{"artifacts":{"sha256:d0001fa1be50275f/p3/tab-1":{"artifact":"table","caption":"Crystal structure data of the phases in the Ir-Mo and Ir-W systems","label":"1","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["IR","MO","W"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.2298/jmmb190211001h":{"authors":["Y.-Y. Huang","B. Wu","F. Li","L.-L. Chen","Z.-X. Deng","K. Chang"],"citation":"Y.-Y. Huang, B. Wu, F. Li, L.-L. Chen, Z.-X. Deng, K. Chang, First-principles and CALPHAD-type study of the Ir-Mo and Ir-W systems, J min metall B Metall 56, 109-118 (2020).","container":"J min metall B Metall","doi":"10.2298/jmmb190211001h","doi_url":"https://doi.org/10.2298/jmmb190211001h","id":"doi:10.2298/jmmb190211001h","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"d0001fa1be50275f","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"First-principles and CALPHAD-type study of the Ir-Mo and Ir-W systems","year":2020}},"part":1,"parts":1,"records":[{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Michalik","kind":"unknown","label":"15","reference":"S.J. Michalik, J.H. Brophy, Trans. Metall. Aime, 227 (1963) 7.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"ε | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,4],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 3-4: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-5SMXRQ5ZFX.1b4cfb","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"ε"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006094,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006094},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.77,"value_stored":2.77},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Michalik","kind":"unknown","label":"15","reference":"S.J. Michalik, J.H. Brophy, Trans. Metall. Aime, 227 (1963) 7.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"ε | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,4],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 3-4: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-5SMXRQ5ZFX.bb11da","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"ε"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006094,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006094},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.77,"value_stored":2.77},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Michalik","kind":"unknown","label":"15","reference":"S.J. Michalik, J.H. Brophy, Trans. Metall. Aime, 227 (1963) 7.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"ε | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,4],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 3-4: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-5SMXRQ5ZFX.e1c996","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"ε"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009733,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009733},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.424,"value_stored":4.424},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"ε | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,4],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 3-4: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-TXDXRWFWNU.25c3cc","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"ε"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03437,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03437},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.463,"value_stored":4.463},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"ε | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,4],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 3-4: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-TXDXRWFWNU.8b351a","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"ε"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02152,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02152},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.795,"value_stored":2.795},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"ε | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,4],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 3-4: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-TXDXRWFWNU.bb6e01","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"ε"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"ε","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02152,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02152},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.795,"value_stored":2.795},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Spooner","kind":"unknown","label":"24","reference":"F.J. Spooner, Acta Cryst., 17 (1964) 6.","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"σ","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"σ | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 9-10: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for σ, inconsistent with printed P42/mnm (tetragonal), so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-D2T2U7CFOF.342df4","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"σ"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"σ","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02119,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02119},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.631,"value_stored":9.631},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Spooner","kind":"unknown","label":"24","reference":"F.J. Spooner, Acta Cryst., 17 (1964) 6.","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"σ","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"σ | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 9-10: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for σ, inconsistent with printed P42/mnm (tetragonal), so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-D2T2U7CFOF.aaf205","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"σ"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"σ","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01091,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01091},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.957,"value_stored":4.957},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Spooner","kind":"unknown","label":"24","reference":"F.J. Spooner, Acta Cryst., 17 (1964) 6.","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"σ","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"σ | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 9-10: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for σ, inconsistent with printed P42/mnm (tetragonal), so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-D2T2U7CFOF.e9b9a5","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"σ"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"σ","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02119,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02119},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.631,"value_stored":9.631},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"σ","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"σ | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 9-10: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for σ, inconsistent with printed P42/mnm (tetragonal), so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-XZUQGWGZZH.2ef7ee","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"σ"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"σ","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03817,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03817},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.957,"value_stored":4.957},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"σ","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"σ | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 9-10: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for σ, inconsistent with printed P42/mnm (tetragonal), so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-XZUQGWGZZH.84c150","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"σ"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"σ","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07473,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07473},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.705,"value_stored":9.705},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"σ","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"σ | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 9-10: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for σ, inconsistent with printed P42/mnm (tetragonal), so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-XZUQGWGZZH.8fcb61","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"σ"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"σ","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07473,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07473},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.705,"value_stored":9.705},{"chemical_system":"IR-MO-W","cited_sources":[{"kind":"unknown","label":"13","reference":"E. raub, P. Walter, Alloys of the platinum-group metals with tungsten, Heraeus Festschr, (1951) 23.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"e | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15,16],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 15-16: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-4EHF5RAPY4.054ba0","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"e"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009643,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009643},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.383,"value_stored":4.383},{"chemical_system":"IR-MO-W","cited_sources":[{"kind":"unknown","label":"13","reference":"E. raub, P. Walter, Alloys of the platinum-group metals with tungsten, Heraeus Festschr, (1951) 23.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"e | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15,16],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 15-16: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-4EHF5RAPY4.355aef","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"e"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006019,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006019},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.736,"value_stored":2.736},{"chemical_system":"IR-MO-W","cited_sources":[{"kind":"unknown","label":"13","reference":"E. raub, P. Walter, Alloys of the platinum-group metals with tungsten, Heraeus Festschr, (1951) 23.","status":"resolved","year":"1951"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"e | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15,16],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 15-16: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-4EHF5RAPY4.fbab1e","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"e"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006019,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006019},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.736,"value_stored":2.736},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"e | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15,16],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 15-16: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-6EEMBAC7L5.23b345","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":16},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"e"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02162,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02162},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.808,"value_stored":2.808},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"e | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15,16],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 15-16: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-6EEMBAC7L5.53923c","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":16},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"e"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02162,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02162},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.808,"value_stored":2.808},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"e | hexagonal | P63/mmc (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies crystal_system, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15,16],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 15-16: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-6EEMBAC7L5.77b99f","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":16},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"e"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"crystal_system":"Hexagonal","phase":"e","space_group":"P63/mmc"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03453,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03453},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.485,"value_stored":4.485},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Knapton","kind":"unknown","label":"21","reference":"A.G. Knapton, J. Inst. Met., 87 (1958) 5.","status":"resolved","year":"1958"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"s","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"s | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[17,18],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 17-18: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for s (sigma), inconsistent with printed P42/mnm, so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-WY3QTM2GBO.01d01b","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"s"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"s","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01102,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01102},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":5.01,"value_stored":5.01},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Knapton","kind":"unknown","label":"21","reference":"A.G. Knapton, J. Inst. Met., 87 (1958) 5.","status":"resolved","year":"1958"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"s","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"s | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[17,18],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 17-18: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for s (sigma), inconsistent with printed P42/mnm, so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-WY3QTM2GBO.30daf7","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"s"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"s","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02128,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02128},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.672,"value_stored":9.672},{"chemical_system":"IR-MO-W","cited_sources":[{"first_author":"Knapton","kind":"unknown","label":"21","reference":"A.G. Knapton, J. Inst. Met., 87 (1958) 5.","status":"resolved","year":"1958"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"phase":"s","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"s | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[17,18],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 17-18: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for s (sigma), inconsistent with printed P42/mnm, so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-WY3QTM2GBO.535369","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"s"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"s","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02128,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02128},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.672,"value_stored":9.672},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"s","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"s | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[17,18],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 17-18: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for s (sigma), inconsistent with printed P42/mnm, so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-CLZ22T3SAC.2bfd49","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":18},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"s"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"s","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07507,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07507},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.749,"value_stored":9.749},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"s","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"s | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[17,18],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 17-18: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for s (sigma), inconsistent with printed P42/mnm, so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-CLZ22T3SAC.b7b132","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":18},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"s"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"s","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07507,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07507},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.749,"value_stored":9.749},{"chemical_system":"IR-MO-W","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"phase":"s","space_group":"P42/mnm"},"before":null,"evidence":{"batch":"table_context_batch_03","doi":"10.2298/jmmb190211001h","pdf_page":3,"pdf_sha256":"d0001fa1be50275fdd7126cfd5c83b183fa57bbb1878783e17c3b9ea19873272","printed":"s | hexagonal | P42/mnm (Structure type | Pearson symbol/Space group columns)","rationale":"Printed table context for this group supplies space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[17,18],"table":"1","table_key":"t043"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"d4dbdd18d64a458f092155df2a32477ba988c2a0695eb86667090a147be91ade","page":3,"pdf_sha256_prefix":"d0001fa1be50275f","seen":"rows 17-18: printed first row (literature ref) plus blank-label continuation row 'This work (cal.)'; group ends at next phase label; Structure type column prints 'hexagonal' for s (sigma), inconsistent with printed P42/mnm, so crystal_system not patched","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":0,"fold_lso":3,"id":"ORC-CLZ22T3SAC.c545a5","locator":{"ref":"sha256:d0001fa1be50275f/p3/tab-1","row":18},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.2298/jmmb190211001h","own_work_of_paper":true},"paper":"doi:10.2298/jmmb190211001h","paper_id":"doi:10.2298/jmmb190211001h","phases":[{"label":"s"}],"pid":"sha256:d0001fa1be50275f/p3/tab-1/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"IR-MO-W","structure":{"phase":"s","space_group":"P42/mnm"},"system":"IR-MO-W","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03864,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03864},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":5.018,"value_stored":5.018}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"IR-MO-W"}