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Stored -3420 is printed/10 (per atom).","verdict":"misread"}}],"id":"ORC-255XO3ADNH.b3b437","locator":{"ref":"sha256:c89cdfcb2b525859/p2/tab-1","row":40},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:model_value","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2014.02.001","own_work_of_paper":true},"overall_composition":{"TH":0.3},"overall_composition_basis":"from_formula","overall_composition_stored":{"TH":0.3,"U":0.0},"paper":"doi:10.1016/j.jnucmat.2014.02.001","paper_id":"doi:10.1016/j.jnucmat.2014.02.001","per_formula_unit_divisor":10.0,"phases":[{"label":"Th3Pu7"}],"pid":"sha256:c89cdfcb2b525859/p2/tab-1/r40#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"CPM_EXPRESSION_TERM","property_code_before_gates":"CPM","property_expression":{"form":"Cp = a + b T + c T^2 + d T^-2 (+ ...)","printed":"Cp coefficient d (dT−2 column)","temperature_range_K":{"max":1650.0,"min":1000.0},"term":"d"},"property_group":"model expression","property_printed":"Cp coefficient d (dT−2 column)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"PU-TH-U","system":"PU-TH","temperature_K":null,"temperature_K_stored":1325.0,"temperature_basis":"printed_range","temperature_range_K":{"max":1650.0,"min":1000.0},"temperature_uncertainty":{"basis":"printed_range","value":325.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":171.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property CPM_EXPRESSION_TERM","sigma_method":{"reason":"no method floor defined for property CPM_EXPRESSION_TERM","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"reviewer","unit_printed":"J K �1 mol �1","value":-3420.0,"value_printed":-34200.0},{"chemical_system":"PU-TH","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"CPM_EXPRESSION_TERM","before":"CPM","evidence":{"form":"Cp = a + b T + c T^2 + d T^-2 (+ ...)","printed":"Cp coefficient a","term":"a"},"field":"property","gate":"R2","rule":"expression_coefficient","visual_check":{"checked":"2026-10-24","image_sha256":"6662da256da92a991060a0bafee3960e5a80b476c7063a02e802957634afe1cb","page":2,"pdf_sha256_prefix":"3ef4d8a52f994c6c","seen":"A printed expression in T (A + B T, Cp polynomial) was split into coefficients stored as values at one temperature; 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