{"artifacts":{"sha256:15e0479ab64b3d87/p10/tab-7":{"artifact":"table","caption":"Experimental Results on Phase Boundaries of Ternary Alloys Determined by DTA AIIoycompositions, mass% Pb Sn Sb","label":"7","page":10},"sha256:15e0479ab64b3d87/p11/tab-8":{"artifact":"table","caption":"Experimental Results on Solid Compositions in the Specimens Equilibrated at 190 and 300 ~","label":"8","page":11},"sha256:15e0479ab64b3d87/p2/tab-3":{"artifact":"table","caption":"Molar Volume Data for Pb, Sn, and Sb","label":"3","page":2},"sha256:15e0479ab64b3d87/p8/tab-6":{"artifact":"table","caption":"Experimental Results on Liquidus Temperatures in the Pb-Sn-Sb System","label":"6","page":8}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["PB","SB","SN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02645349":{"authors":["H. Ohtani","K. Okuda","K. Ishida"],"citation":"H. Ohtani, K. Okuda, K. Ishida, Thermodynamic study of phase equilibria in the Pb-Sn-Sb system, JPE 16, 416-429 (1995).","container":"JPE","doi":"10.1007/bf02645349","doi_url":"https://doi.org/10.1007/bf02645349","id":"doi:10.1007/bf02645349","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"15e0479ab64b3d87","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic study of phase equilibria in the Pb-Sn-Sb system","year":1995},"doi:10.1007/bf02890552":{"citation":"I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 9, 144 (1988).","doi":"10.1007/bf02890552","doi_url":"https://doi.org/10.1007/bf02890552","id":"doi:10.1007/bf02890552","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]}},"part":1,"parts":1,"records":[{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-ESVQLERDT6","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":1},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1977028443,"SB":0.112144189,"SN":0.6901529667},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn60Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ASKHSX4Q6M","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":2},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1977028443,"SB":0.112144189,"SN":0.6901529667},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn60Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":471.15,"temperature_basis":"printed","temperature_printed":"198","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-JLIOXLHKIA","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":3},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1977028443,"SB":0.112144189,"SN":0.6901529667},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn60Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":466.15,"temperature_basis":"printed","temperature_printed":"193","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":466.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-KRYWUP3EJC","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":4},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1982741327,"SB":0.2249364886,"SN":0.5767893787},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn50Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":573.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-CY3L56HR6C","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":5},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1982741327,"SB":0.2249364886,"SN":0.5767893787},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn50Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":472.15,"temperature_basis":"printed","temperature_printed":"199","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":472.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-DB2SUVZZJZ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":6},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1982741327,"SB":0.2249364886,"SN":0.5767893787},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn50Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":463.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-SPVWABLIR7","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":7},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1985610167,"SB":0.2815774383,"SN":0.5198615449},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn45Sb25","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":597.65,"temperature_basis":"printed","temperature_printed":"324.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":597.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-6XO2PDVL2C","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":8},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1985610167,"SB":0.2815774383,"SN":0.5198615449},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn45Sb25","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":491.65,"temperature_basis":"printed","temperature_printed":"218.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":491.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-3E4GOLBGEF","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":9},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1985610167,"SB":0.2815774383,"SN":0.5198615449},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn45Sb25","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.65,"temperature_basis":"printed","temperature_printed":"190.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":463.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-HQZAV2HOP3","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":100},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.6110280452,"SB":0.2136557842,"SN":0.1753161707},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r100#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb73Sn12Sb15","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":525.15,"temperature_basis":"printed","temperature_printed":"252","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":525.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-OVFQRPVAP6","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":101},"merged_ids":["ORC-U66A4LN4R5"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r63#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4669059086,"SB":0.397268825,"SN":0.1358252664},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r101#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb60Sn10Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":635.15,"temperature_basis":"printed","temperature_printed":"362","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":635.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-W2BUBLYDJS","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":103},"merged_ids":["ORC-Z2MVPJX4WP"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r65#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4669059086,"SB":0.397268825,"SN":0.1358252664},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r103#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb60Sn10Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-K5JNC5U4BF","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":104},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3677556302,"SB":0.3754876802,"SN":0.2567566896},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r104#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb50Sn20Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":616.15,"temperature_basis":"printed","temperature_printed":"343","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":616.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-JFNES7HFEA","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":105},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3677556302,"SB":0.3754876802,"SN":0.2567566896},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r105#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb50Sn20Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":522.15,"temperature_basis":"printed","temperature_printed":"249","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":522.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-SB2YCDQQ2V","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":106},"merged_ids":["ORC-SFDVMTQK6N"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r125#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2789125071,"SB":0.3559707917,"SN":0.3651167012},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r106#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb40Sn30Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":610.15,"temperature_basis":"printed","temperature_printed":"337","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":610.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-3IIIHMQH7V","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":108},"merged_ids":["ORC-5ZL7E5GNJ6"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r10#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1988487322,"SB":0.3383825338,"SN":0.462768734},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r108#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn40Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":615.15,"temperature_basis":"printed","temperature_printed":"342","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":615.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-33M4VIU3TA","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":109},"merged_ids":["ORC-KAMH7MFSAM"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r11#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1988487322,"SB":0.3383825338,"SN":0.462768734},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r109#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn40Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":510.15,"temperature_basis":"printed","temperature_printed":"237","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":510.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-QDU5TKF6DM","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":110},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.126324233,"SB":0.3224504896,"SN":0.5512252774},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r110#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb20Sn50Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":620.15,"temperature_basis":"printed","temperature_printed":"347","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":620.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ZW4FWS76VV","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":111},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.126324233,"SB":0.3224504896,"SN":0.5512252774},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r111#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb20Sn50Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":474.15,"temperature_basis":"printed","temperature_printed":"201","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":474.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-BIFRJYEMU4","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":112},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.126324233,"SB":0.3224504896,"SN":0.5512252774},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r112#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb20Sn50Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":463.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-H5VN46GJTW","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":113},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0603219804,"SB":0.3079512401,"SN":0.6317267795},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r113#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb10Sn60Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":627.15,"temperature_basis":"printed","temperature_printed":"354","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":627.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ARMFV7YOVU","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":114},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0603219804,"SB":0.3079512401,"SN":0.6317267795},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r114#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb10Sn60Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":488.15,"temperature_basis":"printed","temperature_printed":"215","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":488.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-IUWPC2TNUR","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":115},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0603219804,"SB":0.3079512401,"SN":0.6317267795},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r115#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb10Sn60Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":466.15,"temperature_basis":"printed","temperature_printed":"193","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":466.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-UV5X7KA3ZC","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":116},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7255080545,"SB":0.1355052142,"SN":0.1389867313},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r116#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb82Sn9Sb9","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":525.15,"temperature_basis":"printed","temperature_printed":"252","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":525.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-PSEUZOP5B7","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":117},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7255080545,"SB":0.1355052142,"SN":0.1389867313},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r117#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb82Sn9Sb9","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":523.65,"temperature_basis":"printed","temperature_printed":"250.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":523.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-LIRF3K3ICV","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":118},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7255080545,"SB":0.1355052142,"SN":0.1389867313},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r118#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb82Sn9Sb9","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":518.15,"temperature_basis":"printed","temperature_printed":"245","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":518.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-ADEUK24GRU","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":119},"merged_ids":["ORC-X4O5JKUTCS"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r98#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.6475488667,"SB":0.1739904106,"SN":0.1784607227},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r119#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb76Sn12Sb12","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":525.15,"temperature_basis":"printed","temperature_printed":"252","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":525.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-UDY4LCYKPA","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":12},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1988487322,"SB":0.3383825338,"SN":0.462768734},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn40Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":463.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5F2AXKCQEE","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":120},"merged_ids":["ORC-BCYX3FKW5B"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r30#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5751514456,"SB":0.209729995,"SN":0.2151185594},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r120#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn15Sb15","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":534.65,"temperature_basis":"printed","temperature_printed":"261.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":534.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-2RJJGF3LO3","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":121},"merged_ids":["ORC-BEOTVGH33S"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r31#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5751514456,"SB":0.209729995,"SN":0.2151185594},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r121#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn15Sb15","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":522.15,"temperature_basis":"printed","temperature_printed":"249","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":522.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-Y22NICBKPW","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":122},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4653227296,"SB":0.263947847,"SN":0.2707294234},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r122#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb60Sn20Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":561.15,"temperature_basis":"printed","temperature_printed":"288","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":561.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-MW4OUNIWX4","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":123},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4653227296,"SB":0.263947847,"SN":0.2707294234},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r123#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb60Sn20Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":522.15,"temperature_basis":"printed","temperature_printed":"249","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":522.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-T7YNYIR3SG","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":124},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4653227296,"SB":0.263947847,"SN":0.2707294234},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r124#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb60Sn20Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":519.15,"temperature_basis":"printed","temperature_printed":"246","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":519.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4BVD62KO3C","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":126},"merged_ids":["ORC-H24SLS5E5X"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r107#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2789125071,"SB":0.3559707917,"SN":0.3651167012},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r126#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb40Sn30Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-F7U6PKKD46","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":127},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1991372827,"SB":0.3953524896,"SN":0.4055102277},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r127#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn35Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":635.65,"temperature_basis":"printed","temperature_printed":"362.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":635.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-FLRYTAZ7HN","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":129},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1991372827,"SB":0.3953524896,"SN":0.4055102277},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r129#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn35Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":472.15,"temperature_basis":"printed","temperature_printed":"199","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":472.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-LFPVCTHU4H","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":13},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1991372827,"SB":0.3953524896,"SN":0.4055102277},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn35Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":655.65,"temperature_basis":"printed","temperature_printed":"382.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":655.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-I5AWKHDXJ5","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":130},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1266740508,"SB":0.431124562,"SN":0.4422013872},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r130#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb20Sn40Sb40","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":657.15,"temperature_basis":"printed","temperature_printed":"384","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":657.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-7N4HPP4VJP","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":131},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0605615665,"SB":0.4637615355,"SN":0.475676898},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r131#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb10Sn45Sb45","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":677.15,"temperature_basis":"printed","temperature_printed":"404","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":677.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-BEJQAYXJ7B","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":14},"merged_ids":["ORC-WEV2ESH7PX"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r128#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1991372827,"SB":0.3953524896,"SN":0.4055102277},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn35Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":522.15,"temperature_basis":"printed","temperature_printed":"249","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":522.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4V6KEOOMPQ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":15},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1991372827,"SB":0.3953524896,"SN":0.4055102277},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn35Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":461.15,"temperature_basis":"printed","temperature_printed":"188","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":461.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-QJIWQKWJ2H","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":16},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1994266718,"SB":0.4524880245,"SN":0.3480853037},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r16#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn30Sb40","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":662.15,"temperature_basis":"printed","temperature_printed":"389","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":662.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-XSFPR5FQCI","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":17},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1994266718,"SB":0.4524880245,"SN":0.3480853037},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r17#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn30Sb40","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":592.15,"temperature_basis":"printed","temperature_printed":"319","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":592.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-HSG44MFLJS","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":18},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1994266718,"SB":0.4524880245,"SN":0.3480853037},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r18#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn30Sb40","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":522.15,"temperature_basis":"printed","temperature_printed":"249","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":522.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-CNZ5FWPLAV","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":19},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2000079807,"SB":0.5672587275,"SN":0.2327332918},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn20Sb50","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":730.15,"temperature_basis":"printed","temperature_printed":"457","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":730.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-M3QUP24BYN","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":20},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2000079807,"SB":0.5672587275,"SN":0.2327332918},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn20Sb50","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":632.15,"temperature_basis":"printed","temperature_printed":"359","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":632.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-FHAOZGN4C6","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":21},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2000079807,"SB":0.5672587275,"SN":0.2327332918},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r21#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn20Sb50","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":524.15,"temperature_basis":"printed","temperature_printed":"251","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":524.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-RUSVM2U54V","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":24},"merged_ids":["ORC-TZRMFVD6VA"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r83#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2005926884,"SB":0.6827004769,"SN":0.1167068347},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r24#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn10Sb60","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":520.15,"temperature_basis":"printed","temperature_printed":"247","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":520.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-4KUB4TVDNX","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":25},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5730926811,"SB":0.0696597543,"SN":0.3572475647},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r25#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn25Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":512.15,"temperature_basis":"printed","temperature_printed":"239","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":512.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-URIOAEK6LL","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":26},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5730926811,"SB":0.0696597543,"SN":0.3572475647},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r26#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn25Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":496.15,"temperature_basis":"printed","temperature_printed":"223","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":496.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-KLHBYB47AZ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":27},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5730926811,"SB":0.0696597543,"SN":0.3572475647},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r27#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn25Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":462.15,"temperature_basis":"printed","temperature_printed":"189","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":462.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-2DXXGBB25B","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":28},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5741202177,"SB":0.1395693039,"SN":0.2863104784},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r28#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn20Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":516.15,"temperature_basis":"printed","temperature_printed":"243","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":516.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-QIXKLSR4Q5","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":29},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5741202177,"SB":0.1395693039,"SN":0.2863104784},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r29#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn20Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":512.15,"temperature_basis":"printed","temperature_printed":"239","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":512.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-GEM2LAM2BI","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":32},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5761863848,"SB":0.2801431831,"SN":0.1436704321},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r32#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn10Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":566.15,"temperature_basis":"printed","temperature_printed":"293","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":566.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ECMSCRQZ5R","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":33},"merged_ids":["ORC-H6SXGEIXJF"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r62#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5761863848,"SB":0.2801431831,"SN":0.1436704321},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r33#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn10Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":519.15,"temperature_basis":"printed","temperature_printed":"246","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":519.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-JKKXSNJFL4","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":34},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5772250552,"SB":0.350810234,"SN":0.0719647108},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r34#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn5Sb25","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":617.15,"temperature_basis":"printed","temperature_printed":"344","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":617.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-QCR5F7S2UZ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":35},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5772250552,"SB":0.350810234,"SN":0.0719647108},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r35#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn5Sb25","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":517.15,"temperature_basis":"printed","temperature_printed":"244","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":517.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-N7QC4UW2XQ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":36},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.838247506,"SB":0.0316989493,"SN":0.1300535447},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r36#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn8Sb2","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":569.15,"temperature_basis":"printed","temperature_printed":"296","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":569.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-EM5X2BDAA4","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":37},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.838247506,"SB":0.0316989493,"SN":0.1300535447},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r37#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn8Sb2","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":516.15,"temperature_basis":"printed","temperature_printed":"243","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":516.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-3HG5MHVQQF","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":38},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.838247506,"SB":0.0316989493,"SN":0.1300535447},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r38#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn8Sb2","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":509.15,"temperature_basis":"printed","temperature_printed":"236","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":509.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-2AUDM2M5VS","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":39},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8389307621,"SB":0.0634495744,"SN":0.0976196636},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r39#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn6Sb4","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":560.15,"temperature_basis":"printed","temperature_printed":"287","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":560.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ZITYTNDUS3","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":40},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8389307621,"SB":0.0634495744,"SN":0.0976196636},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r40#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn6Sb4","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":524.15,"temperature_basis":"printed","temperature_printed":"251","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":524.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-7XYAY4GIQX","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":41},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8389307621,"SB":0.0634495744,"SN":0.0976196636},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r41#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn6Sb4","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.65,"temperature_basis":"printed","temperature_printed":"248.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-GHA2EATMKK","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":43},"merged_ids":["ORC-KFYF77QLWV"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r52#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.839615133,"SB":0.0952520015,"SN":0.0651328655},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r43#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn4Sb6","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-FYWUHUNRJE","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":45},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8403006213,"SB":0.1271063577,"SN":0.032593021},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r45#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn2Sb8","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":538.65,"temperature_basis":"printed","temperature_printed":"265.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":538.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-LZVPHS6SDI","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":46},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8403006213,"SB":0.1271063577,"SN":0.032593021},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r46#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn2Sb8","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":522.65,"temperature_basis":"printed","temperature_printed":"249.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":522.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-UD7WEJIX4P","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":47},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8403006213,"SB":0.1271063577,"SN":0.032593021},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r47#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn2Sb8","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":518.65,"temperature_basis":"printed","temperature_printed":"245.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":518.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-6D3S3PTVDE","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":48},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8545382336,"SB":0.0798997135,"SN":0.0655620529},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r48#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb91Sn4Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":556.65,"temperature_basis":"printed","temperature_printed":"283.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":556.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-QXTX3LIFWC","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":49},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8545382336,"SB":0.0798997135,"SN":0.0655620529},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r49#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb91Sn4Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":523.15,"temperature_basis":"printed","temperature_printed":"250","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":523.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-RUA2VF7CRN","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":50},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.8545382336,"SB":0.0798997135,"SN":0.0655620529},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r50#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb91Sn4Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":519.15,"temperature_basis":"printed","temperature_printed":"246","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":519.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-RU33GAV7R5","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":51},"merged_ids":["ORC-YZ6NVNT2Z3"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r42#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.839615133,"SB":0.0952520015,"SN":0.0651328655},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r51#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn4Sb6","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":537.65,"temperature_basis":"printed","temperature_printed":"264.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":537.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4VAQ6IXHUQ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":53},"merged_ids":["ORC-6MJO7TNB73"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r44#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.839615133,"SB":0.0952520015,"SN":0.0651328655},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r53#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb90Sn4Sb6","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":519.15,"temperature_basis":"printed","temperature_printed":"246","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":519.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-WRH5E3DLN4","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":54},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7818266899,"SB":0.1547024361,"SN":0.063470874},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r54#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb86Sn4Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":527.15,"temperature_basis":"printed","temperature_printed":"254","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":527.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ZLMNP52RJA","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":55},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7818266899,"SB":0.1547024361,"SN":0.063470874},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r55#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb86Sn4Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":520.65,"temperature_basis":"printed","temperature_printed":"247.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":520.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-DLOKNJRWS5","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":56},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7818266899,"SB":0.1547024361,"SN":0.063470874},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r56#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb86Sn4Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":516.65,"temperature_basis":"printed","temperature_printed":"243.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":516.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-IGMA5GGTAS","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":57},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7136102115,"SB":0.2248808157,"SN":0.0615089728},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r57#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb81Sn4Sb15","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":546.15,"temperature_basis":"printed","temperature_printed":"273","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":546.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-DL553GA67A","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":58},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7136102115,"SB":0.2248808157,"SN":0.0615089728},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r58#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb81Sn4Sb15","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":518.15,"temperature_basis":"printed","temperature_printed":"245","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":518.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-EVY6S4TSNR","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":59},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7136102115,"SB":0.2248808157,"SN":0.0615089728},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r59#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb81Sn4Sb15","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":516.65,"temperature_basis":"printed","temperature_printed":"243.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":516.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-RNIN4I7OW4","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":60},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.6988646225,"SB":0.1486579642,"SN":0.1524774132},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r60#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb80Sn10Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":518.15,"temperature_basis":"printed","temperature_printed":"245","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":518.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-UWOWJKU6ZD","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":61},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5761863848,"SB":0.2801431831,"SN":0.1436704321},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r61#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb70Sn10Sb20","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":566.65,"temperature_basis":"printed","temperature_printed":"293.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":566.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-P6YVEF33I6","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":64},"merged_ids":["ORC-TSUZM2DK7U"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r102#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4669059086,"SB":0.397268825,"SN":0.1358252664},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r64#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb60Sn10Sb30","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":567.15,"temperature_basis":"printed","temperature_printed":"294","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":567.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5457NTFUMG","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":66},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4166221949,"SB":0.4511623697,"SN":0.1322154353},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r66#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb55Sn10Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":669.65,"temperature_basis":"printed","temperature_printed":"396.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":669.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4CKF36FXQF","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":67},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4166221949,"SB":0.4511623697,"SN":0.1322154353},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r67#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb55Sn10Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":568.15,"temperature_basis":"printed","temperature_printed":"295","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":568.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-HWIMF4K3E7","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":68},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4166221949,"SB":0.4511623697,"SN":0.1322154353},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r68#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb55Sn10Sb35","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":519.65,"temperature_basis":"printed","temperature_printed":"246.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":519.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-LZD3WB3F6I","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":69},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3689420684,"SB":0.5022654177,"SN":0.1287925138},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r69#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb50Sn10Sb40","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":695.15,"temperature_basis":"printed","temperature_printed":"422","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":695.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-UF4LJFYRWR","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":70},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3689420684,"SB":0.5022654177,"SN":0.1287925138},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r70#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb50Sn10Sb40","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":572.15,"temperature_basis":"printed","temperature_printed":"299","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":572.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-XYAREWRRHR","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":71},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3689420684,"SB":0.5022654177,"SN":0.1287925138},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r71#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb50Sn10Sb40","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-ORSALW33VP","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":72},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3236684195,"SB":0.5507892289,"SN":0.1255423516},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r72#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb45Sn10Sb45","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":723.65,"temperature_basis":"printed","temperature_printed":"450.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":723.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-NGSIOBPQWC","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":73},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3236684195,"SB":0.5507892289,"SN":0.1255423516},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r73#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb45Sn10Sb45","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":572.15,"temperature_basis":"printed","temperature_printed":"299","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":572.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-Y44FTUMBX4","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":74},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3236684195,"SB":0.5507892289,"SN":0.1255423516},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r74#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb45Sn10Sb45","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-SXD2ZESIJD","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":75},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2806235454,"SB":0.5969242631,"SN":0.1224521915},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r75#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb40Sn10Sb50","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":743.15,"temperature_basis":"printed","temperature_printed":"470","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":743.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-2KGOW5ET5N","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":76},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2806235454,"SB":0.5969242631,"SN":0.1224521915},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r76#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb40Sn10Sb50","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":578.15,"temperature_basis":"printed","temperature_printed":"305","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":578.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-25VO3VQ4FQ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":77},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2806235454,"SB":0.5969242631,"SN":0.1224521915},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r77#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb40Sn10Sb50","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":520.15,"temperature_basis":"printed","temperature_printed":"247","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":520.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-MS3HN5A2LM","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":78},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2396468197,"SB":0.6408426781,"SN":0.1195105023},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r78#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb35Sn10Sb55","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":753.65,"temperature_basis":"printed","temperature_printed":"480.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":753.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-TGSIX3L4RQ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":79},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2396468197,"SB":0.6408426781,"SN":0.1195105023},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r79#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb35Sn10Sb55","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":586.15,"temperature_basis":"printed","temperature_printed":"313","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":586.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-NB6DPJPE53","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":80},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2396468197,"SB":0.6408426781,"SN":0.1195105023},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r80#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb35Sn10Sb55","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":520.15,"temperature_basis":"printed","temperature_printed":"247","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":520.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-HSW55YSLEN","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":81},"merged_ids":["ORC-OZCA6MSAT5"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r22#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2005926884,"SB":0.6827004769,"SN":0.1167068347},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r81#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn10Sb60","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":780.15,"temperature_basis":"printed","temperature_printed":"507","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":780.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-CYRMCQE7OJ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":82},"merged_ids":["ORC-XCQHHOLLJK"],"merged_pids":["sha256:15e0479ab64b3d87/p10/tab-7/r23#phase_transition"],"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2005926884,"SB":0.6827004769,"SN":0.1167068347},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r82#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb30Sn10Sb60","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":589.15,"temperature_basis":"printed","temperature_printed":"316","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":589.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-AQCAJGHISC","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":84},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1277352264,"SB":0.7607883229,"SN":0.1114764507},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r84#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb20Sn10Sb70","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":817.15,"temperature_basis":"printed","temperature_printed":"544","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":817.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4X5XEKID7A","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":85},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1277352264,"SB":0.7607883229,"SN":0.1114764507},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r85#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb20Sn10Sb70","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":607.15,"temperature_basis":"printed","temperature_printed":"334","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":607.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-SYPR4PLCIM","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":86},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1277352264,"SB":0.7607883229,"SN":0.1114764507},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r86#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb20Sn10Sb70","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-JBO3TIG23P","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":87},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0611280711,"SB":0.8321771573,"SN":0.1066947716},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r87#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb10Sn10Sb80","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":828.15,"temperature_basis":"printed","temperature_printed":"555","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":828.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-SLXMGPOZCB","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":88},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0611280711,"SB":0.8321771573,"SN":0.1066947716},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r88#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb10Sn10Sb80","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":635.15,"temperature_basis":"printed","temperature_printed":"362","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":635.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-EWWYTCGZTH","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":89},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0611280711,"SB":0.8321771573,"SN":0.1066947716},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r89#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb10Sn10Sb80","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":520.15,"temperature_basis":"printed","temperature_printed":"247","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":520.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-EDDRKHA3IL","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":90},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0299222911,"SB":0.8656231775,"SN":0.1044545314},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r90#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb5Sn10Sb85","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":865.15,"temperature_basis":"printed","temperature_printed":"592","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":865.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-SQ7SNC6FWJ","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":91},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0299222911,"SB":0.8656231775,"SN":0.1044545314},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r91#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb5Sn10Sb85","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":649.65,"temperature_basis":"printed","temperature_printed":"376.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":649.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-IAWGYKNEPA","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":92},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0299222911,"SB":0.8656231775,"SN":0.1044545314},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r92#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb5Sn10Sb85","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-VCMKSD5MMI","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":93},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7380815271,"SB":0.0756626172,"SN":0.1862558558},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r93#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb83Sn12Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":537.65,"temperature_basis":"printed","temperature_printed":"264.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":537.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-CHH6THTIQY","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":94},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7380815271,"SB":0.0756626172,"SN":0.1862558558},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r94#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb83Sn12Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":516.15,"temperature_basis":"printed","temperature_printed":"243","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":516.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4IU2HWRWQD","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":95},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.7380815271,"SB":0.0756626172,"SN":0.1862558558},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r95#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb83Sn12Sb5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":462.65,"temperature_basis":"printed","temperature_printed":"189.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":462.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-E6LHFV7J7P","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":96},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.6726327277,"SB":0.146746754,"SN":0.1806205182},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r96#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb78Sn12Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":523.65,"temperature_basis":"printed","temperature_printed":"250.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":523.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-GKDBN2IK4M","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":97},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.6726327277,"SB":0.146746754,"SN":0.1806205182},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"other"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r97#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb78Sn12Sb10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":519.15,"temperature_basis":"printed","temperature_printed":"246","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":519.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-ZLSDNXF4ZW","locator":{"ref":"sha256:15e0479ab64b3d87/p10/tab-7","row":99},"method":"DTA","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.6110280452,"SB":0.2136557842,"SN":0.1753161707},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p10/tab-7/r99#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Pb73Sn12Sb15","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":535.65,"temperature_basis":"printed","temperature_printed":"262.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":535.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-FSUWBTUJVQ","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":1},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1412853963,"SB":0.2144344713,"SN":0.6442801324},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.022975,"SB":0.432065,"SN":0.54496},"composition_source":"printed","phase":"β"},{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.021586,"SB":0.086374,"SN":0.89204},"composition_source":"printed","phase":"γ"}],"phases":[{"label":"L"},{"label":"β"},{"label":"γ"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5ZLSBNP4A7","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":2},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1412853963,"SB":0.2144344713,"SN":0.6442801324},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.021586,"SB":0.086374,"SN":0.89204},"composition_source":"printed","phase":"γ"}],"phases":[{"label":"L"},{"label":"β"},{"label":"γ"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-O3FZVNXBYI","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":3},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.201085264,"SB":0.628671819,"SN":0.170242917},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.016613,"SB":0.903646,"SN":0.079741},"composition_source":"printed","phase":"α"},{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.072904,"SB":0.582776,"SN":0.34432},"composition_source":"printed","phase":"β"}],"phases":[{"label":"α"},{"label":"β"},{"label":"δ"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-NMPUZNDL5L","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":4},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.201085264,"SB":0.628671819,"SN":0.170242917},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.072904,"SB":0.582776,"SN":0.34432},"composition_source":"printed","phase":"β"}],"phases":[{"label":"α"},{"label":"β"},{"label":"δ"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-S4NSEWR3A7","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":5},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2790996993,"SB":0.3823317464,"SN":0.3385685544},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.065089,"SB":0.515514,"SN":0.419397},"composition_source":"printed","phase":"β"},{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.954171,"SB":0.015019,"SN":0.03081},"composition_source":"printed","phase":"δ"}],"phases":[{"label":"β"},{"label":"δ"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-EEL3RYPHOV","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":6},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2790996993,"SB":0.3823317464,"SN":0.3385685544},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.954171,"SB":0.015019,"SN":0.03081},"composition_source":"printed","phase":"δ"}],"phases":[{"label":"β"},{"label":"δ"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-F7WQMI4UAE","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":7},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2000021508,"SB":0.5661077086,"SN":0.2338901406},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.01063,"SB":0.888357,"SN":0.101013},"composition_source":"printed","phase":"α"},{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.075484,"SB":0.579602,"SN":0.344914},"composition_source":"printed","phase":"β"}],"phases":[{"label":"L"},{"label":"α"},{"label":"β"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-NSPOBPQ5MB","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":8},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2000021508,"SB":0.5661077086,"SN":0.2338901406},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.075484,"SB":0.579602,"SN":0.344914},"composition_source":"printed","phase":"β"}],"phases":[{"label":"L"},{"label":"α"},{"label":"β"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-KCQBCHEIUY","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":9},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2789040043,"SB":0.3547734067,"SN":0.366322589},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.053697,"SB":0.508219,"SN":0.438083},"composition_source":"printed","phase":"β"}],"phases":[{"label":"L"},{"label":"β"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-NSLXAAACBC","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":10},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.126324233,"SB":0.3224504896,"SN":0.5512252774},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.027205,"SB":0.466979,"SN":0.505816},"composition_source":"printed","phase":"β"}],"phases":[{"label":"L"},{"label":"β"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-G4WROIRCBI","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":11},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0603219804,"SB":0.3079512401,"SN":0.6317267795},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.015828,"SB":0.444929,"SN":0.539242},"composition_source":"printed","phase":"β"}],"phases":[{"label":"L"},{"label":"β"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r11#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-Z6NRV7ED5R","locator":{"ref":"sha256:15e0479ab64b3d87/p11/tab-8","row":12},"method":"EPMA","method_basis":"printed in the table row/column","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4124215764,"SB":0.5215368631,"SN":0.0660415604},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"PB":0.016026,"SB":0.937352,"SN":0.046621},"composition_source":"printed","phase":"α"}],"phases":[{"label":"L"},{"label":"α"}],"pid":"sha256:15e0479ab64b3d87/p11/tab-8/r12#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/X_PHASE/classes/microanalysis","floor":0.005,"floor_unit":"mole fraction","n_pairs":0,"prior_source":"orchid_assumed","value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"microanalysis","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"PB-SB-SN","cited_sources":[{"doi":"10.1007/bf02890552","first_author":"Karakaya","kind":"assessment","label":"6","paper":"doi:10.1007/bf02890552","reference":"I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 9, 144 (1988).","status":"resolved","year":"1988"}],"component":"PB","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":0,"id":"ORC-VSBHUF4RW2","locator":{"ref":"sha256:15e0479ab64b3d87/p2/tab-3","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"SB":0.0,"SN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"L"}],"pid":"sha256:15e0479ab64b3d87/p2/tab-3/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"Molar volume","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.969},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0969,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/VOLUME","floor":0.005,"floor_unit":"relative (fraction of the value)","n_pairs":0,"value":0.0969},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"cm3/mol","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"cm3/mol","unit_printed":"cm3/mol","value":19.38,"value_printed":19.38},{"chemical_system":"PB-SB-SN","component":"PB","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":0,"id":"ORC-JBI2AAPIUA","locator":{"ref":"sha256:15e0479ab64b3d87/p2/tab-3","row":2},"observation_type":"equilibrium_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"SB":0.0,"SN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"α"}],"pid":"sha256:15e0479ab64b3d87/p2/tab-3/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"Molar volume","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.969},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1047,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.003722,0.019682],"class":"unknown","entry":"value_types/VOLUME/classes/unknown","floor":0.0054,"floor_unit":"relative (fraction of the value)","n_pairs":43,"prior_source":"orchid_assumed","value":0.1047},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"cm3/mol","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"cm3/mol","unit_printed":"cm3/mol","value":19.38,"value_printed":19.38},{"chemical_system":"PB-SB-SN","cited_sources":[{"doi":"10.1007/bf02890552","first_author":"Karakaya","kind":"assessment","label":"6","paper":"doi:10.1007/bf02890552","reference":"I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 9, 144 (1988).","status":"resolved","year":"1988"}],"component":"PB","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":0,"id":"ORC-E4XIXXEAJF","locator":{"ref":"sha256:15e0479ab64b3d87/p2/tab-3","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"SB":0.0,"SN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"γ"}],"pid":"sha256:15e0479ab64b3d87/p2/tab-3/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"Molar volume","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.92},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.092,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/VOLUME","floor":0.005,"floor_unit":"relative (fraction of the value)","n_pairs":0,"value":0.092},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"cm3/mol","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"cm3/mol","unit_printed":"cm3/mol","value":18.4,"value_printed":18.4},{"chemical_system":"PB-SB-SN","cited_sources":[{"doi":"10.1007/bf02890552","first_author":"Karakaya","kind":"assessment","label":"6","paper":"doi:10.1007/bf02890552","reference":"I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 9, 144 (1988).","status":"resolved","year":"1988"}],"component":"PB","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":0,"id":"ORC-ED4KYYQIPT","locator":{"ref":"sha256:15e0479ab64b3d87/p2/tab-3","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"SB":0.0,"SN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"δ"}],"pid":"sha256:15e0479ab64b3d87/p2/tab-3/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"Molar volume","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.935},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0935,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/VOLUME","floor":0.005,"floor_unit":"relative (fraction of the value)","n_pairs":0,"value":0.0935},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"cm3/mol","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"cm3/mol","unit_printed":"cm3/mol","value":18.7,"value_printed":18.7},{"chemical_system":"PB-SB-SN","cited_sources":[{"doi":"10.1007/bf02890552","first_author":"Karakaya","kind":"assessment","label":"6","paper":"doi:10.1007/bf02890552","reference":"I. Karakaya and W.T. Thompson, Bull. Alloy Phase Diagrams, 9, 144 (1988).","status":"resolved","year":"1988"}],"component":"PB","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":0,"id":"ORC-TW3IVYSZUR","locator":{"ref":"sha256:15e0479ab64b3d87/p2/tab-3","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"SB":0.0,"SN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"ε"}],"pid":"sha256:15e0479ab64b3d87/p2/tab-3/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"Molar volume","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.94365},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09437,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/VOLUME","floor":0.005,"floor_unit":"relative (fraction of the value)","n_pairs":0,"value":0.09437},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"cm3/mol","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"cm3/mol","unit_printed":"cm3/mol","value":18.873,"value_printed":18.873},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-GPZJ225TBQ","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":2},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5761863848,"SB":0.2801431831,"SN":0.1436704321},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":566.65,"temperature_basis":"printed","temperature_printed":"293.5","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":566.65},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-Q6C2CMW3YJ","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":3},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4669059086,"SB":0.397268825,"SN":0.1358252664},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":635.15,"temperature_basis":"printed","temperature_printed":"362","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":635.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-UNZZJ45JXI","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3689420684,"SB":0.5022654177,"SN":0.1287925138},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":695.15,"temperature_basis":"printed","temperature_printed":"422","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":695.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-KF6YKHO5H7","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":5},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2806235454,"SB":0.5969242631,"SN":0.1224521915},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":743.15,"temperature_basis":"printed","temperature_printed":"470","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":743.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-GN4IE3IO4L","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":6},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2005926884,"SB":0.6827004769,"SN":0.1167068347},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":780.15,"temperature_basis":"printed","temperature_printed":"507","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":780.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-HBFISLQAFD","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":7},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1277352264,"SB":0.7607883229,"SN":0.1114764507},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":817.15,"temperature_basis":"printed","temperature_printed":"544","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":817.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-I4SQCCUW7N","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":8},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0611280711,"SB":0.8321771573,"SN":0.1066947716},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":828.15,"temperature_basis":"printed","temperature_printed":"555","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":828.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-OZTRSMK45D","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":9},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.5741202177,"SB":0.1395693039,"SN":0.2863104784},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":516.15,"temperature_basis":"printed","temperature_printed":"243","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":516.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-NOKT4ZLW2Q","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":10},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4653227296,"SB":0.263947847,"SN":0.2707294234},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":561.15,"temperature_basis":"printed","temperature_printed":"288","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":561.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-RRDNLQS4AK","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":11},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3677556302,"SB":0.3754876802,"SN":0.2567566896},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":616.15,"temperature_basis":"printed","temperature_printed":"343","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":616.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-EEGFOJB4PF","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":12},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2797654101,"SB":0.4760791145,"SN":0.2441554754},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":677.15,"temperature_basis":"printed","temperature_printed":"404","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":677.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-BVPVFAJQLQ","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":13},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2000079807,"SB":0.5672587275,"SN":0.2327332918},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":730.15,"temperature_basis":"printed","temperature_printed":"457","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":730.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-LBVWUNCVAL","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":14},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1273795312,"SB":0.6502884085,"SN":0.2223320603},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":774.15,"temperature_basis":"printed","temperature_printed":"501","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":774.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5P2O3IXVE6","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":15},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0609651341,"SB":0.7262141133,"SN":0.2128207527},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":812.15,"temperature_basis":"printed","temperature_printed":"539","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":812.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5O5DJIZYBL","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":16},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.4637502507,"SB":0.1315279401,"SN":0.4047218092},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r16#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":514.15,"temperature_basis":"printed","temperature_printed":"241","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":514.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-IQ4D37YFPO","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":17},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3665767981,"SB":0.2495227088,"SN":0.3839004931},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r17#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":561.15,"temperature_basis":"printed","temperature_printed":"288","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":561.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-SMYENWMQDZ","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":18},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2789125071,"SB":0.3559707917,"SN":0.3651167012},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r18#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":610.15,"temperature_basis":"printed","temperature_printed":"337","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":610.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-HQAS7QTHGT","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":19},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1994266718,"SB":0.4524880245,"SN":0.3480853037},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":662.15,"temperature_basis":"printed","temperature_printed":"389","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":662.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-TP32OKKTNN","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":20},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1270258115,"SB":0.5404021876,"SN":0.3325720008},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":718.15,"temperature_basis":"printed","temperature_printed":"445","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":718.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-R3PQWPLQXI","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":21},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0608030633,"SB":0.6208144571,"SN":0.3183824796},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r21#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":762.15,"temperature_basis":"printed","temperature_printed":"489","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":762.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5KLX4KWCOV","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":22},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.3654054993,"SB":0.1243627126,"SN":0.5102317881},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r22#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":513.15,"temperature_basis":"printed","temperature_printed":"240","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":513.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-USU4CXADLV","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":23},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2780647886,"SB":0.2365925764,"SN":0.485342635},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r23#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":566.15,"temperature_basis":"printed","temperature_printed":"293","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":566.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-G54ZWCVURP","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":24},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1988487322,"SB":0.3383825338,"SN":0.462768734},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r24#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":615.15,"temperature_basis":"printed","temperature_printed":"342","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":615.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-5Q3253RYLP","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":25},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1266740508,"SB":0.431124562,"SN":0.4422013872},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r25#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":657.15,"temperature_basis":"printed","temperature_printed":"384","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":657.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-3ADVWHAJ6E","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":26},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.060641852,"SB":0.5159737077,"SN":0.4233844404},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r26#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":709.15,"temperature_basis":"printed","temperature_printed":"436","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":709.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-C66SYIBIDH","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":27},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.2772222076,"SB":0.1179378314,"SN":0.604839961},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r27#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":523.15,"temperature_basis":"printed","temperature_printed":"250","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":523.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-HR2ML7HW3Y","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":28},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1982741327,"SB":0.2249364886,"SN":0.5767893787},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r28#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":573.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-3ECRCD6K7J","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":29},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.126324233,"SB":0.3224504896,"SN":0.5512252774},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r29#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":620.15,"temperature_basis":"printed","temperature_printed":"347","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":620.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-P6CELE6FVY","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":30},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0604814932,"SB":0.411687431,"SN":0.5278310757},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r30#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":657.15,"temperature_basis":"printed","temperature_printed":"384","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":657.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-V224LCPXQ4","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":31},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1977028443,"SB":0.112144189,"SN":0.6901529667},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r31#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":521.15,"temperature_basis":"printed","temperature_printed":"248","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":521.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-FX7NEJKCD4","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":32},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1259763419,"SB":0.2143749839,"SN":0.6596486742},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r32#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":584.15,"temperature_basis":"printed","temperature_printed":"311","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":584.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-3VLWMBKJPW","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":33},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0603219804,"SB":0.3079512401,"SN":0.6317267795},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r33#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":627.15,"temperature_basis":"printed","temperature_printed":"354","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":627.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-H2RP7F2TVK","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":34},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.1256303617,"SB":0.1068931133,"SN":0.7674765251},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r34#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":528.15,"temperature_basis":"printed","temperature_printed":"255","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":528.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-QD5POLZZDQ","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":35},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0601633067,"SB":0.2047607941,"SN":0.7350758993},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r35#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":592.15,"temperature_basis":"printed","temperature_printed":"319","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":592.15},{"chemical_system":"PB-SB-SN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02645349"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":0,"id":"ORC-TUS35PVJN4","locator":{"ref":"sha256:15e0479ab64b3d87/p8/tab-6","row":36},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/bf02645349","own_work_of_paper":true},"overall_composition":{"PB":0.0600054656,"SB":0.1021117975,"SN":0.837882737},"paper":"doi:10.1007/bf02645349","paper_id":"doi:10.1007/bf02645349","phases":[{"label":"liquidus"}],"pid":"sha256:15e0479ab64b3d87/p8/tab-6/r36#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PB-SB-SN","system":"PB-SB-SN","temperature_K":529.15,"temperature_basis":"printed","temperature_printed":"256","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":529.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"PB-SB-SN"}