{"artifacts":{"doi:10.1034/j.1600-0692.2002.311310106.x/p13/text-07":{"artifact":"text_passage","label":"page 13, passage 7","page":13},"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5":{"artifact":"table","caption":"Invariant reactions in the Fe-Gd-Mo system","label":"5","page":5},"doi:10.1034/j.1600-0692.2002.311310106.x/p6/text-02":{"artifact":"text_passage","label":"page 6, passage 2","page":6},"sha256:862a5fa5a46caf69/p10/tab-8":{"artifact":"table","caption":"Calculated and measured entropy and heat capacity of the ternary phase t in the Fe-Gd-Mo system","label":"8","page":10},"sha256:862a5fa5a46caf69/p6/tab-6":{"artifact":"table","caption":"Calculated and observed liquidus temperatures in the Fe-Gd- Mo system","label":"6","page":6}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1034/j.1600-0692.2002.311310106.x":{"context_id":"context:source-doi-10-1034-j-1600-0692-2002-311310106-x","items":[{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-SQYCNIZOVD","instrument":"differential scanning calorimeter","page":5,"quote":"Several measurements above room temperature were made using a differential scanning calorimeter.","second_reader_agrees":false,"type":"measurement"},{"calibration":"calibrated platinum resistance thermometer","crucible":"0.1 mm thick Al2O3 disc, with a NiCr thin film heater deposited on the underside","extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-XSCB2KEITH","instrument":"high-precision adiabatic calorimeter with two isothermal shields","method":"low-temperature specific heat","page":5,"quote":"The sample holder was a 0.1 mm thick Al2O3 disc, with a NiCr thin film heater deposited on the underside. A calibrated platinum resistance thermometer was employed. The temperature of the isothermal shields was controlled to better than 5 mK. The 50-300 mg samples were cemented to the sample holder using a weighed amount of Apiezon-N grease. The post-heating temperature drift curve was fitted by an exponential function. The experimental errors were estimated to be below 1%.","quote_chars_original":612,"quote_clipped":true,"second_reader_agrees":true,"stated_uncertainty":"below 1%","type":"measurement"},{"extraction_accepted":false,"id":"ORC-GOHTMPGODV","label":"phase t","page":5,"quote":"To provide some thermochemical data, the heat capacity of the ternary intermetallic phase t of three various compositions was measured in the present work (Fig. 8).","second_reader_agrees":false,"type":"sample"}],"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"own_work_method_cues"}},"elements":["FE","GD","MO"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1034/j.1600-0692.2002.311310106.x":{"authors":["Matvei Zinkevich","Norbert Mattern","Hans‐Jürgen Seifert","Eberhard Gmelin"],"citation":"Matvei Zinkevich, Norbert Mattern, Hans‐Jürgen Seifert, Eberhard Gmelin, A thermodynamic assessment of the Fe‐Gd‐Mo system, Scand Jof Metallurgy 31, 34-51 (2002).","container":"Scand Jof Metallurgy","doi":"10.1034/j.1600-0692.2002.311310106.x","doi_url":"https://doi.org/10.1034/j.1600-0692.2002.311310106.x","id":"doi:10.1034/j.1600-0692.2002.311310106.x","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"862a5fa5a46caf69","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"A thermodynamic assessment of the Fe‐Gd‐Mo system","year":2002}},"part":1,"parts":1,"records":[{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-XRAWHJNI6U.25a31d","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":1},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.402},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":28.04,"value_printed":28.04},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-XRAWHJNI6U.347904","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":1},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"°S","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.7415},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":34.83,"value_printed":34.83},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-IDDITI6LVF.6e00f0","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":2},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.458},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":29.16,"value_printed":29.16},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-IDDITI6LVF.82ccc0","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":2},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"°S","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.75},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":35.0,"value_printed":35.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-ACLSNVOFZU.732415","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":3},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.3895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":27.79,"value_printed":27.79},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-ACLSNVOFZU.c8f8f4","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":3},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"°S","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.8255},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":36.51,"value_printed":36.51},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-MPEHHAMLNR.9072ad","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":4},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.959},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":39.18,"value_printed":39.18},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-MPEHHAMLNR.b5c58b","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":4},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"°S","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.917},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":38.34,"value_printed":38.34},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-CUS4G4NGZP.1b5e66","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":5},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.2815},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":25.63,"value_printed":25.63},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-CUS4G4NGZP.febb6c","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":5},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"°S","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.8895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":37.79,"value_printed":37.79},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-PGJ65AQOLK.be5cfa","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":6},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM","property_group":"heat capacity / entropy / enthalpy","property_printed":"°S","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.793},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":35.86,"value_printed":35.86},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-PGJ65AQOLK.d41af0","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":6},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.328},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":26.56,"value_printed":26.56},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-E3THGDZTBA","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":7},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":320.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.4315},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":28.63,"value_printed":28.63},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-L7ACQQIE5N","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":8},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":320.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.53},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":30.6,"value_printed":30.6},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-4CLXQ5B2EG","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":9},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":591.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5285},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":30.57,"value_printed":30.57},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-YVI2HT7DYI","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":10},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":591.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.523},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":30.46,"value_printed":30.46},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-BGV4VA6EXX","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":11},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":756.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5735},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":31.47,"value_printed":31.47},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-LIUXLMOIZV","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":12},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.765,"GD":0.088,"MO":0.147},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":756.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.548},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":30.96,"value_printed":30.96},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-U6RTLBTLYD","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":13},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":400.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.442},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":28.84,"value_printed":28.84},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-F3LMR7C6IR","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":14},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":400.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.471},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":29.42,"value_printed":29.42},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-I7WVCOCJ2T","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":15},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":591.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.498},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":29.96,"value_printed":29.96},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-WWNO6R2V2L","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":16},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":591.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5045},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":30.09,"value_printed":30.09},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-BN73W42IMJ","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":17},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":769.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.553},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":31.06,"value_printed":31.06},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-NQZWZSPMOL","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":18},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.699,"GD":0.107,"MO":0.194},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":769.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.538},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":30.76,"value_printed":30.76},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-KC4NHL73AT","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":19},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":320.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.298},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":25.96,"value_printed":25.96},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-FJLRGIALAZ","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":20},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":320.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.349},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":26.98,"value_printed":26.98},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-RJWES7765T","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":21},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":450.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.376},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":27.52,"value_printed":27.52},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-2QKXLHGQBF","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":22},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":450.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.41},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":28.2,"value_printed":28.2},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-56RLKIC2I6","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":23},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":600.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.4305},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":28.61,"value_printed":28.61},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-4AQVX33PV2","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":24},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":600.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.4635},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":29.27,"value_printed":29.27},{"chemical_system":"FE-GD-MO","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-ENGBWAYWFT","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":25},"observation_type":"equilibrium_property","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":681.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.461},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":29.22,"value_printed":29.22},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'τ'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-AHZAQMSQKA","locator":{"ref":"sha256:862a5fa5a46caf69/p10/tab-8","row":26},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.61,"GD":0.093,"MO":0.297},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p10/tab-8/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":681.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.4905},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J · mol^-1 · K^-1","value":29.81,"value_printed":29.81},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-OFEJRRECHA","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.909,"GD":0.046,"MO":0.045},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"bccFe"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"bccFe","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1705.0,"temperature_basis":"printed","temperature_printed":"1705","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1705.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-Z2VUGE77ER","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":2},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.909,"GD":0.046,"MO":0.045},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"bccFe"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"bccFe","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1743.0,"temperature_basis":"printed","temperature_printed":"1743±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1743.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-3E2AIC7D3N","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.856,"GD":0.094,"MO":0.05},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"bccFe"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"bccFe","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1617.0,"temperature_basis":"printed","temperature_printed":"1617","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1617.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-O6EYE6WSMH","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.856,"GD":0.094,"MO":0.05},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"bccFe"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"bccFe","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1631.0,"temperature_basis":"printed","temperature_printed":"1631±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1631.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-CCB32TI37J","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.696,"GD":0.204,"MO":0.1},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1477.0,"temperature_basis":"printed","temperature_printed":"1477","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1477.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-DLJW4C25KG","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":6},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.696,"GD":0.204,"MO":0.1},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1670.0,"temperature_basis":"printed","temperature_printed":"1670±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1670.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-P7Z6HQNZOP","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.647,"GD":0.248,"MO":0.105},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1460.0,"temperature_basis":"printed","temperature_printed":"1460","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1460.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-JM2SNHD7WB","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":8},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.647,"GD":0.248,"MO":0.105},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1689.0,"temperature_basis":"printed","temperature_printed":"1689±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1689.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-RBRPDPXGXK","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.514,"GD":0.346,"MO":0.14},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1448.0,"temperature_basis":"printed","temperature_printed":"1448","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1448.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-RBXOW4MUNP","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":10},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.514,"GD":0.346,"MO":0.14},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1641.0,"temperature_basis":"printed","temperature_printed":"1641±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1641.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-EASRJFKRJS","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.469,"GD":0.409,"MO":0.122},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1303.0,"temperature_basis":"printed","temperature_printed":"1303","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1303.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-TRO2HWRKRW","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":12},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.469,"GD":0.409,"MO":0.122},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"τ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"τ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1571.0,"temperature_basis":"printed","temperature_printed":"1571±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1571.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-CCD3KXHHJC","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":13},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.657,"GD":0.103,"MO":0.24},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"σ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"σ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1680.0,"temperature_basis":"printed","temperature_printed":"1680","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1680.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-SSXDUNXZVR","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":14},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.657,"GD":0.103,"MO":0.24},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"σ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"σ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1778.0,"temperature_basis":"printed","temperature_printed":"1778±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1778.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-EASMMF7LR7","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":15},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.62,"GD":0.103,"MO":0.277},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"σ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"σ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1743.0,"temperature_basis":"printed","temperature_printed":"1743","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1743.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-PRQWQ5HPUV","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":16},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.62,"GD":0.103,"MO":0.277},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"σ"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r16#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"σ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1843.0,"temperature_basis":"printed","temperature_printed":"1843±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1843.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-TZWJHPA37G","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":17},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.555,"GD":0.2,"MO":0.245},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"(Mo)"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r17#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"(Mo)","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1786.0,"temperature_basis":"printed","temperature_printed":"1786","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1786.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-NUAAA7WF2S","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":18},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.555,"GD":0.2,"MO":0.245},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"(Mo)"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r18#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"(Mo)","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1773.0,"temperature_basis":"printed","temperature_printed":"1773±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1773.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-HQ5QI5WYKK","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":19},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"overall_composition":{"FE":0.36,"GD":0.58,"MO":0.06},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"Fe2Gd"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Fe2Gd","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1077.0,"temperature_basis":"printed","temperature_printed":"1077","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1077.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-SBDJCG7UVW","locator":{"ref":"sha256:862a5fa5a46caf69/p6/tab-6","row":20},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.36,"GD":0.58,"MO":0.06},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L"},{"label":"Fe2Gd"}],"pid":"sha256:862a5fa5a46caf69/p6/tab-6/r20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Fe2Gd","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1265.0,"temperature_basis":"printed","temperature_printed":"1265±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1265.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PXFG6S3N63","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.071,"MO":0.173},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"R","model_phase":"R_PHASE","pearson_symbol":"hR53","prototype":"R-(Co,Cr,Mo)","structure_basis":"mapped_model_phase"},{"label":"bccFe"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U8: L+R->bccFe+τ","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1592.0,"temperature_printed":"1592","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1592.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-GKBYLQXPZG","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"R","model_phase":"R_PHASE","pearson_symbol":"hR53","prototype":"R-(Co,Cr,Mo)","structure_basis":"mapped_model_phase"},{"label":"bccFe"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U8: L+R->bccFe+τ","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1557.0,"temperature_uncertainty":{"basis":"printed","value":20.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":20.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":20.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1557.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JIJH7EQ6VE","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.145,"MO":0.094},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"bccFe"},{"label":"Fe17Gd2"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U1: L+bccFe->Fe17Gd2+τ","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1497.0,"temperature_printed":"1497","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1497.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JFRKVTSMU5","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"bccFe"},{"label":"Fe17Gd2"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U1: L+bccFe->Fe17Gd2+τ","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1589.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1589.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-GEZE77MHE7","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.116,"MO":0.22},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"σ"},{"label":"R","model_phase":"R_PHASE","pearson_symbol":"hR53","prototype":"R-(Co,Cr,Mo)","structure_basis":"mapped_model_phase"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U2: L+σ+R->τ","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1642.0,"temperature_printed":"1642","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1642.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CBOPZU2NYQ","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"σ"},{"label":"R","model_phase":"R_PHASE","pearson_symbol":"hR53","prototype":"R-(Co,Cr,Mo)","structure_basis":"mapped_model_phase"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U2: L+σ+R->τ","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1673.0,"temperature_max_K":1761.0,"temperature_printed":"1673..1761","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1673.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JCVIFYWP4I","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.312,"MO":0.177},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"σ"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"(Mo)"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U3: L+σ->τ+(Mo)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1520.0,"temperature_printed":"1520","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1520.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-7TCUNPFWPM","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"σ"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"(Mo)"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U3: L+σ->τ+(Mo)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1613.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1613.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-RIM3PUODQY","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.221,"MO":0.084},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe17Gd2"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe23Gd6"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U4: L+Fe17Gd2->τ+Fe23Gd6","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1447.0,"temperature_printed":"1447","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1447.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-4D5XOOB74T","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe17Gd2"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe23Gd6"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U4: L+Fe17Gd2->τ+Fe23Gd6","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1439.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1439.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZAHH5G6I2X","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.401,"MO":0.094},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe23Gd6"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe3Gd","model_phase":"FE3GD","pearson_symbol":"hR12","prototype":"Ni3Pu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U5: L+Fe23Gd6->τ+Fe3Gd","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1255.1,"temperature_printed":"1255.1","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1255.1},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-NPGOV7YDBP","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe23Gd6"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe3Gd","model_phase":"FE3GD","pearson_symbol":"hR12","prototype":"Ni3Pu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U5: L+Fe23Gd6->τ+Fe3Gd","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1343.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1343.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-QHSCETOH3C","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":13},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.401,"MO":0.094},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe3Gd","model_phase":"FE3GD","pearson_symbol":"hR12","prototype":"Ni3Pu","structure_basis":"mapped_model_phase"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe2Gd","model_phase":"FE2GD_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U7: L+Fe3Gd->τ+Fe2Gd","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1255.0,"temperature_printed":"1255.0","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1255.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-6MUZ72VBAS","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe3Gd","model_phase":"FE3GD","pearson_symbol":"hR12","prototype":"Ni3Pu","structure_basis":"mapped_model_phase"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe2Gd","model_phase":"FE2GD_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U7: L+Fe3Gd->τ+Fe2Gd","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1343.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1343.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-X62ARCK3LL","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":15},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.484,"MO":0.131},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe2Gd","model_phase":"FE2GD_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"},{"label":"(Mo)"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U6: L+τ->Fe2Gd+(Mo)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":925.0,"temperature_printed":"925","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":925.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-L5WAUCQJOX","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"τ","model_phase":"C14_LAVES","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"Fe2Gd","model_phase":"FE2GD_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"},{"label":"(Mo)"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U6: L+τ->Fe2Gd+(Mo)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1123.0,"temperature_uncertainty":{"basis":"printed","value":15.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":15.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":15.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1123.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-F5UA233X72","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":17},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.487,"MO":0.13},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe2Gd","model_phase":"FE2GD_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"},{"label":"Gd"},{"label":"(Mo)"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"E2: L->Fe2Gd+Gd+(Mo)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":920.0,"temperature_printed":"920","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":920.0},{"chemical_system":"FE-GD-MO","cited_sources":[{"first_author":"Zinkevitch","kind":"unknown","label":"5","reference":"Zinkevitch M, Mattern N, Wendrock H, Behr G, Wetzig K. J Alloys Compd 1999: 283: 265–281.","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-H2BWUYMELN","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fe2Gd","model_phase":"FE2GD_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"},{"label":"Gd"},{"label":"(Mo)"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"E2: L->Fe2Gd+Gd+(Mo)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":923.0,"temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":923.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-D42XDZUZOH","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5","row":19},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GD":0.123,"MO":0.005},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"fccFe"},{"label":"bccFe"},{"label":"Fe17Gd2"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p5/tab-5/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U9: L+fccFe->bccFe+Fe17Gd2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":1604.0,"temperature_printed":"1604","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1604.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-AML6SBWS7S","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p13/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p13/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The first step of the ternary optimization was to obtain the invariant equilibrium Liquid ⇔ Fe2Gd π Gd π (Mo) at around 923 K and the corresponding three phase field Fe2Gd π Gd π (Mo) below the eutectic temperature.","quote_page":13,"reaction":{"printed":"Liquid ⇔ Fe2Gd π Gd π (Mo)","type":"eutectic"},"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":923.0,"temperature_printed":"923 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":923.0},{"chemical_system":"FE-GD-MO","conditions":{"kind":"paper_context","paper":"doi:10.1034/j.1600-0692.2002.311310106.x"},"corrections":[{"after":["Fe61.0Gd9.3Mo29.7"],"before":[],"evidence":{"basis":"one_compound_magnetic","quote_page":6},"field":"phases","gate":"R3","rule":"state_phases_from_quote"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phases_recovered_from_quote"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"phases_recovered_from_quote","detail":"phases read from the quote (one_compound_magnetic); not mapped to model phases","effect":"not_espei_ready","gate":"R3"}],"id":"ORC-ZOFQE6OI3U","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1034/j.1600-0692.2002.311310106.x/p6/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1034/j.1600-0692.2002.311310106.x","own_work_of_paper":true},"paper":"doi:10.1034/j.1600-0692.2002.311310106.x","paper_id":"doi:10.1034/j.1600-0692.2002.311310106.x","phases":[{"label":"Fe61.0Gd9.3Mo29.7","label_source":"quote"}],"pid":"doi:10.1034/j.1600-0692.2002.311310106.x/p6/text-02/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"For the sample of composition Fe61.0Gd9.3Mo29.7 a second order phase transition at TΩ229 K has been detected (Fig. 8), which can be associated with the vanishing of magnetic ordering.","quote_page":6,"reaction":{"type":"magnetic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"FE-GD-MO","system":"FE-GD-MO","temperature_K":229.0,"temperature_printed":"229 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"magnetic","transition_kind_printed":"magnetic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":229.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"FE-GD-MO"}