{"artifacts":{"doi:10.1007/s10973-013-3352-4/p1/text-08":{"artifact":"text_passage","label":"page 1, passage 8","page":1},"doi:10.1007/s10973-013-3352-4/p3/tab-3":{"artifact":"table","caption":"Invariant reactions in the Ho–Sn system","label":"3","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23735569},\n url = {https://doi.org/10.5281/zenodo.23735569},\n note = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID data: umbrella record of the ORCHID datasets}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23736065},\n url = {https://doi.org/10.5281/zenodo.23736065},\n note = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["HO","SN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M3698b4f9":{"catalog_entry":{"license":"CC BY 4.0","name":"HoSn-14Idd.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"L. Bouirden, J. Therm. Anal. Calorim., 115, 941-45(2014).","model_doi":"10.1007/s10973-013-3352-4","reproduced_by_calculation":true,"tdb":"HoSn-14Idd.tdb","tdb_path":"databases/sgte-binary/HoSn-14Idd.tdb","tdb_sha256":"41e6877408a408d40e75d925a0ed2e20731707b02b3cc6aabf3cf9bb6457243b"},"M7f517c1d":{"catalog_entry":{"license":"CC BY 4.0","name":"HoSn-14Idd.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"L. Bouirden, J. Therm. Anal. Calorim., 115, 941-45(2014).","model_doi":"10.1007/s10973-013-3352-4","reproduced_by_calculation":false,"tdb":"HoSn-14Idd.tdb","tdb_path":"databases/sgte-binary/HoSn-14Idd.tdb","tdb_sha256":"41e6877408a408d40e75d925a0ed2e20731707b02b3cc6aabf3cf9bb6457243b"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s10973-013-3352-4":{"authors":["A. Iddaoudi","N. Selhaoui","S. Kardellass","M. Ait Amar","K. Mahdouk","H. Najih","L. Bouirden"],"citation":"A. Iddaoudi, N. Selhaoui, S. Kardellass, M. Ait Amar, K. Mahdouk, H. Najih et al., Thermodynamic optimization of the Ho–Sn system, J Therm Anal Calorim 115, 941-945 (2014).","container":"J Therm Anal Calorim","doi":"10.1007/s10973-013-3352-4","doi_url":"https://doi.org/10.1007/s10973-013-3352-4","id":"doi:10.1007/s10973-013-3352-4","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"9c7f0143cccbf198","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic optimization of the Ho–Sn system","year":2014},"doi:10.1016/0925-8388(93)90859-l":{"authors":["A. Palenzona","P. Manfrinetti"],"citation":"A. Palenzona, P. Manfrinetti, The tin-rich side of the rare earth-tin systems (R = Gd, Tb, Dy, Ho, Er, Tm, Lu and Y), Journal of Alloys and Compounds 201, 43-47 (1993).","container":"Journal of Alloys and Compounds","doi":"10.1016/0925-8388(93)90859-l","doi_url":"https://doi.org/10.1016/0925-8388(93)90859-l","id":"doi:10.1016/0925-8388(93)90859-l","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The tin-rich side of the rare earth-tin systems (R = Gd, Tb, Dy, Ho, Er, Tm, Lu and Y)","year":1993},"doi:10.1361/105497198770342599":{"citation":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","doi":"10.1361/105497198770342599","doi_url":"https://doi.org/10.1361/105497198770342599","id":"doi:10.1361/105497198770342599","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]}},"part":1,"parts":1,"records":[{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":5.563,"dx":{"Liq":-0.0218},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-I4I44YRHFN","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":13},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.46},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.4444444444},"composition_source":"stoichiometry","phase":"Ho5Sn4"},{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"stoichiometry","phase":"Ho5Sn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho5Sn4","mapping_confidence":"confirmed","model_phase":"HO5SN4","pearson_symbol":"oP36","prototype":"Ge4Sm5","structure_basis":"mapped_model_phase"},{"label":"Ho5Sn3","mapping_confidence":"confirmed","model_phase":"HO5SN3_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-091ef0ef#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ho5Sn4 -> Ho5Sn3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1993,"temperature_printed":"1,993","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1993},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-5.67,"dx":{"Liq":0.0},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-6MFCDE47QS","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":10},"model":"M3698b4f9","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.666},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.5555555556},"composition_source":"stoichiometry","phase":"Ho4Sn5"},{"basis":"mole_fraction","composition":{"SN":0.4761904762},"composition_source":"stoichiometry","phase":"Sn10Ho11"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho4Sn5","mapping_confidence":"confirmed","model_phase":"HO4SN5","pearson_symbol":"?","prototype":"(Ho4Sn5)","structure_basis":"mapped_model_phase"},{"label":"Sn10Ho11","mapping_confidence":"confirmed","model_phase":"HO11SN10","pearson_symbol":"tI84","prototype":"Ge10Ho11","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-15276dc7#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ho4Sn5 -> Sn10Ho11"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1423,"temperature_printed":"1,423","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1423},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.071,"dx":{},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-OREQBMNMJU","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":2},"model":"M3698b4f9","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":1.0},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":1.0},"composition_source":"stoichiometric_model_phase","phase":"βSn"},{"basis":"mole_fraction","composition":{"SN":0.75},"composition_source":"stoichiometry","phase":"HoSn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"βSn","mapping_confidence":"confirmed","model_phase":"BCT_A5","pearson_symbol":"tI4","prototype":"beta-Sn","structure_basis":"mapped_model_phase"},{"label":"HoSn3","mapping_confidence":"confirmed","model_phase":"HOSN3","pearson_symbol":"oC16","prototype":"GdSn2.75","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-2b8d9fca#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> βSn + HoSn3","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":505,"temperature_printed":"505","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":505},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-3.139,"dx":{"Liq":-0.0001},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-TQV5OGBNNQ","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":12},"model":"M3698b4f9","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.535},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.4761904762},"composition_source":"stoichiometry","phase":"Sn10Ho11"},{"basis":"mole_fraction","composition":{"SN":0.4444444444},"composition_source":"stoichiometry","phase":"Ho5Sn4"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Sn10Ho11","mapping_confidence":"confirmed","model_phase":"HO11SN10","pearson_symbol":"tI84","prototype":"Ge10Ho11","structure_basis":"mapped_model_phase"},{"label":"Ho5Sn4","mapping_confidence":"confirmed","model_phase":"HO5SN4","pearson_symbol":"oP36","prototype":"Ge4Sm5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-35498caf#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Sn10Ho11 -> Ho5Sn4"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1868,"temperature_printed":"1,868","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1868},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-11.67,"dx":{"Liq":-0.006},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-FZC5C6WJCE","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":9},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.66},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.5555555556},"composition_source":"stoichiometry","phase":"Ho4Sn5"},{"basis":"mole_fraction","composition":{"SN":0.4761904762},"composition_source":"stoichiometry","phase":"Sn10Ho11"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho4Sn5","mapping_confidence":"confirmed","model_phase":"HO4SN5","pearson_symbol":"?","prototype":"(Ho4Sn5)","structure_basis":"mapped_model_phase"},{"label":"Sn10Ho11","mapping_confidence":"confirmed","model_phase":"HO11SN10","pearson_symbol":"tI84","prototype":"Ge10Ho11","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-76f65c7c#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ho4Sn5 -> Sn10Ho11"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1417,"temperature_printed":"1,417","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1417},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-JN67PTK6IX","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":16},"model":"M7f517c1d","observation_type":"phase_transition","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"congruent_same_composition","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"stoichiometry","phase":"Ho5Sn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho5Sn3","mapping_confidence":"confirmed","model_phase":"HO5SN3_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-84761bc0#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> Ho5Sn3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":2181,"temperature_printed":"2,181","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2181},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-27.565,"dx":{"Liq":-0.002},"model":"HoSn-14Idd.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-63AT5MZYUV","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":3},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.995},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.75},"composition_source":"stoichiometry","phase":"HoSn3"},{"basis":"mole_fraction","composition":{"SN":0.7142857143},"composition_source":"stoichiometry","phase":"Ho2Sn5"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"HoSn3","mapping_confidence":"confirmed","model_phase":"HOSN3","pearson_symbol":"oC16","prototype":"GdSn2.75","structure_basis":"mapped_model_phase"},{"label":"Ho2Sn5","mapping_confidence":"confirmed","model_phase":"HO2SN5","pearson_symbol":"oP14","prototype":"Er2Ge5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-88589144#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + HoSn3 -> Ho2Sn5"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":693,"temperature_printed":"693","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":693},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-YICWUY3JIO","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":15},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"congruent_same_composition","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"stoichiometry","phase":"Ho5Sn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho5Sn3","mapping_confidence":"confirmed","model_phase":"HO5SN3_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-89be3a8d#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> Ho5Sn3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":2188,"temperature_printed":"2,188","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2188},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-13.269,"dx":{"Liq":-0.0046},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-SUE3Y7LRDB","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":17},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.13},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"stoichiometry","phase":"Ho5Sn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"Ho5Sn3","mapping_confidence":"confirmed","model_phase":"HO5SN3_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-9a0559f4#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ho +Ho5Sn3","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1525,"temperature_printed":"1,525","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1525},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-13.269,"dx":{"Liq":0.0004},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-2TLY74S423","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":18},"model":"M7f517c1d","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.135},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"stoichiometry","phase":"Ho5Sn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"Ho5Sn3","mapping_confidence":"confirmed","model_phase":"HO5SN3_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-a4ebc5e5#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ho +Ho5Sn3","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1525,"temperature_printed":"1,525","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1525},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":7.315,"dx":{"Liq":0.0159},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-OEAIA7EUFD","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.7},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.6666666667},"composition_source":"stoichiometry","phase":"HoSn2"},{"basis":"mole_fraction","composition":{"SN":0.5555555556},"composition_source":"stoichiometry","phase":"Ho4Sn5"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"HoSn2","mapping_confidence":"confirmed","model_phase":"HOSN2_C49","pearson_symbol":"oC12","prototype":"Si2Zr","structure_basis":"mapped_model_phase"},{"label":"Ho4Sn5","mapping_confidence":"confirmed","model_phase":"HO4SN5","pearson_symbol":"?","prototype":"(Ho4Sn5)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-a6788dca#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + HoSn2 -> Ho4Sn5"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1387,"temperature_printed":"1,387","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1387},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.315,"dx":{"Liq":-0.0011},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-OD2JTC2XVS","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":8},"model":"M3698b4f9","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.683},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.6666666667},"composition_source":"stoichiometry","phase":"HoSn2"},{"basis":"mole_fraction","composition":{"SN":0.5555555556},"composition_source":"stoichiometry","phase":"Ho4Sn5"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"HoSn2","mapping_confidence":"confirmed","model_phase":"HOSN2_C49","pearson_symbol":"oC12","prototype":"Si2Zr","structure_basis":"mapped_model_phase"},{"label":"Ho4Sn5","mapping_confidence":"confirmed","model_phase":"HO4SN5","pearson_symbol":"?","prototype":"(Ho4Sn5)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-b4e71bc0#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + HoSn2 -> Ho4Sn5"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1380,"temperature_printed":"1,380","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1380},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.005,"dx":{"Liq":-0.0004},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-OS5NL7JDSR","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.992},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.7142857143},"composition_source":"stoichiometry","phase":"Ho2Sn5"},{"basis":"mole_fraction","composition":{"SN":0.6666666667},"composition_source":"stoichiometry","phase":"HoSn2"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho2Sn5","mapping_confidence":"confirmed","model_phase":"HO2SN5","pearson_symbol":"oP14","prototype":"Er2Ge5","structure_basis":"mapped_model_phase"},{"label":"HoSn2","mapping_confidence":"confirmed","model_phase":"HOSN2_C49","pearson_symbol":"oC12","prototype":"Si2Zr","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-b543917c#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ho2Sn5 -> HoSn2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":782,"temperature_printed":"782","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":782},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":3.563,"dx":{"Liq":-0.0078},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-RPZ2WNKXHL","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":14},"model":"M3698b4f9","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.474},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.4444444444},"composition_source":"stoichiometry","phase":"Ho5Sn4"},{"basis":"mole_fraction","composition":{"SN":0.375},"composition_source":"stoichiometry","phase":"Ho5Sn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho5Sn4","mapping_confidence":"confirmed","model_phase":"HO5SN4","pearson_symbol":"oP36","prototype":"Ge4Sm5","structure_basis":"mapped_model_phase"},{"label":"Ho5Sn3","mapping_confidence":"confirmed","model_phase":"HO5SN3_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-bd898d0b#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ho5Sn4 -> Ho5Sn3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1991,"temperature_printed":"1,991","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1991},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-3.071,"dx":{"Liq":-0.001},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-DPTF3KLKH3","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.999},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":1.0},"composition_source":"stoichiometric_model_phase","phase":"βSn"},{"basis":"mole_fraction","composition":{"SN":0.75},"composition_source":"stoichiometry","phase":"HoSn3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"βSn","mapping_confidence":"confirmed","model_phase":"BCT_A5","pearson_symbol":"tI4","prototype":"beta-Sn","structure_basis":"mapped_model_phase"},{"label":"HoSn3","mapping_confidence":"confirmed","model_phase":"HOSN3","pearson_symbol":"oC16","prototype":"GdSn2.75","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-ed1b5012#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> βSn + HoSn3","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":502,"temperature_printed":"502","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":502},{"chemical_system":"HO-SN","cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-6.139,"dx":{"Liq":-0.0451},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-YUDYWQZJJ7","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":11},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"doi:10.1361/105497198770342599","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.49},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.4761904762},"composition_source":"stoichiometry","phase":"Sn10Ho11"},{"basis":"mole_fraction","composition":{"SN":0.4444444444},"composition_source":"stoichiometry","phase":"Ho5Sn4"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Sn10Ho11","mapping_confidence":"confirmed","model_phase":"HO11SN10","pearson_symbol":"tI84","prototype":"Ge10Ho11","structure_basis":"mapped_model_phase"},{"label":"Ho5Sn4","mapping_confidence":"confirmed","model_phase":"HO5SN4","pearson_symbol":"oP36","prototype":"Ge4Sm5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r-unplaced-f1236f89#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Sn10Ho11 -> Ho5Sn4"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":1865,"temperature_printed":"1,865","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1865},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-27.565,"dx":{"Liq":0.001},"model":"HoSn-14Idd.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-LPSLJWYDYC","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":4},"model":"M7f517c1d","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.998},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.75},"composition_source":"stoichiometry","phase":"HoSn3"},{"basis":"mole_fraction","composition":{"SN":0.7142857143},"composition_source":"stoichiometry","phase":"Ho2Sn5"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"HoSn3","mapping_confidence":"confirmed","model_phase":"HOSN3","pearson_symbol":"oC16","prototype":"GdSn2.75","structure_basis":"mapped_model_phase"},{"label":"Ho2Sn5","mapping_confidence":"confirmed","model_phase":"HO2SN5","pearson_symbol":"oP14","prototype":"Er2Ge5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r02#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + HoSn3 -> Ho2Sn5"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":693,"temperature_printed":"693","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":693},{"chemical_system":"HO-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.005,"dx":{"Liq":-0.0004},"model":"HoSn-14Idd.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-G5F2B54OCC","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p3/tab-3","row":6},"model":"M3698b4f9","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s10973-013-3352-4","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phase_compositions":[{"basis":"mole_fraction","composition":{"SN":0.992},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"SN":0.7142857143},"composition_source":"stoichiometry","phase":"Ho2Sn5"},{"basis":"mole_fraction","composition":{"SN":0.6666666667},"composition_source":"stoichiometry","phase":"HoSn2"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ho2Sn5","mapping_confidence":"confirmed","model_phase":"HO2SN5","pearson_symbol":"oP14","prototype":"Er2Ge5","structure_basis":"mapped_model_phase"},{"label":"HoSn2","mapping_confidence":"confirmed","model_phase":"HOSN2_C49","pearson_symbol":"oC12","prototype":"Si2Zr","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s10973-013-3352-4/p3/tab-3/r03#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ho2Sn5 -> HoSn2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"HO-SN","system":"HO-SN","temperature_K":782,"temperature_printed":"782","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":782},{"chemical_system":"HO-SN","citations_printed":["[6]"],"cited_sources":[{"doi":"10.1016/0925-8388(93)90859-l","first_author":"Palenzona","kind":"unknown","label":"6","paper":"doi:10.1016/0925-8388(93)90859-l","reference":"Palenzona A, Manfrinetti P. The tin-rich side of the rare earth-tin systems (R = Gd, Tb, Dy, Ho, Er, Tm, Lu and Y). J Alloys Compd. 1993;201:43–7.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-IJWTJPF62F.0399ce","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p1/text-08"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0925-8388(93)90859-l","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phases":[{"label":"HoSn3"}],"pid":"doi:10.1007/s10973-013-3352-4/p1/text-08/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"For the HoSn2, Ho2Sn5, and HoSn3 compounds, a peritectic formation were reported, respectively, at 1,403, 793, and 693 K.","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"HO-SN","system":"HO-SN","temperature_K":693.0,"temperature_printed":"693","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":693.0},{"chemical_system":"HO-SN","citations_printed":["[6]"],"cited_sources":[{"doi":"10.1016/0925-8388(93)90859-l","first_author":"Palenzona","kind":"unknown","label":"6","paper":"doi:10.1016/0925-8388(93)90859-l","reference":"Palenzona A, Manfrinetti P. The tin-rich side of the rare earth-tin systems (R = Gd, Tb, Dy, Ho, Er, Tm, Lu and Y). J Alloys Compd. 1993;201:43–7.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-IJWTJPF62F.dcc46b","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p1/text-08"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0925-8388(93)90859-l","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phases":[{"label":"Ho2Sn5"}],"pid":"doi:10.1007/s10973-013-3352-4/p1/text-08/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"For the HoSn2, Ho2Sn5, and HoSn3 compounds, a peritectic formation were reported, respectively, at 1,403, 793, and 693 K.","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"HO-SN","system":"HO-SN","temperature_K":793.0,"temperature_printed":"793","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":793.0},{"chemical_system":"HO-SN","citations_printed":["[7]"],"cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-JX5IDG3XWS.287a86","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p1/text-08"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"doi:10.1361/105497198770342599","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phases":[{"label":"Ho5Sn3"}],"pid":"doi:10.1007/s10973-013-3352-4/p1/text-08/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"For the Ho5Sn3 compound, a congruent melting was estimated at 2,188 K, while for the Ho5Sn4, Ho11Sn10, Ho4Sn5, HoSn2, Ho2Sn5, and HoSn3 compounds, a peritectic formation was reported, respectively, at 1,993, 1,865, 1,417, 1,387, 782, and 693 K (see Fig. 1).","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"HO-SN","system":"HO-SN","temperature_K":2188.0,"temperature_printed":"2,188","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2188.0},{"chemical_system":"HO-SN","citations_printed":["[7]"],"cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-JX5IDG3XWS.65f997","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p1/text-08"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"doi:10.1361/105497198770342599","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phases":[{"label":"Ho2Sn5"}],"pid":"doi:10.1007/s10973-013-3352-4/p1/text-08/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"For the Ho5Sn3 compound, a congruent melting was estimated at 2,188 K, while for the Ho5Sn4, Ho11Sn10, Ho4Sn5, HoSn2, Ho2Sn5, and HoSn3 compounds, a peritectic formation was reported, respectively, at 1,993, 1,865, 1,417, 1,387, 782, and 693 K (see Fig. 1).","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"HO-SN","system":"HO-SN","temperature_K":782.0,"temperature_printed":"782","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":782.0},{"chemical_system":"HO-SN","citations_printed":["[7]"],"cited_sources":[{"doi":"10.1361/105497198770342599","first_author":"Bulanova","kind":"assessment","label":"7","paper":"doi:10.1361/105497198770342599","reference":"Bulanova MV, Eremenko VN, Petjukh VM, Sidorko VR. The Ho– Sn (Holmium–Tin) System. J Phase Equilib. 1998;19:136–41.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-JX5IDG3XWS.aaa069","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s10973-013-3352-4/p1/text-08"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"doi:10.1361/105497198770342599","own_work_of_paper":false},"paper":"doi:10.1007/s10973-013-3352-4","paper_id":"doi:10.1007/s10973-013-3352-4","phases":[{"label":"HoSn3"}],"pid":"doi:10.1007/s10973-013-3352-4/p1/text-08/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"For the Ho5Sn3 compound, a congruent melting was estimated at 2,188 K, while for the Ho5Sn4, Ho11Sn10, Ho4Sn5, HoSn2, Ho2Sn5, and HoSn3 compounds, a peritectic formation was reported, respectively, at 1,993, 1,865, 1,417, 1,387, 782, and 693 K (see Fig. 1).","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"HO-SN","system":"HO-SN","temperature_K":693.0,"temperature_printed":"693","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":693.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"HO-SN"}