{"artifacts":{"doi:10.1016/j.jct.2017.04.003/p3/tab-1":{"artifact":"table","caption":"Summary of the crystal structures and lattice parameters in the Na-O system at (0.10 ± 0.01) MPa. RT = (295 ± 2) K.","label":"1","page":3},"sha256:152dffd3ba088bc9/p5/tab-1":{"artifact":"table","caption":"Enthalpy of formation for the NaSi and Ag 2 Na compounds and the crystal structures of the Na–X (X = Si, Ag) systems","label":"1","page":5},"sha256:7f95f07531b234dc/p3/tab-2":{"artifact":"table","caption":"The results of first-principle calculations comparing with experimental data","label":"2","page":3},"sha256:80942dc382901f3b/p2/tab-2":{"artifact":"table","caption":"Crystallographic data of solid phases in the Sr � X (X ¼ H, Li, Na, Sc) systems.","label":"2","page":2},"sha256:93322735d8bc2dbb/p3/tab-1":{"artifact":"table","caption":"Crystallographic data of the phases in the Ge–Na and Ge–K systems.","label":"1","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["NA"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02868307":{"authors":["H. W. King"],"citation":"H. W. King, Crystal structures of the elements at 25°C, Bulletin of Alloy Phase Diagrams 2, 401-402 (1981).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02868307","doi_url":"https://doi.org/10.1007/bf02868307","id":"doi:10.1007/bf02868307","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Crystal structures of the elements at 25°C","year":1981},"doi:10.1007/bf02874915":{"authors":["H. A. Wriedt"],"citation":"H. A. Wriedt, The Na−O (Sodium-Oxygen) System, Bulletin of Alloy Phase Diagrams 8, 234-246 (1987).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02874915","doi_url":"https://doi.org/10.1007/bf02874915","id":"doi:10.1007/bf02874915","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Na−O (Sodium-Oxygen) System","year":1987},"doi:10.1016/j.calphad.2012.01.004":{"authors":["Yaru Wang","Peisheng Wang","Dongdong Zhao","Biao Hu","Yong Du","Honghui Xu","Keke Chang"],"citation":"Yaru Wang, Peisheng Wang, Dongdong Zhao, Biao Hu, Yong Du, Honghui Xu et al., Thermodynamic description of the Ge–Na and Ge–K systems using the CALPHAD approach supported by first-principles calculations, Calphad 37, 72-76 (2012).","container":"Calphad","doi":"10.1016/j.calphad.2012.01.004","doi_url":"https://doi.org/10.1016/j.calphad.2012.01.004","id":"doi:10.1016/j.calphad.2012.01.004","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"93322735d8bc2dbb","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic description of the Ge–Na and Ge–K systems using the CALPHAD approach supported by first-principles calculations","year":2012},"doi:10.1016/j.calphad.2012.03.001":{"authors":["Chong Chen","Man Wang","Yong Du","Qiannan Gao","Biao Hu","Shuhong Liu"],"citation":"Chong Chen, Man Wang, Yong Du, Qiannan Gao, Biao Hu, Shuhong Liu, Thermodynamic modeling of the Sr–X (X=H, Li, Na, Sc) systems, Calphad 38, 17-22 (2012).","container":"Calphad","doi":"10.1016/j.calphad.2012.03.001","doi_url":"https://doi.org/10.1016/j.calphad.2012.03.001","id":"doi:10.1016/j.calphad.2012.03.001","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"80942dc382901f3b","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of the Sr–X (X=H, Li, Na, Sc) systems","year":2012},"doi:10.1016/j.jct.2017.04.003":{"authors":["A.L. Smith","C. Guéneau","J.-L. Flèche","S. Chatain","O. Beneš","R.J.M. Konings"],"citation":"A.L. Smith, C. Guéneau, J.-L. Flèche, S. Chatain, O. Beneš, R.J.M. Konings, Thermodynamic assessment of the Na-O and Na-U-O systems: Margin to the safe operation of SFRs, The Journal of Chemical Thermodynamics 114, 93-115 (2017).","container":"The Journal of Chemical Thermodynamics","doi":"10.1016/j.jct.2017.04.003","doi_url":"https://doi.org/10.1016/j.jct.2017.04.003","id":"doi:10.1016/j.jct.2017.04.003","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"34ea69372571cbf8","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Na-O and Na-U-O systems: Margin to the safe operation of SFRs","year":2017},"doi:10.1016/j.msea.2005.11.037":{"authors":["Shengjun Zhang","Carl Brubaker","Chao Jiang","Mei Yang","Yu Zhong","Qingyou Han","Zi-Kui Liu"],"citation":"Shengjun Zhang, Carl Brubaker, Chao Jiang, Mei Yang, Yu Zhong, Qingyou Han et al., A combined first-principles calculation and thermodynamic modeling of the F–K–Na system, Materials Science and Engineering: A 418, 161-171 (2006).","container":"Materials Science and Engineering: A","doi":"10.1016/j.msea.2005.11.037","doi_url":"https://doi.org/10.1016/j.msea.2005.11.037","id":"doi:10.1016/j.msea.2005.11.037","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"7f95f07531b234dc","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"A combined first-principles calculation and thermodynamic modeling of the F–K–Na system","year":2006},"doi:10.1103/physrev.136.a1141":{"authors":["George A. Sullivan","John W. Weymouth"],"citation":"George A. Sullivan, John W. Weymouth, Measurement of the Equilibrium Net Vacancy Concentration in Sodium, Phys. Rev. 136, A1141-A1148 (1964).","container":"Phys. Rev.","doi":"10.1103/physrev.136.a1141","doi_url":"https://doi.org/10.1103/physrev.136.a1141","id":"doi:10.1103/physrev.136.a1141","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Measurement of the Equilibrium Net Vacancy Concentration in Sodium","year":1964},"doi:10.2298/jmmb120113024h":{"authors":["D. Hao","M. Bu","Y. Wang","Y. Tang","Q. Gao","M. Wang","B. Hu","Y. Du"],"citation":"D. Hao, M. Bu, Y. Wang, Y. Tang, Q. Gao, M. Wang et al., Thermodynamic modeling of the Na-X (X = Si, Ag, Cu, Cr) systems, J min metall B Metall 48, 273-282 (2012).","container":"J min metall B Metall","doi":"10.2298/jmmb120113024h","doi_url":"https://doi.org/10.2298/jmmb120113024h","id":"doi:10.2298/jmmb120113024h","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"152dffd3ba088bc9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of the Na-X (X = Si, Ag, Cu, Cr) systems","year":2012}},"part":1,"parts":1,"records":[{"chemical_system":"NA","cited_sources":[{"doi":"10.1007/bf02874915","first_author":"Wriedt","kind":"assessment","label":"14","paper":"doi:10.1007/bf02874915","reference":"H.A. Wriedt, Bull. Alloy Phase Diagrams 8 (3) (1987) 234–246.","status":"resolved","year":"1987"},{"doi":"10.1103/physrev.136.a1141","first_author":"Sullivan","kind":"unknown","label":"15","paper":"doi:10.1103/physrev.136.a1141","reference":"G.A. Sullivan, J.W. Weymouth, Phys. Rev. A 136 (4) (1964) A1141–A1148.","status":"resolved","year":"1964"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"NA","before":"NA-O","evidence":{"basis":"phase_formula","overall_composition":{"O":0.0},"phases":["β-Na (bcc)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":4,"id":"ORC-YQTVPOBIJK","locator":{"ref":"doi:10.1016/j.jct.2017.04.003/p3/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"O":0.0},"paper":"doi:10.1016/j.jct.2017.04.003","paper_id":"doi:10.1016/j.jct.2017.04.003","phases":[{"label":"β-Na (bcc)"}],"pid":"doi:10.1016/j.jct.2017.04.003/p3/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NA-O","structure":{"space_group":"Im3̄m"},"system":"NA","temperature_K":295.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":2.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.00026},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009435,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009435},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.00026},"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.28865,"value_stored":0.428865},{"chemical_system":"NA","cited_sources":[{"first_author":"Barrett","kind":"unknown","label":"27","reference":"C.S. Barrett, Acta Cryst., 9 (1956) 671677.","status":"resolved","year":"1956"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"NA","before":"AG-NA-SI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"NA":1.0,"SI":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"Na","label_source":"printed_source_page","pearson_symbol":"cI2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Na | cI2 | Im-3m | 4.235 [27] / 4.203 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2],"table":"1","table_key":"t144"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Na rows","verdict":"confirmed"}},{"after":{"pearson_symbol":"cI2","phase":"Na","space_group":"Im-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Na | cI2 | Im-3m | 4.235 [27] / 4.203 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2],"table":"1","table_key":"t144"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Na rows","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-QYZBMMSRQU","locator":{"ref":"sha256:152dffd3ba088bc9/p5/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"NA":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"NA":1.0,"SI":0.0},"paper":"doi:10.2298/jmmb120113024h","paper_id":"doi:10.2298/jmmb120113024h","phases":[{"label":"Na","label_source":"printed_source_page","pearson_symbol":"cI2","structure_basis":"printed_source_page"}],"pid":"sha256:152dffd3ba088bc9/p5/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NA-SI","structure":{"pearson_symbol":"cI2","phase":"Na","space_group":"Im-3m"},"system":"NA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009317,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009317},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.235,"value_stored":4.235},{"chemical_system":"NA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"NA","before":"AG-NA-SI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"NA":1.0,"SI":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"Na","label_source":"printed_source_page","pearson_symbol":"cI2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Na | cI2 | Im-3m | 4.235 [27] / 4.203 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2],"table":"1","table_key":"t144"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Na rows","verdict":"confirmed"}},{"after":{"pearson_symbol":"cI2","phase":"Na","space_group":"Im-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Na | cI2 | Im-3m | 4.235 [27] / 4.203 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[1,2],"table":"1","table_key":"t144"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Na rows","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-J57M47N6KP","locator":{"ref":"sha256:152dffd3ba088bc9/p5/tab-1","row":2},"method":"first-principles calculation","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2298/jmmb120113024h","own_work_of_paper":true},"overall_composition":{"NA":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"NA":1.0,"SI":0.0},"paper":"doi:10.2298/jmmb120113024h","paper_id":"doi:10.2298/jmmb120113024h","phases":[{"label":"Na","label_source":"printed_source_page","pearson_symbol":"cI2","structure_basis":"printed_source_page"}],"pid":"sha256:152dffd3ba088bc9/p5/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NA-SI","structure":{"pearson_symbol":"cI2","phase":"Na","space_group":"Im-3m"},"system":"NA","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04203,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04203},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.203,"value_stored":4.203},{"chemical_system":"NA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"NA","before":"F-K-NA","evidence":{"basis":"printed_overall_composition","overall_composition":{"NA":1.0},"phases":["Na"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-H3EK2LLSVV.14359c","locator":{"ref":"sha256:7f95f07531b234dc/p3/tab-2","row":24},"merged_ids":["ORC-H3EK2LLSVV.6f0a42"],"method":"first-principle calculations","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.msea.2005.11.037","own_work_of_paper":true},"overall_composition":{"NA":1.0},"paper":"doi:10.1016/j.msea.2005.11.037","paper_id":"doi:10.1016/j.msea.2005.11.037","phases":[{"label":"Na"}],"pid":"sha256:7f95f07531b234dc/p3/tab-2/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NA":{"phase":"printed:none"}},"reference_state_stored":{"F":{"phase":"printed:none"},"K":{"phase":"printed:none"},"NA":{"phase":"printed:none"}},"source_system":"F-K-NA","system":"NA","temperature_K":293.0,"temperature_basis":"printed","temperature_printed":"293 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1e-09},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J/mol of atom","unit_stored":"J/mol-atom","value":0.0,"value_printed":0,"value_stored":0.0},{"chemical_system":"NA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"NA","before":"F-K-NA","evidence":{"basis":"printed_overall_composition","overall_composition":{"NA":1.0},"phases":["Na"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-J47T5NCK7A","locator":{"ref":"sha256:7f95f07531b234dc/p3/tab-2","row":24},"method":"first-principle calculations","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.msea.2005.11.037","own_work_of_paper":true},"overall_composition":{"NA":1.0},"paper":"doi:10.1016/j.msea.2005.11.037","paper_id":"doi:10.1016/j.msea.2005.11.037","phases":[{"label":"Na"}],"pid":"sha256:7f95f07531b234dc/p3/tab-2/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"Lattice constant a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"F-K-NA","system":"NA","temperature_K":293.0,"temperature_basis":"printed","temperature_printed":"293 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.20985},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04197,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04197},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_basis":"column_header","unit_printed":"Å","unit_stored":"Å","value":4.197,"value_printed":4.197,"value_stored":4.197},{"chemical_system":"NA","cited_sources":[{"first_author":"Aruja","kind":"unknown","label":"55","reference":"E. Aruja, H. Perlitz, Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem. 100 (1939) 195–200.","status":"resolved","year":"1939"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"NA","before":"F-K-NA","evidence":{"basis":"printed_overall_composition","overall_composition":{"NA":1.0},"phases":["Na"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":4,"id":"ORC-EDF5JHF7EI","locator":{"ref":"sha256:7f95f07531b234dc/p3/tab-2","row":25},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"NA":1.0},"paper":"doi:10.1016/j.msea.2005.11.037","paper_id":"doi:10.1016/j.msea.2005.11.037","phases":[{"label":"Na"}],"pid":"sha256:7f95f07531b234dc/p3/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"Lattice constant a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"F-K-NA","system":"NA","temperature_K":293.0,"temperature_basis":"printed","temperature_printed":"293 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00942,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00942},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.0005},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_basis":"column_header","unit_printed":"Å","unit_stored":"Å","value":4.282,"value_printed":4.282,"value_stored":4.282},{"chemical_system":"NA","cited_sources":[{"doi":"10.1007/bf02868307","first_author":"King","kind":"assessment","label":"45","paper":"doi:10.1007/bf02868307","reference":"H.W. King, Bull. Alloy Phase Diagrams 2 (3) (1981) 401–402.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"NA","before":"H-LI-NA-SC-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"LI":0.0,"NA":1.0,"SC":0.0,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"(Na)","label_source":"printed_source_page","pearson_symbol":"cI2","prototype":"W","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.calphad.2012.03.001","pdf_page":2,"pdf_sha256":"80942dc382901f3bff7533e073f4bd810bede342e09178cd834bd5955d5980c7","printed":"(Na) < 96.95 | cI2 / Im-3m / W | a = 0.42096 | 25 °C/[45]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3],"table":"2","table_key":"t152"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"1a78b8a89f130eda00258c1eb0c82329b2a5c73de6ca3f70b81e44efcc92a21d","page":2,"pdf_sha256_prefix":"80942dc382901f3b","seen":"(Na) block","verdict":"confirmed"}},{"after":{"pearson_symbol":"cI2","phase":"(Na)","prototype":"W","space_group":"Im-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.calphad.2012.03.001","pdf_page":2,"pdf_sha256":"80942dc382901f3bff7533e073f4bd810bede342e09178cd834bd5955d5980c7","printed":"(Na) < 96.95 | cI2 / Im-3m / W | a = 0.42096 | 25 °C/[45]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3],"table":"2","table_key":"t152"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"1a78b8a89f130eda00258c1eb0c82329b2a5c73de6ca3f70b81e44efcc92a21d","page":2,"pdf_sha256_prefix":"80942dc382901f3b","seen":"(Na) block","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":4,"id":"ORC-AO5YJDOC37","locator":{"ref":"sha256:80942dc382901f3b/p2/tab-2","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","measured_in":"doi:10.1007/bf02868307","own_work_of_paper":false},"overall_composition":{"NA":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.0,"NA":1.0,"SC":0.0,"SR":0.0},"paper":"doi:10.1016/j.calphad.2012.03.001","paper_id":"doi:10.1016/j.calphad.2012.03.001","phases":[{"label":"(Na)","label_source":"printed_source_page","pearson_symbol":"cI2","prototype":"W","structure_basis":"printed_source_page"}],"pid":"sha256:80942dc382901f3b/p2/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"H-LI-NA-SC-SR","structure":{"pearson_symbol":"cI2","phase":"(Na)","prototype":"W","space_group":"Im-3m"},"system":"NA","temperature_K":370.1,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","printed":"< 96.95","value_K":370.1},"temperature_printed":"< 96.95","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03241,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03241},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.2096,"value_stored":0.42096},{"chemical_system":"NA","cited_sources":[{"doi":"10.1007/bf02868307","first_author":"King","kind":"assessment","label":"30","paper":"doi:10.1007/bf02868307","reference":"H.W. King, Bull. Alloy Phase Diagrams 2 (1981) 401–402.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"NA","before":"GE-K-NA","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"K":0.0,"NA":1.0},"phases":["(Na)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-EW772AKOJP","locator":{"ref":"sha256:93322735d8bc2dbb/p3/tab-1","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","measured_in":"doi:10.1007/bf02868307","own_work_of_paper":false},"overall_composition":{"NA":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"K":0.0,"NA":1.0},"paper":"doi:10.1016/j.calphad.2012.01.004","paper_id":"doi:10.1016/j.calphad.2012.01.004","phases":[{"label":"(Na)"}],"pid":"sha256:93322735d8bc2dbb/p3/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-K-NA","structure":{"prototype":"W"},"system":"NA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03242,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03242},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.21,"value_stored":0.421},{"chemical_system":"NA","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"NA","before":"GE-K-NA","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"K":0.0,"NA":1.0},"phases":["(Na)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-SGAVFCHZHN","locator":{"ref":"sha256:93322735d8bc2dbb/p3/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2012.01.004","own_work_of_paper":true},"overall_composition":{"NA":1.0},"overall_composition_basis":"from_formula","overall_composition_stored":{"K":0.0,"NA":1.0},"paper":"doi:10.1016/j.calphad.2012.01.004","paper_id":"doi:10.1016/j.calphad.2012.01.004","phases":[{"label":"(Na)"}],"pid":"sha256:93322735d8bc2dbb/p3/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"GE-K-NA","structure":{"prototype":"W"},"system":"NA","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009306,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009306},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.23,"value_stored":0.423}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"NA"}