{"artifacts":{"doi:10.1007/s11669-007-9243-2/p5/tab-2":{"artifact":"table","caption":"Results of phase analysis of ternary Nb-Ni-Y alloys annealed at 750 °C for 24 h","label":"2","page":5},"doi:10.1007/s11669-007-9243-2/p5/tab-3":{"artifact":"table","caption":"Solubility of third element in binary phases and homogeneity range of solid solutions in the Nb-Ni- Y system as determined by EPMA after heat treatment for 24 h","label":"3","page":5},"doi:10.1007/s11669-007-9243-2/p6/tab-4":{"artifact":"table","caption":"Chemical compositions of the two immiscible liquids in alloy 17 (Ni 54.90 Nb 25.00 Y 20.10 ) as determined by EDX after levitation and quenching","label":"4","page":6},"doi:10.1007/s11669-007-9243-2/p7/tab-5":{"artifact":"table","caption":"Calculated temperatures (calc) and compositions of phases at the invariant equilibria in the Nb-Ni-Y system compared with experimental data (exp) of this work","label":"5","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1007/s11669-007-9243-2":{"context_id":"context:source-doi-10-1007-s11669-007-9243-2","items":[{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-H7MO3CYLRL","method":"electron probe x-ray microanalysis (EPMA) using wavelength-dispersive x-ray (WDX) spectroscopy for determination of solubilities as well as energy-dispersive (EDX) for chemical phase characterization","page":2,"quote":"The chemical composition of the individual phases was measured by electron probe x-ray microanalysis (EPMA) using wavelength-dispersive x-ray (WDX) spectroscopy for determination of solubilities as well as energy-dispersive (EDX) for chemical phase characterization.","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-M2SLZFISKF","instrument":"Philips XL30 (PHILIPS, Eindhoven, The Netherlands)","method":"scanning electron microscopy (SEM) in the backscattered electron (BSE) imaging mode","page":2,"quote":"The microstructure was analyzed by scanning electron microscopy (SEM) in the backscattered electron (BSE) imaging mode using a Philips XL30 (PHILIPS, Eindhoven, The Netherlands).","second_reader_agrees":false,"type":"measurement"},{"applies_to":"annealed samples","atmosphere":"argon atmosphere","extraction_accepted":true,"heating_or_cooling_rate":"20 K/min","id":"ORC-NGG6VMU5JI","instrument":"Netzsch DSC 404 (NETZSCH, Selb, Germany)","method":"Differential scanning calorimetry (DSC)","page":2,"quote":"Differential scanning calorimetry (DSC) studies of the annealed samples were done using a Netzsch DSC 404 (NETZSCH, Selb, Germany) at a heating rate of 20 K/min up to 1400 to 1500  C in an argon atmosphere.","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-UEHJ4WRUN6","instrument":"Panalytical XPERT'Pro Bragg-Brentano diffractometer (PANALYTICAL, Almelo, The Netherlands)","method":"X-ray diffraction analysis (XRD)","page":2,"quote":"X-ray diffraction analysis (XRD) was conducted with a Panalytical XPERT'Pro Bragg-Brentano diffractometer (PANALYTICAL, Almelo, The Netherlands) using Co Ka radiation and a diffracted beam graphite monochromator.","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-3FATHQKPKU","label":"Specimens of a selected composition","page":1,"quote":"Specimens of a selected composition (about 2 g) were heated in a levitation apparatus under high-purity argon atmosphere to temperatures above the liquidus.","second_reader_agrees":false,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-EQJ34CD343","label":"Ingots of the alloys","page":1,"purity":"99.9 wt.% Nb and 99.99 wt.% Ni and Y","quote":"Ingots of the alloys were melted from 99.9 wt.% Nb and 99.99 wt.% Ni and Y (Alfa Aesar) in an argon arc furnace, using a nonconsumable tungsten electrode on a watercooled copper hearth.","second_reader_agrees":true,"starting_materials":"99.9 wt.% Nb and 99.99 wt.% Ni and Y (Alfa Aesar)","type":"sample"},{"applies_to":"Three exact weights per samples close to 50 mg","duration":"15 min","duration_parsed":{"hours":0.25,"printed":"15 min"},"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-AIRZQKLPTQ","page":1,"quote":"Three exact weights per samples close to 50 mg were dissolved in 5 mL concentrated hydrochloric acid (Merck, p.a.) at 180  C for 15 min by microwave digestion (lPrep, MWS) using 100 mL Teflon vessels.","second_reader_agrees":false,"temperature":{"converted_in_code":false,"printed":"180  C"},"temperature_printed":"180  C","temperature_status":"unparsed","type":"treatment"},{"applies_to":"The ingots","atmosphere_or_container":"wrapped in tantalum foil, annealed at 750 to 1000  C for 24 h in sealed silica ampoules under 15 kPa purified Ar gas","cooling":"quenched into water","duration":"24 h","duration_parsed":{"hours":24.0,"printed":"24 h"},"extraction_accepted":true,"id":"ORC-PN7VEITDWP","page":1,"purpose":"annealed","quote":"The ingots were wrapped in tantalum foil, annealed at 750 to 1000  C for 24 h in sealed silica ampoules under 15 kPa purified Ar gas and then quenched into water.","second_reader_agrees":true,"temperature":{"converted_in_code":false,"printed":"750 to 1000  C"},"temperature_printed":"750 to 1000  C","temperature_status":"unparsed","type":"treatment"}],"paper":"doi:10.1007/s11669-007-9243-2","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"methods_heading"}},"elements":["NB","NI","Y"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s11669-007-9243-2":{"authors":["N. Mattern","M. Zinkevich","W. Löser","G. Behr","J. Acker"],"citation":"N. Mattern, M. Zinkevich, W. Löser, G. Behr, J. Acker, Experimental and Thermodynamic Assessment of the Nb-Ni-Y System, J Phs Eqil and Diff 29, 141-155 (2008).","container":"J Phs Eqil and Diff","doi":"10.1007/s11669-007-9243-2","doi_url":"https://doi.org/10.1007/s11669-007-9243-2","id":"doi:10.1007/s11669-007-9243-2","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"731be51d7878c2ba","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental and Thermodynamic Assessment of the Nb-Ni-Y System","year":2008}},"part":1,"parts":1,"records":[{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-E56G37LFAO","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":1},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0703,"NI":0.91,"Y":0.0197},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"(Ni)"},{"label":"Ni17Y2"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r01#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-TF4EW4GBOS","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":2},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0204,"NI":0.8835,"Y":0.0961},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"(Ni)"},{"label":"Ni17Y2"},{"label":"Ni5Y","model_phase":"NI5Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r02#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-52NZPUTW4B","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":3},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0992,"NI":0.8516,"Y":0.0492},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"(Ni)"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r03#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-JGZB3N3MOE","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":4},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0502,"NI":0.8529,"Y":0.0968},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"(Ni)"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r04#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-IYV6X7F4IY","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":5},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0999,"NI":0.8038,"Y":0.0963},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r05#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-ZZV75EIERB","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":6},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0497,"NI":0.8046,"Y":0.1457},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"Ni4Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r06#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-JBMSAHDWXR","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":7},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0477,"NI":0.7857,"Y":0.1666},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"Ni4Y"},{"label":"NbNi3(a)"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r07#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-CQXLUIF5NG","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":8},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.049,"NI":0.7666,"Y":0.1844},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni3Y"},{"label":"Ni7Y2"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r08#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-WKBYI7WSFD","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":9},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.125,"NI":0.75,"Y":0.125},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni3Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r09#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-HTGS7RNXVC","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":10},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0504,"NI":0.7268,"Y":0.2228},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni3Y"},{"label":"Ni2Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r10#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-ZQNU7G2NMQ","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":11},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.132,"NI":0.7177,"Y":0.1503},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r11#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-6IZXHACZPI","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":12},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.175,"NI":0.65,"Y":0.175},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NbNi3"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r12#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-NZD5FGRUT5","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":13},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.3493,"NI":0.6021,"Y":0.0486},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NbNi3"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r13#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-PXOBS7NFPJ","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":14},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.293,"NI":0.6022,"Y":0.1047},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NbNi3"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r14#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-M7EIYXEGNS","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":15},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.1959,"NI":0.608,"Y":0.1961},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r15#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-52MGYDUHX3","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":16},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.1003,"NI":0.6047,"Y":0.295},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NiY"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r16#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-6OAPJFHMBO","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":17},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.25,"NI":0.549,"Y":0.201},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NiY"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r17#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-ANIE45627P","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":18},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.3263,"NI":0.565,"Y":0.1087},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r18#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-HYBEIEYCSD","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":19},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.1872,"NI":0.5474,"Y":0.2653},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NiY"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r19#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-HCNQADIMAH","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":20},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.5435,"NI":0.4071,"Y":0.0494},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"μ","model_phase":"MU_PHASE"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r20#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-ELJ6JPO2BD","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":21},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.5312,"NI":0.3946,"Y":0.074},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r21#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-BHZZOARIAW","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":22},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.4668,"NI":0.4003,"Y":0.1329},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r22#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-MFOGMVLHXD","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":23},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.4,"NI":0.4,"Y":0.2},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"(Nb)"},{"label":"Ni2Y(a)"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"Ni2Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r23#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-ASG4H5DJRM","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":24},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.3034,"NI":0.409,"Y":0.2876},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"(Nb)"},{"label":"Ni2Y(a)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r24#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-DXRP2EBJIP","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":25},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.1994,"NI":0.4142,"Y":0.3864},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r25#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-XVK2UHKIYX","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":26},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.1772,"NI":0.4146,"Y":0.4082},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r26#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-I4CZLVHCSB","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":27},"method":"XRD, SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.0911,"NI":0.4112,"Y":0.4977},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"(Nb)"},{"label":"Ni2Y3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r27#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-55ZSIHS4DC","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":28},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.55,"NI":0.4,"Y":0.05},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"(Nb)"},{"label":"Ni2Y3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r28#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-5FICFBHRV6","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":29},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.35,"NI":0.6,"Y":0.05},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY3"},{"label":"(Nb)"},{"label":"Ni2Y3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r29#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-OIYT5OUCQ7","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":30},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.05,"NI":0.3,"Y":0.65},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY3"},{"label":"(Nb)"},{"label":"Ni2Y3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r30#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-AURMCTAAKC","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":31},"method":"XRD","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.05,"NI":0.2,"Y":0.75},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY3"},{"label":"(Nb)"},{"label":"(Y)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r31#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"xrd","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-RNVXBSGCL4","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":32},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NI":0.91},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"(Ni)"},{"label":"Ni17Y2"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r32#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-MIZ72RW6Z5","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":33},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.02,"NI":0.88,"Y":0.1},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"(Ni)"},{"label":"Ni17Y2"},{"label":"Ni5Y","model_phase":"NI5Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r33#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-JNXRYPSEEM","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":34},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.1,"NI":0.85,"Y":0.05},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"(Ni)"},{"label":"Ni5Y","model_phase":"NI5Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r34#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-VCRVEGVQ7H","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":35},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.1,"NI":0.8,"Y":0.1},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r35#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-BXLYR5RGE4","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":36},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.05,"NI":0.8,"Y":0.15},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"Ni4Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r36#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-2I7V5RDUJX","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":37},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.05,"NI":0.78,"Y":0.17},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"Ni4Y"},{"label":"NbNi3(a)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r37#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-ZSE6T5TEOS","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":38},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.05,"NI":0.76,"Y":0.19},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni3Y"},{"label":"Ni7Y2"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r38#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-KHJE5XYBJF","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":39},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.05,"NI":0.72,"Y":0.23},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni3Y"},{"label":"Ni2Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r39#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-4UPH3GIQ5W","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":40},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.15,"NI":0.7,"Y":0.15},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r40#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-TI4RSTDC2E","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":41},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.23,"NI":0.54,"Y":0.23},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"NiY"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r41#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-LVU5CMQ3II","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":42},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.4,"NI":0.5,"Y":0.1},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"Ni2Y"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r42#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-IYKM3KRF4K","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-2","row":43},"method":"XRD; SEM/EDX","method_basis":"printed in the table row/column","observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.45,"NI":0.4,"Y":0.15},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"NiY"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-2/r43#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1023.15,"temperature_basis":"printed","temperature_printed":"750 °C","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"metallography_microscopy","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-DRZK2DGVTN","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":1},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.0005},"composition_source":"printed","phase":"NbNi3"}],"phases":[{"label":"NbNi3"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"Ni2Y"},{"label":"Ni5Y","model_phase":"NI5Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1273.15,"temperature_basis":"printed","temperature_printed":"1000","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-DR26FFGTYY","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":2},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.0018},"composition_source":"printed","phase":"μ"}],"phases":[{"label":"μ","model_phase":"MU_PHASE"},{"label":"Ni2Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1273.15,"temperature_basis":"printed","temperature_printed":"1000","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-DGHWLLWRR3","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":3},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.002},"composition_source":"printed","phase":"Ni5Y"}],"phases":[{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"Ni4Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1273.15,"temperature_basis":"printed","temperature_printed":"1000","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-B7LJ4M6B6R","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":4},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.005},"composition_source":"printed","phase":"Ni3Y"}],"phases":[{"label":"Ni3Y"},{"label":"Ni7Y2"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1273.15,"temperature_basis":"printed","temperature_printed":"1000","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-PU36NJVJO2","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":5},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.001},"composition_source":"printed","phase":"Ni2Y"}],"phases":[{"label":"Ni2Y"},{"label":"NbNi3"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1073.15,"temperature_basis":"printed","temperature_printed":"800","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-55PLW4YGPP","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":6},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.0002},"composition_source":"printed","phase":"NiY"}],"phases":[{"label":"NiY"},{"label":"Ni2Y"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1073.15,"temperature_basis":"printed","temperature_printed":"800","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-77BVKLPLZW","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":7},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.0002},"composition_source":"printed","phase":"Ni2Y3"}],"phases":[{"label":"Ni2Y3"},{"label":"NiY"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1073.15,"temperature_basis":"printed","temperature_printed":"800","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-VDJVMATG7W","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":8},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.979,"NI":0.02,"Y":0.001},"composition_source":"printed","phase":"(Nb)"}],"phases":[{"label":"(Nb)"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"NiY"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1273.15,"temperature_basis":"printed","temperature_printed":"1000","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-3QUEKZAXN4","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p5/tab-3","row":9},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.083},"composition_source":"printed","phase":"(Ni)"}],"phases":[{"label":"(Ni)"},{"label":"Ni5Y","model_phase":"NI5Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p5/tab-3/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1273.15,"temperature_basis":"printed","temperature_printed":"1000","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-JEYB5OFW7B","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p6/tab-4","row":1},"method":"EDX","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.25,"NI":0.549,"Y":0.201},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.45,"NI":0.5,"Y":0.05},"composition_source":"printed","phase":"Liquid 1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.11,"NI":0.58,"Y":0.31},"composition_source":"printed","phase":"Liquid 2"}],"phases":[{"label":"Liquid 1","model_phase":"LIQUID"},{"label":"Liquid 2","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-007-9243-2/p6/tab-4/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1473.15,"temperature_basis":"printed","temperature_printed":"1200","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-GUKEHSNUNA","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p6/tab-4","row":2},"method":"EDX","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.25,"NI":0.549,"Y":0.201},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.43,"NI":0.5,"Y":0.07},"composition_source":"printed","phase":"Liquid 1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.13,"NI":0.58,"Y":0.29},"composition_source":"printed","phase":"Liquid 2"}],"phases":[{"label":"Liquid 1","model_phase":"LIQUID"},{"label":"Liquid 2","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-007-9243-2/p6/tab-4/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1573.15,"temperature_basis":"printed","temperature_printed":"1300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":1,"id":"ORC-ZJYUNB7MOG","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p6/tab-4","row":3},"method":"EDX","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"overall_composition":{"NB":0.25,"NI":0.549,"Y":0.201},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.4,"NI":0.5,"Y":0.1},"composition_source":"printed","phase":"Liquid 1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.17,"NI":0.58,"Y":0.25},"composition_source":"printed","phase":"Liquid 2"}],"phases":[{"label":"Liquid 1","model_phase":"LIQUID"},{"label":"Liquid 2","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11669-007-9243-2/p6/tab-4/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1673.15,"temperature_basis":"printed","temperature_printed":"1400","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-HMKL2F6346","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":1},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.063,"Y":0.054},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105},"composition_source":"printed","phase":"Ni17Y2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.167},"composition_source":"printed","phase":"Ni5Y"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.079,"Y":0.0},"composition_source":"printed","phase":"(Ni)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni17Y2"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U1: L + Ni17Y2 <-> Ni5Y + (Ni)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1520.15,"temperature_printed":"1247","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1520.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-L4IJBLBMJU","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction","composition":{"NB":0.0,"NI":0.833333,"Y":0.166667},"composition_source":"stoichiometric_model_phase","phase":"Ni5Y"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni17Y2"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U1: L + Ni17Y2 <-> Ni5Y + (Ni)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1529.15,"temperature_printed":"1256","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1529.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-RMMS5247YB","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.094,"Y":0.164},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.167},"composition_source":"printed","phase":"Ni5Y"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.25},"composition_source":"printed","phase":"NbNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.2},"composition_source":"printed","phase":"Ni4Y"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"NbNi3"},{"label":"Ni4Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U2: L + Ni5Y <-> NbNi3 + Ni4Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1507.15,"temperature_printed":"1234","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1507.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-6EXWK64QT3","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction","composition":{"NB":0.0,"NI":0.833333,"Y":0.166667},"composition_source":"stoichiometric_model_phase","phase":"Ni5Y"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"NbNi3"},{"label":"Ni4Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U2: L + Ni5Y <-> NbNi3 + Ni4Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1508.15,"temperature_printed":"1235","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1508.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-QMCZ6I2J34","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":5},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.084,"Y":0.193},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.2},"composition_source":"printed","phase":"Ni4Y"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.251},"composition_source":"printed","phase":"NbNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.222},"composition_source":"printed","phase":"Ni7Y2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni4Y"},{"label":"NbNi3"},{"label":"Ni7Y2"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U3: L + Ni4Y <-> NbNi3 + Ni7Y2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1477.15,"temperature_printed":"1204","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1477.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-BZFCEJB6G7","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni4Y"},{"label":"NbNi3"},{"label":"Ni7Y2"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U3: L + Ni4Y <-> NbNi3 + Ni7Y2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1464.15,"temperature_printed":"1191","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1464.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-DNZRB2JKJK","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":7},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.071,"Y":0.229},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.222},"composition_source":"printed","phase":"Ni7Y2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.251},"composition_source":"printed","phase":"NbNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25},"composition_source":"printed","phase":"Ni3Y"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Y2"},{"label":"NbNi3"},{"label":"Ni3Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U4: L + Ni7Y2 <-> NbNi3 + Ni3Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1435.15,"temperature_printed":"1162","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1435.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-XYSAB33PHD","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Y2"},{"label":"NbNi3"},{"label":"Ni3Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U4: L + Ni7Y2 <-> NbNi3 + Ni3Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1434.15,"temperature_printed":"1161","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1434.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-NV5AGSK5GG","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":9},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.04,"Y":0.307},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25},"composition_source":"printed","phase":"Ni3Y"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.253},"composition_source":"printed","phase":"NbNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333},"composition_source":"printed","phase":"Ni2Y"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Y"},{"label":"NbNi3"},{"label":"Ni2Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U5: L + Ni3Y <-> NbNi3 + Ni2Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1331.15,"temperature_printed":"1058","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1331.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-7WS7TEE4UH","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Y"},{"label":"NbNi3"},{"label":"Ni2Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U5: L + Ni3Y <-> NbNi3 + Ni2Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1336.15,"temperature_printed":"1063","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1336.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-E74KZV27OE","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":11},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.042,"Y":0.33},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.257},"composition_source":"printed","phase":"NbNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.489},"composition_source":"printed","phase":"μ"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333},"composition_source":"printed","phase":"Ni2Y"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NbNi3"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"Ni2Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U6: L + NbNi3 <-> μ + Ni2Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1299.15,"temperature_printed":"1026","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1299.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-BZA7VYJ6SB","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NbNi3"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"Ni2Y"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U6: L + NbNi3 <-> μ + Ni2Y","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1308.15,"temperature_printed":"1035","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1308.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-BN4NBKPNOX","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":13},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.012,"Y":0.444},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.969,"Y":0.0},"composition_source":"printed","phase":"(Nb)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.584},"composition_source":"printed","phase":"μ"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5},"composition_source":"printed","phase":"NiY"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"NiY"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U7: L + (Nb) <-> μ + NiY","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1294.15,"temperature_printed":"1021","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1294.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-GPBPRIWPCQ","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"NiY"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"U7: L + (Nb) <-> μ + NiY","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1281.15,"temperature_printed":"1008","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1281.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-WRTSLRZX4D","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":15},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.102,"Y":0.042},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.167},"composition_source":"printed","phase":"Ni5Y"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.11,"Y":0.0},"composition_source":"printed","phase":"(Ni)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.233},"composition_source":"printed","phase":"NbNi3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"E1: L <-> Ni5Y + (Ni) + NbNi3","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1500.15,"temperature_printed":"1227","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1500.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-RBIAPHMMS4","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction","composition":{"NB":0.0,"NI":0.833333,"Y":0.166667},"composition_source":"stoichiometric_model_phase","phase":"Ni5Y"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"E1: L <-> Ni5Y + (Ni) + NbNi3","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1497.15,"temperature_printed":"1224","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1497.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-3R5LDC66IC","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":17},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.011,"Y":0.41},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.532},"composition_source":"printed","phase":"μ"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333},"composition_source":"printed","phase":"Ni2Y"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5},"composition_source":"printed","phase":"NiY"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"Ni2Y"},{"label":"NiY"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"E2: L <-> μ + Ni2Y + NiY","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1209.15,"temperature_printed":"936","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1209.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-6S6CXVW4TA","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"μ","model_phase":"MU_PHASE"},{"label":"Ni2Y"},{"label":"NiY"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"E2: L <-> μ + Ni2Y + NiY","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1203.15,"temperature_printed":"930","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1203.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":0,"fold_lso":1,"id":"ORC-TLNGWY33SI","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":19},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.438,"Y":0.05},"composition_source":"printed","phase":"L'"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.115,"Y":0.31},"composition_source":"printed","phase":"L''"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.956,"Y":0.0},"composition_source":"printed","phase":"(Nb)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.596},"composition_source":"printed","phase":"μ"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.438,"Y":0.05},"composition_source":"printed","phase":"L′"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.115,"Y":0.31},"composition_source":"printed","phase":"L″"}],"phases":[{"label":"L'","model_phase":"LIQUID"},{"label":"L''","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"μ","model_phase":"MU_PHASE"}],"phases_dropped":[{"label":"L′","reason":"repeats phase 'L''"},{"label":"L″","reason":"repeats phase 'L'''"}],"phases_stored":["L'","L''","(Nb)","μ","L′","L″"],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"M1: L' + L'' + (Nb) <-> μ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1535.15,"temperature_printed":"1262","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1535.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-AWDLCHLR2K","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":20},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L'","model_phase":"LIQUID"},{"label":"L''","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"μ","model_phase":"MU_PHASE"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"M1: L' + L'' + (Nb) <-> μ","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1577.15,"temperature_printed":"1304","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1577.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-RZEKKOMBZR","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":21},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.0,"Y":0.729},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.999,"Y":0.0},"composition_source":"printed","phase":"(Nb)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.0,"Y":0.999},"composition_source":"printed","phase":"(Y)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.75},"composition_source":"printed","phase":"NiY3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"(Y)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"NiY3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"D1: L + (Nb) + (Y) <-> NiY3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1175.15,"temperature_printed":"902","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1175.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-AHJUIIDG7X","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":22},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"(Y)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"NiY3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"D1: L + (Nb) + (Y) <-> NiY3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1168.15,"temperature_printed":"895","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-DOSBM5R4RJ","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":23},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.0,"Y":0.648},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.998,"Y":0.0},"composition_source":"printed","phase":"(Nb)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.6},"composition_source":"printed","phase":"Ni2Y3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.75},"composition_source":"printed","phase":"NiY3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"Ni2Y3"},{"label":"NiY3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"D2: L + (Nb) <-> Ni2Y3 + NiY3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1078.15,"temperature_printed":"805","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1078.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-R3NA5SEBWT","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":24},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"Ni2Y3"},{"label":"NiY3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"D2: L + (Nb) <-> Ni2Y3 + NiY3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1075.15,"temperature_printed":"802","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1075.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-LU76DDTSW5","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":25},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.0,"Y":0.626},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.998,"Y":0.0},"composition_source":"printed","phase":"(Nb)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5},"composition_source":"printed","phase":"NiY"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.6},"composition_source":"printed","phase":"Ni2Y3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"NiY"},{"label":"Ni2Y3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"D3: L + (Nb) + NiY <-> Ni2Y3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1093.15,"temperature_printed":"820","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1093.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11669-007-9243-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-PIINDFEOLM","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":26},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Nb)"},{"label":"NiY"},{"label":"Ni2Y3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"D3: L + (Nb) + NiY <-> Ni2Y3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1082.15,"temperature_printed":"809","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1082.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-33LTQ3HCU2","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":27},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.118,"Y":0.079},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.167},"composition_source":"printed","phase":"Ni5Y"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.245},"composition_source":"printed","phase":"NbNi3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni5Y","model_phase":"NI5Y"},{"label":"NbNi3"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"e1(max): L <-> Ni5Y + NbNi3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1564.15,"temperature_printed":"1291","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"max","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1564.15},{"chemical_system":"NB-NI-Y","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":1,"id":"ORC-HELNDM7U5V","locator":{"ref":"doi:10.1007/s11669-007-9243-2/p7/tab-5","row":28},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: multicomponent TDB with 3 ternary parameters)","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-007-9243-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-007-9243-2","paper_id":"doi:10.1007/s11669-007-9243-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.006,"Y":0.505},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5},"composition_source":"printed","phase":"NiY"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NB":0.983,"Y":0.0},"composition_source":"printed","phase":"(Nb)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiY"},{"label":"(Nb)"}],"pid":"doi:10.1007/s11669-007-9243-2/p7/tab-5/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"e2(max): L <-> NiY + (Nb)","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NB-NI-Y","system":"NB-NI-Y","temperature_K":1332.15,"temperature_printed":"1059","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"max","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1332.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"NB-NI-Y"}