{"artifacts":{"doi:10.1016/j.jallcom.2013.11.094/p1/text-11":{"artifact":"text_passage","label":"page 1, passage 11","page":1},"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2":{"artifact":"table","caption":"Enthalpies of formation for the intermetallics involved in the Na–Te binary system (all in SI units).","label":"2","page":4},"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3":{"artifact":"table","caption":"Invariant reactions in the Na–Te system (all in SI units).","label":"3","page":4}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["NA","TE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M7eaca6a7":{"catalog_entry":{"license":"CC BY 4.0","name":"NaTe-14Che.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Y. Chen, Y. Liu, M. Chu, L. Wang, J. Alloys Compd., 588, 605-10(2014).","model_doi":"10.1016/j.jallcom.2013.11.094","reproduced_by_calculation":false,"tdb":"NaTe-14Che.tdb","tdb_path":"databases/sgte-binary/NaTe-14Che.tdb","tdb_sha256":"345a0a074cafc669931dd4287c8fab592be447108b75b5510ce532b185f26c9f"},"M866a77cb":{"catalog_entry":{"license":"CC BY 4.0","name":"NaTe-14Che.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"Y. Chen, Y. Liu, M. Chu, L. Wang, J. Alloys Compd., 588, 605-10(2014).","model_doi":"10.1016/j.jallcom.2013.11.094","tdb":"NaTe-14Che.tdb","tdb_path":"databases/sgte-binary/NaTe-14Che.tdb","tdb_sha256":"345a0a074cafc669931dd4287c8fab592be447108b75b5510ce532b185f26c9f"},"Maae6607c":{"catalog_entry":{"license":"CC BY 4.0","name":"NaTe-14Che.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Y. Chen, Y. Liu, M. Chu, L. Wang, J. Alloys Compd., 588, 605-10(2014).","model_doi":"10.1016/j.jallcom.2013.11.094","reproduced_by_calculation":true,"tdb":"NaTe-14Che.tdb","tdb_path":"databases/sgte-binary/NaTe-14Che.tdb","tdb_sha256":"345a0a074cafc669931dd4287c8fab592be447108b75b5510ce532b185f26c9f"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/bbpc.19890930105":{"authors":["Anthony Petric","Arthur D. Pelton","Marie‐Louise Saboungi"],"citation":"Anthony Petric, Arthur D. Pelton, Marie‐Louise Saboungi, Thermodynamic properties of molten Na‐Te solutions, Ber Bunsenges Phys Chem 93, 18-24 (1989).","container":"Ber Bunsenges Phys Chem","doi":"10.1002/bbpc.19890930105","doi_url":"https://doi.org/10.1002/bbpc.19890930105","id":"doi:10.1002/bbpc.19890930105","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermodynamic properties of molten Na‐Te solutions","year":1989},"doi:10.1016/j.jallcom.2013.11.094":{"authors":["Yang Chen","Yajun Liu","Maoyou Chu","Lijun Wang"],"citation":"Yang Chen, Yajun Liu, Maoyou Chu, Lijun Wang, Phase diagrams and thermodynamic descriptions for Na–Te and K–Te binary systems, Journal of Alloys and Compounds 588, 605-610 (2014).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2013.11.094","doi_url":"https://doi.org/10.1016/j.jallcom.2013.11.094","id":"doi:10.1016/j.jallcom.2013.11.094","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"c6bc933c800c6b20","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Phase diagrams and thermodynamic descriptions for Na–Te and K–Te binary systems","year":2014},"doi:10.1021/j150301a004":{"authors":["C. A. Kraus","S. W. Glass"],"citation":"C. A. Kraus, S. W. Glass, Liquid Mixtures of Tellurium and Sodium Telluride. I. Specific Resistance as a Function of Compostion and Temperature, J. Phys. Chem. 33, 984-994 (1929).","container":"J. Phys. Chem.","doi":"10.1021/j150301a004","doi_url":"https://doi.org/10.1021/j150301a004","id":"doi:10.1021/j150301a004","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Liquid Mixtures of Tellurium and Sodium Telluride. I. Specific Resistance as a Function of Compostion and Temperature","year":1929},"ref:79e0cc5a16a96cce":{"citation":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","id":"ref:79e0cc5a16a96cce","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1910}},"part":1,"parts":1,"records":[{"chemical_system":"NA-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["basis per formula unit (inferred)","state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-5X6PWFQ3DG.f0834d","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2","row":1},"merged_ids":["ORC-5X6PWFQ3DG.ad44eb"],"model":"M866a77cb","observation_type":"equilibrium_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2013.11.094","own_work_of_paper":true},"overall_composition":{"TE":0.333333},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phases":[{"label":"Na2Te"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpies of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NA":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"NA-TE","system":"NA-TE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":16.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.7,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"scaled_for_unstated_basis":3,"value":11.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-330.0,"value_printed":-330.0,"value_stored":-330000.0},{"chemical_system":"NA-TE","cited_sources":[{"first_author":"Morachevskii","kind":"unknown","label":"13","reference":"A.G. Morachevskii, E.A. Maiorova, N.M. Romanchenko, M.V. Kozlova, Zh. Prikl. Khim. 55 (3) (1982) 526.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["basis per formula unit (inferred)"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-35NFM3LGWI.b422b2","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2","row":2},"merged_ids":["ORC-35NFM3LGWI.e50d19"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"TE":0.333333},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phases":[{"label":"Na2Te"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpies of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NA":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"NA-TE","system":"NA-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":16.735},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":3,"value":10.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-334.7,"value_printed":-334.7,"value_stored":-334700.0},{"chemical_system":"NA-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-4LAJOTPUWU.7503a8","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2","row":3},"merged_ids":["ORC-4LAJOTPUWU.fbc5e0"],"model":"M866a77cb","observation_type":"equilibrium_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2013.11.094","own_work_of_paper":true},"overall_composition":{"TE":0.5},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phases":[{"label":"NaTe"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpies of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NA":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"NA-TE","system":"NA-TE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.75},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.8,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"scaled_for_unstated_basis":2,"value":7.8},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-175.0,"value_printed":-175.0,"value_stored":-175000.0},{"chemical_system":"NA-TE","cited_sources":[{"first_author":"Morachevskii","kind":"unknown","label":"13","reference":"A.G. Morachevskii, E.A. Maiorova, N.M. Romanchenko, M.V. Kozlova, Zh. Prikl. Khim. 55 (3) (1982) 526.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-OO6FMFVXP3.cb02b8","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2","row":4},"merged_ids":["ORC-OO6FMFVXP3.36b3fb"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"TE":0.5},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phases":[{"label":"NaTe"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpies of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NA":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"NA-TE","system":"NA-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.375},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-167.5,"value_printed":-167.5,"value_stored":-167500.0},{"chemical_system":"NA-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"id":"ORC-RU3TVFWBLE.8b916f","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2","row":5},"merged_ids":["ORC-RU3TVFWBLE.209bc7"],"model":"M866a77cb","observation_type":"equilibrium_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2013.11.094","own_work_of_paper":true},"overall_composition":{"TE":0.75},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phases":[{"label":"NaTe3"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpies of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NA":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"NA-TE","system":"NA-TE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":9.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":15.6,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"scaled_for_unstated_basis":4,"value":15.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-180.0,"value_printed":-180.0,"value_stored":-180000.0},{"chemical_system":"NA-TE","cited_sources":[{"first_author":"Morachevskii","kind":"unknown","label":"13","reference":"A.G. Morachevskii, E.A. Maiorova, N.M. Romanchenko, M.V. Kozlova, Zh. Prikl. Khim. 55 (3) (1982) 526.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-JPKWKV7D7J.9fab5f","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2","row":6},"merged_ids":["ORC-JPKWKV7D7J.e5337a"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"TE":0.75},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phases":[{"label":"NaTe3"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpies of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NA":{"phase":"BCC_A2"},"TE":{"phase":"HEXAGONAL_A8"}},"source_system":"NA-TE","system":"NA-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.37},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":14.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":4,"value":14.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-167.4,"value_printed":-167.4,"value_stored":-167400.0},{"chemical_system":"NA-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-77GSLBGDM6","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":1},"model":"M7eaca6a7","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2013.11.094","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.0001},"composition_source":"printed","phase":"Na"},{"basis":"mole_fraction","composition":{"TE":0.3333333333},"composition_source":"stoichiometry","phase":"Na2Te"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Na2Te","mapping_confidence":"confirmed","model_phase":"NA2TE_C1","pearson_symbol":"cF12","prototype":"CaF2","structure_basis":"mapped_model_phase"}],"phases_dropped":[{"label":"Na","reason":"not a phase (reaction / line / placeholder label)"}],"phases_stored":["liq","Na","Na2Te"],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> Na + Na2Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":370,"temperature_printed":"370","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":370},{"chemical_system":"NA-TE","cited_sources":[{"first_author":"Pellini","kind":"experimental","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-GXDS4XESA5","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:79e0cc5a16a96cce","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.0},"composition_source":"stoichiometric_model_phase","phase":"Na"},{"basis":"mole_fraction","composition":{"TE":0.3333333333},"composition_source":"stoichiometry","phase":"Na2Te"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Na2Te","mapping_confidence":"confirmed","model_phase":"NA2TE_C1","pearson_symbol":"cF12","prototype":"CaF2","structure_basis":"mapped_model_phase"}],"phases_dropped":[{"label":"Na","reason":"not a phase (reaction / line / placeholder label)"}],"phases_stored":["liq","Na","Na2Te"],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r02#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> Na + Na2Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":370.8,"temperature_printed":"370.8","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":370.8},{"chemical_system":"NA-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.274,"dx":{"liq":0.0129},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-BPFMLIXWCD","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":3},"model":"Maae6607c","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2013.11.094","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.53},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.3333333333},"composition_source":"stoichiometry","phase":"Na2Te"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Na2Te","mapping_confidence":"confirmed","model_phase":"NA2TE_C1","pearson_symbol":"cF12","prototype":"CaF2","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r03#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq + Na2Te -> NaTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":628,"temperature_printed":"628","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":628},{"chemical_system":"NA-TE","cited_sources":[{"first_author":"Pellini","kind":"experimental","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-7.274,"dx":{},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-PILYUS57G3","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:79e0cc5a16a96cce","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.3333333333},"composition_source":"stoichiometry","phase":"Na2Te"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Na2Te","mapping_confidence":"confirmed","model_phase":"NA2TE_C1","pearson_symbol":"cF12","prototype":"CaF2","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r04#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq + Na2Te -> NaTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":621,"temperature_printed":"621","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":621},{"chemical_system":"NA-TE","cited_sources":[{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"experimental","label":"9","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 995.","status":"resolved","year":"1929"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.274,"dx":{},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-2XI6LLN33J","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1021/j150301a004","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.3333333333},"composition_source":"stoichiometry","phase":"Na2Te"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Na2Te","mapping_confidence":"confirmed","model_phase":"NA2TE_C1","pearson_symbol":"cF12","prototype":"CaF2","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r05#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq + Na2Te -> NaTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":628,"temperature_printed":"628","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":628},{"chemical_system":"NA-TE","cited_sources":[{"doi":"10.1002/bbpc.19890930105","first_author":"Petric","kind":"experimental","label":"10","paper":"doi:10.1002/bbpc.19890930105","reference":"A. Petric, A.D. Pelton, Ber. Bunseges. Phys. Chem. 93 (1989) 18.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-6.274,"dx":{},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-W2456QYIK4","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1002/bbpc.19890930105","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.3333333333},"composition_source":"stoichiometry","phase":"Na2Te"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Na2Te","mapping_confidence":"confirmed","model_phase":"NA2TE_C1","pearson_symbol":"cF12","prototype":"CaF2","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r06#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq + Na2Te -> NaTe"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":622,"temperature_printed":"622","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":622},{"chemical_system":"NA-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-5.992,"dx":{"liq":0.0145},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-TPSVAQPATR","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":7},"model":"Maae6607c","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2013.11.094","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.58},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"stoichiometry","phase":"NaTe3"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NaTe3","mapping_confidence":"confirmed","model_phase":"NATE3","pearson_symbol":"hP48","prototype":"NaTe3","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r07#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> NaTe3 + NaTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":600,"temperature_printed":"600","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":600},{"chemical_system":"NA-TE","cited_sources":[{"first_author":"Pellini","kind":"experimental","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-15.992,"dx":{},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-AHSHBC6H2X","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:79e0cc5a16a96cce","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"stoichiometry","phase":"NaTe3"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NaTe3","mapping_confidence":"confirmed","model_phase":"NATE3","pearson_symbol":"hP48","prototype":"NaTe3","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r08#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> NaTe3 + NaTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":590,"temperature_printed":"590","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":590},{"chemical_system":"NA-TE","cited_sources":[{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"experimental","label":"9","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 995.","status":"resolved","year":"1929"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-13.992,"dx":{},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-BBCVKNYBIN","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":9},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1021/j150301a004","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"stoichiometry","phase":"NaTe3"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NaTe3","mapping_confidence":"confirmed","model_phase":"NATE3","pearson_symbol":"hP48","prototype":"NaTe3","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r09#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> NaTe3 + NaTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":592,"temperature_printed":"592","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":592},{"chemical_system":"NA-TE","cited_sources":[{"doi":"10.1002/bbpc.19890930105","first_author":"Petric","kind":"experimental","label":"10","paper":"doi:10.1002/bbpc.19890930105","reference":"A. Petric, A.D. Pelton, Ber. Bunseges. Phys. Chem. 93 (1989) 18.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-14.992,"dx":{},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-NSN6UL3NYA","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1002/bbpc.19890930105","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"stoichiometry","phase":"NaTe3"},{"basis":"mole_fraction","composition":{"TE":0.5},"composition_source":"stoichiometry","phase":"NaTe"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NaTe3","mapping_confidence":"confirmed","model_phase":"NATE3","pearson_symbol":"hP48","prototype":"NaTe3","structure_basis":"mapped_model_phase"},{"label":"NaTe","mapping_confidence":"confirmed","model_phase":"NATE","pearson_symbol":"oP48","prototype":"NaTe","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r10#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> NaTe3 + NaTe","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":591,"temperature_printed":"591","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":591},{"chemical_system":"NA-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-21.511,"dx":{"liq":-0.0177},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-TUHPNLZWHI","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":11},"model":"M7eaca6a7","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2013.11.094","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.87},"composition_source":"printed","phase":"liq"},{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"stoichiometry","phase":"NaTe3"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"stoichiometric_model_phase","phase":"Te"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NaTe3","mapping_confidence":"confirmed","model_phase":"NATE3","pearson_symbol":"hP48","prototype":"NaTe3","structure_basis":"mapped_model_phase"},{"label":"Te","mapping_confidence":"confirmed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r11#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> NaTe3 + Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":673,"temperature_printed":"673","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":673},{"chemical_system":"NA-TE","cited_sources":[{"first_author":"Pellini","kind":"experimental","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"},{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"experimental","label":"9","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 995.","status":"resolved","year":"1929"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-18.511,"dx":{},"model":"NaTe-14Che.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-W5Q7T3MLB3","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:79e0cc5a16a96cce","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phase_compositions":[{"basis":"mole_fraction","composition":{"TE":0.75},"composition_source":"stoichiometry","phase":"NaTe3"},{"basis":"mole_fraction","composition":{"TE":1.0},"composition_source":"stoichiometric_model_phase","phase":"Te"}],"phases":[{"label":"liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NaTe3","mapping_confidence":"confirmed","model_phase":"NATE3","pearson_symbol":"hP48","prototype":"NaTe3","structure_basis":"mapped_model_phase"},{"label":"Te","mapping_confidence":"confirmed","model_phase":"HEXAGONAL_A8","pearson_symbol":"hP3","prototype":"gamma-Se","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p4/tab-3/r12#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"liq -> NaTe3 + Te","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NA-TE","system":"NA-TE","temperature_K":676,"temperature_printed":"676","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":676},{"chemical_system":"NA-TE","citations_printed":["7","9"],"cited_sources":[{"first_author":"Pellini","kind":"unknown","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"},{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"unknown","label":"9","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 995.","status":"resolved","year":"1929"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ALVSKBJBYC","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"ref:79e0cc5a16a96cce","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature for the invariant reaction involving Na-Te melts, Te and NaTe3 was identified at 676 K by Pellini and Quercigh [7] and Kraus and Glass [9].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":676.0,"temperature_printed":"676 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":676.0},{"chemical_system":"NA-TE","citations_printed":["9"],"cited_sources":[{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"unknown","label":"9","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 995.","status":"resolved","year":"1929"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-E55RUDEPIH.21001a","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1021/j150301a004","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature for the invariant reaction involving Na-Te melts, NaTe and NaTe3 was identified at 590 K by Pellini and Quercigh [7], at 592 K by Kraus and Glass [9], and at 591 K by Petric and Pelton [10].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":592.0,"temperature_printed":"592 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":592.0},{"chemical_system":"NA-TE","citations_printed":["10"],"cited_sources":[{"doi":"10.1002/bbpc.19890930105","first_author":"Petric","kind":"unknown","label":"10","paper":"doi:10.1002/bbpc.19890930105","reference":"A. Petric, A.D. Pelton, Ber. Bunseges. Phys. Chem. 93 (1989) 18.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-E55RUDEPIH.4c3b11","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1002/bbpc.19890930105","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature for the invariant reaction involving Na-Te melts, NaTe and NaTe3 was identified at 590 K by Pellini and Quercigh [7], at 592 K by Kraus and Glass [9], and at 591 K by Petric and Pelton [10].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":591.0,"temperature_printed":"591 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":591.0},{"chemical_system":"NA-TE","citations_printed":["7"],"cited_sources":[{"first_author":"Pellini","kind":"unknown","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-E55RUDEPIH.7e511e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"ref:79e0cc5a16a96cce","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature for the invariant reaction involving Na-Te melts, NaTe and NaTe3 was identified at 590 K by Pellini and Quercigh [7], at 592 K by Kraus and Glass [9], and at 591 K by Petric and Pelton [10].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":590.0,"temperature_printed":"590 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":590.0},{"chemical_system":"NA-TE","citations_printed":["9"],"cited_sources":[{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"unknown","label":"9","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 995.","status":"resolved","year":"1929"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GB2GA4EIV5.0b6885","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1021/j150301a004","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The peritectic temperature for the invariant reaction involving Na-Te melts, Na2Te and NaTe was identified at 621 K by Pellini and Quercigh [7], 628 K by Kraus and Glass [9], and 622 K by Petric and Pelton [10].","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":628.0,"temperature_printed":"628 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":628.0},{"chemical_system":"NA-TE","citations_printed":["10"],"cited_sources":[{"doi":"10.1002/bbpc.19890930105","first_author":"Petric","kind":"unknown","label":"10","paper":"doi:10.1002/bbpc.19890930105","reference":"A. Petric, A.D. Pelton, Ber. Bunseges. Phys. Chem. 93 (1989) 18.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GB2GA4EIV5.b47e33","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1002/bbpc.19890930105","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The peritectic temperature for the invariant reaction involving Na-Te melts, Na2Te and NaTe was identified at 621 K by Pellini and Quercigh [7], 628 K by Kraus and Glass [9], and 622 K by Petric and Pelton [10].","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":622.0,"temperature_printed":"622 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":622.0},{"chemical_system":"NA-TE","citations_printed":["7"],"cited_sources":[{"first_author":"Pellini","kind":"unknown","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GB2GA4EIV5.c52e8c","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"ref:79e0cc5a16a96cce","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The peritectic temperature for the invariant reaction involving Na-Te melts, Na2Te and NaTe was identified at 621 K by Pellini and Quercigh [7], 628 K by Kraus and Glass [9], and 622 K by Petric and Pelton [10].","quote_page":1,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":621.0,"temperature_printed":"621 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":621.0},{"chemical_system":"NA-TE","citations_printed":["7"],"cited_sources":[{"first_author":"Pellini","kind":"unknown","label":"7","reference":"G. Pellini, E. Quercigh, Atti. Acad. Lincei. 19 (2) (1910) 350.","status":"resolved","year":"1910"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5QY22QNZ3Q","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"ref:79e0cc5a16a96cce","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature for the invariant reaction involving Na-Te melts, NaTe and bcc Na was identified at 370.8 K by Pellini and Quercigh [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":370.8,"temperature_printed":"370.8 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":370.8},{"chemical_system":"NA-TE","citations_printed":["8","9"],"cited_sources":[{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"unknown","label":"8","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 984.","status":"resolved","year":"1929"},{"doi":"10.1021/j150301a004","first_author":"Kraus","kind":"unknown","label":"9","paper":"doi:10.1021/j150301a004","reference":"C.A. Kraus, S.W. Glass, J. Phys. Chem. 33 (1929) 995.","status":"resolved","year":"1929"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-A2AMQCM5L4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11"},"method":"resistometry and thermal analysis","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1021/j150301a004","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2013.11.094","paper_id":"doi:10.1016/j.jallcom.2013.11.094","phases":[{"label":"NaTe3"}],"pid":"doi:10.1016/j.jallcom.2013.11.094/p1/text-11/s16#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"In addition, the congruent melting temperature of NaTe3 was reported to be 709 K with resistometric by Kraus and Glass [8] and thermal analysis by Kraus and Glass [9].","quote_page":1,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NA-TE","system":"NA-TE","temperature_K":709.0,"temperature_printed":"709 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":709.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"NA-TE"}