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Composition from formula FeNb4P (Fe 1/6, Nb 4/6, P 1/6) in the sibling convention (keys NB,P; 6 digits); structure in the batch convention {phase, space_group} with the printed P4/mcc.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t133"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"614dd225951991c371c68345ae9007d54ee7af3abe8f858d27fa8e833a8de0aa","page":4,"pdf_sha256_prefix":"691a61712b92a113","seen":"r17 a 0.616 c 0.503 = calculated cell, r18 a 0.613 c 0.5006 = observed cell of the FeNb4P row (last row, 300 dpi crop: subscript 4 on Nb clear).","verdict":"confirmed"}},{"after":{"phase":"FeNb4P","space_group":"P4/mcc"},"before":null,"evidence":{"class":"phase","decision_file":"phase_t133.json","doi":"10.2355/isijinternational.49.947","pdf_page":4,"pdf_sha256":"691a61712b92a113b51a63f5d4017ad8550312bf5d270a8dbeb1f78b5f47ab29","printed":"FeNb4P | stable | P4/mcc | a = 0.6160 c = 0.5030 | a = 0.6130 c = 0.5006 | −48.6","rationale":"Values are printed only on the FeNb4P row; FeNbP row values are r15/r16 (a,b,c). Composition from formula FeNb4P (Fe 1/6, Nb 4/6, P 1/6) in the sibling convention (keys NB,P; 6 digits); structure in the batch convention {phase, space_group} with the printed P4/mcc.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t133"},"field":"structure","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"614dd225951991c371c68345ae9007d54ee7af3abe8f858d27fa8e833a8de0aa","page":4,"pdf_sha256_prefix":"691a61712b92a113","seen":"r17 a 0.616 c 0.503 = calculated cell, r18 a 0.613 c 0.5006 = observed cell of the FeNb4P row (last row, 300 dpi crop: subscript 4 on Nb clear).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-TU624ULLNW.1b173c","locator":{"ref":"doi:10.2355/isijinternational.49.947/p4/tab-1","row":17},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.2355/isijinternational.49.947","own_work_of_paper":true},"overall_composition":{"NB":0.666667,"P":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.2355/isijinternational.49.947","paper_id":"doi:10.2355/isijinternational.49.947","phases":[{"label":"FeNb4P","label_source":"printed_source_page"}],"pid":"doi:10.2355/isijinternational.49.947/p4/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-NB-P","structure":{"phase":"FeNb4P","space_group":"P4/mcc"},"system":"FE-NB-P","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04743,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04743},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.16,"value_stored":0.616},{"chemical_system":"FE-NB-P","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"FeNb4P","label_source":"printed_source_page"}],"before":[{"label":"FeNbP"}],"evidence":{"class":"phase","decision_file":"phase_t133.json","doi":"10.2355/isijinternational.49.947","pdf_page":4,"pdf_sha256":"691a61712b92a113b51a63f5d4017ad8550312bf5d270a8dbeb1f78b5f47ab29","printed":"FeNb4P | stable | P4/mcc | a = 0.6160 c = 0.5030 | a = 0.6130 c = 0.5006 | −48.6","rationale":"Values are printed only on the FeNb4P row; FeNbP row values are r15/r16 (a,b,c). 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Composition from formula FeNb4P (Fe 1/6, Nb 4/6, P 1/6) in the sibling convention (keys NB,P; 6 digits); structure in the batch convention {phase, space_group} with the printed P4/mcc.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t133"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"614dd225951991c371c68345ae9007d54ee7af3abe8f858d27fa8e833a8de0aa","page":4,"pdf_sha256_prefix":"691a61712b92a113","seen":"r17 a 0.616 c 0.503 = calculated cell, r18 a 0.613 c 0.5006 = observed cell of the FeNb4P row (last row, 300 dpi crop: subscript 4 on Nb clear).","verdict":"confirmed"}},{"after":{"phase":"FeNb4P","space_group":"P4/mcc"},"before":null,"evidence":{"class":"phase","decision_file":"phase_t133.json","doi":"10.2355/isijinternational.49.947","pdf_page":4,"pdf_sha256":"691a61712b92a113b51a63f5d4017ad8550312bf5d270a8dbeb1f78b5f47ab29","printed":"FeNb4P | stable | P4/mcc | a = 0.6160 c = 0.5030 | a = 0.6130 c = 0.5006 | −48.6","rationale":"Values are printed only on the FeNb4P row; FeNbP row values are r15/r16 (a,b,c). Composition from formula FeNb4P (Fe 1/6, Nb 4/6, P 1/6) in the sibling convention (keys NB,P; 6 digits); structure in the batch convention {phase, space_group} with the printed P4/mcc.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t133"},"field":"structure","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"614dd225951991c371c68345ae9007d54ee7af3abe8f858d27fa8e833a8de0aa","page":4,"pdf_sha256_prefix":"691a61712b92a113","seen":"r17 a 0.616 c 0.503 = calculated cell, r18 a 0.613 c 0.5006 = observed cell of the FeNb4P row (last row, 300 dpi crop: subscript 4 on Nb clear).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-TU624ULLNW.f47870","locator":{"ref":"doi:10.2355/isijinternational.49.947/p4/tab-1","row":17},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.2355/isijinternational.49.947","own_work_of_paper":true},"overall_composition":{"NB":0.666667,"P":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.2355/isijinternational.49.947","paper_id":"doi:10.2355/isijinternational.49.947","phases":[{"label":"FeNb4P","label_source":"printed_source_page"}],"pid":"doi:10.2355/isijinternational.49.947/p4/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-NB-P","structure":{"phase":"FeNb4P","space_group":"P4/mcc"},"system":"FE-NB-P","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03873,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03873},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.03,"value_stored":0.503},{"chemical_system":"FE-NB-P","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.2355/isijinternational.49.947"},"corrections":[{"after":[{"label":"FeNb4P","label_source":"printed_source_page"}],"before":[{"label":"FeNbP"}],"evidence":{"class":"phase","decision_file":"phase_t133.json","doi":"10.2355/isijinternational.49.947","pdf_page":4,"pdf_sha256":"691a61712b92a113b51a63f5d4017ad8550312bf5d270a8dbeb1f78b5f47ab29","printed":"FeNb4P | stable | P4/mcc | a = 0.6160 c = 0.5030 | a = 0.6130 c = 0.5006 | −48.6","rationale":"Values are printed only on the FeNb4P row; FeNbP row values are r15/r16 (a,b,c). 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Composition from formula FeNb4P (Fe 1/6, Nb 4/6, P 1/6) in the sibling convention (keys NB,P; 6 digits); structure in the batch convention {phase, space_group} with the printed P4/mcc.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t133"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"614dd225951991c371c68345ae9007d54ee7af3abe8f858d27fa8e833a8de0aa","page":4,"pdf_sha256_prefix":"691a61712b92a113","seen":"r17 a 0.616 c 0.503 = calculated cell, r18 a 0.613 c 0.5006 = observed cell of the FeNb4P row (last row, 300 dpi crop: subscript 4 on Nb clear).","verdict":"confirmed"}},{"after":{"phase":"FeNb4P","space_group":"P4/mcc"},"before":null,"evidence":{"class":"phase","decision_file":"phase_t133.json","doi":"10.2355/isijinternational.49.947","pdf_page":4,"pdf_sha256":"691a61712b92a113b51a63f5d4017ad8550312bf5d270a8dbeb1f78b5f47ab29","printed":"FeNb4P | stable | P4/mcc | a = 0.6160 c = 0.5030 | a = 0.6130 c = 0.5006 | −48.6","rationale":"Values are printed only on the FeNb4P row; FeNbP row values are r15/r16 (a,b,c). 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Composition from formula FeNb4P (Fe 1/6, Nb 4/6, P 1/6) in the sibling convention (keys NB,P; 6 digits); structure in the batch convention {phase, space_group} with the printed P4/mcc.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t133"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"614dd225951991c371c68345ae9007d54ee7af3abe8f858d27fa8e833a8de0aa","page":4,"pdf_sha256_prefix":"691a61712b92a113","seen":"r17 a 0.616 c 0.503 = calculated cell, r18 a 0.613 c 0.5006 = observed cell of the FeNb4P row (last row, 300 dpi crop: subscript 4 on Nb clear).","verdict":"confirmed"}},{"after":{"NB":0.666667,"P":0.166667},"before":{"NB":0.333333,"P":0.333333},"evidence":{"class":"phase","decision_file":"phase_t133.json","doi":"10.2355/isijinternational.49.947","pdf_page":4,"pdf_sha256":"691a61712b92a113b51a63f5d4017ad8550312bf5d270a8dbeb1f78b5f47ab29","printed":"FeNb4P | stable | P4/mcc | a = 0.6160 c = 0.5030 | a = 0.6130 c = 0.5006 | −48.6","rationale":"Values are printed only on the FeNb4P row; FeNbP row values are r15/r16 (a,b,c). Composition from formula FeNb4P (Fe 1/6, Nb 4/6, P 1/6) in the sibling convention (keys NB,P; 6 digits); structure in the batch convention {phase, space_group} with the printed P4/mcc.","report_id":"ORCHID-TD-20261028-v1","table":"1","table_key":"t133"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"614dd225951991c371c68345ae9007d54ee7af3abe8f858d27fa8e833a8de0aa","page":4,"pdf_sha256_prefix":"691a61712b92a113","seen":"r17 a 0.616 c 0.503 = calculated cell, r18 a 0.613 c 0.5006 = observed cell of the FeNb4P row (last row, 300 dpi crop: subscript 4 on Nb clear).","verdict":"confirmed"}},{"after":{"phase":"FeNb4P","space_group":"P4/mcc"},"before":null,"evidence":{"class":"phase","decision_file":"phase_t133.json","doi":"10.2355/isijinternational.49.947","pdf_page":4,"pdf_sha256":"691a61712b92a113b51a63f5d4017ad8550312bf5d270a8dbeb1f78b5f47ab29","printed":"FeNb4P | stable | P4/mcc | a = 0.6160 c = 0.5030 | a = 0.6130 c = 0.5006 | −48.6","rationale":"Values are printed only on the FeNb4P row; FeNbP row values are r15/r16 (a,b,c). 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