{"artifacts":{"doi:10.1002/mgea.39/p20/text-63":{"artifact":"text_passage","label":"page 20, passage 63","page":20}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["MN","TM"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/mgea.39":{"authors":["Hongjian Ye","Jiang Wang","Qing Chen","Guanghui Rao","Huaiying Zhou"],"citation":"Hongjian Ye, Jiang Wang, Qing Chen, Guanghui Rao, Huaiying Zhou, Development of thermodynamic database of the Mn‐RE (RE = rare earth metals) binary systems, Materials Genome Engineering Advances 2 (2024).","container":"Materials Genome Engineering Advances","doi":"10.1002/mgea.39","doi_url":"https://doi.org/10.1002/mgea.39","id":"doi:10.1002/mgea.39","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"88f839cf8a903a5b","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Development of thermodynamic database of the Mn‐RE (RE = rare earth metals) binary systems","year":2024}},"part":1,"parts":1,"records":[{"chemical_system":"MN-TM","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298 K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:3)","effect":"not_accepted","gate":"R3"}],"id":"ORC-BVTYYRYXTY","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1002/mgea.39/p20/text-63"},"observation_type":"equilibrium_property","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1002/mgea.39","own_work_of_paper":true},"paper":"doi:10.1002/mgea.39","paper_id":"doi:10.1002/mgea.39","pid":"doi:10.1002/mgea.39/p20/text-63/s02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"enthalpy of formation","quote":"Figure 23 depicts the calculated enthalpy of formation of the Mn-Tm intermetallic compounds at 298 K in comparison with Kim et al.'s assessment[19] and the DFT results.[93,94] The calculated enthalpies of formation of Mn12Tm, Mn23Tm6, and Mn2Tm are -1.384, -3.310, and -3.10 kJ/ mol-atom, respectively, which are less negative than those from Kim et al.,[19] but closer to the average values of the DFT data.[93,94]","quote_page":20,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-TM","system":"MN-TM","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_printed":"298 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":0.1384},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_stored":"kJ/ mol-atom","value":-1.384,"value_stored":-1.384}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"MN-TM"}