{"artifacts":{"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1":{"artifact":"table","caption":"Reported","label":"1","page":2},"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2":{"artifact":"table","caption":"Temperatures","label":"2","page":3},"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3":{"artifact":"table","caption":"Homogeneity","label":"3","page":4}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["GE","TE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M122dcbf1":{"catalog_entry":{"license":"CC BY 4.0","name":"GeTe-99Sch-LB.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Calphad, 23, 1-18 (1999).","model_doi":"10.1016/s0364-5916(99)00012-7","reproduced_by_calculation":true,"tdb":"GeTe-99Sch-LB.tdb","tdb_path":"databases/sgte-binary/GeTe-99Sch-LB.tdb","tdb_sha256":"4acca1dfd153da40a8872dc47d0c1232e920515ed2a0575569eda9a05fb00c44"},"Mefa8c9b5":{"catalog_entry":{"license":"CC BY 4.0","name":"GeTe-99Sch-LB.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"Calphad, 23, 1-18 (1999).","model_doi":"10.1016/s0364-5916(99)00012-7","tdb":"GeTe-99Sch-LB.tdb","tdb_path":"databases/sgte-binary/GeTe-99Sch-LB.tdb","tdb_sha256":"4acca1dfd153da40a8872dc47d0c1232e920515ed2a0575569eda9a05fb00c44"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/s0364-5916(99)00012-7":{"authors":["A. Schlieper","Y. Feutelais","S.G. Fries","B. Legendre","R. Blachnik"],"citation":"A. Schlieper, Y. Feutelais, S.G. Fries, B. Legendre, R. Blachnik, Thermodynamic evaluation of the Germanium — Tellurium system, Calphad 23, 1-18 (1999).","container":"Calphad","doi":"10.1016/s0364-5916(99)00012-7","doi_url":"https://doi.org/10.1016/s0364-5916(99)00012-7","id":"doi:10.1016/s0364-5916(99)00012-7","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"5bbc45e6e4595523","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic evaluation of the Germanium — Tellurium system","year":1999}},"part":1,"parts":1,"records":[{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"60","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-M4BFSOIAU2","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1","row":1},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"[60McH]","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":997.0,"temperature_basis":"printed","temperature_printed":"997","tool_release":"tools-release-v2.1.18","transition_kind":"congruent melting","transition_kind_printed":"melting","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":997.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"66","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-CBWVML4XQJ","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1","row":2},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"[66BRE]","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":998.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"tools-release-v2.1.18","transition_kind":"congruent melting","transition_kind_printed":"melting","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":998.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-SKJLKS6WXM","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1","row":3},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"[77LEG1, 77LEG2]","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":997.0,"temperature_basis":"printed","temperature_printed":"997","tool_release":"tools-release-v2.1.18","transition_kind":"congruent melting","transition_kind_printed":"melting","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":997.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"96Opp","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-57OGHCU6K4","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phases":[{"label":"melting"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"[96Opp]","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":998.0,"temperature_basis":"printed","temperature_printed":"998","tool_release":"tools-release-v2.1.18","transition_kind":"congruent melting","transition_kind_printed":"melting","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":998.0},{"chemical_system":"GE-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-LIZNQOGUKW","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1","row":5},"model":"Mefa8c9b5","observation_type":"phase_transition","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/s0364-5916(99)00012-7","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p2/tab-1/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"calculated","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":993.3,"temperature_basis":"printed","temperature_printed":"993.3","tool_release":"tools-release-v2.1.18","transition_kind":"congruent melting","transition_kind_printed":"melting","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":993.3},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"53","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-T5AETXW4TP","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":1},"method":"X-ray","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.5,"TE":0.5},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":588.0,"temperature_basis":"printed","temperature_printed":"588","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"65","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-L6EUP6MDIB","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":2},"method":"Microhardness","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.499,"TE":0.501},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":523.0,"temperature_basis":"printed","temperature_printed":"523","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/X_PHASE/classes/experimental_unspecified","floor":0.01,"floor_unit":"mole fraction","n_pairs":6,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/T_CONDITION/classes/experimental_unspecified","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"69","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-XQL6FA7XXE","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":3},"method":"X-ray","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.498,"TE":0.502},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":623.0,"temperature_basis":"printed","temperature_printed":"623","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"75","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-E24BNBZBBG","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":4},"method":"Thermal- Expansion, Electrical Resistivity","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.4965,"TE":0.5035},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":703.0,"temperature_basis":"printed","temperature_printed":"703","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"dilatometry_resistivity","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"dilatometry_resistivity","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"75","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-RLKSWQPJPH","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":5},"method":"Thermal- Expansion, Electrical Resistivity","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.494,"TE":0.506},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":633.0,"temperature_basis":"printed","temperature_printed":"633","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"dilatometry_resistivity","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"dilatometry_resistivity","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"76","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"disputed_queued_for_review","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-HWVB23IYDM","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":6},"method":"X-ray, Metallography","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.492,"TE":0.508},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_basis":"not_printed","temperature_printed":"473","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"76","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-QK2MVTRODK","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":7},"method":"X-ray, Metallography","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.499,"TE":0.501},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":573.0,"temperature_basis":"printed","temperature_printed":"573","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-WV2OO4OLON","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":8},"method":"Microstructure","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.496,"TE":0.504},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":613.0,"temperature_basis":"printed","temperature_printed":"613","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/X_PHASE/classes/metallography_microscopy","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"79","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-TZRF3V2ENC","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":9},"method":"Resistivity, Thermo-EMF","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.484,"TE":0.516},"composition_source":"printed","phase":"α-GeTe"}],"phases":[{"label":"α-GeTe","model_phase":"GETE_LOW"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":673.0,"temperature_basis":"printed","temperature_printed":"673","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"dilatometry_resistivity","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"dilatometry_resistivity","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"65","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-KAIETFVBQ7","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":10},"method":"Microstructure","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.485,"TE":0.515},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":703.0,"temperature_basis":"printed","temperature_printed":"703","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/X_PHASE/classes/metallography_microscopy","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"76","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-MHFJJFAPA7","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":11},"method":"X-ray, Metallography","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.487,"TE":0.513},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r11#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":693.0,"temperature_basis":"printed","temperature_printed":"693","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"76","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-TGAIM54TZH","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":12},"method":"X-ray, Metallography","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.484,"TE":0.516},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r12#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":773.0,"temperature_basis":"printed","temperature_printed":"773","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"76","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-E65HQKZJQS","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":13},"method":"X-ray, Metallography","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.485,"TE":0.515},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r13#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":873.0,"temperature_basis":"printed","temperature_printed":"873","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-YQT7LT2BQM","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":14},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.506,"TE":0.494},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r14#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":729.0,"temperature_basis":"printed","temperature_printed":"729","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/X_PHASE/classes/thermal_analysis","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-M54GVUAQAP","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":15},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.5,"TE":0.5},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r15#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":711.0,"temperature_basis":"printed","temperature_printed":"711","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/X_PHASE/classes/thermal_analysis","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-ZPUP7PSFPK","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":16},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.499,"TE":0.501},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r16#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":709.0,"temperature_basis":"printed","temperature_printed":"709","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/X_PHASE/classes/thermal_analysis","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-TU7W2XKO5Y","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":17},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.484,"TE":0.516},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r17#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":688.0,"temperature_basis":"printed","temperature_printed":"688","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/X_PHASE/classes/thermal_analysis","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"79","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-6L4TQFABDS","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":18},"method":"Resistivity, Thermo-EMF","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.487,"TE":0.513},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r18#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":723.0,"temperature_basis":"printed","temperature_printed":"723","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"dilatometry_resistivity","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"dilatometry_resistivity","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"79","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-UUY55AYHAI","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":19},"method":"Resistivity, Thermo-EMF","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.489,"TE":0.511},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r19#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":823.0,"temperature_basis":"printed","temperature_printed":"823","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"dilatometry_resistivity","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"dilatometry_resistivity","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"85","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-ABDQVOAGQL","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":20},"method":"Crystal Growth","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.4966,"TE":0.5034},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r20#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":827.0,"temperature_basis":"printed","temperature_printed":"827","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/X_PHASE/classes/experimental_unspecified","floor":0.01,"floor_unit":"mole fraction","n_pairs":6,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/T_CONDITION/classes/experimental_unspecified","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"85","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-TUJRTXGT3A","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":21},"method":"Crystal Growth","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.4956,"TE":0.5044},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r21#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":874.0,"temperature_basis":"printed","temperature_printed":"874","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/X_PHASE/classes/experimental_unspecified","floor":0.01,"floor_unit":"mole fraction","n_pairs":6,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/T_CONDITION/classes/experimental_unspecified","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"85","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-LZKBMJTPHH","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":22},"method":"Crystal Growth","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.4942,"TE":0.5058},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r22#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":926.0,"temperature_basis":"printed","temperature_printed":"926","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/X_PHASE/classes/experimental_unspecified","floor":0.01,"floor_unit":"mole fraction","n_pairs":6,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/T_CONDITION/classes/experimental_unspecified","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"85","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-SH3OZ62XPR","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":23},"method":"Crystal Growth","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.4935,"TE":0.5065},"composition_source":"printed","phase":"β-GeTe"}],"phases":[{"label":"β-GeTe","model_phase":"GETE_B1"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r23#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":973.0,"temperature_basis":"printed","temperature_printed":"973","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/X_PHASE/classes/experimental_unspecified","floor":0.01,"floor_unit":"mole fraction","n_pairs":6,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/T_CONDITION/classes/experimental_unspecified","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"69","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-OYZZDNEGOH","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":24},"method":"X-ray","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.471,"TE":0.529},"composition_source":"printed","phase":"γ-GeTe"}],"phases":[{"label":"γ-GeTe","model_phase":"GETE_GAMMA"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r24#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":623.0,"temperature_basis":"printed","temperature_printed":"623","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"xrd","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-MLBBLMD7HT","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":25},"method":"Microstructure","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.487,"TE":0.513},"composition_source":"printed","phase":"γ-GeTe"}],"phases":[{"label":"γ-GeTe","model_phase":"GETE_GAMMA"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r25#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":613.0,"temperature_basis":"printed","temperature_printed":"613","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/X_PHASE/classes/metallography_microscopy","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-2OWNV22H2L","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":26},"method":"Metallography, Microhardness","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.482,"TE":0.518},"composition_source":"printed","phase":"γ-GeTe"}],"phases":[{"label":"γ-GeTe","model_phase":"GETE_GAMMA"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r26#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":573.0,"temperature_basis":"printed","temperature_printed":"573","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/X_PHASE/classes/metallography_microscopy","floor":0.01,"floor_unit":"mole fraction","n_pairs":1,"prior_source":"orchid_assumed","value":0.01},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"79","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-GMC6TTSFZ3","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3","row":27},"method":"Resistivity, Thermo-EMF","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"method_names_experiment_only","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"GE":0.477,"TE":0.523},"composition_source":"printed","phase":"γ-GeTe"}],"phases":[{"label":"γ-GeTe","model_phase":"GETE_GAMMA"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p4/tab-3/r27#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-TE","system":"GE-TE","temperature_K":523.0,"temperature_basis":"printed","temperature_printed":"523","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"dilatometry_resistivity","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"dilatometry_resistivity","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"34","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-YM3RZ5E6VF","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> β + Ge","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":998.0,"temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":998.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"34","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-MF4QJTADC5","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> α + Te","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":643.0,"temperature_max_K":648.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":643.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"51","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-NX4XX5O44Z","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":3},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":733.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":733.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"51","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-66R3JKMTDD","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":663.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":663.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"53","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-F7T35VTVNV","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":713.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":713.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"60","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-BK3WFF6ADE","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> β + Ge","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":996.0,"temperature_max_K":996.8,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":996.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"62","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-Q7LMBUE5B5","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":725.0,"temperature_uncertainty":{"basis":"printed","value":25.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":25.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":25.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":725.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"65","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-FDBOG4II5Q","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":703.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":703.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"65","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-O7YZ2HMRUT","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":9},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> α + Te","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":653.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":653.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"65","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-S2EZPI3H22","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.49,"TE":0.51},"composition_source":"stoichiometric_model_phase","phase":"γ"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"γ","model_phase":"GETE_GAMMA"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γ -> α + Te","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":638.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":638.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"69","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-4IIRPLBYYQ","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":11},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":701.0,"temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":701.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"69","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-KWCE4VWF5E","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":673.0,"temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":673.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"75","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-56QG7PO5OZ","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":14},"merged_ids":["ORC-XAOJEFLTNW"],"merged_pids":["doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r13#invariant_reaction"],"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":700.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":700.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"75","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-74Z5T2KT7I","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":15},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":630.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":630.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"76","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-MY4VHHJ4W5","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":673.0,"temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":673.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"76","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-ZKNVEC7HPF","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":17},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":638.0,"temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":638.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-F7FJ4C5HKP","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":700.0,"temperature_uncertainty":{"basis":"printed","value":4.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":700.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-F4OT3AURCX","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":19},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":675.0,"temperature_uncertainty":{"basis":"printed","value":4.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":675.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-TA6SJ23POK","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":20},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> α + Te","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":655.0,"temperature_uncertainty":{"basis":"printed","value":4.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":655.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-EI3J4M7ENM","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":21},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.49,"TE":0.51},"composition_source":"stoichiometric_model_phase","phase":"γ"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"γ","model_phase":"GETE_GAMMA"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γ -> α + Te","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":629.0,"temperature_uncertainty":{"basis":"printed","value":4.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":629.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-DYIQOHVHNC","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":22},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> β + Ge","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":993.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":993.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-NCMAZDQJ7Z","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":23},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":703.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":703.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-7DEH6VWT7P","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":24},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":673.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":673.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-AIPUW77DYA","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":25},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> α + Te","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":648.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":648.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"1","status":"unresolved"},{"kind":"unknown","label":"77","status":"unresolved"},{"kind":"unknown","label":"2","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-SJR37GQKJF","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":26},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.49,"TE":0.51},"composition_source":"stoichiometric_model_phase","phase":"γ"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"γ","model_phase":"GETE_GAMMA"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γ -> α + Te","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":638.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":638.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"82","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-4BVADXFP5S","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":27},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> α + Te","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":655.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":655.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"84","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-NSSWDDJZWT","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":28},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":678.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":678.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"84","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-6L3S75QOS6","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":29},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r29#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> α + Te","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":658.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":658.0},{"chemical_system":"GE-TE","cited_sources":[{"kind":"unknown","label":"86","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-P3DC22R2L2","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":30},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r30#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":683.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":683.0},{"chemical_system":"GE-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-6WWYIUPAN6","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":31},"model":"M122dcbf1","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/s0364-5916(99)00012-7","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r31#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> β + Ge","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":993.1,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":993.1},{"chemical_system":"GE-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-SKIMSQ3KGN","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":32},"model":"M122dcbf1","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/s0364-5916(99)00012-7","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"}],"phases":[{"label":"α","model_phase":"GETE_LOW"},{"label":"β","model_phase":"GETE_B1"},{"label":"Ge","model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"α -> β + Ge","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":703.2,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":703.2},{"chemical_system":"GE-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-H6GS7HLNAA","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":33},"model":"M122dcbf1","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/s0364-5916(99)00012-7","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"β"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"β","model_phase":"GETE_B1"},{"label":"α","model_phase":"GETE_LOW"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r33#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"β -> α + L","type":"metatectic/catatectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":678.2,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"metatectic/catatectic","transition_kind_printed":"Metatectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":678.2},{"chemical_system":"GE-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-DPDTOKPB5K","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":34},"model":"M122dcbf1","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/s0364-5916(99)00012-7","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r34#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> α + Te","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":658.1,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":658.1},{"chemical_system":"GE-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-4MBVNMQFVE","locator":{"ref":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2","row":35},"model":"M122dcbf1","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/s0364-5916(99)00012-7","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(99)00012-7","paper_id":"doi:10.1016/s0364-5916(99)00012-7","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.49,"TE":0.51},"composition_source":"stoichiometric_model_phase","phase":"γ"},{"basis":"mole_fraction","composition":{"GE":0.5,"TE":0.5},"composition_source":"formula_nominal","phase":"α"}],"phases":[{"label":"γ","model_phase":"GETE_GAMMA"},{"label":"α","model_phase":"GETE_LOW"},{"label":"Te","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/s0364-5916(99)00012-7/p3/tab-2/r35#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γ -> α + Te","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"GE-TE","system":"GE-TE","temperature_K":638.3,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":638.3}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"GE-TE"}