{"artifacts":{"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3":{"artifact":"table","caption":"Invariant reactions in the Mo–La system","label":"3","page":5}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["LA","MO"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M71bc1e4b":{"catalog_entry":{"license":"CC BY 4.0","name":"LaMo-08Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Alloys Compd., 453, 174-79(2008).","model_doi":"10.1016/j.jallcom.2006.11.155","reproduced_by_calculation":false,"tdb":"LaMo-08Wan.tdb","tdb_path":"databases/sgte-binary/LaMo-08Wan.tdb","tdb_sha256":"10142dd3033186857f3ac13a3f4f0070ed9e8636472a70f176f06f876d54c818"},"Me5f7198a":{"catalog_entry":{"license":"CC BY 4.0","name":"LaMo-08Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Alloys Compd., 453, 174-79(2008).","model_doi":"10.1016/j.jallcom.2006.11.155","reproduced_by_calculation":true,"tdb":"LaMo-08Wan.tdb","tdb_path":"databases/sgte-binary/LaMo-08Wan.tdb","tdb_sha256":"10142dd3033186857f3ac13a3f4f0070ed9e8636472a70f176f06f876d54c818"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.jallcom.2006.11.155":{"authors":["C.P. Wang","J. Wang","X.J. Liu","I. Ohnuma","R. Kainuma","K. Ishida"],"citation":"C.P. Wang, J. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–La and Mo–La systems, Journal of Alloys and Compounds 453, 174-179 (2008).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2006.11.155","doi_url":"https://doi.org/10.1016/j.jallcom.2006.11.155","id":"doi:10.1016/j.jallcom.2006.11.155","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"67615f47a459cf96","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Co–La and Mo–La systems","year":2008},"ref:bba7c5b8939acbe6":{"citation":"L. Brewer, in: O. Kubaschewski (Ed.), Molybdenum, Physico-Chemical Properties of its Compounds and Alloys. Atomic Energy Review Special Issue No. 7, International Atomic Energy Agency, Vienna, 1980.","id":"ref:bba7c5b8939acbe6","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1980}},"part":1,"parts":1,"records":[{"chemical_system":"LA-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.016,"dx":{"L1":0.0042,"L2":0.7442,"bcc (Mo)":0.0012},"fail_reason":"composition","model":"LaMo-08Wan.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-GHDO2PYHTO","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3","row":2},"model":"Me5f7198a","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.155","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.155","paper_id":"doi:10.1016/j.jallcom.2006.11.155","phase_compositions":[{"basis":"mole_fraction","composition":{"MO":0.95},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction","composition":{"MO":0.21},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"MO":0.9987},"composition_source":"printed","phase":"bcc (Mo)"}],"phases":[{"label":"L2","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"L1","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"bcc (Mo)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3/r-unplaced-6b49f6d6#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 -> L1 + bcc (Mo)","type":"monotectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LA-MO","system":"LA-MO","temperature_K":2819.15,"temperature_printed":"2546","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2819.15},{"chemical_system":"LA-MO","cited_sources":[{"first_author":"Brewer","kind":"experimental","label":"19","reference":"L. Brewer, in: O. Kubaschewski (Ed.), Molybdenum, Physico-Chemical Properties of its Compounds and Alloys. Atomic Energy Review Special Issue No. 7, International Atomic Energy Agency, Vienna, 1980.","status":"resolved","year":"1980"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.016,"dx":{"L1":0.0042,"L2":0.7542,"bcc (Mo)":0.0012},"fail_reason":"composition","model":"LaMo-08Wan.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-ZVUU3AR6HU","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:bba7c5b8939acbe6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.155","paper_id":"doi:10.1016/j.jallcom.2006.11.155","phase_compositions":[{"basis":"mole_fraction","composition":{"MO":0.96},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction","composition":{"MO":0.21},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"MO":0.9987},"composition_source":"printed","phase":"bcc (Mo)"}],"phases":[{"label":"L2","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"L1","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"bcc (Mo)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3/r-unplaced-cf59a502#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 -> L1 + bcc (Mo)","type":"monotectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LA-MO","system":"LA-MO","temperature_K":2820.15,"temperature_printed":"2547","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2820.15},{"chemical_system":"LA-MO","cited_sources":[{"first_author":"Brewer","kind":"experimental","label":"19","reference":"L. Brewer, in: O. Kubaschewski (Ed.), Molybdenum, Physico-Chemical Properties of its Compounds and Alloys. Atomic Energy Review Special Issue No. 7, International Atomic Energy Agency, Vienna, 1980.","status":"resolved","year":"1980"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-MUHCWUD5XK","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3","row":3},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:bba7c5b8939acbe6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.155","paper_id":"doi:10.1016/j.jallcom.2006.11.155","phase_compositions":[{"basis":"mole_fraction","composition":{"MO":0.0009},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"MO":0.0},"composition_source":"printed","phase":"bcc (La)"},{"basis":"mole_fraction","composition":{"MO":1.0},"composition_source":"printed","phase":"bcc (Mo)"}],"phases":[{"label":"L1"},{"label":"bcc (La)"},{"label":"bcc (Mo)"}],"pid":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L1 -> bcc (La) + bcc (Mo)","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"LA-MO","system":"LA-MO","temperature_K":1191.15,"temperature_printed":"918","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1191.15},{"chemical_system":"LA-MO","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-DEMMVRCSZV","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3","row":4},"model":"M71bc1e4b","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.155","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.155","paper_id":"doi:10.1016/j.jallcom.2006.11.155","phase_compositions":[{"basis":"mole_fraction","composition":{"MO":0.00085},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"MO":1.0},"composition_source":"printed","phase":"bcc (Mo)"}],"phases":[{"label":"L1"},{"label":"bcc (La)"},{"label":"bcc (Mo)"}],"pid":"doi:10.1016/j.jallcom.2006.11.155/p5/tab-3/r02#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L1 -> bcc (La) + bcc (Mo)","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"LA-MO","system":"LA-MO","temperature_K":1190.15,"temperature_printed":"917","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1190.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"LA-MO"}