{"artifacts":{"doi:10.1002/mgea.39/p5/text-89":{"artifact":"text_passage","label":"page 5, passage 89","page":5},"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3":{"artifact":"table","caption":"Calculated invariant reactions with the experimental data in the Mn–Sm system.","label":"3","page":3},"doi:10.1016/s0925-8388(00)01364-5/p2/text-03":{"artifact":"text_passage","label":"page 2, passage 3","page":2},"sha256:8d259316449324fb/p3/tab-2":{"artifact":"table","caption":"Enthalpy of formation of binary compounds Mn–RE in kJ mol 21 of atoms at 298 K","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["MN","SM"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M0f467ca1":{"catalog_entry":{"license":"CC BY 4.0","name":"MnSm-09Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"F.S. Pan, J. Alloys Compd., 481, 291-95(2009).","model_doi":"10.1016/j.jallcom.2009.03.121","reproduced_by_calculation":false,"tdb":"MnSm-09Wan.tdb","tdb_path":"databases/sgte-binary/MnSm-09Wan.tdb","tdb_sha256":"47864add5c99ef020901a6c284fb7083acb7bb772985a1669b9611328fb38296"},"M9ab83b60":{"catalog_entry":{"license":"CC BY 4.0","name":"MnSm-09Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"F.S. Pan, J. Alloys Compd., 481, 291-95(2009).","model_doi":"10.1016/j.jallcom.2009.03.121","reproduced_by_calculation":true,"tdb":"MnSm-09Wan.tdb","tdb_path":"databases/sgte-binary/MnSm-09Wan.tdb","tdb_sha256":"47864add5c99ef020901a6c284fb7083acb7bb772985a1669b9611328fb38296"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/mgea.39":{"authors":["Hongjian Ye","Jiang Wang","Qing Chen","Guanghui Rao","Huaiying Zhou"],"citation":"Hongjian Ye, Jiang Wang, Qing Chen, Guanghui Rao, Huaiying Zhou, Development of thermodynamic database of the Mn‐RE (RE = rare earth metals) binary systems, Materials Genome Engineering Advances 2 (2024).","container":"Materials Genome Engineering Advances","doi":"10.1002/mgea.39","doi_url":"https://doi.org/10.1002/mgea.39","id":"doi:10.1002/mgea.39","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"88f839cf8a903a5b","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Development of thermodynamic database of the Mn‐RE (RE = rare earth metals) binary systems","year":2024},"doi:10.1016/j.jallcom.2009.03.121":{"authors":["C.P. Wang","H.L. Zhang","S.L. Wang","Z. Lin","X.J. Liu","A.T. Tang","F.S. Pan"],"citation":"C.P. Wang, H.L. Zhang, S.L. Wang, Z. Lin, X.J. Liu, A.T. Tang et al., Thermodynamic assessments of the Mn–Sm and Mn–Ho systems, Journal of Alloys and Compounds 481, 291-295 (2009).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2009.03.121","doi_url":"https://doi.org/10.1016/j.jallcom.2009.03.121","id":"doi:10.1016/j.jallcom.2009.03.121","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"8eb912cf5b0c6579","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessments of the Mn–Sm and Mn–Ho systems","year":2009},"doi:10.1016/s0925-8388(00)01364-5":{"authors":["J. Gröbner","A. Pisch","R. Schmid-Fetzer"],"citation":"J. Gröbner, A. Pisch, R. Schmid-Fetzer, Thermodynamic optimization of the systems Mn–Gd and Mn–Y using new experimental results, Journal of Alloys and Compounds 317-318, 433-437 (2001).","container":"Journal of Alloys and Compounds","doi":"10.1016/s0925-8388(00)01364-5","doi_url":"https://doi.org/10.1016/s0925-8388(00)01364-5","id":"doi:10.1016/s0925-8388(00)01364-5","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"Thermodynamic optimization of the systems Mn–Gd and Mn–Y using new experimental results","year":2001},"doi:10.1515/ijmr-1970-610106":{"citation":"H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 61 (1970) 22–23.","doi":"10.1515/ijmr-1970-610106","doi_url":"https://doi.org/10.1515/ijmr-1970-610106","id":"doi:10.1515/ijmr-1970-610106","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"ref:ad4e041dffff58e8":{"citation":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","id":"ref:ad4e041dffff58e8","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1990}},"part":1,"parts":1,"records":[{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Shilov","kind":"unknown","label":"9","reference":"A.L. Shilov, L.N. Padruets, M.E. Kost, Zh. Fiz. Khim 57 (1983) 555–560, Translated from Russ. J. Phys. Chem. 57 (1983) 338. ¨ C. Colinet, in:","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"MN":0.793103,"SM":0.206897,"Y":0.0},"before":{"MN":0.0,"SM":1.0,"Y":0.0},"evidence":{"basis":"generic_label_with_row_element","label":"Mn23RE6","max_deviation":0.7931},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"MN-SM","before":"GD-MN-SM-Y","evidence":{"basis":"generic_label_with_row_element","overall_composition":{"MN":0.793103,"SM":0.206897,"Y":0.0},"phases":["Mn23RE6"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Mn23Sm6","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-PNIDQR52CL.2d37c6","locator":{"ref":"sha256:8d259316449324fb/p3/tab-2","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MN":0.793103,"SM":0.206897},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":0.0,"SM":1.0,"Y":0.0},"paper":"doi:10.1016/s0925-8388(00)01364-5","paper_id":"doi:10.1016/s0925-8388(00)01364-5","phases":[{"label":"Mn23RE6"}],"pid":"sha256:8d259316449324fb/p3/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"MN":{"phase":"printed:none"},"SM":{"phase":"printed:none"}},"reference_state_stored":{"GD":{"phase":"printed:none"},"MN":{"phase":"printed:none"},"SM":{"phase":"printed:none"},"Y":{"phase":"printed:none"}},"source_system":"GD-MN-SM-Y","system":"MN-SM","temperature_K":1320.0,"temperature_basis":"printed","temperature_printed":"1320 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.1585},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ mol^-1 of atoms","unit_stored":"J/mol-atom","value":-3.17,"value_printed":-3.17,"value_stored":-3170.0},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Shilov","kind":"unknown","label":"9","reference":"A.L. Shilov, L.N. Padruets, M.E. Kost, Zh. Fiz. Khim 57 (1983) 555–560, Translated from Russ. J. Phys. Chem. 57 (1983) 338. ¨ C. Colinet, in:","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"MN":0.793103,"SM":0.206897,"Y":0.0},"before":{"MN":0.0,"SM":1.0,"Y":0.0},"evidence":{"basis":"printed_formula","label":"Mn23Sm6","max_deviation":0.7931},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"MN-SM","before":"GD-MN-SM-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":0.793103,"SM":0.206897,"Y":0.0},"phases":["Mn23Sm6"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dft_outlier_unexplained":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Mn23RE6","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-PNIDQR52CL.cf24ce","locator":{"ref":"sha256:8d259316449324fb/p3/tab-2","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"MN":0.793103,"SM":0.206897},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":0.0,"SM":1.0,"Y":0.0},"paper":"doi:10.1016/s0925-8388(00)01364-5","paper_id":"doi:10.1016/s0925-8388(00)01364-5","phases":[{"label":"Mn23Sm6"}],"pid":"sha256:8d259316449324fb/p3/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"MN":{"phase":"printed:none"},"SM":{"phase":"printed:none"}},"reference_state_stored":{"GD":{"phase":"printed:none"},"MN":{"phase":"printed:none"},"SM":{"phase":"printed:none"},"Y":{"phase":"printed:none"}},"source_system":"GD-MN-SM-Y","system":"MN-SM","temperature_K":1320.0,"temperature_basis":"printed","temperature_printed":"1320 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.1585},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ mol-1 of atoms","unit_stored":"J/mol-atom","value":-3.17,"value_printed":-3.17,"value_stored":-3170.0},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.165,"dx":{"Mn23Sm6":-0.0001},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-GSIG6XLJDX","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"βMn"},{"basis":"mole_fraction","composition":{"SM":0.2069},"composition_source":"printed","phase":"Mn23Sm6"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"},{"label":"Mn23Sm6","mapping_confidence":"confirmed","model_phase":"MN23SM6_D8A","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-0cf45c81#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + βMn ↔ Mn23Sm6","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1298.15,"temperature_printed":"1025","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1298.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-3AKRTS34KR","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":2},"model":"M0f467ca1","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"βMn"},{"basis":"mole_fraction","composition":{"SM":0.2069},"composition_source":"printed","phase":"Mn23Sm6"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"},{"label":"Mn23Sm6","mapping_confidence":"confirmed","model_phase":"MN23SM6_D8A","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"mapped_model_phase"},{"label":"αMn","mapping_confidence":"confirmed","model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-4be85ec5#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βMn + Mn23Sm6 ↔ αMn","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":979.15,"temperature_printed":"706","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":979.15},{"chemical_system":"MN-SM","cited_sources":[{"doi":"10.1515/ijmr-1970-610106","first_author":"Kirchmayr","kind":"experimental","label":"9","paper":"doi:10.1515/ijmr-1970-610106","reference":"H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 61 (1970) 22–23.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.022,"dx":{},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-NAG2BBZGOJ","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":15},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1515/ijmr-1970-610106","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"γMn"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"βMn"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-79878bf0#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + γMn ↔ βMn","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1368.15,"temperature_printed":"1095","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1368.15},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-13.875,"dx":{"Mn2Sm":-0.0},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-ZD6HGAAXYZ","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.3333},"composition_source":"printed","phase":"Mn2Sm"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"βSm"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Mn2Sm","mapping_confidence":"confirmed","model_phase":"MN2SM_C14","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"βSm","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-7b7541d0#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Mn2Sm + βSm","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1068.15,"temperature_printed":"795","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1068.15},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":3.978,"dx":{},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-GZ7VJOEUGJ","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"γMn"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"βMn"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-b2eed752#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + γMn ↔ βMn","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1373.15,"temperature_printed":"1100","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1373.15},{"chemical_system":"MN-SM","cited_sources":[{"doi":"10.1515/ijmr-1970-610106","first_author":"Kirchmayr","kind":"experimental","label":"9","paper":"doi:10.1515/ijmr-1970-610106","reference":"H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 61 (1970) 22–23.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-4.848,"dx":{},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-RJS4ZRJ3QN","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1515/ijmr-1970-610106","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"γSm"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"βSm"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"γSm","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βSm","mapping_confidence":"proposed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-bb5c63ba#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + γSm ↔ βSm","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1190.15,"temperature_printed":"917","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1190.15},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-AO7C5QFU2R","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"βMn"},{"basis":"mole_fraction","composition":{"SM":0.2069},"composition_source":"printed","phase":"Mn23Sm6"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"},{"label":"Mn23Sm6","mapping_confidence":"confirmed","model_phase":"MN23SM6_D8A","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"mapped_model_phase"},{"label":"αMn","mapping_confidence":"confirmed","model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-c2e4ec64#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βMn + Mn23Sm6 ↔ αMn","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1000.15,"temperature_printed":"727","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1000.15},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":1.685,"dx":{"Mn23Sm6":-0.0001,"Mn2Sm":-0.0},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-PC4H33GTDW","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.2069},"composition_source":"printed","phase":"Mn23Sm6"},{"basis":"mole_fraction","composition":{"SM":0.3333},"composition_source":"printed","phase":"Mn2Sm"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Mn23Sm6","mapping_confidence":"confirmed","model_phase":"MN23SM6_D8A","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"mapped_model_phase"},{"label":"Mn2Sm","mapping_confidence":"confirmed","model_phase":"MN2SM_C14","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-cd45a965#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Mn23Sm6 ↔ Mn2Sm","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1203.15,"temperature_printed":"930","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203.15},{"chemical_system":"MN-SM","cited_sources":[{"doi":"10.1515/ijmr-1970-610106","first_author":"Kirchmayr","kind":"experimental","label":"9","paper":"doi:10.1515/ijmr-1970-610106","reference":"H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 61 (1970) 22–23.","status":"resolved","year":"1970"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-4.779,"dx":{},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-4JCKWHTSOJ","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1515/ijmr-1970-610106","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-d96a2bc3#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + δMn ↔ γMn","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1406.15,"temperature_printed":"1133","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1406.15},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-XRGTJSPHUZ","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":3},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.3333},"composition_source":"printed","phase":"Mn2Sm"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"αSm"}],"phases":[{"label":"βSm","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"Mn2Sm","mapping_confidence":"confirmed","model_phase":"MN2SM_C14","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"αSm","mapping_confidence":"confirmed","model_phase":"RHOMB_C19"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-de8911a5#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βSm ↔ Mn2Sm + αSm","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1007.15,"temperature_printed":"734","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1007.15},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.221,"dx":{},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-CHMBYKZLOE","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":17},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-faaa1b00#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + δMn ↔ γMn","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1411.15,"temperature_printed":"1138","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1411.15},{"chemical_system":"MN-SM","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., ASM International, 1990, pp. 2605–2606.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.152,"dx":{},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-TT75UJEC7X","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:ad4e041dffff58e8","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"γSm"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"βSm"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"γSm","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βSm","mapping_confidence":"proposed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r-unplaced-fc0435b7#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + γSm ↔ βSm","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1195.15,"temperature_printed":"922","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1195.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-6XKHCHMRQG","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":4},"model":"M0f467ca1","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.9999},"composition_source":"printed","phase":"βSm"},{"basis":"mole_fraction","composition":{"SM":0.3333},"composition_source":"printed","phase":"Mn2Sm"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"αSm"}],"phases":[{"label":"βSm","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"Mn2Sm","mapping_confidence":"confirmed","model_phase":"MN2SM_C14","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"αSm","mapping_confidence":"confirmed","model_phase":"RHOMB_C19"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βSm ↔ Mn2Sm + αSm","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1007.15,"temperature_printed":"734","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1007.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-13.875,"dx":{"L":0.0165,"Mn2Sm":-0.0},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-LQV44FWYKS","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":6},"model":"M0f467ca1","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.6948},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"SM":0.3333},"composition_source":"printed","phase":"Mn2Sm"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"βSm"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Mn2Sm","mapping_confidence":"confirmed","model_phase":"MN2SM_C14","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"},{"label":"βSm","mapping_confidence":"confirmed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r03#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ Mn2Sm + βSm","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1068.15,"temperature_printed":"795","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1068.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.152,"dx":{"L":0.0062},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-I62WTCPICZ","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":9},"model":"M9ab83b60","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.836},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"γSm"},{"basis":"mole_fraction","composition":{"SM":1.0},"composition_source":"printed","phase":"βSm"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"γSm","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βSm","mapping_confidence":"proposed","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r05#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + γSm ↔ βSm","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1195.15,"temperature_printed":"922","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1195.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.685,"dx":{"L":-0.0007,"Mn23Sm6":-0.0001,"Mn2Sm":-0.0},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-XOZSOFWCNK","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":11},"model":"M9ab83b60","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.5259},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"SM":0.2069},"composition_source":"printed","phase":"Mn23Sm6"},{"basis":"mole_fraction","composition":{"SM":0.3333},"composition_source":"printed","phase":"Mn2Sm"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Mn23Sm6","mapping_confidence":"confirmed","model_phase":"MN23SM6_D8A","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"mapped_model_phase"},{"label":"Mn2Sm","mapping_confidence":"confirmed","model_phase":"MN2SM_C14","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r09#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Mn23Sm6 ↔ Mn2Sm","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1202.15,"temperature_printed":"929","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1202.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.165,"dx":{"L":0.001,"Mn23Sm6":-0.0001},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-AHZQR6RO3I","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":13},"model":"M9ab83b60","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.3956},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"βMn"},{"basis":"mole_fraction","composition":{"SM":0.2069},"composition_source":"printed","phase":"Mn23Sm6"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"},{"label":"Mn23Sm6","mapping_confidence":"confirmed","model_phase":"MN23SM6_D8A","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r10#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + βMn ↔ Mn23Sm6","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1298.15,"temperature_printed":"1025","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1298.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":3.978,"dx":{"L":-0.009},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-U652VFRRMR","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":16},"model":"M9ab83b60","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.3003},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"γMn"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"βMn"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r12#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + γMn ↔ βMn","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1373.15,"temperature_printed":"1100","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1373.15},{"chemical_system":"MN-SM","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.221,"dx":{"L":-0.0001},"model":"MnSm-09Wan.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-6IRTZ3UB3L","locator":{"ref":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3","row":19},"model":"M9ab83b60","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2009.03.121","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2009.03.121","paper_id":"doi:10.1016/j.jallcom.2009.03.121","phase_compositions":[{"basis":"mole_fraction","composition":{"SM":0.2187},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"SM":0.0},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2009.03.121/p3/tab-3/r15#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + δMn ↔ γMn","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-SM","system":"MN-SM","temperature_K":1411.15,"temperature_printed":"1138","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1411.15},{"chemical_system":"MN-SM","citations_printed":["18","34","49","60"],"cited_sources":[{"first_author":"Kim","kind":"assessment","label":"18","reference":"Kim J, Jung IH. Critical systematic evaluation and thermodynamic optimization of the Mn-RE system: RE=La, Ce, Pr, Nd and Sm. J Alloys Compd. 2012;525:191-201.","status":"resolved","year":"2012"},{"first_author":"Kirchmayr","kind":"unknown","label":"34","reference":"Kirchmayr HR, Lugscheider W. Die Zustandsbilder neodymsamarium-und terbium-mangan. Z Metallkd. 1970;61(1):22-23.","status":"resolved","year":"1970"},{"first_author":"Wang","kind":"unknown","label":"49","reference":"Wang CP, Zhang HL, Wang SL, et al. Thermodynamic assessments of the Mn-Sm and Mn-Ho systems. J Alloys Compd. 2009;481(1-2): 291-295.","status":"resolved","year":"2009"},{"first_author":"Okamoto","kind":"unknown","label":"60","reference":"Okamoto H. Supplemental literature review of binary phase diagrams: Cs-In, Cs-K, Cs-Rb, Eu-In, Ho-MnK-Rb, Li-MgMg-Nd, Mg-Zn, MnSm, O-Sb, and Si-Sr. J Phase Equilibria Diffus. 2013;34(3):251-263.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:2)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7GASFHKW37.3cc148","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1002/mgea.39/p5/text-89"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1002/mgea.39","paper_id":"doi:10.1002/mgea.39","pid":"doi:10.1002/mgea.39/p5/text-89/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Two intermetallic compounds Mn23Sm6 and Mn2Sm were confirmed, which were formed by peritectic reactions (L þ cub-Mn ↔ Mn23Sm6 at 1298 K and L þ Mn23Sm6 ↔ Mn2Sm at 1203 K).","quote_page":5,"reaction":{"printed":"L þ cub-Mn ↔ Mn23Sm6","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-SM","system":"MN-SM","temperature_K":1298.0,"temperature_printed":"1298 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1298.0},{"chemical_system":"MN-SM","citations_printed":["18","34","49","60"],"cited_sources":[{"first_author":"Kim","kind":"assessment","label":"18","reference":"Kim J, Jung IH. Critical systematic evaluation and thermodynamic optimization of the Mn-RE system: RE=La, Ce, Pr, Nd and Sm. J Alloys Compd. 2012;525:191-201.","status":"resolved","year":"2012"},{"first_author":"Kirchmayr","kind":"unknown","label":"34","reference":"Kirchmayr HR, Lugscheider W. Die Zustandsbilder neodymsamarium-und terbium-mangan. Z Metallkd. 1970;61(1):22-23.","status":"resolved","year":"1970"},{"first_author":"Wang","kind":"unknown","label":"49","reference":"Wang CP, Zhang HL, Wang SL, et al. Thermodynamic assessments of the Mn-Sm and Mn-Ho systems. J Alloys Compd. 2009;481(1-2): 291-295.","status":"resolved","year":"2009"},{"first_author":"Okamoto","kind":"unknown","label":"60","reference":"Okamoto H. Supplemental literature review of binary phase diagrams: Cs-In, Cs-K, Cs-Rb, Eu-In, Ho-MnK-Rb, Li-MgMg-Nd, Mg-Zn, MnSm, O-Sb, and Si-Sr. J Phase Equilibria Diffus. 2013;34(3):251-263.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:2)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7GASFHKW37.3d449f","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1002/mgea.39/p5/text-89"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1002/mgea.39","paper_id":"doi:10.1002/mgea.39","pid":"doi:10.1002/mgea.39/p5/text-89/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Two intermetallic compounds Mn23Sm6 and Mn2Sm were confirmed, which were formed by peritectic reactions (L þ cub-Mn ↔ Mn23Sm6 at 1298 K and L þ Mn23Sm6 ↔ Mn2Sm at 1203 K).","quote_page":5,"reaction":{"printed":"L þ Mn23Sm6 ↔ Mn2Sm","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-SM","system":"MN-SM","temperature_K":1203.0,"temperature_printed":"1203 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203.0},{"chemical_system":"MN-SM","citations_printed":["62"],"cited_sources":[{"first_author":"Shilov","kind":"unknown","label":"62","reference":"Shilov AL, Padurets LN, Kost ME. Formation enthalpy determination for intermetallic compounds and their hydrides from differential thermal analysis data. Zhurnal Fizicheskoj Khimii. 1983;57:555-560.","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":["Mn23Sm6"],"before":[],"evidence":{"basis":"one_compound_in_quote","quote_page":5},"field":"phases","gate":"R3","rule":"state_phases_from_quote"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phases_recovered_from_quote"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":0,"gate_failures":[{"code":"phases_recovered_from_quote","detail":"phases read from the quote (one_compound_in_quote); not mapped to model phases","effect":"not_espei_ready","gate":"R3"}],"id":"ORC-IFDVP2YZP4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1002/mgea.39/p5/text-89"},"method":"high-temperature isoperibolic calorimetry","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1002/mgea.39","paper_id":"doi:10.1002/mgea.39","phases":[{"label":"Mn23Sm6","label_source":"quote"}],"pid":"doi:10.1002/mgea.39/p5/text-89/s05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"enthalpy of formation","quote":"Using high-temperature isoperibolic calorimetry, Shilov et al.[62] determined the enthalpy of formation of Mn23Sm6 at 1320 K to be -92 � 5 kJ/mol.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","reference_state":{},"reference_state_stored":{"printed":"pure solid elements"},"source_system":"MN-SM","system":"MN-SM","temperature_K":1320.0,"temperature_printed":"1320 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"printed","value":5.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"reason":"unit 'unspecified' not convertible to kJ/mol-atom","value":null},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"unspecified","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"unspecified","value":-92.0},{"chemical_system":"MN-SM","citations_printed":["9"],"cited_sources":[{"first_author":"Shilov","kind":"unknown","label":"9","reference":"A.L. Shilov, L.N. Padruets, M.E. Kost, Zh. Fiz. Khim 57 (1983) 555–560, Translated from Russ. J. Phys. Chem. 57 (1983) 338. ¨ C. Colinet, in:","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-3.17,"before":23.17,"evidence":{"printed":"−3.17 kJ mol−1 of atoms"},"field":"value","gate":"G3","rule":"sign_read_from_page","visual_check":{"checked":"2026-10-23","image_sha256":"786cde6baef7a42513ef211679739b4df3205e4c5e5e23b919f406ae0bfd7507","page":2,"pdf_sha256_prefix":"8d259316449324fb","seen":"Sec. 2 text: 'The only value reported is for Mn23Sm6 (-3.17 kJ mol^-1 of atoms at 1320 K) [9]'. Printed negative; stored 23.17 is OCR of '-3.17' (minus read as '2'; 'mol 21' = mol^-1).","verdict":"corrected"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"review_state":"proposed","second_reader":"done","sign_pdf_page_verified":true,"value_in_quote":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-CXQJEPWHY3","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0925-8388(00)01364-5/p2/text-03"},"observation_type":"equilibrium_property","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/s0925-8388(00)01364-5","paper_id":"doi:10.1016/s0925-8388(00)01364-5","phases":[{"label":"Mn 23 Sm 6"}],"pid":"doi:10.1016/s0925-8388(00)01364-5/p2/text-03/s17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"enthalpy of formation","quote":"Experimental data of enthalpies of formation are very scarce in literature. The only value reported is for Mn 23 Sm 6 (23.17 kJ mol 21 of atoms at 1320 K) [9] (see Table 2).","quote_page":2,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-SM","system":"MN-SM","temperature_K":1320.0,"temperature_printed":"1320 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":2.317},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ mol 21 of atoms","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ mol 21 of atoms","value":-3.17,"value_stored":23.17}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"MN-SM"}