{"artifacts":{"doi:10.2320/matertrans.45.1507/p3/tab-1":{"artifact":"table","caption":"Crystallographic data of various binary and ternary phases in the Ni-Si-Ti system.","label":"1","page":3},"doi:10.2320/matertrans.45.1507/p3/tab-2":{"artifact":"table","caption":"Calculated results of the enthalpy of formation and equilibrium lattice constant for various binary and ternary phases in the Ni-Si-Ti system.","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["NI","SI","TI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.2320/matertrans.45.1507":{"authors":["Tatsuya Tokunaga","Koji Hashima","Hiroshi Ohtani","Mitsuhiro Hasebe"],"citation":"Tatsuya Tokunaga, Koji Hashima, Hiroshi Ohtani, Mitsuhiro Hasebe, Thermodynamic Analysis of the Ni-Si-Ti System Using Thermochemical Properties Determined from Ab Initio Calculations, Mater. Trans. 45, 1507-1514 (2004).","container":"Mater. Trans.","doi":"10.2320/matertrans.45.1507","doi_url":"https://doi.org/10.2320/matertrans.45.1507","id":"doi:10.2320/matertrans.45.1507","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"46ad50eedde23b8d","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Analysis of the Ni-Si-Ti System Using Thermochemical Properties Determined from Ab Initio Calculations","year":2004}},"part":1,"parts":1,"records":[{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"G-Ni16Si7Ti6","label_source":"printed_source_page","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"G-Ni16Si7Ti6 | — | cF116 | Mn23Th6 | a = 1.1187","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row; strukturbericht printed '—'","verdict":"confirmed"}},{"after":{"pearson_symbol":"cF116","phase":"G-Ni16Si7Ti6","prototype":"Mn23Th6"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"G-Ni16Si7Ti6 | — | cF116 | Mn23Th6 | a = 1.1187","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row; strukturbericht printed '—'","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-2DVFXJ365B","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.241379,"TI":0.206897},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G-Ni16Si7Ti6","label_source":"printed_source_page","pearson_symbol":"cF116","prototype":"Mn23Th6","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"cF116","phase":"G-Ni16Si7Ti6","prototype":"Mn23Th6"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02461,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02461},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.187,"value_stored":1.1187},{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"G'-Ni3SiTi2","label_source":"printed_source_page","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"G'-Ni3SiTi2 | — | hP12 | MgZn2 | a = 0.479, c = 0.755","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[14],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP12","phase":"G'-Ni3SiTi2","prototype":"MgZn2"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"G'-Ni3SiTi2 | — | hP12 | MgZn2 | a = 0.479, c = 0.755","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[14],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-XMSYFULQZ6.5d0d07","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.166667,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G'-Ni3SiTi2","label_source":"printed_source_page","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"hP12","phase":"G'-Ni3SiTi2","prototype":"MgZn2"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01054,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01054},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.79,"value_stored":0.479},{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"G'-Ni3SiTi2","label_source":"printed_source_page","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"G'-Ni3SiTi2 | — | hP12 | MgZn2 | a = 0.479, c = 0.755","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[14],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP12","phase":"G'-Ni3SiTi2","prototype":"MgZn2"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"G'-Ni3SiTi2 | — | hP12 | MgZn2 | a = 0.479, c = 0.755","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[14],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-XMSYFULQZ6.6c87bc","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.166667,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G'-Ni3SiTi2","label_source":"printed_source_page","pearson_symbol":"hP12","prototype":"MgZn2","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"hP12","phase":"G'-Ni3SiTi2","prototype":"MgZn2"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01661,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01661},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.55,"value_stored":0.755},{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"V-Ni4Si7Ti4","label_source":"printed_source_page","pearson_symbol":"tI60","prototype":"Co4Ge7Zr4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"V-Ni4Si7Ti4 | — | tI60 | Co4Ge7Zr4 | a = 1.25229, c = 0.49343","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}},{"after":{"pearson_symbol":"tI60","phase":"V-Ni4Si7Ti4","prototype":"Co4Ge7Zr4"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"V-Ni4Si7Ti4 | — | tI60 | Co4Ge7Zr4 | a = 1.25229, c = 0.49343","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-2TXKRTL5BO.36d899","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.466667,"TI":0.266667},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"V-Ni4Si7Ti4","label_source":"printed_source_page","pearson_symbol":"tI60","prototype":"Co4Ge7Zr4","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"tI60","phase":"V-Ni4Si7Ti4","prototype":"Co4Ge7Zr4"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02755,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02755},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.5229,"value_stored":1.25229},{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"V-Ni4Si7Ti4","label_source":"printed_source_page","pearson_symbol":"tI60","prototype":"Co4Ge7Zr4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"V-Ni4Si7Ti4 | — | tI60 | Co4Ge7Zr4 | a = 1.25229, c = 0.49343","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}},{"after":{"pearson_symbol":"tI60","phase":"V-Ni4Si7Ti4","prototype":"Co4Ge7Zr4"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"V-Ni4Si7Ti4 | — | tI60 | Co4Ge7Zr4 | a = 1.25229, c = 0.49343","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[15],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-2TXKRTL5BO.f282fd","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.466667,"TI":0.266667},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"V-Ni4Si7Ti4","label_source":"printed_source_page","pearson_symbol":"tI60","prototype":"Co4Ge7Zr4","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"tI60","phase":"V-Ni4Si7Ti4","prototype":"Co4Ge7Zr4"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01086,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01086},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.9343,"value_stored":0.49343},{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"E-NiSiTi","label_source":"printed_source_page","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"E-NiSiTi | — | oP12 | Co2Si | a = 0.61484, b = 0.36698, c = 0.70173","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}},{"after":{"pearson_symbol":"oP12","phase":"E-NiSiTi","prototype":"Co2Si"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"E-NiSiTi | — | oP12 | Co2Si | a = 0.61484, b = 0.36698, c = 0.70173","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-4GORXNXG5Y.7f311f","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.333333,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"E-NiSiTi","label_source":"printed_source_page","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"oP12","phase":"E-NiSiTi","prototype":"Co2Si"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008074,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008074},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.6698,"value_stored":0.36698},{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"E-NiSiTi","label_source":"printed_source_page","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"E-NiSiTi | — | oP12 | Co2Si | a = 0.61484, b = 0.36698, c = 0.70173","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}},{"after":{"pearson_symbol":"oP12","phase":"E-NiSiTi","prototype":"Co2Si"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"E-NiSiTi | — | oP12 | Co2Si | a = 0.61484, b = 0.36698, c = 0.70173","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-4GORXNXG5Y.a18ab3","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.333333,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"E-NiSiTi","label_source":"printed_source_page","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"oP12","phase":"E-NiSiTi","prototype":"Co2Si"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01544,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01544},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.0173,"value_stored":0.70173},{"chemical_system":"NI-SI-TI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":[{"label":"E-NiSiTi","label_source":"printed_source_page","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"E-NiSiTi | — | oP12 | Co2Si | a = 0.61484, b = 0.36698, c = 0.70173","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"1","table_key":"t173"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}},{"after":{"pearson_symbol":"oP12","phase":"E-NiSiTi","prototype":"Co2Si"},"before":null,"evidence":{"batch":"table_context_batch_09","doi":"10.2320/matertrans.45.1507","pdf_page":3,"pdf_sha256":"46ad50eedde23b8deba0f4e74b1b9f8345f139bd88063bc53a762c3cd5f24908","printed":"E-NiSiTi | — | oP12 | Co2Si | a = 0.61484, b = 0.36698, c = 0.70173","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[16],"table":"1","table_key":"t173"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 09","image_sha256":"ba99d3f211dfb538021cb7fc0ae9d00bf42453afef249aa4dee8233a8833a3e7","page":3,"pdf_sha256_prefix":"46ad50eedde23b8d","seen":"own row","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-4GORXNXG5Y.fdd93b","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.333333,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"E-NiSiTi","label_source":"printed_source_page","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"printed_source_page"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-SI-TI","structure":{"pearson_symbol":"oP12","phase":"E-NiSiTi","prototype":"Co2Si"},"system":"NI-SI-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01353,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01353},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.1484,"value_stored":0.61484},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-UQ5KQWDARR.916640","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":15},"merged_ids":["ORC-UQ5KQWDARR.ad36ae"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.241379,"TI":0.206897},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G-Ni16Si7Ti6"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔH (ab initio)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.7335},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/(mole of atoms)","unit_stored":"J/mol-atom","value":-54.67,"value_printed":-54.67,"value_stored":-54670.0},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-G5LBQJSDZC.314d0b","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":15},"merged_ids":["ORC-G5LBQJSDZC.c3265e"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.241379,"TI":0.206897},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G-Ni16Si7Ti6"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.56616},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1132,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1132},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":11.3232,"value_printed":1.13232,"value_stored":1.13232},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-6T5Z7DZXE2.3f16b8","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":16},"merged_ids":["ORC-6T5Z7DZXE2.e6ad87"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.166667,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G'-Ni3SiTi2"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔH (ab initio)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.96},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/(mole of atoms)","unit_stored":"J/mol-atom","value":-59.2,"value_printed":-59.2,"value_stored":-59200.0},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-QYYI5BJD5X.324835","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":16},"merged_ids":["ORC-QYYI5BJD5X.8928d6"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.166667,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G'-Ni3SiTi2"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","property_printed":"c","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.380135},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07603,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07603},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":7.6027,"value_printed":0.76027,"value_stored":0.76027},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-QYYI5BJD5X.bc9c4c","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":16},"merged_ids":["ORC-QYYI5BJD5X.c01cac"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.166667,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"G'-Ni3SiTi2"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.241175},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04824,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04824},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":4.8235,"value_printed":0.48235,"value_stored":0.48235},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-JFWABD54P6.90e26b","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":17},"merged_ids":["ORC-JFWABD54P6.a665d8"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.466667,"TI":0.266667},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"V-Ni4Si7Ti4"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.4225},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/(mole of atoms)","unit_stored":"J/mol-atom","value":-68.45,"value_printed":-68.45,"value_stored":-68450.0},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-GJ3G4ZRRAZ.44462d","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":17},"merged_ids":["ORC-GJ3G4ZRRAZ.69221b"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.466667,"TI":0.266667},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"V-Ni4Si7Ti4"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","property_printed":"c","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.24839},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04968,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04968},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":4.9678,"value_printed":0.49678,"value_stored":0.49678},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-GJ3G4ZRRAZ.7d8fe1","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":17},"merged_ids":["ORC-GJ3G4ZRRAZ.88830b"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.466667,"TI":0.266667},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"V-Ni4Si7Ti4"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.630395},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1261,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1261},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":12.6079,"value_printed":1.26079,"value_stored":1.26079},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-KNO75JD6E5.3fa5f1","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":18},"merged_ids":["ORC-KNO75JD6E5.84286c"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.333333,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"E-NiSiTi"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.093},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/(mole of atoms)","unit_stored":"J/mol-atom","value":-81.86,"value_printed":-81.86,"value_stored":-81860.0},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-2IBXABR2NE.04236b","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":18},"merged_ids":["ORC-2IBXABR2NE.d42140"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.333333,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"E-NiSiTi"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.308095},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06162,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06162},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":6.1619,"value_printed":0.61619,"value_stored":0.61619},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-2IBXABR2NE.3dc799","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":18},"merged_ids":["ORC-2IBXABR2NE.79f3df"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.333333,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"E-NiSiTi"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","property_printed":"b","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.183895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03678,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.03678},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":3.6779,"value_printed":0.36779,"value_stored":0.36779},{"chemical_system":"NI-SI-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-2IBXABR2NE.78eb77","locator":{"ref":"doi:10.2320/matertrans.45.1507/p3/tab-2","row":18},"merged_ids":["ORC-2IBXABR2NE.903003"],"method":"Ab initio","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2320/matertrans.45.1507","own_work_of_paper":true},"overall_composition":{"SI":0.333333,"TI":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.2320/matertrans.45.1507","paper_id":"doi:10.2320/matertrans.45.1507","phases":[{"label":"E-NiSiTi"}],"pid":"doi:10.2320/matertrans.45.1507/p3/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","property_printed":"c","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"SI":{"phase":"DIAMOND_A4"},"TI":{"phase":"HCP_A3"}},"source_system":"NI-SI-TI","system":"NI-SI-TI","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.351635},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07033,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07033},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"nm","unit_stored":"nm","value":7.0327,"value_printed":0.70327,"value_stored":0.70327}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"NI-SI-TI"}