{"artifacts":{"doi:10.1007/s11664-022-09474-1/p10/text-02":{"artifact":"text_passage","label":"page 10, passage 2","page":10},"doi:10.1007/s11664-022-09474-1/p5/text-03":{"artifact":"text_passage","label":"page 5, passage 3","page":5},"doi:10.1007/s11664-022-09474-1/p5/text-06":{"artifact":"text_passage","label":"page 5, passage 6","page":5},"sha256:193b1abe9db6a119/p2/tab-i":{"artifact":"table","caption":"Crystal structures of solid phases in the Ge-X (X = As, Se, S, P) systems","label":"I","page":2},"sha256:193b1abe9db6a119/p3/tab-ii":{"artifact":"table","caption":"Summary of experimental and calculated data used for the enthalpies of the formation from first- principles (0 K) and CALPHAD","label":"II","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["GE","SE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/zaac.19754110110":{"authors":["H. Wiedemeier","P. A. Siemers"],"citation":"H. Wiedemeier, P. A. Siemers, The thermal expansion and high temperature transformation of GeSe, Zeitschrift anorg allge chemie 411, 90-96 (1975).","container":"Zeitschrift anorg allge chemie","doi":"10.1002/zaac.19754110110","doi_url":"https://doi.org/10.1002/zaac.19754110110","id":"doi:10.1002/zaac.19754110110","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The thermal expansion and high temperature transformation of GeSe","year":1975},"doi:10.1006/jssc.1999.8557":{"authors":["Andrzej Grzechnik","Svein Stølen","Egil Bakken","Tor Grande","Mohamed Mezouar"],"citation":"Andrzej Grzechnik, Svein Stølen, Egil Bakken, Tor Grande, Mohamed Mezouar, Structural Transformations in Three-Dimensional Crystalline GeSe2 at High Pressures and High Temperatures, Journal of Solid State Chemistry 150, 121-127 (2000).","container":"Journal of Solid State Chemistry","doi":"10.1006/jssc.1999.8557","doi_url":"https://doi.org/10.1006/jssc.1999.8557","id":"doi:10.1006/jssc.1999.8557","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Structural Transformations in Three-Dimensional Crystalline GeSe2 at High Pressures and High Temperatures","year":2000},"doi:10.1007/s11664-022-09474-1":{"authors":["Shanxiong Chen","Jiong Wang","Shangzhao Yu","Biao Hu","Qing Wu","Yong Du"],"citation":"Shanxiong Chen, Jiong Wang, Shangzhao Yu, Biao Hu, Qing Wu, Yong Du, Thermodynamic Modeling of the Ge-X (X = As, Se, S, P) Systems, J. Electron. Mater. 51, 2114-2130 (2022).","container":"J. Electron. Mater.","doi":"10.1007/s11664-022-09474-1","doi_url":"https://doi.org/10.1007/s11664-022-09474-1","id":"doi:10.1007/s11664-022-09474-1","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"193b1abe9db6a119","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Modeling of the Ge-X (X = As, Se, S, P) Systems","year":2022},"doi:10.1021/ic50031a032":{"authors":["S. N. Dutta","G. A. Jeffrey"],"citation":"S. N. Dutta, G. A. Jeffrey, On the Structure of Germanium Selenide and Related Binary IV/VI Compounds, Inorg. Chem. 4, 1363-1366 (1965).","container":"Inorg. Chem.","doi":"10.1021/ic50031a032","doi_url":"https://doi.org/10.1021/ic50031a032","id":"doi:10.1021/ic50031a032","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"On the Structure of Germanium Selenide and Related Binary IV/VI Compounds","year":1965}},"part":1,"parts":1,"records":[{"chemical_system":"GE-SE","cited_sources":[{"doi":"10.1021/ic50031a032","first_author":"Dutta","kind":"unknown","label":"23","paper":"doi:10.1021/ic50031a032","reference":"S.N. Dutta, and G.A. Jeffrey, On the Structure of Germanium Selenide and Related Binary IV/VI Compounds. Inorg. Chem. 4, 1363 (1965).","status":"resolved","year":"1965"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-XB6KIH2RYF.d1df4c","locator":{"ref":"sha256:193b1abe9db6a119/p2/tab-i","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p2/tab-i/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AS-GE-P-S-SE","structure":{"pearson_symbol":"oC8","prototype":"P (black)"},"system":"GE-SE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0238,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0238},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":10.82,"value_stored":10.82},{"chemical_system":"GE-SE","cited_sources":[{"doi":"10.1021/ic50031a032","first_author":"Dutta","kind":"unknown","label":"23","paper":"doi:10.1021/ic50031a032","reference":"S.N. Dutta, and G.A. Jeffrey, On the Structure of Germanium Selenide and Related Binary IV/VI Compounds. Inorg. Chem. 4, 1363 (1965).","status":"resolved","year":"1965"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-XB6KIH2RYF.f401f8","locator":{"ref":"sha256:193b1abe9db6a119/p2/tab-i","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p2/tab-i/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AS-GE-P-S-SE","structure":{"pearson_symbol":"oC8","prototype":"P (black)"},"system":"GE-SE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009687,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009687},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.403,"value_stored":4.403},{"chemical_system":"GE-SE","cited_sources":[{"doi":"10.1021/ic50031a032","first_author":"Dutta","kind":"unknown","label":"23","paper":"doi:10.1021/ic50031a032","reference":"S.N. Dutta, and G.A. Jeffrey, On the Structure of Germanium Selenide and Related Binary IV/VI Compounds. Inorg. Chem. 4, 1363 (1965).","status":"resolved","year":"1965"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-XB6KIH2RYF.f6c3fa","locator":{"ref":"sha256:193b1abe9db6a119/p2/tab-i","row":6},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p2/tab-i/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AS-GE-P-S-SE","structure":{"pearson_symbol":"oC8","prototype":"P (black)"},"system":"GE-SE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008474,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008474},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.852,"value_stored":3.852},{"chemical_system":"GE-SE","cited_sources":[{"doi":"10.1002/zaac.19754110110","first_author":"Wiedemeier","kind":"unknown","label":"25","paper":"doi:10.1002/zaac.19754110110","reference":"H. Wiedemeier, and P.A. Siemers, The thermal expansion and high temperature transformation of GeSe. Z. Anorg. Allg. Chem. 411, 90 (1975).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["βGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-WXXKA2JHRM","locator":{"ref":"sha256:193b1abe9db6a119/p2/tab-i","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"βGeSe"}],"pid":"sha256:193b1abe9db6a119/p2/tab-i/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AS-GE-P-S-SE","structure":{"pearson_symbol":"cF8"},"system":"GE-SE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01261,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01261},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":5.73,"value_stored":5.73},{"chemical_system":"GE-SE","cited_sources":[{"doi":"10.1006/jssc.1999.8557","first_author":"Grzechnik","kind":"unknown","label":"28","paper":"doi:10.1006/jssc.1999.8557","reference":"A. Grzechnik, S. Stølen, E. Bakken, T. Grande, and M. Mezouar, Structural transformations in three-dimensional crystalline ­GeSe2 at high pressures and high temperatures. J. Solid State Chem. 150, 121 (2000).","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["GeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-2PJGRRAMOL.a53974","locator":{"ref":"sha256:193b1abe9db6a119/p2/tab-i","row":8},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"GeSe2"}],"pid":"sha256:193b1abe9db6a119/p2/tab-i/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AS-GE-P-S-SE","structure":{"prototype":"Orthorhombic"},"system":"GE-SE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01212,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01212},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":5.5073,"value_stored":5.5073},{"chemical_system":"GE-SE","cited_sources":[{"doi":"10.1006/jssc.1999.8557","first_author":"Grzechnik","kind":"unknown","label":"28","paper":"doi:10.1006/jssc.1999.8557","reference":"A. Grzechnik, S. Stølen, E. Bakken, T. Grande, and M. Mezouar, Structural transformations in three-dimensional crystalline ­GeSe2 at high pressures and high temperatures. J. Solid State Chem. 150, 121 (2000).","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["GeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-2PJGRRAMOL.bb7227","locator":{"ref":"sha256:193b1abe9db6a119/p2/tab-i","row":8},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"GeSe2"}],"pid":"sha256:193b1abe9db6a119/p2/tab-i/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AS-GE-P-S-SE","structure":{"prototype":"Orthorhombic"},"system":"GE-SE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02186,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02186},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.9374,"value_stored":9.9374},{"chemical_system":"GE-SE","cited_sources":[{"doi":"10.1006/jssc.1999.8557","first_author":"Grzechnik","kind":"unknown","label":"28","paper":"doi:10.1006/jssc.1999.8557","reference":"A. Grzechnik, S. Stølen, E. Bakken, T. Grande, and M. Mezouar, Structural transformations in three-dimensional crystalline ­GeSe2 at high pressures and high temperatures. J. Solid State Chem. 150, 121 (2000).","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["GeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-2PJGRRAMOL.e07503","locator":{"ref":"sha256:193b1abe9db6a119/p2/tab-i","row":8},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"GeSe2"}],"pid":"sha256:193b1abe9db6a119/p2/tab-i/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AS-GE-P-S-SE","structure":{"prototype":"Orthorhombic"},"system":"GE-SE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01212,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01212},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":5.5073,"value_stored":5.5073},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"48","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-42O4HANJMU.e92808","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":11},"merged_ids":["ORC-42O4HANJMU.8af363"],"method":"Statistical mechanical","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.2975},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-25.95,"value_printed":-25.95,"value_stored":-25950.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"47","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-JQHMKGWXCJ.aaac41","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":12},"merged_ids":["ORC-JQHMKGWXCJ.05ced5"],"method":"Fluorine combination","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.088062,5.330144],"class":"combustion_calorimetry","entry":"value_types/HM_FORM/classes/combustion_calorimetry","floor":1.0,"floor_unit":"kJ/mol-atom","n_pairs":15,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.5},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-25.7,"value_printed":-25.7,"value_stored":-25700.0},{"chemical_system":"GE-SE","cited_sources":[{"first_author":"Saal","kind":"assessment","label":"35","reference":"J.E. Saal, S. Kirklin, M. Aykol, B. Meredig, and C. Wolverton, Materials design and discovery with high-throughput density Thermodynamic Modeling of the Ge‑X (X = As, Se, S, P) Systems﻿ 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. functional theory: the open quantum materials database (OQMD). JOM 65, 1501 (2013). A. Jain, S.P. Ong, G. Hautier, W. Chen, W.","status":"resolved","year":2013,"year_basis":"printed_parenthesised_year","year_read":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-QC7UF7GRLP.32fc35","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":13},"merged_ids":["ORC-QC7UF7GRLP.c58a0c"],"method":"First–principles","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.075},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-21.5,"value_printed":-21.5,"value_stored":-21500.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"36","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-O3IMWO3O3P.44d200","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":14},"merged_ids":["ORC-O3IMWO3O3P.ecd559"],"method":"First–principles","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9575},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-19.15,"value_printed":-19.15,"value_stored":-19150.0},{"chemical_system":"GE-SE","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-AKBFU4UXZZ.4c8fa7","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":15},"merged_ids":["ORC-AKBFU4UXZZ.50395a"],"method":"First–principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.077},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-21.54,"value_printed":-21.54,"value_stored":-21540.0},{"chemical_system":"GE-SE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"phases":["αGeSe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-Z5UVFFHRMB.083ab6","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":16},"merged_ids":["ORC-Z5UVFFHRMB.79d78a"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"overall_composition":{"GE":0.5,"SE":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.5,"P":0.0,"S":0.0,"SE":0.5},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.19895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-23.979,"value_printed":-23.979,"value_stored":-23979.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"55","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-M6NSW2QH2K.eaaaa0","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":17},"merged_ids":["ORC-M6NSW2QH2K.0d1732"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":9.1},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.1,"sigma_method":{"basis":"prior","ci95":null,"class":"dsc_dta","entry":"value_types/HM_FORM/classes/dsc_dta","floor":2.0,"floor_unit":"kJ/mol-atom","n_pairs":2,"prior_source":"kubaschewski","value":2.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":9.1},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-24.7,"value_printed":-24.7,"value_stored":-24700.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"54","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-6WBSLIA4HF.bcc9cd","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":18},"merged_ids":["ORC-6WBSLIA4HF.56fcf9"],"method":"Drop calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.6},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-28.13,"value_printed":-28.13,"value_stored":-28130.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"53","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-Q3HE3MVOKA.63033f","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":19},"merged_ids":["ORC-Q3HE3MVOKA.4364c0"],"method":"Fluorine combination calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.088062,5.330144],"class":"combustion_calorimetry","entry":"value_types/HM_FORM/classes/combustion_calorimetry","floor":1.0,"floor_unit":"kJ/mol-atom","n_pairs":15,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.6},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-34.3,"value_printed":-34.3,"value_stored":-34300.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"48","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-T2US6YJT5E.2e4667","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":20},"merged_ids":["ORC-T2US6YJT5E.7d7a95"],"method":"Statistical mechanical","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.72},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-34.4,"value_printed":-34.4,"value_stored":-34400.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"52","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-PXPFOAZ35U.576687","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":21},"merged_ids":["ORC-PXPFOAZ35U.55dd7a"],"method":"Torsion effusion measurements","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":5.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.7,"sigma_method":{"basis":"calibrated","ci95":[1.153192,7.653003],"class":"kems_vapour","entry":"value_types/HM_FORM/classes/kems_vapour","floor":4.2,"floor_unit":"kJ/mol-atom","n_pairs":20,"value":4.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.7},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-38.0,"value_printed":-38,"value_stored":-38000.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"49","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-TPO2BAR2LI.dfe21d","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":22},"merged_ids":["ORC-TPO2BAR2LI.bc2d1c"],"method":"Knudsen's measurements","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.2,"sigma_method":{"basis":"calibrated","ci95":[1.153192,7.653003],"class":"kems_vapour","entry":"value_types/HM_FORM/classes/kems_vapour","floor":4.2,"floor_unit":"kJ/mol-atom","n_pairs":20,"value":4.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.8},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-30.3,"value_printed":-30.3,"value_stored":-30300.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"50","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-6J4CERAXQQ.6afc23","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":23},"merged_ids":["ORC-6J4CERAXQQ.da2379"],"method":"Theoretical","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.7535},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-15.07,"value_printed":-15.07,"value_stored":-15070.0},{"chemical_system":"GE-SE","cited_sources":[{"first_author":"Saal","kind":"assessment","label":"35","reference":"J.E. Saal, S. Kirklin, M. Aykol, B. Meredig, and C. Wolverton, Materials design and discovery with high-throughput density Thermodynamic Modeling of the Ge‑X (X = As, Se, S, P) Systems﻿ 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. functional theory: the open quantum materials database (OQMD). JOM 65, 1501 (2013). A. Jain, S.P. Ong, G. Hautier, W. Chen, W.","status":"resolved","year":2013,"year_basis":"printed_parenthesised_year","year_read":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-ZNLBDQHISX.359afd","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":24},"merged_ids":["ORC-ZNLBDQHISX.d99adc"],"method":"First–principles","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.245},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-24.9,"value_printed":-24.9,"value_stored":-24900.0},{"chemical_system":"GE-SE","cited_sources":[{"kind":"unknown","label":"36","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-RPCKA4ZWRK.873b2f","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":25},"merged_ids":["ORC-RPCKA4ZWRK.e212c6"],"method":"First–principles","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.164},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-23.28,"value_printed":-23.28,"value_stored":-23280.0},{"chemical_system":"GE-SE","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-YXGI5R22BT.b8c0cc","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":26},"merged_ids":["ORC-YXGI5R22BT.493058"],"method":"First–principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.29},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-25.8,"value_printed":-25.8,"value_stored":-25800.0},{"chemical_system":"GE-SE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"phases":["αGeSe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-KHQHYOG3HB.de9183","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":27},"merged_ids":["ORC-KHQHYOG3HB.bb4ae0"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"overall_composition":{"GE":0.333333,"SE":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.333333,"P":0.0,"S":0.0,"SE":0.666667},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"αGeSe2"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.14785},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-22.957,"value_printed":-22.957,"value_stored":-22957.0},{"chemical_system":"GE-SE","cited_sources":[{"first_author":"Saal","kind":"assessment","label":"35","reference":"J.E. Saal, S. Kirklin, M. Aykol, B. Meredig, and C. Wolverton, Materials design and discovery with high-throughput density Thermodynamic Modeling of the Ge‑X (X = As, Se, S, P) Systems﻿ 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. functional theory: the open quantum materials database (OQMD). JOM 65, 1501 (2013). A. Jain, S.P. Ong, G. Hautier, W. Chen, W.","status":"resolved","year":2013,"year_basis":"printed_parenthesised_year","year_read":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.3,"P":0.0,"S":0.0,"SE":0.7},"phases":["Ge3Se7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-YUAOJ6JUDU.402c1d","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":28},"merged_ids":["ORC-YUAOJ6JUDU.5fb829"],"method":"First–principles","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"GE":0.3,"SE":0.7},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.3,"P":0.0,"S":0.0,"SE":0.7},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"Ge3Se7"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r28#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.196},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-23.92,"value_printed":-23.92,"value_stored":-23920.0},{"chemical_system":"GE-SE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GE-SE","before":"AS-GE-P-S-SE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GE":0.3,"P":0.0,"S":0.0,"SE":0.7},"phases":["Ge3Se7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-V5WEVXENH6.bd6348","locator":{"ref":"sha256:193b1abe9db6a119/p3/tab-ii","row":29},"merged_ids":["ORC-V5WEVXENH6.1f79f3"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"overall_composition":{"GE":0.3,"SE":0.7},"overall_composition_basis":"from_formula","overall_composition_stored":{"GE":0.3,"P":0.0,"S":0.0,"SE":0.7},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"Ge3Se7"}],"pid":"sha256:193b1abe9db6a119/p3/tab-ii/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"reference_state_stored":{"AS":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"GE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"P":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"S":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"},"SE":{"phase":"printed:diamond_A4, rhombohedral_A7, hexagonal_A8, orthorhombic_S and red_P"}},"source_system":"AS-GE-P-S-SE","system":"GE-SE","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"298.15","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.10325},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mole−atom","unit_stored":"J/mol-atom","value":-22.065,"value_printed":-22.065,"value_stored":-22065.0},{"chemical_system":"GE-SE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-VAL6TMKMVK","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-022-09474-1/p10/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"βGeSe"}],"pid":"doi:10.1007/s11664-022-09474-1/p10/text-02/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"In the present thermodynamic assessment, the melting point of \u0000GeS2 is 1110 K, βGeSe melts incongruently at 931.4 K, and the transition between αGeS and βGeS occurs at","quote_page":10,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-SE","system":"GE-SE","temperature_K":931.4,"temperature_printed":"931.4 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":931.4},{"chemical_system":"GE-SE","citations_printed":["38"],"cited_sources":[{"kind":"unknown","label":"38","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:3)","effect":"not_accepted","gate":"R3"}],"id":"ORC-YXHHCPEWAH.89f45b","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-022-09474-1/p5/text-03"},"method":"thermal analysis","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","pid":"doi:10.1007/s11664-022-09474-1/p5/text-03/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"They discovered a monotectic reaction, Liquid#1 → Liquid#2 + (Ge) at 1173 K; a peritectic reaction, Liquid#2 + (Ge) → GeSe at 934 K; and an eutectic reaction, Liquid#2 → GeSe + \u0000GeSe2 at 851 K.","quote_page":5,"reaction":{"printed":"Liquid#2 → GeSe + \u0000GeSe2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-SE","system":"GE-SE","temperature_K":851.0,"temperature_printed":"851 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_INVARIANT/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":851.0},{"chemical_system":"GE-SE","citations_printed":["38"],"cited_sources":[{"kind":"unknown","label":"38","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:3)","effect":"not_accepted","gate":"R3"}],"id":"ORC-YXHHCPEWAH.eff00c","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-022-09474-1/p5/text-03"},"method":"thermal analysis","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","pid":"doi:10.1007/s11664-022-09474-1/p5/text-03/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"They discovered a monotectic reaction, Liquid#1 → Liquid#2 + (Ge) at 1173 K; a peritectic reaction, Liquid#2 + (Ge) → GeSe at 934 K; and an eutectic reaction, Liquid#2 → GeSe + \u0000GeSe2 at 851 K.","quote_page":5,"reaction":{"printed":"Liquid#2 + (Ge) → GeSe","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-SE","system":"GE-SE","temperature_K":934.0,"temperature_printed":"934 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_INVARIANT/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":934.0},{"chemical_system":"GE-SE","citations_printed":["38"],"cited_sources":[{"kind":"unknown","label":"38","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-L5FOQ6ASVN","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-022-09474-1/p5/text-03"},"method":"thermal analysis","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"GeSe2"}],"pid":"doi:10.1007/s11664-022-09474-1/p5/text-03/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Meanwhile, the \u0000GeSe2 phase melting congruently at 1013.15 K was also confirmed.","quote_page":5,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-SE","system":"GE-SE","temperature_K":1013.15,"temperature_printed":"1013.15 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1013.15},{"chemical_system":"GE-SE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11664-022-09474-1"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"id":"ORC-TOSLDTLUMH","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-022-09474-1/p5/text-03"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"GeSe2"}],"pid":"doi:10.1007/s11664-022-09474-1/p5/text-03/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The other \u0000GeSe2 phase melted congruently at 1015 ± 2 K.","quote_page":5,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-SE","system":"GE-SE","temperature_K":1015.0,"temperature_printed":"1015 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1015.0},{"chemical_system":"GE-SE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11664-022-09474-1"},"corrections":[{"after":["βGeSe2","αGeSe2"],"before":[],"evidence":{"basis":"one_reaction_one_temperature","quote_page":5},"field":"phases","gate":"R3","rule":"state_phases_from_quote"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phases_recovered_from_quote"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"phases_recovered_from_quote","detail":"phases read from the quote (one_reaction_one_temperature); not mapped to model phases","effect":"not_espei_ready","gate":"R3"}],"id":"ORC-USBQO7PI2L","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-022-09474-1/p5/text-06"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-022-09474-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-022-09474-1","paper_id":"doi:10.1007/s11664-022-09474-1","phases":[{"label":"βGeSe2","label_source":"quote"},{"label":"αGeSe2","label_source":"quote"}],"pid":"doi:10.1007/s11664-022-09474-1/p5/text-06/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"They observed that the λ-type phase transition βGeSe2 → αGeSe2 occurred at 420 K, and αGeSe2 is the low-temperature phase and βGeSe2 is the high-temperature phase.","quote_page":5,"reaction":{"printed":"βGeSe2 → αGeSe2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"GE-SE","system":"GE-SE","temperature_K":420.0,"temperature_printed":"420 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":420.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"GE-SE"}