{"artifacts":{"doi:10.1016/s0364-5916(00)00007-9/p4/text-11":{"artifact":"text_passage","label":"page 4, passage 11","page":4},"doi:10.1016/s0364-5916(00)00007-9/p5/text-03":{"artifact":"text_passage","label":"page 5, passage 3","page":5},"doi:10.1016/s0364-5916(00)00007-9/p6/text-02":{"artifact":"text_passage","label":"page 6, passage 2","page":6},"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1":{"artifact":"table","caption":"Summary","label":"1","page":9},"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2":{"artifact":"table","caption":"Standard","label":"2","page":9}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["SI","TE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"Mc8e5055f":{"catalog_entry":{"license":"CC BY 4.0","name":"SiTe-99Feu-LB.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Y. Feutelais, A. Schlieper, S.G. Fries, Calphad, 23, 365-78(1999).","model_doi":"10.1016/s0364-5916(00)00007-9","reproduced_by_calculation":false,"tdb":"SiTe-99Feu-LB.tdb","tdb_path":"databases/sgte-binary/SiTe-99Feu-LB.tdb","tdb_sha256":"0d62124cd250a55a5554101c3b5f31292094d5a990a1b3e8e227e9fa23feeb44"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/s0364-5916(00)00007-9":{"authors":["Y. Feutelais","A. Schlieper","S.G. Fries"],"citation":"Y. Feutelais, A. Schlieper, S.G. Fries, Thermodynamic evaluation of the system silicon — Tellurium, Calphad 23, 365-378 (1999).","container":"Calphad","doi":"10.1016/s0364-5916(00)00007-9","doi_url":"https://doi.org/10.1016/s0364-5916(00)00007-9","id":"doi:10.1016/s0364-5916(00)00007-9","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"c4b90095184c873a","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic evaluation of the system silicon — Tellurium","year":1999},"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#12":{"citation":"reference [12] of doi:10-1016-s0364-5916-00-00007-9 (no printed entry could be read)","id":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#12","kind":"unresolved_citation","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["unresolved_citation"]},"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#13":{"citation":"reference [13] of doi:10-1016-s0364-5916-00-00007-9 (no printed entry could be read)","id":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#13","kind":"unresolved_citation","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["unresolved_citation"]},"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#14":{"citation":"reference [14] of doi:10-1016-s0364-5916-00-00007-9 (no printed entry could be read)","id":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#14","kind":"unresolved_citation","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["unresolved_citation"]},"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#16":{"citation":"reference [16] of doi:10-1016-s0364-5916-00-00007-9 (no printed entry could be read)","id":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#16","kind":"unresolved_citation","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["unresolved_citation"]},"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#17":{"citation":"reference [17] of doi:10-1016-s0364-5916-00-00007-9 (no printed entry could be read)","id":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#17","kind":"unresolved_citation","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["unresolved_citation"]},"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#19":{"citation":"reference [19] of doi:10-1016-s0364-5916-00-00007-9 (no printed entry could be read)","id":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#19","kind":"unresolved_citation","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["unresolved_citation"]}},"part":1,"parts":1,"records":[{"chemical_system":"SI-TE","cited_sources":[{"first_author":"EXSTEEN","kind":"unknown","label":"22","reference":"G. EXSTEEN,J. DROWART,A. VAN DER AUWERA-MAHIEUand R. CALLAERTS,.I. Phys. Chem., 71,(1967), 4130.","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":2.6,"before":13.0,"evidence":{"divisor":5.0,"sigma_printed":13.0,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-4WEMGUOLGR","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2","row":3},"method":"2nd Law","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"TE":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","per_formula_unit_divisor":5.0,"phases":[{"label":"α-Si2Te3","model_phase":"SI2TE3_LT"}],"pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH0","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"fixed_state_variables":{"T":298.15},"phase":"DIAMOND_A4"},"TE":{"fixed_state_variables":{"T":298.15},"phase":"HEXAGONAL_A8"}},"source_system":"SI-TE","system":"SI-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":2.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.0,"sigma_method":{"basis":"prior","ci95":null,"class":"kems_vapour_second_law","entry":"value_types/HM_FORM/classes/kems_vapour_second_law","floor":3.0,"floor_unit":"kJ/mol-atom","n_pairs":1,"prior_source":"drowart2005","value":3.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.6},"sigma_reading":{"basis":"last_printed_digit","value":0.1},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":13.0},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ.mol−1 (mol = mol of formula unit)","unit_stored":"J/mol-atom","value":-18.4,"value_printed":-92,"value_stored":-18400.0},{"chemical_system":"SI-TE","cited_sources":[{"first_author":"EXSTEEN","kind":"unknown","label":"22","reference":"G. EXSTEEN,J. DROWART,A. VAN DER AUWERA-MAHIEUand R. CALLAERTS,.I. Phys. Chem., 71,(1967), 4130.","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":3.8,"before":19.0,"evidence":{"divisor":5.0,"sigma_printed":19.0,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-CWG2DBYN6M","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2","row":4},"method":"3rd Law","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"TE":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","per_formula_unit_divisor":5.0,"phases":[{"label":"α-Si2Te3","model_phase":"SI2TE3_LT"}],"pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH0","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"fixed_state_variables":{"T":298.15},"phase":"DIAMOND_A4"},"TE":{"fixed_state_variables":{"T":298.15},"phase":"HEXAGONAL_A8"}},"source_system":"SI-TE","system":"SI-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":3.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.8,"sigma_method":{"basis":"prior","ci95":null,"class":"kems_vapour_third_law","entry":"value_types/HM_FORM/classes/kems_vapour_third_law","floor":2.0,"floor_unit":"kJ/mol-atom","n_pairs":0,"prior_source":"drowart2005","value":2.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.8},"sigma_reading":{"basis":"last_printed_digit","value":0.1},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":19.0},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ.mol−1 (mol = mol of formula unit)","unit_stored":"J/mol-atom","value":-17.8,"value_printed":-89,"value_stored":-17800.0},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"13","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.4,"before":7.0,"evidence":{"divisor":5.0,"sigma_printed":7.0,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-Q77N3JJJ37","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2","row":5},"method":"2nd Law","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#13","own_work_of_paper":false},"overall_composition":{"TE":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","per_formula_unit_divisor":5.0,"phases":[{"label":"α-Si2Te3","model_phase":"SI2TE3_LT"}],"pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH0","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"fixed_state_variables":{"T":298.15},"phase":"DIAMOND_A4"},"TE":{"fixed_state_variables":{"T":298.15},"phase":"HEXAGONAL_A8"}},"source_system":"SI-TE","system":"SI-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.4},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.0,"sigma_method":{"basis":"prior","ci95":null,"class":"kems_vapour_second_law","entry":"value_types/HM_FORM/classes/kems_vapour_second_law","floor":3.0,"floor_unit":"kJ/mol-atom","n_pairs":1,"prior_source":"drowart2005","value":3.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.4},"sigma_reading":{"basis":"last_printed_digit","value":0.1},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":7.0},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ.mol−1 (mol = mol of formula unit)","unit_stored":"J/mol-atom","value":-13.8,"value_printed":-69,"value_stored":-13800.0},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"13","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.0,"before":5.0,"evidence":{"divisor":5.0,"sigma_printed":5.0,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-T5IN5YOYEN","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2","row":6},"method":"3rd Law","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#13","own_work_of_paper":false},"overall_composition":{"TE":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","per_formula_unit_divisor":5.0,"phases":[{"label":"α-Si2Te3","model_phase":"SI2TE3_LT"}],"pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH0","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"fixed_state_variables":{"T":298.15},"phase":"DIAMOND_A4"},"TE":{"fixed_state_variables":{"T":298.15},"phase":"HEXAGONAL_A8"}},"source_system":"SI-TE","system":"SI-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":2.0,"sigma_method":{"basis":"prior","ci95":null,"class":"kems_vapour_third_law","entry":"value_types/HM_FORM/classes/kems_vapour_third_law","floor":2.0,"floor_unit":"kJ/mol-atom","n_pairs":0,"prior_source":"drowart2005","value":2.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.1},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":5.0},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ.mol−1 (mol = mol of formula unit)","unit_stored":"J/mol-atom","value":-14.4,"value_printed":-72,"value_stored":-14400.0},{"chemical_system":"SI-TE","cited_sources":[{"first_author":"OHARE","kind":"unknown","label":"21","reference":"P.A.G.O’HARE, G.A. HOPE and C.M. BECK II, .I. Chem. Thermodynamics, 25,(1993), 919.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":1.2,"before":6.0,"evidence":{"divisor":5.0,"sigma_printed":6.0,"why":"value divided by the atoms per formula unit"},"field":"uncertainty.value","gate":"R2","rule":"printed_sigma_rescaled_with_value","visual_check":{"checked":"2026-10-24","image_sha256":"bd42012ea2bde15a3c0a5db0986aa83283a532ad7fdd608a1a82ad1664641505","page":8,"pdf_sha256_prefix":"a5b5f8815db7a2de","seen":"Values printed per formula unit and divided by the atom count kept the printed sigma undivided; the sigma is a property of the printed number and is divided by the same count (relative uncertainty unchanged).","verdict":"rule_confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":1,"id":"ORC-FGHEJFMUYN","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2","row":7},"method":"calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"TE":0.6},"overall_composition_basis":"from_formula","paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","per_formula_unit_divisor":5.0,"phases":[{"label":"α-Si2Te3","model_phase":"SI2TE3_LT"}],"pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH0","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"fixed_state_variables":{"T":298.15},"phase":"DIAMOND_A4"},"TE":{"fixed_state_variables":{"T":298.15},"phase":"HEXAGONAL_A8"}},"source_system":"SI-TE","system":"SI-TE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","rescaled_with_value":true,"value":1.2},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.2},"sigma_reading":{"basis":"last_printed_digit","value":0.1},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"uncertainty_stored":{"basis":"printed","value":6.0},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"kJ.mol−1 (mol = mol of formula unit)","unit_stored":"J/mol-atom","value":-14.2,"value_printed":-71,"value_stored":-14200.0},{"chemical_system":"SI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-Z3S2K6PHZ4","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":12},"model":"Mc8e5055f","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/s0364-5916(00)00007-9","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-015c50cc#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":680.15,"temperature_printed":"407.0","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":680.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"19","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-6A5VHYDGCX","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":6},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#19","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-07273060#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":1162.15,"temperature_printed":"889 *","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1162.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"14","status":"unresolved"},{"kind":"unknown","label":"15","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2MSCKY634H","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":5},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#14","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-0b9dadec#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":679.15,"temperature_printed":"406 ± 1","temperature_uncertainty":{"basis":"printed","value":1.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":679.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"13","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ECRPAXYUZV","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":3},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#13","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-1826aaa2#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":1165.15,"temperature_printed":"892 ± 0.5","temperature_uncertainty":{"basis":"printed","value":0.5},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":0.5},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1165.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"12","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-W7JQSNOULI","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":1},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#12","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-2086f038#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":1165.15,"temperature_printed":"892 ± 3","temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1165.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"17","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-DWL6NL2BTV","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":9},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#17","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-2a595a4b#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":1159.15,"temperature_printed":"886 ± 2 - 5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1159.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"12","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3N4ENNT75E","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":2},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#12","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-5256be00#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":682.15,"temperature_printed":"409 ± 1","temperature_uncertainty":{"basis":"printed","value":1.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":682.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"16","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7RTIOECO3V","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":8},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#16","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-64a0ed62#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":680.15,"temperature_printed":"407","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":680.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"17","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2YDBJOAM7Z","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":10},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#17","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-83c36452#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":687.15,"temperature_printed":"414","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":687.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"14","status":"unresolved"},{"kind":"unknown","label":"15","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-6ITLFIIPMD","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#14","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-88bd2a89#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":1168.15,"temperature_printed":"895 ± 3","temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168.15},{"chemical_system":"SI-TE","cited_sources":[{"kind":"unknown","label":"16","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-RKV7DRKJPH","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":7},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#16","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r-unplaced-98b6a8d0#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":1158.15,"temperature_printed":"885 °","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1158.15},{"chemical_system":"SI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-FU7EOXLZUB","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1","row":11},"model":"Mc8e5055f","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/s0364-5916(00)00007-9","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p9/tab-1/r05#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SI-TE","system":"SI-TE","temperature_K":1165.25,"temperature_printed":"892.1","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1165.25},{"chemical_system":"SI-TE","citations_printed":["17"],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-4DUEZVUZSR","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p4/text-11"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/s0364-5916(00)00007-9","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p4/text-11/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Thus we defined a hypothetical transformation temperature Ttrans = 401°C as being the average value of the reported measurements of [17].","quote_page":4,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"SI-TE","system":"SI-TE","temperature_K":674.15,"temperature_printed":"401 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":674.15},{"chemical_system":"SI-TE","citations_printed":["16"],"cited_sources":[{"kind":"unknown","label":"16","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WYJX7JQO3O","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#16","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03/s01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The reported values of [16] being measured on cooling, we may expect some delay in the observation of the peritectic invariant which explains the low observed temperature of 885°C.","quote_page":5,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"SI-TE","system":"SI-TE","temperature_K":1158.15,"temperature_printed":"885 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1158.15},{"chemical_system":"SI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-753SD23PDW","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/s0364-5916(00)00007-9","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"This confirms our choice of 892°C for this invariant temperature, as 7°C seems a realistic value for the temperature shift.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"SI-TE","system":"SI-TE","temperature_K":1165.15,"temperature_printed":"892 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1165.15},{"chemical_system":"SI-TE","citations_printed":["16"],"cited_sources":[{"kind":"unknown","label":"16","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2OFAA7XCA2","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#16","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"On thte contrary, [16] reported an observed melting point of pure silicon at 1411°C.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"SI-TE","system":"SI-TE","temperature_K":1684.15,"temperature_printed":"1411 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1684.15},{"chemical_system":"SI-TE","citations_printed":["14"],"cited_sources":[{"kind":"assessment","label":"14","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-H746PQRBLH","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"unresolved:source:doi:10-1016-s0364-5916-00-00007-9#14","own_work_of_paper":false},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p5/text-03/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"As shown in the Figure 1, the liquidus data reported by [14] (1406 K, XT= = 0.4) was not used in the final optimization data file because it is in complete disagreement with other results.","quote_page":5,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"SI-TE","system":"SI-TE","temperature_K":1406.0,"temperature_printed":"1406 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1406.0},{"chemical_system":"SI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ME4NFMMO6A.11a0ce","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p6/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/s0364-5916(00)00007-9","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p6/text-02/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"As explained above, the temperature of transition of silicon sesquitelluride is 401°C and corresponds, according to our assumption, to equilibria between Si, (Y- SiaTes and ,B- S&Tea on the one hand and Q - S&Tea, p - SizTes and Te on the other hand.","quote_page":6,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"SI-TE","system":"SI-TE","temperature_K":674.15,"temperature_printed":"401 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":674.15},{"chemical_system":"SI-TE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ME4NFMMO6A.14de5b","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(00)00007-9/p6/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/s0364-5916(00)00007-9","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(00)00007-9","paper_id":"doi:10.1016/s0364-5916(00)00007-9","pid":"doi:10.1016/s0364-5916(00)00007-9/p6/text-02/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The calculated invariants are : T = 892.1\"C Si + L + p-SisTes with zke = 0.604 T = 407.O\"C L + ,&SisTes + Te with zTe L - 0.865","quote_page":6,"reaction":{"printed":"Si + L + p-SisTes"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"SI-TE","system":"SI-TE","temperature_K":1165.25,"temperature_printed":"892.1 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1165.25}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"SI-TE"}