{"artifacts":{"doi:10.1007/s11669-018-0622-7/p3/tab-1":{"artifact":"table","caption":"Comparison between the calculated and measured invariant reactions in the Mn-H systems (at about 50 MPa)","label":"1","page":3},"doi:10.1007/s11669-018-0622-7/p3/tab-2":{"artifact":"table","caption":"Formation energy of Mn-H system from DFT databases","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["H","MN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M97c80e2f":{"catalog_entry":{"license":"CC BY 4.0","name":"MnH-18Lia.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Y. Liang, S. Liu, Y. Du, J. Phase Equilib. Diffus., 39, 186-95(2018).","model_doi":"10.1007/s11669-018-0622-7","reproduced_by_calculation":false,"tdb":"MnH-18Lia.tdb","tdb_path":"databases/sgte-binary/MnH-18Lia.tdb","tdb_sha256":"ee68c7da6eef802be4a9624d50b502f276af086beef8a60376334c879957d1ea"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s11669-018-0622-7":{"authors":["Yongpeng Liang","Shuhong Liu","Yong Du"],"citation":"Yongpeng Liang, Shuhong Liu, Yong Du, Thermodynamic Assessment of the Mn-H and Mg-Mn-H Systems, J. Phase Equilib. Diffus. 39, 186-195 (2018).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-018-0622-7","doi_url":"https://doi.org/10.1007/s11669-018-0622-7","id":"doi:10.1007/s11669-018-0622-7","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"94a834c008b90447","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessment of the Mn-H and Mg-Mn-H Systems","year":2018},"ref:8dbe9615a890288c":{"citation":"H.E. Serdyuk and B.I. Shapovalov, The Constitution Diagram of the Manganese-Hydride System, lzv. EU.Z Chernaya Metall., 1982, 8, p 70-74","id":"ref:8dbe9615a890288c","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1982}},"part":1,"parts":1,"records":[{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-H54PLG365N.251b66","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":1},"merged_ids":["ORC-H54PLG365N.7b735a"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.1165},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atoms","unit_stored":"J/mol-atom","value":2.33,"value_printed":2.33,"value_stored":2330.0},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-H54PLG365N.daf370","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":1},"merged_ids":["ORC-H54PLG365N.52eae7"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.167472519},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.04824},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"eV/atom","unit_stored":"J/mol-atom","value":23.34945037,"value_printed":0.242,"value_stored":23349.45037},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-DHVE6SQ3GC.38c9dc","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":2},"merged_ids":["ORC-DHVE6SQ3GC.67e7f9"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.279},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atoms","unit_stored":"J/mol-atom","value":5.58,"value_printed":5.58,"value_stored":5580.0},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-DHVE6SQ3GC.9426db","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":2},"merged_ids":["ORC-DHVE6SQ3GC.12b59c"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.793250365},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.04824},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"eV/atom","unit_stored":"J/mol-atom","value":55.8650073,"value_printed":0.579,"value_stored":55865.0073},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"24","reference":"https://www.materialsproject.org/materials/mp-24416/#. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-RQ5XFUJIIE.70ff32","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":3},"merged_ids":["ORC-RQ5XFUJIIE.3eb637"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.8056525232},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.04824},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"eV/atom","unit_stored":"J/mol-atom","value":16.11305046,"value_printed":0.167,"value_stored":16113.05046},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"24","reference":"https://www.materialsproject.org/materials/mp-24416/#. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-RQ5XFUJIIE.f5b655","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":3},"merged_ids":["ORC-RQ5XFUJIIE.a15dc1"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.08},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atoms","unit_stored":"J/mol-atom","value":1.6,"value_printed":1.6,"value_stored":1600.0},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-6BWCK2PCFQ.6a3724","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":4},"merged_ids":["ORC-6BWCK2PCFQ.997968"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH3"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.174},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atoms","unit_stored":"J/mol-atom","value":3.48,"value_printed":3.48,"value_stored":3480.0},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-6BWCK2PCFQ.87650d","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":4},"merged_ids":["ORC-6BWCK2PCFQ.111f1f"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH3"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.741560245},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.04824},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"eV/atom","unit_stored":"J/mol-atom","value":34.8312049,"value_printed":0.361,"value_stored":34831.2049},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-NJ2X3MWOZX.636e2e","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":5},"merged_ids":["ORC-NJ2X3MWOZX.0520a7"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH3"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.181},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atoms","unit_stored":"J/mol-atom","value":3.62,"value_printed":3.62,"value_stored":3620.0},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-NJ2X3MWOZX.8728d7","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":5},"merged_ids":["ORC-NJ2X3MWOZX.7ba2ac"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"MnH3"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.813924244},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.04824},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"eV/atom","unit_stored":"J/mol-atom","value":36.27848488,"value_printed":0.376,"value_stored":36278.48488},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-QY7V64EOKA.cfe956","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":6},"merged_ids":["ORC-QY7V64EOKA.c97a4e"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"Mn3H"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.244},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atoms","unit_stored":"J/mol-atom","value":4.88,"value_printed":4.88,"value_stored":4880.0},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-QY7V64EOKA.f25454","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":6},"merged_ids":["ORC-QY7V64EOKA.d8b42e"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"Mn3H"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.445903169},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.04824},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"eV/atom","unit_stored":"J/mol-atom","value":48.91806338,"value_printed":0.507,"value_stored":48918.06338},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-LFZL3MLUX7.c17406","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":7},"merged_ids":["ORC-LFZL3MLUX7.f73cd9"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"Mn3H"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.275},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ/mol-atoms","unit_stored":"J/mol-atom","value":5.5,"value_printed":5.5,"value_stored":5500.0},{"chemical_system":"H-MN","cited_sources":[{"kind":"unknown","label":"23","reference":"http://oqmd.org/materials/composition/Mn-H. Accessed 10 Feb 2018","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":0,"id":"ORC-LFZL3MLUX7.f83f1e","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-2","row":7},"merged_ids":["ORC-LFZL3MLUX7.fda541"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"MN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phases":[{"label":"Mn3H"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation energy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"H":{"fixed_state_variables":{"T":298.15},"phase":"1/2_MOLE_H2(G)","phase_before_quality_fix":"1"},"MN":{"fixed_state_variables":{"T":298.15},"phase":"CBCC_A12"}},"source_system":"H-MN","system":"H-MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.754656232},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.04824},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"eV/atom","unit_stored":"J/mol-atom","value":55.09312464,"value_printed":0.571,"value_stored":55093.12464},{"chemical_system":"H-MN","cited_sources":[{"first_author":"Serdyuk","kind":"experimental","label":"19","reference":"H.E. Serdyuk and B.I. Shapovalov, The Constitution Diagram of the Manganese-Hydride System, lzv. EU.Z Chernaya Metall., 1982, 8, p 70-74","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-26.108,"dx":{"(δMn)":0.04,"L":0.0575},"model":"MnH-18Lia.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-3XBXHJA3ZZ","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:8dbe9615a890288c","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.062},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"H":0.042},"composition_source":"printed","phase":"(δMn)"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(δMn)","mapping_confidence":"confirmed","model_phase":"BCC_A2"},{"label":"Gas","mapping_confidence":"confirmed","model_phase":"GAS"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r-unplaced-3bf39a3d#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> (δMn) + Gas","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":1489.15,"temperature_printed":"1216","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1489.15},{"chemical_system":"H-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-28.108,"dx":{"(δMn)":0.0396,"L":0.0575},"model":"MnH-18Lia.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-VQ4MD7MVLK","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":2},"model":"M97c80e2f","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-018-0622-7","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.062},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"H":0.0416},"composition_source":"printed","phase":"(δMn)"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(δMn)","mapping_confidence":"confirmed","model_phase":"BCC_A2"},{"label":"Gas","mapping_confidence":"confirmed","model_phase":"GAS"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r02#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> (δMn) + Gas","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":1487.15,"temperature_printed":"1214","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1487.15},{"chemical_system":"H-MN","cited_sources":[{"first_author":"Serdyuk","kind":"experimental","label":"19","reference":"H.E. Serdyuk and B.I. Shapovalov, The Constitution Diagram of the Manganese-Hydride System, lzv. EU.Z Chernaya Metall., 1982, 8, p 70-74","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":5.784,"dx":{"(γMn)":0.0442,"(δMn)":0.0311},"model":"MnH-18Lia.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-BXQGGNX5W7","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":3},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:8dbe9615a890288c","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.033},"composition_source":"printed","phase":"(δMn)"},{"basis":"mole_fraction","composition":{"H":0.046},"composition_source":"printed","phase":"(γMn)"}],"phases":[{"label":"(δMn)","mapping_confidence":"confirmed","model_phase":"BCC_A2"},{"label":"Gas","mapping_confidence":"confirmed","model_phase":"GAS"},{"label":"(γMn)","mapping_confidence":"confirmed","model_phase":"FCC_A1"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r03#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(δMn) + Gas -> (γMn)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":1416.15,"temperature_printed":"1143","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1416.15},{"chemical_system":"H-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":7.784,"dx":{"(γMn)":0.0375,"(δMn)":0.0357},"model":"MnH-18Lia.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-M2UUNOENH6","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":4},"model":"M97c80e2f","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-018-0622-7","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.0376},"composition_source":"printed","phase":"(δMn)"},{"basis":"mole_fraction","composition":{"H":0.0393},"composition_source":"printed","phase":"(γMn)"}],"phases":[{"label":"(δMn)","mapping_confidence":"confirmed","model_phase":"BCC_A2"},{"label":"Gas","mapping_confidence":"confirmed","model_phase":"GAS"},{"label":"(γMn)","mapping_confidence":"confirmed","model_phase":"FCC_A1"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r04#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(δMn) + Gas -> (γMn)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":1418.15,"temperature_printed":"1145","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1418.15},{"chemical_system":"H-MN","cited_sources":[{"first_author":"Serdyuk","kind":"experimental","label":"19","reference":"H.E. Serdyuk and B.I. Shapovalov, The Constitution Diagram of the Manganese-Hydride System, lzv. EU.Z Chernaya Metall., 1982, 8, p 70-74","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-ANZ7FXN4YG","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:8dbe9615a890288c","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.041},"composition_source":"printed","phase":"(γMn)"},{"basis":"mole_fraction","composition":{"H":0.034},"composition_source":"printed","phase":"(βMn)"}],"phases":[{"label":"(γMn)","mapping_confidence":"confirmed","model_phase":"FCC_A1"},{"label":"(βMn)","mapping_confidence":"confirmed","model_phase":"CUB_A13"},{"label":"Gas","mapping_confidence":"confirmed","model_phase":"GAS"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r05#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(γMn) -> (βMn) + Gas"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":1330.15,"temperature_printed":"1057","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1330.15},{"chemical_system":"H-MN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-OKQYTIGJ25","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":6},"model":"M97c80e2f","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-018-0622-7","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.0381},"composition_source":"printed","phase":"(γMn)"},{"basis":"mole_fraction","composition":{"H":0.0328},"composition_source":"printed","phase":"(βMn)"}],"phases":[{"label":"(γMn)","mapping_confidence":"confirmed","model_phase":"FCC_A1"},{"label":"(βMn)","mapping_confidence":"confirmed","model_phase":"CUB_A13"},{"label":"Gas","mapping_confidence":"confirmed","model_phase":"GAS"}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r06#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(γMn) -> (βMn) + Gas"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":1328.15,"temperature_printed":"1055","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1328.15},{"chemical_system":"H-MN","cited_sources":[{"first_author":"Serdyuk","kind":"experimental","label":"19","reference":"H.E. Serdyuk and B.I. Shapovalov, The Constitution Diagram of the Manganese-Hydride System, lzv. EU.Z Chernaya Metall., 1982, 8, p 70-74","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"ε","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_label_not_an_element_polymorph_of_this_structure"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-HZ7ILJYSMD","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:8dbe9615a890288c","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.028},"composition_source":"printed","phase":"(βMn)"},{"basis":"mole_fraction","composition":{"H":0.018},"composition_source":"printed","phase":"(αMn)"}],"phases":[{"label":"(βMn)","mapping_confidence":"confirmed","model_phase":"CUB_A13"},{"label":"(αMn)","mapping_confidence":"confirmed","model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","structure_basis":"mapped_model_phase"},{"label":"ε","model_phase_rejected":{"mapping_confidence":"confirmed","model_phase":"BCC_A2","reason":"greek_label_not_an_element_polymorph_of_this_structure"}}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r07#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βMn) -> (αMn) + ε"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":935.15,"temperature_printed":"662","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":935.15},{"chemical_system":"H-MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"ε","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_label_not_an_element_polymorph_of_this_structure"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-5OTFCBDFV4","locator":{"ref":"doi:10.1007/s11669-018-0622-7/p3/tab-1","row":8},"model":"M97c80e2f","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-018-0622-7","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-018-0622-7","paper_id":"doi:10.1007/s11669-018-0622-7","phase_compositions":[{"basis":"mole_fraction","composition":{"H":0.0194},"composition_source":"printed","phase":"(βMn)"},{"basis":"mole_fraction","composition":{"H":0.0096},"composition_source":"printed","phase":"(αMn)"}],"phases":[{"label":"(βMn)","mapping_confidence":"confirmed","model_phase":"CUB_A13"},{"label":"(αMn)","mapping_confidence":"confirmed","model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","structure_basis":"mapped_model_phase"},{"label":"ε","model_phase_rejected":{"mapping_confidence":"confirmed","model_phase":"BCC_A2","reason":"greek_label_not_an_element_polymorph_of_this_structure"}}],"pid":"doi:10.1007/s11669-018-0622-7/p3/tab-1/r08#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βMn) -> (αMn) + ε"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"H-MN","system":"H-MN","temperature_K":937.15,"temperature_printed":"664","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":937.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"H-MN"}