{"artifacts":{"doi:10.1007/bf02646113/p3/tab-i":{"artifact":"table","caption":"Calculated Univariant Points in the AI-Mn System","label":"I","page":3},"doi:10.1007/bf02898263/p3/tab-i":{"artifact":"table","caption":"Special Points of the Assessed Ag-Mn Phase Diagram","label":"I","page":3},"doi:10.1007/bf02898263/p5/tab-3":{"artifact":"table","caption":"Ag-Mn Lattice Parameter Data at 21 ~","label":"3","page":5},"doi:10.1007/s11669-003-0004-6/p1/text-06":{"artifact":"text_passage","label":"page 1, passage 6","page":1},"doi:10.1007/s11669-010-9740-6/p2/tab-1":{"artifact":"table","caption":"List of symbols and crystallographic data of the phases in the Mn-B system","label":"1","page":2},"doi:10.1007/s11669-011-9976-9/p8/tab-5":{"artifact":"table","caption":"Summary of the invariant equilibria in the Hf2Mn system","label":"5","page":8},"doi:10.1016/0364-5916(89)90003-5/p2/text-05":{"artifact":"text_passage","label":"page 2, passage 5","page":2},"doi:10.1016/j.calphad.2012.03.004/p8/tab-4":{"artifact":"table","caption":"Calculated total energy and structural parameters for the end-members of C14 and m with NM, FM and AFM magnetic ordering based on DFT [16]. The values in boldface show the most stable magnetic configurations. Total energies are in","label":"4","page":8},"doi:10.1016/j.calphad.2012.03.004/p9/tab-5":{"artifact":"table","caption":"Calculated total energy, structural parameters of Fe, Mn, and Nb, comparing with the literature data. Total energies E total are in kJ/mol-atoms, lattice parameters a","label":"5","page":9},"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5":{"artifact":"table","caption":"Comparison of invariant reactions in the Mn–Pr system between calculated and experimental data","label":"5","page":5},"doi:10.1016/j.jallcom.2023.173060/p3/tab-1":{"artifact":"table","caption":"Crystallographic data of solid phases in the Hf-Mn system.","label":"1","page":3},"doi:10.1361/105497199770335938/p8/tab-3":{"artifact":"table","caption":"Comparison between the experimental and calculated invariant reactions in the Al-Mn phase diagram","label":"3","page":8},"doi:10.1361/105497199770335938/p9/tab-3":{"artifact":"table","caption":"Comparison between the experimental and calculated invariant reactions in the Al-Mn phase diagram (continued)","label":"3","page":9},"doi:10.2298/jmmb120717049w/p4/tab-2":{"artifact":"table","caption":"Calculated invariant reactions compared with the literature data in the La–Mn systems","label":"2","page":4},"sha256:30fb4308ad772cc9/p6/tab-4":{"artifact":"table","caption":"Enthalpies of formation of the stoichiometric C14 Laves phase from ab initio calcu­ lations and CALPHAD assessments. Data without references are obtained from the present work.","label":"4","page":6},"sha256:9ce403d6580e9b80/p3/tab-2":{"artifact":"table","caption":"Crystal structure for the solid phases in the Cd–X (X ¼Sn, Mn, Fe) systems.","label":"2","page":3},"sha256:b1df2c382b053970/p2/tab-1":{"artifact":"table","caption":"Crystallographic data of the phases in the LieSieMn ternary system.","label":"1","page":2}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["MN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M075fa117":{"catalog_entry":{"license":"CC BY 4.0","name":"LaMn-12Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Y. Wang, B. Hu, S. Liu, Y. Du, J. Mining Metall. B, 48, 391-94(2012).","model_doi":"10.2298/jmmb120717049w","reproduced_by_calculation":false,"tdb":"LaMn-12Wan.tdb","tdb_path":"databases/sgte-binary/LaMn-12Wan.tdb","tdb_sha256":"7161f70fb98ae05289a08fd2e9e5ba4e68ddde81d4fd3109c16b61e23e28e918"},"M24c39354":{"catalog_entry":{"license":"CC BY 4.0","name":"MnPr-09Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"C.P. Wang, Z. Lin, X.J. Liu, J. Alloys Compd., 469, 123-28(2009).","model_doi":"10.1016/j.jallcom.2008.01.092","reproduced_by_calculation":false,"tdb":"MnPr-09Wan.tdb","tdb_path":"databases/sgte-binary/MnPr-09Wan.tdb","tdb_sha256":"afe8988cd246247a7c2272e521cf151b636463bc6e2185e9edc58a4386b4c784"},"M62b6cccc":{"catalog_entry":{"license":"CC BY 4.0","name":"HfMn-12Zho.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib. Diffus., 33, 20-28(2012).","model_doi":"10.1007/s11669-011-9976-9","reproduced_by_calculation":true,"tdb":"HfMn-12Zho.tdb","tdb_path":"databases/sgte-binary/HfMn-12Zho.tdb","tdb_sha256":"13bc2c3266d585e0795f1cb07275ad60b1fa8c1bd349e103547672c826b36065"},"M87369021":{"catalog_entry":{"license":"CC BY 4.0","name":"AlMn-99Liu-LB.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib., 20, 45-56(1999).","model_doi":"10.1361/105497199770335938","reproduced_by_calculation":false,"tdb":"AlMn-99Liu-LB.tdb","tdb_path":"databases/sgte-binary/AlMn-99Liu-LB.tdb","tdb_sha256":"0984f6432fe9feec050bbf07d239613b47ecc06d9c3f6c184f7f7b2dde34c077"},"Mabe01570":{"catalog_entry":{"license":"CC BY 4.0","name":"AgMn-90Kar.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"I. Karakaya, W.T. Thompson, Bull. Alloy Phase Diag., 11, 480-86(1990).","model_doi":"10.1007/bf02898263","reproduced_by_calculation":false,"tdb":"AgMn-90Kar.tdb","tdb_path":"databases/sgte-binary/AgMn-90Kar.tdb","tdb_sha256":"0d7140384c10ff2293fb524cc17b5a5f54529203283c9e9c9729f038a64396ae"},"Mcf2b79f9":{"catalog_entry":{"license":"CC BY 4.0","name":"AlMn-92Jan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_doi":"10.1007/bf02646113","reproduced_by_calculation":false,"tdb":"AlMn-92Jan.tdb","tdb_path":"databases/sgte-binary/AlMn-92Jan.tdb","tdb_sha256":"2ba454e592e714093688a2689bbaf18a3fd93e81742cf1616194509f6fec95b0"},"Mf65a53ff":{"catalog_entry":{"license":"CC BY 4.0","name":"AlMn-92Jan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"cited_model_is_corpus_tdb","model_doi":"10.1007/bf02646113","reproduced_by_calculation":false,"tdb":"AlMn-92Jan.tdb","tdb_path":"databases/sgte-binary/AlMn-92Jan.tdb","tdb_sha256":"2ba454e592e714093688a2689bbaf18a3fd93e81742cf1616194509f6fec95b0"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02645298":{"authors":["H. Okamoto"],"citation":"H. Okamoto, The Hf-Mn (hafnium-manganese) system, JPE 16, 361-363 (1995).","container":"JPE","doi":"10.1007/bf02645298","doi_url":"https://doi.org/10.1007/bf02645298","id":"doi:10.1007/bf02645298","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Hf-Mn (hafnium-manganese) system","year":1995},"doi:10.1007/bf02646113":{"authors":["Åke Jansson"],"citation":"Åke Jansson, A thermodynamic evaluation of the Al-Mn system, Metall Trans A 23, 2953-2962 (1992).","container":"Metall Trans A","doi":"10.1007/bf02646113","doi_url":"https://doi.org/10.1007/bf02646113","id":"doi:10.1007/bf02646113","kind":"cited_work","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work"],"title":"A thermodynamic evaluation of the Al-Mn system","year":1992},"doi:10.1007/bf02869863":{"citation":"P.K. Liao and K.E. Spear, The B-Mn (Boron-Manganese) System, Bull. Alloy Phase Diag., 1986, 7(6), p 543-549, p 585-586","doi":"10.1007/bf02869863","doi_url":"https://doi.org/10.1007/bf02869863","id":"doi:10.1007/bf02869863","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1007/bf02877580":{"citation":"N.A. Gokcen, The phase transformation in Mn, Bull. Alloy Phase Diagr. 10 (1989) 313.","doi":"10.1007/bf02877580","doi_url":"https://doi.org/10.1007/bf02877580","id":"doi:10.1007/bf02877580","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1007/bf02898263":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag-Mn (Silver-Manganese) system, Bulletin of Alloy Phase Diagrams 11, 480-486 (1990).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02898263","doi_url":"https://doi.org/10.1007/bf02898263","id":"doi:10.1007/bf02898263","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"91702cad0a1b48c8","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag-Mn (Silver-Manganese) system","year":1990},"doi:10.1007/s11669-003-0004-6":{"authors":["A. Nicholas Grundy","Bengt Hallstedt","Ludwig J. Gauckler"],"citation":"A. Nicholas Grundy, Bengt Hallstedt, Ludwig J. Gauckler, Assessment of the Mn-O system, JPE 24, 21-39 (2003).","container":"JPE","doi":"10.1007/s11669-003-0004-6","doi_url":"https://doi.org/10.1007/s11669-003-0004-6","id":"doi:10.1007/s11669-003-0004-6","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"52c6a05ef09c63a7","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Assessment of the Mn-O system","year":2003},"doi:10.1007/s11669-010-9740-6":{"authors":["Weihua Sun","Yong Du","Shuhong Liu","Baiyun Huang","Chao Jiang"],"citation":"Weihua Sun, Yong Du, Shuhong Liu, Baiyun Huang, Chao Jiang, Thermodynamic Assessment of the Mn-B System, J. Phase Equilib. Diffus. 31, 357-364 (2010).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-010-9740-6","doi_url":"https://doi.org/10.1007/s11669-010-9740-6","id":"doi:10.1007/s11669-010-9740-6","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"2ad95102ef127e95","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessment of the Mn-B System","year":2010},"doi:10.1007/s11669-011-9976-9":{"authors":["Peng Zhou","Shuhong Liu","Peisheng Wang","Honghui Xu","Yingbiao Peng","Xiaoming Yuan","Yong Du","Jun Zhang","Weidong Huang"],"citation":"Peng Zhou, Shuhong Liu, Peisheng Wang, Honghui Xu, Yingbiao Peng, Xiaoming Yuan et al., Experimental Investigation and Thermodynamic Assessment of the Hf-Mn System, J. Phase Equilib. Diffus. 33, 20-28 (2012).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-011-9976-9","doi_url":"https://doi.org/10.1007/s11669-011-9976-9","id":"doi:10.1007/s11669-011-9976-9","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"75550c6c9f76e78e","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental Investigation and Thermodynamic Assessment of the Hf-Mn System","year":2012},"doi:10.1016/0364-5916(89)90003-5":{"authors":["Weiming Huang"],"citation":"Weiming Huang, An Assessment of the Co-Mn System, Calphad 13, 231-242 (1989).","container":"Calphad","doi":"10.1016/0364-5916(89)90003-5","doi_url":"https://doi.org/10.1016/0364-5916(89)90003-5","id":"doi:10.1016/0364-5916(89)90003-5","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"6aa82221e836f29b","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"An Assessment of the Co-Mn System","year":1989},"doi:10.1016/0364-5916(91)90030-n":{"authors":["A.T. Dinsdale"],"citation":"A.T. Dinsdale, SGTE data for pure elements, Calphad 15, 317-425 (1991).","container":"Calphad","doi":"10.1016/0364-5916(91)90030-n","doi_url":"https://doi.org/10.1016/0364-5916(91)90030-n","id":"doi:10.1016/0364-5916(91)90030-n","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"SGTE data for pure elements","year":1991},"doi:10.1016/j.calphad.2004.05.002":{"authors":["Yi Wang"],"citation":"Yi Wang, Ab initio lattice stability in comparison with CALPHAD lattice stability, Calphad (2004).","container":"Calphad","doi":"10.1016/j.calphad.2004.05.002","doi_url":"https://doi.org/10.1016/j.calphad.2004.05.002","id":"doi:10.1016/j.calphad.2004.05.002","kind":"cited_work","metadata_source":"openalex/crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Ab initio lattice stability in comparison with CALPHAD lattice stability","year":2004},"doi:10.1016/j.calphad.2012.03.004":{"authors":["Shuhong Liu","Bengt Hallstedt","Denis Music","Yong Du"],"citation":"Shuhong Liu, Bengt Hallstedt, Denis Music, Yong Du, Ab initio calculations and thermodynamic modeling for the Fe–Mn–Nb system, Calphad 38, 43-58 (2012).","container":"Calphad","doi":"10.1016/j.calphad.2012.03.004","doi_url":"https://doi.org/10.1016/j.calphad.2012.03.004","id":"doi:10.1016/j.calphad.2012.03.004","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"Ab initio calculations and thermodynamic modeling for the Fe–Mn–Nb system","year":2012},"doi:10.1016/j.calphad.2014.06.006":{"authors":["Aning Qin","Rong Wang","Yaru Wang","Jiong Wang","Shuhong Liu","Kaiming Cheng","Yong Du","Bosse Sundman"],"citation":"Aning Qin, Rong Wang, Yaru Wang, Jiong Wang, Shuhong Liu, Kaiming Cheng et al., Thermodynamic assessment of the Cd–X (X=Sn, Mn, Fe) systems, Calphad 47, 83-91 (2014).","container":"Calphad","doi":"10.1016/j.calphad.2014.06.006","doi_url":"https://doi.org/10.1016/j.calphad.2014.06.006","id":"doi:10.1016/j.calphad.2014.06.006","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"9ce403d6580e9b80","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Cd–X (X=Sn, Mn, Fe) systems","year":2014},"doi:10.1016/j.jallcom.2008.01.092":{"authors":["C.P. Wang","Z. Lin","X.J. Liu"],"citation":"C.P. Wang, Z. Lin, X.J. Liu, Thermodynamic assessments of the Dy–Mn and Mn–Pr systems, Journal of Alloys and Compounds 469, 123-128 (2009).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2008.01.092","doi_url":"https://doi.org/10.1016/j.jallcom.2008.01.092","id":"doi:10.1016/j.jallcom.2008.01.092","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"b8a46815fbcb5b76","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessments of the Dy–Mn and Mn–Pr systems","year":2009},"doi:10.1016/j.jallcom.2014.06.202":{"authors":["A. Berche","E. Ruiz-Théron","J.-C. Tedenac","R.-M. Ayral","F. Rouessac","P. Jund"],"citation":"A. Berche, E. Ruiz-Théron, J.-C. Tedenac, R.-M. Ayral, F. Rouessac, P. Jund, Thermodynamic description of the Mn–Si system: An experimental and theoretical work, Journal of Alloys and Compounds 615, 693-702 (2014).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2014.06.202","doi_url":"https://doi.org/10.1016/j.jallcom.2014.06.202","id":"doi:10.1016/j.jallcom.2014.06.202","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"7a69fbc71e383186","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic description of the Mn–Si system: An experimental and theoretical work","year":2014},"doi:10.1016/j.jallcom.2018.07.211":{"authors":["Zhaohui Long","Xiaorong Dai","Zhi Li","Fucheng Yin","Zhanpeng Jin"],"citation":"Zhaohui Long, Xiaorong Dai, Zhi Li, Fucheng Yin, Zhanpeng Jin, Experimental investigation and thermodynamic description of the Li–Si–Mn ternary system, Journal of Alloys and Compounds 768, 686-696 (2018).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2018.07.211","doi_url":"https://doi.org/10.1016/j.jallcom.2018.07.211","id":"doi:10.1016/j.jallcom.2018.07.211","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"b1df2c382b053970","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental investigation and thermodynamic description of the Li–Si–Mn ternary system","year":2018},"doi:10.1016/j.jallcom.2021.161957":{"authors":["Weisen Zheng","Wei Song","Tong Wu","Jingya Wang","Yanlin He","Xiao-Gang Lu"],"citation":"Weisen Zheng, Wei Song, Tong Wu, Jingya Wang, Yanlin He, Xiao-Gang Lu, Experimental investigation and thermodynamic modeling of the ternary Ti–Fe–Mn system for hydrogen storage applications, Journal of Alloys and Compounds 891, 161957 (2022).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2021.161957","doi_url":"https://doi.org/10.1016/j.jallcom.2021.161957","id":"doi:10.1016/j.jallcom.2021.161957","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"30fb4308ad772cc9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental investigation and thermodynamic modeling of the ternary Ti–Fe–Mn system for hydrogen storage applications","year":2022},"doi:10.1016/j.jallcom.2023.173060":{"authors":["Pavel Brož","Xinlin Yan","Vitaliy Romaka","Olga Fabrichnaya","Mario J. Kriegel","Vilma Buršíková","Jiří Buršík","Jan Vřešťál","Gerda Rogl","Herwig Michor","Ernst Bauer","Markus Eiberger","Andriy Grytsiv","Gerald Giester","Peter F. Rogl"],"citation":"Pavel Brož, Xinlin Yan, Vitaliy Romaka, Olga Fabrichnaya, Mario J. Kriegel, Vilma Buršíková et al., Constitution, physical properties and thermodynamic modeling of the Hf-Mn system, Journal of Alloys and Compounds 976, 173060 (2024).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2023.173060","doi_url":"https://doi.org/10.1016/j.jallcom.2023.173060","id":"doi:10.1016/j.jallcom.2023.173060","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"e4edef58f093c43f","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Constitution, physical properties and thermodynamic modeling of the Hf-Mn system","year":2024},"doi:10.1016/s0925-8388(98)00742-7":{"authors":["A.V Morozkin","Yu.D Seropegin","I.A Sviridov","V.A Moskalev","I.A Tskhadadze","I.G Ryabinkin"],"citation":"A.V Morozkin, Yu.D Seropegin, I.A Sviridov, V.A Moskalev, I.A Tskhadadze, I.G Ryabinkin, Phase equilibria in the {Sm,Tb,Tm}–Mn–Si systems at 870/1070 K, Journal of Alloys and Compounds 280, 178-187 (1998).","container":"Journal of Alloys and Compounds","doi":"10.1016/s0925-8388(98)00742-7","doi_url":"https://doi.org/10.1016/s0925-8388(98)00742-7","id":"doi:10.1016/s0925-8388(98)00742-7","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase equilibria in the {Sm,Tb,Tm}–Mn–Si systems at 870/1070 K","year":1998},"doi:10.1039/c6cp04542a":{"authors":["A. U. Khan","P. Brož","M. Premović","J. Pavlů","J. Vřeštál","X. Yan","D. Maccio","A. Saccone","G. Giester","P. Rogl"],"citation":"A. U. Khan, P. Brož, M. Premović, J. Pavlů, J. Vřeštál, X. Yan et al., The Ti–Mn system revisited: experimental investigation and thermodynamic modelling, Phys. Chem. Chem. Phys. 18, 23326-23339 (2016).","container":"Phys. Chem. Chem. Phys.","doi":"10.1039/c6cp04542a","doi_url":"https://doi.org/10.1039/c6cp04542a","id":"doi:10.1039/c6cp04542a","kind":"cited_work","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work"],"title":"The Ti–Mn system revisited: experimental investigation and thermodynamic modelling","year":2016},"doi:10.1361/105497199770335938":{"authors":["X. J. Liu","I. Ohnuma","R. Kainuma","K. Ishida"],"citation":"X. J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Aluminum-Manganese (Al-Mn) binary phase diagram, JPE 20, 45-56 (1999).","container":"JPE","doi":"10.1361/105497199770335938","doi_url":"https://doi.org/10.1361/105497199770335938","id":"doi:10.1361/105497199770335938","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"65219cf9bc7619d2","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Aluminum-Manganese (Al-Mn) binary phase diagram","year":1999},"doi:10.2298/jmmb120717049w":{"authors":["Y. Wang","B. Hu","S. Liu","Y. Du"],"citation":"Y. Wang, B. Hu, S. Liu, Y. Du, Thermodynamic reassessment of the La-Mn system, J min metall B Metall 48, 391-394 (2012).","container":"J min metall B Metall","doi":"10.2298/jmmb120717049w","doi_url":"https://doi.org/10.2298/jmmb120717049w","id":"doi:10.2298/jmmb120717049w","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"67f2de1b2cf57cc8","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic reassessment of the La-Mn system","year":2012},"ref:4051979bc5796ef7":{"citation":"A.J. McAlster and J.L. Murray, Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, P.R. Subramanian, H. Okamoto, and L. Kacprzak, Ed., ASM International, 1990, p 171-173","id":"ref:4051979bc5796ef7","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1990},"ref:6377c70343cad517":{"citation":"T.B. Massalski, P.R. Subramanian, H. Okamoto, L. Kacprzak, Binary Alloy Phase Diagrams, 2nd ed., ASM International, 1990.","id":"ref:6377c70343cad517","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1990}},"part":1,"parts":1,"records":[{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["αMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-BAKXP75JFB.73394a","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"αMn"}],"phases":[{"label":"αMn","model_phase":"CBCC_A12"}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETERS","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01963,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01963},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.9219,"value_stored":0.89219},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["αMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-BAKXP75JFB.fdaae6","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"αMn"}],"phases":[{"label":"αMn","model_phase":"CBCC_A12"}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01963,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01963},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.9219,"value_stored":0.89219},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"BCC_A2","evidence":{"label":"βMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored T=298.15 (assumed_room_temperature) contradicts footnote (a) 'Measurement temperature unknown' on βMn, γMn, δMn rows","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t081)","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"βMn 0.63152 (a); γMn 0.386624 (a); δMn 0.30806 (a) [King2]","verdict":"confirmed"}}],"id":"ORC-L4HFQQEL6M.1e0d74","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"βMn"}],"phases":[{"label":"βMn","model_phase_rejected":{"model_phase":"BCC_A2","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETERS","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01389,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01389},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.3152,"value_stored":0.63152},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"BCC_A2","evidence":{"label":"βMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored T=298.15 (assumed_room_temperature) contradicts footnote (a) 'Measurement temperature unknown' on βMn, γMn, δMn rows","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t081)","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"βMn 0.63152 (a); γMn 0.386624 (a); δMn 0.30806 (a) [King2]","verdict":"confirmed"}}],"id":"ORC-L4HFQQEL6M.b9c764","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"βMn"}],"phases":[{"label":"βMn","model_phase_rejected":{"model_phase":"BCC_A2","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01389,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01389},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.3152,"value_stored":0.63152},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"CBCC_A12","evidence":{"label":"γMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored T=298.15 (assumed_room_temperature) contradicts footnote (a) 'Measurement temperature unknown' on βMn, γMn, δMn rows","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t081)","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"βMn 0.63152 (a); γMn 0.386624 (a); δMn 0.30806 (a) [King2]","verdict":"confirmed"}}],"id":"ORC-IFYUQ5H5GR.8d85c3","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":11},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"γMn"}],"phases":[{"label":"γMn","model_phase_rejected":{"model_phase":"CBCC_A12","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETERS","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008506,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008506},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.86624,"value_stored":0.386624},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"CBCC_A12","evidence":{"label":"γMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored T=298.15 (assumed_room_temperature) contradicts footnote (a) 'Measurement temperature unknown' on βMn, γMn, δMn rows","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t081)","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"βMn 0.63152 (a); γMn 0.386624 (a); δMn 0.30806 (a) [King2]","verdict":"confirmed"}}],"id":"ORC-IFYUQ5H5GR.a163f5","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":11},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"γMn"}],"phases":[{"label":"γMn","model_phase_rejected":{"model_phase":"CBCC_A12","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008506,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008506},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.86624,"value_stored":0.386624},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["δMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"CBCC_A12","evidence":{"label":"δMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored T=298.15 (assumed_room_temperature) contradicts footnote (a) 'Measurement temperature unknown' on βMn, γMn, δMn rows","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t081)","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"βMn 0.63152 (a); γMn 0.386624 (a); δMn 0.30806 (a) [King2]","verdict":"confirmed"}}],"id":"ORC-NPDXVCVPMB.8253bf","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"δMn"}],"phases":[{"label":"δMn","model_phase_rejected":{"model_phase":"CBCC_A12","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETERS","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006777,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006777},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.0806,"value_stored":0.30806},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":0.0,"MN":1.0},"phases":["δMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"CBCC_A12","evidence":{"label":"δMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored T=298.15 (assumed_room_temperature) contradicts footnote (a) 'Measurement temperature unknown' on βMn, γMn, δMn rows","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t081)","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"βMn 0.63152 (a); γMn 0.386624 (a); δMn 0.30806 (a) [King2]","verdict":"confirmed"}}],"id":"ORC-NPDXVCVPMB.93ccdf","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_stored":{"AG":0.0,"MN":1.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","composition_stored":{"AG":0.0,"MN":1.0},"phase":"δMn"}],"phases":[{"label":"δMn","model_phase_rejected":{"model_phase":"CBCC_A12","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006777,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006777},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.0806,"value_stored":0.30806},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02869863","first_author":"Liao","kind":"assessment","label":"3","paper":"doi:10.1007/bf02869863","reference":"P.K. Liao and K.E. Spear, The B-Mn (Boron-Manganese) System, Bull. Alloy Phase Diag., 1986, 7(6), p 543-549, p 585-586","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"B-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["(δMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-SMVXHKMYBF","locator":{"ref":"doi:10.1007/s11669-010-9740-6/p2/tab-1","row":2},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-010-9740-6","paper_id":"doi:10.1007/s11669-010-9740-6","phases":[{"label":"(δMn)"}],"pid":"doi:10.1007/s11669-010-9740-6/p2/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-MN","structure":{"pearson_symbol":"cI2","prototype":"W","space_group":"Im3m"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02372,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02372},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.0806,"value_stored":3.0806},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02869863","first_author":"Liao","kind":"assessment","label":"3","paper":"doi:10.1007/bf02869863","reference":"P.K. Liao and K.E. Spear, The B-Mn (Boron-Manganese) System, Bull. Alloy Phase Diag., 1986, 7(6), p 543-549, p 585-586","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"B-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-LLAVNBQIZP","locator":{"ref":"doi:10.1007/s11669-010-9740-6/p2/tab-1","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-010-9740-6","paper_id":"doi:10.1007/s11669-010-9740-6","phases":[{"label":"(γMn)"}],"pid":"doi:10.1007/s11669-010-9740-6/p2/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-MN","structure":{"pearson_symbol":"cF4","prototype":"Cu","space_group":"Fm3m"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02974,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02974},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.8624,"value_stored":3.8624},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02869863","first_author":"Liao","kind":"assessment","label":"3","paper":"doi:10.1007/bf02869863","reference":"P.K. Liao and K.E. Spear, The B-Mn (Boron-Manganese) System, Bull. Alloy Phase Diag., 1986, 7(6), p 543-549, p 585-586","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"B-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["(βMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-YNBJ2VFFCS","locator":{"ref":"doi:10.1007/s11669-010-9740-6/p2/tab-1","row":4},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-010-9740-6","paper_id":"doi:10.1007/s11669-010-9740-6","phases":[{"label":"(βMn)"}],"pid":"doi:10.1007/s11669-010-9740-6/p2/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-MN","structure":{"pearson_symbol":"cP20","prototype":"βMn"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04863,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04863},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.3152,"value_stored":6.3152},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02869863","first_author":"Liao","kind":"assessment","label":"3","paper":"doi:10.1007/bf02869863","reference":"P.K. Liao and K.E. Spear, The B-Mn (Boron-Manganese) System, Bull. Alloy Phase Diag., 1986, 7(6), p 543-549, p 585-586","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"B-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["(αMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-CE2LY22UA6","locator":{"ref":"doi:10.1007/s11669-010-9740-6/p2/tab-1","row":5},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-010-9740-6","paper_id":"doi:10.1007/s11669-010-9740-6","phases":[{"label":"(αMn)"}],"pid":"doi:10.1007/s11669-010-9740-6/p2/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-MN","structure":{"pearson_symbol":"cI58","prototype":"αMn","space_group":"I43m"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06864,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.06864},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.9139,"value_stored":8.9139},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["C14"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"C14","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2012.03.004","pdf_page":8,"pdf_sha256":"cfecab996b1fcdb98f8704d34f1aad875e05a4c72fa56fc2e3766b2bec473e3c","printed":"Structure: C14 (first row of block: C14 NbMn2 NM -913.923 4.802 7.930 158.4)","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2,3,4,5,6,7,9,10,11,12,13,14,15,16,17,18,19],"table":"4","table_key":"t004"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"7736eb11fb391ed9d5613d83df9047ba99daf7ba872b2b974cf463c6dc521e5a","page":8,"pdf_sha256_prefix":"cfecab996b1fcdb9","seen":"C14 block = NbMn2, MnNb2, MnMn2, NbNb2, NbFe2, FeNb2, FeFe2; ends before the μ block (Fe7Nb6)","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5GPIGU4FR3.8f5c52","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4","row":7},"merged_ids":["ORC-QQNRU7WZSH.5cbfc7"],"merged_pids":["doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r08#structural_property"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"C14"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","structure":{"phase":"C14","strukturbericht":"C14"},"system":"MN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07358,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07358},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.358,"value_stored":7.358},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["C14"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"C14","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2012.03.004","pdf_page":8,"pdf_sha256":"cfecab996b1fcdb98f8704d34f1aad875e05a4c72fa56fc2e3766b2bec473e3c","printed":"Structure: C14 (first row of block: C14 NbMn2 NM -913.923 4.802 7.930 158.4)","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2,3,4,5,6,7,9,10,11,12,13,14,15,16,17,18,19],"table":"4","table_key":"t004"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"7736eb11fb391ed9d5613d83df9047ba99daf7ba872b2b974cf463c6dc521e5a","page":8,"pdf_sha256_prefix":"cfecab996b1fcdb9","seen":"C14 block = NbMn2, MnNb2, MnMn2, NbNb2, NbFe2, FeNb2, FeFe2; ends before the μ block (Fe7Nb6)","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5GPIGU4FR3.af5ff7","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4","row":7},"merged_ids":["ORC-ET65D5MLIQ.697fb3","ORC-QQNRU7WZSH.bd068f"],"merged_pids":["doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r08#structural_property","doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r09#structural_property"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"C14"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V0","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","structure":{"phase":"C14","strukturbericht":"C14"},"system":"MN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.951,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":3.951},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å3 per formula unit","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3 per formula unit","value":131.7},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["C14"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"C14","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2012.03.004","pdf_page":8,"pdf_sha256":"cfecab996b1fcdb98f8704d34f1aad875e05a4c72fa56fc2e3766b2bec473e3c","printed":"Structure: C14 (first row of block: C14 NbMn2 NM -913.923 4.802 7.930 158.4)","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2,3,4,5,6,7,9,10,11,12,13,14,15,16,17,18,19],"table":"4","table_key":"t004"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"7736eb11fb391ed9d5613d83df9047ba99daf7ba872b2b974cf463c6dc521e5a","page":8,"pdf_sha256_prefix":"cfecab996b1fcdb9","seen":"C14 block = NbMn2, MnNb2, MnMn2, NbNb2, NbFe2, FeNb2, FeFe2; ends before the μ block (Fe7Nb6)","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5GPIGU4FR3.e0fa5d","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4","row":7},"merged_ids":["ORC-ET65D5MLIQ.401516","ORC-QQNRU7WZSH.2a018c"],"merged_pids":["doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r08#structural_property","doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r09#structural_property"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"C14"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","structure":{"phase":"C14","strukturbericht":"C14"},"system":"MN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04547,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04547},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.547,"value_stored":4.547},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["C14"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"C14","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2012.03.004","pdf_page":8,"pdf_sha256":"cfecab996b1fcdb98f8704d34f1aad875e05a4c72fa56fc2e3766b2bec473e3c","printed":"Structure: C14 (first row of block: C14 NbMn2 NM -913.923 4.802 7.930 158.4)","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2,3,4,5,6,7,9,10,11,12,13,14,15,16,17,18,19],"table":"4","table_key":"t004"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"7736eb11fb391ed9d5613d83df9047ba99daf7ba872b2b974cf463c6dc521e5a","page":8,"pdf_sha256_prefix":"cfecab996b1fcdb9","seen":"C14 block = NbMn2, MnNb2, MnMn2, NbNb2, NbFe2, FeNb2, FeFe2; ends before the μ block (Fe7Nb6)","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5GPIGU4FR3.f7ef3c","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4","row":7},"merged_ids":["ORC-ET65D5MLIQ.feb436","ORC-QQNRU7WZSH.f99292"],"merged_pids":["doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r08#structural_property","doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r09#structural_property"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"C14"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V0","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","structure":{"phase":"C14","strukturbericht":"C14"},"system":"MN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.951,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/VOLUME","floor":0.03,"floor_unit":"relative (fraction of the value)","value":3.951},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3","value":131.7},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["C14"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"C14","strukturbericht":"C14"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2012.03.004","pdf_page":8,"pdf_sha256":"cfecab996b1fcdb98f8704d34f1aad875e05a4c72fa56fc2e3766b2bec473e3c","printed":"Structure: C14 (first row of block: C14 NbMn2 NM -913.923 4.802 7.930 158.4)","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2,3,4,5,6,7,9,10,11,12,13,14,15,16,17,18,19],"table":"4","table_key":"t004"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"7736eb11fb391ed9d5613d83df9047ba99daf7ba872b2b974cf463c6dc521e5a","page":8,"pdf_sha256_prefix":"cfecab996b1fcdb9","seen":"C14 block = NbMn2, MnNb2, MnMn2, NbNb2, NbFe2, FeNb2, FeFe2; ends before the μ block (Fe7Nb6)","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-ET65D5MLIQ.98d3ea","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4","row":9},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"C14"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p8/tab-4/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","structure":{"phase":"C14","strukturbericht":"C14"},"system":"MN","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07357,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07357},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.357,"value_stored":7.357},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5SRNIG5XLE.35d24b","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"(γMn)"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","system":"MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02692,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02692},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.496,"value_stored":3.496},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5SRNIG5XLE.d3226e","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"(γMn)"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V0","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","system":"MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.2135,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/VOLUME","floor":0.005,"floor_unit":"relative (fraction of the value)","n_pairs":0,"value":0.2135},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3","value":42.7},{"chemical_system":"MN","cited_sources":[{"doi":"10.1016/j.calphad.2004.05.002","first_author":"Wang","kind":"assessment","label":"78","paper":"doi:10.1016/j.calphad.2004.05.002","reference":"Y. Wang, S. Curtarolo, C. Jiang, R. Arroyave, T. Wang, G. Ceder, L.-Q. Chen, Z.K. Liu, Calphad 28 (2004) 79–90.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-2XOEYEDDEX.47b145","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5","row":4},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"(γMn)"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V0","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","system":"MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.215,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/VOLUME","floor":0.005,"floor_unit":"relative (fraction of the value)","n_pairs":0,"value":0.215},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3","value":43.0},{"chemical_system":"MN","cited_sources":[{"doi":"10.1016/j.calphad.2004.05.002","first_author":"Wang","kind":"assessment","label":"78","paper":"doi:10.1016/j.calphad.2004.05.002","reference":"Y. Wang, S. Curtarolo, C. Jiang, R. Arroyave, T. Wang, G. Ceder, L.-Q. Chen, Z.K. Liu, Calphad 28 (2004) 79–90.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-2XOEYEDDEX.7599f2","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5","row":4},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"(γMn)"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","system":"MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02697,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02697},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.502,"value_stored":3.502},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-KHHDSJ6IKS.7e53e1","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5","row":5},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"(γMn)"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","system":"MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02733,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02733},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.55,"value_stored":3.55},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-NB","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"NB":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-KHHDSJ6IKS.de5c8f","locator":{"ref":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5","row":5},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.03.004","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"NB":0.0},"paper":"doi:10.1016/j.calphad.2012.03.004","paper_id":"doi:10.1016/j.calphad.2012.03.004","phases":[{"label":"(γMn)"}],"pid":"doi:10.1016/j.calphad.2012.03.004/p9/tab-5/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_V0","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"FE-MN-NB","system":"MN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.2235,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/VOLUME","floor":0.005,"floor_unit":"relative (fraction of the value)","n_pairs":0,"value":0.2235},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å3","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å3","value":44.7},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"HF-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["(αMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored 727.0 K is the printed stability limit '≤ 727' (°C column, stored as K); no measurement T printed","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t160)","image_sha256":"3c999bed028a339846385ff56b9cb84fb322ecef1617a87ee3a5d439d94cdf96","page":3,"pdf_sha256_prefix":"e4edef58f093c43f","seen":"(αMn) I-43m αMn 0.8913 ≤ 727 [12]","verdict":"confirmed"}}],"id":"ORC-MNLB3O2CFS","locator":{"ref":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2023.173060","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2023.173060","paper_id":"doi:10.1016/j.jallcom.2023.173060","phases":[{"label":"(αMn)"}],"pid":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"HF-MN","structure":{"prototype":"αMn"},"system":"MN","temperature_K":727.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":727.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01961,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01961},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.913,"value_stored":0.8913},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"HF-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"(βMn)","label_source":"printed_source_page","prototype":"βMn","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.jallcom.2023.173060","pdf_page":3,"pdf_sha256":"e4edef58f093c43f7248ec31ed4f69dbb22491390f09088480f788bfad6e5c5e","printed":"(βMn) | P4_132 | βMn | 0.6315 | 1100-727 | [12]","rationale":"Printed table context for this group supplies phase, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13],"table":"1","table_key":"t160"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8c9ff3b8332d90a22ab02a67ac075ea06fadefac45b83e87d00ca7f4fddae21b","page":3,"pdf_sha256_prefix":"e4edef58f093c43f","seen":"own row","verdict":"confirmed"}},{"after":{"phase":"(βMn)","prototype":"βMn","space_group":"P4132"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.jallcom.2023.173060","pdf_page":3,"pdf_sha256":"e4edef58f093c43f7248ec31ed4f69dbb22491390f09088480f788bfad6e5c5e","printed":"(βMn) | P4_132 | βMn | 0.6315 | 1100-727 | [12]","rationale":"Printed table context for this group supplies phase, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13],"table":"1","table_key":"t160"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8c9ff3b8332d90a22ab02a67ac075ea06fadefac45b83e87d00ca7f4fddae21b","page":3,"pdf_sha256_prefix":"e4edef58f093c43f","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5WVPYBWXZ4","locator":{"ref":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2023.173060","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2023.173060","paper_id":"doi:10.1016/j.jallcom.2023.173060","phases":[{"label":"(βMn)","label_source":"printed_source_page","prototype":"βMn","structure_basis":"printed_source_page"}],"pid":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"HF-MN","structure":{"phase":"(βMn)","prototype":"βMn","space_group":"P4132"},"system":"MN","temperature_K":913.5,"temperature_basis":"printed_range","temperature_range_K":{"max":1100.0,"min":727.0},"temperature_uncertainty":{"basis":"printed_range","value":186.5},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01389,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01389},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.315,"value_stored":0.6315},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"HF-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored 1119.0 K is the midpoint of the printed stability range '1138–1100' °C stored as K; no measurement T printed (phase label also UNKNOWN; page prints (γMn))","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t160)","image_sha256":"3c999bed028a339846385ff56b9cb84fb322ecef1617a87ee3a5d439d94cdf96","page":3,"pdf_sha256_prefix":"e4edef58f093c43f","seen":"(γMn) Fd-3m Cu 0.3860 ... 1138–1100 [12]","verdict":"confirmed"}}],"id":"ORC-RFUQ2NN5FM","locator":{"ref":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2023.173060","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2023.173060","paper_id":"doi:10.1016/j.jallcom.2023.173060","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"HF-MN","system":"MN","temperature_K":1119.0,"temperature_basis":"printed_range","temperature_range_K":{"max":1138.0,"min":1100.0},"temperature_uncertainty":{"basis":"printed_range","value":19.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008492,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008492},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.86,"value_stored":0.386},{"chemical_system":"MN","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"MN","before":"HF-MN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"(δMn)","label_source":"printed_source_page","prototype":"W","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.jallcom.2023.173060","pdf_page":3,"pdf_sha256":"e4edef58f093c43f7248ec31ed4f69dbb22491390f09088480f788bfad6e5c5e","printed":"(δMn) | Im-3m | W | 0.3080 | 1246-1138 | [12]","rationale":"Printed table context for this group supplies phase, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15],"table":"1","table_key":"t160"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8c9ff3b8332d90a22ab02a67ac075ea06fadefac45b83e87d00ca7f4fddae21b","page":3,"pdf_sha256_prefix":"e4edef58f093c43f","seen":"own row","verdict":"confirmed"}},{"after":{"phase":"(δMn)","prototype":"W","space_group":"Im-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.jallcom.2023.173060","pdf_page":3,"pdf_sha256":"e4edef58f093c43f7248ec31ed4f69dbb22491390f09088480f788bfad6e5c5e","printed":"(δMn) | Im-3m | W | 0.3080 | 1246-1138 | [12]","rationale":"Printed table context for this group supplies phase, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15],"table":"1","table_key":"t160"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8c9ff3b8332d90a22ab02a67ac075ea06fadefac45b83e87d00ca7f4fddae21b","page":3,"pdf_sha256_prefix":"e4edef58f093c43f","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-PGOCEXJD5E","locator":{"ref":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2023.173060","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2023.173060","paper_id":"doi:10.1016/j.jallcom.2023.173060","phases":[{"label":"(δMn)","label_source":"printed_source_page","prototype":"W","structure_basis":"printed_source_page"}],"pid":"doi:10.1016/j.jallcom.2023.173060/p3/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"HF-MN","structure":{"phase":"(δMn)","prototype":"W","space_group":"Im-3m"},"system":"MN","temperature_K":1192.0,"temperature_basis":"printed_range","temperature_range_K":{"max":1246.0,"min":1138.0},"temperature_uncertainty":{"basis":"printed_range","value":54.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006776,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006776},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.08,"value_stored":0.308},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"FE-MN-TI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"TI":0.0},"phases":["C14 Laves Mn2Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-ZNJNUARKDF.bcc915","locator":{"ref":"sha256:30fb4308ad772cc9/p6/tab-4","row":19},"merged_ids":["ORC-ZNJNUARKDF.4fe746"],"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"TI":0.0},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"C14 Laves Mn2Mn","label_variants":["C14 Laves"]}],"pid":"sha256:30fb4308ad772cc9/p6/tab-4/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"reference_state_stored":{"FE":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"TI":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"source_system":"FE-MN-TI","system":"MN","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.50625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":10.125,"value_printed":10.125,"value_stored":10125.0},{"chemical_system":"MN","cited_sources":[{"doi":"10.1039/c6cp04542a","first_author":"Khan","kind":"assessment","label":"29","paper":"doi:10.1039/c6cp04542a","reference":"A.U. Khan, P. Brož, M. Premović, J. Pavlů, J. Vřeštál, X. Yan, D. Maccio, A. Saccone, G. Giester, P. Rogl, The Ti–Mn system revisited: experimental investigation and thermodynamic modelling, Phys. Chem. Chem. Phys. 18 (2016) 23326–23339.","status":"resolved","year":"2016"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"FE-MN-TI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"TI":0.0},"phases":["C14 Laves Mn2Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-2RVTMN57IY.116795","locator":{"ref":"sha256:30fb4308ad772cc9/p6/tab-4","row":20},"merged_ids":["ORC-2RVTMN57IY.402f56"],"method":"ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","measured_in":"doi:10.1039/c6cp04542a","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"TI":0.0},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"C14 Laves Mn2Mn","label_variants":["C14 Laves"]}],"pid":"sha256:30fb4308ad772cc9/p6/tab-4/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"reference_state_stored":{"FE":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"TI":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"source_system":"FE-MN-TI","system":"MN","temperature_K":0.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.3913},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":7.826,"value_printed":7.826,"value_stored":7826.0},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"ΔfH"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"MN","before":"FE-MN-TI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"TI":0.0},"phases":["C14 Laves Mn2Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-TEV2VKRUZJ.96a814","locator":{"ref":"sha256:30fb4308ad772cc9/p6/tab-4","row":21},"merged_ids":["ORC-TEV2VKRUZJ.6f22cd"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2021.161957","own_work_of_paper":true},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"TI":0.0},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"C14 Laves Mn2Mn","label_variants":["C14 Laves"]}],"pid":"sha256:30fb4308ad772cc9/p6/tab-4/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"reference_state_stored":{"FE":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"TI":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"source_system":"FE-MN-TI","system":"MN","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.50625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":10.125,"value_printed":10.125,"value_stored":10125.0},{"chemical_system":"MN","cited_sources":[{"doi":"10.1039/c6cp04542a","first_author":"Khan","kind":"assessment","label":"29","paper":"doi:10.1039/c6cp04542a","reference":"A.U. Khan, P. Brož, M. Premović, J. Pavlů, J. Vřeštál, X. Yan, D. Maccio, A. Saccone, G. Giester, P. Rogl, The Ti–Mn system revisited: experimental investigation and thermodynamic modelling, Phys. Chem. Chem. Phys. 18 (2016) 23326–23339.","status":"resolved","year":"2016"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"ΔfH"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"MN","before":"FE-MN-TI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"TI":0.0},"phases":["C14 Laves Mn2Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-DI6UXQFWVB.e6bfe4","locator":{"ref":"sha256:30fb4308ad772cc9/p6/tab-4","row":22},"merged_ids":["ORC-DI6UXQFWVB.65f97e"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1039/c6cp04542a","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"TI":0.0},"paper":"doi:10.1016/j.jallcom.2021.161957","paper_id":"doi:10.1016/j.jallcom.2021.161957","phases":[{"label":"C14 Laves Mn2Mn","label_variants":["C14 Laves"]}],"pid":"sha256:30fb4308ad772cc9/p6/tab-4/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"reference_state_stored":{"FE":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"MN":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"},"TI":{"phase":"printed:hcp Ti, bcc Fe and cbcc Mn"}},"source_system":"FE-MN-TI","system":"MN","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.3913},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":7.826,"value_printed":7.826,"value_stored":7826.0},{"chemical_system":"MN","cited_sources":[{"first_author":"King","kind":"assessment","label":"49","reference":"H. King, Crystal structures of the elements at 25 1C, J. Phase Equilib. 2 (1981) 401–402.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"CD-FE-MN-SN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"FE":0.0,"MN":1.0,"SN":0.0},"phases":["(αMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-FGXV4C6HT5","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"MN":1.0,"SN":0.0},"paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"(αMn)"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"cI58","prototype":"αMn"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0687,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.0687},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.9219,"value_stored":0.89219},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02877580","first_author":"Gokcen","kind":"assessment","label":"50","paper":"doi:10.1007/bf02877580","reference":"N.A. Gokcen, The phase transformation in Mn, Bull. Alloy Phase Diagr. 10 (1989) 313.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"CD-FE-MN-SN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"FE":0.0,"MN":1.0,"SN":0.0},"phases":["(βMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-7GDKG2QIAI","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"MN":1.0,"SN":0.0},"paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"(βMn)"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"cP20","prototype":"βMn"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04863,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04863},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.3152,"value_stored":0.63152},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02877580","first_author":"Gokcen","kind":"assessment","label":"50","paper":"doi:10.1007/bf02877580","reference":"N.A. Gokcen, The phase transformation in Mn, Bull. Alloy Phase Diagr. 10 (1989) 313.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"CD-FE-MN-SN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"FE":0.0,"MN":1.0,"SN":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-N74TBLJAAH","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"MN":1.0,"SN":0.0},"paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"(γMn)"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"cF4","prototype":"Cu"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02972,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02972},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.86,"value_stored":0.386},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02877580","first_author":"Gokcen","kind":"assessment","label":"50","paper":"doi:10.1007/bf02877580","reference":"N.A. Gokcen, The phase transformation in Mn, Bull. Alloy Phase Diagr. 10 (1989) 313.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"CD-FE-MN-SN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"FE":0.0,"MN":1.0,"SN":0.0},"phases":["(δMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-3GEBPS7KDF","locator":{"ref":"sha256:9ce403d6580e9b80/p3/tab-2","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"MN":1.0,"SN":0.0},"paper":"doi:10.1016/j.calphad.2014.06.006","paper_id":"doi:10.1016/j.calphad.2014.06.006","phases":[{"label":"(δMn)"}],"pid":"sha256:9ce403d6580e9b80/p3/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"CD-FE-MN-SN","structure":{"pearson_symbol":"cI2","prototype":"W"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02372,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02372},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.08,"value_stored":0.308},{"chemical_system":"MN","cited_sources":[{"doi":"10.1016/j.jallcom.2014.06.202","first_author":"Berche","kind":"assessment","label":"19","paper":"doi:10.1016/j.jallcom.2014.06.202","reference":"A. Berche, E. RuizeTh\u0002 eron, J.eC. T\u0002 edenac, R.eM. Ayral, F. Rouessac, P. Jund, Thermodynamic description of the MneSi system: an experimental and theoretical work, J. Alloys Compd. 615 (2014) 693e702.","status":"resolved","year":"2014"},{"doi":"10.1016/s0925-8388(98)00742-7","first_author":"Morozkin","kind":"unknown","label":"20","paper":"doi:10.1016/s0925-8388(98)00742-7","reference":"A.V. Morozkin, Y.D. Seropegin, I.A. Sviridov, V.A. Moskalev, I.A. Tskhadadze, I.G. Ryabinkin, Phase equilibria in the {Sm,Tb,TmeMneSi systems at 870/1070 K: Structural data and melting temperatures of some ternary compounds in the ReMneSi systems (R¼Y, LaeLu), J. Alloys Compd. 280 (1998) 178e187.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"LI-MN-SI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"SI":0.0},"phases":["(αMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-K7GUESHLSQ","locator":{"ref":"sha256:b1df2c382b053970/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2014.06.202","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"SI":0.0},"paper":"doi:10.1016/j.jallcom.2018.07.211","paper_id":"doi:10.1016/j.jallcom.2018.07.211","phases":[{"label":"(αMn)"}],"pid":"sha256:b1df2c382b053970/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"LI-MN-SI","structure":{"pearson_symbol":"cI58","space_group":"I-43m"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01961,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01961},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.914,"value_stored":0.8914},{"chemical_system":"MN","cited_sources":[{"doi":"10.1016/j.jallcom.2014.06.202","first_author":"Berche","kind":"assessment","label":"19","paper":"doi:10.1016/j.jallcom.2014.06.202","reference":"A. Berche, E. RuizeTh\u0002 eron, J.eC. T\u0002 edenac, R.eM. Ayral, F. Rouessac, P. Jund, Thermodynamic description of the MneSi system: an experimental and theoretical work, J. Alloys Compd. 615 (2014) 693e702.","status":"resolved","year":"2014"},{"doi":"10.1016/s0925-8388(98)00742-7","first_author":"Morozkin","kind":"unknown","label":"20","paper":"doi:10.1016/s0925-8388(98)00742-7","reference":"A.V. Morozkin, Y.D. Seropegin, I.A. Sviridov, V.A. Moskalev, I.A. Tskhadadze, I.G. Ryabinkin, Phase equilibria in the {Sm,Tb,TmeMneSi systems at 870/1070 K: Structural data and melting temperatures of some ternary compounds in the ReMneSi systems (R¼Y, LaeLu), J. Alloys Compd. 280 (1998) 178e187.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"LI-MN-SI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"SI":0.0},"phases":["(βMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-3RURIJQKFX","locator":{"ref":"sha256:b1df2c382b053970/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2014.06.202","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"SI":0.0},"paper":"doi:10.1016/j.jallcom.2018.07.211","paper_id":"doi:10.1016/j.jallcom.2018.07.211","phases":[{"label":"(βMn)"}],"pid":"sha256:b1df2c382b053970/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"LI-MN-SI","structure":{"pearson_symbol":"cP20","space_group":"P4132"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01389,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01389},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.314,"value_stored":0.6314},{"chemical_system":"MN","cited_sources":[{"doi":"10.1016/j.jallcom.2014.06.202","first_author":"Berche","kind":"assessment","label":"19","paper":"doi:10.1016/j.jallcom.2014.06.202","reference":"A. Berche, E. RuizeTh\u0002 eron, J.eC. T\u0002 edenac, R.eM. Ayral, F. Rouessac, P. Jund, Thermodynamic description of the MneSi system: an experimental and theoretical work, J. Alloys Compd. 615 (2014) 693e702.","status":"resolved","year":"2014"},{"doi":"10.1016/s0925-8388(98)00742-7","first_author":"Morozkin","kind":"unknown","label":"20","paper":"doi:10.1016/s0925-8388(98)00742-7","reference":"A.V. Morozkin, Y.D. Seropegin, I.A. Sviridov, V.A. Moskalev, I.A. Tskhadadze, I.G. Ryabinkin, Phase equilibria in the {Sm,Tb,TmeMneSi systems at 870/1070 K: Structural data and melting temperatures of some ternary compounds in the ReMneSi systems (R¼Y, LaeLu), J. Alloys Compd. 280 (1998) 178e187.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"LI-MN-SI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"MN":1.0,"SI":0.0},"phases":["(γMn)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-MMT3OJFLAI","locator":{"ref":"sha256:b1df2c382b053970/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2014.06.202","own_work_of_paper":false},"overall_composition":{"MN":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"MN":1.0,"SI":0.0},"paper":"doi:10.1016/j.jallcom.2018.07.211","paper_id":"doi:10.1016/j.jallcom.2018.07.211","phases":[{"label":"(γMn)"}],"pid":"sha256:b1df2c382b053970/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"LI-MN-SI","structure":{"pearson_symbol":"cF4","space_group":"Fm-3m"},"system":"MN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01258,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01258},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.72,"value_stored":0.572},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["L","bcc"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-EL32L2IMIK","locator":{"ref":"doi:10.1007/bf02646113/p3/tab-i","row":14},"model":"Mcf2b79f9","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/bf02646113","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/bf02646113","paper_id":"doi:10.1007/bf02646113","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"bcc"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"bcc","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/bf02646113/p3/tab-i/r14#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liquid -> bcc","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1519,"temperature_printed":"1519","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1519},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["Bcc","fcc"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-WBBN5CXRVA","locator":{"ref":"doi:10.1007/bf02646113/p3/tab-i","row":15},"model":"Mcf2b79f9","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/bf02646113","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/bf02646113","paper_id":"doi:10.1007/bf02646113","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"Bcc"},{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"fcc"}],"phases":[{"label":"Bcc","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"fcc","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/bf02646113/p3/tab-i/r15#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Bcc -> fcc","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1411,"temperature_printed":"1411","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1411},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["Fcc","β-Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":1.0,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"pass","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-3WJ2QT2OWX","locator":{"ref":"doi:10.1007/bf02646113/p3/tab-i","row":16},"model":"Mcf2b79f9","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/bf02646113","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/bf02646113","paper_id":"doi:10.1007/bf02646113","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"Fcc"},{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"β-Mn"}],"phases":[{"label":"Fcc","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"β-Mn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/bf02646113/p3/tab-i/r16#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Fcc -> β-Mn","type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1360,"temperature_printed":"1360","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1360},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["β-Mn","α-Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":0.0,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"pass","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-UVLDFFHLRK","locator":{"ref":"doi:10.1007/bf02646113/p3/tab-i","row":17},"model":"Mcf2b79f9","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/bf02646113","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/bf02646113","paper_id":"doi:10.1007/bf02646113","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"β-Mn"},{"basis":"mole_fraction","composition":{"MN":1.0},"composition_source":"printed","phase":"α-Mn"}],"phases":[{"label":"β-Mn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"},{"label":"α-Mn","mapping_confidence":"confirmed","model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/bf02646113/p3/tab-i/r17#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"β-Mn -> α-Mn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":980,"temperature_printed":"980","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":980},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["L","δMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"CBCC_A12","evidence":{"label":"δMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-34V5AAV5UW","locator":{"ref":"doi:10.1007/bf02898263/p3/tab-i","row":7},"model":"Mabe01570","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","phase":"δMn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"δMn","model_phase_rejected":{"model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p3/tab-i/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> δMn","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-MN","system":"MN","temperature_K":1519.15,"temperature_printed":"1246","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Melting","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1519.15},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":["δMn","γMn"],"before":["δMn"],"evidence":{"added":["γMn"],"printed":"δMn -> γMn"},"field":"phases","gate":"R3I","rule":"phases_from_printed_reaction"},{"after":null,"before":"CBCC_A12","evidence":{"label":"δMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["phases_added_from_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"phases_added_from_printed_reaction","detail":"phases ['γMn'] read from the printed reaction; not mapped to model phases","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-AQEQCVGAJH","locator":{"ref":"doi:10.1007/bf02898263/p3/tab-i","row":8},"model":"Mabe01570","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","phase":"δMn"}],"phases":[{"label":"δMn","model_phase_rejected":{"model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","reason":"element_polymorph_contradicts_model"}},{"label":"γMn","label_source":"printed_reaction"}],"phases_stored":[{"label":"δMn","model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn"}],"pid":"doi:10.1007/bf02898263/p3/tab-i/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δMn -> γMn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-MN","system":"MN","temperature_K":1411.15,"temperature_printed":"1138","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1411.15},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["γMn","βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"CBCC_A12","evidence":{"label":"γMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"},{"after":null,"before":"BCC_A2","evidence":{"label":"βMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-M74O6D2IC2","locator":{"ref":"doi:10.1007/bf02898263/p3/tab-i","row":9},"model":"Mabe01570","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","phase":"γMn"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","phase":"βMn"}],"phases":[{"label":"γMn","model_phase_rejected":{"model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","reason":"element_polymorph_contradicts_model"}},{"label":"βMn","model_phase_rejected":{"model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","reason":"element_polymorph_contradicts_model"}}],"pid":"doi:10.1007/bf02898263/p3/tab-i/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"γMn -> βMn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-MN","system":"MN","temperature_K":1373.15,"temperature_printed":"1100","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1373.15},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AG-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["βMn","αMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"BCC_A2","evidence":{"label":"βMn","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"element_polymorph_contradicts_model"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-7LA6XHYBTH","locator":{"ref":"doi:10.1007/bf02898263/p3/tab-i","row":10},"model":"Mabe01570","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","phase":"βMn"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"MN":1.0},"composition_source":"printed","phase":"αMn"}],"phases":[{"label":"βMn","model_phase_rejected":{"model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","reason":"element_polymorph_contradicts_model"}},{"label":"αMn","model_phase":"CBCC_A12","pearson_symbol":"cI58","prototype":"alpha-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/bf02898263/p3/tab-i/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βMn -> αMn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-MN","system":"MN","temperature_K":1000.15,"temperature_printed":"727","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1000.15},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"HF-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","βMn","γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.461,"dx":{"βMn":0.0,"δMn":-0.0},"model":"HfMn-12Zho.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-L22E4WCB77","locator":{"ref":"doi:10.1007/s11669-011-9976-9/p8/tab-5","row":11},"model":"M62b6cccc","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-011-9976-9","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-011-9976-9","paper_id":"doi:10.1007/s11669-011-9976-9","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.9973},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.9958},"composition_source":"printed","phase":"βMn"},{"basis":"mole_fraction","composition":{"MN":0.9998},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-011-9976-9/p8/tab-5/r11#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δMn -> βMn + γMn"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"HF-MN","system":"MN","temperature_K":1389,"temperature_printed":"1389","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1389},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02645298","first_author":"Okamoto","kind":"assessment","label":"8","paper":"doi:10.1007/bf02645298","reference":"H. Okamoto, The Hf-Mn(Hafnium-Manganese) System, J. Phase Equilib., 1995, 16, p 361-363 28","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"HF-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","βMn","γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-6.461,"dx":{"βMn":-0.0128,"γMn":-0.0028,"δMn":-0.0023},"model":"HfMn-12Zho.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","source_disputed":true,"state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-5ZAH7D7BOD","locator":{"ref":"doi:10.1007/s11669-011-9976-9/p8/tab-5","row":12},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/bf02645298","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-011-9976-9","paper_id":"doi:10.1007/s11669-011-9976-9","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.995},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.983},"composition_source":"printed","phase":"βMn"},{"basis":"mole_fraction","composition":{"MN":0.997},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-011-9976-9/p8/tab-5/r12#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δMn -> βMn + γMn"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"HF-MN","system":"MN","temperature_K":1383,"temperature_printed":"1383","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1383},{"chemical_system":"MN","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"11","reference":"T.B. Massalski, P.R. Subramanian, H. Okamoto, L. Kacprzak, Binary Alloy Phase Diagrams, 2nd ed., ASM International, 1990.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"MN-PR","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":0.15,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"pass","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-OOMLSSHQBB","locator":{"ref":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5","row":1},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:6377c70343cad517","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.01.092","paper_id":"doi:10.1016/j.jallcom.2008.01.092","phase_compositions":[{"basis":"mole_fraction","composition":{},"composition_source":"printed","composition_stored":{"PR":0.0},"phase":"δMn"}],"phases":[{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5/r-unplaced-2177cd9c#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"δMn -> γMn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-PR","system":"MN","temperature_K":1411.15,"temperature_printed":"1138","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1411.15},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"MN-PR","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":-5.85,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"pass","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-3XVMENQEPE","locator":{"ref":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5","row":2},"model":"M24c39354","observation_type":"phase_transition","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.01.092","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.01.092","paper_id":"doi:10.1016/j.jallcom.2008.01.092","phase_compositions":[{"basis":"mole_fraction","composition":{},"composition_source":"printed","composition_stored":{"PR":0.0},"phase":"δMn"}],"phases":[{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5/r-unplaced-d49971a7#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"δMn -> γMn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"MN-PR","system":"MN","temperature_K":1405.15,"temperature_printed":"1132","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1405.15},{"chemical_system":"MN","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"11","reference":"T.B. Massalski, P.R. Subramanian, H. Okamoto, L. Kacprzak, Binary Alloy Phase Diagrams, 2nd ed., ASM International, 1990.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"MN-PR","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["γMn","βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":14.15,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"pass","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-E7KY74SQNF","locator":{"ref":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5","row":3},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:6377c70343cad517","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2008.01.092","paper_id":"doi:10.1016/j.jallcom.2008.01.092","phase_compositions":[{"basis":"mole_fraction","composition":{},"composition_source":"printed","composition_stored":{"PR":0.0},"phase":"γMn"},{"basis":"mole_fraction","composition":{},"composition_source":"stoichiometric_model_phase","composition_stored":{"PR":0.0},"phase":"βMn"}],"phases":[{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5/r01#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"γMn -> βMn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-PR","system":"MN","temperature_K":1373.15,"temperature_printed":"1100","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1373.15},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"MN-PR","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["γMn","βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":1.15,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"pass","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-4GRDV7RFJZ","locator":{"ref":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5","row":4},"model":"M24c39354","observation_type":"phase_transition","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2008.01.092","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2008.01.092","paper_id":"doi:10.1016/j.jallcom.2008.01.092","phase_compositions":[{"basis":"mole_fraction","composition":{},"composition_source":"printed","composition_stored":{"PR":0.0},"phase":"γMn"},{"basis":"mole_fraction","composition":{},"composition_source":"stoichiometric_model_phase","composition_stored":{"PR":0.0},"phase":"βMn"}],"phases":[{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2008.01.092/p5/tab-5/r02#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"γMn -> βMn","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"MN-PR","system":"MN","temperature_K":1360.15,"temperature_printed":"1087","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Allotropic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1360.15},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn","βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectoid with 3 phases in a 1-component system ('δMn + γMn -> βMn')","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-DLNT5HLOVS","locator":{"ref":"doi:10.1361/105497199770335938/p8/tab-3","row":46},"model":"M87369021","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1361/105497199770335938","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1361/105497199770335938","paper_id":"doi:10.1361/105497199770335938","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.8918},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.9067},"composition_source":"printed","phase":"γMn"},{"basis":"mole_fraction","composition":{"MN":0.8981},"composition_source":"printed","phase":"βMn"}],"phases":[{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497199770335938/p8/tab-3/r46#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δMn + γMn -> βMn","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1346,"temperature_printed":"1346","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1346},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02646113","first_author":"Jansson","kind":"assessment","label":"92Jan","paper":"doi:10.1007/bf02646113","reference":"A. Jansson, Metall. Trans., Vol 23A, 1992, p 2953-2962","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn","βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectoid with 3 phases in a 1-component system ('δMn + γMn -> βMn')","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-AGQUJ5G6L6","locator":{"ref":"doi:10.1361/105497199770335938/p8/tab-3","row":47},"model":"Mf65a53ff","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/bf02646113","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1361/105497199770335938","paper_id":"doi:10.1361/105497199770335938","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.9029},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.913},"composition_source":"printed","phase":"γMn"},{"basis":"mole_fraction","composition":{"MN":0.9097},"composition_source":"printed","phase":"βMn"}],"phases":[{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497199770335938/p8/tab-3/r47#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δMn + γMn -> βMn","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1331,"temperature_printed":"1331","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1331},{"chemical_system":"MN","cited_sources":[{"first_author":"McAlster","kind":"assessment","label":"90Mca","reference":"A.J. McAlster and J.L. Murray, Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, P.R. Subramanian, H. Okamoto, and L. Kacprzak, Ed., ASM International, 1990, p 171-173","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn","βMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectoid with 3 phases in a 1-component system ('δMn + γMn -> βMn')","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-LU3B2O26PE","locator":{"ref":"doi:10.1361/105497199770335938/p8/tab-3","row":48},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"ref:4051979bc5796ef7","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1361/105497199770335938","paper_id":"doi:10.1361/105497199770335938","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.879},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.909},"composition_source":"printed","phase":"γMn"},{"basis":"mole_fraction","composition":{"MN":0.9},"composition_source":"printed","phase":"βMn"}],"phases":[{"label":"δMn","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"βMn","mapping_confidence":"confirmed","model_phase":"CUB_A13","pearson_symbol":"cP20","prototype":"beta-Mn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497199770335938/p8/tab-3/r48#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"δMn + γMn -> βMn","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1344,"temperature_printed":"1344","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1344},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":-36.0,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"fail","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-KPE5MNCJGC","locator":{"ref":"doi:10.1361/105497199770335938/p9/tab-3","row":6},"model":"M87369021","observation_type":"phase_transition","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1361/105497199770335938","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1361/105497199770335938","paper_id":"doi:10.1361/105497199770335938","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.9505},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.9505},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"δMn","mapping_confidence":"proposed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497199770335938/p9/tab-3/r06#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"δMn -> γMn","type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1323,"temperature_printed":"1323","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent transformation","transition_kind_printed":"Congruent point","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1323},{"chemical_system":"MN","cited_sources":[{"doi":"10.1007/bf02646113","first_author":"Jansson","kind":"assessment","label":"92Jan","paper":"doi:10.1007/bf02646113","reference":"A. Jansson, Metall. Trans., Vol 23A, 1992, p 2953-2962","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":-32.0,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"fail","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-23AJB5A7R6","locator":{"ref":"doi:10.1361/105497199770335938/p9/tab-3","row":7},"model":"Mf65a53ff","observation_type":"phase_transition","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/bf02646113","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1361/105497199770335938","paper_id":"doi:10.1361/105497199770335938","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.9425},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.9425},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"δMn","mapping_confidence":"proposed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497199770335938/p9/tab-3/r07#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"δMn -> γMn","type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1327,"temperature_printed":"1327","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent transformation","transition_kind_printed":"Congruent point","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1327},{"chemical_system":"MN","cited_sources":[{"first_author":"McAlster","kind":"assessment","label":"90Mca","reference":"A.J. McAlster and J.L. Murray, Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, P.R. Subramanian, H. Okamoto, and L. Kacprzak, Ed., ASM International, 1990, p 171-173","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"AL-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["δMn","γMn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pure MN transition temperatures","dT_K":-31.0,"model":"SGTE unary 5.0 (unary50_bengt.tdb)","result":"fail","tolerance":{"dT_K":25.0}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-USKO7GKZFI","locator":{"ref":"doi:10.1361/105497199770335938/p9/tab-3","row":8},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"phase_transition","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"ref:4051979bc5796ef7","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1361/105497199770335938","paper_id":"doi:10.1361/105497199770335938","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.94},"composition_source":"printed","phase":"δMn"},{"basis":"mole_fraction","composition":{"MN":0.94},"composition_source":"printed","phase":"γMn"}],"phases":[{"label":"δMn","mapping_confidence":"proposed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"γMn","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497199770335938/p9/tab-3/r08#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"δMn -> γMn","type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-MN","system":"MN","temperature_K":1328,"temperature_printed":"1328","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent transformation","transition_kind_printed":"Congruent point","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1328},{"chemical_system":"MN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"MN","before":"LA-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["(δMn)","(γMn)","Liquid"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.02,"dx":{"(γMn)":-0.1329},"fail_reason":"composition","model":"LaMn-12Wan.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-H3NNNG42QG","locator":{"ref":"doi:10.2298/jmmb120717049w/p4/tab-2","row":2},"model":"M075fa117","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.2298/jmmb120717049w","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.2298/jmmb120717049w","paper_id":"doi:10.2298/jmmb120717049w","phase_compositions":[{"basis":"mole_fraction","composition":{"MN":0.999},"composition_source":"printed","phase":"(δMn)"},{"basis":"mole_fraction","composition":{"MN":0.867},"composition_source":"printed","phase":"(γMn)"},{"basis":"mole_fraction","composition":{"MN":0.999},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"(δMn)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"(γMn)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"}],"pid":"doi:10.2298/jmmb120717049w/p4/tab-2/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(δMn) ↔ (γMn), Liquid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"LA-MN","system":"MN","temperature_K":1410.95,"temperature_printed":"1137.8","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1410.95},{"chemical_system":"MN","citations_printed":["8","9"],"cited_sources":[{"first_author":"Fernandez","kind":"unknown","label":"8","reference":"A. Fernández Guillermet and W. Huang: “Thermodynamic Analysis of Manganese,” Int. J. Thermophys., 1990, 11, pp. 949-69.","status":"resolved","year":"1990"},{"doi":"10.1016/0364-5916(91)90030-n","first_author":"Dinsdale","kind":"assessment","label":"9","paper":"doi:10.1016/0364-5916(91)90030-n","reference":"A.T. Dinsdale: “SGTE Data for Pure Elements,” Calphad, 1991, 15, pp. 317-425.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"MN-O","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["alpha-Mn","beta-Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","system_is_state_subsystem":true,"value_in_quote":true},"fold_lpo":2,"fold_lso":4,"id":"ORC-7ZBCJ5JB63.90ede1","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-003-0004-6/p1/text-06"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-003-0004-6","paper_id":"doi:10.1007/s11669-003-0004-6","phases":[{"label":"alpha-Mn"},{"label":"beta-Mn"}],"pid":"doi:10.1007/s11669-003-0004-6/p1/text-06/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Manganese exists in four modifications: ␣-Mn (up to 980 K), ␤-Mn (up to 1360 K), ␥-Mn (up to 1411 K), and ␦-Mn (up to the melting temperature of 1519 K).","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-O","system":"MN","temperature_K":980.0,"temperature_printed":"980 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":980.0},{"chemical_system":"MN","citations_printed":["8","9"],"cited_sources":[{"first_author":"Fernandez","kind":"unknown","label":"8","reference":"A. Fernández Guillermet and W. Huang: “Thermodynamic Analysis of Manganese,” Int. J. Thermophys., 1990, 11, pp. 949-69.","status":"resolved","year":"1990"},{"doi":"10.1016/0364-5916(91)90030-n","first_author":"Dinsdale","kind":"assessment","label":"9","paper":"doi:10.1016/0364-5916(91)90030-n","reference":"A.T. Dinsdale: “SGTE Data for Pure Elements,” Calphad, 1991, 15, pp. 317-425.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"MN-O","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["beta-Mn","gamma-Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","system_is_state_subsystem":true,"value_in_quote":true},"fold_lpo":2,"fold_lso":4,"id":"ORC-7ZBCJ5JB63.9687d4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-003-0004-6/p1/text-06"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-003-0004-6","paper_id":"doi:10.1007/s11669-003-0004-6","phases":[{"label":"beta-Mn"},{"label":"gamma-Mn"}],"pid":"doi:10.1007/s11669-003-0004-6/p1/text-06/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Manganese exists in four modifications: ␣-Mn (up to 980 K), ␤-Mn (up to 1360 K), ␥-Mn (up to 1411 K), and ␦-Mn (up to the melting temperature of 1519 K).","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-O","system":"MN","temperature_K":1360.0,"temperature_printed":"1360 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1360.0},{"chemical_system":"MN","citations_printed":["8","9"],"cited_sources":[{"first_author":"Fernandez","kind":"unknown","label":"8","reference":"A. Fernández Guillermet and W. Huang: “Thermodynamic Analysis of Manganese,” Int. J. Thermophys., 1990, 11, pp. 949-69.","status":"resolved","year":"1990"},{"doi":"10.1016/0364-5916(91)90030-n","first_author":"Dinsdale","kind":"assessment","label":"9","paper":"doi:10.1016/0364-5916(91)90030-n","reference":"A.T. Dinsdale: “SGTE Data for Pure Elements,” Calphad, 1991, 15, pp. 317-425.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"MN","before":"MN-O","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["gamma-Mn","delta-Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","system_is_state_subsystem":true,"value_in_quote":true},"fold_lpo":2,"fold_lso":4,"id":"ORC-7ZBCJ5JB63.9b7eb9","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-003-0004-6/p1/text-06"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-003-0004-6","paper_id":"doi:10.1007/s11669-003-0004-6","phases":[{"label":"gamma-Mn"},{"label":"delta-Mn"}],"pid":"doi:10.1007/s11669-003-0004-6/p1/text-06/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Manganese exists in four modifications: ␣-Mn (up to 980 K), ␤-Mn (up to 1360 K), ␥-Mn (up to 1411 K), and ␦-Mn (up to the melting temperature of 1519 K).","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"MN-O","system":"MN","temperature_K":1411.0,"temperature_printed":"1411 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1411.0},{"chemical_system":"MN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/0364-5916(89)90003-5"},"corrections":[{"after":"MN","before":"CO-MN","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["alpha-Mn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","system_is_state_subsystem":true,"value_in_quote":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-4LK2MJ6GLT","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(89)90003-5/p2/text-05"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/0364-5916(89)90003-5","own_work_of_paper":true},"paper":"doi:10.1016/0364-5916(89)90003-5","paper_id":"doi:10.1016/0364-5916(89)90003-5","phases":[{"label":"alpha-Mn"}],"pid":"doi:10.1016/0364-5916(89)90003-5/p2/text-05/s21#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The a-Mn is antiferromagnetic with TN= 95 K.","quote_page":2,"reaction":{"type":"magnetic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"CO-MN","system":"MN","temperature_K":95.0,"temperature_printed":"95 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"magnetic","transition_kind_printed":"magnetic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":95.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"MN"}