{"artifacts":{"doi:10.1007/s11669-022-00950-z/p16/tab-6":{"artifact":"table","caption":"Calculated invariant reactions of Te-Li system in comparison with literature data [88,91]","label":"6","page":16},"doi:10.1007/s11669-022-00950-z/p4/text-07":{"artifact":"text_passage","label":"page 4, passage 7","page":4},"sha256:b40cf8ff5f0922f1/p3/tab-1":{"artifact":"table","caption":"Crystal structures of phases in Te-X (X = Cu, Ga, Li, Sr) systems [26]","label":"1","page":3},"sha256:b40cf8ff5f0922f1/p5/tab-2":{"artifact":"table","caption":"Summary of experimental and calculated enthalpies of the formation from first principles (0 K) and CALPHAD (298.15 K) [58,59,79,96,98]","label":"2","page":5}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["LI","TE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M0471545d":{"catalog_entry":{"license":"CC BY 4.0","name":"LiTe-22Yu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib. Diffus., 43, 193-213(2022).","model_doi":"10.1007/s11669-022-00950-z","reproduced_by_calculation":true,"tdb":"LiTe-22Yu.tdb","tdb_path":"databases/sgte-binary/LiTe-22Yu.tdb","tdb_sha256":"036b3481f222317d3bcbeb3f51c5b4afb04df8b7d60054bd5a9a7b55e5161508"},"M5d305063":{"catalog_entry":{"license":"CC BY 4.0","name":"LiTe-22Yu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib. Diffus., 43, 193-213(2022).","model_doi":"10.1007/s11669-022-00950-z","reproduced_by_calculation":false,"tdb":"LiTe-22Yu.tdb","tdb_path":"databases/sgte-binary/LiTe-22Yu.tdb","tdb_sha256":"036b3481f222317d3bcbeb3f51c5b4afb04df8b7d60054bd5a9a7b55e5161508"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02667559":{"authors":["J. Songster","A. D. Pelton"],"citation":"J. Songster, A. D. Pelton, The li-te (lithium-tellurium) system, JPE 13, 300-303 (1992).","container":"JPE","doi":"10.1007/bf02667559","doi_url":"https://doi.org/10.1007/bf02667559","id":"doi:10.1007/bf02667559","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The li-te (lithium-tellurium) system","year":1992},"doi:10.1007/s11669-022-00950-z":{"authors":["Shangzhao Yu","Jiong Wang","Dongyu Cui","Shanxiong Chen","Qing Wu","Yong Du"],"citation":"Shangzhao Yu, Jiong Wang, Dongyu Cui, Shanxiong Chen, Qing Wu, Yong Du, Thermodynamic Modelling of the Te-X (X = Cu, Ga, Li, Sr) Systems, J. Phase Equilib. Diffus. 43, 193-213 (2022).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-022-00950-z","doi_url":"https://doi.org/10.1007/s11669-022-00950-z","id":"doi:10.1007/s11669-022-00950-z","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"b40cf8ff5f0922f1","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Modelling of the Te-X (X = Cu, Ga, Li, Sr) Systems","year":2022},"doi:10.1007/s11837-013-0755-4":{"authors":["James E. Saal","Scott Kirklin","Muratahan Aykol","Bryce Meredig","C. Wolverton"],"citation":"James E. Saal, Scott Kirklin, Muratahan Aykol, Bryce Meredig, C. Wolverton, Materials Design and Discovery with High-Throughput Density Functional Theory: The Open Quantum Materials Database (OQMD), JOM 65, 1501-1509 (2013).","container":"JOM","doi":"10.1007/s11837-013-0755-4","doi_url":"https://doi.org/10.1007/s11837-013-0755-4","id":"doi:10.1007/s11837-013-0755-4","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Materials Design and Discovery with High-Throughput Density Functional Theory: The Open Quantum Materials Database (OQMD)","year":2013},"doi:10.1016/0022-1902(78)80301-7":{"authors":["B.F. Hitch","L.M. Toth","J. Brynestad"],"citation":"B.F. Hitch, L.M. Toth, J. Brynestad, The decomposition equilibrium of LiTe3, Journal of Inorganic and Nuclear Chemistry 40, 31-34 (1978).","container":"Journal of Inorganic and Nuclear Chemistry","doi":"10.1016/0022-1902(78)80301-7","doi_url":"https://doi.org/10.1016/0022-1902(78)80301-7","id":"doi:10.1016/0022-1902(78)80301-7","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The decomposition equilibrium of LiTe3","year":1978},"doi:10.1063/1.4812323":{"authors":["Anubhav Jain","Shyue Ping Ong","Geoffroy Hautier","Wei Chen","William Davidson Richards","Stephen Dacek","Shreyas Cholia","Dan Gunter","David Skinner","Gerbrand Ceder","Kristin A. Persson"],"citation":"Anubhav Jain, Shyue Ping Ong, Geoffroy Hautier, Wei Chen, William Davidson Richards, Stephen Dacek et al., Commentary: The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013).","container":"APL Materials","doi":"10.1063/1.4812323","doi_url":"https://doi.org/10.1063/1.4812323","id":"doi:10.1063/1.4812323","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Commentary: The Materials Project: A materials genome approach to accelerating materials innovation","year":2013},"doi:10.1107/s0567740877006141":{"authors":["D. Y. Valentine","O. B. Cavin","H. L. Yakel"],"citation":"D. Y. Valentine, O. B. Cavin, H. L. Yakel, On the crystal structure of LiTe3, Acta Crystallogr B Struct Crystallogr Cryst Chem 33, 1389-1396 (1977).","container":"Acta Crystallogr B Struct Crystallogr Cryst Chem","doi":"10.1107/s0567740877006141","doi_url":"https://doi.org/10.1107/s0567740877006141","id":"doi:10.1107/s0567740877006141","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"On the crystal structure of LiTe3","year":1977},"doi:10.1149/1.2403448":{"authors":["P. T. Cunningham","S. A. Johnson","E. J. Cairns"],"citation":"P. T. Cunningham, S. A. Johnson, E. J. Cairns, Phase Equilibria in Lithium-Chalcogen Systems, J. Electrochem. Soc. 120, 328 (1973).","container":"J. Electrochem. Soc.","doi":"10.1149/1.2403448","doi_url":"https://doi.org/10.1149/1.2403448","id":"doi:10.1149/1.2403448","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase Equilibria in Lithium-Chalcogen Systems","year":1973}},"part":1,"parts":1,"records":[{"chemical_system":"LI-TE","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"26","reference":"P. Villars, and L. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Compounds. ASM International, Materials Park, Ohio, USA, 1991.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"LI-TE","before":"CU-GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GA":0.0,"LI":0.666667,"SR":0.0,"TE":0.333333},"phases":["Li2Te"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["unit_scale_inconsistent_on_page"],"lattice_length_outside_typical_range":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"unit_scale_inconsistent_on_page","detail":"Header 'Lattice parameter, Å' but Te-Li/Te-Sr cells print 0.652, 0.871/2.135, 0.666: nm-scale numbers (Li2Te CaF2 and SrTe NaCl a ≈ 6.5-6.7 Å). Stored x Å is wrong by 10x; page states Å, so no exact conversion can be applied.","effect":"not_accepted","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (fieldunit, t188)","image_sha256":"4da2de6be12e5bfeb97e4302b4464a903be9490456ca9fe61b8ab16d6cd4b23f","page":3,"pdf_sha256_prefix":"b40cf8ff5f0922f1","seen":"Rows Li2Te (cF12, Fm-3m, CaF2) a 0.652; LiTe3 (hP48, P-3c1) a 0.871, c 2.135; SrTe (cF8, Fm-3m, NaCl) a 0.666","verdict":"confirmed"}}],"id":"ORC-TNG6SCPIM5","locator":{"ref":"sha256:b40cf8ff5f0922f1/p3/tab-1","row":22},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.666667,"TE":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"GA":0.0,"LI":0.666667,"SR":0.0,"TE":0.333333},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"Li2Te"}],"pid":"sha256:b40cf8ff5f0922f1/p3/tab-1/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-GA-LI-SR-TE","structure":{"pearson_symbol":"cF12","prototype":"CaF2"},"system":"LI-TE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00502,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.00502},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":0.652,"value_stored":0.652},{"chemical_system":"LI-TE","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"26","reference":"P. Villars, and L. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Compounds. ASM International, Materials Park, Ohio, USA, 1991.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"LI-TE","before":"CU-GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GA":0.0,"LI":0.25,"SR":0.0,"TE":0.75},"phases":["LiTe3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["unit_scale_inconsistent_on_page"],"lattice_length_outside_typical_range":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"unit_scale_inconsistent_on_page","detail":"Header 'Lattice parameter, Å' but Te-Li/Te-Sr cells print 0.652, 0.871/2.135, 0.666: nm-scale numbers (Li2Te CaF2 and SrTe NaCl a ≈ 6.5-6.7 Å). Stored x Å is wrong by 10x; page states Å, so no exact conversion can be applied.","effect":"not_accepted","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (fieldunit, t188)","image_sha256":"4da2de6be12e5bfeb97e4302b4464a903be9490456ca9fe61b8ab16d6cd4b23f","page":3,"pdf_sha256_prefix":"b40cf8ff5f0922f1","seen":"Rows Li2Te (cF12, Fm-3m, CaF2) a 0.652; LiTe3 (hP48, P-3c1) a 0.871, c 2.135; SrTe (cF8, Fm-3m, NaCl) a 0.666","verdict":"confirmed"}}],"id":"ORC-X65AGFPNYE.19529d","locator":{"ref":"sha256:b40cf8ff5f0922f1/p3/tab-1","row":23},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.25,"TE":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"GA":0.0,"LI":0.25,"SR":0.0,"TE":0.75},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"LiTe3"}],"pid":"sha256:b40cf8ff5f0922f1/p3/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-GA-LI-SR-TE","structure":{"pearson_symbol":"hP48","prototype":"LiTe3"},"system":"LI-TE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006707,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.006707},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":0.871,"value_stored":0.871},{"chemical_system":"LI-TE","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"26","reference":"P. Villars, and L. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Compounds. ASM International, Materials Park, Ohio, USA, 1991.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"LI-TE","before":"CU-GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GA":0.0,"LI":0.25,"SR":0.0,"TE":0.75},"phases":["LiTe3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["unit_scale_inconsistent_on_page"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"unit_scale_inconsistent_on_page","detail":"Header 'Lattice parameter, Å' but Te-Li/Te-Sr cells print 0.652, 0.871/2.135, 0.666: nm-scale numbers (Li2Te CaF2 and SrTe NaCl a ≈ 6.5-6.7 Å). Stored x Å is wrong by 10x; page states Å, so no exact conversion can be applied.","effect":"not_accepted","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (fieldunit, t188)","image_sha256":"4da2de6be12e5bfeb97e4302b4464a903be9490456ca9fe61b8ab16d6cd4b23f","page":3,"pdf_sha256_prefix":"b40cf8ff5f0922f1","seen":"Rows Li2Te (cF12, Fm-3m, CaF2) a 0.652; LiTe3 (hP48, P-3c1) a 0.871, c 2.135; SrTe (cF8, Fm-3m, NaCl) a 0.666","verdict":"confirmed"}}],"id":"ORC-X65AGFPNYE.b14198","locator":{"ref":"sha256:b40cf8ff5f0922f1/p3/tab-1","row":23},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.25,"TE":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"GA":0.0,"LI":0.25,"SR":0.0,"TE":0.75},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"LiTe3"}],"pid":"sha256:b40cf8ff5f0922f1/p3/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CU-GA-LI-SR-TE","structure":{"pearson_symbol":"hP48","prototype":"LiTe3"},"system":"LI-TE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01644,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.01644},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":2.135,"value_stored":2.135},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"LI-TE","before":"GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"LI":0.666667,"SR":0.0,"TE":0.333333},"phases":["Li2Te"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-FTLZK7Z4TL","locator":{"ref":"sha256:b40cf8ff5f0922f1/p5/tab-2","row":14},"method":"First-principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-022-00950-z","own_work_of_paper":true},"overall_composition":{"LI":0.666667,"TE":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"SR":0.0,"TE":0.333333},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"Li2Te"}],"pid":"sha256:b40cf8ff5f0922f1/p5/tab-2/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"LI":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"reference_state_stored":{"GA":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"SR":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"source_system":"GA-LI-SR-TE","system":"LI-TE","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.0006},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-100.012,"value_printed":-100.012,"value_stored":-100012.0},{"chemical_system":"LI-TE","cited_sources":[{"first_author":"Morachevskii","kind":"unknown","label":"96","reference":"A. Morachevskii, Lithium-Tellurium System: Thermodynamic and Electrochemical Studies and Prospects for Use in Chemical Current Sources, Russ. J. Appl. Chem., 2020, 93, p 313–324. J. Phase Equilib. Diffus. (2022) 43:193–213","status":"resolved","year":"2022"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"LI-TE","before":"GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"LI":0.666667,"SR":0.0,"TE":0.333333},"phases":["Li2Te"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:computation_context","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-PJVN7M5AQ4","locator":{"ref":"sha256:b40cf8ff5f0922f1/p5/tab-2","row":15},"method":"First-principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.666667,"TE":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"SR":0.0,"TE":0.333333},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"Li2Te"}],"pid":"sha256:b40cf8ff5f0922f1/p5/tab-2/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"LI":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"reference_state_stored":{"GA":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"SR":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"source_system":"GA-LI-SR-TE","system":"LI-TE","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.78335},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-115.667,"value_printed":-115.667,"value_stored":-115667.0},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1007/s11837-013-0755-4","first_author":"Saal","kind":"unknown","label":"58","paper":"doi:10.1007/s11837-013-0755-4","reference":"J.E. Saal, S. Kirklin, M. Aykol, B. Meredig, and C. Wolverton, Materials Design and Discovery with High-Throughput Density Functional Theory: The Open Quantum Materials Database (OQMD), JOM, 2013, 65, p 1501–1509. https://doi.org/10.1007/ s11837-013-0755-4 123 212","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"LI-TE","before":"GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"LI":0.666667,"SR":0.0,"TE":0.333333},"phases":["Li2Te"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-S2GCYHQKVS","locator":{"ref":"sha256:b40cf8ff5f0922f1/p5/tab-2","row":16},"method":"First-principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.666667,"TE":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"SR":0.0,"TE":0.333333},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"Li2Te"}],"pid":"sha256:b40cf8ff5f0922f1/p5/tab-2/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"LI":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"reference_state_stored":{"GA":{"phase":"ORTHORHOMBIC_A11"},"LI":{"phase":"BCC_A2"},"SR":{"phase":"FCC_A1"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"GA-LI-SR-TE","system":"LI-TE","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.0295},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-100.59,"value_printed":-100.59,"value_stored":-100590.0},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1063/1.4812323","first_author":"Jain","kind":"unknown","label":"59","paper":"doi:10.1063/1.4812323","reference":"A. Jain, S.P. Ong, G. Hautier, W. Chen, W.D. Richards, S. Dacek, S. Cholia, D. Gunter, D. Skinner, and G. Ceder, Commentary: The Materials Project: A Materials Genome Approach to Accelerating Materials Innovation, APL Mater., 2013, 1, p 011002.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"LI-TE","before":"GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"LI":0.666667,"SR":0.0,"TE":0.333333},"phases":["Li2Te"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-TOR6JTQIQ5","locator":{"ref":"sha256:b40cf8ff5f0922f1/p5/tab-2","row":17},"method":"First-principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.666667,"TE":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"SR":0.0,"TE":0.333333},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"Li2Te"}],"pid":"sha256:b40cf8ff5f0922f1/p5/tab-2/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"LI":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"reference_state_stored":{"GA":{"phase":"ORTHORHOMBIC_A11"},"LI":{"phase":"BCC_A2"},"SR":{"phase":"FCC_A1"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"GA-LI-SR-TE","system":"LI-TE","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.6805},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-113.61,"value_printed":-113.61,"value_stored":-113610.0},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"LI-TE","before":"GA-LI-SR-TE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"LI":0.666667,"SR":0.0,"TE":0.333333},"phases":["Li2Te"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-3FHXFANSEL","locator":{"ref":"sha256:b40cf8ff5f0922f1/p5/tab-2","row":18},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","own_work_of_paper":true},"overall_composition":{"LI":0.666667,"TE":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"SR":0.0,"TE":0.333333},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phases":[{"label":"Li2Te"}],"pid":"sha256:b40cf8ff5f0922f1/p5/tab-2/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"LI":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"reference_state_stored":{"GA":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"SR":{"phase":"printed:none"},"TE":{"phase":"printed:none"}},"source_system":"GA-LI-SR-TE","system":"LI-TE","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.94745},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-atom","unit_stored":"J/mol-atom","value":-118.949,"value_printed":-118.949,"value_stored":-118949.0},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"experimental","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":2.127,"dx":{"L1":-0.1087,"L2":0.0563,"Li2Te":-0.0003},"fail_reason":"composition","model":"LiTe-22Yu.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-LJ32BOKFPN","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1149/1.2403448","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.24},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction","composition":{"TE":0.075},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L2","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"L1","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-17d897ed#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 -> L1 + Li2Te","type":"monotectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":1085.2,"temperature_printed":"1085.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1085.2},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1007/bf02667559","first_author":"Sangster","kind":"assessment","label":"91","paper":"doi:10.1007/bf02667559","reference":"J. Sangster, and A. Pelton, The Li-Te (Lithium-Tellurium) System, J. Phase Equilibria, 1992, 13, p 300–303.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":1.8,"dx":{"Li2Te":-0.0003,"LiTe3":0.0},"model":"LiTe-22Yu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","source_disputed":true,"state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-FRVQROY4FH","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":14},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/bf02667559","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"printed","phase":"(Te)"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"},{"label":"(Te)","mapping_confidence":"confirmed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-6c8a8b54#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"LiTe3 -> (Te) + Li2Te"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":577,"temperature_printed":"577","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":577},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"experimental","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.108,"dx":{"L":0.0304,"Li2Te":-0.0003,"LiTe3":0.0},"model":"LiTe-22Yu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-BYUJJZRN7H","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1149/1.2403448","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.64},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-7a7d982f#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> LiTe3 + Li2Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":721.7,"temperature_printed":"721.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":721.7},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-4X3KTVELRO","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":1},"model":"M5d305063","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.0},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.0},"composition_source":"printed","phase":"(Li)"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(Li)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-7f0956f4#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> (Li) + Li2Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":453.6,"temperature_printed":"453.6","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":453.6},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.058,"dx":{"L":0.0001,"LiTe3":0.0},"model":"LiTe-22Yu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-NZYZ7Q4OPU","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":3},"model":"M0471545d","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.884},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"printed","phase":"(Te)"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(Te)","mapping_confidence":"confirmed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"},{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-8d56015f#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> (Te) + LiTe3","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":696.9,"temperature_printed":"696.9","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":696.9},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"experimental","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-QFLM5Z5AVL","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":12},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1149/1.2403448","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-9790de0a#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> LiTe3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":733,"temperature_printed":"733","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":733},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"experimental","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-CA37ENEZCO","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":10},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1149/1.2403448","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-98cd922c#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> Li2Te"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":1472,"temperature_printed":"1472","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1472},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"experimental","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-W7OAHGL4AP","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1149/1.2403448","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.0},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.0},"composition_source":"printed","phase":"(Li)"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(Li)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-9c3c9bd9#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> (Li) + Li2Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":453.1,"temperature_printed":"453.1","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":453.1},{"chemical_system":"LI-TE","cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"experimental","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.658,"dx":{"L":0.0111,"LiTe3":0.0},"model":"LiTe-22Yu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-ABCB7QIFLI","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1149/1.2403448","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.895},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"printed","phase":"(Te)"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(Te)","mapping_confidence":"confirmed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"},{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-9de16e56#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> (Te) + LiTe3","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":696.3,"temperature_printed":"696.3","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":696.3},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.173,"dx":{"L1":-0.1337,"L2":0.0003,"Li2Te":-0.0003},"fail_reason":"composition","model":"LiTe-22Yu.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-EXWHRCKHCV","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":7},"model":"M0471545d","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.184},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction","composition":{"TE":0.05},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L2","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"L1","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-b42e8589#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 -> L1 + Li2Te","type":"monotectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":1082.9,"temperature_printed":"1082.9","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1082.9},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-GQOM6UFZ4L","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":11},"model":"M5d305063","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-c05130bd#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> LiTe3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":732.7,"temperature_printed":"732.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":732.7},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-VFH3W56XIH","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":9},"model":"M0471545d","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-c3fb7aab#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> Li2Te"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":1468.2,"temperature_printed":"1468.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1468.2},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.1,"dx":{"Li2Te":-0.0003,"LiTe3":0.0},"model":"LiTe-22Yu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-2AWBJQKDL3","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":13},"model":"M0471545d","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"printed","phase":"(Te)"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"},{"label":"(Te)","mapping_confidence":"confirmed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-c6cf7e8a#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"LiTe3 -> (Te) + Li2Te"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":575.1,"temperature_printed":"575.1","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":575.1},{"chemical_system":"LI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.108,"dx":{"L":-0.0006,"Li2Te":-0.0003,"LiTe3":0.0},"model":"LiTe-22Yu.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-L34BY4YTIL","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p16/tab-6","row":5},"model":"M0471545d","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-022-00950-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.609},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"printed","phase":"LiTe3"},{"basis":"mole_fraction","composition":{"TE":0.333},"composition_source":"printed","phase":"Li2Te"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"LiTe3","mapping_confidence":"confirmed","model_phase":"LITE3","pearson_symbol":"hP48","prototype":"LiTe3","structure_basis":"mapped_model_phase"},{"label":"Li2Te","mapping_confidence":"confirmed","model_phase":"LI2TE_C1"}],"pid":"doi:10.1007/s11669-022-00950-z/p16/tab-6/r-unplaced-db083483#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> LiTe3 + Li2Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"LI-TE","system":"LI-TE","temperature_K":722.7,"temperature_printed":"722.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":722.7},{"chemical_system":"LI-TE","citations_printed":["[88]"],"cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"unknown","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (garbled_reaction_sign)","effect":"not_accepted","gate":"R3"}],"id":"ORC-IJ3PS7MU7I.27d736","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p4/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1149/1.2403448","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","pid":"doi:10.1007/s11669-022-00950-z/p4/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There are three eutectic reactions: L ? (Li) ? Li2Te, L ? (Te) ? LiTe3, and L ? LiTe3 ? Li2Te occurring at about 453.1, 696.3 and 721.7 K, respectively.","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"LI-TE","system":"LI-TE","temperature_K":696.3,"temperature_printed":"696.3 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":696.3},{"chemical_system":"LI-TE","citations_printed":["[88]"],"cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"unknown","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (garbled_reaction_sign)","effect":"not_accepted","gate":"R3"}],"id":"ORC-IJ3PS7MU7I.2a7976","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p4/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1149/1.2403448","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","pid":"doi:10.1007/s11669-022-00950-z/p4/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There are three eutectic reactions: L ? (Li) ? Li2Te, L ? (Te) ? LiTe3, and L ? LiTe3 ? Li2Te occurring at about 453.1, 696.3 and 721.7 K, respectively.","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"LI-TE","system":"LI-TE","temperature_K":453.1,"temperature_printed":"453.1 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":453.1},{"chemical_system":"LI-TE","citations_printed":["[88]"],"cited_sources":[{"doi":"10.1149/1.2403448","first_author":"Cunningham","kind":"unknown","label":"88","paper":"doi:10.1149/1.2403448","reference":"P. Cunningham, S. Johnson, and E. Cairns, Phase Equilibria in Lithium-Chalcogen Systems: III Lithium-Tellurium, J. Electrochem. Soc., 1973, 120, p 328.","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (garbled_reaction_sign)","effect":"not_accepted","gate":"R3"}],"id":"ORC-IJ3PS7MU7I.6a89d6","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p4/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1149/1.2403448","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","pid":"doi:10.1007/s11669-022-00950-z/p4/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There are three eutectic reactions: L ? (Li) ? Li2Te, L ? (Te) ? LiTe3, and L ? LiTe3 ? Li2Te occurring at about 453.1, 696.3 and 721.7 K, respectively.","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"LI-TE","system":"LI-TE","temperature_K":721.7,"temperature_printed":"721.7 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":721.7},{"chemical_system":"LI-TE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-022-00950-z"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7JCHU5EZQY","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p4/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-022-00950-z","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","pid":"doi:10.1007/s11669-022-00950-z/p4/text-07/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"In addition, there is a monotectic reactions: L2 ? L1 ? Li2Te occurring at 1085.2 K.","quote_page":4,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"LI-TE","system":"LI-TE","temperature_K":1085.2,"temperature_printed":"1085.2 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1085.2},{"chemical_system":"LI-TE","citations_printed":["[89]","[90]"],"cited_sources":[{"doi":"10.1107/s0567740877006141","first_author":"Valentine","kind":"unknown","label":"89","paper":"doi:10.1107/s0567740877006141","reference":"D.Y. Valentine, O.B. Cavin, and H.L. Yakel, On the Crystal Structure of LiTe3, Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem., 1977, 33, p 1389–1396.","status":"resolved","year":"1977"},{"doi":"10.1016/0022-1902(78)80301-7","first_author":"Hitch","kind":"unknown","label":"90","paper":"doi:10.1016/0022-1902(78)80301-7","reference":"B. Hitch, L. Toth, and J. Brynestad, The Decomposition Equilibrium of LiTe3, J. Inorg. Nucl. Chem., 1978, 40, p 31–34.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-BMAOOQ2VDB","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-00950-z/p4/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-00950-z","paper_id":"doi:10.1007/s11669-022-00950-z","pid":"doi:10.1007/s11669-022-00950-z/p4/text-07/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Valentine et al.[89] and Hitch et al.[90] reported LiTe3 decomposition at 577 K.","quote_page":4,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"LI-TE","system":"LI-TE","temperature_K":577.0,"temperature_printed":"577.0 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":577.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"LI-TE"}