{"artifacts":{"doi:10.1002/mgea.39/p22/text-04":{"artifact":"text_passage","label":"page 22, passage 4","page":22}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["MN","Y"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/mgea.39":{"authors":["Hongjian Ye","Jiang Wang","Qing Chen","Guanghui Rao","Huaiying Zhou"],"citation":"Hongjian Ye, Jiang Wang, Qing Chen, Guanghui Rao, Huaiying Zhou, Development of thermodynamic database of the Mn‐RE (RE = rare earth metals) binary systems, Materials Genome Engineering Advances 2 (2024).","container":"Materials Genome Engineering Advances","doi":"10.1002/mgea.39","doi_url":"https://doi.org/10.1002/mgea.39","id":"doi:10.1002/mgea.39","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"88f839cf8a903a5b","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Development of thermodynamic database of the Mn‐RE (RE = rare earth metals) binary systems","year":2024}},"part":1,"parts":1,"records":[{"chemical_system":"MN-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:3)","effect":"not_accepted","gate":"R3"}],"id":"ORC-QSFZEOSOG5.3ba00d","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1002/mgea.39/p22/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1002/mgea.39","own_work_of_paper":true},"paper":"doi:10.1002/mgea.39","paper_id":"doi:10.1002/mgea.39","pid":"doi:10.1002/mgea.39/p22/text-04/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated compositions and temperatures of the three eutectic reactions (L ↔ Mn12Y þ Mn23Y6, L ↔ Mn2Y þ Mn23Y6, and L ↔ Mn2Y þ hcp-Y) are 11.9 at.% Y and 1353.4 K, 29.1 at.% Y and 1370.1 K, and 60.6 at.% Y and 1151.7 K, respectively.","quote_page":22,"reaction":{"printed":"L ↔ Mn2Y þ hcp-Y","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-Y","system":"MN-Y","temperature_K":1151.7,"temperature_printed":"1151.7 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1151.7},{"chemical_system":"MN-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:3)","effect":"not_accepted","gate":"R3"}],"id":"ORC-QSFZEOSOG5.4bb1e2","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1002/mgea.39/p22/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1002/mgea.39","own_work_of_paper":true},"paper":"doi:10.1002/mgea.39","paper_id":"doi:10.1002/mgea.39","pid":"doi:10.1002/mgea.39/p22/text-04/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated compositions and temperatures of the three eutectic reactions (L ↔ Mn12Y þ Mn23Y6, L ↔ Mn2Y þ Mn23Y6, and L ↔ Mn2Y þ hcp-Y) are 11.9 at.% Y and 1353.4 K, 29.1 at.% Y and 1370.1 K, and 60.6 at.% Y and 1151.7 K, respectively.","quote_page":22,"reaction":{"printed":"L ↔ Mn12Y þ Mn23Y6","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-Y","system":"MN-Y","temperature_K":1353.4,"temperature_printed":"1353.4 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1353.4},{"chemical_system":"MN-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:3)","effect":"not_accepted","gate":"R3"}],"id":"ORC-QSFZEOSOG5.63e359","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1002/mgea.39/p22/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1002/mgea.39","own_work_of_paper":true},"paper":"doi:10.1002/mgea.39","paper_id":"doi:10.1002/mgea.39","pid":"doi:10.1002/mgea.39/p22/text-04/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated compositions and temperatures of the three eutectic reactions (L ↔ Mn12Y þ Mn23Y6, L ↔ Mn2Y þ Mn23Y6, and L ↔ Mn2Y þ hcp-Y) are 11.9 at.% Y and 1353.4 K, 29.1 at.% Y and 1370.1 K, and 60.6 at.% Y and 1151.7 K, respectively.","quote_page":22,"reaction":{"printed":"L ↔ Mn2Y þ Mn23Y6","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-Y","system":"MN-Y","temperature_K":1370.1,"temperature_printed":"1370.1 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 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