MN":0.228,"SN":0.209},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.661,"MN":0.176,"SN":0.163},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":923.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-AZKBU3ENHQ","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":9},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.748,"MN":0.148,"SN":0.104},"composition_source":"printed","phase":"Bcc (A2/B2 transition)"}],"phases":[{"label":"Bcc (A2/B2 transition)"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":923.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-52CRSZEV32","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":10},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.847,"MN":0.089,"SN":0.064},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.783,"MN":0.101,"SN":0.116},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":923.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-HIGT3SM5YW","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":11},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.877,"MN":0.047,"SN":0.076},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.812,"MN":0.055,"SN":0.133},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r11#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","temperature_printed":"600","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-5EAOJDEKPA","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":12},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.831,"MN":0.112,"SN":0.057},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.667,"MN":0.17,"SN":0.163},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Fcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r12#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-MWI7MEJ5BL","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":13},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.766,"MN":0.122,"SN":0.112},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.666,"MN":0.17,"SN":0.164},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r13#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-RXK6LIACXJ","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":14},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.846,"MN":0.091,"SN":0.063},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.778,"MN":0.102,"SN":0.12},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r14#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-4ZIKKEG35B","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":15},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.833,"MN":0.111,"SN":0.056},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.669,"MN":0.168,"SN":0.163},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Fcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r15#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-CXAKHHRFA3","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":16},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.779,"MN":0.086,"SN":0.135},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.667,"MN":0.168,"SN":0.165},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r16#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-TNYCGNNZ3C","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":17},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.875,"MN":0.047,"SN":0.078},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.81,"MN":0.055,"SN":0.135},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r17#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","temperature_printed":"550","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-JTK4IIBNOQ","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":18},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.868,"MN":0.075,"SN":0.057},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.679,"MN":0.169,"SN":0.152},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Fcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r18#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-CFB5DKSXCJ","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":19},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.558,"MN":0.19,"SN":0.252},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.66,"MN":0.174,"SN":0.166},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r19#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-ZJ67BEW6O6","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":20},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.835,"MN":0.127,"SN":0.038},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.679,"MN":0.169,"SN":0.152},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Fcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r20#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-U7NUZTXOGY","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":21},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.687,"MN":0.067,"SN":0.246},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.665,"MN":0.165,"SN":0.17},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r21#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-LXQBG7JRAW","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":22},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.764,"MN":0.207,"SN":0.029},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.659,"MN":0.183,"SN":0.158},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Fcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r22#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-5GCWOZYSHR","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":23},"method":"diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"SN":0.131},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.669,"MN":0.165,"SN":0.166},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r23#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-KH4AQTF7FS","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":24},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.755,"MN":0.1,"SN":0.145},"composition_source":"printed","phase":"Bcc (A2/B2 transition)"}],"phases":[{"label":"Bcc (A2/B2 transition)"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r24#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-J7PK5BHPSS","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":25},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.822,"MN":0.136,"SN":0.042},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.754,"MN":0.147,"SN":0.099},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r25#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-RQKCKP333T","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":26},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.628,"MN":0.246,"SN":0.126},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.67,"MN":0.17,"SN":0.16},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r26#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":923.15,"temperature_basis":"printed","temperature_printed":"650","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-XUODHMN5QR","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":27},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.787,"MN":0.135,"SN":0.078},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.837,"MN":0.031,"SN":0.132},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r27#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":923.15,"temperature_basis":"printed","temperature_printed":"650","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-SXLMTLTDN4","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":28},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.736,"MN":0.228,"SN":0.036},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.672,"MN":0.244,"SN":0.084},"composition_source":"printed","phase":"Bcc"}],"phases":[{"label":"Fcc"},{"label":"Bcc"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r28#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","temperature_printed":"600","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-FCNEU5MVLM","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":29},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.816,"MN":0.132,"SN":0.052},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.664,"MN":0.174,"SN":0.162},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Fcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r29#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","temperature_printed":"600","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-L5PLWD2WEP","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":30},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.797,"MN":0.099,"SN":0.104},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.669,"MN":0.166,"SN":0.165},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r30#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":873.15,"temperature_basis":"printed","temperature_printed":"600","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-3XYZDRJXLA","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":31},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.494,"MN":0.253,"SN":0.253},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.66,"MN":0.174,"SN":0.166},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Bcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r31#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","temperature_printed":"550","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"CU-MN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11661-004-0073-0"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-MFS2C6TB6I","locator":{"ref":"sha256:adc465912b1c609d/p6/tab-iv","row":32},"method":"Diffusion couple","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11661-004-0073-0","own_work_of_paper":true},"paper":"doi:10.1007/s11661-004-0073-0","paper_id":"doi:10.1007/s11661-004-0073-0","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.872,"MN":0.063,"SN":0.065},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"CU":0.675,"MN":0.163,"SN":0.162},"composition_source":"printed","phase":"Cu4MnSn"}],"phases":[{"label":"Fcc"},{"label":"Cu4MnSn"}],"pid":"sha256:adc465912b1c609d/p6/tab-iv/r32#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"CU-MN-SN","system":"CU-MN-SN","temperature_K":823.15,"temperature_basis":"printed","temperature_printed":"550","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"diffusion_couple","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"diffusion_couple","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"CU-MN-SN"}