{"artifacts":{"sha256:8df6e975c3b6dbea/p2/tab-1":{"artifact":"table","caption":"Crystal structure data of the compounds in the Y-Si-C system.","label":"1","page":2},"sha256:8df6e975c3b6dbea/p3/tab-2":{"artifact":"table","caption":"Enthalpy (kJ/mole-atom) and entropy (kJ/K·mole-atom) of formation for the compounds in the Y-Si-C system at various temperatures.","label":"2","page":3},"sha256:8df6e975c3b6dbea/p3/tab-3":{"artifact":"table","caption":"Summary of formation enthalpies for the compounds in the Y-Si-C system ac- cording to the present work.","label":"3","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["SI","Y"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02676225":{"authors":["R. I. Polotskaya","V. R. Sidorko"],"citation":"R. I. Polotskaya, V. R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metall Met Ceram 36, 315-319 (1997).","container":"Powder Metall Met Ceram","doi":"10.1007/bf02676225","doi_url":"https://doi.org/10.1007/bf02676225","id":"doi:10.1007/bf02676225","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermodynamic properties of yttrium silicides","year":1997},"doi:10.1016/0022-5088(72)90144-0":{"authors":["I. Mayer","I. Felner"],"citation":"I. Mayer, I. Felner, High-temperature X-ray study of rare-earth silicides, Journal of the Less Common Metals 29, 25-31 (1972).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(72)90144-0","doi_url":"https://doi.org/10.1016/0022-5088(72)90144-0","id":"doi:10.1016/0022-5088(72)90144-0","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"High-temperature X-ray study of rare-earth silicides","year":1972},"doi:10.1016/0022-5088(74)90021-6":{"authors":["I. Mayer","I. Felner"],"citation":"I. Mayer, I. Felner, Nowotny phases of M5X3-type rare-earth silicides and germanides with boron, Journal of the Less Common Metals 37, 171-173 (1974).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(74)90021-6","doi_url":"https://doi.org/10.1016/0022-5088(74)90021-6","id":"doi:10.1016/0022-5088(74)90021-6","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Nowotny phases of M5X3-type rare-earth silicides and germanides with boron","year":1974},"doi:10.1016/0022-5088(81)90200-9":{"authors":["A.K. Niessen","F.R. De Boer"],"citation":"A.K. Niessen, F.R. De Boer, The enthalpy of formation of solid borides, carbides, nitrides, silicides and phosphides of transition and noble metals, Journal of the Less Common Metals 82, 75-80 (1981).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(81)90200-9","doi_url":"https://doi.org/10.1016/0022-5088(81)90200-9","id":"doi:10.1016/0022-5088(81)90200-9","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The enthalpy of formation of solid borides, carbides, nitrides, silicides and phosphides of transition and noble metals","year":1981},"doi:10.1016/0022-5088(84)90028-6":{"authors":["T.W. Button","I.J. McColm"],"citation":"T.W. Button, I.J. McColm, Reaction of carbon with lanthanide silicides IV: The Y5Si3-C system, Journal of the Less Common Metals 97, 237-244 (1984).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(84)90028-6","doi_url":"https://doi.org/10.1016/0022-5088(84)90028-6","id":"doi:10.1016/0022-5088(84)90028-6","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Reaction of carbon with lanthanide silicides IV: The Y5Si3-C system","year":1984},"doi:10.1016/0022-5088(86)90377-2":{"authors":["I.J McColm","V Kotrocvo","T.W Button","N.J Clark","B Bruer"],"citation":"I.J McColm, V Kotrocvo, T.W Button, N.J Clark, B Bruer, Hydrogen sorption properties of D88-type systems: I. Hydrides of Y5Si3, Journal of the Less Common Metals 115, 113-125 (1986).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(86)90377-2","doi_url":"https://doi.org/10.1016/0022-5088(86)90377-2","id":"doi:10.1016/0022-5088(86)90377-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Hydrogen sorption properties of D88-type systems: I. Hydrides of Y5Si3","year":1986},"doi:10.1016/0022-5088(87)90167-6":{"authors":["V. Kotroczo","I.J. McColm","N.J. Clark"],"citation":"V. Kotroczo, I.J. McColm, N.J. Clark, Hydrogen sorption properties of D88-type systems II: Sc5Si3 and Y5Si3-Sc5Si3 solid solutions, Journal of the Less Common Metals 132, 1-13 (1987).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(87)90167-6","doi_url":"https://doi.org/10.1016/0022-5088(87)90167-6","id":"doi:10.1016/0022-5088(87)90167-6","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Hydrogen sorption properties of D88-type systems II: Sc5Si3 and Y5Si3-Sc5Si3 solid solutions","year":1987},"doi:10.1016/0022-5088(87)90517-0":{"authors":["I.J McColm","V Kotroczo"],"citation":"I.J McColm, V Kotroczo, Hydrogen sorption properties of D88-type systems III. The effect of germanium substitution in Ys−aScaSi3 phases, Journal of the Less Common Metals 131, 191-199 (1987).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(87)90517-0","doi_url":"https://doi.org/10.1016/0022-5088(87)90517-0","id":"doi:10.1016/0022-5088(87)90517-0","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Hydrogen sorption properties of D88-type systems III. The effect of germanium substitution in Ys−aScaSi3 phases","year":1987},"doi:10.1016/0022-5088(90)90149-e":{"authors":["T.W. Button","I.J. McColm","J.M. Ward"],"citation":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxide-silicides, Journal of the Less Common Metals 159, 205-222 (1990).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(90)90149-e","doi_url":"https://doi.org/10.1016/0022-5088(90)90149-e","id":"doi:10.1016/0022-5088(90)90149-e","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Preparation of yttrium silicides and oxide-silicides","year":1990},"doi:10.1016/0022-5088(90)90292-r":{"authors":["L. Topor","O.J. Kleppa"],"citation":"L. Topor, O.J. Kleppa, Standard enthalpies of formation of Me5Si3 (Me  Y, Lu, Zr) and of Hf3Si2, Journal of the Less Common Metals 167, 91-99 (1990).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(90)90292-r","doi_url":"https://doi.org/10.1016/0022-5088(90)90292-r","id":"doi:10.1016/0022-5088(90)90292-r","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Standard enthalpies of formation of Me5Si3 (Me  Y, Lu, Zr) and of Hf3Si2","year":1990},"doi:10.1016/0304-8853(93)90175-2":{"authors":["F. Canepa","S. Cirafici","F. Merlo","A. Palenzona"],"citation":"F. Canepa, S. Cirafici, F. Merlo, A. Palenzona, Electrical resistivity measurements on some R5Si3 phases: R = Gd, Tb, Yb, Lu and Y, Journal of Magnetism and Magnetic Materials 118, 182-186 (1993).","container":"Journal of Magnetism and Magnetic Materials","doi":"10.1016/0304-8853(93)90175-2","doi_url":"https://doi.org/10.1016/0304-8853(93)90175-2","id":"doi:10.1016/0304-8853(93)90175-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Electrical resistivity measurements on some R5Si3 phases: R = Gd, Tb, Yb, Lu and Y","year":1993},"doi:10.1016/0925-8388(92)90051-a":{"authors":["V Kotroczo","I.J McColm","M Rebbeck","J.M Ward"],"citation":"V Kotroczo, I.J McColm, M Rebbeck, J.M Ward, Stable and metastable phases in the metal-rich YZrSi system and their hydrogen reactivity, Journal of Alloys and Compounds 189, 87-96 (1992).","container":"Journal of Alloys and Compounds","doi":"10.1016/0925-8388(92)90051-a","doi_url":"https://doi.org/10.1016/0925-8388(92)90051-a","id":"doi:10.1016/0925-8388(92)90051-a","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Stable and metastable phases in the metal-rich YZrSi system and their hydrogen reactivity","year":1992},"doi:10.1016/0925-8388(92)90250-d":{"authors":["I.J. McColm","J.M. Ward"],"citation":"I.J. McColm, J.M. Ward, Hydrogen sorption properties of D88-type systems: IV. Y5Ge3 and Y5Si3Y5Ge3 solid solutions, Journal of Alloys and Compounds 178, 91-100 (1992).","container":"Journal of Alloys and Compounds","doi":"10.1016/0925-8388(92)90250-d","doi_url":"https://doi.org/10.1016/0925-8388(92)90250-d","id":"doi:10.1016/0925-8388(92)90250-d","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Hydrogen sorption properties of D88-type systems: IV. Y5Ge3 and Y5Si3Y5Ge3 solid solutions","year":1992},"doi:10.1016/j.jallcom.2003.09.023":{"authors":["A.Yu Kozlov","V.V Pavlyuk"],"citation":"A.Yu Kozlov, V.V Pavlyuk, Investigation of the interaction of the components in the Y–Si–Sb system at 670 K, Journal of Alloys and Compounds 370, 192-197 (2004).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2003.09.023","doi_url":"https://doi.org/10.1016/j.jallcom.2003.09.023","id":"doi:10.1016/j.jallcom.2003.09.023","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Investigation of the interaction of the components in the Y–Si–Sb system at 670 K","year":2004},"doi:10.1016/j.jallcom.2004.03.069":{"authors":["A.O. Pecharsky","V.K. Pecharsky","K.A. Gschneidner"],"citation":"A.O. Pecharsky, V.K. Pecharsky, K.A. Gschneidner, Phase relationships and low temperature heat capacities of alloys in the Y5Si4–Y5Ge4 pseudo binary system, Journal of Alloys and Compounds 379, 127-134 (2004).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2004.03.069","doi_url":"https://doi.org/10.1016/j.jallcom.2004.03.069","id":"doi:10.1016/j.jallcom.2004.03.069","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase relationships and low temperature heat capacities of alloys in the Y5Si4–Y5Ge4 pseudo binary system","year":2004},"doi:10.1016/j.jallcom.2005.09.012":{"authors":["Jérome Roger","Volodymyr Babizhetskyy","Thierry Guizouarn","Kurt Hiebl","Roland Guérin","Jean-François Halet"],"citation":"Jérome Roger, Volodymyr Babizhetskyy, Thierry Guizouarn, Kurt Hiebl, Roland Guérin, Jean-François Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417, 72-84 (2006).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2005.09.012","doi_url":"https://doi.org/10.1016/j.jallcom.2005.09.012","id":"doi:10.1016/j.jallcom.2005.09.012","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho)","year":2006},"doi:10.1016/j.jeurceramsoc.2019.07.012":{"authors":["Kai Xu","Houke Zou","Keke Chang","Zixuan Deng","Xiaobing Zhou","Yeyan Huang","Leilei Chen","Feng Huang","Qing Huang"],"citation":"Kai Xu, Houke Zou, Keke Chang, Zixuan Deng, Xiaobing Zhou, Yeyan Huang et al., Thermodynamic description of the sintering aid system in silicon carbide ceramics with the addition of yttrium, Journal of the European Ceramic Society 39, 4510-4519 (2019).","container":"Journal of the European Ceramic Society","doi":"10.1016/j.jeurceramsoc.2019.07.012","doi_url":"https://doi.org/10.1016/j.jeurceramsoc.2019.07.012","id":"doi:10.1016/j.jeurceramsoc.2019.07.012","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"8df6e975c3b6dbea","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic description of the sintering aid system in silicon carbide ceramics with the addition of yttrium","year":2019},"doi:10.1016/s0925-8388(98)00504-0":{"authors":["S.V. Meschel","O.J. Kleppa"],"citation":"S.V. Meschel, O.J. Kleppa, Standard enthalpies of formation of some 4d transition metal silicides by high temperature direct synthesis calorimetry, Journal of Alloys and Compounds 274, 193-200 (1998).","container":"Journal of Alloys and Compounds","doi":"10.1016/s0925-8388(98)00504-0","doi_url":"https://doi.org/10.1016/s0925-8388(98)00504-0","id":"doi:10.1016/s0925-8388(98)00504-0","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Standard enthalpies of formation of some 4d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},"doi:10.1021/ic50063a026":{"authors":["Aravamudhan Raman"],"citation":"Aravamudhan Raman, Ternary FeB- and CrB-type phases with yttrium, lanthanum, and some rare earths, Inorg. Chem. 7, 973-976 (1968).","container":"Inorg. Chem.","doi":"10.1021/ic50063a026","doi_url":"https://doi.org/10.1021/ic50063a026","id":"doi:10.1021/ic50063a026","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Ternary FeB- and CrB-type phases with yttrium, lanthanum, and some rare earths","year":1968},"doi:10.1021/j100810a028":{"authors":["I. P. Mayer","Ephraim Banks","Ben Post"],"citation":"I. P. Mayer, Ephraim Banks, Ben Post, RARE EARTH DISILICIDES<sup>1</sup>, J. Phys. Chem. 66, 693-696 (1962).","container":"J. Phys. Chem.","doi":"10.1021/j100810a028","doi_url":"https://doi.org/10.1021/j100810a028","id":"doi:10.1021/j100810a028","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"RARE EARTH DISILICIDES<sup>1</sup>","year":1962},"doi:10.1021/j150582a030":{"authors":["J. A. Perri","E. Banks","B. Post"],"citation":"J. A. Perri, E. Banks, B. Post, Polymorphism of Rare Earth Disilicides, J. Phys. Chem. 63, 2073-2074 (1959).","container":"J. Phys. Chem.","doi":"10.1021/j150582a030","doi_url":"https://doi.org/10.1021/j150582a030","id":"doi:10.1021/j150582a030","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Polymorphism of Rare Earth Disilicides","year":1959},"doi:10.1107/s0365110x59001657":{"authors":["E. Parthé"],"citation":"E. Parthé, The crystal structure of YSi and Hf5Ge3(C), Acta Cryst 12, 559-560 (1959).","container":"Acta Cryst","doi":"10.1107/s0365110x59001657","doi_url":"https://doi.org/10.1107/s0365110x59001657","id":"doi:10.1107/s0365110x59001657","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The crystal structure of YSi and Hf5Ge3(C)","year":1959},"doi:10.1107/s0365110x60002144":{"authors":["E. Parthé"],"citation":"E. Parthé, The crystal structure of Y<sub>5</sub>Si<sub>3</sub>and Y<sub>5</sub>Ge<sub>3</sub>, Acta Cryst 13, 868-871 (1960).","container":"Acta Cryst","doi":"10.1107/s0365110x60002144","doi_url":"https://doi.org/10.1107/s0365110x60002144","id":"doi:10.1107/s0365110x60002144","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The crystal structure of Y<sub>5</sub>Si<sub>3</sub>and Y<sub>5</sub>Ge<sub>3</sub>","year":1960},"doi:10.1107/s0365110x67001902":{"authors":["G. S. Smith","A. G. Tharp","W. Johnson"],"citation":"G. S. Smith, A. G. Tharp, W. Johnson, Rare earth–germanium and –silicon compounds at 5:4 and 5:3 compositions, Acta Cryst 22, 940-943 (1967).","container":"Acta Cryst","doi":"10.1107/s0365110x67001902","doi_url":"https://doi.org/10.1107/s0365110x67001902","id":"doi:10.1107/s0365110x67001902","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Rare earth–germanium and –silicon compounds at 5:4 and 5:3 compositions","year":1967},"doi:10.3139/146.110003":{"citation":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the ce-Si, Y-Si mg-Ce-Si and Mg-Y-Si systems, Int. J. Mater. Res. 100 (2009) 208–217.","doi":"10.3139/146.110003","doi_url":"https://doi.org/10.3139/146.110003","id":"doi:10.3139/146.110003","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]}},"part":1,"parts":1,"records":[{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(87)90167-6","first_author":"Kotroczo","kind":"unknown","label":"28","paper":"doi:10.1016/0022-5088(87)90167-6","reference":"V. Kotroczo, I.J. McColm, N.J. Clark, Hydrogen sorption properties of D88-type systems II: Sc5Si3 and Y5Si3-Sc5Si3 solid solutions, Journal of the Less Common Metals 132 (1987) 1–13.","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-VJI2LRK4BD.0cf24f","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(87)90167-6","first_author":"Kotroczo","kind":"unknown","label":"28","paper":"doi:10.1016/0022-5088(87)90167-6","reference":"V. Kotroczo, I.J. McColm, N.J. Clark, Hydrogen sorption properties of D88-type systems II: Sc5Si3 and Y5Si3-Sc5Si3 solid solutions, Journal of the Less Common Metals 132 (1987) 1–13.","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-VJI2LRK4BD.80019d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01398,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01398},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.353,"value_stored":6.353},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(87)90167-6","first_author":"Kotroczo","kind":"unknown","label":"28","paper":"doi:10.1016/0022-5088(87)90167-6","reference":"V. Kotroczo, I.J. McColm, N.J. Clark, Hydrogen sorption properties of D88-type systems II: Sc5Si3 and Y5Si3-Sc5Si3 solid solutions, Journal of the Less Common Metals 132 (1987) 1–13.","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-VJI2LRK4BD.b72e42","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ECOJ7HMYV7.6307e5","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0185,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0185},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.41,"value_stored":8.41},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ECOJ7HMYV7.a7c2ec","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01396,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01396},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.344,"value_stored":6.344},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ECOJ7HMYV7.ceb788","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":2},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0185,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0185},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.41,"value_stored":8.41},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"30","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, M. Ben Yahia, V. Babizhetskyy, J. Bauer, S. Cordier, R. Guérin, K. Hiebl, X. Rocquefelte, J.-Y. Saillard, J.-F. Halet, Mn5Si3-type host-interstitial boron rareearth metal silicide compounds RE5Si3: Crystal structures, physical properties and theoretical considerations, Journal of Solid State Chemistry 179 (2006) 2310–2328.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-77ICV5C5WV.177a8b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0185,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0185},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.41,"value_stored":8.41},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"30","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, M. Ben Yahia, V. Babizhetskyy, J. Bauer, S. Cordier, R. Guérin, K. Hiebl, X. Rocquefelte, J.-Y. Saillard, J.-F. Halet, Mn5Si3-type host-interstitial boron rareearth metal silicide compounds RE5Si3: Crystal structures, physical properties and theoretical considerations, Journal of Solid State Chemistry 179 (2006) 2310–2328.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-77ICV5C5WV.82ce07","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01396,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01396},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.344,"value_stored":6.344},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"30","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, M. Ben Yahia, V. Babizhetskyy, J. Bauer, S. Cordier, R. Guérin, K. Hiebl, X. Rocquefelte, J.-Y. Saillard, J.-F. Halet, Mn5Si3-type host-interstitial boron rareearth metal silicide compounds RE5Si3: Crystal structures, physical properties and theoretical considerations, Journal of Solid State Chemistry 179 (2006) 2310–2328.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-77ICV5C5WV.85dd82","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0185,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0185},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.41,"value_stored":8.41},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x60002144","first_author":"Parthe","kind":"unknown","label":"31","paper":"doi:10.1107/s0365110x60002144","reference":"E. Parthe, The crystal structure of Y5Si3 and Y5Ge3, Acta Crystallographica 13 (1960) 868–871.","status":"resolved","year":"1960"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-P2KD7KIUBR.7f3917","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01849,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01849},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.403,"value_stored":8.403},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x60002144","first_author":"Parthe","kind":"unknown","label":"31","paper":"doi:10.1107/s0365110x60002144","reference":"E. Parthe, The crystal structure of Y5Si3 and Y5Ge3, Acta Crystallographica 13 (1960) 868–871.","status":"resolved","year":"1960"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-P2KD7KIUBR.b45a46","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01849,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01849},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.403,"value_stored":8.403},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x60002144","first_author":"Parthe","kind":"unknown","label":"31","paper":"doi:10.1107/s0365110x60002144","reference":"E. Parthe, The crystal structure of Y5Si3 and Y5Ge3, Acta Crystallographica 13 (1960) 868–871.","status":"resolved","year":"1960"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-P2KD7KIUBR.cd614a","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01387,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01387},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.303,"value_stored":6.303},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0925-8388(92)90051-a","first_author":"Kotroczo","kind":"unknown","label":"32","paper":"doi:10.1016/0925-8388(92)90051-a","reference":"V. Kotroczo, I.J. McColm, M. Rebbeck, J.M. Ward, Stable and metastable phases in the metal-rich Y-Zr-Si system and their hydrogen reactivity, Journal of Alloys and Compounds 189 (1992) 87–96.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AVFQSQITLV.979e7b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0925-8388(92)90051-a","first_author":"Kotroczo","kind":"unknown","label":"32","paper":"doi:10.1016/0925-8388(92)90051-a","reference":"V. Kotroczo, I.J. McColm, M. Rebbeck, J.M. Ward, Stable and metastable phases in the metal-rich Y-Zr-Si system and their hydrogen reactivity, Journal of Alloys and Compounds 189 (1992) 87–96.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AVFQSQITLV.d2adc0","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0925-8388(92)90051-a","first_author":"Kotroczo","kind":"unknown","label":"32","paper":"doi:10.1016/0925-8388(92)90051-a","reference":"V. Kotroczo, I.J. McColm, M. Rebbeck, J.M. Ward, Stable and metastable phases in the metal-rich Y-Zr-Si system and their hydrogen reactivity, Journal of Alloys and Compounds 189 (1992) 87–96.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AVFQSQITLV.e5c074","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01393,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01393},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.333,"value_stored":6.333},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0304-8853(93)90175-2","first_author":"Canepa","kind":"unknown","label":"33","paper":"doi:10.1016/0304-8853(93)90175-2","reference":"F. Canepa, S. Cirafici, F. Merlo, A. Palenzona, Electrical resistivity measurements on some R5Si3 phases: R = Gd, Tb, Yb, Lu and Y, Journal of Magnetism and Magnetic Materials 118 (1993) 182–186.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UR3MS2HW6R.3ac0c4","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01853,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01853},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.423,"value_stored":8.423},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0304-8853(93)90175-2","first_author":"Canepa","kind":"unknown","label":"33","paper":"doi:10.1016/0304-8853(93)90175-2","reference":"F. Canepa, S. Cirafici, F. Merlo, A. Palenzona, Electrical resistivity measurements on some R5Si3 phases: R = Gd, Tb, Yb, Lu and Y, Journal of Magnetism and Magnetic Materials 118 (1993) 182–186.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UR3MS2HW6R.73ed0d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01398,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01398},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.354,"value_stored":6.354},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0304-8853(93)90175-2","first_author":"Canepa","kind":"unknown","label":"33","paper":"doi:10.1016/0304-8853(93)90175-2","reference":"F. Canepa, S. Cirafici, F. Merlo, A. Palenzona, Electrical resistivity measurements on some R5Si3 phases: R = Gd, Tb, Yb, Lu and Y, Journal of Magnetism and Magnetic Materials 118 (1993) 182–186.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UR3MS2HW6R.db51e0","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":6},"observation_type":"structural_property","origin":{"basis":"cited_reference_title_experiment","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01853,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01853},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.423,"value_stored":8.423},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(74)90021-6","first_author":"Mayer","kind":"unknown","label":"34","paper":"doi:10.1016/0022-5088(74)90021-6","reference":"I. Mayer, I. Felner, Nowotny phases of M5X3-type rare-earth silicides and germanides with boron, Journal of the Less Common Metals 37 (1974) 171–173.","status":"resolved","year":"1974"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BDJX5W4Y63.75f779","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01852,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01852},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.42,"value_stored":8.42},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(74)90021-6","first_author":"Mayer","kind":"unknown","label":"34","paper":"doi:10.1016/0022-5088(74)90021-6","reference":"I. Mayer, I. Felner, Nowotny phases of M5X3-type rare-earth silicides and germanides with boron, Journal of the Less Common Metals 37 (1974) 171–173.","status":"resolved","year":"1974"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BDJX5W4Y63.98011f","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0139,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0139},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.32,"value_stored":6.32},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(74)90021-6","first_author":"Mayer","kind":"unknown","label":"34","paper":"doi:10.1016/0022-5088(74)90021-6","reference":"I. Mayer, I. Felner, Nowotny phases of M5X3-type rare-earth silicides and germanides with boron, Journal of the Less Common Metals 37 (1974) 171–173.","status":"resolved","year":"1974"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BDJX5W4Y63.ff2b17","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01852,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01852},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.42,"value_stored":8.42},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2003.09.023","first_author":"Kozlov","kind":"unknown","label":"35","paper":"doi:10.1016/j.jallcom.2003.09.023","reference":"A.Y. Kozlov, V.V. Pavlyuk, Investigation of the interaction of the components in the Y–Si–Sb system at 670 K, Journal of Alloys and Compounds 370 (2004) 192–197.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UWRKCSV7AU.2af394","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0185,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0185},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.41,"value_stored":8.41},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2003.09.023","first_author":"Kozlov","kind":"unknown","label":"35","paper":"doi:10.1016/j.jallcom.2003.09.023","reference":"A.Y. Kozlov, V.V. Pavlyuk, Investigation of the interaction of the components in the Y–Si–Sb system at 670 K, Journal of Alloys and Compounds 370 (2004) 192–197.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UWRKCSV7AU.79a6f3","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01395,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.34,"value_stored":6.34},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2003.09.023","first_author":"Kozlov","kind":"unknown","label":"35","paper":"doi:10.1016/j.jallcom.2003.09.023","reference":"A.Y. Kozlov, V.V. Pavlyuk, Investigation of the interaction of the components in the Y–Si–Sb system at 670 K, Journal of Alloys and Compounds 370 (2004) 192–197.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-UWRKCSV7AU.b5c9ae","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0185,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0185},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.41,"value_stored":8.41},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0925-8388(92)90250-d","first_author":"McColm","kind":"unknown","label":"36","paper":"doi:10.1016/0925-8388(92)90250-d","reference":"I.J. McColm, J.M. Ward, Hydrogen sorption properties of D88-type systems: IV. Y5Ge3 and Y5Si3-Y5Ge3 solid solutions, Journal of Alloys and Compounds 178 (1992) 91–100.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-QPW7DGQ57V.1c8f93","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0925-8388(92)90250-d","first_author":"McColm","kind":"unknown","label":"36","paper":"doi:10.1016/0925-8388(92)90250-d","reference":"I.J. McColm, J.M. Ward, Hydrogen sorption properties of D88-type systems: IV. Y5Ge3 and Y5Si3-Y5Ge3 solid solutions, Journal of Alloys and Compounds 178 (1992) 91–100.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-QPW7DGQ57V.4c391d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01398,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01398},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.353,"value_stored":6.353},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0925-8388(92)90250-d","first_author":"McColm","kind":"unknown","label":"36","paper":"doi:10.1016/0925-8388(92)90250-d","reference":"I.J. McColm, J.M. Ward, Hydrogen sorption properties of D88-type systems: IV. Y5Ge3 and Y5Si3-Y5Ge3 solid solutions, Journal of Alloys and Compounds 178 (1992) 91–100.","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-QPW7DGQ57V.e9cac1","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JSB3FL2333.156f6d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01397,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01397},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.352,"value_stored":6.352},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JSB3FL2333.4bfe04","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01854,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01854},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.429,"value_stored":8.429},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JSB3FL2333.fa44a6","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01854,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01854},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.429,"value_stored":8.429},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(87)90517-0","first_author":"McColm","kind":"unknown","label":"38","paper":"doi:10.1016/0022-5088(87)90517-0","reference":"I.J. McColm, V. Kotroczo, Hydrogen sorption properties of D88-type systems III. The effect of germanium substitution in Ys−aScaSi3 phases, Journal of the Less Common Metals 131 (1987) 191–199.","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OVSKWFGZGE.8f67ba","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(87)90517-0","first_author":"McColm","kind":"unknown","label":"38","paper":"doi:10.1016/0022-5088(87)90517-0","reference":"I.J. McColm, V. Kotroczo, Hydrogen sorption properties of D88-type systems III. The effect of germanium substitution in Ys−aScaSi3 phases, Journal of the Less Common Metals 131 (1987) 191–199.","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OVSKWFGZGE.9c2aad","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01398,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01398},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.353,"value_stored":6.353},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(87)90517-0","first_author":"McColm","kind":"unknown","label":"38","paper":"doi:10.1016/0022-5088(87)90517-0","reference":"I.J. McColm, V. Kotroczo, Hydrogen sorption properties of D88-type systems III. The effect of germanium substitution in Ys−aScaSi3 phases, Journal of the Less Common Metals 131 (1987) 191–199.","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OVSKWFGZGE.c2e1e3","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(86)90377-2","first_author":"McColm","kind":"unknown","label":"39","paper":"doi:10.1016/0022-5088(86)90377-2","reference":"I.J. McColm, V. Kotrocvo, T.W. Button, N.J. Clark, B. Bruer, Hydrogen sorption properties of D88-type systems: I. Hydrides of Y5Si3, Journal of the Less Common Metals 115 (1986) 113–125.","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZDPRSUHH4U.0087b6","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01398,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01398},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.353,"value_stored":6.353},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(86)90377-2","first_author":"McColm","kind":"unknown","label":"39","paper":"doi:10.1016/0022-5088(86)90377-2","reference":"I.J. McColm, V. Kotrocvo, T.W. Button, N.J. Clark, B. Bruer, Hydrogen sorption properties of D88-type systems: I. Hydrides of Y5Si3, Journal of the Less Common Metals 115 (1986) 113–125.","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZDPRSUHH4U.30b50f","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(86)90377-2","first_author":"McColm","kind":"unknown","label":"39","paper":"doi:10.1016/0022-5088(86)90377-2","reference":"I.J. McColm, V. Kotrocvo, T.W. Button, N.J. Clark, B. Bruer, Hydrogen sorption properties of D88-type systems: I. Hydrides of Y5Si3, Journal of the Less Common Metals 115 (1986) 113–125.","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZDPRSUHH4U.a3b8d6","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(84)90028-6","first_author":"Button","kind":"unknown","label":"40","paper":"doi:10.1016/0022-5088(84)90028-6","reference":"T.W. Button, I.J. McColm, Reaction of carbon with lanthanide silicides IV: The Y5Si3-C system, J. Less-Common Met. 97 (1984) 237–244.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CVEGDNVPOO.8d7867","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(84)90028-6","first_author":"Button","kind":"unknown","label":"40","paper":"doi:10.1016/0022-5088(84)90028-6","reference":"T.W. Button, I.J. McColm, Reaction of carbon with lanthanide silicides IV: The Y5Si3-C system, J. Less-Common Met. 97 (1984) 237–244.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CVEGDNVPOO.930421","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01857,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01857},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.442,"value_stored":8.442},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(84)90028-6","first_author":"Button","kind":"unknown","label":"40","paper":"doi:10.1016/0022-5088(84)90028-6","reference":"T.W. Button, I.J. McColm, Reaction of carbon with lanthanide silicides IV: The Y5Si3-C system, J. Less-Common Met. 97 (1984) 237–244.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-CVEGDNVPOO.b17386","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":13},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01398,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01398},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.353,"value_stored":6.353},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5YXLVA7F3T.51be17","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01859,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01859},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.448,"value_stored":8.448},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5YXLVA7F3T.9fe459","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01859,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01859},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.448,"value_stored":8.448},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5YXLVA7F3T.c4245d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Mn5Si3","space_group_number":193},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01404,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01404},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.384,"value_stored":6.384},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x67001902","first_author":"Smith","kind":"unknown","label":"41","paper":"doi:10.1107/s0365110x67001902","reference":"G.S. Smith, A.G. Tharp, W. Johnson, Rare earth–germanium and –silicon compounds at 5:4 and 5:3 compositions, Acta Crystallographica 22 (1967) 940–943.","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5WFFHOQ5KM.3a0c1b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01626,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01626},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.39,"value_stored":7.39},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x67001902","first_author":"Smith","kind":"unknown","label":"41","paper":"doi:10.1107/s0365110x67001902","reference":"G.S. Smith, A.G. Tharp, W. Johnson, Rare earth–germanium and –silicon compounds at 5:4 and 5:3 compositions, Acta Crystallographica 22 (1967) 940–943.","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5WFFHOQ5KM.455abc","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01681,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01681},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.64,"value_stored":7.64},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x67001902","first_author":"Smith","kind":"unknown","label":"41","paper":"doi:10.1107/s0365110x67001902","reference":"G.S. Smith, A.G. Tharp, W. Johnson, Rare earth–germanium and –silicon compounds at 5:4 and 5:3 compositions, Acta Crystallographica 22 (1967) 940–943.","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5WFFHOQ5KM.94f77a","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03194,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03194},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":14.52,"value_stored":14.52},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"42","reference":"G.S. Smith, A.G. Tharp, Q. Johnson, Crystallographic Data on New Rare EarthGermanium and Silicon Compounds, Nature 210 (1966) 1148–1149.","status":"resolved","year":"1966"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-M4VBZO36CA.04c90e","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01681,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01681},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.64,"value_stored":7.64},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"42","reference":"G.S. Smith, A.G. Tharp, Q. Johnson, Crystallographic Data on New Rare EarthGermanium and Silicon Compounds, Nature 210 (1966) 1148–1149.","status":"resolved","year":"1966"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-M4VBZO36CA.802f72","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03194,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03194},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":14.52,"value_stored":14.52},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Smith","kind":"unknown","label":"42","reference":"G.S. Smith, A.G. Tharp, Q. Johnson, Crystallographic Data on New Rare EarthGermanium and Silicon Compounds, Nature 210 (1966) 1148–1149.","status":"resolved","year":"1966"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-M4VBZO36CA.c312e1","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01626,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01626},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.39,"value_stored":7.39},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PDED6OAZAY.94351b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0165,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0165},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.499,"value_stored":7.499},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PDED6OAZAY.cc9a27","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03248,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03248},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":14.763,"value_stored":14.763},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PDED6OAZAY.ea46df","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01705,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01705},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.751,"value_stored":7.751},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2004.03.069","first_author":"Pecharsky","kind":"unknown","label":"43","paper":"doi:10.1016/j.jallcom.2004.03.069","reference":"A.O. Pecharsky, V.K. Pecharsky, K.A. Gschneidner, Phase relationships and low temperature heat capacities of alloys in the Y5Si4–Y5Ge4 pseudo binary system, Journal of Alloys and Compounds 379 (2004) 127–134.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-VERJYQJ7JB.495fff","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":18},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01685,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01685},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.659,"value_stored":7.659},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2004.03.069","first_author":"Pecharsky","kind":"unknown","label":"43","paper":"doi:10.1016/j.jallcom.2004.03.069","reference":"A.O. Pecharsky, V.K. Pecharsky, K.A. Gschneidner, Phase relationships and low temperature heat capacities of alloys in the Y5Si4–Y5Ge4 pseudo binary system, Journal of Alloys and Compounds 379 (2004) 127–134.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-VERJYQJ7JB.86cd55","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":18},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01644,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01644},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.472,"value_stored":7.472},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2004.03.069","first_author":"Pecharsky","kind":"unknown","label":"43","paper":"doi:10.1016/j.jallcom.2004.03.069","reference":"A.O. Pecharsky, V.K. Pecharsky, K.A. Gschneidner, Phase relationships and low temperature heat capacities of alloys in the Y5Si4–Y5Ge4 pseudo binary system, Journal of Alloys and Compounds 379 (2004) 127–134.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-VERJYQJ7JB.f1a3cc","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":18},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03215,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03215},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":14.613,"value_stored":14.613},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HRCSLF6FIX.0d6d95","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":19},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01637,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01637},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.442,"value_stored":7.442},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HRCSLF6FIX.811532","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":19},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03216,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03216},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":14.62,"value_stored":14.62},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HRCSLF6FIX.bb7eea","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":19},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"Gd5Si4","space_group":"Pnma","space_group_number":62},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01695,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01695},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.704,"value_stored":7.704},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-6TI7HOZXKR.6d6d6e","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":20},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009392,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009392},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.269,"value_stored":4.269},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-6TI7HOZXKR.8d3af0","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":20},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008455,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008455},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.843,"value_stored":3.843},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-6TI7HOZXKR.f1481d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":20},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02324,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02324},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":10.562,"value_stored":10.562},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/ic50063a026","first_author":"Raman","kind":"unknown","label":"44","paper":"doi:10.1021/ic50063a026","reference":"A. Raman, Ternary FeB-and CrB-type phases with yttrium, lanthanum, and some rare earths, Inorganic Chemistry 7 (1968) 973–976.","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZPFAZ3H47I.1a1707","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":21},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02317,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02317},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":10.53,"value_stored":10.53},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/ic50063a026","first_author":"Raman","kind":"unknown","label":"44","paper":"doi:10.1021/ic50063a026","reference":"A. Raman, Ternary FeB-and CrB-type phases with yttrium, lanthanum, and some rare earths, Inorganic Chemistry 7 (1968) 973–976.","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZPFAZ3H47I.cf8c97","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":21},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008417,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008417},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.826,"value_stored":3.826},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/ic50063a026","first_author":"Raman","kind":"unknown","label":"44","paper":"doi:10.1021/ic50063a026","reference":"A. Raman, Ternary FeB-and CrB-type phases with yttrium, lanthanum, and some rare earths, Inorganic Chemistry 7 (1968) 973–976.","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZPFAZ3H47I.e14b85","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":21},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009352,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009352},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.251,"value_stored":4.251},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2003.09.023","first_author":"Kozlov","kind":"unknown","label":"35","paper":"doi:10.1016/j.jallcom.2003.09.023","reference":"A.Y. Kozlov, V.V. Pavlyuk, Investigation of the interaction of the components in the Y–Si–Sb system at 670 K, Journal of Alloys and Compounds 370 (2004) 192–197.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-GR3TM65WBX.90c52d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":22},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009354,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009354},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.252,"value_stored":4.252},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2003.09.023","first_author":"Kozlov","kind":"unknown","label":"35","paper":"doi:10.1016/j.jallcom.2003.09.023","reference":"A.Y. Kozlov, V.V. Pavlyuk, Investigation of the interaction of the components in the Y–Si–Sb system at 670 K, Journal of Alloys and Compounds 370 (2004) 192–197.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-GR3TM65WBX.e113f9","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":22},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02317,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02317},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":10.534,"value_stored":10.534},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2003.09.023","first_author":"Kozlov","kind":"unknown","label":"35","paper":"doi:10.1016/j.jallcom.2003.09.023","reference":"A.Y. Kozlov, V.V. Pavlyuk, Investigation of the interaction of the components in the Y–Si–Sb system at 670 K, Journal of Alloys and Compounds 370 (2004) 192–197.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-GR3TM65WBX.f57c83","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":22},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008435,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008435},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.834,"value_stored":3.834},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x59001657","first_author":"Parthe","kind":"unknown","label":"45","paper":"doi:10.1107/s0365110x59001657","reference":"E. Parthe, The crystal structure of YSi and Hf5Ge3(C), Acta Crystallographica 12 (1959) 559–560.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-MHURTPYA72.bca0e8","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02316,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02316},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":10.526,"value_stored":10.526},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x59001657","first_author":"Parthe","kind":"unknown","label":"45","paper":"doi:10.1107/s0365110x59001657","reference":"E. Parthe, The crystal structure of YSi and Hf5Ge3(C), Acta Crystallographica 12 (1959) 559–560.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-MHURTPYA72.d7f733","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008496,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008496},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.862,"value_stored":3.862},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1107/s0365110x59001657","first_author":"Parthe","kind":"unknown","label":"45","paper":"doi:10.1107/s0365110x59001657","reference":"E. Parthe, The crystal structure of YSi and Hf5Ge3(C), Acta Crystallographica 12 (1959) 559–560.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-MHURTPYA72.dbc3a6","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009352,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009352},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.251,"value_stored":4.251},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OC3HAPJOHN.188c04","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":24},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00843,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00843},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.832,"value_stored":3.832},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OC3HAPJOHN.35188b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":24},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02316,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02316},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":10.528,"value_stored":10.528},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OC3HAPJOHN.6c41e1","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":24},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009376,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009376},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.262,"value_stored":4.262},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-XPLWEBGPXM.1a01d3","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009427,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009427},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.285,"value_stored":4.285},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-XPLWEBGPXM.b62ec8","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02322,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02322},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":10.554,"value_stored":10.554},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-XPLWEBGPXM.d36690","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"space_group":"Cmcm","space_group_number":63},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008448,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008448},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.84,"value_stored":3.84},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JRIEXYZJ4Z.88397c","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":26},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008468,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008468},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.849,"value_stored":3.849},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JRIEXYZJ4Z.aa9493","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":26},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008468,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008468},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.849,"value_stored":3.849},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-JRIEXYZJ4Z.ae6ee7","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":26},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02737,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02737},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":12.441,"value_stored":12.441},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OPVKOX2Q6O.5255f9","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":27},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008866,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008866},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.03,"value_stored":4.03},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OPVKOX2Q6O.98bcdb","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":27},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008866,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008866},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.03,"value_stored":4.03},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OPVKOX2Q6O.f130b7","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":27},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02599,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02599},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":11.813,"value_stored":11.813},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PBLPNM2376.50830b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":28},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r28#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02946,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02946},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":13.39,"value_stored":13.39},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PBLPNM2376.74a893","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":28},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r28#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008932,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008932},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.06,"value_stored":4.06},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90149-e","first_author":"Button","kind":"unknown","label":"37","paper":"doi:10.1016/0022-5088(90)90149-e","reference":"T.W. Button, I.J. McColm, J.M. Ward, Preparation of yttrium silicides and oxidesilicides, Journal of the Less Common Metals 159 (1990) 205–222.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PBLPNM2376.90ee09","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":28},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r28#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02618,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02618},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":11.901,"value_stored":11.901},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AE2RZPTAU6.800b03","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":29},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r29#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008901,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008901},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.046,"value_stored":4.046},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AE2RZPTAU6.cff68c","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":29},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r29#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0261,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0261},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":11.862,"value_stored":11.862},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AE2RZPTAU6.f80e56","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":29},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r29#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0297},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":13.5,"value_stored":13.5},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j100810a028","first_author":"Mayer","kind":"unknown","label":"46","paper":"doi:10.1021/j100810a028","reference":"I. Mayer, E. Banks, B. Post, Rare earth disilicides 1, The Journal of Physical Chemistry 66 (1962) 693–696.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5AIJEYXTHR.4d6086","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":30},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00847,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00847},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.85,"value_stored":3.85},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j100810a028","first_author":"Mayer","kind":"unknown","label":"46","paper":"doi:10.1021/j100810a028","reference":"I. Mayer, E. Banks, B. Post, Rare earth disilicides 1, The Journal of Physical Chemistry 66 (1962) 693–696.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5AIJEYXTHR.bc8aae","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":30},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00847,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00847},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.85,"value_stored":3.85},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j100810a028","first_author":"Mayer","kind":"unknown","label":"46","paper":"doi:10.1021/j100810a028","reference":"I. Mayer, E. Banks, B. Post, Rare earth disilicides 1, The Journal of Physical Chemistry 66 (1962) 693–696.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5AIJEYXTHR.f9154b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":30},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009108,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009108},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.14,"value_stored":4.14},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-RSYVCA52B6.738ac0","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":31},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009112,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009112},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.142,"value_stored":4.142},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-RSYVCA52B6.dab134","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":31},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008448,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008448},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.84,"value_stored":3.84},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/j.jallcom.2005.09.012","first_author":"Roger","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2005.09.012","reference":"J. Roger, V. Babizhetskyy, T. Guizouarn, K. Hiebl, R. Guérin, J.-F. Halet, The ternary RE–Si–B systems (RE=Dy, Ho, Er and Y) at 1270K: Solid state phase equilibria and magnetic properties of the solid solution REB2−xSix (RE=Dy and Ho), Journal of Alloys and Compounds 417 (2006) 72–84.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-RSYVCA52B6.dcb97a","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":31},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008448,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008448},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.84,"value_stored":3.84},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(72)90144-0","first_author":"Mayer","kind":"unknown","label":"47","paper":"doi:10.1016/0022-5088(72)90144-0","reference":"I. Mayer, I. Felner, High-temperature X-ray study of rare-earth silicides, Journal of the Less Common Metals 29 (1972) 25–31.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HPY3ITEXPA.470f73","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":32},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r32#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008455,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008455},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.843,"value_stored":3.843},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(72)90144-0","first_author":"Mayer","kind":"unknown","label":"47","paper":"doi:10.1016/0022-5088(72)90144-0","reference":"I. Mayer, I. Felner, High-temperature X-ray study of rare-earth silicides, Journal of the Less Common Metals 29 (1972) 25–31.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HPY3ITEXPA.5f8ad9","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":32},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r32#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008455,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008455},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.843,"value_stored":3.843},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(72)90144-0","first_author":"Mayer","kind":"unknown","label":"47","paper":"doi:10.1016/0022-5088(72)90144-0","reference":"I. Mayer, I. Felner, High-temperature X-ray study of rare-earth silicides, Journal of the Less Common Metals 29 (1972) 25–31.","status":"resolved","year":"1972"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HPY3ITEXPA.62f668","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":32},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r32#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009115,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009115},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.143,"value_stored":4.143},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Kotur","kind":"unknown","label":"48","reference":"B.Y. Kotur, I.R. Mokra, Ternary systems Sc-Y-Si and Sc-Lu-Si, Inorganic Materials 30 (1994) 729–732.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-3ICMKKFC3U.24c9cd","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":33},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008444,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008444},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.838,"value_stored":3.838},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Kotur","kind":"unknown","label":"48","reference":"B.Y. Kotur, I.R. Mokra, Ternary systems Sc-Y-Si and Sc-Lu-Si, Inorganic Materials 30 (1994) 729–732.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-3ICMKKFC3U.4fbb44","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":33},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009088,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009088},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.131,"value_stored":4.131},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Kotur","kind":"unknown","label":"48","reference":"B.Y. Kotur, I.R. Mokra, Ternary systems Sc-Y-Si and Sc-Lu-Si, Inorganic Materials 30 (1994) 729–732.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-3ICMKKFC3U.9e849b","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":33},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008444,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008444},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.838,"value_stored":3.838},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-C4NGVZDZ2C.0ef66d","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":34},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r34#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02616,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02616},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":11.891,"value_stored":11.891},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-C4NGVZDZ2C.8e6196","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":34},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r34#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009029,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009029},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.104,"value_stored":4.104},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-C4NGVZDZ2C.a45a09","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":34},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r34#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"AlB2","space_group":"P6/mmm","space_group_number":191},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009029,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009029},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.104,"value_stored":4.104},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j100810a028","first_author":"Mayer","kind":"unknown","label":"46","paper":"doi:10.1021/j100810a028","reference":"I. Mayer, E. Banks, B. Post, Rare earth disilicides 1, The Journal of Physical Chemistry 66 (1962) 693–696.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-FJJUHA5NYB.98e9d8","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":35},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r35#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008646,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008646},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.93,"value_stored":3.93},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j100810a028","first_author":"Mayer","kind":"unknown","label":"46","paper":"doi:10.1021/j100810a028","reference":"I. Mayer, E. Banks, B. Post, Rare earth disilicides 1, The Journal of Physical Chemistry 66 (1962) 693–696.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-FJJUHA5NYB.d33de0","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":35},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r35#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00891,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00891},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.05,"value_stored":4.05},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j100810a028","first_author":"Mayer","kind":"unknown","label":"46","paper":"doi:10.1021/j100810a028","reference":"I. Mayer, E. Banks, B. Post, Rare earth disilicides 1, The Journal of Physical Chemistry 66 (1962) 693–696.","status":"resolved","year":"1962"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-FJJUHA5NYB.f56eef","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":35},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r35#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02948},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":13.4,"value_stored":13.4},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j150582a030","first_author":"Perri","kind":"unknown","label":"49","paper":"doi:10.1021/j150582a030","reference":"J.A. Perri, E. Banks, B. Post, Polymorphism of rare earth disilicides, The Journal of Physical Chemistry 63 (1959) 2073–2074.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-F2VK3I3UH2.0deaa8","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":36},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r36#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00869,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00869},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.95,"value_stored":3.95},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j150582a030","first_author":"Perri","kind":"unknown","label":"49","paper":"doi:10.1021/j150582a030","reference":"J.A. Perri, E. Banks, B. Post, Polymorphism of rare earth disilicides, The Journal of Physical Chemistry 63 (1959) 2073–2074.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-F2VK3I3UH2.cfae7c","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":36},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r36#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008888,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008888},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.04,"value_stored":4.04},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1021/j150582a030","first_author":"Perri","kind":"unknown","label":"49","paper":"doi:10.1021/j150582a030","reference":"J.A. Perri, E. Banks, B. Post, Polymorphism of rare earth disilicides, The Journal of Physical Chemistry 63 (1959) 2073–2074.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-F2VK3I3UH2.d55f43","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":36},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r36#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02911,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02911},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":13.23,"value_stored":13.23},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-7WV6NA773Y.105c48","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":37},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r37#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008699,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008699},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.954,"value_stored":3.954},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-7WV6NA773Y.3b4a89","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":37},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r37#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008738,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008738},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":3.972,"value_stored":3.972},{"chemical_system":"SI-Y","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-7WV6NA773Y.51accf","locator":{"ref":"sha256:8df6e975c3b6dbea/p2/tab-1","row":37},"observation_type":"structural_property","origin":{"basis":"this_work_kind_unstated","class":"unspecified","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p2/tab-1/r37#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","claude-opus-5.5#2","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"C-SI-Y","structure":{"prototype":"GdSi1.4","space_group":"Imma","space_group_number":74},"system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03251,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03251},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":14.775,"value_stored":14.775},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'YSi2'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-URIPMRCZ3I.8cc05d","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":1},"merged_ids":["ORC-URIPMRCZ3I.c86db4"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.4},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.4},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-66.0,"value_printed":-66.0,"value_stored":-66000.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-2.8,"before":-2800.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'YSi2'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-URIPMRCZ3I.d59230","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":1},"merged_ids":["ORC-URIPMRCZ3I.873a14"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4000.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4000.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/SM_FORM/classes/unknown","floor":1.0,"floor_unit":"J/K/mol-atom","n_pairs":4,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4000.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-2.8,"value_printed":-2.8,"value_stored":-2800.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/s0925-8388(98)00504-0","first_author":"Meschel","kind":"unknown","label":"65","paper":"doi:10.1016/s0925-8388(98)00504-0","reference":"S.V. Meschel, O.J. Kleppa, Standard enthalpies of formation of some 4d transition metal silicides by high temperature direct synthesis calorimetry, Journal of Alloys and Compounds 274 (1998) 193–200.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'YSi2'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-4GRDKBOGIM.4fa341","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":2},"merged_ids":["ORC-4GRDKBOGIM.e82b52"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.4},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.4},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-61.8,"value_printed":-61.8,"value_stored":-61800.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-1.969,"before":-1969.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5TNMRC7JAK.d38d71","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":3},"merged_ids":["ORC-5TNMRC7JAK.154eb1"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":98.45},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-1.969,"value_printed":-1.969,"value_stored":-1969.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-5TNMRC7JAK.eb508b","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":3},"merged_ids":["ORC-5TNMRC7JAK.8f20ab"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.0133},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-60.266,"value_printed":-60.266,"value_stored":-60266.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZFKVRMRWWG.78afef","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":4},"merged_ids":["ORC-ZFKVRMRWWG.337931"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.94607},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-38.9214,"value_printed":-38.9214,"value_stored":-38921.4},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-2.5,"before":-2500.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZFKVRMRWWG.e31d01","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":4},"merged_ids":["ORC-ZFKVRMRWWG.660c5c"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":125.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-2.5,"value_printed":-2.5,"value_stored":-2500.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(81)90200-9","first_author":"Niessen","kind":"unknown","label":"68","paper":"doi:10.1016/0022-5088(81)90200-9","reference":"A.K. Niessen, F.R. De Boer, The enthalpy of formation of solid borides, carbides, nitrides, silicides and phosphides of transition and noble metals, Journal of the Less Common Metals 82 (1981) 75–80.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HEAPMVD35C.a085fe","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":5},"merged_ids":["ORC-HEAPMVD35C.9a8ee7"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.4},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-68.0,"value_printed":-68,"value_stored":-68000.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y3Si5'","reason":"phase_label_ambiguous","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BFAMJ2DIA5.917539","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":6},"merged_ids":["ORC-BFAMJ2DIA5.dd461e"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.8,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.8},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-74.2,"value_printed":-74.2,"value_stored":-74200.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-3.1,"before":-3100.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y3Si5'","reason":"phase_label_ambiguous","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BFAMJ2DIA5.f3bc8b","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":6},"merged_ids":["ORC-BFAMJ2DIA5.63b8f1"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4500.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4500.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/SM_FORM/classes/unknown","floor":1.0,"floor_unit":"J/K/mol-atom","n_pairs":4,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4500.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-3.1,"value_printed":-3.1,"value_stored":-3100.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-1.727,"before":-1727.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-GMCXKOYY5C.8c5791","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":7},"merged_ids":["ORC-GMCXKOYY5C.c90ff9"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":86.35},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-1.727,"value_printed":-1.727,"value_stored":-1727.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-GMCXKOYY5C.ba6711","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":7},"merged_ids":["ORC-GMCXKOYY5C.867f70"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.33125},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-66.625,"value_printed":-66.625,"value_stored":-66625.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-5.0,"before":-5000.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5(R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BNY46GIZ3M.52c020","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":8},"merged_ids":["ORC-BNY46GIZ3M.a9b4b2"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5(R)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":250.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-5.0,"value_printed":-5,"value_stored":-5000.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5(R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BNY46GIZ3M.bcb664","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":8},"merged_ids":["ORC-BNY46GIZ3M.3d9499"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5(R)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.25765},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-45.153,"value_printed":-45.153,"value_stored":-45153.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-4.0,"before":-4000.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5(H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-XODFJ2OJEI.0286f6","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":9},"merged_ids":["ORC-XODFJ2OJEI.5f811d"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5(H)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":200.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-4.0,"value_printed":-4,"value_stored":-4000.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5(H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-XODFJ2OJEI.b549ee","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":9},"merged_ids":["ORC-XODFJ2OJEI.46ba62"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5(H)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.2215},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-44.43,"value_printed":-44.43,"value_stored":-44430.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AYWJZHYTRS.aeb0ce","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":10},"merged_ids":["ORC-AYWJZHYTRS.5bb1a2"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-89.1,"value_printed":-89.1,"value_stored":-89100.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":0.4,"before":400.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":false,"gate_failures":["formation_entropy_out_of_range"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"formation_entropy_out_of_range","detail":"SM_FORM 400 J/mol-atom/K: above 150 J/K per mole of atoms","effect":"not_accepted","gate":"R2","visual_check":{"checked":"2026-10-24","image_sha256":"60f1711bdeaa76f08d91b3cfee8e1b5b7c833b36e04758d53af0912747b45c1d","page":3,"pdf_sha256_prefix":"07674a521dd9c77a","seen":"Columns headed 'entropy of formation' that print absolute (third-law) entropies: positive values above 15 J/K per mole of atoms, impossible for the formation of a condensed compound from condensed elements.","verdict":"rule_confirmed"}}],"id":"ORC-AYWJZHYTRS.b60942","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":10},"merged_ids":["ORC-AYWJZHYTRS.c62495"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":4700.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4700.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/SM_FORM/classes/unknown","floor":1.0,"floor_unit":"J/K/mol-atom","n_pairs":4,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":4700.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":0.4,"value_printed":0.4,"value_stored":400.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/s0925-8388(98)00504-0","first_author":"Meschel","kind":"unknown","label":"65","paper":"doi:10.1016/s0925-8388(98)00504-0","reference":"S.V. Meschel, O.J. Kleppa, Standard enthalpies of formation of some 4d transition metal silicides by high temperature direct synthesis calorimetry, Journal of Alloys and Compounds 274 (1998) 193–200.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-M5W5YRWCXR.cc9321","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":11},"merged_ids":["ORC-M5W5YRWCXR.430153"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.3},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.3},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-80.7,"value_printed":-80.7,"value_stored":-80700.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-6.049,"before":-6049.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-EREDQQYMFI.3f45a3","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":12},"merged_ids":["ORC-EREDQQYMFI.fc69bb"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":302.45},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-6.049,"value_printed":-6.049,"value_stored":-6049.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-EREDQQYMFI.a71699","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":12},"merged_ids":["ORC-EREDQQYMFI.da9204"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.325},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-86.5,"value_printed":-86.5,"value_stored":-86500.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-10.6649,"before":-10664.9,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-YXP34I2RE5.a8b67b","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":13},"merged_ids":["ORC-YXP34I2RE5.07aeef"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":533.245},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-10.6649,"value_printed":-10.6649,"value_stored":-10664.9},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-YXP34I2RE5.ff2476","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":13},"merged_ids":["ORC-YXP34I2RE5.e16df7"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.096},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-61.92,"value_printed":-61.92,"value_stored":-61920.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(81)90200-9","first_author":"Niessen","kind":"unknown","label":"68","paper":"doi:10.1016/0022-5088(81)90200-9","reference":"A.K. Niessen, F.R. De Boer, The enthalpy of formation of solid borides, carbides, nitrides, silicides and phosphides of transition and noble metals, Journal of the Less Common Metals 82 (1981) 75–80.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ALWZX3LKS2.a33dfa","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":14},"merged_ids":["ORC-ALWZX3LKS2.239596"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-78.0,"value_printed":-78,"value_stored":-78000.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":850.15,"before":298.15,"evidence":{"paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","pdf_page":3,"pdf_sha256":"8df6e975c3b6dbea63b0baeb9d49faf44a4ceaa8f0497a3242ee168cd3a85b51","rationale":"The record assumes 298.15 K, while the page ties the cited experimental value to 577 degrees C (850.15 K).","report_id":"ORCHID-Y11-20261027-v1"},"field":"temperature_K","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page review, AI-assisted, not human re-review; ORCHID-Y11-20261027-v1","image_sha256":"85a3855602df80c06b0e34d4619267e5d0b17270364468b40ec3de7db851bcc1","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Table 2 gives Y5Si4, -93.0 +/- 5.5, reference [66]; the adjoining text identifies the [66] EMF result at 577 degrees C.","verdict":"confirmed"}},{"after":"printed","before":"assumed_standard_298K","evidence":{"paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","pdf_page":3,"pdf_sha256":"8df6e975c3b6dbea63b0baeb9d49faf44a4ceaa8f0497a3242ee168cd3a85b51","rationale":"The record assumes 298.15 K, while the page ties the cited experimental value to 577 degrees C (850.15 K).","report_id":"ORCHID-Y11-20261027-v1"},"field":"temperature_basis","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page review, AI-assisted, not human re-review; ORCHID-Y11-20261027-v1","image_sha256":"85a3855602df80c06b0e34d4619267e5d0b17270364468b40ec3de7db851bcc1","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Table 2 gives Y5Si4, -93.0 +/- 5.5, reference [66]; the adjoining text identifies the [66] EMF result at 577 degrees C.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Proposed for 2026.10.1; not applied to either locked repository.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-3KKWBH2XDZ.b64d86","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":15},"merged_ids":["ORC-3KKWBH2XDZ.a50d24"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":850.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":5.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":5.5},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-93.0,"value_printed":-93.0,"value_stored":-93000.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":2.9,"before":2900.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":false,"gate_failures":["formation_entropy_out_of_range"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"formation_entropy_out_of_range","detail":"SM_FORM 2900 J/mol-atom/K: above 150 J/K per mole of atoms","effect":"not_accepted","gate":"R2","visual_check":{"checked":"2026-10-24","image_sha256":"60f1711bdeaa76f08d91b3cfee8e1b5b7c833b36e04758d53af0912747b45c1d","page":3,"pdf_sha256_prefix":"07674a521dd9c77a","seen":"Columns headed 'entropy of formation' that print absolute (third-law) entropies: positive values above 15 J/K per mole of atoms, impossible for the formation of a condensed compound from condensed elements.","verdict":"rule_confirmed"}}],"id":"ORC-3KKWBH2XDZ.b73182","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":15},"merged_ids":["ORC-3KKWBH2XDZ.da1fa1"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":6400.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":6400.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/SM_FORM/classes/unknown","floor":1.0,"floor_unit":"J/K/mol-atom","n_pairs":4,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":6400.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":2.9,"value_printed":2.9,"value_stored":2900.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-O4VSQBSGLF.2aea17","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":16},"merged_ids":["ORC-O4VSQBSGLF.d4f468"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.0611},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-81.222,"value_printed":-81.222,"value_stored":-81222.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-1.242,"before":-1242.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-O4VSQBSGLF.c1aa71","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":16},"merged_ids":["ORC-O4VSQBSGLF.0db6c1"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":62.1},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-1.242,"value_printed":-1.242,"value_stored":-1242.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OFWJAMR2XL.124240","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":17},"merged_ids":["ORC-OFWJAMR2XL.e96b9b"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.2575},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-65.15,"value_printed":-65.15,"value_stored":-65150.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-12.5997,"before":-12599.7,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-OFWJAMR2XL.5331a9","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":17},"merged_ids":["ORC-OFWJAMR2XL.54c8c5"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":629.985},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-12.5997,"value_printed":-12.5997,"value_stored":-12599.7},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y5Si3'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-6S6FJDBDPS.361c7d","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":18},"merged_ids":["ORC-6S6FJDBDPS.2a7f92"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":6.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":6.7,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":6.7},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-92.1,"value_printed":-92.1,"value_stored":-92100.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1007/bf02676225","first_author":"Polotskaya","kind":"unknown","label":"66","paper":"doi:10.1007/bf02676225","reference":"R.I. Polotskaya, V.R. Sidorko, Thermodynamic properties of yttrium silicides, Powder Metallurgy and Metal Ceramics 36 (1997) 315–319.","status":"resolved","year":"1997"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":5.6,"before":5600.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"espei_ready_before_gates":true,"extraction_accepted":false,"gate_failures":["formation_entropy_out_of_range"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"gate_failures":[{"code":"formation_entropy_out_of_range","detail":"SM_FORM 5600 J/mol-atom/K: above 150 J/K per mole of atoms","effect":"not_accepted","gate":"R2","visual_check":{"checked":"2026-10-24","image_sha256":"60f1711bdeaa76f08d91b3cfee8e1b5b7c833b36e04758d53af0912747b45c1d","page":3,"pdf_sha256_prefix":"07674a521dd9c77a","seen":"Columns headed 'entropy of formation' that print absolute (third-law) entropies: positive values above 15 J/K per mole of atoms, impossible for the formation of a condensed compound from condensed elements.","verdict":"rule_confirmed"}}],"id":"ORC-6S6FJDBDPS.5c9f32","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":18},"merged_ids":["ORC-6S6FJDBDPS.833e67"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":7800.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7800.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/SM_FORM/classes/unknown","floor":1.0,"floor_unit":"J/K/mol-atom","n_pairs":4,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7800.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":5.6,"value_printed":5.6,"value_stored":5600.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/s0925-8388(98)00504-0","first_author":"Meschel","kind":"unknown","label":"65","paper":"doi:10.1016/s0925-8388(98)00504-0","reference":"S.V. Meschel, O.J. Kleppa, Standard enthalpies of formation of some 4d transition metal silicides by high temperature direct synthesis calorimetry, Journal of Alloys and Compounds 274 (1998) 193–200.","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y5Si3'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-DSMEXZLUVF.79fcd5","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":19},"merged_ids":["ORC-DSMEXZLUVF.ff4fc5"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.3},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.3},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-80.4,"value_printed":-80.4,"value_stored":-80400.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.1016/0022-5088(90)90292-r","first_author":"Topor","kind":"unknown","label":"67","paper":"doi:10.1016/0022-5088(90)90292-r","reference":"L. Topor, O.J. Kleppa, Standard enthalpies of formation of Me5Si3 (Me=Y, Lu, Zr) and of Hf3Si2, Journal of the Less Common Metals 167 (1990) 91–99.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y5Si3'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-DI7K5WNBQD.9f1700","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":20},"merged_ids":["ORC-DI7K5WNBQD.81f28b"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.6,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.6},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-71.7,"value_printed":-71.7,"value_stored":-71700.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-QHTM3V44JE.96cc50","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":21},"merged_ids":["ORC-QHTM3V44JE.f1aa78"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.8125},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-76.25,"value_printed":-76.25,"value_stored":-76250.0},{"chemical_system":"SI-Y","cited_sources":[{"doi":"10.3139/146.110003","first_author":"Shukla","kind":"assessment","label":"22","paper":"doi:10.3139/146.110003","reference":"A. Shukla, Y.-B. Kang, A.D. Pelton, Thermodynamic assessment of the Ce–Si, Y–Si, Mg–Ce–Si and Mg–Y–Si systems, International Journal of Materials Research 100 (2009) 208–217.","status":"resolved","year":"2009"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-1.483,"before":-1483.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-QHTM3V44JE.c3219e","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":21},"merged_ids":["ORC-QHTM3V44JE.33e571"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":74.15},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-1.483,"value_printed":-1.483,"value_stored":-1483.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":-11.187,"before":-11187.0,"evidence":{"header_seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","out_of_range_in_table":"32 of 32","property_printed":"Formation entropy","unit_printed":"kJ/K·mole-atom"},"field":"value","gate":"G2","rule":"table_unit_scale_0.001","visual_check":{"checked":"2026-10-23","image_sha256":"3ed862e7bd45608d797e09496f886a674024501f3b5ed1dbdd23a1d5a5cef388","page":3,"pdf_sha256_prefix":"8df6e975c3b6dbea","seen":"Caption: 'Enthalpy (kJ/mole-atom) and entropy (kJ/K.mole-atom) of formation'; 'Formation entropy' column has no own unit. Printed = value_printed: YSi2 -2.8+/-4.0 [66], -1.969, -2.5; Y3Si5 -3.1, -1.727, -5, -4; YSi 0.4. Caption literally kJ; magnitudes only plausible as J (caption typo?).","verdict":"confirmed"}},{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AE33NW5SCU.51e9eb","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":22},"merged_ids":["ORC-AE33NW5SCU.405aff"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"Formation entropy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":559.35},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"caption","unit_printed":"kJ/K·mole-atom","value":-11.187,"value_printed":-11.187,"value_stored":-11187.0},{"chemical_system":"SI-Y","cited_sources":[{"first_author":"Ran","kind":"assessment","label":"21","reference":"Q. Ran, H.L. Lukas, G. Effenberg, G. Petzow, A thermodynamic assessment of the YSi system, Z. Metallkd 80 (1989) 402–405.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-AE33NW5SCU.78b361","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-2","row":22},"merged_ids":["ORC-AE33NW5SCU.934627"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-2/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-60.0,"value_printed":-60,"value_stored":-60000.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y5Si3'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-BXE4DG4MGE","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":1},"method":"First principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (First principles)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.4995},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-69.99,"value_printed":-69.99,"value_stored":-69990.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.375,"Y":0.625},"phases":["Y5Si3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-RFYH5SIN6U","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":2},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.375,"Y":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si3"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (CALPHAD)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.519},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-70.38,"value_printed":-70.38,"value_stored":-70380.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-3F4IKD7X5A","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":3},"method":"First principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (First principles)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.7545},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-75.09,"value_printed":-75.09,"value_stored":-75090.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.444444,"Y":0.555556},"phases":["Y5Si4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-ZR6D4A3ZJQ","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":4},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.444444,"Y":0.555556},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y5Si4"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (CALPHAD)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.8335},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-76.67,"value_printed":-76.67,"value_stored":-76670.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-HXREVNZHBF","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":5},"method":"First principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (First principles)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.0945},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-81.89,"value_printed":-81.89,"value_stored":-81890.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.5,"Y":0.5},"phases":["YSi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-644PZJN6PG","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":6},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.5,"Y":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (CALPHAD)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.0945},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-81.89,"value_printed":-81.89,"value_stored":-81890.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y3Si5 (H)'","reason":"phase_label_ambiguous","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-XAWUXWICRX","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":7},"method":"First principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (First principles)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.353},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-47.06,"value_printed":-47.06,"value_stored":-47060.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-B43BTGH6JQ","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":8},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (CALPHAD)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.0625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-61.25,"value_printed":-61.25,"value_stored":-61250.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'Y3Si5 (R)'","reason":"phase_label_ambiguous","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-3E7T6VEXR2","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":9},"method":"First principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (First principles)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.0655},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-61.31,"value_printed":-61.31,"value_stored":-61310.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.625,"Y":0.375},"phases":["Y3Si5 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-V3OLJUKJ5V","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":10},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.625,"Y":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"Y3Si5 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (CALPHAD)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.094},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-61.88,"value_printed":-61.88,"value_stored":-61880.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'YSi2 (H)'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-K47LECRQ4P","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":11},"method":"First principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (First principles)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-49.25,"value_printed":-49.25,"value_stored":-49250.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (H)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-3NVN2XDUWX","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":12},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (H)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (CALPHAD)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.72},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-54.4,"value_printed":-54.4,"value_stored":-54400.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"label 'YSi2 (R)'","reason":"phase_label_not_mapped","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-PXWJTJAKXJ","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":13},"method":"First principles","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (First principles)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (static calculation)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.5455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.966,"sigma_method":{"basis":"calibrated","ci95":[6.939,13.23],"class":"dft","entry":"dft/literature/strata/pblock_anion","floor":9.966,"floor_unit":"kJ/mol-atom","n_pairs":123,"stratum":"literature/pblock_anion","value":9.966},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-50.91,"value_printed":-50.91,"value_stored":-50910.0},{"chemical_system":"SI-Y","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"SI-Y","before":"C-SI-Y","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"SI":0.666667,"Y":0.333333},"phases":["YSi2 (R)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":2,"id":"ORC-WOUJPUI6TH","locator":{"ref":"sha256:8df6e975c3b6dbea/p3/tab-3","row":14},"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jeurceramsoc.2019.07.012","own_work_of_paper":true},"overall_composition":{"SI":0.666667,"Y":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jeurceramsoc.2019.07.012","paper_id":"doi:10.1016/j.jeurceramsoc.2019.07.012","phases":[{"label":"YSi2 (R)"}],"pid":"sha256:8df6e975c3b6dbea/p3/tab-3/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Formation enthalpy (CALPHAD)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"reference_state_stored":{"C":{"phase":"GRAPHITE"},"SI":{"phase":"DIAMOND_A4"},"Y":{"phase":"HCP_A3"}},"source_system":"C-SI-Y","system":"SI-Y","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.7335},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":-54.67,"value_printed":-54.67,"value_stored":-54670.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"SI-Y"}