{"artifacts":{"doi:10.1016/j.calphad.2007.07.001/p1/text-07":{"artifact":"text_passage","label":"page 1, passage 7","page":1},"doi:10.1016/j.calphad.2007.07.001/p2/text-05":{"artifact":"text_passage","label":"page 2, passage 5","page":2},"doi:10.1016/j.calphad.2007.07.001/p3/tab-1":{"artifact":"table","caption":"The invariant reactions of the Ni–Zr system","label":"1","page":3},"doi:10.1016/j.calphad.2007.07.001/p4/tab-1":{"artifact":"table","caption":"(continued)","label":"1","page":4},"doi:10.1016/j.calphad.2007.07.001/p4/tab-2":{"artifact":"table","caption":"The eutectic temperature between the NiZr and NiZr 2 compounds obtained by DSC","label":"2","page":4},"doi:10.1016/j.calphad.2011.10.003/p12/text-07":{"artifact":"text_passage","label":"page 12, passage 7","page":12},"doi:10.1016/j.calphad.2011.10.003/p9/tab-8":{"artifact":"table","caption":"Selected invariant Ni–Zr equilibria calculated in this work.","label":"8","page":9},"doi:10.1016/j.intermet.2019.106640/p2/tab-2":{"artifact":"table","caption":"Crystallographic data for the intermediate phases in the Ni–Zr system.","label":"2","page":2},"doi:10.1016/j.intermet.2019.106640/p3/tab-2":{"artifact":"table","caption":"(continued )","label":"2","page":3},"doi:10.1016/j.intermet.2019.106640/p3/tab-3":{"artifact":"table","caption":"Co-ordinates of special points in the Ni–Zr system.","label":"3","page":3},"doi:10.1016/j.intermet.2019.106640/p4/tab-3":{"artifact":"table","caption":"(continued )","label":"3","page":4},"doi:10.1016/j.intermet.2019.106640/p4/text-03":{"artifact":"text_passage","label":"page 4, passage 3","page":4},"doi:10.1016/j.intermet.2019.106640/p7/tab-6":{"artifact":"table","caption":"Enthalpy of formation (Δ f H ∘ m ) of intermediate phases.","label":"6","page":7},"doi:10.1016/j.tca.2018.08.011/p8/text-03":{"artifact":"text_passage","label":"page 8, passage 3","page":8}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1016/j.calphad.2007.07.001":{"context_id":"context:source-doi-10-1016-j-calphad-2007-07-001","items":[{"applies_to":"four different compositions of the Ni-Zr alloys","extraction_accepted":true,"has_dropped_fields":true,"heating_or_cooling_rate":"20, 10, 5 K/min","id":"ORC-4WMGJJAQHH","method":"DSC technique","page":4,"quote":"In this work, four different compositions of the Ni-Zr alloys were studied from room temperature to 1373 K at the heating rates of 20, 10, 5 K/min by the DSC technique.","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-XWAIVF763M","instrument":"Netzsch STA 449C","method":"thermogravimetric (TG)","page":4,"quote":"of the thermogravimetric (TG) part of Netzsch STA 449C to identify whether the oxidation occurred.","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-3QS7YVHILR","page":2,"quote":"Between the NiZr and NiZr2 compounds, four master alloys of about 20 g with the compositions of 65, 68, 72 and 74 wt.% Zr were prepared by melting in an arc furnace under purified argon atmosphere.","second_reader_agrees":false,"synthesis":"melting in an arc furnace under purified argon atmosphere","type":"sample"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-3QS7YVHILR","label":"74 wt.% Zr","nominal_composition":"74 wt.% Zr","page":2,"quote":"Between the NiZr and NiZr2 compounds, four master alloys of about 20 g with the compositions of 65, 68, 72 and 74 wt.% Zr were prepared by melting in an arc furnace under purified argon atmosphere.","second_reader_agrees":false,"synthesis":"melting in an arc furnace under purified argon atmosphere","type":"sample"}],"paper":"doi:10.1016/j.calphad.2007.07.001","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"own_work_method_cues"}},"elements":["NI","ZR"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M2217bc45":{"catalog_entry":{"license":"CC BY 4.0","name":"NiZr-20Jan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Intermetallics, 116, 106640(2020).","model_doi":"10.1016/j.intermet.2019.106640","reproduced_by_calculation":true,"tdb":"NiZr-20Jan.tdb","tdb_path":"databases/sgte-binary/NiZr-20Jan.tdb","tdb_sha256":"bc80ea0218a30fd0bbcd26744c0c2228335b50415a694754c27af164ef7efdba"},"M31bb0da5":{"catalog_entry":{"license":"CC BY 4.0","name":"NiZr-20Jan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Intermetallics, 116, 106640(2020).","model_doi":"10.1016/j.intermet.2019.106640","reproduced_by_calculation":false,"tdb":"NiZr-20Jan.tdb","tdb_path":"databases/sgte-binary/NiZr-20Jan.tdb","tdb_sha256":"bc80ea0218a30fd0bbcd26744c0c2228335b50415a694754c27af164ef7efdba"},"Maf581929":{"catalog_entry":{"license":"CC BY 4.0","name":"NiZr-11Cac.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_doi":"10.1016/j.calphad.2011.10.003","reproduced_by_calculation":true,"tdb":"NiZr-11Cac.tdb","tdb_path":"databases/sgte-binary/NiZr-11Cac.tdb","tdb_sha256":"ef2178351f0f844eb6af52eb5864f7b3688dd69346681f5addc8b952a0c5e739"},"Mbf8577b3":{"catalog_entry":{"license":"CC BY 4.0","name":"NiZr-20Jan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"Intermetallics, 116, 106640(2020).","model_doi":"10.1016/j.intermet.2019.106640","tdb":"NiZr-20Jan.tdb","tdb_path":"databases/sgte-binary/NiZr-20Jan.tdb","tdb_sha256":"bc80ea0218a30fd0bbcd26744c0c2228335b50415a694754c27af164ef7efdba"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf03398286":{"citation":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","doi":"10.1007/bf03398286","doi_url":"https://doi.org/10.1007/bf03398286","id":"doi:10.1007/bf03398286","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1957},"doi:10.1007/s11106-017-9888-2":{"authors":["O. L. Semenova","V. M. Petyukh","O. S. Fomichev"],"citation":"O. L. Semenova, V. M. Petyukh, O. S. Fomichev, The Quasibinary ZrCo–ZrNi Phase Diagram, Powder Metall Met Ceram 56, 210-219 (2017).","container":"Powder Metall Met Ceram","doi":"10.1007/s11106-017-9888-2","doi_url":"https://doi.org/10.1007/s11106-017-9888-2","id":"doi:10.1007/s11106-017-9888-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Quasibinary ZrCo–ZrNi Phase Diagram","year":2017},"doi:10.1016/0022-5088(79)90135-8":{"authors":["J.L Glimois","C Becle","G Develey","J.M Moreau"],"citation":"J.L Glimois, C Becle, G Develey, J.M Moreau, Crystal structure of the intermetallic compound Ni11Zr9, Journal of the Less Common Metals 64, 87-90 (1979).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(79)90135-8","doi_url":"https://doi.org/10.1016/0022-5088(79)90135-8","id":"doi:10.1016/0022-5088(79)90135-8","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Crystal structure of the intermetallic compound Ni11Zr9","year":1979},"doi:10.1016/0022-5088(79)90241-8":{"authors":["Lars Bsenko"],"citation":"Lars Bsenko, The HfNi and ZrNi systems in the region 65 – 80 at.% Ni, Journal of the Less Common Metals 63, 171-179 (1979).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(79)90241-8","doi_url":"https://doi.org/10.1016/0022-5088(79)90241-8","id":"doi:10.1016/0022-5088(79)90241-8","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The HfNi and ZrNi systems in the region 65 – 80 at.% Ni","year":1979},"doi:10.1016/0022-5088(83)90497-6":{"authors":["J.C. Gachon","M. Dirand","J. Hertz"],"citation":"J.C. Gachon, M. Dirand, J. Hertz, Enthalpic and structural studies of the NiZr system, Journal of the Less Common Metals 92, 307-315 (1983).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(83)90497-6","doi_url":"https://doi.org/10.1016/0022-5088(83)90497-6","id":"doi:10.1016/0022-5088(83)90497-6","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Enthalpic and structural studies of the NiZr system","year":1983},"doi:10.1016/0036-9748(80)90208-2":{"authors":["F.H.M. Spit","J.W. Drijver","S. Radelaar"],"citation":"F.H.M. Spit, J.W. Drijver, S. Radelaar, Hydrogen sorption by the metallic glass Ni64Zr36 and by related crystalline compounds, Scripta Metallurgica 14, 1071-1076 (1980).","container":"Scripta Metallurgica","doi":"10.1016/0036-9748(80)90208-2","doi_url":"https://doi.org/10.1016/0036-9748(80)90208-2","id":"doi:10.1016/0036-9748(80)90208-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Hydrogen sorption by the metallic glass Ni64Zr36 and by related crystalline compounds","year":1980},"doi:10.1016/0364-5916(81)90015-8":{"citation":"R.E. Watson, L.H. Bennett, Optimized prediction for heats of formation of transition metal alloys, Calphad 5 (1) (1981) 2–40.","doi":"10.1016/0364-5916(81)90015-8","doi_url":"https://doi.org/10.1016/0364-5916(81)90015-8","id":"doi:10.1016/0364-5916(81)90015-8","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1016/0364-5916(85)90001-x":{"authors":["N. Saunders"],"citation":"N. Saunders, Phase diagram calculations for eight glass forming alloy systems, Calphad 9, 297-309 (1985).","container":"Calphad","doi":"10.1016/0364-5916(85)90001-x","doi_url":"https://doi.org/10.1016/0364-5916(85)90001-x","id":"doi:10.1016/0364-5916(85)90001-x","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work","journal_article"],"title":"Phase diagram calculations for eight glass forming alloy systems","year":1985},"doi:10.1016/0364-5916(85)90032-x":{"citation":"C. Colinet, A. Pasturel, P. Hicter, Calphad 9 (1985) 71–99.","doi":"10.1016/0364-5916(85)90032-x","doi_url":"https://doi.org/10.1016/0364-5916(85)90032-x","id":"doi:10.1016/0364-5916(85)90032-x","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1016/j.calphad.2007.07.001":{"authors":["Na Wang","Changrong Li","Zhenmin Du","Fenge Wang"],"citation":"Na Wang, Changrong Li, Zhenmin Du, Fenge Wang, Experimental study and thermodynamic re-assessment of the Ni–Zr system, Calphad 31, 413-421 (2007).","container":"Calphad","doi":"10.1016/j.calphad.2007.07.001","doi_url":"https://doi.org/10.1016/j.calphad.2007.07.001","id":"doi:10.1016/j.calphad.2007.07.001","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"efca121a1f4e551c","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental study and thermodynamic re-assessment of the Ni–Zr system","year":2007},"doi:10.1016/j.calphad.2011.10.003":{"authors":["G. Cacciamani","P. Riani","F. Valenza"],"citation":"G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).","container":"Calphad","doi":"10.1016/j.calphad.2011.10.003","doi_url":"https://doi.org/10.1016/j.calphad.2011.10.003","id":"doi:10.1016/j.calphad.2011.10.003","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"50edf41fd24d5da2","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system","year":2011},"doi:10.1016/j.cplett.2007.06.031":{"authors":["R.F. Zhang","S.H. Sheng","B.X. Liu"],"citation":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chemical Physics Letters 442, 511-514 (2007).","container":"Chemical Physics Letters","doi":"10.1016/j.cplett.2007.06.031","doi_url":"https://doi.org/10.1016/j.cplett.2007.06.031","id":"doi:10.1016/j.cplett.2007.06.031","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Predicting the formation enthalpies of binary intermetallic compounds","year":2007},"doi:10.1016/j.intermet.2014.05.021":{"authors":["Jinglian Du","Bin Wen","Roderick Melnik","Yoshiyuki Kawazoe"],"citation":"Jinglian Du, Bin Wen, Roderick Melnik, Yoshiyuki Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54, 110-119 (2014).","container":"Intermetallics","doi":"10.1016/j.intermet.2014.05.021","doi_url":"https://doi.org/10.1016/j.intermet.2014.05.021","id":"doi:10.1016/j.intermet.2014.05.021","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds","year":2014},"doi:10.1016/j.intermet.2019.106640":{"authors":["Asmita Jana","Soumya Sridar","Suzana G. Fries","Thomas Hammerschmidt","K.C. Hari Kumar"],"citation":"Asmita Jana, Soumya Sridar, Suzana G. Fries, Thomas Hammerschmidt, K.C. Hari Kumar, Thermodynamic modelling of the Ni–Zr system, Intermetallics 116, 106640 (2020).","container":"Intermetallics","doi":"10.1016/j.intermet.2019.106640","doi_url":"https://doi.org/10.1016/j.intermet.2019.106640","id":"doi:10.1016/j.intermet.2019.106640","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"63a18f6828c8eb89","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modelling of the Ni–Zr system","year":2020},"doi:10.1016/j.jallcom.2004.01.064":{"authors":["H.T Takeshita","S Kondo","H Miyamura","N Takeichi","N Kuriyama","T Oishi"],"citation":"H.T Takeshita, S Kondo, H Miyamura, N Takeichi, N Kuriyama, T Oishi, Re-examination of Zr7Ni10 single-phase region, Journal of Alloys and Compounds 376, 268-274 (2004).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2004.01.064","doi_url":"https://doi.org/10.1016/j.jallcom.2004.01.064","id":"doi:10.1016/j.jallcom.2004.01.064","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Re-examination of Zr7Ni10 single-phase region","year":2004},"doi:10.1016/j.jallcom.2018.04.019":{"authors":["Xiaoma Tao","Pei Yao","Wenwang Wei","Hongmei Chen","Yifang Ouyang","Yong Du","Yuan Yuan","Qing Peng"],"citation":"Xiaoma Tao, Pei Yao, Wenwang Wei, Hongmei Chen, Yifang Ouyang, Yong Du et al., An experimental study on the interdiffusion behaviors and mechanical properties of Ni-Zr system, Journal of Alloys and Compounds 752, 412-419 (2018).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2018.04.019","doi_url":"https://doi.org/10.1016/j.jallcom.2018.04.019","id":"doi:10.1016/j.jallcom.2018.04.019","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"An experimental study on the interdiffusion behaviors and mechanical properties of Ni-Zr system","year":2018},"doi:10.1016/j.tca.2018.08.011":{"authors":["A.J. Ross","T. Gheno","P.K. Ray","M.J. Kramer","X.L. Liu","G. Lindwall","B. Zhou","S.L. Shang","B. Gleeson","Z-K. Liu"],"citation":"A.J. Ross, T. Gheno, P.K. Ray, M.J. Kramer, X.L. Liu, G. Lindwall et al., A first-principles based description of the Hf-Ni system supported by high-temperature synchrotron experiments, Thermochimica Acta 668, 142-151 (2018).","container":"Thermochimica Acta","doi":"10.1016/j.tca.2018.08.011","doi_url":"https://doi.org/10.1016/j.tca.2018.08.011","id":"doi:10.1016/j.tca.2018.08.011","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"619ca4f00babd65b","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"A first-principles based description of the Hf-Ni system supported by high-temperature synchrotron experiments","year":2018},"doi:10.1016/s0925-8388(98)00246-1":{"authors":["Qiti Guo","O.J. Kleppa"],"citation":"Qiti Guo, O.J. Kleppa, Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by high-temperature direct synthesis calorimetry, Journal of Alloys and Compounds 269, 181-186 (1998).","container":"Journal of Alloys and Compounds","doi":"10.1016/s0925-8388(98)00246-1","doi_url":"https://doi.org/10.1016/s0925-8388(98)00246-1","id":"doi:10.1016/s0925-8388(98)00246-1","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by high-temperature direct synthesis calorimetry","year":1998},"doi:10.1039/b201036b":{"authors":["A. I. Zaitsev","N. E. Zaitseva","E. Kh. Shakhpazov","A. A. Kodentsov"],"citation":"A. I. Zaitsev, N. E. Zaitseva, E. Kh. Shakhpazov, A. A. Kodentsov, Thermodynamic properties and phase equilibria in the nickel–zirconium system. The liquid to amorphous state transition, Phys. Chem. Chem. Phys. 4, 6047-6058 (2002).","container":"Phys. Chem. Chem. Phys.","doi":"10.1039/b201036b","doi_url":"https://doi.org/10.1039/b201036b","id":"doi:10.1039/b201036b","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermodynamic properties and phase equilibria in the nickel–zirconium system. The liquid to amorphous state transition","year":2002},"doi:10.1063/1.109404":{"authors":["K. Ohsaka","E. H. Trinh","J. C. Holzer","W. L. Johnson"],"citation":"K. Ohsaka, E. H. Trinh, J. C. Holzer, W. L. Johnson, Gibbs free-energy difference between the glass and crystalline phases of a Ni-Zr alloy, Applied Physics Letters 62, 2319-2321 (1993).","container":"Applied Physics Letters","doi":"10.1063/1.109404","doi_url":"https://doi.org/10.1063/1.109404","id":"doi:10.1063/1.109404","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Gibbs free-energy difference between the glass and crystalline phases of a Ni-Zr alloy","year":1993},"doi:10.1063/1.333963":{"authors":["M. P. Henaff","C. Colinet","A. Pasturel","K. H. J. Buschow"],"citation":"M. P. Henaff, C. Colinet, A. Pasturel, K. H. J. Buschow, Study of the enthalpies of formation and crystallization in the system Zr-Ni, Journal of Applied Physics 56, 307-310 (1984).","container":"Journal of Applied Physics","doi":"10.1063/1.333963","doi_url":"https://doi.org/10.1063/1.333963","id":"doi:10.1063/1.333963","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Study of the enthalpies of formation and crystallization in the system Zr-Ni","year":1984},"doi:10.1103/physrevb.71.144103":{"authors":["R. G. Hennig","A. E. Carlsson","K. F. Kelton","C. L. Henley"],"citation":"R. G. Hennig, A. E. Carlsson, K. F. Kelton, C. L. Henley, <i>Ab initio</i>Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005).","container":"Phys. Rev. B","doi":"10.1103/physrevb.71.144103","doi_url":"https://doi.org/10.1103/physrevb.71.144103","id":"doi:10.1103/physrevb.71.144103","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"<i>Ab initio</i>Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals","year":2005},"doi:10.1107/s0365110x62002339":{"authors":["M. E. Kirkpatrick","J. F. Smith","W. L. Larsen"],"citation":"M. E. Kirkpatrick, J. F. Smith, W. L. Larsen, Structures of the intermediate phases Ni<sub>10</sub>Zr<sub>7</sub>and Ni<sub>10</sub>Hf<sub>7</sub>, Acta Cryst 15, 894-903 (1962).","container":"Acta Cryst","doi":"10.1107/s0365110x62002339","doi_url":"https://doi.org/10.1107/s0365110x62002339","id":"doi:10.1107/s0365110x62002339","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Structures of the intermediate phases Ni<sub>10</sub>Zr<sub>7</sub>and Ni<sub>10</sub>Hf<sub>7</sub>","year":1962},"doi:10.1107/s0567740872004649":{"authors":["F. R. Eshelman","J. F. Smith"],"citation":"F. R. Eshelman, J. F. Smith, The structure of Zr2Ni7, Acta Crystallogr B Struct Crystallogr Cryst Chem 28, 1594-1600 (1972).","container":"Acta Crystallogr B Struct Crystallogr Cryst Chem","doi":"10.1107/s0567740872004649","doi_url":"https://doi.org/10.1107/s0567740872004649","id":"doi:10.1107/s0567740872004649","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The structure of Zr2Ni7","year":1972},"doi:10.1557/jmr.1994.0598":{"authors":["G. Ghosh"],"citation":"G. Ghosh, Thermodynamics and kinetics of stable and metastable phases in the Ni–Zr system, J. Mater. Res. 9, 598-616 (1994).","container":"J. Mater. Res.","doi":"10.1557/jmr.1994.0598","doi_url":"https://doi.org/10.1557/jmr.1994.0598","id":"doi:10.1557/jmr.1994.0598","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermodynamics and kinetics of stable and metastable phases in the Ni–Zr system","year":1994},"doi:10.2320/matertrans.46.2838":{"authors":["Taichi Abe","Hidehiro Onodera","Masato Shimono","Machiko Ode"],"citation":"Taichi Abe, Hidehiro Onodera, Masato Shimono, Machiko Ode, Thermodynamic Modeling of the Undercooled Liquid in the Ni&amp;ndash;Zr System, Mater. Trans. 46, 2838-2843 (2005).","container":"Mater. Trans.","doi":"10.2320/matertrans.46.2838","doi_url":"https://doi.org/10.2320/matertrans.46.2838","id":"doi:10.2320/matertrans.46.2838","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"897b1b0468ec71e5","roles":["cited_source"],"source_kinds":["journal_article"],"title":"Thermodynamic Modeling of the Undercooled Liquid in the Ni&amp;ndash;Zr System","year":2005},"ref:28c66992669d0d07":{"citation":"E.T. Hayes, A.H. Roberson, O.G. Paasche, The Zirconium-Nickel phase diagram, Trans. ASM 45 (1953) 893–900.","id":"ref:28c66992669d0d07","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1953},"ref:380a1b11f81ca38a":{"citation":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","id":"ref:380a1b11f81ca38a","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":2013},"ref:c15d8b8bfabd1411":{"citation":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","id":"ref:c15d8b8bfabd1411","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1961}},"part":1,"parts":1,"records":[{"chemical_system":"NI-ZR","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2007.07.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":3,"id":"ORC-FH3EQCGYLL","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2","row":1},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"overall_composition":{"NI":0.456,"ZR":0.544},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phases":[{"label":"NiZr","model_phase":"NIZR_B33"},{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1290.5,"temperature_basis":"printed","temperature_printed":"1290.5","tool_release":"tools-release-v2.1.18","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1290.5},{"chemical_system":"NI-ZR","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2007.07.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":3,"id":"ORC-2QEDX7PNES","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2","row":2},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"overall_composition":{"NI":0.423,"ZR":0.577},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phases":[{"label":"NiZr","model_phase":"NIZR_B33"},{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1298.4,"temperature_basis":"printed","temperature_printed":"1298.4","tool_release":"tools-release-v2.1.18","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1298.4},{"chemical_system":"NI-ZR","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2007.07.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":3,"id":"ORC-JTVKIHMEVV","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2","row":3},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"overall_composition":{"NI":0.377,"ZR":0.623},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phases":[{"label":"NiZr","model_phase":"NIZR_B33"},{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1294.5,"temperature_basis":"printed","temperature_printed":"1294.5","tool_release":"tools-release-v2.1.18","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1294.5},{"chemical_system":"NI-ZR","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2007.07.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":3,"id":"ORC-QNA6ZV5A6F","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2","row":4},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"overall_composition":{"NI":0.353,"ZR":0.647},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phases":[{"label":"NiZr","model_phase":"NIZR_B33"},{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1297.1,"temperature_basis":"printed","temperature_printed":"1297.1","tool_release":"tools-release-v2.1.18","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1297.1},{"chemical_system":"NI-ZR","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2007.07.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":3,"id":"ORC-CHKEF5ISX4","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2","row":5},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"overall_composition":{"NI":0.353,"ZR":0.647},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phases":[{"label":"NiZr","model_phase":"NIZR_B33"},{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1294.0,"temperature_basis":"printed","temperature_printed":"1294.0","tool_release":"tools-release-v2.1.18","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1294.0},{"chemical_system":"NI-ZR","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2007.07.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":3,"id":"ORC-PQQ6M37ABV","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2","row":6},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"overall_composition":{"NI":0.353,"ZR":0.647},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phases":[{"label":"NiZr","model_phase":"NIZR_B33"},{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-2/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1297.4,"temperature_basis":"printed","temperature_printed":"1297.4","tool_release":"tools-release-v2.1.18","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1297.4},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"},{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-4QATXCK2DC","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24","space_group":"F-43m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01475,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01475},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.7064,"value_stored":670.64},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-YL5K5E7NLL","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24","space_group":"F-43m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01477,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01477},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.713,"value_stored":671.3},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-UZFK2WI6KN","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":3},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24","space_group":"F-43m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01481,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01481},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.734,"value_stored":673.4},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-N3YL3UTR5D.024518","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":4},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24","sites":[{"label":"Ni2","species":"Ni","wyckoff":"16e","x":0.12394,"y":0.37606,"z":0.62394}],"space_group":"F-43m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-N3YL3UTR5D.7e542f","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":4},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24","sites":[{"label":"Zr1","species":"Zr","wyckoff":"4b","x":0.0,"y":0.0,"z":0.5}],"space_group":"F-43m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-N3YL3UTR5D.a9e499","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":4},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24","space_group":"F-43m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05167,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.05167},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.71,"value_stored":671.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-N3YL3UTR5D.c15eb7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":4},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24","sites":[{"label":"Ni1","species":"Ni","wyckoff":"4c","x":0.25,"y":0.25,"z":0.25}],"space_group":"F-43m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0567740872004649","first_author":"Eshelman","kind":"unknown","label":"31","paper":"doi:10.1107/s0567740872004649","reference":"F.R. Eshelman, J.F. Smith, The structure of Zr2Ni7, Acta Crystallogr. B 28(5) (1972) 1594–1600.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-2GLFVORIHM.131a28","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_ALPHA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":90.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0567740872004649","first_author":"Eshelman","kind":"unknown","label":"31","paper":"doi:10.1107/s0567740872004649","reference":"F.R. Eshelman, J.F. Smith, The structure of Zr2Ni7, Acta Crystallogr. B 28(5) (1972) 1594–1600.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-2GLFVORIHM.185de6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01341,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01341},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.0965,"value_stored":609.65},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0567740872004649","first_author":"Eshelman","kind":"unknown","label":"31","paper":"doi:10.1107/s0567740872004649","reference":"F.R. Eshelman, J.F. Smith, The structure of Zr2Ni7, Acta Crystallogr. B 28(5) (1972) 1594–1600.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-2GLFVORIHM.4dc498","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":95.83},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0567740872004649","first_author":"Eshelman","kind":"unknown","label":"31","paper":"doi:10.1107/s0567740872004649","reference":"F.R. Eshelman, J.F. Smith, The structure of Zr2Ni7, Acta Crystallogr. B 28(5) (1972) 1594–1600.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-2GLFVORIHM.561014","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01812,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01812},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.235,"value_stored":823.5},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0567740872004649","first_author":"Eshelman","kind":"unknown","label":"31","paper":"doi:10.1107/s0567740872004649","reference":"F.R. Eshelman, J.F. Smith, The structure of Zr2Ni7, Acta Crystallogr. B 28(5) (1972) 1594–1600.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-2GLFVORIHM.851680","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":90.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0567740872004649","first_author":"Eshelman","kind":"unknown","label":"31","paper":"doi:10.1107/s0567740872004649","reference":"F.R. Eshelman, J.F. Smith, The structure of Zr2Ni7, Acta Crystallogr. B 28(5) (1972) 1594–1600.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-2GLFVORIHM.9797a1","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01034,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01034},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.698,"value_stored":469.8},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3D4BXMTX7J.3e8b6d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08239,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08239},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.239,"value_stored":823.9},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3D4BXMTX7J.4d5585","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06532,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06532},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.532,"value_stored":653.2},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3D4BXMTX7J.a0d087","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04704,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04704},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.704,"value_stored":470.4},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3ASN4SFPWK.1ca7db","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06105,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06105},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.105,"value_stored":610.5},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3ASN4SFPWK.937581","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04694,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04694},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.694,"value_stored":469.4},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3ASN4SFPWK.d9578f","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08275,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08275},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.275,"value_stored":827.5},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.1f3a37","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","sites":[{"label":"Ni2","species":"Ni","wyckoff":"4f","x":0.25,"y":0.25,"z":0.5}],"space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.4ee346","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/LATTICE_ANGLE","floor":0.1,"floor_unit":"degree","n_pairs":1,"value":0.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":97.95},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.581c10","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","sites":[{"label":"Ni1","species":"Ni","wyckoff":"2c","x":0.0,"y":0.0,"z":0.5}],"space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.5b1139","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06342,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.06342},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.237,"value_stored":823.7},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.6a0bdc","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_ALPHA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/LATTICE_ANGLE","floor":0.1,"floor_unit":"degree","n_pairs":1,"value":0.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":90.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.77f7fa","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03547,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03547},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.607,"value_stored":460.7},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.83fb0e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04836,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04836},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.281,"value_stored":628.1},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.98bf10","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/LATTICE_ANGLE","floor":0.1,"floor_unit":"degree","n_pairs":1,"value":0.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":90.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.aacb39","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","sites":[{"label":"Ni3","species":"Ni","wyckoff":"8j","x":0.12757,"y":0.16546,"z":0.84377}],"space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Q4N3AVPWBQ.e13a6a","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":8},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"mS18","sites":[{"label":"Zr1","species":"Zr","wyckoff":"4i","x":0.10881,"y":0.5,"z":0.77287}],"space_group":"C2/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Becle","kind":"unknown","label":"32","reference":"C. Becle, B. Bourniquel, G. Develey, M. Saillard, The intermetallic compound Ni3Zr, J. Less-Common Met 66 (1979) 59–66.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-MMYAMLTLCO.559f61","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009467,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009467},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.3034,"value_stored":430.34},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Becle","kind":"unknown","label":"32","reference":"C. Becle, B. Bourniquel, G. Develey, M. Saillard, The intermetallic compound Ni3Zr, J. Less-Common Met 66 (1979) 59–66.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-MMYAMLTLCO.8a15c3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01168,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01168},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.309,"value_stored":530.9},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3PRGZBDMJB.4df839","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0432,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0432},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.32,"value_stored":432.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-3PRGZBDMJB.8cf59c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05324,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.05324},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.324,"value_stored":532.4},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-EPXBDQCBV5.b659bf","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01176,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01176},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.345,"value_stored":534.5},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-EPXBDQCBV5.f2532d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009526,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009526},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.33,"value_stored":433.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-THPXGW7XHH.79f53e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":12},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8","sites":[{"label":"Zr1","species":"Zr","wyckoff":"2c","x":0.33333,"y":0.66667,"z":0.25}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-THPXGW7XHH.a0504e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":12},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8","sites":[{"label":"Ni1","species":"Ni","wyckoff":"6h","x":0.15599,"y":0.31197,"z":0.75}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-THPXGW7XHH.e6b92d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":12},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04096,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04096},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.32,"value_stored":532.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-THPXGW7XHH.e9087a","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":12},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"hP8"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03326,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03326},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.319,"value_stored":431.9},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-TCABP73YJM.21743f","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":75.26},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-TCABP73YJM.27d624","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":68.04},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-TCABP73YJM.549995","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_ALPHA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":75.19},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-TCABP73YJM.742082","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01889,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01889},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.5878,"value_stored":858.78},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-TCABP73YJM.ce224e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01424,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01424},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.4721,"value_stored":647.21},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-TCABP73YJM.d9efdc","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01774,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01774},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.0645,"value_stored":806.45},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-DCNF2V7XWJ.9dacce","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08095,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08095},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.095,"value_stored":809.5},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-DCNF2V7XWJ.a761c9","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06469,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06469},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.469,"value_stored":646.9},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-DCNF2V7XWJ.b2c116","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08586,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08586},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.586,"value_stored":858.6},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.0153d1","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Zr2","species":"Zr","wyckoff":"2i","x":0.24617,"y":0.55905,"z":0.60724}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.026be6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Zr1","species":"Zr","wyckoff":"2i","x":0.06968,"y":0.90439,"z":0.3143}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.1b3b09","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_ALPHA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/LATTICE_ANGLE","floor":0.1,"floor_unit":"degree","n_pairs":1,"value":0.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":75.44},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.4b1371","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni5","species":"Ni","wyckoff":"2i","x":0.1366,"y":0.21255,"z":0.3424}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.57cc9f","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/LATTICE_ANGLE","floor":0.1,"floor_unit":"degree","n_pairs":1,"value":0.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":75.35},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.5e69bc","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Zr4","species":"Zr","wyckoff":"2i","x":0.43391,"y":0.9627,"z":0.7518}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.5f4fa3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Zr3","species":"Zr","wyckoff":"2i","x":0.25049,"y":0.43613,"z":0.0337}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.6c9a6c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni9","species":"Ni","wyckoff":"2i","x":0.31758,"y":0.74468,"z":0.04696}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.703eb3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni7","species":"Ni","wyckoff":"2i","x":0.30328,"y":0.24398,"z":0.54247}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.811de5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni4","species":"Ni","wyckoff":"2i","x":0.11982,"y":0.5551,"z":0.34781}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.85c24b","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni3","species":"Ni","wyckoff":"2i","x":0.09905,"y":0.2806,"z":0.84671}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.8bd45e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni10","species":"Ni","wyckoff":"2i","x":0.48524,"y":0.38131,"z":0.24514}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.9caf72","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06604,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.06604},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.577,"value_stored":857.7},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.bbaed8","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni2","species":"Ni","wyckoff":"2i","x":0.0978,"y":0.75876,"z":0.84738}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.be9c9d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni6","species":"Ni","wyckoff":"2i","x":0.28524,"y":0.88465,"z":0.53024}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.c14242","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06225,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.06225},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":8.085,"value_stored":808.5},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.cbca4c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni8","species":"Ni","wyckoff":"2i","x":0.31667,"y":0.09875,"z":0.03567}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.dc362b","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/LATTICE_ANGLE","floor":0.1,"floor_unit":"degree","n_pairs":1,"value":0.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":68.04},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.f4ef27","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni1","species":"Ni","wyckoff":"1a","x":0.0,"y":0.0,"z":0.0}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.facccb","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","sites":[{"label":"Ni11","species":"Ni","wyckoff":"2i","x":0.48394,"y":0.70667,"z":0.27509}],"space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SFGWHESLXV.fc9892","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":15},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"aP29","space_group":"P-1"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0498,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.0498},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.468,"value_stored":646.8},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0365110x62002339","first_author":"Kirkpatrick","kind":"unknown","label":"34","paper":"doi:10.1107/s0365110x62002339","reference":"M.E. Kirkpatrick, J.F. Smith, W.L. Larsen, Structures of the intermediate phases Ni10Zr7 and Ni10Hf7, Acta Crystallogr. 15 (1962) 894–903.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-KFKNFRGGEF.87239e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","space_group":"Cmce"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02026,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02026},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.211,"value_stored":921.1},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0365110x62002339","first_author":"Kirkpatrick","kind":"unknown","label":"34","paper":"doi:10.1107/s0365110x62002339","reference":"M.E. Kirkpatrick, J.F. Smith, W.L. Larsen, Structures of the intermediate phases Ni10Zr7 and Ni10Hf7, Acta Crystallogr. 15 (1962) 894–903.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-KFKNFRGGEF.96984d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","space_group":"Cmce"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02014,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02014},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.156,"value_stored":915.6},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0365110x62002339","first_author":"Kirkpatrick","kind":"unknown","label":"34","paper":"doi:10.1107/s0365110x62002339","reference":"M.E. Kirkpatrick, J.F. Smith, W.L. Larsen, Structures of the intermediate phases Ni10Zr7 and Ni10Hf7, Acta Crystallogr. 15 (1962) 894–903.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-KFKNFRGGEF.f4b6fa","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","space_group":"Cmce"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02725,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02725},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":12.386,"value_stored":1238.6},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.03eeb3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07065,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07065},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.175,"value_stored":917.5},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.254431","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09583,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.09583},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":12.445,"value_stored":1244.5},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.263c5c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07077,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07077},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.191,"value_stored":919.1},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.2d96f0","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","sites":[{"label":"Zr4","species":"Zr","wyckoff":"4b","x":0.0,"y":0.0,"z":0.5}],"space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.6c0999","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","sites":[{"label":"Zr2","species":"Zr","wyckoff":"8e","x":0.25,"y":0.24908,"z":0.25}],"space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.c50f15","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","sites":[{"label":"Zr1","species":"Zr","wyckoff":"8f","x":0.0,"y":0.18608,"z":0.18628}],"space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.c555e6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","sites":[{"label":"Zr3","species":"Zr","wyckoff":"8d","x":0.19137,"y":0.5,"z":0.5}],"space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.c67855","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","sites":[{"label":"Ni1","species":"Ni","wyckoff":"16g","x":0.14534,"y":0.20817,"z":0.49318}],"space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.d9a315","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","sites":[{"label":"Ni2","species":"Ni","wyckoff":"16g","x":0.14545,"y":0.00642,"z":0.70751}],"space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YHMO3TXN2X.feaeec","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS68","sites":[{"label":"Ni3","species":"Ni","wyckoff":"8f","x":0.0,"y":0.10541,"z":0.8952}],"space_group":"Cmce"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0365110x62002339","first_author":"Kirkpatrick","kind":"unknown","label":"34","paper":"doi:10.1107/s0365110x62002339","reference":"M.E. Kirkpatrick, J.F. Smith, W.L. Larsen, Structures of the intermediate phases Ni10Zr7 and Ni10Hf7, Acta Crystallogr. 15 (1962) 894–903.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-X75ALV2HEP.2c09e7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":18},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02051,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02051},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.325,"value_stored":932.5},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0365110x62002339","first_author":"Kirkpatrick","kind":"unknown","label":"34","paper":"doi:10.1107/s0365110x62002339","reference":"M.E. Kirkpatrick, J.F. Smith, W.L. Larsen, Structures of the intermediate phases Ni10Zr7 and Ni10Hf7, Acta Crystallogr. 15 (1962) 894–903.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-X75ALV2HEP.401f9f","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":18},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02749,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02749},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":12.497,"value_stored":1249.7},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1107/s0365110x62002339","first_author":"Kirkpatrick","kind":"unknown","label":"34","paper":"doi:10.1107/s0365110x62002339","reference":"M.E. Kirkpatrick, J.F. Smith, W.L. Larsen, Structures of the intermediate phases Ni10Zr7 and Ni10Hf7, Acta Crystallogr. 15 (1962) 894–903.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-X75ALV2HEP.ab7b4b","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":18},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02026,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02026},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.21,"value_stored":921.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-QRGFPSGHIV.6c7667","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":19},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09191,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.09191},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.191,"value_stored":919.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-QRGFPSGHIV.bfc161","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":19},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.092,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.092},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.2,"value_stored":920.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-QRGFPSGHIV.eacb89","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":19},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1245,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1245},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":12.446,"value_stored":1244.6},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-MW5MC3XIOX.40ccd6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":20},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0923,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0923},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.23,"value_stored":923.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-MW5MC3XIOX.691c81","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":20},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1249,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1249},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":12.488,"value_stored":1248.8},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-MW5MC3XIOX.ff6b22","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":20},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09213,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.09213},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.213,"value_stored":921.3},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.304c1a","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Zr1","species":"Zr","wyckoff":"4b","x":0.0,"y":0.0,"z":0.5}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.478595","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Ni3","species":"Ni","wyckoff":"8c","x":0.10642,"y":0.10466,"z":0.99856}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.57636f","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Zr3","species":"Zr","wyckoff":"8c","x":0.18552,"y":0.68616,"z":0.49788}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.6587c2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Zr4","species":"Zr","wyckoff":"8c","x":0.24714,"y":0.74666,"z":0.74961}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.67c188","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09573,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.09573},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":12.432,"value_stored":1243.2},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.94dc4c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07075,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07075},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.188,"value_stored":918.8},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.a7e504","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Ni1","species":"Ni","wyckoff":"8c","x":0.00537,"y":0.20635,"z":0.35348}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.b9b253","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Zr2","species":"Zr","wyckoff":"8c","x":0.00052,"y":0.0001,"z":0.80826}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.c35453","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07072,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07072},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.184,"value_stored":918.4},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.d7ce36","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Ni5","species":"Ni","wyckoff":"8c","x":0.20942,"y":0.50813,"z":0.1468}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.df4f4b","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Ni4","species":"Ni","wyckoff":"8c","x":0.20721,"y":0.506,"z":0.85583}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7SCIEAZJA.e987c6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":21},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"label":"Ni2","species":"Ni","wyckoff":"8c","x":0.01203,"y":0.20851,"z":0.64343}],"space_group":"Pbca"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90135-8","first_author":"Glimois","kind":"unknown","label":"35","paper":"doi:10.1016/0022-5088(79)90135-8","reference":"J.L. Glimois, C. Becle, G. Develey, J.M. Moreau, Crystal structure of the intermetallic compound Ni11Zr9, J. Less-Common Met 64 (1979) 87–90.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-62SS2FSLUO.59e9c1","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":22},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02174,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02174},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.881,"value_stored":988.1},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90135-8","first_author":"Glimois","kind":"unknown","label":"35","paper":"doi:10.1016/0022-5088(79)90135-8","reference":"J.L. Glimois, C. Becle, G. Develey, J.M. Moreau, Crystal structure of the intermetallic compound Ni11Zr9, J. Less-Common Met 64 (1979) 87–90.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-62SS2FSLUO.db9624","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":22},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01454,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01454},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.611,"value_stored":661.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-TTFWLDEV2A.543b96","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":23},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06472,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06472},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.472,"value_stored":647.2},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-TTFWLDEV2A.a16c8e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":23},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1001,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1001},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.012,"value_stored":1001.2},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-CKWMMF6DPE.91c380","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":24},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0221,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0221},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.044,"value_stored":1004.4},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-CKWMMF6DPE.98179f","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":24},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01428,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01428},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.492,"value_stored":649.2},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.3ca518","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04987,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04987},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.476,"value_stored":647.6},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.67fd4c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"label":"Zr1","species":"Zr","wyckoff":"8h","x":0.08525,"y":0.25101,"z":0.5}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.755bf7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"label":"Ni2","species":"Ni","wyckoff":"4d","x":0.0,"y":0.5,"z":0.25}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.9acd89","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"label":"Ni3","species":"Ni","wyckoff":"2b","x":0.0,"y":0.0,"z":0.5}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.b2c7f9","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"label":"Ni1","species":"Ni","wyckoff":"16i","x":0.11938,"y":0.77587,"z":0.20486}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.bfc53a","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"label":"Zr3","species":"Zr","wyckoff":"2a","x":0.0,"y":0.0,"z":0.0}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.d19cdc","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"label":"Zr2","species":"Zr","wyckoff":"8h","x":0.0899,"y":0.31195,"z":0.0}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4BI2UD7JQY.e73f9d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":25},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07696,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07696},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.995,"value_stored":999.5},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-BAJJX46553.066ca0","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":26},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02186,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02186},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.937,"value_stored":993.7},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-BAJJX46553.e13558","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":26},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00719,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00719},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.268,"value_stored":326.8},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-BAJJX46553.fe2f45","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":26},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009022,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009022},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.101,"value_stored":410.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-HWFN52KJAA.456c89","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":27},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1001,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1001},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.012,"value_stored":1001.2},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-HWFN52KJAA.5a003b","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":27},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0408,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0408},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.08,"value_stored":408.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-HWFN52KJAA.e845b2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":27},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03303,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.03303},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.303,"value_stored":330.3},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-HR2CN66NRK.4a3fa0","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":28},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r28#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04097,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04097},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.097,"value_stored":409.7},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-HR2CN66NRK.d9e9e8","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":28},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r28#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1006,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1006},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.057,"value_stored":1005.7},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-HR2CN66NRK.e9a7b9","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":28},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r28#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03311,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.03311},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.311,"value_stored":331.1},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-VYC6ICJ4S5.15984d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":29},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r29#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07702,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07702},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.002,"value_stored":1000.2},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-VYC6ICJ4S5.894fdb","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":29},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r29#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0313,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.0313},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.065,"value_stored":406.5},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-VYC6ICJ4S5.b5ebbc","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":29},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r29#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02549,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02549},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.31,"value_stored":331.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-3UMPJM2PHF.050c2c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":30},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01425,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01425},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.477,"value_stored":647.7},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-3UMPJM2PHF.733566","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":30},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01153,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01153},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.241,"value_stored":524.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-VXTFTETY6A.58e91a","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":31},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05221,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.05221},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.221,"value_stored":522.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:computation_context"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-VXTFTETY6A.f84e98","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":31},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_first_principles","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06515,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06515},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.515,"value_stored":651.5},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-RBPWCQ6WL6.9bcb74","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":32},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r32#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01436,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01436},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.526,"value_stored":652.6},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-RBPWCQ6WL6.f28dbc","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":32},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r32#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01156,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01156},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.254,"value_stored":525.4},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-A2JRANT3ZP.0d2e0c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":33},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","sites":[{"label":"Ni1","species":"Ni","wyckoff":"4a","x":0.0,"y":0.0,"z":0.25}],"space_group":"I4/mcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-A2JRANT3ZP.74efa1","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":33},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0501,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.0501},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.507,"value_stored":650.7},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-A2JRANT3ZP.887201","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":33},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04027,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04027},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.23,"value_stored":523.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-A2JRANT3ZP.f5a3b0","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p2/tab-2","row":33},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p2/tab-2/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","sites":[{"label":"Zr1","species":"Zr","wyckoff":"8h","x":0.83721,"y":0.33721,"z":0.0}],"space_group":"I4/mcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"},{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-7ABE7RLFKA","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":1},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01475,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01475},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.7064,"value_stored":670.64},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-KMW2IIR5XH","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01477,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01477},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.713,"value_stored":671.3},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-76AN5CJL3Z","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":3},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01481,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01481},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.734,"value_stored":673.4},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-OE4NB25O5R","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":4},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"cF24"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05167,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.05167},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.71,"value_stored":671.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.011ea0","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.00000 0.00000 0.50000","label":"Zr1","species":"Zr","wyckoff":"4b","x":0.0,"y":0.0,"z":0.5}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.5aaf92","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.00052 0.00010 0.80826","label":"Zr2","species":"Zr","wyckoff":"8c","x":0.00052,"y":0.0001,"z":0.80826}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.5b6da3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.18552 0.68616 0.49788","label":"Zr3","species":"Zr","wyckoff":"8c","x":0.18552,"y":0.68616,"z":0.49788}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.6f7a5d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.10642 0.10466 0.99856","label":"Ni3","species":"Ni","wyckoff":"8c","x":0.10642,"y":0.10466,"z":0.99856}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.7d7ddc","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.00537 0.20635 0.35348","label":"Ni1","species":"Ni","wyckoff":"8c","x":0.00537,"y":0.20635,"z":0.35348}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.b5b86b","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.01203 0.20851 0.64343","label":"Ni2","species":"Ni","wyckoff":"8c","x":0.01203,"y":0.20851,"z":0.64343}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.ce4513","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.20721 0.50600 0.85583","label":"Ni4","species":"Ni","wyckoff":"8c","x":0.20721,"y":0.506,"z":0.85583}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.e6d278","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.20942 0.50813 0.14680","label":"Ni5","species":"Ni","wyckoff":"8c","x":0.20942,"y":0.50813,"z":0.1468}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQJFQUKSMO.ecd8dd","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":5},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"sites":[{"coordinates_printed":"0.24714 0.74666 0.74961","label":"Zr4","species":"Zr","wyckoff":"8c","x":0.24714,"y":0.74666,"z":0.74961}]},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90135-8","first_author":"Glimois","kind":"unknown","label":"35","paper":"doi:10.1016/0022-5088(79)90135-8","reference":"J.L. Glimois, C. Becle, G. Develey, J.M. Moreau, Crystal structure of the intermetallic compound Ni11Zr9, J. Less-Common Met 64 (1979) 87–90.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-4FHI3YC54L.053cb5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01454,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01454},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.611,"value_stored":661.1},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"doi":"10.1016/0022-5088(79)90135-8","first_author":"Glimois","kind":"unknown","label":"35","paper":"doi:10.1016/0022-5088(79)90135-8","reference":"J.L. Glimois, C. Becle, G. Develey, J.M. Moreau, Crystal structure of the intermetallic compound Ni11Zr9, J. Less-Common Met 64 (1979) 87–90.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-4FHI3YC54L.5218ef","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02174,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02174},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.881,"value_stored":988.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-VTZA4T4F3H.30c407","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01424,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01424},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.472,"value_stored":647.2},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-VTZA4T4F3H.f7ade8","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02203,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02203},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.012,"value_stored":1001.2},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-IP4SL74JOP.34f188","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01428,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01428},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.492,"value_stored":649.2},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-IP4SL74JOP.e8893e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0221,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0221},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.044,"value_stored":1004.4},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.37b498","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"coordinates_printed":"0.00000 0.50000 0.25000","label":"Ni2","species":"Ni","wyckoff":"4d","x":0.0,"y":0.5,"z":0.25}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.67a0a5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07696,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07696},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.995,"value_stored":999.5},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.73a621","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"coordinates_printed":"0.08525 0.25101 0.50000","label":"Zr1","species":"Zr","wyckoff":"8h","x":0.08525,"y":0.25101,"z":0.5}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.8d0091","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"coordinates_printed":"0.11938 0.77587 0.20486","label":"Ni1","species":"Ni","wyckoff":"16i","x":0.11938,"y":0.77587,"z":0.20486}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.8db8d7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04987,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04987},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.476,"value_stored":647.6},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.b2b570","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"coordinates_printed":"0.08990 0.31195 0.00000","label":"Zr2","species":"Zr","wyckoff":"8h","x":0.0899,"y":0.31195,"z":0.0}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.c017ce","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"coordinates_printed":"0.00000 0.00000 0.00000","label":"Zr3","species":"Zr","wyckoff":"2a","x":0.0,"y":0.0,"z":0.0}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JHR3LM2WV5.c95d8c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":9},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SITE_FRACTIONAL_COORDINATES","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI40","sites":[{"coordinates_printed":"0.00000 0.00000 0.50000","label":"Ni3","species":"Ni","wyckoff":"2b","x":0.0,"y":0.0,"z":0.5}],"space_group":"I4/m"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{},"reason":"no numeric quantity (no value, no printed phase composition)","sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-UYLRB27EMV.8b87e9","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00719,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00719},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.268,"value_stored":326.8},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-UYLRB27EMV.8d43e1","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02186,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02186},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":9.937,"value_stored":993.7},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-UYLRB27EMV.94fadb","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009022,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009022},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.101,"value_stored":410.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-Z3VVGMBAN7.8d6cca","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007267,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007267},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.303,"value_stored":330.3},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-Z3VVGMBAN7.9a166d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02203,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02203},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.012,"value_stored":1001.2},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-Z3VVGMBAN7.ab00ea","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008976,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008976},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.08,"value_stored":408.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-YEKQ6D3JX6.8afa24","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":12},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007284,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007284},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.311,"value_stored":331.1},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-YEKQ6D3JX6.a331c3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":12},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009013,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009013},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.097,"value_stored":409.7},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-YEKQ6D3JX6.c1a970","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":12},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02213,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02213},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":10.057,"value_stored":1005.7},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"NiZr","label_source":"printed_source_page","pearson_symbol":"oS8","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.intermet.2019.106640","pdf_page":3,"pdf_sha256":"63a18f6828c8eb89b35c4b7b7b861441cb6561c5f1815f1ba0fcdc6a03c76fd2","printed":"Phase formula: NiZr, Space group: Cmcm, Pearson symbol: oS8 ... a = 331.0, b = 1000.2, c = 406.5 [PW]","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13,19],"table":"2","table_key":"t148"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8eecf82d118a9d297966283500211ef185caf8061b4ccca2293440d691173cc6","page":3,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"a = 3.31 Å matches the NiZr block cell lines (PW 331.0 pm); block runs from its header to 'Phase formula: NiZr2'","verdict":"confirmed"}},{"after":{"pearson_symbol":"oS8","phase":"NiZr","space_group":"Cmcm"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.intermet.2019.106640","pdf_page":3,"pdf_sha256":"63a18f6828c8eb89b35c4b7b7b861441cb6561c5f1815f1ba0fcdc6a03c76fd2","printed":"Phase formula: NiZr, Space group: Cmcm, Pearson symbol: oS8 ... a = 331.0, b = 1000.2, c = 406.5 [PW]","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13,19],"table":"2","table_key":"t148"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8eecf82d118a9d297966283500211ef185caf8061b4ccca2293440d691173cc6","page":3,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"a = 3.31 Å matches the NiZr block cell lines (PW 331.0 pm); block runs from its header to 'Phase formula: NiZr2'","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:composition","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-5PZTV4EGXX","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":13},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","label_source":"printed_source_page","pearson_symbol":"oS8","structure_basis":"printed_source_page"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","phase":"NiZr","space_group":"Cmcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02549,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02549},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.31,"value_stored":331.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-GQLVHSU4S5.913fef","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01153,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01153},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.241,"value_stored":524.1},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-GQLVHSU4S5.9ea53e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01425,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01425},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.477,"value_stored":647.7},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-D4B3UVXHEZ.32175c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":15},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01433,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01433},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.515,"value_stored":651.5},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-D4B3UVXHEZ.511e07","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":15},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01149,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01149},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.221,"value_stored":522.1},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-5D5UWF3SDB.965237","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01156,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01156},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.254,"value_stored":525.4},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-5D5UWF3SDB.c8e904","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01436,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01436},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.526,"value_stored":652.6},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-LBF6OSYZKP.2bf6b4","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04027,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04027},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.23,"value_stored":523.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-LBF6OSYZKP.a86ddf","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":17},"model":"Mbf8577b3","observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"tI12","space_group":"I4/mcm"},"system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0501,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.0501},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.507,"value_stored":650.7},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"NiZr","label_source":"printed_source_page","pearson_symbol":"oS8","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.intermet.2019.106640","pdf_page":3,"pdf_sha256":"63a18f6828c8eb89b35c4b7b7b861441cb6561c5f1815f1ba0fcdc6a03c76fd2","printed":"Phase formula: NiZr, Space group: Cmcm, Pearson symbol: oS8 ... a = 331.0, b = 1000.2, c = 406.5 [PW]","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13,19],"table":"2","table_key":"t148"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8eecf82d118a9d297966283500211ef185caf8061b4ccca2293440d691173cc6","page":3,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"a = 3.31 Å matches the NiZr block cell lines (PW 331.0 pm); block runs from its header to 'Phase formula: NiZr2'","verdict":"confirmed"}},{"after":{"pearson_symbol":"oS8","phase":"NiZr","space_group":"Cmcm"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.1016/j.intermet.2019.106640","pdf_page":3,"pdf_sha256":"63a18f6828c8eb89b35c4b7b7b861441cb6561c5f1815f1ba0fcdc6a03c76fd2","printed":"Phase formula: NiZr, Space group: Cmcm, Pearson symbol: oS8 ... a = 331.0, b = 1000.2, c = 406.5 [PW]","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[13,19],"table":"2","table_key":"t148"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"8eecf82d118a9d297966283500211ef185caf8061b4ccca2293440d691173cc6","page":3,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"a = 3.31 Å matches the NiZr block cell lines (PW 331.0 pm); block runs from its header to 'Phase formula: NiZr2'","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-WOE7TIFH73","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":19},"method":"ab initio (VASP)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","label_source":"printed_source_page","pearson_symbol":"oS8","structure_basis":"printed_source_page"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","structure":{"pearson_symbol":"oS8","phase":"NiZr","space_group":"Cmcm"},"system":"NI-ZR","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0331,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0331},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.31,"value_stored":331.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"},{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["record_not_on_page"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"record_not_on_page","detail":"No printed NiZr cell line has a 331.x with c 408: PW 331.0/406.5, [29] 330.3/408, [30] 331.1/409.7. Pair a 3.31 / c 4.08 mixes two lines; phase UNKNOWN and no b. Correct values already stored by other records.","effect":"not_accepted","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (phase, t148)","image_sha256":"537cb0526c02142b482b13d9cc004b3b492398eae3c90cd4052da2fb952c923b","page":3,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"NiZr block, 4 cell-parameter lines; none prints a = 331.0 together with c = 408","verdict":"confirmed"}}],"id":"ORC-UGO6XCZEPF.075869","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":22},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007282,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007282},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":3.31,"value_stored":331.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Villars","kind":"assessment","label":"27","reference":"P. Villars, Pearson’s Handbook: Desk Edition: Crystallographic Data for Intermetallic Phases, vol. 1, ASM international Materials Park, OH, 1997.","status":"resolved","year":"1997"},{"first_author":"Kirkpatrick","kind":"unknown","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"},{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"},{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["record_not_on_page"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"record_not_on_page","detail":"No printed NiZr cell line has a 331.x with c 408: PW 331.0/406.5, [29] 330.3/408, [30] 331.1/409.7. Pair a 3.31 / c 4.08 mixes two lines; phase UNKNOWN and no b. Correct values already stored by other records.","effect":"not_accepted","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (phase, t148)","image_sha256":"537cb0526c02142b482b13d9cc004b3b492398eae3c90cd4052da2fb952c923b","page":3,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"NiZr block, 4 cell-parameter lines; none prints a = 331.0 together with c = 408","verdict":"confirmed"}}],"id":"ORC-UGO6XCZEPF.210cf4","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-2","row":22},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"UNKNOWN"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-2/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008976,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008976},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.08,"value_stored":408.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0022-5088(83)90497-6","first_author":"Gachon","kind":"unknown","label":"40","paper":"doi:10.1016/0022-5088(83)90497-6","reference":"J.C. Gachon, M. Dirand, J. Hertz, Enthalpic and structural studies of the NiZr system, J. Less Common. Met. 92 (1983) 307–315.","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["molar_basis_unverified"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"molar_basis_unverified","detail":"Table 6 prints J/mol for Ni5Zr, while the release normalizes to J/mol-atom by a magnitude heuristic; the page does not state that basis.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-27; Codex Y11 blind page reading (ORCHID-Y11-20261027-v1), confirmed by a Claude blind check; AI-assisted","image_sha256":"811f8af8c01baf34fbaa3c49fc3c26bcf0825a58d7828706d3ae8c6b5312bcc3","page":7,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"The numerical value may be correct, but its molar normalization is not independently fit-safe from the page. Proposed exclusion for 2026.10.1 pending source-level resolution.","verdict":"confirmed"}}],"id":"ORC-JHGFPEFR4Q","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":1},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-31.8,"value_printed":-31800.0,"value_stored":-31800.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1063/1.333963","first_author":"Henaff","kind":"unknown","label":"7","paper":"doi:10.1063/1.333963","reference":"M.P. Henaff, C. Colinet, A. Pasturel, K.H.J. Buschow, Study of the enthalpies of formation and crystallization in the system Zr-Ni, J. Appl. Phys. 56 (1984) 307–310.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["pa_molar_basis_requires_confirmation"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"pa_molar_basis_requires_confirmation","detail":"ORCHID-PA-20261028-v1: UNRESOLVED Table6 Ni5Zr -34980 andNiZr2 -30700 J/mol formation; table/figure do not explicitly define peratom versus performula. No rescaling without supporting basis definition. Supplementary PDF p5 lists formula-siz","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"Codex rendered-page review; AI-assisted; ORCHID-PA-20261028-v1","image_sha256":"eb2ee7f03d835c755df8d14654ef29f8e0f8a68307599c0773fcbae5b0f52d0f","page":7,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"UNRESOLVED Table6 Ni5Zr -34980 andNiZr2 -30700 J/mol formation; table/figure do not explicitly define peratom versus performula. No rescaling without supporting basis definition. Supplementary PDF p5 lists formula-sized model energies, distinct from comparison Table6; the imported experimental denominator is not explicitly defined. No rescaling justified.","verdict":"confirmed"}}],"id":"ORC-NBII3YNUOQ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":2},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":6.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":6.7,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":6.7},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-34.98,"value_printed":-34980.0,"value_stored":-34980.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"18","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.K. Shakhpazov, A.A. Kodentsov, Thermodynamic properties and phase equilibria in the nickel–zirconium system. the liquid to amorphous state transition, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-DW34TPDF4Z","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":3},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-31.4,"value_printed":-31400.0,"value_stored":-31400.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(85)90032-x","first_author":"Colinet","kind":"assessment","label":"46","paper":"doi:10.1016/0364-5916(85)90032-x","reference":"C. Colinet, A. Pasturel, P. Hicter, Trends in cohesive energy of transition metal alloys, Calphad 9 (1) (1985) 71–99.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Y5XIVNG6DK","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":4},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.95},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-39.0,"value_printed":-39000.0,"value_stored":-39000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JAK7P56BTV","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":5},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.3647},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-27.294,"value_printed":-27294.0,"value_stored":-27294.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-RS6VJRJSVB","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":6},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5679},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-31.358,"value_printed":-31358.0,"value_stored":-31358.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-32XE34GMC6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":7},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5438},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-30.876,"value_printed":-30876.0,"value_stored":-30876.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YBD3FC5VSL","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":8},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.95545},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-39.109,"value_printed":-39109.0,"value_stored":-39109.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-FAPCA6PXNQ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":9},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.8056},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-36.112,"value_printed":-36112.0,"value_stored":-36112.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-OJMHUMMPVX","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":10},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni5Zr","model_phase":"NI5ZR_C15B"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.60045},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-32.009,"value_printed":-32009.0,"value_stored":-32009.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1063/1.333963","first_author":"Henaff","kind":"unknown","label":"7","paper":"doi:10.1063/1.333963","reference":"M.P. Henaff, C. Colinet, A. Pasturel, K.H.J. Buschow, Study of the enthalpies of formation and crystallization in the system Zr-Ni, J. Appl. Phys. 56 (1984) 307–310.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-E4GHYBSZIC","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":11},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.48},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.48},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-45.94,"value_printed":-45940.0,"value_stored":-45940.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/s0925-8388(98)00246-1","first_author":"Guo","kind":"unknown","label":"14","paper":"doi:10.1016/s0925-8388(98)00246-1","reference":"Q. Guo, O.J. Kleppa, Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by hightemperature direct synthesis calorimetry: II. Alloys of (Ti, Zr, Hf) with (Co, Ni), J. Alloy. Comp. 269 (1998) 181–186.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-GU43PC6QE6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":12},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.7},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-40.6,"value_printed":-40600.0,"value_stored":-40600.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"18","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.K. Shakhpazov, A.A. Kodentsov, Thermodynamic properties and phase equilibria in the nickel–zirconium system. the liquid to amorphous state transition, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-NZMKKYQGQA","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":13},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-42.1,"value_printed":-42100.0,"value_stored":-42100.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(85)90032-x","first_author":"Colinet","kind":"assessment","label":"46","paper":"doi:10.1016/0364-5916(85)90032-x","reference":"C. Colinet, A. Pasturel, P. Hicter, Trends in cohesive energy of transition metal alloys, Calphad 9 (1) (1985) 71–99.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-EHLTJH2RZO","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":14},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-45.0,"value_printed":-45000.0,"value_stored":-45000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-CRB6ONXOAH","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":15},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.79105},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-35.821,"value_printed":-35821.0,"value_stored":-35821.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Z37L3H5WDH","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":16},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.07445},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-41.489,"value_printed":-41489.0,"value_stored":-41489.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-7BK2MP7HDT","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":17},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.075},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-41.5,"value_printed":-41500.0,"value_stored":-41500.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-7R2MS4KKVQ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":18},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.34315},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.863,"value_printed":-46863.0,"value_stored":-46863.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-737FGYBVRQ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":19},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.314},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.28,"value_printed":-46280.0,"value_stored":-46280.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-LBKCL7YNK6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":20},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.222222},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.8297},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-36.594,"value_printed":-36594.0,"value_stored":-36594.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(85)90032-x","first_author":"Colinet","kind":"assessment","label":"46","paper":"doi:10.1016/0364-5916(85)90032-x","reference":"C. Colinet, A. Pasturel, P. Hicter, Trends in cohesive energy of transition metal alloys, Calphad 9 (1) (1985) 71–99.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-Z5NYQI7MSF","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":21},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr","model_phase":"NI3ZR_D019"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.45},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-49.0,"value_printed":-49000.0,"value_stored":-49000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-YXJABFTAWI","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":22},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr","model_phase":"NI3ZR_D019"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.98175},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-39.635,"value_printed":-39635.0,"value_stored":-39635.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-KGIVYCHB6R","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":23},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr","model_phase":"NI3ZR_D019"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.2433},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-44.866,"value_printed":-44866.0,"value_stored":-44866.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-6UF2BIWHBG","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":24},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr","model_phase":"NI3ZR_D019"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.2192},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-44.384,"value_printed":-44384.0,"value_stored":-44384.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-IQDGXNPUVC","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":25},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr","model_phase":"NI3ZR_D019"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4743},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-49.486,"value_printed":-49486.0,"value_stored":-49486.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-4NKKPWN3P5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":26},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr","model_phase":"NI3ZR_D019"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.49205},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-49.841,"value_printed":-49841.0,"value_stored":-49841.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-WRGRFW3UT2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":27},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni3Zr","model_phase":"NI3ZR_D019"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.96235},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-39.247,"value_printed":-39247.0,"value_stored":-39247.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0036-9748(80)90208-2","first_author":"Spit","kind":"unknown","label":"39","paper":"doi:10.1016/0036-9748(80)90208-2","reference":"F.H.M. Spit, J.W. Drijver, S. Radelaar, Hydrogen sorption by the metallic glass Ni64Zr36 and by related crystalline compounds, Scr. Metall. 14 (1980) 1071–1076.","status":"resolved","year":"1980"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-7E33JTQBGV","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":28},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8","model_phase":"NI21ZR8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r28#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-45.0,"value_printed":-45000.0,"value_stored":-45000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-6MTO6RBD7I","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":29},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8","model_phase":"NI21ZR8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.38275},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-47.655,"value_printed":-47655.0,"value_stored":-47655.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-VXPSPECYVI","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":30},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8","model_phase":"NI21ZR8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r30#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.14105},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-42.821,"value_printed":-42821.0,"value_stored":-42821.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-STYGBX7V34","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":31},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8","model_phase":"NI21ZR8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.0696},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-41.392,"value_printed":-41392.0,"value_stored":-41392.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-SWHS37PIN2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":32},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8","model_phase":"NI21ZR8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.37215},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-47.443,"value_printed":-47443.0,"value_stored":-47443.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-XR5LQBYAQE","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":33},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.275862},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni21Zr8","model_phase":"NI21ZR8"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.11175},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-42.235,"value_printed":-42235.0,"value_stored":-42235.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-DTOFTSLMYF","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":34},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Pbca)","model_phase":"NI10ZR7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4109},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.218,"value_printed":-48218.0,"value_stored":-48218.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-H4WUSHGUYB","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":35},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Pbca)","model_phase":"NI10ZR7"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r35#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.41945},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.389,"value_printed":-48389.0,"value_stored":-48389.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0036-9748(80)90208-2","first_author":"Spit","kind":"unknown","label":"39","paper":"doi:10.1016/0036-9748(80)90208-2","reference":"F.H.M. Spit, J.W. Drijver, S. Radelaar, Hydrogen sorption by the metallic glass Ni64Zr36 and by related crystalline compounds, Scr. Metall. 14 (1980) 1071–1076.","status":"resolved","year":"1980"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-UNCLQ3XYUM.431024","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":36},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r36#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.0,"value_printed":-48000.0,"value_stored":-48000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0036-9748(80)90208-2","first_author":"Spit","kind":"unknown","label":"39","paper":"doi:10.1016/0036-9748(80)90208-2","reference":"F.H.M. Spit, J.W. Drijver, S. Radelaar, Hydrogen sorption by the metallic glass Ni64Zr36 and by related crystalline compounds, Scr. Metall. 14 (1980) 1071–1076.","status":"resolved","year":"1980"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-UNCLQ3XYUM.e16ebf","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":36},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r36#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.0,"value_printed":-48000,"value_stored":-48000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1063/1.333963","first_author":"Henaff","kind":"unknown","label":"7","paper":"doi:10.1063/1.333963","reference":"M.P. Henaff, C. Colinet, A. Pasturel, K.H.J. Buschow, Study of the enthalpies of formation and crystallization in the system Zr-Ni, J. Appl. Phys. 56 (1984) 307–310.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-KXUDL7OM6F.40519d","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":37},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r37#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":5.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-52.17,"value_printed":-52170.0,"value_stored":-52170.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1063/1.333963","first_author":"Henaff","kind":"unknown","label":"7","paper":"doi:10.1063/1.333963","reference":"M.P. Henaff, C. Colinet, A. Pasturel, K.H.J. Buschow, Study of the enthalpies of formation and crystallization in the system Zr-Ni, J. Appl. Phys. 56 (1984) 307–310.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-KXUDL7OM6F.6f0ea7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":37},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r37#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":5.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-52.17,"value_printed":-52170,"value_stored":-52170.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"18","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.K. Shakhpazov, A.A. Kodentsov, Thermodynamic properties and phase equilibria in the nickel–zirconium system. the liquid to amorphous state transition, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-YD4ZMVK7XT.3bcb4a","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":38},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r38#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.7,"value_printed":-46700,"value_stored":-46700.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"18","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.K. Shakhpazov, A.A. Kodentsov, Thermodynamic properties and phase equilibria in the nickel–zirconium system. the liquid to amorphous state transition, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-YD4ZMVK7XT.dcfda7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":38},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r38#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.7,"value_printed":-46700.0,"value_stored":-46700.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(85)90032-x","first_author":"Colinet","kind":"assessment","label":"46","paper":"doi:10.1016/0364-5916(85)90032-x","reference":"C. Colinet, A. Pasturel, P. Hicter, Trends in cohesive energy of transition metal alloys, Calphad 9 (1) (1985) 71–99.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-PEO5MLDXF3.d6eff6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":39},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r39#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-54.0,"value_printed":-54000.0,"value_stored":-54000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(85)90032-x","first_author":"Colinet","kind":"assessment","label":"46","paper":"doi:10.1016/0364-5916(85)90032-x","reference":"C. Colinet, A. Pasturel, P. Hicter, Trends in cohesive energy of transition metal alloys, Calphad 9 (1) (1985) 71–99.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-PEO5MLDXF3.ef2c69","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":39},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r39#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-54.0,"value_printed":-54000,"value_stored":-54000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-LWR5ZGMXIA.88d30a","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":40},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r40#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.60485},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-52.097,"value_printed":-52097,"value_stored":-52097.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-LWR5ZGMXIA.e0b48e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":40},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r40#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.60485},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-52.097,"value_printed":-52097.0,"value_stored":-52097.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-MPXS4RSC5U.4e3999","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":41},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r41#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.1902},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-43.804,"value_printed":-43804,"value_stored":-43804.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:composition","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-MPXS4RSC5U.51f8c5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":41},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r41#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.1902},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-43.804,"value_printed":-43804.0,"value_stored":-43804.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-PK7BHD23RS.0a7ff9","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":42},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r42#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.21915},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-44.383,"value_printed":-44383,"value_stored":-44383.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:composition","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-PK7BHD23RS.6b85cd","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":42},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r42#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.21915},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-44.383,"value_printed":-44383.0,"value_stored":-44383.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:composition","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-2WUWUQ34HC.1d274e","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":43},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r43#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4108},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.216,"value_printed":-48216.0,"value_stored":-48216.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-2WUWUQ34HC.d31fe8","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":43},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r43#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4108},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.216,"value_printed":-48216,"value_stored":-48216.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-FANXAX2G6R.023ee4","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":44},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r44#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4209},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.418,"value_printed":-48418.0,"value_stored":-48418.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-FANXAX2G6R.d42dc8","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":44},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r44#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4209},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.418,"value_printed":-48418,"value_stored":-48418.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Z7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-ULXNGAS2A5.7c5a7c","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":45},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.411765},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Zr7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r45#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.34085},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.817,"value_printed":-46817,"value_stored":-46817.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_label_readings_disagree"],"review_state":"extracted","specification_gaps":["state:T_K","state:composition","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"phase_label_readings_disagree","detail":"the same printed value is also stored with phase(s) Ni10Zr7 (Cmce)","effect":"not_espei_ready","gate":"G7"}],"id":"ORC-ULXNGAS2A5.faaf83","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":45},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni10Z7 (Cmce)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r45#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.34085},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.817,"value_printed":-46817.0,"value_stored":-46817.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-BZZILRQMJL","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":46},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r46#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.26075},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-25.215,"value_printed":-25215.0,"value_stored":-25215.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-VNEVGK7Q6I","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":47},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r47#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.85735},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-37.147,"value_printed":-37147.0,"value_stored":-37147.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-FFCQ3E4LDH","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":48},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r48#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.985},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-39.7,"value_printed":-39700.0,"value_stored":-39700.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-5F6KHYBYYD","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":49},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r49#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.0733},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-41.466,"value_printed":-41466.0,"value_stored":-41466.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-CA44EFIYON","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":50},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r50#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.084},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-41.68,"value_printed":-41680.0,"value_stored":-41680.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-GB6NYFOTIB","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":51},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.45},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r51#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.33725},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.745,"value_printed":-46745.0,"value_stored":-46745.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1063/1.333963","first_author":"Henaff","kind":"unknown","label":"7","paper":"doi:10.1063/1.333963","reference":"M.P. Henaff, C. Colinet, A. Pasturel, K.H.J. Buschow, Study of the enthalpies of formation and crystallization in the system Zr-Ni, J. Appl. Phys. 56 (1984) 307–310.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-C4WYA34UNE","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":52},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r52#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.47},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.47},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.53,"value_printed":-48530.0,"value_stored":-48530.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Sidorov","kind":"unknown","label":"9","reference":"O.Y. Sidorov, Y.O. Esin, P.V. Geld, Heats of formation of zirconium alloys with iron, cobalt, nickel, and copper, Rasplavy 3 (3) (1989) 28–33.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-SQKWTPBE3O","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":53},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r53#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-53.0,"value_printed":-53000.0,"value_stored":-53000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/s0925-8388(98)00246-1","first_author":"Guo","kind":"unknown","label":"14","paper":"doi:10.1016/s0925-8388(98)00246-1","reference":"Q. Guo, O.J. Kleppa, Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by hightemperature direct synthesis calorimetry: II. Alloys of (Ti, Zr, Hf) with (Co, Ni), J. Alloy. Comp. 269 (1998) 181–186.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-CKFBRJRIJZ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":54},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r54#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.5},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-50.5,"value_printed":-50500.0,"value_stored":-50500.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"18","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.K. Shakhpazov, A.A. Kodentsov, Thermodynamic properties and phase equilibria in the nickel–zirconium system. the liquid to amorphous state transition, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-XPCTUCJD7M","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":55},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r55#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.5},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.7,"value_printed":-46700.0,"value_stored":-46700.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(81)90015-8","first_author":"Watson","kind":"assessment","label":"45","paper":"doi:10.1016/0364-5916(81)90015-8","reference":"R.E. Watson, L.H. Bennett, Optimized prediction for heats of formation of transition metal alloys, Calphad 5 (1) (1981) 2–40.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-QSMAK57FUU","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":56},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r56#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.41215},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.243,"value_printed":-48243.0,"value_stored":-48243.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(85)90032-x","first_author":"Colinet","kind":"assessment","label":"46","paper":"doi:10.1016/0364-5916(85)90032-x","reference":"C. Colinet, A. Pasturel, P. Hicter, Trends in cohesive energy of transition metal alloys, Calphad 9 (1) (1985) 71–99.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-L7AY7AL264","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":57},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r57#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-50.0,"value_printed":-50000.0,"value_stored":-50000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-EWYB4CEXAQ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":58},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r58#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.5435},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-50.87,"value_printed":-50870.0,"value_stored":-50870.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-ACFGMPKJBB","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":59},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r59#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.19985},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-43.997,"value_printed":-43997.0,"value_stored":-43997.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-H7AA4OGAT3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":60},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r60#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4192},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.384,"value_printed":-48384.0,"value_stored":-48384.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-UMW5SKLJZP","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":61},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r61#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.40685},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.137,"value_printed":-48137.0,"value_stored":-48137.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-I45M3R3FH7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":62},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r62#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.41845},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-48.369,"value_printed":-48369.0,"value_stored":-48369.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-LE7JOZUOLJ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":63},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr","model_phase":"NIZR_B33"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r63#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.3115},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-46.23,"value_printed":-46230.0,"value_stored":-46230.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"18","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.K. Shakhpazov, A.A. Kodentsov, Thermodynamic properties and phase equilibria in the nickel–zirconium system. the liquid to amorphous state transition, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":true,"gate_failures":["pa_molar_basis_requires_confirmation"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"pa_molar_basis_requires_confirmation","detail":"ORCHID-PA-20261028-v1: UNRESOLVED Table6 Ni5Zr -34980 andNiZr2 -30700 J/mol formation; table/figure do not explicitly define peratom versus performula. No rescaling without supporting basis definition. Supplementary PDF p5 lists formula-siz","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"Codex rendered-page review; AI-assisted; ORCHID-PA-20261028-v1","image_sha256":"eb2ee7f03d835c755df8d14654ef29f8e0f8a68307599c0773fcbae5b0f52d0f","page":7,"pdf_sha256_prefix":"63a18f6828c8eb89","seen":"UNRESOLVED Table6 Ni5Zr -34980 andNiZr2 -30700 J/mol formation; table/figure do not explicitly define peratom versus performula. No rescaling without supporting basis definition. Supplementary PDF p5 lists formula-sized model energies, distinct from comparison Table6; the imported experimental denominator is not explicitly defined. No rescaling justified.","verdict":"confirmed"}}],"id":"ORC-2E4AGFCJE5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":64},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r64#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-30.7,"value_printed":-30700.0,"value_stored":-30700.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1063/1.333963","first_author":"Henaff","kind":"unknown","label":"7","paper":"doi:10.1063/1.333963","reference":"M.P. Henaff, C. Colinet, A. Pasturel, K.H.J. Buschow, Study of the enthalpies of formation and crystallization in the system Zr-Ni, J. Appl. Phys. 56 (1984) 307–310.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-T5HGFKTXNE","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":65},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r65#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":6.11},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":6.11,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":6.11},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-37.24,"value_printed":-37240.0,"value_stored":-37240.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/s0925-8388(98)00246-1","first_author":"Guo","kind":"unknown","label":"14","paper":"doi:10.1016/s0925-8388(98)00246-1","reference":"Q. Guo, O.J. Kleppa, Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by hightemperature direct synthesis calorimetry: II. Alloys of (Ti, Zr, Hf) with (Co, Ni), J. Alloy. Comp. 269 (1998) 181–186.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-PG6CDZMBRO","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":66},"method":"experimental","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r66#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":0.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.9},"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-31.2,"value_printed":-31200.0,"value_stored":-31200.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0364-5916(85)90032-x","first_author":"Colinet","kind":"assessment","label":"46","paper":"doi:10.1016/0364-5916(85)90032-x","reference":"C. Colinet, A. Pasturel, P. Hicter, Trends in cohesive energy of transition metal alloys, Calphad 9 (1) (1985) 71–99.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-NJ4YWFRO75","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":67},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r67#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.75},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-35.0,"value_printed":-35000.0,"value_stored":-35000.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.cplett.2007.06.031","first_author":"Zhang","kind":"assessment","label":"47","paper":"doi:10.1016/j.cplett.2007.06.031","reference":"R.F. Zhang, S.H. Sheng, B.X. Liu, Predicting the formation enthalpies of binary intermetallic compounds, Chem. Phys. Lett. 442 (4) (2007) 511–514.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-6SAV7FNKSG","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":68},"method":"empirical","method_basis":"printed in the table row/column","model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r68#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.8644},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-37.288,"value_printed":-37288.0,"value_stored":-37288.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"41","reference":"S. Kirklin, J. E. Saal, B. Meredig, A. Thompson, J. W. Doak, M. Aykol, S. Rühl, C. Wolverton, The open quantum materials database (OQMD): assessing the accuracy of DFT formation energies, Npj Comput. Mater.","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-B4KWZSDQXV","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":69},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r69#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5679},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-31.358,"value_printed":-31358.0,"value_stored":-31358.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1103/physrevb.71.144103","first_author":"Hennig","kind":"unknown","label":"30","paper":"doi:10.1103/physrevb.71.144103","reference":"R.G. Hennig, A.E. Carlsson, K.F. Kelton, C.L. Henley, Ab initio Ti-Zr-Ni phase diagram predicts stability of icosahedral TiZrNi quasicrystals, Phys. Rev. B 71 (2005) 144103.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-NWCFMGE54O","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":70},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r70#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.592},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-31.84,"value_printed":-31840.0,"value_stored":-31840.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.intermet.2014.05.021","first_author":"Du","kind":"unknown","label":"29","paper":"doi:10.1016/j.intermet.2014.05.021","reference":"J. Du, B. Wen, R. Melnik, Y. Kawazoe, First-principles studies on structural, mechanical, thermodynamic and electronic properties of Ni–Zr intermetallic compounds, Intermetallics 54 (2014) 110–119.","status":"resolved","year":"2014"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-NC755NLLRE","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":71},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r71#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.69585},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-33.917,"value_printed":-33917.0,"value_stored":-33917.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-T3CZFXMRMM","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":72},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r72#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.7017},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-34.034,"value_printed":-34034.0,"value_stored":-34034.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-JZ7L3HAQVX","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p7/tab-6","row":73},"model":"Mbf8577b3","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"overall_composition":{"ZR":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"NiZr2","model_phase":"NIZR2_C16"}],"pid":"doi:10.1016/j.intermet.2019.106640/p7/tab-6/r73#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°m","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"NI":{"phase":"FCC_A1"},"ZR":{"phase":"HCP_A3"}},"source_system":"NI-ZR","system":"NI-ZR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5926},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"J/mol","unit_stored":"J/mol-atom","value":-31.852,"value_printed":-31852.0,"value_stored":-31852.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-GQ35TCO4TX","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni7Zr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1713.0,"temperature_printed":"1713","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1713.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"12","reference":"S.A. Pogodin, V.I. Sokorobogatova, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-UW4T27M4RI","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni7Zr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1693.0,"temperature_printed":"1693","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1693.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"17","reference":"E.T. Smith, R.W. Guard, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-KJJD7URAQ4","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":3},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni7Zr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1723.0,"temperature_printed":"1723","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1723.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kramer","kind":"unknown","label":"18","reference":"D. Kramer, Trans. AIME 215 (1959) 256–258.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-I6AUQ3VT7F","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni7Zr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1848.0,"temperature_uncertainty":{"basis":"printed","value":25.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":25.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":25.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1848.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-V4I2WBHVL6","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":5},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni7Zr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1711.0,"temperature_printed":"1711","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1711.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-UCS5DXD53U","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":6},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni7Zr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1713.0,"temperature_printed":"1713","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1713.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-AS7J6VMVJS","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":7},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni7Zr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1711.0,"temperature_printed":"1711","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1711.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.16},"before":{"ZR":0.0016},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.167},"before":{"ZR":0.00167},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-2EUQGT3VU5","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.16},"composition_source":"printed","composition_stored":{"ZR":0.0016},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","composition_stored":{"ZR":0.00167},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → (Ni5Zr)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1573.0,"temperature_printed":"1573","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1573.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"12","reference":"S.A. Pogodin, V.I. Sokorobogatova, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-HQ3UARSZNP","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":9},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.833333,"ZR":0.166667},"composition_source":"formula_nominal","phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → (Ni5Zr)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1573.0,"temperature_printed":"1573","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1573.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"17","reference":"E.T. Smith, R.W. Guard, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.167},"before":{"ZR":0.00167},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-RZNTZTIMP4","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","composition_stored":{"ZR":0.00167},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → (Ni5Zr)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1553.0,"temperature_printed":"1553 ± 10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1553.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kramer","kind":"unknown","label":"18","reference":"D. Kramer, Trans. AIME 215 (1959) 256–258.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.21},"before":{"ZR":0.0021},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.18},"before":{"ZR":0.0018},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-JKN75ZUNYA","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":11},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.21},"composition_source":"printed","composition_stored":{"ZR":0.0021},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.18},"composition_source":"printed","composition_stored":{"ZR":0.0018},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → (Ni5Zr)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1613.0,"temperature_printed":"1613 ± 10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1613.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.149},"before":{"ZR":0.00149},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.157},"before":{"ZR":0.00157},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-5APUUBX3A3","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":12},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.149},"composition_source":"printed","composition_stored":{"ZR":0.00149},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.157},"composition_source":"printed","composition_stored":{"ZR":0.00157},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → (Ni5Zr)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1577.0,"temperature_printed":"1577","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1577.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.144},"before":{"ZR":0.00144},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.167},"before":{"ZR":0.00167},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-U2JNQCDQCF","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":13},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.144},"composition_source":"printed","composition_stored":{"ZR":0.00144},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","composition_stored":{"ZR":0.00167},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → (Ni5Zr)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1573.0,"temperature_printed":"1573","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1573.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.146},"before":{"ZR":0.00146},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.172},"before":{"ZR":0.00172},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-VQC4ZRITGT","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":14},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.146},"composition_source":"printed","composition_stored":{"ZR":0.00146},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.172},"composition_source":"printed","composition_stored":{"ZR":0.00172},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → (Ni5Zr)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1573.0,"temperature_printed":"1573","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1573.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.088},"before":{"ZR":0.00088},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.167},"before":{"ZR":0.00167},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-DEMM72CILB","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":15},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.088},"composition_source":"printed","composition_stored":{"ZR":0.00088},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","composition_stored":{"ZR":0.00167},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → (Ni) + (Ni5Zr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1443.0,"temperature_printed":"1443","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1443.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"12","reference":"S.A. Pogodin, V.I. Sokorobogatova, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.098},"before":{"ZR":0.00098},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.006},"before":{"ZR":6e-05},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-RAARFD6GDJ","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.098},"composition_source":"printed","composition_stored":{"ZR":0.00098},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.006},"composition_source":"printed","composition_stored":{"ZR":6e-05},"phase":"(Ni)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.833333,"ZR":0.166667},"composition_source":"formula_nominal","phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → (Ni) + (Ni5Zr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1448.0,"temperature_printed":"1448","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1448.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"17","reference":"E.T. Smith, R.W. Guard, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.097},"before":{"ZR":0.00097},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.167},"before":{"ZR":0.00167},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-AXYCPEDOHO","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":17},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.097},"composition_source":"printed","composition_stored":{"ZR":0.00097},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","composition_stored":{"ZR":0.00167},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → (Ni) + (Ni5Zr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1483.0,"temperature_printed":"1483","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1483.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kramer","kind":"unknown","label":"18","reference":"D. Kramer, Trans. AIME 215 (1959) 256–258.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.085},"before":{"ZR":0.00085},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.15},"before":{"ZR":0.0015},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-NZGJG3UNAO","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.085},"composition_source":"printed","composition_stored":{"ZR":0.00085},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.15},"composition_source":"printed","composition_stored":{"ZR":0.0015},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → (Ni) + (Ni5Zr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1458.0,"temperature_printed":"1458","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1458.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.089},"before":{"ZR":0.00089},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.0095},"before":{"ZR":9.5e-05},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.149},"before":{"ZR":0.00149},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-GYYEMSQCBY","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":19},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.089},"composition_source":"printed","composition_stored":{"ZR":0.00089},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.0095},"composition_source":"printed","composition_stored":{"ZR":9.5e-05},"phase":"(Ni)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.149},"composition_source":"printed","composition_stored":{"ZR":0.00149},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → (Ni) + (Ni5Zr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1437.0,"temperature_printed":"1437","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1437.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.095},"before":{"ZR":0.00095},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.0126},"before":{"ZR":0.000126},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.167},"before":{"ZR":0.00167},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-GFR4653GOO","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":20},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.095},"composition_source":"printed","composition_stored":{"ZR":0.00095},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.0126},"composition_source":"printed","composition_stored":{"ZR":0.000126},"phase":"(Ni)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","composition_stored":{"ZR":0.00167},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → (Ni) + (Ni5Zr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1444.0,"temperature_printed":"1444","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1444.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.09},"before":{"ZR":0.0009},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.0092},"before":{"ZR":9.2e-05},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.149},"before":{"ZR":0.00149},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(Ni5Zr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-WZENMCBIKM","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":21},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.09},"composition_source":"printed","composition_stored":{"ZR":0.0009},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.0092},"composition_source":"printed","composition_stored":{"ZR":9.2e-05},"phase":"(Ni)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.149},"composition_source":"printed","composition_stored":{"ZR":0.00149},"phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → (Ni) + (Ni5Zr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1443.0,"temperature_printed":"1443","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1443.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.34},"before":{"ZR":0.0034},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.286},"before":{"ZR":0.00286},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-BZQVQ22SDS","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":22},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.34},"composition_source":"printed","composition_stored":{"ZR":0.0034},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.286},"composition_source":"printed","composition_stored":{"ZR":0.00286},"phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → Ni21Zr8","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1453.0,"temperature_printed":"1453","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1453.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"17","reference":"E.T. Smith, R.W. Guard, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.333},"before":{"ZR":0.00333},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.286},"before":{"ZR":0.00286},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-PUFACWHE7A","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":23},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.333},"composition_source":"printed","composition_stored":{"ZR":0.00333},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.286},"composition_source":"printed","composition_stored":{"ZR":0.00286},"phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → Ni21Zr8","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1453.0,"temperature_printed":"1453","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1453.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.32},"before":{"ZR":0.0032},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-ETKCW3FSZD","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":24},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.32},"composition_source":"printed","composition_stored":{"ZR":0.0032},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → Ni21Zr8","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1454.0,"temperature_printed":"1454","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1454.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.326},"before":{"ZR":0.00326},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-PK53BXJDPD","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":25},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.326},"composition_source":"printed","composition_stored":{"ZR":0.00326},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → Ni21Zr8","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1452.0,"temperature_printed":"1452","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1452.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.33},"before":{"ZR":0.0033},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-3NLCT53QQI","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":26},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.33},"composition_source":"printed","composition_stored":{"ZR":0.0033},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 → Ni21Zr8","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1453.0,"temperature_printed":"1453","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1453.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"19","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, J. Less-Common Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.25},"before":{"ZR":0.0025},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni3Zr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-M7E32VBTQP","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":27},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.25},"composition_source":"printed","composition_stored":{"ZR":0.0025},"phase":"Ni3Zr"}],"phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni3Zr","model_phase":"NI3ZR_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni7Zr2 + Ni21Zr8 → Ni3Zr","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1193.0,"temperature_printed":"1193 ± 10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1193.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.25},"before":{"ZR":0.0025},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni3Zr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-S2NRSUKN45","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":28},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.25},"composition_source":"printed","composition_stored":{"ZR":0.0025},"phase":"Ni3Zr"}],"phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni3Zr","model_phase":"NI3ZR_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni7Zr2 + Ni21Zr8 → Ni3Zr","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1197.0,"temperature_printed":"1197","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1197.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.22},"before":{"ZR":0.0022},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni7Zr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.25},"before":{"ZR":0.0025},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni3Zr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-O4OLHKO3UM","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":29},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","composition_stored":{"ZR":0.0022},"phase":"Ni7Zr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.25},"composition_source":"printed","composition_stored":{"ZR":0.0025},"phase":"Ni3Zr"}],"phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni3Zr","model_phase":"NI3ZR_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r29#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni7Zr2 + Ni21Zr8 → Ni3Zr","type":"peritectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1193.0,"temperature_printed":"1193","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectoid","transition_kind_printed":"Peritectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1193.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-24O2CWQRSF","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":30},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r30#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → NiZr","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1533.0,"temperature_printed":"1533","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1533.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"12","reference":"S.A. Pogodin, V.I. Sokorobogatova, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-6R7NLJQGKF","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":31},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r31#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → NiZr","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1483.0,"temperature_printed":"1483","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1483.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"11","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-VXBPYY4YCU","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":32},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → NiZr","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1743.0,"temperature_printed":"~1743","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1743.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"17","reference":"E.T. Smith, R.W. Guard, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-L7C7XTPSMQ","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":33},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r33#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → NiZr","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1623.0,"temperature_printed":"1623","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1623.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-BWL7QUNDLI","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":34},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r34#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → NiZr","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1529.0,"temperature_printed":"1529","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1529.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-QILSZU3Y77","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":35},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r35#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → NiZr","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1542.0,"temperature_printed":"1542","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1542.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-WBTGWI2KLK","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":36},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r36#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → NiZr","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1533.0,"temperature_printed":"1533","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1533.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.42},"before":{"ZR":0.0042},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-2KZ2OCZDSJ","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":37},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.42},"composition_source":"printed","composition_stored":{"ZR":0.0042},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r37#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr → Ni11Zr9","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1443.0,"temperature_printed":"1443","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1443.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"17","reference":"E.T. Smith, R.W. Guard, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.44},"before":{"ZR":0.0044},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-TWEN6DM2IB","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":38},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.44},"composition_source":"printed","composition_stored":{"ZR":0.0044},"phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r38#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr → Ni11Zr9","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1468.0,"temperature_printed":"1468 ± 10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1468.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.432},"before":{"ZR":0.00432},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-QD3C3QINEO","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":39},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.432},"composition_source":"printed","composition_stored":{"ZR":0.00432},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r39#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr → Ni11Zr9","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1443.0,"temperature_printed":"1443","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1443.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.424},"before":{"ZR":0.00424},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-IUN6FMCSZC","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":40},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.424},"composition_source":"printed","composition_stored":{"ZR":0.00424},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r40#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr → Ni11Zr9","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1450.0,"temperature_printed":"1450","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1450.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.438},"before":{"ZR":0.00438},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-DDX7CUFCPX","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":41},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.438},"composition_source":"printed","composition_stored":{"ZR":0.00438},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r41#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr → Ni11Zr9","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1443.0,"temperature_printed":"1443","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1443.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.42},"before":{"ZR":0.0042},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.41},"before":{"ZR":0.0041},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-3CEUEHB7YJ","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":42},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.42},"composition_source":"printed","composition_stored":{"ZR":0.0042},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.41},"composition_source":"printed","composition_stored":{"ZR":0.0041},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r42#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni11Zr9 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1433.0,"temperature_printed":"1433","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1433.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.416},"before":{"ZR":0.00416},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.419},"before":{"ZR":0.00419},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["reaction_class_conflicts_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"reaction_class_conflicts_printed_reaction","detail":"class 'peritectic' but the printed reaction 'L → Ni11Zr9 + Ni10Zr7' reads 'eutectic'","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-XYI3MSFAYH","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":43},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.416},"composition_source":"printed","composition_stored":{"ZR":0.00416},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.419},"composition_source":"printed","composition_stored":{"ZR":0.00419},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r43#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni11Zr9 + Ni10Zr7","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1425.0,"temperature_printed":"1425","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1425.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.41},"before":{"ZR":0.0041},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.412},"before":{"ZR":0.00412},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["reaction_class_conflicts_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"reaction_class_conflicts_printed_reaction","detail":"class 'peritectic' but the printed reaction 'L → Ni11Zr9 + Ni10Zr7' reads 'eutectic'","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-IZJWCK62IY","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":44},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.41},"composition_source":"printed","composition_stored":{"ZR":0.0041},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.412},"composition_source":"printed","composition_stored":{"ZR":0.00412},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r44#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni11Zr9 + Ni10Zr7","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1431.0,"temperature_printed":"1431","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1431.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.426},"before":{"ZR":0.00426},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.412},"before":{"ZR":0.00412},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-V5Z5TIA5WN","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":45},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.426},"composition_source":"printed","composition_stored":{"ZR":0.00426},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.412},"composition_source":"printed","composition_stored":{"ZR":0.00412},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r45#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni11Zr9 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1430.0,"temperature_printed":"1430","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1430.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.363},"before":{"ZR":0.00363},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.286},"before":{"ZR":0.00286},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.41},"before":{"ZR":0.0041},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-ECCYEWKITX","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":46},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.363},"composition_source":"printed","composition_stored":{"ZR":0.00363},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.286},"composition_source":"printed","composition_stored":{"ZR":0.00286},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.41},"composition_source":"printed","composition_stored":{"ZR":0.0041},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r46#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni21Zr8 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1333.0,"temperature_printed":"1333","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1333.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"12","reference":"S.A. Pogodin, V.I. Sokorobogatova, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.375},"before":{"ZR":0.00375},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.286},"before":{"ZR":0.00286},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.41},"before":{"ZR":0.0041},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-YFH4R5KW47","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":47},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.375},"composition_source":"printed","composition_stored":{"ZR":0.00375},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.286},"composition_source":"printed","composition_stored":{"ZR":0.00286},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.41},"composition_source":"printed","composition_stored":{"ZR":0.0041},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r47#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni21Zr8 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1343.0,"temperature_printed":"1343","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1343.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"17","reference":"E.T. Smith, R.W. Guard, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.37},"before":{"ZR":0.0037},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.286},"before":{"ZR":0.00286},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.44},"before":{"ZR":0.0044},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-UKSMTXWLA3","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":48},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.37},"composition_source":"printed","composition_stored":{"ZR":0.0037},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.286},"composition_source":"printed","composition_stored":{"ZR":0.00286},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.44},"composition_source":"printed","composition_stored":{"ZR":0.0044},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r48#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni21Zr8 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1343.0,"temperature_printed":"1343 ± 10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1343.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"19","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, J. Less-Common Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.36},"before":{"ZR":0.0036},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.412},"before":{"ZR":0.00412},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-FOJBOLF25J","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":49},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.36},"composition_source":"printed","composition_stored":{"ZR":0.0036},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.412},"composition_source":"printed","composition_stored":{"ZR":0.00412},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r49#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni21Zr8 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1348.0,"temperature_printed":"1348 ± 10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1348.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.356},"before":{"ZR":0.00356},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.275},"before":{"ZR":0.00275},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.41},"before":{"ZR":0.0041},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-JRDSZSZUXW","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":50},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.356},"composition_source":"printed","composition_stored":{"ZR":0.00356},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.275},"composition_source":"printed","composition_stored":{"ZR":0.00275},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.41},"composition_source":"printed","composition_stored":{"ZR":0.0041},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r50#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni21Zr8 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1344.0,"temperature_printed":"1344","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1344.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.355},"before":{"ZR":0.00355},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.412},"before":{"ZR":0.00412},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-ZWEUNLX4W5","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":51},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.355},"composition_source":"printed","composition_stored":{"ZR":0.00355},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.412},"composition_source":"printed","composition_stored":{"ZR":0.00412},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r51#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni21Zr8 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1347.0,"temperature_printed":"1347","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1347.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.358},"before":{"ZR":0.00358},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.276},"before":{"ZR":0.00276},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni21Zr8]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}},{"after":{"ZR":0.412},"before":{"ZR":0.00412},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"5b532174e15b04db583bab3ba6abb548beecc72bfe73ec275494cd2335480b19","page":3,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p3 (printed 415) Table 1 Ni-Zr header 'Composition of phase, at.% Zr' but Ni7Zr2 printed 0.22, Ni5Zr 0.167, NiZr 0.5, Ni21Zr8 0.276: fractions under an at.% header.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-DYC3VP2DOF","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1","row":52},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.358},"composition_source":"printed","composition_stored":{"ZR":0.00358},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.276},"composition_source":"printed","composition_stored":{"ZR":0.00276},"phase":"Ni21Zr8"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.412},"composition_source":"printed","composition_stored":{"ZR":0.00412},"phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p3/tab-1/r52#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L → Ni21Zr8 + Ni10Zr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1345.0,"temperature_printed":"1345","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1345.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.41},"before":{"ZR":0.0041},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-6XRCGGPGYL","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.41},"composition_source":"printed","composition_stored":{"ZR":0.0041},"phase":"Ni10Zr7"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 -> Ni10Zr7 + NiZr","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1248.0,"temperature_printed":"1248 ± 10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1248.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.422},"before":{"ZR":0.00422},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-ZLLBBRZLL5","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":2},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.422},"composition_source":"printed","composition_stored":{"ZR":0.00422},"phase":"Ni10Zr7"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 -> Ni10Zr7 + NiZr","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1250.0,"temperature_printed":"1250","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1250.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.412},"before":{"ZR":0.00412},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-5FD7MKVKEF","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":3},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.412},"composition_source":"printed","composition_stored":{"ZR":0.00412},"phase":"Ni10Zr7"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 -> Ni10Zr7 + NiZr","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1248.0,"temperature_printed":"1248","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1248.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.45},"before":{"ZR":0.0045},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni11Zr9]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.412},"before":{"ZR":0.00412},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[Ni10Zr7]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-REV2ST7OBA","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":4},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","composition_stored":{"ZR":0.0045},"phase":"Ni11Zr9"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.412},"composition_source":"printed","composition_stored":{"ZR":0.00412},"phase":"Ni10Zr7"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 -> Ni10Zr7 + NiZr","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1248.0,"temperature_printed":"1248","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1248.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-PYSCV6WJD7","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":5},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1393.0,"temperature_printed":"1393","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1393.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"11","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-XKL4E43RML","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1473.0,"temperature_printed":"1473","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1473.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-LP5DDMWN53","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":7},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1402.0,"temperature_printed":"1402","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1402.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-ZMV67SZZ3N","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":8},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1392.0,"temperature_printed":"1392","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1392.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-RVZHJPQTF4","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":9},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1393.0,"temperature_printed":"1393","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1393.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.635},"before":{"ZR":0.00635},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-ILNT2KKQML","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.635},"composition_source":"printed","composition_stored":{"ZR":0.00635},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1283.0,"temperature_printed":"1283","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1283.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"12","reference":"S.A. Pogodin, V.I. Sokorobogatova, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.523},"before":{"ZR":0.00523},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-5J2NRGVXEQ","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":11},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.523},"composition_source":"printed","composition_stored":{"ZR":0.00523},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1438.0,"temperature_printed":"1438","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1438.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"11","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.635},"before":{"ZR":0.00635},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-KK2NKVLMFX","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.635},"composition_source":"printed","composition_stored":{"ZR":0.00635},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1258.0,"temperature_printed":"1258","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1258.0},{"chemical_system":"NI-ZR","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2007.07.001"},"corrections":[{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-PF75M3VXQD","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":13},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1295.0,"temperature_printed":"1295","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1295.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.607},"before":{"ZR":0.00607},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-UBXDP55B3W","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":14},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.607},"composition_source":"printed","composition_stored":{"ZR":0.00607},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1338.0,"temperature_printed":"1338","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1338.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.617},"before":{"ZR":0.00617},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-VH5IVINRHK","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":15},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.617},"composition_source":"printed","composition_stored":{"ZR":0.00617},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1351.0,"temperature_printed":"1351","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1351.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.601},"before":{"ZR":0.00601},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.5},"before":{"ZR":0.005},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-QO63KDRLOZ","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":16},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.601},"composition_source":"printed","composition_stored":{"ZR":0.00601},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","composition_stored":{"ZR":0.005},"phase":"NiZr"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr + NiZr2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1295.0,"temperature_printed":"1295","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1295.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.759},"before":{"ZR":0.00759},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-TMM36VB76L","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":17},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.759},"composition_source":"printed","composition_stored":{"ZR":0.00759},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2 + (βZr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1233.0,"temperature_printed":"1233","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1233.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"11","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.759},"before":{"ZR":0.00759},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.971},"before":{"ZR":0.00971},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-SSMMB6KQON","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.759},"composition_source":"printed","composition_stored":{"ZR":0.00759},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.971},"composition_source":"printed","composition_stored":{"ZR":0.00971},"phase":"(βZr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2 + (βZr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1234.0,"temperature_printed":"1234","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1234.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.773},"before":{"ZR":0.00773},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.974},"before":{"ZR":0.00974},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-X2YEAL4EV7","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":19},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.773},"composition_source":"printed","composition_stored":{"ZR":0.00773},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.974},"composition_source":"printed","composition_stored":{"ZR":0.00974},"phase":"(βZr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2 + (βZr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1227.0,"temperature_printed":"1227","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1227.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.765},"before":{"ZR":0.00765},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.972},"before":{"ZR":0.00972},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-S76FZDJ5GB","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":20},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.765},"composition_source":"printed","composition_stored":{"ZR":0.00765},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.972},"composition_source":"printed","composition_stored":{"ZR":0.00972},"phase":"(βZr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2 + (βZr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1235.0,"temperature_printed":"1235","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1235.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.757},"before":{"ZR":0.00757},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[L]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.971},"before":{"ZR":0.00971},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-Z3MD6SD3RC","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":21},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.757},"composition_source":"printed","composition_stored":{"ZR":0.00757},"phase":"L"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.971},"composition_source":"printed","composition_stored":{"ZR":0.00971},"phase":"(βZr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> NiZr2 + (βZr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1232.0,"temperature_printed":"1232","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1232.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.98},"before":{"ZR":0.0098},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-MNTL6U2IH5","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":22},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.98},"composition_source":"printed","composition_stored":{"ZR":0.0098},"phase":"(βZr)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) -> NiZr2 + (αZr)","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1118.0,"temperature_printed":"1118","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1118.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"11","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.98},"before":{"ZR":0.0098},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-C2ONZXRR6V","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":23},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.98},"composition_source":"printed","composition_stored":{"ZR":0.0098},"phase":"(βZr)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) -> NiZr2 + (αZr)","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1081.0,"temperature_printed":"1081","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1081.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.982},"before":{"ZR":0.00982},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.998},"before":{"ZR":0.00998},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(αZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-A5B3DU4TG3","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":24},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.982},"composition_source":"printed","composition_stored":{"ZR":0.00982},"phase":"(βZr)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.998},"composition_source":"printed","composition_stored":{"ZR":0.00998},"phase":"(αZr)"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) -> NiZr2 + (αZr)","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1100.0,"temperature_printed":"1100","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1100.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"ZR":0.983},"before":{"ZR":0.00983},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":1.0},"before":{"ZR":0.01},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(αZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-7RQCI7ODT6","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":25},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.983},"composition_source":"printed","composition_stored":{"ZR":0.00983},"phase":"(βZr)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":1.0},"composition_source":"printed","composition_stored":{"ZR":0.01},"phase":"(αZr)"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) -> NiZr2 + (αZr)","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1091.0,"temperature_printed":"1091","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1091.0},{"chemical_system":"NI-ZR","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"ZR":0.98},"before":{"ZR":0.0098},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(βZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.667},"before":{"ZR":0.00667},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[NiZr2]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}},{"after":{"ZR":0.99},"before":{"ZR":0.0099},"evidence":{"factor":100,"printed_header":"at.%","printed_values":"mole fractions (<= 1)"},"field":"phase_compositions[(αZr)]","gate":"A1","rule":"fraction_printed_under_atomic_percent_header","visual_check":{"checked":"2026-10-24","image_sha256":"e8502431b28900ebf37ceb5df5be1f7681148286f8484b6e521e01b3086f0997","page":4,"pdf_sha256_prefix":"efca121a1f4e551c","seen":"p4 (printed 416) Table 1 (continued) Ni-Zr header 'Composition of phase, at.% Zr' but NiZr2 printed 0.667, NiZr 0.5, (betaZr) 0.971: fractions under an at.% header (Table 2 below uses real at.%, 54.4-64.7, and is a different table).","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","composition_double_division_corrected":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":3,"id":"ORC-CVHSJWIZDF","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1","row":26},"observation_type":"invariant_reaction","origin":{"basis":"this_work_paper_text_says_both_kinds_in_table","class":"unspecified","measured_in":"doi:10.1016/j.calphad.2007.07.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phase_compositions":[{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.98},"composition_source":"printed","composition_stored":{"ZR":0.0098},"phase":"(βZr)"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.667},"composition_source":"printed","composition_stored":{"ZR":0.00667},"phase":"NiZr2"},{"basis":"mole_fraction (printed as a fraction under an at.% header)","basis_stored":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.99},"composition_source":"printed","composition_stored":{"ZR":0.0099},"phase":"(αZr)"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p4/tab-1/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) -> NiZr2 + (αZr)","type":"eutectoid"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1118.0,"temperature_printed":"1118","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectoid","transition_kind_printed":"Eutectoid","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1118.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.101,"dx":{"L":-0.0002,"Zr2Ni":0.0003,"ZrNi":0.0},"model":"NiZr-11Cac.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-3XBG7ULNGS","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8","row":6},"model":"Maf581929","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.61},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.5},"composition_source":"printed","phase":"ZrNi"},{"basis":"mole_fraction","composition":{"ZR":0.667},"composition_source":"printed","phase":"Zr2Ni"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"ZrNi","mapping_confidence":"confirmed","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Zr2Ni","mapping_confidence":"confirmed","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8/r-unplaced-01522eee#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> ZrNi + Zr2Ni","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1307.15,"temperature_printed":"1034","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1307.15},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-WP5BAHZM4F","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8","row":2},"model":"Maf581929","observation_type":"phase_transition","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.5},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.5},"composition_source":"printed","phase":"ZrNi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"ZrNi","mapping_confidence":"confirmed","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8/r-unplaced-11c21f04#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> ZrNi","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1492.15,"temperature_printed":"1219","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1492.15},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-UMA7DFJEBR","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8","row":1},"model":"Maf581929","observation_type":"phase_transition","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.222},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.222},"composition_source":"printed","phase":"Zr2Ni7"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Zr2Ni7","mapping_confidence":"confirmed","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8/r-unplaced-25639bd9#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> Zr2Ni7","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1658.15,"temperature_printed":"1385","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1658.15},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.423,"dx":{"L":0.0004,"Ni":0.0002,"ZrNi5":0.0002},"model":"NiZr-11Cac.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-5OQCBUVUUG","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8","row":4},"model":"Maf581929","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.09},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.01},"composition_source":"printed","phase":"Ni"},{"basis":"mole_fraction","composition":{"ZR":0.149},"composition_source":"printed","phase":"ZrNi5"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ni","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"ZrNi5","mapping_confidence":"confirmed","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8/r-unplaced-4bb44293#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Ni + ZrNi5","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1432.15,"temperature_printed":"1159","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1432.15},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.494,"dx":{"L":-0.0005,"Zr7Ni10":0.0,"Zr8Ni21":0.0001},"model":"NiZr-11Cac.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-E352C7BNF6","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8","row":5},"model":"Maf581929","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.346},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.276},"composition_source":"printed","phase":"Zr8Ni21"},{"basis":"mole_fraction","composition":{"ZR":0.396},"composition_source":"printed","phase":"Zr7Ni10"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Zr8Ni21","mapping_confidence":"confirmed","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Zr7Ni10","mapping_confidence":"confirmed","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8/r-unplaced-5a0dcb88#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Zr8Ni21 + Zr7Ni10","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1359.15,"temperature_printed":"1086","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1359.15},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-CT4WXZLUF4","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8","row":3},"model":"Maf581929","observation_type":"phase_transition","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.667},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.667},"composition_source":"printed","phase":"Zr2Ni"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Zr2Ni","mapping_confidence":"confirmed","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8/r-unplaced-7e4442ba#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> Zr2Ni","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1357.15,"temperature_printed":"1084","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1357.15},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.292,"dx":{"L":0.0001,"Zr2Ni":0.0003,"bcc - Zr":-0.0002},"model":"NiZr-11Cac.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-X2U4LEGILQ","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8","row":7},"model":"Maf581929","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.772},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.667},"composition_source":"printed","phase":"Zr2Ni"},{"basis":"mole_fraction","composition":{"ZR":0.973},"composition_source":"printed","phase":"bcc - Zr"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Zr2Ni","mapping_confidence":"confirmed","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"bcc - Zr","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2011.10.003/p9/tab-8/r-unplaced-b3fb4b39#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Zr2Ni + bcc - Zr","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1210.15,"temperature_printed":"937","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1210.15},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-ZTF4K6B2ZE","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":1},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.16},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","phase":"Ni5Zr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni5Zr","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni5Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1573.0,"temperature_printed":"1573","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1573.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kramer","kind":"unknown","label":"38","reference":"D. Kramer, On the nickel-rich end of the zirconium-nickel phase diagram, Trans. AIME 215 (1959) 256–258.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-ZB5W2TMOQ4","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":2},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.21},"composition_source":"printed","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.18},"composition_source":"printed","phase":"Ni5Zr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni5Zr","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni5Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1613.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1613.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-FW6UNWSO2F","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":3},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.22},"composition_source":"printed","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","phase":"Ni5Zr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni5Zr","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni5Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1553.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1553.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"49","reference":"S.A. Pogodin, V.I. Sokorobogatova, Alloys of nickel-zirconium, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-32SCJZNHI3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":4},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"},{"basis":"mole_fraction","composition":{"NI":0.833333,"ZR":0.166667},"composition_source":"formula_nominal","phase":"Ni5Zr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni5Zr","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni5Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1573.0,"temperature_printed":"1573","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1573.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-TC2JQE32YS","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"},{"basis":"mole_fraction","composition":{"NI":0.833333,"ZR":0.166667},"composition_source":"formula_nominal","phase":"Ni5Zr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni5Zr","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni5Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1573.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1573.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-2MKGSEJUCQ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":6},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.144},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2222},"composition_source":"printed","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.1634},"composition_source":"printed","phase":"Ni5Zr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni5Zr","model_phase":"NI5ZR_C15B","pearson_symbol":"cF24","prototype":"AuBe5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni5Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1569.0,"temperature_printed":"1569","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1569.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-WFF72E5KZF","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":7},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.34},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni21Zr8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1453.0,"temperature_printed":"1453","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1453.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-FOY633YMXC","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":8},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.333},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni21Zr8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1453.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1453.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HMCSPFPZXO","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":10},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"},{"basis":"mole_fraction","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni21Zr8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1470.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1470.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-BANYHE4AXV","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":11},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.3293},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2222},"composition_source":"printed","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2759},"composition_source":"printed","phase":"Ni21Zr8"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni7Zr2 ⇌ Ni21Zr8"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1462.0,"temperature_printed":"1462","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1462.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-PM235YLC6E","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":12},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.088},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ (Ni) + (Ni5Zr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1443.0,"temperature_printed":"1443","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1443.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kramer","kind":"unknown","label":"38","reference":"D. Kramer, On the nickel-rich end of the zirconium-nickel phase diagram, Trans. AIME 215 (1959) 256–258.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-ADKGCKU2UA","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":13},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.085},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.15},"composition_source":"printed","phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ (Ni) + (Ni5Zr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1458.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1458.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-FSFCZ3YIUG","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":14},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.097},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ (Ni) + (Ni5Zr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1483.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1483.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"49","reference":"S.A. Pogodin, V.I. Sokorobogatova, Alloys of nickel-zirconium, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-DJVVSNOQMZ","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":15},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.098},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.006},"composition_source":"printed","phase":"(Ni)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ (Ni) + (Ni5Zr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1448.0,"temperature_printed":"1448","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1448.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-2F5BSDVOSX","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":16},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ (Ni) + (Ni5Zr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1453.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1453.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-XJVNKVR4N7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":17},"model":"M31bb0da5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.0888},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.0107},"composition_source":"printed","phase":"(Ni)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.1404},"composition_source":"printed","phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ (Ni) + (Ni5Zr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1447.0,"temperature_printed":"1447","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1447.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HE6IQO6THP","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":18},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.42},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr ⇌ Ni11Zr9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1443.0,"temperature_printed":"1443","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1443.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-4UZGRDTK6L","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":19},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr ⇌ Ni11Zr9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1468.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1468.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-U2VXMGIT64","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":20},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr ⇌ Ni11Zr9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1430.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1430.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-O4EQRS7MG2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":21},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.4364},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","phase":"Ni11Zr9"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + NiZr ⇌ Ni11Zr9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1434.0,"temperature_printed":"1434","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1434.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-2VUIKWFOB6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":22},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.42},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni11Zr9 ⇌ Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1433.0,"temperature_printed":"1433","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1433.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-NDA7CNFZO3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":23},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni11Zr9 ⇌ Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1468.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1468.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-FOZX7JPFMW","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":24},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni11Zr9 ⇌ Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1393.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1393.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-57VSMIYFDL","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":25},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.4098},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","phase":"Ni11Zr9"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.4118},"composition_source":"printed","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni11Zr9 ⇌ Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1401.0,"temperature_printed":"1401","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1401.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-IOS2KO2L52","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":26},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.363},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni21Zr8 + Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1333.0,"temperature_printed":"1333","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1333.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-2CD6XBUHWF","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":27},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.36},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni21Zr8 + Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1348.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1348.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-WHIVGQOYVT","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":28},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.37},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni21Zr8 + Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1343.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1343.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"49","reference":"S.A. Pogodin, V.I. Sokorobogatova, Alloys of nickel-zirconium, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-4Q55OKNTX6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":29},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.375},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r29#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni21Zr8 + Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1343.0,"temperature_printed":"1343","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1343.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"PetKov","kind":"unknown","label":"50","reference":"V.V. Pet’Kov, V.Y. Markiv, V.V. Gorskiy, Compounds with an MgCu2-type structure in nickel alloys with zirconium and hafnium, Russ. Metall, (Metally) 2 (1972) 137–139.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-V5K2KWOBVS","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":30},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r30#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni21Zr8 + Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1323.0,"temperature_printed":"1323","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1323.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-B6BFA7LLUA","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":31},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r31#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni21Zr8 + Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1348.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1348.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-QBZWJVVJAL","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":32},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.3628},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2759},"composition_source":"printed","phase":"Ni21Zr8"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.4118},"composition_source":"printed","phase":"Ni10Zr7"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni21Zr8 + Ni10Zr7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1340.0,"temperature_printed":"1340","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1340.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-OVAYYER27E","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":33},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.635},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r33#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr + NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1283.0,"temperature_printed":"1283","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1283.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"49","reference":"S.A. Pogodin, V.I. Sokorobogatova, Alloys of nickel-zirconium, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-7KACDT72DM","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":34},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.523},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r34#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr + NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1438.0,"temperature_printed":"1438","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1438.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"51","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, The Zirconium-Nickel phase diagram, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-YIF3TTONO7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":35},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:28c66992669d0d07","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.635},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r35#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr + NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1258.0,"temperature_printed":"1258","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1258.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Wang","kind":"assessment","label":"17","reference":"N. Wang, C. Li, Z. Du, F. Wang, Experimental study and thermodynamic reassessment of the Ni–Zr system, Calphad 31 (2007) 413–421. 10 A. Jana et al. Intermetallics 116 (2020) 106640","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-UW42Q5LAZY","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":36},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_is_assessment_unconfirmed","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r36#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr + NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1295.0,"temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1295.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-RJRHHSPXX5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":37},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.645},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r37#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr + NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1298.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1298.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HONM67JSDY","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":38},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.6182},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.6667},"composition_source":"printed","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r38#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr + NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1293.0,"temperature_printed":"1293","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1293.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"33","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, The Hf–Ni and Zr–Ni systems in the region 65–80 at.% Ni, J. Less Common. Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HJEDEL7B3G","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":39},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"},{"basis":"mole_fraction","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction","composition":{"NI":0.75,"ZR":0.25},"composition_source":"stoichiometric_model_phase","phase":"Ni3Zr"}],"phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni3Zr","model_phase":"NI3ZR_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r39#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni7Zr2 + Ni21Zr8 ⇌ Ni3Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1193.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1193.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-Z3TTNTTOQB","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":40},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"},{"basis":"mole_fraction","composition":{"NI":0.724138,"ZR":0.275862},"composition_source":"stoichiometric_model_phase","phase":"Ni21Zr8"},{"basis":"mole_fraction","composition":{"NI":0.75,"ZR":0.25},"composition_source":"stoichiometric_model_phase","phase":"Ni3Zr"}],"phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni3Zr","model_phase":"NI3ZR_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r40#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni7Zr2 + Ni21Zr8 ⇌ Ni3Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1261.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1261.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-TLWKJ5RQS7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":41},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2222},"composition_source":"printed","phase":"Ni7Zr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2759},"composition_source":"printed","phase":"Ni21Zr8"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.25},"composition_source":"printed","phase":"Ni3Zr"}],"phases":[{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"},{"label":"Ni21Zr8","model_phase":"NI21ZR8","pearson_symbol":"aP29","prototype":"Hf8Ni21","structure_basis":"mapped_model_phase"},{"label":"Ni3Zr","model_phase":"NI3ZR_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r41#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni7Zr2 + Ni21Zr8 ⇌ Ni3Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1261.0,"temperature_printed":"1261","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1261.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-4EAHDTTZDN","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":42},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"},{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r42#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 ⇌ Ni10Zr7 + NiZr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1248.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1248.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-H7TGIYXKE2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":43},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"},{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r43#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 ⇌ Ni10Zr7 + NiZr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1468.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1468.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.jallcom.2004.01.064","first_author":"Takeshita","kind":"unknown","label":"37","paper":"doi:10.1016/j.jallcom.2004.01.064","reference":"H.T. Takeshita, S. Kondo, H. Miyamura, N. Takeichi, N. Kuriyama, T. Oishi, Reexamination of Zr7Ni10 single-phase region, J. Alloy. Comp. 376 (2004) 268–274.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-UMAUXTSVQT","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":44},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"},{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r44#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 ⇌ Ni10Zr7 + NiZr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1251.0,"temperature_printed":"1251","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1251.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-T4NJQYECEP","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":45},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"},{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r45#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 ⇌ Ni10Zr7 + NiZr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1248.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1248.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1016/j.jallcom.2018.04.019","first_author":"Tao","kind":"assessment","label":"26","paper":"doi:10.1016/j.jallcom.2018.04.019","reference":"X. Tao, P. Yao, W. Wei, H. Chen, Y. Ouyang, Y. Du, Y. Yuan, Q. Peng, An experimental study on the interdiffusion behaviors and mechanical properties of Ni-Zr system, J. Alloy. Comp. 752 (2018) 412–419.","status":"resolved","year":"2018"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-L6VWEUPAQ5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":46},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.55,"ZR":0.45},"composition_source":"stoichiometric_model_phase","phase":"Ni11Zr9"},{"basis":"mole_fraction","composition":{"NI":0.588235,"ZR":0.411765},"composition_source":"stoichiometric_model_phase","phase":"Ni10Zr7"},{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r46#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 ⇌ Ni10Zr7 + NiZr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1206.0,"temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1206.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HZRTCYXFZP","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":47},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.45},"composition_source":"printed","phase":"Ni11Zr9"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.4118},"composition_source":"printed","phase":"Ni10Zr7"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.5},"composition_source":"printed","phase":"NiZr"}],"phases":[{"label":"Ni11Zr9","model_phase":"NI11ZR9","pearson_symbol":"tI40","prototype":"Pt11Zr9","structure_basis":"mapped_model_phase"},{"label":"Ni10Zr7","model_phase":"NI10ZR7","pearson_symbol":"oC68","prototype":"Ni10Zr7","structure_basis":"mapped_model_phase"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r47#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Ni11Zr9 ⇌ Ni10Zr7 + NiZr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1250.0,"temperature_printed":"1250","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1250.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-42JFIRKUNP","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":48},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.759},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.971},"composition_source":"printed","phase":"(βZr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r48#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr2 + (βZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1233.0,"temperature_printed":"1233","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1233.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"51","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, The Zirconium-Nickel phase diagram, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-TWAV3NC2PW","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":49},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:28c66992669d0d07","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.759},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r49#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr2 + (βZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1234.0,"temperature_printed":"1234","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1234.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1063/1.109404","first_author":"Ohsaka","kind":"assessment","label":"12","paper":"doi:10.1063/1.109404","reference":"K. Ohsaka, E.H. Trinh, J.C. Holzer, W.L. Johnson, Gibbs free-energy difference between the glass and crystalline phases of a Ni-Zr alloy, Appl. Phys. Lett. 62 (1993) 2319–2321.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-RSIRSOXWXO","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":50},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_is_assessment_unconfirmed","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r50#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr2 + (βZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1218.0,"temperature_printed":"1218","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1218.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-6DIIH4556U","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":51},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r51#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr2 + (βZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1248.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1248.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-SIZU7O4ZY3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":52},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.7441},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.6667},"composition_source":"printed","phase":"NiZr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.97},"composition_source":"printed","phase":"(βZr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r52#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr2 + (βZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1235.0,"temperature_printed":"1235","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1235.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-VB572W2JWY","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":53},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.98},"composition_source":"printed","phase":"(βZr)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r53#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) ⇌ NiZr2 + (αZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1118.0,"temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1118.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"51","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, The Zirconium-Nickel phase diagram, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-XVJ5LLI2K7","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":54},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:28c66992669d0d07","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.98},"composition_source":"printed","phase":"(βZr)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.333333,"ZR":0.666667},"composition_source":"stoichiometric_model_phase","phase":"NiZr2"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r54#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) ⇌ NiZr2 + (αZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1081.0,"temperature_printed":"1081","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1081.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-IFYKCODTQ5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":55},"model":"M2217bc45","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.9803},"composition_source":"printed","phase":"(βZr)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.6667},"composition_source":"printed","phase":"NiZr2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.99},"composition_source":"printed","phase":"(αZr)"}],"phases":[{"label":"(βZr)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"NiZr2","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"},{"label":"(αZr)","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r55#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(βZr) ⇌ NiZr2 + (αZr)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1108.0,"temperature_printed":"1108","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1108.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-B5OHNIQAQ5","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":56},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r56#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni7Zr2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1713.0,"temperature_printed":"1713","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1713.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"49","reference":"S.A. Pogodin, V.I. Sokorobogatova, Alloys of nickel-zirconium, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-U7Z4UTSMZA","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":57},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r57#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni7Zr2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1693.0,"temperature_printed":"1693","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1693.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"48","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-GFXOQE2UG2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":58},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r58#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni7Zr2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1723.0,"temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1723.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kramer","kind":"unknown","label":"38","reference":"D. Kramer, On the nickel-rich end of the zirconium-nickel phase diagram, Trans. AIME 215 (1959) 256–258.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-DFD4F5LWWV","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":59},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r59#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni7Zr2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1848.0,"temperature_uncertainty":{"basis":"printed","value":25.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":25.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":25.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1848.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-J4IYWKLTG6","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":60},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_title_experiment","class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"NI":0.777778,"ZR":0.222222},"composition_source":"stoichiometric_model_phase","phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r60#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni7Zr2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1713.0,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1713.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-US6EGPCLHL","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":61},"model":"M31bb0da5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2222},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.2222},"composition_source":"printed","phase":"Ni7Zr2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni7Zr2","model_phase":"NI7ZR2","pearson_symbol":"mC36","prototype":"Ni7Zr2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r61#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ Ni7Zr2","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1707.0,"temperature_printed":"1707","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1707.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-Z4Y2XTR4OI","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":62},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r62#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1533.0,"temperature_printed":"1533","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1533.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"49","reference":"S.A. Pogodin, V.I. Sokorobogatova, Alloys of nickel-zirconium, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-TP5VPQHGCY","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":63},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.097},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZR":0.167},"composition_source":"printed","phase":"(Ni5Zr)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"},{"label":"(Ni5Zr)"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r63#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1483.0,"temperature_printed":"1483","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1483.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"51","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, The Zirconium-Nickel phase diagram, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HMKBYSGZN2","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p3/tab-3","row":64},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:28c66992669d0d07","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"NI":0.5,"ZR":0.5},"composition_source":"stoichiometric_model_phase","phase":"NiZr"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"NiZr","model_phase":"NIZR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p3/tab-3/r64#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ⇌ NiZr","type":"congruent melting","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1743.0,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1743.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1007/s11106-017-9888-2","first_author":"Semenova","kind":"unknown","label":"25","paper":"doi:10.1007/s11106-017-9888-2","reference":"O.L. Semenova, V.M. Petyukh, O.S. Fomichev, The quasibinary ZrCo–ZrNi phase diagram, Powder Metall. Met. Ceram. 56 (2017) 210–219.","status":"resolved","year":"2017"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-4ZE464O47Y","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":3},"observation_type":"phase_transition","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","measured_in":"doi:10.1007/s11106-017-9888-2","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r-unplaced-1d6a0f75#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1503.0,"temperature_printed":"1503±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1503.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-OAF2G3CZR3","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":4},"model":"M31bb0da5","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r-unplaced-30309cce#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1496.0,"temperature_printed":"1496","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1496.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"experimental","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GMAGGK5IRW","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":2},"observation_type":"phase_transition","origin":{"basis":"cited_work_is_experimental","class":"experimental","measured_in":"ref:380a1b11f81ca38a","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r-unplaced-3087093b#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1533.0,"temperature_printed":"1533±7","temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1533.0},{"chemical_system":"NI-ZR","cited_sources":[{"doi":"10.1007/bf03398286","first_author":"Smith","kind":"experimental","label":"48","paper":"doi:10.1007/bf03398286","reference":"E.T. Smith, R.W. Guard, Investigation of the nickel-rich portion of the system Ni-Zr, Trans. AIME 209 (1957) 1189–1190.","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-6VV2YZENPY","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":1},"observation_type":"phase_transition","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1007/bf03398286","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r-unplaced-fd599d88#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1623.0,"temperature_printed":"1623±10","temperature_uncertainty":{"basis":"printed","value":10.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":10.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1623.0},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-PDWEPHQY4Y","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":5},"observation_type":"phase_transition","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:c15d8b8bfabd1411","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.6666666667},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.6666666667},"composition_source":"stoichiometry","phase":"NiZr2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NiZr2","mapping_confidence":"confirmed","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r01#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1393,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1393},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"51","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, The Zirconium-Nickel phase diagram, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-S52RSEXR5X","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":6},"observation_type":"phase_transition","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:28c66992669d0d07","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.6666666667},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.6666666667},"composition_source":"stoichiometry","phase":"NiZr2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NiZr2","mapping_confidence":"confirmed","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r02#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1473,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1473},{"chemical_system":"NI-ZR","cited_sources":[{"first_author":"Kosorukova","kind":"experimental","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-MK4HG3ABPN","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":7},"observation_type":"phase_transition","origin":{"basis":"cited_work_is_experimental","class":"experimental","measured_in":"ref:380a1b11f81ca38a","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.6666666667},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.6666666667},"composition_source":"stoichiometry","phase":"NiZr2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NiZr2","mapping_confidence":"confirmed","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r03#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1328,"temperature_uncertainty":{"basis":"printed","value":7.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1328},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-2TZX7OXMDR","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/tab-3","row":8},"model":"M2217bc45","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.intermet.2019.106640","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","phase_compositions":[{"basis":"mole_fraction","composition":{"ZR":0.6667},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"ZR":0.6667},"composition_source":"printed","phase":"NiZr2"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"NiZr2","mapping_confidence":"confirmed","model_phase":"NIZR2_C16","pearson_symbol":"tI12","prototype":"Al2Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.intermet.2019.106640/p4/tab-3/r04#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L -> NiZr2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1339,"temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1339},{"chemical_system":"NI-ZR","citations_printed":["10"],"cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WRQTD5IFOX.2e6d28","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This eutectic temperature has been experimentally measured by Kirkpatrick and Larsen [10], Hayes et al. [11] and Pogodin and Sokorobogatova [12], and the value is 1283 K, 1258 K and 1438 K respectively, while the calculated temperature is about 1333 K [4], 1338 K [5], 1384 K [6] and 1351 K [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1283.0,"temperature_printed":"1283 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1283.0},{"chemical_system":"NI-ZR","citations_printed":["4"],"cited_sources":[{"doi":"10.1016/0364-5916(85)90001-x","first_author":"Saunders","kind":"assessment","label":"4","paper":"doi:10.1016/0364-5916(85)90001-x","reference":"N. Saunders, CALPHAD 9 (4) (1985) 297–309.","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WRQTD5IFOX.4dd101","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"doi:10.1016/0364-5916(85)90001-x","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This eutectic temperature has been experimentally measured by Kirkpatrick and Larsen [10], Hayes et al. [11] and Pogodin and Sokorobogatova [12], and the value is 1283 K, 1258 K and 1438 K respectively, while the calculated temperature is about 1333 K [4], 1338 K [5], 1384 K [6] and 1351 K [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1333.0,"temperature_printed":"1333 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1333.0},{"chemical_system":"NI-ZR","citations_printed":["5"],"cited_sources":[{"doi":"10.1557/jmr.1994.0598","first_author":"Ghosh","kind":"unknown","label":"5","paper":"doi:10.1557/jmr.1994.0598","reference":"G. Ghosh, J. Mater. Res. 9 (3) (1994) 598–616.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WRQTD5IFOX.6b6a70","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This eutectic temperature has been experimentally measured by Kirkpatrick and Larsen [10], Hayes et al. [11] and Pogodin and Sokorobogatova [12], and the value is 1283 K, 1258 K and 1438 K respectively, while the calculated temperature is about 1333 K [4], 1338 K [5], 1384 K [6] and 1351 K [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1338.0,"temperature_printed":"1338 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1338.0},{"chemical_system":"NI-ZR","citations_printed":["6"],"cited_sources":[{"first_author":"Conclusions","kind":"assessment","label":"6","reference":"Conclusions The Ni–Zr system has been re-assessed thermodynamically with the integrative consideration of all the experimental data of the equilibria and the thermodynamic information of the phases from both the literature reports and the present work. Special attentions have been paid to the eutectic temperature between the NiZr and NiZr2 compounds and the temperature dependence of the mixing ent","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WRQTD5IFOX.8fbd1c","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This eutectic temperature has been experimentally measured by Kirkpatrick and Larsen [10], Hayes et al. [11] and Pogodin and Sokorobogatova [12], and the value is 1283 K, 1258 K and 1438 K respectively, while the calculated temperature is about 1333 K [4], 1338 K [5], 1384 K [6] and 1351 K [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1384.0,"temperature_printed":"1384 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1384.0},{"chemical_system":"NI-ZR","citations_printed":["7"],"cited_sources":[{"doi":"10.1039/b201036b","first_author":"Zaitsev","kind":"unknown","label":"7","paper":"doi:10.1039/b201036b","reference":"A.I. Zaitsev, N.E. Zaitseva, E.Kh. Shakhpazov, A.A. Kodentsov, Phys. Chem. Chem. Phys. 4 (2002) 6047–6058.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WRQTD5IFOX.bfb6cc","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This eutectic temperature has been experimentally measured by Kirkpatrick and Larsen [10], Hayes et al. [11] and Pogodin and Sokorobogatova [12], and the value is 1283 K, 1258 K and 1438 K respectively, while the calculated temperature is about 1333 K [4], 1338 K [5], 1384 K [6] and 1351 K [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1351.0,"temperature_printed":"1351 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1351.0},{"chemical_system":"NI-ZR","citations_printed":["12"],"cited_sources":[{"first_author":"Pogodin","kind":"unknown","label":"12","reference":"S.A. Pogodin, V.I. Sokorobogatova, Izv. Sekt. Fiz.-Khim. Anal., Inst. Obshch. Neorg. Khim., Akad. Nauk SSSR 25 (1954) 70–80.","status":"resolved","year":"1954"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WRQTD5IFOX.d0f93e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This eutectic temperature has been experimentally measured by Kirkpatrick and Larsen [10], Hayes et al. [11] and Pogodin and Sokorobogatova [12], and the value is 1283 K, 1258 K and 1438 K respectively, while the calculated temperature is about 1333 K [4], 1338 K [5], 1384 K [6] and 1351 K [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1438.0,"temperature_printed":"1438 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1438.0},{"chemical_system":"NI-ZR","citations_printed":["11"],"cited_sources":[{"first_author":"Hayes","kind":"unknown","label":"11","reference":"E.T. Hayes, A.H. Roberson, O.G. Paasche, Trans. ASM 45 (1953) 893–900.","status":"resolved","year":"1953"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WRQTD5IFOX.ec1fd3","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This eutectic temperature has been experimentally measured by Kirkpatrick and Larsen [10], Hayes et al. [11] and Pogodin and Sokorobogatova [12], and the value is 1283 K, 1258 K and 1438 K respectively, while the calculated temperature is about 1333 K [4], 1338 K [5], 1384 K [6] and 1351 K [7].","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1258.0,"temperature_printed":"1258 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1258.0},{"chemical_system":"NI-ZR","citations_printed":["8"],"cited_sources":[{"doi":"10.2320/matertrans.46.2838","first_author":"Abe","kind":"assessment","label":"8","paper":"doi:10.2320/matertrans.46.2838","reference":"T. Abe, H. Onodera, M. Shimono, M. Ode, Mater. Trans. JIM 46 (12) (2005) 2838–2843.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-W5EJWCV2PO","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p1/text-07"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"doi:10.2320/matertrans.46.2838","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p1/text-07/s10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature calculated by Abe et al. [8] is about 1280 K and close to the measured value [10], while their calculated melting points of NiZr and NiZr2 are much lower than the experimental data.","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1280.0,"temperature_printed":"1280 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1280.0},{"chemical_system":"NI-ZR","citations_printed":["19"],"cited_sources":[{"doi":"10.1016/0022-5088(79)90241-8","first_author":"Bsenko","kind":"unknown","label":"19","paper":"doi:10.1016/0022-5088(79)90241-8","reference":"L. Bsenko, J. Less-Common Met. 63 (1979) 171–179.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":["Ni7Zr2","Ni21Zr8","Ni3Zr"],"before":[],"evidence":{"basis":"one_reaction_one_temperature","quote_page":2},"field":"phases","gate":"R3","rule":"state_phases_from_quote"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phases_recovered_from_quote"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"phases_recovered_from_quote","detail":"phases read from the quote (one_reaction_one_temperature); not mapped to model phases","effect":"not_espei_ready","gate":"R3"}],"id":"ORC-7A3KYYBNSB","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p2/text-05"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","phases":[{"label":"Ni7Zr2","label_source":"quote"},{"label":"Ni21Zr8","label_source":"quote"},{"label":"Ni3Zr","label_source":"quote"}],"pid":"doi:10.1016/j.calphad.2007.07.001/p2/text-05/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Bsenko [19] studied the region of 64-78 at.% Ni by X-ray diffraction and optical microscopy and confirmed the Ni3 Zr compound formed by the peritectoid reaction Ni7 Zr2 + Ni21 Zr8 → Ni3 Zr at 1193 K.","quote_page":2,"reaction":{"printed":"Ni7 Zr2 + Ni21 Zr8 → Ni3 Zr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1193.0,"temperature_printed":"1193 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1193.0},{"chemical_system":"NI-ZR","citations_printed":["10"],"cited_sources":[{"first_author":"Kirkpatrick","kind":"unknown","label":"10","reference":"M.E. Kirkpatrick, W.L. Larsen, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-IH4YE7HPRN","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2007.07.001/p2/text-05"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2007.07.001","paper_id":"doi:10.1016/j.calphad.2007.07.001","pid":"doi:10.1016/j.calphad.2007.07.001/p2/text-05/s16#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Kirkpatrick and Larsen [10] first identified the existence of two compounds Ni10 Zr7 and Ni11 Zr9 , establishing the composition range of Ni10 Zr7 phase as 41.1-43.5 at.% Zr and the eutectoid decomposition of Ni11 Zr9 phase at 1248 K.","quote_page":2,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1248.0,"temperature_printed":"1248 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1248.0},{"chemical_system":"NI-ZR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-AKRBW4N67Z","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2011.10.003/p12/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.10.003","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.10.003","paper_id":"doi:10.1016/j.calphad.2011.10.003","pid":"doi:10.1016/j.calphad.2011.10.003/p12/text-07/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Characteristic features of the projection are as follows: (a) the large primary solidification area of ZrB2 , (b) the deep valley close to the Zr-Ni binary subsystem which includes the lowest ternary eutectic of the system Liquid ZrB2 + Zr7 Ni10 + Zr8 Ni21 at 874 °C.","quote_page":12,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1147.15,"temperature_printed":"874 °C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1147.15},{"chemical_system":"NI-ZR","citations_printed":["24","28"],"cited_sources":[{"first_author":"Kosorukova","kind":"unknown","label":"24","reference":"T. Kosorukova, V. Ivanchenko, G. Firstov, H. No€el, Experimental reinvestigation of Ni-Zr system, in: Solid State Phenomena, vol.194, Trans Tech Publications, Switzerland, 2013, pp. 14–20.","status":"resolved","year":"2013"},{"first_author":"Kirkpatrick","kind":"assessment","label":"28","reference":"M.E. Kirkpatrick, W.L. Larsen, Phase relationships in the Nickel-Zirconium and Nickel-Hafnium alloy systems, Trans. ASM 54 (1961) 580–590.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"pending","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-BGYF7XF2CY","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.intermet.2019.106640/p4/text-03"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"ref:380a1b11f81ca38a","own_work_of_paper":false},"paper":"doi:10.1016/j.intermet.2019.106640","paper_id":"doi:10.1016/j.intermet.2019.106640","pid":"doi:10.1016/j.intermet.2019.106640/p4/text-03/s01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"determined by Refs. [24,28] that Ni10Zr7 phase forms peritectically from liquid and Ni11Zr9 at 1433 K, in the calculated phase diagrams by Refs. [17,54,55], it forms congruently.","quote_page":4,"reaction":{"printed":"liquid + Ni11Zr9 -> Ni10Zr7","type":"peritectic"},"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1433.0,"temperature_printed":"1433 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1433.0},{"chemical_system":"NI-ZR","citations_printed":["24"],"cited_sources":[{"first_author":"Eremenko","kind":"unknown","label":"24","reference":"N.N. Eremenko, E.L. Semenova, L.A. Tret’yachenko, V. Petyukh, Reaction of 151","status":"resolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5WN3TOEDD4.e7fefa","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.tca.2018.08.011/p8/text-03"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.tca.2018.08.011","paper_id":"doi:10.1016/j.tca.2018.08.011","pid":"doi:10.1016/j.tca.2018.08.011/p8/text-03/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Work by Eremenko [24] showed that the liquidus between the compounds NiZr and NiHf was roughly a linear interpolation between the melting points of these two compounds: 1543 and 1778 K, respectively.","quote_page":8,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"NI-ZR","system":"NI-ZR","temperature_K":1543.0,"temperature_printed":"1543","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1543.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"NI-ZR"}