{"artifacts":{"doi:10.1016/j.intermet.2013.12.009/p1/text-11":{"artifact":"text_passage","label":"page 1, passage 11","page":1},"doi:10.1016/j.intermet.2013.12.009/p2/text-15":{"artifact":"text_passage","label":"page 2, passage 15","page":2},"doi:10.1016/j.intermet.2013.12.009/p2/text-16":{"artifact":"text_passage","label":"page 2, passage 16","page":2},"doi:10.1016/j.intermet.2013.12.009/p2/text-17":{"artifact":"text_passage","label":"page 2, passage 17","page":2},"doi:10.1016/j.intermet.2013.12.009/p3/tab-2":{"artifact":"table","caption":"Temperature and composition of the phases involved in the reactions; ND means “no data”.","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23735569},\n url = {https://doi.org/10.5281/zenodo.23735569},\n note = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID data: umbrella record of the ORCHID datasets}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23736065},\n url = {https://doi.org/10.5281/zenodo.23736065},\n note = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["GE","MN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M624fd2b6":{"catalog_entry":{"license":"CC BY 4.0","name":"GeMn-14Ber.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"A. Berche, J.-C. Tedenac, P. Jund, Intermetallics, 47, 23-30(2014).","model_doi":"10.1016/j.intermet.2013.12.009","reproduced_by_calculation":true,"tdb":"GeMn-14Ber.tdb","tdb_path":"databases/sgte-binary/GeMn-14Ber.tdb","tdb_sha256":"4243bd74c559c91eeb7c71acf2cbf638400c8237a00c1f75d3c66f8b80d563b3"},"Mc4a3a27c":{"catalog_entry":{"license":"CC BY 4.0","name":"GeMn-14Ber.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"A. Berche, J.-C. Tedenac, P. Jund, Intermetallics, 47, 23-30(2014).","model_doi":"10.1016/j.intermet.2013.12.009","reproduced_by_calculation":false,"tdb":"GeMn-14Ber.tdb","tdb_path":"databases/sgte-binary/GeMn-14Ber.tdb","tdb_sha256":"4243bd74c559c91eeb7c71acf2cbf638400c8237a00c1f75d3c66f8b80d563b3"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0022-5088(70)90030-5":{"authors":["S.K. Gupta","K.P. Gupta"],"citation":"S.K. Gupta, K.P. Gupta, Phase equilibria in the Manganese-Germanium system in the composition range 20–35 at.% Germanium, Journal of the Less Common Metals 20, 1-6 (1970).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(70)90030-5","doi_url":"https://doi.org/10.1016/0022-5088(70)90030-5","id":"doi:10.1016/0022-5088(70)90030-5","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase equilibria in the Manganese-Germanium system in the composition range 20–35 at.% Germanium","year":1970},"doi:10.1016/j.intermet.2013.12.009":{"authors":["A. Berche","J.C. Tedenac","P. Jund"],"citation":"A. Berche, J.C. Tedenac, P. Jund, Thermodynamic modeling of the germanium–manganese system, Intermetallics 47, 23-30 (2014).","container":"Intermetallics","doi":"10.1016/j.intermet.2013.12.009","doi_url":"https://doi.org/10.1016/j.intermet.2013.12.009","id":"doi:10.1016/j.intermet.2013.12.009","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"a16cf97190fe1c74","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of the germanium–manganese system","year":2014},"doi:10.1021/ja01152a518":{"authors":["James H. Downing","Daniel Cubicciotti"],"citation":"James H. Downing, Daniel Cubicciotti, On the Freezing Point Diagram of the Germanium—Manganese System, J. Am. Chem. Soc. 73, 4025-4025 (1951).","container":"J. Am. Chem. Soc.","doi":"10.1021/ja01152a518","doi_url":"https://doi.org/10.1021/ja01152a518","id":"doi:10.1021/ja01152a518","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"On the Freezing Point Diagram of the Germanium—Manganese System","year":1951},"doi:10.1103/physrevb.83.174103":{"authors":["Emmanuel Arras","Damien Caliste","Thierry Deutsch","Frédéric Lançon","Pascal Pochet"],"citation":"Emmanuel Arras, Damien Caliste, Thierry Deutsch, Frédéric Lançon, Pascal Pochet, Phase diagram, structure, and magnetic properties of the Ge-Mn system: A first-principles study, Phys. Rev. B 83 (2011).","container":"Phys. Rev. B","doi":"10.1103/physrevb.83.174103","doi_url":"https://doi.org/10.1103/physrevb.83.174103","id":"doi:10.1103/physrevb.83.174103","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase diagram, structure, and magnetic properties of the Ge-Mn system: A first-principles study","year":2011},"doi:10.1143/jpsj.16.1995":{"authors":["Tetuo Ohoyama"],"citation":"Tetuo Ohoyama, X-ray and Magnetic Studies of the Manganese-Germanium System, J. Phys. Soc. Jpn. 16, 1995-2002 (1961).","container":"J. Phys. Soc. Jpn.","doi":"10.1143/jpsj.16.1995","doi_url":"https://doi.org/10.1143/jpsj.16.1995","id":"doi:10.1143/jpsj.16.1995","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"X-ray and Magnetic Studies of the Manganese-Germanium System","year":1961}},"part":1,"parts":1,"records":[{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-KHVJDKYZHR","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":1},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.475},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.0},"composition_source":"printed","phase":"DIAMOND"},{"basis":"mole_fraction","composition":{"MN":0.6},"composition_source":"printed","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"DIAMOND","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = DIAMOND + Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":970.0,"temperature_printed":"970","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":970.0},{"chemical_system":"GE-MN","cited_sources":[{"doi":"10.1021/ja01152a518","first_author":"Downing","kind":"unknown","label":"21","paper":"doi:10.1021/ja01152a518","reference":"Downing JH, Cubicciotti D. On the freezing point diagram of the germaniume manganese system. J Am Chem Soc 1951;73(8):4025.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-HDIHLT22IK","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":2},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.36},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"GE":0.421053,"MN":0.578947},"composition_source":"stoichiometric_model_phase","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"DIAMOND","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = DIAMOND + Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":993.0,"temperature_printed":"993","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":993.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-H6K6YJQ74V","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":3},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.43},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.0},"composition_source":"printed","phase":"DIAMOND"},{"basis":"mole_fraction","composition":{"MN":0.6},"composition_source":"printed","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"DIAMOND","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = DIAMOND + Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":993.0,"temperature_printed":"993","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":993.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Laridjani","kind":"unknown","label":"23","reference":"Laridjani M, Bigare M, Guinier A. Study of the intermediate phases in the Mne Ge system. Mém Sci Rev Métall 1970;67(10):675e9.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-ZR6RNOD7QM","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":4},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.58},"composition_source":"printed","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"DIAMOND","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = DIAMOND + Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1005.0,"temperature_printed":"1005","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1005.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-G3TKVFYJJ6","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":5},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.416},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.0},"composition_source":"printed","phase":"DIAMOND"},{"basis":"mole_fraction","composition":{"MN":0.579},"composition_source":"printed","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"DIAMOND","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = DIAMOND + Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":991.0,"temperature_printed":"991","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":991.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-V7LVLC5MRI","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":6},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.495},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.6},"composition_source":"printed","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Mn5Ge3 = Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1018.0,"temperature_printed":"1018","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1018.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-FUQ66TNHXJ","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":7},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.48},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.6},"composition_source":"printed","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Mn5Ge3 = Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1069.0,"temperature_printed":"1069","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1069.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-T4MHH4ETKL","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":8},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.485},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.579},"composition_source":"printed","phase":"Mn11Ge8"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn11Ge8","model_phase":"GE8MN11","pearson_symbol":"oP76","prototype":"Cr11Ge8","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Mn5Ge3 = Mn11Ge8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1070.0,"temperature_printed":"1070","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1070.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-327FEW4LHJ","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":9},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge3","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1205.0,"temperature_printed":"1205","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1205.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-DUH4CCQXAL","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":10},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge3","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1239.0,"temperature_printed":"1239","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1239.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-5BHUGYHJJ5","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":11},"model":"Mc4a3a27c","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge3","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1235.0,"temperature_printed":"1235","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1235.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-CPENXN4TFN","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":12},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.375,"MN":0.625},"composition_source":"stoichiometric_model_phase","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"GE":0.333333,"MN":0.666667},"composition_source":"formula_nominal","phase":"Mn2Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge3 + Mn2Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1170.0,"temperature_printed":"1170","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1170.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-UVNJBOVBJF","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":13},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.644},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.628},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.655},"composition_source":"printed","phase":"Mn2Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge3 + Mn2Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1219.0,"temperature_printed":"1219","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1219.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-SKDHAA3JGQ","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":14},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.648},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.661},"composition_source":"printed","phase":"Mn2Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge3 + Mn2Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1229.0,"temperature_printed":"1229","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1229.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-RHMYF72DD2","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":15},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.666},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.666},"composition_source":"printed","phase":"Mn2Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn2Ge","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1238.0,"temperature_printed":"1238","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1238.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-KE65FGXUTM","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":16},"model":"Mc4a3a27c","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.663},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.663},"composition_source":"printed","phase":"Mn2Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn2Ge","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1234.0,"temperature_printed":"1234","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1234.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-HZS4I6O6FB","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":17},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.667},"composition_source":"printed","phase":"Mn2Ge"},{"basis":"mole_fraction","composition":{"MN":0.628},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.716},"composition_source":"printed","phase":"Mn5Ge2"}],"phases":[{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn2Ge = Mn5Ge3 + Mn5Ge2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1063.0,"temperature_printed":"1063","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1063.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-ZPTHYE4M32","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":18},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.67},"composition_source":"printed","phase":"Mn2Ge"},{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.711},"composition_source":"printed","phase":"Mn5Ge2"}],"phases":[{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn2Ge = Mn5Ge3 + Mn5Ge2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1066.0,"temperature_printed":"1066","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1066.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-VO3SXYKKFF","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":19},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.695},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.68},"composition_source":"printed","phase":"Mn2Ge"},{"basis":"mole_fraction","composition":{"MN":0.706},"composition_source":"printed","phase":"Mn5Ge2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn2Ge + Mn5Ge2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1208.0,"temperature_printed":"1208","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1208.0},{"chemical_system":"GE-MN","cited_sources":[{"doi":"10.1016/0022-5088(70)90030-5","first_author":"Gupta","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(70)90030-5","reference":"Gupta SI, Gupta KP. Phase equilibria in the manganese germanium system in the composition range 20e35 at.% Ge. J Less Common Met 1970;20:1e6.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-IEF3PPIMCJ","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":20},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.333333,"MN":0.666667},"composition_source":"formula_nominal","phase":"Mn2Ge"},{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"formula_nominal","phase":"Mn5Ge2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn2Ge + Mn5Ge2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1198.0,"temperature_printed":"1198","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1198.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-FL7IVWVK2Y","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":21},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.699},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.675},"composition_source":"printed","phase":"Mn2Ge"},{"basis":"mole_fraction","composition":{"MN":0.711},"composition_source":"printed","phase":"Mn5Ge2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn2Ge","model_phase":"GEMN2_B82","pearson_symbol":"hP6","prototype":"InNi2","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn2Ge + Mn5Ge2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1213.0,"temperature_printed":"1213","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1213.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-SBMOALENUK","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":22},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.628},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.717},"composition_source":"printed","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.7},"composition_source":"printed","phase":"LT_Mn5Ge2"}],"phases":[{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"LT_Mn5Ge2","model_phase":"GE2MN5_LT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn5Ge3 + Mn5Ge2 = LT_Mn5Ge2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":963.0,"temperature_printed":"963","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":963.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-AIL2TPMT7T","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":23},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.625},"composition_source":"printed","phase":"Mn5Ge3"},{"basis":"mole_fraction","composition":{"MN":0.714},"composition_source":"printed","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.714},"composition_source":"printed","phase":"LT_Mn5Ge2"}],"phases":[{"label":"Mn5Ge3","model_phase":"GE3MN5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"LT_Mn5Ge2","model_phase":"GE2MN5_LT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn5Ge3 + Mn5Ge2 = LT_Mn5Ge2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":934.0,"temperature_printed":"934","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":934.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-7MNNYOYXKM","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":24},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"congruent_same_composition","phase":"Liquid"},{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"formula_nominal","phase":"Mn5Ge2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1193.0,"temperature_printed":"1193","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1193.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-JO43LTKLYY","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":25},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.715},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.715},"composition_source":"printed","phase":"Mn5Ge2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1226.0,"temperature_printed":"1226","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1226.0},{"chemical_system":"GE-MN","cited_sources":[{"doi":"10.1016/0022-5088(70)90030-5","first_author":"Gupta","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(70)90030-5","reference":"Gupta SI, Gupta KP. Phase equilibria in the manganese germanium system in the composition range 20e35 at.% Ge. J Less Common Met 1970;20:1e6.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-IASTXVHNPR","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":26},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"congruent_same_composition","phase":"Liquid"},{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"formula_nominal","phase":"Mn5Ge2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1223.0,"temperature_printed":"1223","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1223.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-QLONLEYCDR","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":27},"model":"Mc4a3a27c","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.718},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.718},"composition_source":"printed","phase":"Mn5Ge2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1220.0,"temperature_printed":"1220","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1220.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-RJNOQN3QZY","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":28},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"formula_nominal","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"stoichiometric_model_phase","phase":"LT_Mn5Ge2"},{"basis":"mole_fraction","composition":{"GE":0.25,"MN":0.75},"composition_source":"stoichiometric_model_phase","phase":"LT_Mn3Ge"}],"phases":[{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"LT_Mn5Ge2","model_phase":"GE2MN5_LT"},{"label":"LT_Mn3Ge","model_phase":"GEMN3_D022"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn5Ge2 = LT_Mn5Ge2 + LT_Mn3Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":903.0,"temperature_printed":"903","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":903.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-2VQZAK7HZA","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":29},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.718},"composition_source":"printed","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.7},"composition_source":"printed","phase":"LT_Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.765},"composition_source":"printed","phase":"LT_Mn3Ge"}],"phases":[{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"LT_Mn5Ge2","model_phase":"GE2MN5_LT"},{"label":"LT_Mn3Ge","model_phase":"GEMN3_D022"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r29#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn5Ge2 = LT_Mn5Ge2 + LT_Mn3Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":893.0,"temperature_printed":"893","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":893.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-NJLZXQKTTT","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":30},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.717},"composition_source":"printed","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.714},"composition_source":"printed","phase":"LT_Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.75},"composition_source":"printed","phase":"LT_Mn3Ge"}],"phases":[{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"LT_Mn5Ge2","model_phase":"GE2MN5_LT"},{"label":"LT_Mn3Ge","model_phase":"GEMN3_D022"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r30#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn5Ge2 = LT_Mn5Ge2 + LT_Mn3Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":910.0,"temperature_printed":"910","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":910.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-DPFYY3H7UT","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":31},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"formula_nominal","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"GE":0.25,"MN":0.75},"composition_source":"formula_nominal","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r31#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2 + Mn3Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1170.0,"temperature_printed":"1170","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1170.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-YFEGPALMZT","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":32},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.76},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.765},"composition_source":"printed","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.732},"composition_source":"printed","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2 + Mn3Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1185.0,"temperature_printed":"1185","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1185.0},{"chemical_system":"GE-MN","cited_sources":[{"doi":"10.1016/0022-5088(70)90030-5","first_author":"Gupta","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(70)90030-5","reference":"Gupta SI, Gupta KP. Phase equilibria in the manganese germanium system in the composition range 20e35 at.% Ge. J Less Common Met 1970;20:1e6.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-5HDCE7KGPD","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":33},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.285714,"MN":0.714286},"composition_source":"formula_nominal","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"GE":0.25,"MN":0.75},"composition_source":"formula_nominal","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r33#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2 + Mn3Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1195.0,"temperature_printed":"1195","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1195.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-GLO3CTAX3V","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":34},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.753},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.734},"composition_source":"printed","phase":"Mn5Ge2"},{"basis":"mole_fraction","composition":{"MN":0.762},"composition_source":"printed","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn5Ge2","model_phase":"GE2MN5_HT"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r34#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn5Ge2 + Mn3Ge"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1194.0,"temperature_printed":"1194","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1194.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-B5EXN3KKMV","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":35},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.777},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.777},"composition_source":"printed","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r35#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn3Ge","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1203.0,"temperature_printed":"1203","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-V36WSMA2GJ","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":36},"model":"Mc4a3a27c","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.768},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.768},"composition_source":"printed","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r36#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn3Ge","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1198.0,"temperature_printed":"1198","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1198.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-5FTZXNPD54","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":37},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.777},"composition_source":"printed","phase":"Mn3Ge"},{"basis":"mole_fraction","composition":{"MN":0.777},"composition_source":"printed","phase":"LT_Mn3Ge"}],"phases":[{"label":"Mn3Ge","model_phase":"GEMN3_D019"},{"label":"LT_Mn3Ge","model_phase":"GEMN3_D022"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r37#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn3Ge = LT_Mn3Ge","type":"polymorphic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":953.0,"temperature_printed":"953","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":953.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-ACTCQONERS","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":38},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.758},"composition_source":"printed","phase":"Mn3Ge"},{"basis":"mole_fraction","composition":{"MN":0.75},"composition_source":"printed","phase":"LT_Mn3Ge"},{"basis":"mole_fraction","composition":{"MN":0.89},"composition_source":"printed","phase":"FCC_A1"}],"phases":[{"label":"Mn3Ge","model_phase":"GEMN3_D019"},{"label":"LT_Mn3Ge","model_phase":"GEMN3_D022"},{"label":"FCC_A1","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r38#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Mn3Ge = LT_Mn3Ge + FCC_A1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":951.0,"temperature_printed":"951","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":951.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-LSMYSD7HEU","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":39},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.25,"MN":0.75},"composition_source":"formula_nominal","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"},{"label":"FCC_A1","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r39#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn3Ge + FCC_A1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1173.0,"temperature_printed":"1173","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1173.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-F6MUAAPX5J","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":40},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.776},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.772},"composition_source":"printed","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"},{"label":"FCC_A1","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r40#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn3Ge + FCC_A1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1189.0,"temperature_printed":"1189","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1189.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"assessment","label":"19","reference":"Zwicker U. On the gamma-phase in manganese alloys. Z Met 1951;42:327e30.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-5HH5ZFRO3R","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":41},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.25,"MN":0.75},"composition_source":"formula_nominal","phase":"Mn3Ge"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"},{"label":"FCC_A1","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r41#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn3Ge + FCC_A1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1182.0,"temperature_printed":"1182","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1182.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-T73SJPYKCM","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":42},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.793},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.783},"composition_source":"printed","phase":"Mn3Ge"},{"basis":"mole_fraction","composition":{"MN":0.904},"composition_source":"printed","phase":"FCC_A1"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Mn3Ge","model_phase":"GEMN3_D019"},{"label":"FCC_A1","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r42#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = Mn3Ge + FCC_A1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1187.0,"temperature_printed":"1187","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1187.0},{"chemical_system":"GE-MN","cited_sources":[{"first_author":"Zwicker","kind":"assessment","label":"19","reference":"Zwicker U. On the gamma-phase in manganese alloys. Z Met 1951;42:327e30.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-CPX4THTQS5","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":43},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.91},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.97},"composition_source":"printed","phase":"BCC_A2"},{"basis":"mole_fraction","composition":{"MN":0.93},"composition_source":"printed","phase":"FCC_A1"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"BCC_A2","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"FCC_A1","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r43#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + BCC_A2 = FCC_A1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1435.0,"temperature_printed":"1435","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1435.0},{"chemical_system":"GE-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-DSECU4XVY2","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2","row":44},"model":"M624fd2b6","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2013.12.009","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.925},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"MN":0.969},"composition_source":"printed","phase":"BCC_A2"},{"basis":"mole_fraction","composition":{"MN":0.964},"composition_source":"printed","phase":"FCC_A1"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"BCC_A2","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"FCC_A1","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2013.12.009/p3/tab-2/r44#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + BCC_A2 = FCC_A1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-MN","system":"GE-MN","temperature_K":1414.0,"temperature_printed":"1414","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1414.0},{"chemical_system":"GE-MN","citations_printed":["8"],"cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-X2Y7YKZ6KU.007dfd","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"It decomposes via a peritectic transition into liquid and Mn5Ge3 at 1069 K [7] or 1018 K [8].","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1018.0,"temperature_printed":"1018 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1018.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-X2Y7YKZ6KU.6acfa2","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"It decomposes via a peritectic transition into liquid and Mn5Ge3 at 1069 K [7] or 1018 K [8].","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1069.0,"temperature_printed":"1069 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1069.0},{"chemical_system":"GE-MN","citations_printed":["8"],"cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-VJKKJETF43.88b1f1","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It melts congruently at 1239 K [7] or 1205 K [8].","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1205.0,"temperature_printed":"1205 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1205.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-VJKKJETF43.cad46b","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It melts congruently at 1239 K [7] or 1205 K [8].","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1239.0,"temperature_printed":"1239 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1239.0},{"chemical_system":"GE-MN","citations_printed":["11"],"cited_sources":[{"doi":"10.1103/physrevb.83.174103","first_author":"Arras","kind":"unknown","label":"11","paper":"doi:10.1103/physrevb.83.174103","reference":"Arras E, Caliste D, Deutsch T, Lançon F, Pochet P. Phase diagram, structure, and magnetic properties of the GeeMn system: a first-principles study. Phys Rev B 2011;B83:174103.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-BQC3WOY6ZI","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Its Curie temperature is of 300 K according to Arras [11].","quote_page":1,"reaction":{"type":"magnetic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":300.0,"temperature_printed":"300 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"magnetic","transition_kind_printed":"magnetic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":300.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7R4OPAIMFP","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It melts congruently for xMn 1⁄4 0.666 at 1219 K [7].","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1219.0,"temperature_printed":"1219 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1219.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-NAHHPYSXJR","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"On cooling, this phase decomposes into Mn5Ge3 and Mn5Ge2 at 1063 K [7].","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1063.0,"temperature_printed":"1063 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1063.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-Z4J6755HR7.14a5e8","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It melts congruently at 1226 K [7], 1223 K [13] or 1193 K [8].","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1226.0,"temperature_printed":"1226 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1226.0},{"chemical_system":"GE-MN","citations_printed":["13"],"cited_sources":[{"doi":"10.1016/0022-5088(70)90030-5","first_author":"Gupta","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(70)90030-5","reference":"Gupta SI, Gupta KP. Phase equilibria in the manganese germanium system in the composition range 20e35 at.% Ge. J Less Common Met 1970;20:1e6.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-Z4J6755HR7.d883ae","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It melts congruently at 1226 K [7], 1223 K [13] or 1193 K [8].","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1223.0,"temperature_printed":"1223 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1223.0},{"chemical_system":"GE-MN","citations_printed":["8"],"cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-Z4J6755HR7.f7da51","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It melts congruently at 1226 K [7], 1223 K [13] or 1193 K [8].","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1193.0,"temperature_printed":"1193 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1193.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-SK5ORHD7AS","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p1/text-11/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It transforms into Mn5Ge2 and Mn5Ge3 at 963 K [7].","quote_page":1,"reaction":{"printed":"LT-Mn5Ge2 -> Mn5Ge2 + Mn5Ge3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":963.0,"temperature_printed":"963 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":963.0},{"chemical_system":"GE-MN","citations_printed":["18"],"cited_sources":[{"doi":"10.1143/jpsj.16.1995","first_author":"Ohoyama","kind":"unknown","label":"18","paper":"doi:10.1143/jpsj.16.1995","reference":"Ohoyama T. X-ray and magnetic studies of the manganeseegermanium system. J Phys Soc Jpn 1961;16(10):1995e2002.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-KEIWDNE62H.3f8bf0","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-15"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-15/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"This phase transforms into Mn3Ge at 953 K [7], at 903 K [8], around 773 K [18] or higher than 850 K [15].","quote_page":2,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":773.0,"temperature_printed":"773 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":773.0},{"chemical_system":"GE-MN","citations_printed":["8"],"cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-KEIWDNE62H.5b55ad","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-15"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-15/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"This phase transforms into Mn3Ge at 953 K [7], at 903 K [8], around 773 K [18] or higher than 850 K [15].","quote_page":2,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":903.0,"temperature_printed":"903 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":903.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-KEIWDNE62H.bd0e7c","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-15"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-15/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"This phase transforms into Mn3Ge at 953 K [7], at 903 K [8], around 773 K [18] or higher than 850 K [15].","quote_page":2,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":953.0,"temperature_printed":"953 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":953.0},{"chemical_system":"GE-MN","citations_printed":["13"],"cited_sources":[{"doi":"10.1016/0022-5088(70)90030-5","first_author":"Gupta","kind":"unknown","label":"13","paper":"doi:10.1016/0022-5088(70)90030-5","reference":"Gupta SI, Gupta KP. Phase equilibria in the manganese germanium system in the composition range 20e35 at.% Ge. J Less Common Met 1970;20:1e6.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-VKNIWQ6HO3.183e74","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-16/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This phase melts congruently at 1203 K [7] or decomposes via an eutectic reaction at 1173 K [8] or around 1203 K [13].","quote_page":2,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1203.0,"temperature_printed":"1203 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203.0},{"chemical_system":"GE-MN","citations_printed":["7"],"cited_sources":[{"first_author":"Wachtel","kind":"unknown","label":"7","reference":"Wachtel E, Henig ET. Phase equilibria of the manganeseegermanium alloys. Z Met 1969;60(3):243e7.","status":"resolved","year":"1969"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-VKNIWQ6HO3.7c7849","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-16/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"This phase melts congruently at 1203 K [7] or decomposes via an eutectic reaction at 1173 K [8] or around 1203 K [13].","quote_page":2,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1203.0,"temperature_printed":"1203 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203.0},{"chemical_system":"GE-MN","citations_printed":["8"],"cited_sources":[{"first_author":"Zwicker","kind":"unknown","label":"8","reference":"Zwicker U, Jahn E, Schubert E. A study of the manganeseegermanium system. Z Met 1949;40(12):433e6.","status":"resolved","year":"1949"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-VKNIWQ6HO3.f42623","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-16/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This phase melts congruently at 1203 K [7] or decomposes via an eutectic reaction at 1173 K [8] or around 1203 K [13].","quote_page":2,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1173.0,"temperature_printed":"1173 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1173.0},{"chemical_system":"GE-MN","citations_printed":["11"],"cited_sources":[{"doi":"10.1103/physrevb.83.174103","first_author":"Arras","kind":"unknown","label":"11","paper":"doi:10.1103/physrevb.83.174103","reference":"Arras E, Caliste D, Deutsch T, Lançon F, Pochet P. Phase diagram, structure, and magnetic properties of the GeeMn system: a first-principles study. Phys Rev B 2011;B83:174103.","status":"resolved","year":"2011"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3RRZDSHWTA","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-16"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-16/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Its Curie temperature is measured at 365 K according to Arras [11].","quote_page":2,"reaction":{"type":"magnetic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":365.0,"temperature_printed":"365 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"magnetic","transition_kind_printed":"magnetic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":365.0},{"chemical_system":"GE-MN","citations_printed":["21"],"cited_sources":[{"doi":"10.1021/ja01152a518","first_author":"Downing","kind":"unknown","label":"21","paper":"doi:10.1021/ja01152a518","reference":"Downing JH, Cubicciotti D. On the freezing point diagram of the germaniume manganese system. J Am Chem Soc 1951;73(8):4025.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3IE2W7PBOA","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2013.12.009/p2/text-17"},"method":"thermal analyses on cooling","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2013.12.009","paper_id":"doi:10.1016/j.intermet.2013.12.009","pid":"doi:10.1016/j.intermet.2013.12.009/p2/text-17/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"They use 99.9% germanium which freezing point is measured at 1230 K.","quote_page":2,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-MN","system":"GE-MN","temperature_K":1230.0,"temperature_printed":"1230 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1230.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"GE-MN"}