{"artifacts":{"doi:10.1007/s11669-009-9501-6/p1/text-04":{"artifact":"text_passage","label":"page 1, passage 4","page":1},"doi:10.1007/s11669-009-9501-6/p12/text-10":{"artifact":"text_passage","label":"page 12, passage 10","page":12},"doi:10.1007/s11669-009-9501-6/p9/text-02":{"artifact":"text_passage","label":"page 9, passage 2","page":9}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["FE","LA"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s11669-009-9501-6":{"authors":["E. Povoden-Karadeniz","A. N. Grundy","M. Chen","T. Ivas","L. J. Gauckler"],"citation":"E. Povoden-Karadeniz, A. N. Grundy, M. Chen, T. Ivas, L. J. Gauckler, Thermodynamic Assessment of the La-Fe-O System, J. Phase Equilib. Diffus. 30, 351-366 (2009).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-009-9501-6","doi_url":"https://doi.org/10.1007/s11669-009-9501-6","id":"doi:10.1007/s11669-009-9501-6","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"2a351be4bf1399f9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessment of the La-Fe-O System","year":2009}},"part":1,"parts":1,"records":[{"chemical_system":"FE-LA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":-179.5313,"before":25745.0,"evidence":{"printed":"Δf,elements°H298 K (LaFe12O19) = −5745 kJ/mol"},"field":"value","gate":"page","rule":"read_from_page","visual_check":{"checked":"2026-10-24","image_sha256":"ef9ba7c216d86007054e375a8b21e023c50294a6c9bade9d37d6b6459280e748","page":1,"pdf_sha256_prefix":"2a351be4bf1399f9","seen":"stored 25745 misread the minus sign as '2'; per formula unit LaFe12O19 (32 atoms): -5745/32 = -179.53 kJ/mol-atom","verdict":"corrected"}},{"after":"kJ/mol-atom","before":"kJ/mol (basis unstated)","evidence":{"printed":"Δf,elements°H298 K (LaFe12O19) = −5745 kJ/mol"},"field":"unit","gate":"page","rule":"read_from_page","visual_check":{"checked":"2026-10-24","image_sha256":"ef9ba7c216d86007054e375a8b21e023c50294a6c9bade9d37d6b6459280e748","page":1,"pdf_sha256_prefix":"2a351be4bf1399f9","seen":"stored 25745 misread the minus sign as '2'; per formula unit LaFe12O19 (32 atoms): -5745/32 = -179.53 kJ/mol-atom","verdict":"corrected"}},{"after":298.15,"before":298.0,"evidence":{"printed":"298 K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-JFYFFAMNMQ","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-009-9501-6/p1/text-04"},"observation_type":"equilibrium_property","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-009-9501-6","own_work_of_paper":true},"paper":"doi:10.1007/s11669-009-9501-6","paper_id":"doi:10.1007/s11669-009-9501-6","pid":"doi:10.1007/s11669-009-9501-6/p1/text-04/s05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"Df,elements°H298 K","quote":"Lanthanum-doped hexaferrite, LaFe12O19, is modeled as a stoichiometric phase. Df,elements°H298 K (LaFe12O19) = 25745 kJ/mol, °S298 K (LaFe12O19) = 683 J/mol Æ K, and Df,oxides°G (LaFe12O19) = 4634 2 37.071T (J/mol) from 1073 to 1723 K are calculated.","quote_page":1,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"FE-LA","system":"FE-LA","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_printed":"298 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":2574.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"unstated","unit_stored":"kJ/mol","value":-179.5313,"value_stored":25745.0},{"chemical_system":"FE-LA","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2NWF5ODITT.107107","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-009-9501-6/p12/text-10"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-009-9501-6","own_work_of_paper":true},"paper":"doi:10.1007/s11669-009-9501-6","paper_id":"doi:10.1007/s11669-009-9501-6","pid":"doi:10.1007/s11669-009-9501-6/p12/text-10/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"r-La1±xFe1±yO3\u0002d melts at 2176 K at pO2 1⁄4 105 Pa; 2136 K is calculated in air.","quote_page":12,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"FE-LA","system":"FE-LA","temperature_K":2136.0,"temperature_printed":"2136 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2136.0},{"chemical_system":"FE-LA","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2NWF5ODITT.2e5f08","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-009-9501-6/p12/text-10"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-009-9501-6","own_work_of_paper":true},"paper":"doi:10.1007/s11669-009-9501-6","paper_id":"doi:10.1007/s11669-009-9501-6","pid":"doi:10.1007/s11669-009-9501-6/p12/text-10/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"r-La1±xFe1±yO3\u0002d melts at 2176 K at pO2 1⁄4 105 Pa; 2136 K is calculated in air.","quote_page":12,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"FE-LA","system":"FE-LA","temperature_K":2176.0,"temperature_printed":"2176 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2176.0},{"chemical_system":"FE-LA","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:2)","effect":"not_accepted","gate":"R3"}],"id":"ORC-SJF23RYVTG.b615fb","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-009-9501-6/p12/text-10"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-009-9501-6","own_work_of_paper":true},"paper":"doi:10.1007/s11669-009-9501-6","paper_id":"doi:10.1007/s11669-009-9501-6","pid":"doi:10.1007/s11669-009-9501-6/p12/text-10/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated eutectic at the LaO1.5-rich side changes from T = 2055 K and 32.0 cat.% Fe in air (Fig. 10b) to 2077 K and 30.9 cat.% in pure oxygen; for the eutectic at the Fe-rich side T = 1704 K and 88.8 cat.% Fe in pure oxygen, and 1701 K and 88.5 cat.% Fe in air are calculated.","quote_page":12,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"FE-LA","system":"FE-LA","temperature_K":2077.0,"temperature_printed":"2077 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2077.0},{"chemical_system":"FE-LA","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:2)","effect":"not_accepted","gate":"R3"}],"id":"ORC-SJF23RYVTG.e933ba","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-009-9501-6/p12/text-10"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-009-9501-6","own_work_of_paper":true},"paper":"doi:10.1007/s11669-009-9501-6","paper_id":"doi:10.1007/s11669-009-9501-6","pid":"doi:10.1007/s11669-009-9501-6/p12/text-10/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated eutectic at the LaO1.5-rich side changes from T = 2055 K and 32.0 cat.% Fe in air (Fig. 10b) to 2077 K and 30.9 cat.% in pure oxygen; 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