{"artifacts":{"sha256:30fb4308ad772cc9/p4/tab-3":{"artifact":"table","caption":"Phase compositions of the Ti-Fe-Mn alloys measured in the present work.","label":"3","page":4},"sha256:30fb4308ad772cc9/p9/tab-6":{"artifact":"table","caption":"Calculated and measured phase constitutions of the reported Ti-Fe-Mn alloys.","label":"6","page":9},"sha256:30fb4308ad772cc9/p9/tab-7":{"artifact":"table","caption":"Calculated and measured phase compositions of the reported Ti–Fe–Mn alloys.","label":"7","page":9}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1016/j.jallcom.2021.161957":{"context_id":"context:source-doi-10-1016-j-jallcom-2021-161957","items":[{"applies_to":"individual phases","extraction_accepted":false,"id":"ORC-RAIZO23YKE","instrument":"JEOL JXA 8900","method":"EPMA","page":2,"quote":"After being grounded and polished, the chemical compositions of individual phases were measured by EPMA on JEOL JXA 8900 with an acceleration voltage of 20 kV and probe current of 20 nA.","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-LNKOUA26MZ","page":2,"purity":"99.99 wt% Ti, 99.99 wt% Fe and 99.95 wt% Mn","quote":"The raw materials used were 99.99 wt% Ti, 99.99 wt% Fe and 99.95 wt% Mn. The alloys were prepared in the non-consumption vacuum melting furnace under an Ar atmosphere.","second_reader_agrees":true,"synthesis":"prepared in the non-consumption vacuum melting furnace under an Ar atmosphere","type":"sample"},{"applies_to":"The blocks","atmosphere_or_container":"sealed in quartz capsules under protection of Ar atmosphere","duration":"480 or 240 h","duration_parsed":{"alternatives_hours":[240.0],"printed":"480 or 240 h"},"extraction_accepted":false,"id":"ORC-APUKKFLDYB","page":2,"purpose":"heated","quote":"The blocks were sealed in quartz capsules under protection of Ar atmosphere and then heated at 1273 or 1373 K in a tube furnace for 480 or 240 h, respectively.","second_reader_agrees":true,"temperature":{"T_K":1373.0,"converted_in_code":false,"printed":"1273 or 1373 K","unit_basis":"printed_with_value","unit_printed":"K","value_printed":1373.0},"temperature_printed":"1273 or 1373 K","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"The ingots","duration":"7 days","duration_parsed":{"hours":168.0,"printed":"7 days"},"extraction_accepted":false,"id":"ORC-F6TIT2FFBL","page":2,"purpose":"homogenized","quote":"The ingots were remelted four times and homogenized at 1373 K for 7 days.","second_reader_agrees":true,"temperature":{"T_K":1373.0,"converted_in_code":false,"printed":"1373 K","unit_basis":"printed_with_value","unit_printed":"K","value_printed":1373.0},"temperature_printed":"1373 K","temperature_status":"parsed_from_printed","type":"treatment"}],"paper":"doi:10.1016/j.jallcom.2021.161957","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"own_work_method_cues"}},"elements":["FE","MN","TI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.jallcom.2020.156075":{"authors":["Erika M. Dematteis","Fermin Cuevas","Michel Latroche"],"citation":"Erika M. Dematteis, Fermin Cuevas, Michel Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, Journal of Alloys and Compounds 851, 156075 (2021).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2020.156075","doi_url":"https://doi.org/10.1016/j.jallcom.2020.156075","id":"doi:10.1016/j.jallcom.2020.156075","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound","year":2021},"doi:10.1016/j.jallcom.2021.161957":{"authors":["Weisen Zheng","Wei Song","Tong Wu","Jingya Wang","Yanlin He","Xiao-Gang Lu"],"citation":"Weisen Zheng, Wei Song, Tong Wu, Jingya Wang, Yanlin He, Xiao-Gang Lu, Experimental investigation and thermodynamic modeling of the ternary Ti–Fe–Mn system for hydrogen storage applications, Journal of Alloys and Compounds 891, 161957 (2022).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2021.161957","doi_url":"https://doi.org/10.1016/j.jallcom.2021.161957","id":"doi:10.1016/j.jallcom.2021.161957","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"30fb4308ad772cc9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental investigation and thermodynamic modeling of the ternary Ti–Fe–Mn system for hydrogen storage applications","year":2022},"doi:10.2320/jinstmet.jc201404":{"authors":["Kouji Sakaki","Hyunjeong Kim","Akihiko Machida","Tetsu Watanuki","Yumiko Nakamura"],"citation":"Kouji Sakaki, Hyunjeong Kim, Akihiko Machida, Tetsu Watanuki, Yumiko Nakamura, Compositional Dependence of Hydrogenation Properties in Ti<sub>1+<i>y</i></sub>(Fe<sub>1−<i>x</i></sub>Mn<sub><i>x</i></sub>)<sub>1−<i>y</i></sub> (0.2≦<i>x</i>≦0.5, 0≦<i>y</i>≦0.08), J.Japan Inst.Metals 79, 112-117 (2015).","container":"J.Japan Inst.Metals","doi":"10.2320/jinstmet.jc201404","doi_url":"https://doi.org/10.2320/jinstmet.jc201404","id":"doi:10.2320/jinstmet.jc201404","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Compositional Dependence of Hydrogenation Properties in Ti<sub>1+<i>y</i></sub>(Fe<sub>1−<i>x</i></sub>Mn<sub><i>x</i></sub>)<sub>1−<i>y</i></sub> (0.2≦<i>x</i>≦0.5, 0≦<i>y</i>≦0.08)","year":2015}},"part":1,"parts":1,"records":[{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase TiFe printed composition {'FE': 0.2371, 'MN': 0.233, 'TI': 0.5299} deviates 0.26 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-ZIXS2FH2OZ","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.1067,"MN":0.1749,"TI":0.7184},"composition_source":"printed","phase":"βTi"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.2371,"MN":0.233,"TI":0.5299},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"βTi"},{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase TiFe printed composition {'FE': 0.2786, 'MN': 0.1857, 'TI': 0.5357} deviates 0.22 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-CS23AKKUJM","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":2},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.1606,"MN":0.1614,"TI":0.678},"composition_source":"printed","phase":"βTi"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.2786,"MN":0.1857,"TI":0.5357},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"βTi"},{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase TiFe printed composition {'FE': 0.295, 'MN': 0.1672, 'TI': 0.5378} deviates 0.21 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-DUSYRDPCWW","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.1331,"MN":0.1294,"TI":0.7375},"composition_source":"printed","phase":"βTi"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.295,"MN":0.1672,"TI":0.5378},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"βTi"},{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-DOCABWOLZS","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.192,"MN":0.0227,"TI":0.7853},"composition_source":"printed","phase":"βTi"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4452,"MN":0.0272,"TI":0.5276},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"βTi"},{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-K4BGA5PXGH","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":6},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.1671,"MN":0.0698,"TI":0.7631},"composition_source":"printed","phase":"βTi"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.3873,"MN":0.0829,"TI":0.5298},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"βTi"},{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase TiFe printed composition {'FE': 0.3254, 'MN': 0.1675, 'TI': 0.5071} deviates 0.17 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-K6VPGIYWQM","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":7},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.3254,"MN":0.1675,"TI":0.5071},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.2244,"MN":0.3774,"TI":0.3982},"composition_source":"printed","phase":"C14 Laves"}],"phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase TiFe printed composition {'FE': 0.3148, 'MN': 0.1688, 'TI': 0.5164} deviates 0.19 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-MP4JHW2N5A","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":8},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.3148,"MN":0.1688,"TI":0.5164},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.2467,"MN":0.3121,"TI":0.4412},"composition_source":"printed","phase":"C14 Laves"}],"phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-VQ626OL2OJ","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":10},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4057,"MN":0.0885,"TI":0.5058},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.3671,"MN":0.2632,"TI":0.3697},"composition_source":"printed","phase":"C14 Laves"}],"phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-SQTWV3O4FA","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":11},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4051,"MN":0.0874,"TI":0.5075},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.379,"MN":0.2235,"TI":0.3975},"composition_source":"printed","phase":"C14 Laves"}],"phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r11#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-54MBRANEEZ","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":13},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4379,"MN":0.3006,"TI":0.2615},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.3931,"MN":0.4679,"TI":0.139},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"C14 Laves"},{"label":"αMn"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r13#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-C5Y5NUAD4Y","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":14},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.466,"MN":0.285,"TI":0.249},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4412,"MN":0.4185,"TI":0.1403},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"C14 Laves"},{"label":"αMn"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r14#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5LONQNO37C","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":16},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.5055,"MN":0.2453,"TI":0.2492},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4864,"MN":0.4044,"TI":0.1092},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"C14 Laves"},{"label":"αMn"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r16#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-NWH3H5FIQP","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":17},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.5039,"MN":0.2495,"TI":0.2466},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4861,"MN":0.3703,"TI":0.1436},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"C14 Laves"},{"label":"αMn"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r17#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5KDVWG3ZH6","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":19},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4685,"MN":0.0137,"TI":0.5178},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4997,"MN":0.1387,"TI":0.3616},"composition_source":"printed","phase":"C14 Laves"}],"phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r19#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-WO2ZRVQBJR","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":20},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4534,"MN":0.0388,"TI":0.5078},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4937,"MN":0.1224,"TI":0.3839},"composition_source":"printed","phase":"C14 Laves"}],"phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r20#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-4A27FN6IAQ","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":22},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.5698,"MN":0.1776,"TI":0.2526},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.584,"MN":0.3032,"TI":0.1128},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"C14 Laves"},{"label":"αMn"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r22#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-BUNSORSAIT","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":23},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.6251,"MN":0.1128,"TI":0.2621},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.7693,"MN":0.1999,"TI":0.0308},"composition_source":"printed","phase":"γFe"}],"phases":[{"label":"C14 Laves"},{"label":"γFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r23#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-QNV2FZYLX5","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":24},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.6252,"MN":0.1097,"TI":0.2651},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.8014,"MN":0.1717,"TI":0.0269},"composition_source":"printed","phase":"γFe"}],"phases":[{"label":"C14 Laves"},{"label":"γFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r24#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"disputed_queued_for_review"},"fold_lpo":4,"fold_lso":0,"id":"ORC-3P5SRUSNWM","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":26},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.7041,"MN":0.0106,"TI":0.2853},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.942,"MN":0.0163,"TI":0.0417},"composition_source":"printed","phase":"αFe"}],"phases":[{"label":"C14 Laves"},{"label":"αFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r26#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-47LWU6GT3V","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":27},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.7074,"MN":0.0073,"TI":0.2853},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.9244,"MN":0.0079,"TI":0.0677},"composition_source":"printed","phase":"αFe"}],"phases":[{"label":"C14 Laves"},{"label":"αFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r27#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-GAKLZ25SJP","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":29},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.661,"MN":0.0729,"TI":0.2661},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.8456,"MN":0.1263,"TI":0.0281},"composition_source":"printed","phase":"γFe"}],"phases":[{"label":"C14 Laves"},{"label":"γFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r29#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-UPGD6NR4QI","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":30},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.6986,"MN":0.0146,"TI":0.2868},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.9522,"MN":0.0191,"TI":0.0287},"composition_source":"printed","phase":"αFe"}],"phases":[{"label":"C14 Laves"},{"label":"αFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r30#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2021.161957"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-G52N2ZBLVL","locator":{"ref":"sha256:30fb4308ad772cc9/p4/tab-3","row":31},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.7038,"MN":0.0159,"TI":0.2803},"composition_source":"printed","phase":"C14 Laves"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.9127,"MN":0.0206,"TI":0.0667},"composition_source":"printed","phase":"αFe"}],"phases":[{"label":"C14 Laves"},{"label":"αFe"}],"pid":"sha256:30fb4308ad772cc9/p4/tab-3/r31#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.2320/jinstmet.jc201404","first_author":"Sakaki","kind":"unknown","label":"14","paper":"doi:10.2320/jinstmet.jc201404","reference":"K. Sakaki, H. Kim, A. Machida, T. Watanuki, Y. Nakamura, Compositional dependence of hydrogenation properties in Ti1+y(Fe1-xMnx)1-y (0.2≤x≤0.5, 0≤y≤0.08), J. Jpn. Inst. Met. Mater. 79 (2015) 112–117.","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-AEMYB6CT54","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":1},"observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.4,"MN":0.1,"TI":0.5},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r01#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","temperature_printed":"1373","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-N6IJYSSCTB","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":2},"observation_type":"phase_assemblage_node","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"overall_composition":{"FE":0.4,"MN":0.1,"TI":0.5},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r02#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","temperature_printed":"1373","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.2320/jinstmet.jc201404","first_author":"Sakaki","kind":"unknown","label":"14","paper":"doi:10.2320/jinstmet.jc201404","reference":"K. Sakaki, H. Kim, A. Machida, T. Watanuki, Y. Nakamura, Compositional dependence of hydrogenation properties in Ti1+y(Fe1-xMnx)1-y (0.2≤x≤0.5, 0≤y≤0.08), J. Jpn. Inst. Met. Mater. 79 (2015) 112–117.","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-TS77PF55N7","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":3},"observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.35,"MN":0.15,"TI":0.5},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r03#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","temperature_printed":"1373","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5EGBYKVZJT","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":4},"observation_type":"phase_assemblage_node","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"overall_composition":{"FE":0.35,"MN":0.15,"TI":0.5},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r04#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1373.0,"temperature_basis":"printed","temperature_printed":"1373","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.2320/jinstmet.jc201404","first_author":"Sakaki","kind":"unknown","label":"14","paper":"doi:10.2320/jinstmet.jc201404","reference":"K. Sakaki, H. Kim, A. Machida, T. Watanuki, Y. Nakamura, Compositional dependence of hydrogenation properties in Ti1+y(Fe1-xMnx)1-y (0.2≤x≤0.5, 0≤y≤0.08), J. Jpn. Inst. Met. Mater. 79 (2015) 112–117.","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-ZVP4I3DZ5I","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":5},"observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.28,"MN":0.2,"TI":0.52},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r05#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","temperature_printed":"1273","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-A6LUXI5XDE","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":6},"observation_type":"phase_assemblage_node","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"overall_composition":{"FE":0.28,"MN":0.2,"TI":0.52},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r06#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","temperature_printed":"1273","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.2320/jinstmet.jc201404","first_author":"Sakaki","kind":"unknown","label":"14","paper":"doi:10.2320/jinstmet.jc201404","reference":"K. Sakaki, H. Kim, A. Machida, T. Watanuki, Y. Nakamura, Compositional dependence of hydrogenation properties in Ti1+y(Fe1-xMnx)1-y (0.2≤x≤0.5, 0≤y≤0.08), J. Jpn. Inst. Met. Mater. 79 (2015) 112–117.","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-7CBRDIS6TS","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":7},"observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.25,"MN":0.22,"TI":0.53},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r07#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","temperature_printed":"1273","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-RJMFMG5ZWI","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":8},"observation_type":"phase_assemblage_node","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"overall_composition":{"FE":0.25,"MN":0.22,"TI":0.53},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r08#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","temperature_printed":"1273","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.2320/jinstmet.jc201404","first_author":"Sakaki","kind":"unknown","label":"14","paper":"doi:10.2320/jinstmet.jc201404","reference":"K. Sakaki, H. Kim, A. Machida, T. Watanuki, Y. Nakamura, Compositional dependence of hydrogenation properties in Ti1+y(Fe1-xMnx)1-y (0.2≤x≤0.5, 0≤y≤0.08), J. Jpn. Inst. Met. Mater. 79 (2015) 112–117.","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-VI47KPWHPJ","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":9},"observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.23,"MN":0.23,"TI":0.54},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"},{"label":"unidentified phase"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r09#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","temperature_printed":"1273","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-44JYM5VSX5","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-6","row":10},"observation_type":"phase_assemblage_node","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"overall_composition":{"FE":0.23,"MN":0.23,"TI":0.54},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"TiFe"},{"label":"βTi"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-6/r10#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","temperature_printed":"1273","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-T2PFCL6J4D","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.463,"MN":0.011,"TI":0.526},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.466,"MN":0.011,"TI":0.523},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.1999,"MN":0.0143,"TI":0.7858},"composition_source":"printed","phase":"βTi"}],"phases":[{"label":"TiFe"},{"label":"βTi"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-IFEKN7AR5A","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":2},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.488,"MN":0.024,"TI":0.488},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4785,"MN":0.0214,"TI":0.5001},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.6047,"MN":0.0557,"TI":0.3396},"composition_source":"printed","phase":"C14 Laves"}],"phases":[{"label":"TiFe"},{"label":"C14 Laves"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-OKJHXMFI5A","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":3},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.475,"MN":0.025,"TI":0.5},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.475,"MN":0.025,"TI":0.5},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-7MX7CXBA26","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.462,"MN":0.026,"TI":0.513},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.462,"MN":0.026,"TI":0.512},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-6KH6BOO6L3","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.447,"MN":0.026,"TI":0.526},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4475,"MN":0.026,"TI":0.5265},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.1969,"MN":0.0267,"TI":0.7764},"composition_source":"printed","phase":"βTi"}],"phases":[{"label":"TiFe"},{"label":"βTi"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-CNC56DGHAQ","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":6},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.432,"MN":0.027,"TI":0.541},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4463,"MN":0.027,"TI":0.5267},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.1967,"MN":0.0273,"TI":0.776},"composition_source":"printed","phase":"βTi"}],"phases":[{"label":"TiFe"},{"label":"βTi"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-UHALPCPQ6Z","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":7},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.45,"MN":0.05,"TI":0.5},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.45,"MN":0.05,"TI":0.5},"composition_source":"printed","phase":"TiFe"}],"phases":[{"label":"TiFe"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"FE-MN-TI","cited_sources":[{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"2","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, F. Cuevas, M. Latroche, Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound, J. Alloys Compd. 851 (2021) 156075.","status":"resolved","year":"2021"},{"doi":"10.1016/j.jallcom.2020.156075","first_author":"Dematteis","kind":"unknown","label":"45","paper":"doi:10.1016/j.jallcom.2020.156075","reference":"E.M. Dematteis, D.M. Dreistadt, G. Capurso, J. Jepsen, F. Cuevas, M. Latroche, Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn, J. Alloys Compd. 874 (2021) 159925. 12","status":"resolved","year":"2021"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-QN22OWIJAZ","locator":{"ref":"sha256:30fb4308ad772cc9/p9/tab-7","row":8},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"FE":0.421,"MN":0.053,"TI":0.526},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.4213,"MN":0.047,"TI":0.5317},"composition_source":"printed","phase":"TiFe"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"FE":0.17,"MN":0.05,"TI":0.78},"composition_source":"printed","phase":"βTi"}],"phases":[{"label":"TiFe"},{"label":"βTi"}],"pid":"sha256:30fb4308ad772cc9/p9/tab-7/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-TI","system":"FE-MN-TI","temperature_K":1273.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"FE-MN-TI"}