{"artifacts":{"doi:10.1007/s11669-022-01023-x/p17/text-05":{"artifact":"text_passage","label":"page 17, passage 5","page":17},"doi:10.1007/s11669-022-01023-x/p17/text-06":{"artifact":"text_passage","label":"page 17, passage 6","page":17},"doi:10.1007/s11669-022-01023-x/p20/text-86":{"artifact":"text_passage","label":"page 20, passage 86","page":20},"sha256:d348ad5cfcdd3fe6/p6/tab-1":{"artifact":"table","caption":"Crystal structure and lattice parameters data of the stable intermediate binary phases in Nd-Ru, Dy-Ru, and Gd-Ru binary systems","label":"1","page":6},"sha256:d348ad5cfcdd3fe6/p7/tab-2":{"artifact":"table","caption":"The comparison between the optimized, calculated, predicted, interpolated, and measured enthalpies, entropies, and Gibbs energies of formation of the thirteen solid compounds that exist in the Nd-Ru, Dy-Ru, and Gd-Ru systems","label":"2","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["ND","RU"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s11669-022-01023-x":{"authors":["S. Kardellass","V. P. Vassiliev","K. Mahdouk","N. Laaroussi","N. Selhaoui"],"citation":"S. Kardellass, V. P. Vassiliev, K. Mahdouk, N. Laaroussi, N. Selhaoui, Excess Thermodynamic Properties of Solutions in Ln-Ru (Ln = Nd, Gd, Dy) Binary Systems Based on Quadratic, Exponential and Combined Models Supported by Ab-Initio Calculations, J. Phase Equilib. Diffus. 44, 43-75 (2023).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-022-01023-x","doi_url":"https://doi.org/10.1007/s11669-022-01023-x","id":"doi:10.1007/s11669-022-01023-x","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"d348ad5cfcdd3fe6","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Excess Thermodynamic Properties of Solutions in Ln-Ru (Ln = Nd, Gd, Dy) Binary Systems Based on Quadratic, Exponential and Combined Models Supported by Ab-Initio Calculations","year":2023},"doi:10.1016/0022-5088(90)90186-n":{"authors":["A Palenzona","F Canepa"],"citation":"A Palenzona, F Canepa, The phase diagrams of the La-Ru and Nd-Ru systems, Journal of the Less Common Metals 157, 307-313 (1990).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(90)90186-n","doi_url":"https://doi.org/10.1016/0022-5088(90)90186-n","id":"doi:10.1016/0022-5088(90)90186-n","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The phase diagrams of the La-Ru and Nd-Ru systems","year":1990},"doi:10.1016/j.cplett.2007.06.031":{"authors":["R.F. Zhang","S.H. Sheng","B.X. Liu"],"citation":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chemical Physics Letters 442, 511-514 (2007).","container":"Chemical Physics Letters","doi":"10.1016/j.cplett.2007.06.031","doi_url":"https://doi.org/10.1016/j.cplett.2007.06.031","id":"doi:10.1016/j.cplett.2007.06.031","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Predicting the formation enthalpies of binary intermetallic compounds","year":2007},"doi:10.1038/npjcompumats.2015.10":{"authors":["Scott Kirklin","James E Saal","Bryce Meredig","Alex Thompson","Jeff W Doak","Muratahan Aykol","Stephan Rühl","Chris Wolverton"],"citation":"Scott Kirklin, James E Saal, Bryce Meredig, Alex Thompson, Jeff W Doak, Muratahan Aykol et al., The Open Quantum Materials Database (OQMD): assessing the accuracy of DFT formation energies, npj Comput Mater 1 (2015).","container":"npj Comput Mater","doi":"10.1038/npjcompumats.2015.10","doi_url":"https://doi.org/10.1038/npjcompumats.2015.10","id":"doi:10.1038/npjcompumats.2015.10","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Open Quantum Materials Database (OQMD): assessing the accuracy of DFT formation energies","year":2015},"doi:10.1063/1.4812323":{"authors":["Anubhav Jain","Shyue Ping Ong","Geoffroy Hautier","Wei Chen","William Davidson Richards","Stephen Dacek","Shreyas Cholia","Dan Gunter","David Skinner","Gerbrand Ceder","Kristin A. Persson"],"citation":"Anubhav Jain, Shyue Ping Ong, Geoffroy Hautier, Wei Chen, William Davidson Richards, Stephen Dacek et al., Commentary: The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013).","container":"APL Materials","doi":"10.1063/1.4812323","doi_url":"https://doi.org/10.1063/1.4812323","id":"doi:10.1063/1.4812323","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Commentary: The Materials Project: A materials genome approach to accelerating materials innovation","year":2013},"doi:10.2478/amm-2014-0228":{"authors":["A. Debski","R. Debski","W. Gasior"],"citation":"A. Debski, R. Debski, W. Gasior, New Features of Entall Database: Comparison of Experimental and Model Formation Enthalpies/ Nowe Funkcje Bazy Danych Entall: Porównanie Doświadczalnych I Modelowych Entalpii Tworzenia, Archives of Metallurgy and Materials 59, 1337-1343 (2014).","container":"Archives of Metallurgy and Materials","doi":"10.2478/amm-2014-0228","doi_url":"https://doi.org/10.2478/amm-2014-0228","id":"doi:10.2478/amm-2014-0228","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"New Features of Entall Database: Comparison of Experimental and Model Formation Enthalpies/ Nowe Funkcje Bazy Danych Entall: Porównanie Doświadczalnych I Modelowych Entalpii Tworzenia","year":2014}},"part":1,"parts":1,"records":[{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-S6UUVVQFYE.14ca80","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd3Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01409,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01409},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.406,"value_stored":0.6406},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-S6UUVVQFYE.7a6c89","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd3Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02129,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02129},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.675,"value_stored":0.9675},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-S6UUVVQFYE.b33c09","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd3Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01618,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01618},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.355,"value_stored":0.7355},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-IGI7O3VU7V.4ea0d6","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02124,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02124},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.655,"value_stored":0.9655},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-IGI7O3VU7V.7a3742","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01617,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01617},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.349,"value_stored":0.7349},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-IGI7O3VU7V.92b50f","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01408,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01408},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.399,"value_stored":0.6399},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-AWDAP6CBFZ.41b2ad","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02123,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02123},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.65,"value_stored":0.965},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-AWDAP6CBFZ.79a676","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01619,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01619},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.359,"value_stored":0.7359},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-AWDAP6CBFZ.9d4d76","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01419,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01419},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.448,"value_stored":0.6448},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-NMTNPKTA5N.0c6f10","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02123,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02123},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.649,"value_stored":0.9649},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-NMTNPKTA5N.423d4b","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01618,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01618},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.353,"value_stored":0.7353},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.25},"phases":["Nd₃Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-NMTNPKTA5N.4627cf","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.25},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.25},"composition_source":"printed","phase":"Nd₃Ru"}],"phases":[{"label":"Nd₃Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP16"},"system":"ND-RU","temperature_K":880.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":880.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01409,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01409},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.406,"value_stored":0.6406},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-PEUGKWZEY4.4c28e5","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd5Ru2"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":96.67},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-PEUGKWZEY4.69868e","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd5Ru2"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01615,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01615},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.342,"value_stored":0.7342},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-PEUGKWZEY4.db5098","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd5Ru2"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01432,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01432},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.509,"value_stored":0.6509},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-PEUGKWZEY4.ec7579","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd5Ru2"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03585,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03585},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":16.295,"value_stored":1.6295},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-N7OX4Q2HHB.102436","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":96.66},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-N7OX4Q2HHB.698391","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01431,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01431},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.505,"value_stored":0.6505},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-N7OX4Q2HHB.a47e1a","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03584,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03584},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":16.289,"value_stored":1.6289},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-N7OX4Q2HHB.ef403a","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01615,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01615},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.339,"value_stored":0.7339},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-YHIQLJPHB5.499f01","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01613,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01613},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.33,"value_stored":0.733},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-YHIQLJPHB5.4ee4ce","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":96.63},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-YHIQLJPHB5.70f939","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03584,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03584},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":16.29,"value_stored":1.629},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.286},"phases":["Nd₅Ru₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-YHIQLJPHB5.b5217e","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.286},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.286},"composition_source":"printed","phase":"Nd₅Ru₂"}],"phases":[{"label":"Nd₅Ru₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"mC28"},"system":"ND-RU","temperature_K":915.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":915.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01431,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01431},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.503,"value_stored":0.6503},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.3},"phases":["Nd₇Ru₃"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-O6S5FINSI5.cea308","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.3},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.3},"composition_source":"printed","phase":"Nd₇Ru₃"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.3},"composition_source":"printed","phase":"Nd7Ru3"}],"phases":[{"label":"Nd₇Ru₃"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP40"},"system":"ND-RU","temperature_K":890.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":890.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01437,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01437},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.532,"value_stored":0.6532},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.3},"phases":["Nd₇Ru₃"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-O6S5FINSI5.ea3f93","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.3},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.3},"composition_source":"printed","phase":"Nd₇Ru₃"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.3},"composition_source":"printed","phase":"Nd7Ru3"}],"phases":[{"label":"Nd₇Ru₃"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP40"},"system":"ND-RU","temperature_K":890.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":890.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05023,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.05023},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":22.83,"value_stored":2.283},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.3},"phases":["Nd₇Ru₃"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-O6S5FINSI5.f48272","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.3},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.3},"composition_source":"printed","phase":"Nd₇Ru₃"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.3},"composition_source":"printed","phase":"Nd7Ru3"}],"phases":[{"label":"Nd₇Ru₃"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"oP40"},"system":"ND-RU","temperature_K":890.0,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","value_K":890.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01607,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01607},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.303,"value_stored":0.7303},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-KU3OPZ7LZ4","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu2"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01675,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01675},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.614,"value_stored":0.7614},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-M46K4VX54E","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01675,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01675},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.612,"value_stored":0.7612},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-OZEBXMAL22","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0168,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0168},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.637,"value_stored":0.7637},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-SVG3KXYBZR.fd8ea5","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01171,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01171},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.323,"value_stored":0.5323},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-SVG3KXYBZR.fee828","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01981,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01981},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.004,"value_stored":0.9004},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-7CI6CJWOQA","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01674,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01674},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.608,"value_stored":0.7608},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-OTZ7BM5JIF.978a04","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0197,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0197},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.955,"value_stored":0.8955},{"chemical_system":"ND-RU","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"ND-RU","before":"DY-GD-ND-RU","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"RU":0.667},"phases":["NdRu₂"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-OTZ7BM5JIF.c35bdf","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p6/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"RU":0.667},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"RU":0.667},"composition_source":"printed","phase":"NdRu₂"}],"phases":[{"label":"NdRu₂"}],"pid":"sha256:d348ad5cfcdd3fe6/p6/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"DY-GD-ND-RU","structure":{"pearson_symbol":"cF24","strukturbericht":"C15"},"system":"ND-RU","temperature_K":1600.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":1600.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01164,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01164},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.293,"value_stored":0.5293},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":1000.0,"before":null,"evidence":{"printed":"ΔGf at 1000 K"},"field":"temperature_K","gate":"R2","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"4ba20fceda43c7b536b1400d64d6bed2370f7207ae327fa75df578f8c219187f","page":3,"pdf_sha256_prefix":"5e3db49d7b0a901d","seen":"A quantity whose printed label names its temperature (e.g. 'G^ex_Li (633 K)', 'ΔGf at 1000 K') takes that temperature when the record has none.","verdict":"rule_confirmed"}},{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-WX5DFUPIPY.0898db","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":2},"merged_ids":["ORC-WX5DFUPIPY.0ebb95"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf at 1000 K","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":1000.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.6929},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-13.858,"value_printed":-13.858,"value_stored":-13858.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-WX5DFUPIPY.23dcd4","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":2},"merged_ids":["ORC-WX5DFUPIPY.b4421a"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0611},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-1.222,"value_printed":-1.222},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-WX5DFUPIPY.99c478","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":2},"merged_ids":["ORC-WX5DFUPIPY.dcc17f"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.754},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-15.08,"value_printed":-15.08,"value_stored":-15080.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":1000.0,"before":null,"evidence":{"printed":"ΔGf at 1000 K"},"field":"temperature_K","gate":"R2","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"4ba20fceda43c7b536b1400d64d6bed2370f7207ae327fa75df578f8c219187f","page":3,"pdf_sha256_prefix":"5e3db49d7b0a901d","seen":"A quantity whose printed label names its temperature (e.g. 'G^ex_Li (633 K)', 'ΔGf at 1000 K') takes that temperature when the record has none.","verdict":"rule_confirmed"}},{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-LHSZRAXCWX.00c27c","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":3},"merged_ids":["ORC-LHSZRAXCWX.60c959"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf at 1000 K","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":1000.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.75905},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-15.181,"value_printed":-15.181,"value_stored":-15181.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-LHSZRAXCWX.1c5848","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":3},"merged_ids":["ORC-LHSZRAXCWX.e93036"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0001},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-0.002,"value_printed":-0.002},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-LHSZRAXCWX.371224","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":3},"merged_ids":["ORC-LHSZRAXCWX.ca756a"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.75915},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-15.183,"value_printed":-15.183,"value_stored":-15183.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-IGWVCPNB7T.10731e","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":4},"merged_ids":["ORC-IGWVCPNB7T.353dac"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.8487},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-16.974,"value_printed":-16.974,"value_stored":-16974.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-IGWVCPNB7T.125a71","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":4},"merged_ids":["ORC-IGWVCPNB7T.9b83d4"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.10115},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-2.023,"value_printed":-2.023},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":1000.0,"before":null,"evidence":{"printed":"ΔGf at 1000 K"},"field":"temperature_K","gate":"R2","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"4ba20fceda43c7b536b1400d64d6bed2370f7207ae327fa75df578f8c219187f","page":3,"pdf_sha256_prefix":"5e3db49d7b0a901d","seen":"A quantity whose printed label names its temperature (e.g. 'G^ex_Li (633 K)', 'ΔGf at 1000 K') takes that temperature when the record has none.","verdict":"rule_confirmed"}},{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-IGWVCPNB7T.5a2804","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":4},"merged_ids":["ORC-IGWVCPNB7T.be8dd5"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf at 1000 K","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":1000.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.7475},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-14.95,"value_printed":-14.95,"value_stored":-14950.0},{"chemical_system":"ND-RU","cited_sources":[{"doi":"10.2478/amm-2014-0228","first_author":"Debski","kind":"unknown","label":"39","paper":"doi:10.2478/amm-2014-0228","reference":"A. Debski, R. Debski, and W. Gasior, New Features of Entall Database: Comparison of Experimental and Model Formation Enthalpies, Arch. Metall. Mater., 2014, 59, p 1337–1343. https:// doi.org/10.2478/amm-2014-0228","status":"resolved","year":"2014"},{"kind":"unknown","label":"40","reference":"F.R. de Boer, R. Boom, W.C.M. Mattens, A.R. Miedema, and A.K. Niessen, Cohesion in metals. Transition metal alloys. NorthHolland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-DJAED4AUNY.07df5d","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":5},"merged_ids":["ORC-DJAED4AUNY.c116ea"],"method":"Miedema's model","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.25475},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-25.095,"value_printed":-25.095,"value_stored":-25095.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-6KFE7FLSRE.26bf19","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":6},"merged_ids":["ORC-6KFE7FLSRE.638411"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.07255},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-21.451,"value_printed":-21.451,"value_stored":-21451.0},{"chemical_system":"ND-RU","cited_sources":[{"doi":"10.1063/1.4812323","first_author":"Jain","kind":"unknown","label":"41","paper":"doi:10.1063/1.4812323","reference":"A. Jain, S.P. Ong, G. Hautier, W. Chen, W.D. Richards, S. Dacek, S. Cholia, D. Gunter, D. Skinner, G. Ceder, and K.A. Persson, Commentary: The Materials Project: A Materials Genome Approach to Accelerating Materials Innovation, APL Mater., 2013, 1, p 011002. https://doi.org/10.1063/1.4812323","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Nd3Ru'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-2KBA7NMGGX.1f473d","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":7},"merged_ids":["ORC-2KBA7NMGGX.442e8c"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"DHCP"},"RU":{"phase":"HCP_A3"}},"reference_state_stored":{"DY":{"phase":"HCP_A3"},"GD":{"phase":"HCP_A3"},"LA":{"phase":"DHCP"},"ND":{"phase":"DHCP"},"RU":{"phase":"HCP_A3"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation documented by the database)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9395},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-18.79,"value_printed":-18.79,"value_stored":-18790.0},{"chemical_system":"ND-RU","cited_sources":[{"doi":"10.1038/npjcompumats.2015.10","first_author":"Kirklin","kind":"unknown","label":"42","paper":"doi:10.1038/npjcompumats.2015.10","reference":"S. Kirklin, J.E. Saal, B. Meredig, A. Thompson, J.W. Doak, M. Aykol, S. Rühl, and C. Wolverton, The Open Quantum Materials Database (OQMD): Assessing the Accuracy of DFT Formation Energies, npj Comput. Mater., 2015. https://doi.org/10.1038/ npjcompumats.2015.10","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Nd3Ru'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-N2B42IOD2X.1ce4aa","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":8},"merged_ids":["ORC-N2B42IOD2X.cc8965"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"DHCP"},"RU":{"phase":"HCP_A3"}},"reference_state_stored":{"DY":{"phase":"HCP_A3"},"GD":{"phase":"HCP_A3"},"LA":{"phase":"DHCP"},"ND":{"phase":"DHCP"},"RU":{"phase":"HCP_A3"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation documented by the database)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.90585},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-18.117,"value_printed":-18.117,"value_stored":-18117.0},{"chemical_system":"ND-RU","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"unknown","label":"43","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, and B.X. Liu, Predicting the Formation Enthalpies of Binary Intermetallic Compounds, Chem. Phys. Lett., 2007, 442, p 511–514. https://doi.org/10.1016/j.cplett.2007. 06.031","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd3Ru","max_deviation":0.25},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.75,"RU":0.25},"phases":["Nd3Ru"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-CADCX3EABU.48d977","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":9},"merged_ids":["ORC-CADCX3EABU.6f7a0e"],"method":"Modified Miedema's model","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ND":0.75,"RU":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd3Ru"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.0923},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-21.846,"value_printed":-21.846,"value_stored":-21846.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-FGT3TZSBNU.2fedd0","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":24},"merged_ids":["ORC-FGT3TZSBNU.984bb1"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.7559},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-15.118,"value_printed":-15.118,"value_stored":-15118.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":1000.0,"before":null,"evidence":{"printed":"ΔGf at 1000 K"},"field":"temperature_K","gate":"R2","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"4ba20fceda43c7b536b1400d64d6bed2370f7207ae327fa75df578f8c219187f","page":3,"pdf_sha256_prefix":"5e3db49d7b0a901d","seen":"A quantity whose printed label names its temperature (e.g. 'G^ex_Li (633 K)', 'ΔGf at 1000 K') takes that temperature when the record has none.","verdict":"rule_confirmed"}},{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-FGT3TZSBNU.916415","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":24},"merged_ids":["ORC-FGT3TZSBNU.ed2c88"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf at 1000 K","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":1000.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.7497},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-14.994,"value_printed":-14.994,"value_stored":-14994.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-FGT3TZSBNU.a5e9e3","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":24},"merged_ids":["ORC-FGT3TZSBNU.db2d12"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0062},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-0.124,"value_printed":-0.124},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-MJK6GE3LIG.047909","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":25},"merged_ids":["ORC-MJK6GE3LIG.637d38"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.006},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-0.12,"value_printed":-0.12},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-MJK6GE3LIG.174009","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":25},"merged_ids":["ORC-MJK6GE3LIG.7abbb5"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.81055},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-16.211,"value_printed":-16.211,"value_stored":-16211.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-MJK6GE3LIG.69cdf3","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":25},"merged_ids":["ORC-MJK6GE3LIG.c1732c"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.81655},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-16.331,"value_printed":-16.331,"value_stored":-16331.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-ZACHWUXVFU.03678b","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":26},"merged_ids":["ORC-ZACHWUXVFU.f945eb"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0686},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-1.372,"value_printed":-1.372},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-ZACHWUXVFU.053dbf","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":26},"merged_ids":["ORC-ZACHWUXVFU.061790"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.80785},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-16.157,"value_printed":-16.157,"value_stored":-16157.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-ZACHWUXVFU.05a500","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":26},"merged_ids":["ORC-ZACHWUXVFU.f2656f"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.87645},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-17.529,"value_printed":-17.529,"value_stored":-17529.0},{"chemical_system":"ND-RU","cited_sources":[{"doi":"10.2478/amm-2014-0228","first_author":"Debski","kind":"unknown","label":"39","paper":"doi:10.2478/amm-2014-0228","reference":"A. Debski, R. Debski, and W. Gasior, New Features of Entall Database: Comparison of Experimental and Model Formation Enthalpies, Arch. Metall. Mater., 2014, 59, p 1337–1343. https:// doi.org/10.2478/amm-2014-0228","status":"resolved","year":"2014"},{"kind":"unknown","label":"40","reference":"F.R. de Boer, R. Boom, W.C.M. Mattens, A.R. Miedema, and A.K. Niessen, Cohesion in metals. Transition metal alloys. NorthHolland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-ORQDUTCGW5.1cbaa7","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":27},"merged_ids":["ORC-ORQDUTCGW5.9f1466"],"method":"Miedema's model","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.50905},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-30.181,"value_printed":-30.181,"value_stored":-30181.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-6VRM73R4HH.54c6e6","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":28},"merged_ids":["ORC-6VRM73R4HH.df8ec5"],"method":"Ab-initio (Magnetic)","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r28#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.25725},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-25.145,"value_printed":-25.145,"value_stored":-25145.0},{"chemical_system":"ND-RU","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"unknown","label":"43","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, and B.X. Liu, Predicting the Formation Enthalpies of Binary Intermetallic Compounds, Chem. Phys. Lett., 2007, 442, p 511–514. https://doi.org/10.1016/j.cplett.2007. 06.031","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"Nd7Ru3","max_deviation":0.3},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.7,"RU":0.3},"phases":["Nd7Ru3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-W47AKPSOOM.11e230","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":29},"merged_ids":["ORC-W47AKPSOOM.e8e5dd"],"method":"Modified Miedema's model","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ND":0.7,"RU":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"Nd7Ru3"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.26835},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-25.367,"value_printed":-25.367,"value_stored":-25367.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-WXZ7AJECCE.7e5c37","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":33},"merged_ids":["ORC-WXZ7AJECCE.d81e24"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0012},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-0.024,"value_printed":-0.024},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-WXZ7AJECCE.9ece81","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":33},"merged_ids":["ORC-WXZ7AJECCE.e7a2be"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.80925},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-16.185,"value_printed":-16.185,"value_stored":-16185.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":1000.0,"before":null,"evidence":{"printed":"ΔGf at 1000 K"},"field":"temperature_K","gate":"R2","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"4ba20fceda43c7b536b1400d64d6bed2370f7207ae327fa75df578f8c219187f","page":3,"pdf_sha256_prefix":"5e3db49d7b0a901d","seen":"A quantity whose printed label names its temperature (e.g. 'G^ex_Li (633 K)', 'ΔGf at 1000 K') takes that temperature when the record has none.","verdict":"rule_confirmed"}},{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-WXZ7AJECCE.b0a67d","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":33},"merged_ids":["ORC-WXZ7AJECCE.df4537"],"method":"OptimizationQM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf at 1000 K","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":1000.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.80805},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-16.161,"value_printed":-16.161,"value_stored":-16161.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":1000.0,"before":null,"evidence":{"printed":"ΔGf at 1000 K"},"field":"temperature_K","gate":"R2","rule":"temperature_printed_in_quantity_label","visual_check":{"checked":"2026-10-24","image_sha256":"4ba20fceda43c7b536b1400d64d6bed2370f7207ae327fa75df578f8c219187f","page":3,"pdf_sha256_prefix":"5e3db49d7b0a901d","seen":"A quantity whose printed label names its temperature (e.g. 'G^ex_Li (633 K)', 'ΔGf at 1000 K') takes that temperature when the record has none.","verdict":"rule_confirmed"}},{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-SXNKOE23KO.2b4f42","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":34},"merged_ids":["ORC-SXNKOE23KO.d4ef88"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf at 1000 K","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_K":1000.0,"temperature_basis":"quantity_label","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.71745},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-14.349,"value_printed":-14.349,"value_stored":-14349.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-SXNKOE23KO.78c2f5","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":34},"merged_ids":["ORC-SXNKOE23KO.7b1f61"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.115},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-2.3,"value_printed":-2.3},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-SXNKOE23KO.d0bad2","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":34},"merged_ids":["ORC-SXNKOE23KO.e981dd"],"method":"OptimizationEM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.8325},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-16.65,"value_printed":-16.65,"value_stored":-16650.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-X32YE4ZGKP.1274f8","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":35},"merged_ids":["ORC-X32YE4ZGKP.9d2854"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r35#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_group":"formation","property_printed":"ΔGf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.84735},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at","unit_stored":"J/mol-atom","value":-16.947,"value_printed":-16.947,"value_stored":-16947.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-X32YE4ZGKP.1eb9d6","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":35},"merged_ids":["ORC-X32YE4ZGKP.ed4d4a"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r35#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.09745},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol-at.","unit_stored":"J/mol-atom","value":-21.949,"value_printed":-21.949,"value_stored":-21949.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"before":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"evidence":{"basis":"printed_formula","label":"NdRu2","max_deviation":0.6667},"field":"overall_composition","gate":"A1","rule":"overall_composition_from_printed_formula"},{"after":"ND-RU","before":"DY-GD-LA-ND-RU","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"GD":0.0,"LA":0.0,"ND":0.333333,"RU":0.666667},"phases":["NdRu2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":4,"id":"ORC-X32YE4ZGKP.346cb1","locator":{"ref":"sha256:d348ad5cfcdd3fe6/p7/tab-2","row":35},"merged_ids":["ORC-X32YE4ZGKP.5b4f65"],"method":"OptimizationCM","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"overall_composition":{"ND":0.333333,"RU":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"GD":0.0,"LA":0.0,"ND":1.0,"RU":0.0},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","phases":[{"label":"NdRu2"}],"pid":"sha256:d348ad5cfcdd3fe6/p7/tab-2/r35#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"general_table","reference_state":{"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"reference_state_stored":{"DY":{"phase":"printed:none"},"GD":{"phase":"printed:none"},"LA":{"phase":"printed:none"},"ND":{"phase":"printed:none"},"RU":{"phase":"printed:none"}},"source_system":"DY-GD-LA-ND-RU","system":"ND-RU","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.25005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_printed":"J/mol-at K","value":-5.001,"value_printed":-5.001},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (garbled_reaction_sign)","effect":"not_accepted","gate":"R3"}],"id":"ORC-54UGFG7HGJ.b42436","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-01023-x/p17/text-05"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","pid":"doi:10.1007/s11669-022-01023-x/p17/text-05/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"A consistent thermodynamic assessment could not be obtained to agree with both temperature and composition for the Liq Nd5Ru3 ? Nd7Ru3 eutectic reaction calculated at (1155 K; 33.28 at.% Ru) with the quadratic model, and (1148 K; 33.96 at.% Ru) with a combined model instead of (1128 K; 34.00 at.% Ru) as reported by Ref 23.","quote_page":17,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"ND-RU","system":"ND-RU","temperature_K":1155.0,"temperature_printed":"1155 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1155.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (garbled_reaction_sign)","effect":"not_accepted","gate":"R3"}],"id":"ORC-54UGFG7HGJ.b93588","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-01023-x/p17/text-05"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","pid":"doi:10.1007/s11669-022-01023-x/p17/text-05/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"A consistent thermodynamic assessment could not be obtained to agree with both temperature and composition for the Liq Nd5Ru3 ? Nd7Ru3 eutectic reaction calculated at (1155 K; 33.28 at.% Ru) with the quadratic model, and (1148 K; 33.96 at.% Ru) with a combined model instead of (1128 K; 34.00 at.% Ru) as reported by Ref 23.","quote_page":17,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"ND-RU","system":"ND-RU","temperature_K":1148.0,"temperature_printed":"1148 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1148.0},{"chemical_system":"ND-RU","citations_printed":["23"],"cited_sources":[{"doi":"10.1016/0022-5088(90)90186-n","first_author":"Palenzona","kind":"unknown","label":"23","paper":"doi:10.1016/0022-5088(90)90186-n","reference":"A. Palenzona, and F. Canepa, The Phase Diagrams of the La-Ru and Nd-Ru Systems, J. Less-Common Met., 1990, 157, p 307–313. https://doi.org/10.1016/0022-5088(90)90186-N","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (garbled_reaction_sign)","effect":"not_accepted","gate":"R3"}],"id":"ORC-54UGFG7HGJ.f56e28","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-01023-x/p17/text-05"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","pid":"doi:10.1007/s11669-022-01023-x/p17/text-05/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"A consistent thermodynamic assessment could not be obtained to agree with both temperature and composition for the Liq Nd5Ru3 ? Nd7Ru3 eutectic reaction calculated at (1155 K; 33.28 at.% Ru) with the quadratic model, and (1148 K; 33.96 at.% Ru) with a combined model instead of (1128 K; 34.00 at.% Ru) as reported by Ref 23.","quote_page":17,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"ND-RU","system":"ND-RU","temperature_K":1128.0,"temperature_printed":"1128 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1128.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-53FCKZKXYU","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-01023-x/p17/text-06"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","pid":"doi:10.1007/s11669-022-01023-x/p17/text-06/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The temperature description for this reaction is much better using the exponential model (1134 K; 33.56 at.% Ru).","quote_page":17,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"ND-RU","system":"ND-RU","temperature_K":1134.0,"temperature_printed":"1134 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1134.0},{"chemical_system":"ND-RU","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ZJN3FUBN5Z","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-022-01023-x/p20/text-86"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-022-01023-x","own_work_of_paper":true},"paper":"doi:10.1007/s11669-022-01023-x","paper_id":"doi:10.1007/s11669-022-01023-x","pid":"doi:10.1007/s11669-022-01023-x/p20/text-86/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The (aNd) (bNd) allotropic transition was well reproduced at temperature 1136 K and 7 at.% Ru.","quote_page":20,"reaction":{"type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"ND-RU","system":"ND-RU","temperature_K":1136.0,"temperature_printed":"1136 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"polymorphic","transition_kind_printed":"polymorphic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1136.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"ND-RU"}