{"artifacts":{"sha256:a3a35c694215c71c/p5/tab-3":{"artifact":"table","caption":"Average elemental chemical composition of the tungsten-rich phase and the oxides observed in first set of samples sintered at different temperatures.","label":"3","page":5},"sha256:a3a35c694215c71c/p7/tab-4":{"artifact":"table","caption":"Average elemental chemical composition of the phases observed in the second set of samples sintered at different conditions.","label":"4","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1016/j.ijrmhm.2018.01.006":{"context_id":"context:source-doi-10-1016-j-ijrmhm-2018-01-006","items":[{"extraction_accepted":false,"id":"ORC-O3EQGIYKCG","method":"X-ray diffraction (XRD)","page":2,"quote":"The microstructural constituents were then characterized qualitatively and quantitatively using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS).","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-O3EQGIYKCG","method":"scanning electron microscopy (SEM)","page":2,"quote":"The microstructural constituents were then characterized qualitatively and quantitatively using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS).","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-O3EQGIYKCG","method":"energy dispersive X-ray spectroscopy (EDS)","page":2,"quote":"The microstructural constituents were then characterized qualitatively and quantitatively using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS).","second_reader_agrees":false,"type":"measurement"},{"applies_to":"first set of tungsten-35 at.% manganese alloy sample sintered at 1425 °C for 30 min","extraction_accepted":false,"id":"ORC-S2EVYBTWG4","method":"X-ray diffraction","page":3,"quote":"Fig. 1. The X-ray diffraction pattern for the first set of tungsten-35 at.% manganese alloy sample sintered at 1425 °C for 30 min.","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-FVWWLKAVVE","label":"tungsten-35 at.% manganese (W-14 wt% Mn)","nominal_composition":"tungsten-35 at.% manganese (W-14 wt% Mn)","page":2,"quote":"In order to continue the research work reported in [12], two sets of tungsten-35 at.% manganese (W-14 wt% Mn) samples were prepared and sintered in different ways to reduce the oxidation of manganese.","second_reader_agrees":false,"type":"sample"},{"applies_to":"first set of tungsten-35 at.% manganese alloy sample","duration":"30 min","duration_parsed":{"hours":0.5,"printed":"30 min"},"extraction_accepted":true,"id":"ORC-YVL2FZTLSL","page":3,"purpose":"sintered","quote":"Fig. 1. The X-ray diffraction pattern for the first set of tungsten-35 at.% manganese alloy sample sintered at 1425 °C for 30 min.","second_reader_agrees":true,"temperature":{"T_K":1698.15,"converted_in_code":true,"printed":"1425 °C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":1425.0},"temperature_printed":"1425 °C","temperature_status":"parsed_from_printed","type":"treatment"}],"paper":"doi:10.1016/j.ijrmhm.2018.01.006","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"methods_heading"}},"elements":["MN","O","W"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.ijrmhm.2018.01.006":{"authors":["Ossama Elsebaie","Kevin M. Jaansalu"],"citation":"Ossama Elsebaie, Kevin M. Jaansalu, A study of the manganese–tungsten binary phase diagram, International Journal of Refractory Metals and Hard Materials 72, 332-340 (2018).","container":"International Journal of Refractory Metals and Hard Materials","doi":"10.1016/j.ijrmhm.2018.01.006","doi_url":"https://doi.org/10.1016/j.ijrmhm.2018.01.006","id":"doi:10.1016/j.ijrmhm.2018.01.006","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"a3a35c694215c71c","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"A study of the manganese–tungsten binary phase diagram","year":2018}},"part":1,"parts":1,"records":[{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-QJBSJ3KY6H","locator":{"ref":"sha256:a3a35c694215c71c/p5/tab-3","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.039},"composition_source":"printed","phase":"tungsten-rich phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.049},"composition_source":"printed","phase":"tungsten-rich phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.044},"composition_source":"printed","phase":"tungsten-rich phase (Average)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.27,"O":0.17,"W":0.56},"composition_source":"printed","phase":"oxide phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.32,"O":0.31,"W":0.37},"composition_source":"printed","phase":"oxide phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.039},"composition_source":"printed","phase":"tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.27,"O":0.17,"W":0.56},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"tungsten-rich phase"},{"label":"oxide phase"},{"label":"tungsten-rich phase (Surface)"},{"label":"tungsten-rich phase (Interior)"},{"label":"tungsten-rich phase (Average)"},{"label":"oxide phase (Surface)"},{"label":"oxide phase (Interior)"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p5/tab-3/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1498.15,"temperature_basis":"printed","temperature_printed":"1225","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-4BLOHQCIEW","locator":{"ref":"sha256:a3a35c694215c71c/p5/tab-3","row":2},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.076},"composition_source":"printed","phase":"tungsten-rich phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.053},"composition_source":"printed","phase":"tungsten-rich phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.064},"composition_source":"printed","phase":"tungsten-rich phase (Average)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.36,"O":0.14,"W":0.5},"composition_source":"printed","phase":"oxide phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.57,"O":0.41,"W":0.02},"composition_source":"printed","phase":"oxide phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.076},"composition_source":"printed","phase":"tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.36,"O":0.14,"W":0.5},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"tungsten-rich phase"},{"label":"oxide phase"},{"label":"tungsten-rich phase (Surface)"},{"label":"tungsten-rich phase (Interior)"},{"label":"tungsten-rich phase (Average)"},{"label":"oxide phase (Surface)"},{"label":"oxide phase (Interior)"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p5/tab-3/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1548.15,"temperature_basis":"printed","temperature_printed":"1275","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-SCIUVK4WSN","locator":{"ref":"sha256:a3a35c694215c71c/p5/tab-3","row":3},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.049},"composition_source":"printed","phase":"tungsten-rich phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.038},"composition_source":"printed","phase":"tungsten-rich phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.051},"composition_source":"printed","phase":"tungsten-rich phase (Average)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.43,"O":0.157,"W":0.413},"composition_source":"printed","phase":"oxide phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.64,"O":0.32,"W":0.04},"composition_source":"printed","phase":"oxide phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.049},"composition_source":"printed","phase":"tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.43,"O":0.157,"W":0.413},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"tungsten-rich phase"},{"label":"oxide phase"},{"label":"tungsten-rich phase (Surface)"},{"label":"tungsten-rich phase (Interior)"},{"label":"tungsten-rich phase (Average)"},{"label":"oxide phase (Surface)"},{"label":"oxide phase (Interior)"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p5/tab-3/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1623.15,"temperature_basis":"printed","temperature_printed":"1350","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-DMOFVOPHVU","locator":{"ref":"sha256:a3a35c694215c71c/p5/tab-3","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.037},"composition_source":"printed","phase":"tungsten-rich phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.049},"composition_source":"printed","phase":"tungsten-rich phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.037},"composition_source":"printed","phase":"tungsten-rich phase (Average)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.35,"O":0.14,"W":0.51},"composition_source":"printed","phase":"oxide phase (Surface)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.61,"O":0.37,"W":0.02},"composition_source":"printed","phase":"oxide phase (Interior)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.037},"composition_source":"printed","phase":"tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.35,"O":0.14,"W":0.51},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"tungsten-rich phase"},{"label":"oxide phase"},{"label":"tungsten-rich phase (Surface)"},{"label":"tungsten-rich phase (Interior)"},{"label":"tungsten-rich phase (Average)"},{"label":"oxide phase (Surface)"},{"label":"oxide phase (Interior)"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p5/tab-3/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1698.15,"temperature_basis":"printed","temperature_printed":"1425","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-ISEJ6GWRLP","locator":{"ref":"sha256:a3a35c694215c71c/p7/tab-4","row":1},"method":"EDS","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.075,"O":0.0,"W":0.925},"composition_source":"printed","phase":"Tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.877,"O":0.0,"W":0.123},"composition_source":"printed","phase":"Manganese-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.44,"O":0.36,"W":0.2},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"Tungsten-rich phase"},{"label":"Manganese-rich phase"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p7/tab-4/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1498.15,"temperature_basis":"printed","temperature_printed":"1225","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-33LWBC3SP4","locator":{"ref":"sha256:a3a35c694215c71c/p7/tab-4","row":2},"method":"EDS","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.093,"O":0.001,"W":0.906},"composition_source":"printed","phase":"Tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.898,"O":0.0,"W":0.102},"composition_source":"printed","phase":"Manganese-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.72,"O":0.21,"W":0.07},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"Tungsten-rich phase"},{"label":"Manganese-rich phase"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p7/tab-4/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1548.15,"temperature_basis":"printed","temperature_printed":"1275","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-RAWYW6FAYN","locator":{"ref":"sha256:a3a35c694215c71c/p7/tab-4","row":3},"method":"EDS","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.115,"O":0.0,"W":0.885},"composition_source":"printed","phase":"Tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.958,"O":0.0,"W":0.042},"composition_source":"printed","phase":"Manganese-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.7,"O":0.29,"W":0.01},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"Tungsten-rich phase"},{"label":"Manganese-rich phase"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p7/tab-4/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1623.15,"temperature_basis":"printed","temperature_printed":"1350","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-VEE7KLWGJG","locator":{"ref":"sha256:a3a35c694215c71c/p7/tab-4","row":4},"method":"EDS","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.081,"O":0.0,"W":0.919},"composition_source":"printed","phase":"Tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.937},"composition_source":"printed","phase":"Manganese-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.77,"O":0.2,"W":0.03},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"Tungsten-rich phase"},{"label":"Manganese-rich phase"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p7/tab-4/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1698.15,"temperature_basis":"printed","temperature_printed":"1425","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-QQWPEABH2X","locator":{"ref":"sha256:a3a35c694215c71c/p7/tab-4","row":6},"method":"EDS","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.116,"O":0.0,"W":0.884},"composition_source":"printed","phase":"Tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.969},"composition_source":"printed","phase":"Manganese-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.46,"O":0.48,"W":0.06},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"Tungsten-rich phase"},{"label":"Manganese-rich phase"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p7/tab-4/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1548.15,"temperature_basis":"printed","temperature_printed":"1275","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-Z2ZTOFYEEZ","locator":{"ref":"sha256:a3a35c694215c71c/p7/tab-4","row":7},"method":"EDS","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.12,"O":0.0,"W":0.88},"composition_source":"printed","phase":"Tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.977,"O":0.002,"W":0.021},"composition_source":"printed","phase":"Manganese-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.67,"O":0.32,"W":0.01},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"Tungsten-rich phase"},{"label":"Manganese-rich phase"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p7/tab-4/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1623.15,"temperature_basis":"printed","temperature_printed":"1350","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"MN-O-W","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.ijrmhm.2018.01.006"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":2,"id":"ORC-JJKUKY6OVO","locator":{"ref":"sha256:a3a35c694215c71c/p7/tab-4","row":8},"method":"EDS","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.ijrmhm.2018.01.006","own_work_of_paper":true},"paper":"doi:10.1016/j.ijrmhm.2018.01.006","paper_id":"doi:10.1016/j.ijrmhm.2018.01.006","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.091,"O":0.0,"W":0.909},"composition_source":"printed","phase":"Tungsten-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.979,"O":0.0,"W":0.021},"composition_source":"printed","phase":"Manganese-rich phase"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":0.54,"O":0.43,"W":0.03},"composition_source":"printed","phase":"Oxide phase"}],"phases":[{"label":"Tungsten-rich phase"},{"label":"Manganese-rich phase"},{"label":"Oxide phase"}],"pid":"sha256:a3a35c694215c71c/p7/tab-4/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MN-O-W","system":"MN-O-W","temperature_K":1698.15,"temperature_basis":"printed","temperature_printed":"1425","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"MN-O-W"}