{"artifacts":{"doi:10.1361/105497106x92826/p10/tab-6":{"artifact":"table","caption":"Invariant equilibrium reactions related to the Sn-rich liquid phase","label":"6","page":10},"sha256:c44997db7259ff59/p10/tab-7":{"artifact":"table","caption":"Surface tension and molar volume of pure elements","label":"7","page":10},"sha256:c44997db7259ff59/p3/tab-1":{"artifact":"table","caption":"Experimental phase boundaries of the Sn-Ti-Zn system determined by DSC","label":"1","page":3},"sha256:c44997db7259ff59/p3/tab-2":{"artifact":"table","caption":"Experimental solid compositions of samples equilibrated at 600 and 700 °C","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23735569},\n url = {https://doi.org/10.5281/zenodo.23735569},\n note = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID data: umbrella record of the ORCHID datasets}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23736065},\n url = {https://doi.org/10.5281/zenodo.23736065},\n note = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["SN","TI","ZN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/srin.199400921":{"authors":["Toshihiro Tanaka","Takamichi Iida"],"citation":"Toshihiro Tanaka, Takamichi Iida, Application of a thermodynamic database to the calculation of surface tension for iron-base liquid alloys, Steel Research 65, 21-28 (1994).","container":"Steel Research","doi":"10.1002/srin.199400921","doi_url":"https://doi.org/10.1002/srin.199400921","id":"doi:10.1002/srin.199400921","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Application of a thermodynamic database to the calculation of surface tension for iron-base liquid alloys","year":1994},"doi:10.1016/j.jallcom.2003.11.026":{"authors":["G.P Vassilev","X.J Liu","K Ishida"],"citation":"G.P Vassilev, X.J Liu, K Ishida, Reaction kinetics and phase diagram studies in the Ti–Zn system, Journal of Alloys and Compounds 375, 162-170 (2004).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2003.11.026","doi_url":"https://doi.org/10.1016/j.jallcom.2003.11.026","id":"doi:10.1016/j.jallcom.2003.11.026","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Reaction kinetics and phase diagram studies in the Ti–Zn system","year":2004},"doi:10.1103/physrevb.54.16533":{"authors":["John P. Perdew","Kieron Burke","Yue Wang"],"citation":"John P. Perdew, Kieron Burke, Yue Wang, Generalized gradient approximation for the exchange-correlation hole of a many-electron system, Phys. Rev. B 54, 16533-16539 (1996).","container":"Phys. Rev. B","doi":"10.1103/physrevb.54.16533","doi_url":"https://doi.org/10.1103/physrevb.54.16533","id":"doi:10.1103/physrevb.54.16533","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Generalized gradient approximation for the exchange-correlation hole of a many-electron system","year":1996},"doi:10.1361/105497106x92826":{"authors":["K. Doi","S. Ono","H. Ohtani","M. Hasebe"],"citation":"K. Doi, S. Ono, H. Ohtani, M. Hasebe, Thermodynamic study of the phase equilibria in the Sn−Ti−Zn ternary system, JPED 27, 63-74 (2006).","container":"JPED","doi":"10.1361/105497106x92826","doi_url":"https://doi.org/10.1361/105497106x92826","id":"doi:10.1361/105497106x92826","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"c44997db7259ff59","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic study of the phase equilibria in the Sn−Ti−Zn ternary system","year":2006},"doi:10.2320/materia.35.320":{"authors":["Tadashi Takemoto"],"citation":"Tadashi Takemoto, Lead-free Solder and Micro-joining., Materia Japan 35, 320-325 (1996).","container":"Materia Japan","doi":"10.2320/materia.35.320","doi_url":"https://doi.org/10.2320/materia.35.320","id":"doi:10.2320/materia.35.320","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Lead-free Solder and Micro-joining.","year":1996}},"part":1,"parts":1,"records":[{"chemical_system":"SN-TI-ZN","cited_sources":[{"doi":"10.1002/srin.199400921","first_author":"Tanaka","kind":"unknown","label":"14","paper":"doi:10.1002/srin.199400921","reference":"T. Tanaka and T. Iida, Application of a Thermodynamic Database to the Calculation of Surface Tension for Iron-Base Liquid Alloys, Steel Res., 1994, 65, p 21-27","status":"resolved","year":"1994"},{"doi":"10.1002/srin.199400921","first_author":"Tanaka","kind":"unknown","label":"14","paper":"doi:10.1002/srin.199400921","reference":"T. Tanaka and T. Iida, Application of a Thermodynamic Database to the Calculation of Surface Tension for Iron-Base Liquid Alloys, Steel Res., 1994, 65, p 21-27","status":"resolved","year":"1994"},{"doi":"10.2320/materia.35.320","first_author":"Takemoto","kind":"unknown","label":"1","paper":"doi:10.2320/materia.35.320","reference":"T. Takemoto, Lead-free Solder and Micro-joining, Materia Jpn., 1996, 35, p 320-325 (in Japanese)","status":"resolved","year":"1996"},{"kind":"unknown","label":"17","status":"unresolved"},{"kind":"unknown","label":"0","status":"unresolved"},{"doi":"10.1016/j.jallcom.2003.11.026","first_author":"Vassilev","kind":"unknown","label":"10","paper":"doi:10.1016/j.jallcom.2003.11.026","reference":"G.P. Vassilev, Contribution to the Zinc-Rich Side of the Ti-Zn System, Z. Metallkde., 2004, 95(9), p 813-817 74","status":"resolved","year":"2004"},{"doi":"10.1103/physrevb.54.16533","first_author":"Perdew","kind":"unknown","label":"6","paper":"doi:10.1103/physrevb.54.16533","reference":"J.P. Perdew, K. Burke, and Y. Wang, Generalized Gradient Approximation for the Exchange-Correlation Hole of a ManyElectron System, Phys. Rev. B, 1996, 54, p 16533-16539","status":"resolved","year":"1996"},{"first_author":"Redlich","kind":"unknown","label":"3","reference":"O. Redlich and A.T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem., 1948, 40, p 354-384","status":"resolved","year":"1948"},{"kind":"unknown","label":"0","status":"unresolved"},{"kind":"unknown","label":"87","status":"unresolved"},{"doi":"10.1016/j.jallcom.2003.11.026","first_author":"Vassilev","kind":"unknown","label":"10","paper":"doi:10.1016/j.jallcom.2003.11.026","reference":"G.P. Vassilev, Contribution to the Zinc-Rich Side of the Ti-Zn System, Z. Metallkde., 2004, 95(9), p 813-817 74","status":"resolved","year":"2004"},{"first_author":"Hayes","kind":"assessment","label":"4","reference":"F. Hayes, Thermodynamic Database for Light Metal Alloys, COST 507, Volume 2, I. Ansara, A.T. Dinsdale, and M.H. Rand, Ed., Office for Official Publications of the European Communities, Luxembourg, 1998, p 284-287","status":"resolved","year":"1998"},{"doi":"10.2320/materia.35.320","first_author":"Takemoto","kind":"unknown","label":"1","paper":"doi:10.2320/materia.35.320","reference":"T. Takemoto, Lead-free Solder and Micro-joining, Materia Jpn., 1996, 35, p 320-325 (in Japanese)","status":"resolved","year":"1996"},{"kind":"unknown","label":"723","status":"unresolved"},{"kind":"unknown","label":"17","status":"unresolved"},{"kind":"unknown","label":"32","status":"unresolved"},{"doi":"10.1016/j.jallcom.2003.11.026","first_author":"Vassilev","kind":"unknown","label":"10","paper":"doi:10.1016/j.jallcom.2003.11.026","reference":"G.P. Vassilev, Contribution to the Zinc-Rich Side of the Ti-Zn System, Z. Metallkde., 2004, 95(9), p 813-817 74","status":"resolved","year":"2004"},{"doi":"10.1103/physrevb.54.16533","first_author":"Perdew","kind":"unknown","label":"6","paper":"doi:10.1103/physrevb.54.16533","reference":"J.P. Perdew, K. Burke, and Y. Wang, Generalized Gradient Approximation for the Exchange-Correlation Hole of a ManyElectron System, Phys. Rev. B, 1996, 54, p 16533-16539","status":"resolved","year":"1996"},{"first_author":"Redlich","kind":"unknown","label":"3","reference":"O. Redlich and A.T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem., 1948, 40, p 354-384","status":"resolved","year":"1948"},{"kind":"unknown","label":"561","status":"unresolved"},{"kind":"unknown","label":"0","status":"unresolved"},{"kind":"unknown","label":"103","status":"unresolved"},{"kind":"unknown","label":"723","status":"unresolved"},{"kind":"unknown","label":"538","status":"unresolved"},{"kind":"unknown","label":"55","status":"unresolved"}],"component":"SN","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-D6CC22Q666.176fad","locator":{"ref":"sha256:c44997db7259ff59/p10/tab-7","row":1},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"TI":0.0,"ZN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p10/tab-7/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"Vm,X","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":505.0,"temperature_basis":"printed","temperature_printed":"505","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.85},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0918,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.003722,0.019682],"class":"unknown","entry":"value_types/VOLUME/classes/unknown","floor":0.0054,"floor_unit":"relative (fraction of the value)","n_pairs":43,"prior_source":"orchid_assumed","value":0.0918},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"10^-6 m^3/mol","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"10^-6 m^3/mol","unit_printed":"10^-6 m^3/mol","value":17.0,"value_printed":17.0},{"chemical_system":"SN-TI-ZN","cited_sources":[{"doi":"10.1002/srin.199400921","first_author":"Tanaka","kind":"unknown","label":"14","paper":"doi:10.1002/srin.199400921","reference":"T. Tanaka and T. Iida, Application of a Thermodynamic Database to the Calculation of Surface Tension for Iron-Base Liquid Alloys, Steel Res., 1994, 65, p 21-27","status":"resolved","year":"1994"},{"doi":"10.1002/srin.199400921","first_author":"Tanaka","kind":"unknown","label":"14","paper":"doi:10.1002/srin.199400921","reference":"T. Tanaka and T. Iida, Application of a Thermodynamic Database to the Calculation of Surface Tension for Iron-Base Liquid Alloys, Steel Res., 1994, 65, p 21-27","status":"resolved","year":"1994"},{"doi":"10.2320/materia.35.320","first_author":"Takemoto","kind":"unknown","label":"1","paper":"doi:10.2320/materia.35.320","reference":"T. Takemoto, Lead-free Solder and Micro-joining, Materia Jpn., 1996, 35, p 320-325 (in Japanese)","status":"resolved","year":"1996"},{"kind":"unknown","label":"17","status":"unresolved"},{"kind":"unknown","label":"0","status":"unresolved"},{"doi":"10.1016/j.jallcom.2003.11.026","first_author":"Vassilev","kind":"unknown","label":"10","paper":"doi:10.1016/j.jallcom.2003.11.026","reference":"G.P. Vassilev, Contribution to the Zinc-Rich Side of the Ti-Zn System, Z. Metallkde., 2004, 95(9), p 813-817 74","status":"resolved","year":"2004"},{"doi":"10.1103/physrevb.54.16533","first_author":"Perdew","kind":"unknown","label":"6","paper":"doi:10.1103/physrevb.54.16533","reference":"J.P. Perdew, K. Burke, and Y. Wang, Generalized Gradient Approximation for the Exchange-Correlation Hole of a ManyElectron System, Phys. Rev. B, 1996, 54, p 16533-16539","status":"resolved","year":"1996"},{"first_author":"Redlich","kind":"unknown","label":"3","reference":"O. Redlich and A.T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem., 1948, 40, p 354-384","status":"resolved","year":"1948"},{"kind":"unknown","label":"0","status":"unresolved"},{"kind":"unknown","label":"87","status":"unresolved"},{"doi":"10.1016/j.jallcom.2003.11.026","first_author":"Vassilev","kind":"unknown","label":"10","paper":"doi:10.1016/j.jallcom.2003.11.026","reference":"G.P. Vassilev, Contribution to the Zinc-Rich Side of the Ti-Zn System, Z. Metallkde., 2004, 95(9), p 813-817 74","status":"resolved","year":"2004"},{"first_author":"Hayes","kind":"assessment","label":"4","reference":"F. Hayes, Thermodynamic Database for Light Metal Alloys, COST 507, Volume 2, I. Ansara, A.T. Dinsdale, and M.H. Rand, Ed., Office for Official Publications of the European Communities, Luxembourg, 1998, p 284-287","status":"resolved","year":"1998"},{"doi":"10.2320/materia.35.320","first_author":"Takemoto","kind":"unknown","label":"1","paper":"doi:10.2320/materia.35.320","reference":"T. Takemoto, Lead-free Solder and Micro-joining, Materia Jpn., 1996, 35, p 320-325 (in Japanese)","status":"resolved","year":"1996"},{"kind":"unknown","label":"723","status":"unresolved"},{"kind":"unknown","label":"17","status":"unresolved"},{"kind":"unknown","label":"32","status":"unresolved"},{"doi":"10.1016/j.jallcom.2003.11.026","first_author":"Vassilev","kind":"unknown","label":"10","paper":"doi:10.1016/j.jallcom.2003.11.026","reference":"G.P. Vassilev, Contribution to the Zinc-Rich Side of the Ti-Zn System, Z. Metallkde., 2004, 95(9), p 813-817 74","status":"resolved","year":"2004"},{"doi":"10.1103/physrevb.54.16533","first_author":"Perdew","kind":"unknown","label":"6","paper":"doi:10.1103/physrevb.54.16533","reference":"J.P. Perdew, K. Burke, and Y. Wang, Generalized Gradient Approximation for the Exchange-Correlation Hole of a ManyElectron System, Phys. Rev. B, 1996, 54, p 16533-16539","status":"resolved","year":"1996"},{"first_author":"Redlich","kind":"unknown","label":"3","reference":"O. Redlich and A.T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem., 1948, 40, p 354-384","status":"resolved","year":"1948"},{"kind":"unknown","label":"561","status":"unresolved"},{"kind":"unknown","label":"0","status":"unresolved"},{"kind":"unknown","label":"103","status":"unresolved"},{"kind":"unknown","label":"723","status":"unresolved"},{"kind":"unknown","label":"538","status":"unresolved"},{"kind":"unknown","label":"55","status":"unresolved"}],"component":"SN","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":723.0,"before":505.0,"evidence":{"class":"temperature","decision_file":"temperature_t218.json","doi":"10.1361/105497106x92826","pdf_page":10,"pdf_sha256":"c44997db7259ff59413a4029ce1ec7e89372b7ee88d276efba0b448d96d2a678","printed":"Sn | Tm,X 505 K | Vm,X 17.0 | ... | V_X at 723 K, 10^-6 m^3/mol: 17.32","rationale":"column header prints the temperature 723 K for this value","report_id":"ORCHID-TD-20261028-v1","table":"7","table_key":"t218"},"field":"temperature_K","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"8f071bb8fdb98091269c63889de0421904f0555c62a3a0d60a615fd0bf9dfa60","page":10,"pdf_sha256_prefix":"c44997db7259ff59","seen":"Sn row, column 'V_X at 723 K': 17.32; stored T=505 is Tm (belongs to the Vm,X 17.0 cell)","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"human_review_residual_concern","detail":"value is the liquid molar volume extrapolated to 723 K from Vm at Tm and α (for Ti far below Tm); phase not printed (liquid implied)","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-D6CC22Q666.e88f78","locator":{"ref":"sha256:c44997db7259ff59/p10/tab-7","row":1},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"TI":0.0,"ZN":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p10/tab-7/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"MOLAR_VOLUME","property_group":"crystal structure","property_printed":"VX at 723 K","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":723.0,"temperature_basis":"printed","temperature_printed":"505","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.866},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09353,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.003722,0.019682],"class":"unknown","entry":"value_types/VOLUME/classes/unknown","floor":0.0054,"floor_unit":"relative (fraction of the value)","n_pairs":43,"prior_source":"orchid_assumed","value":0.09353},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"10^-6 m^3/mol","value_type":"VOLUME"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"10^-6 m^3/mol","unit_printed":"10^-6 m^3/mol","value":17.32,"value_printed":17.32},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-LAEGSJQ264","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":1},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0,"TI":0.0405484152,"ZN":0.9594515848},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ti-Zn"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":684.35,"temperature_basis":"printed","temperature_printed":"411.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":684.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-MUAG5AZNWF","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":2},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0,"TI":0.0405484152,"ZN":0.9594515848},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ti-Zn"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":731.85,"temperature_basis":"printed","temperature_printed":"458.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":731.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4MJ5BI5YXP","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":3},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0,"TI":0.0405484152,"ZN":0.9594515848},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ti-Zn"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":894.35,"temperature_basis":"printed","temperature_printed":"621.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":894.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-WTUZ7IRNKA","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":4},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7920159614,"TI":0.0446408395,"ZN":0.1633431992},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.55,"temperature_basis":"printed","temperature_printed":"198.4","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.55},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-GBWYN5WLZ2","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":5},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7920159614,"TI":0.0446408395,"ZN":0.1633431992},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":495.75,"temperature_basis":"printed","temperature_printed":"222.6","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":495.75},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-X5COBF7K4D","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":6},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7920159614,"TI":0.0446408395,"ZN":0.1633431992},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":906.85,"temperature_basis":"printed","temperature_printed":"633.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":906.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-VNJN22J37I","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":7},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7539305299,"TI":0.0869648927,"ZN":0.1591045774},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.55,"temperature_basis":"printed","temperature_printed":"198.4","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.55},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-FT4LN7X4GP","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":8},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7539305299,"TI":0.0869648927,"ZN":0.1591045774},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":498.55,"temperature_basis":"printed","temperature_printed":"225.4","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":498.55},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-GUIMH5YZ43","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":9},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7539305299,"TI":0.0869648927,"ZN":0.1591045774},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":938.35,"temperature_basis":"printed","temperature_printed":"665.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":938.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-WELJFAY3TM","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":10},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7177716766,"TI":0.1271479542,"ZN":0.1550803692},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.35,"temperature_basis":"printed","temperature_printed":"198.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-NIBF6WUAB7","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":11},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7177716766,"TI":0.1271479542,"ZN":0.1550803692},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":504.65,"temperature_basis":"printed","temperature_printed":"231.5","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":504.65},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-KTBII57FLD","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":12},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7177716766,"TI":0.1271479542,"ZN":0.1550803692},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":925.05,"temperature_basis":"printed","temperature_printed":"651.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":925.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-FM2EGZCFSG","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":13},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.7177716766,"TI":0.1271479542,"ZN":0.1550803692},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":1003.65,"temperature_basis":"printed","temperature_printed":"730.5","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1003.65},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-WNXYOL2FM5","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":14},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.6833968217,"TI":0.1653484716,"ZN":0.1512547067},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.05,"temperature_basis":"printed","temperature_printed":"197.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-EWZNW2LGEE","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":15},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.6833968217,"TI":0.1653484716,"ZN":0.1512547067},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":509.05,"temperature_basis":"printed","temperature_printed":"235.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":509.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-C6MUVKHEJX","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":16},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.6833968217,"TI":0.1653484716,"ZN":0.1512547067},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r16#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Zn series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":1044.35,"temperature_basis":"printed","temperature_printed":"771.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1044.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-2YXXBW6XVP","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":17},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.6377458733,"TI":0.0616210766,"ZN":0.3006330501},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r17#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.05,"temperature_basis":"printed","temperature_printed":"197.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-EBIGRR4V5A","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":18},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.6377458733,"TI":0.0616210766,"ZN":0.3006330501},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r18#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":553.15,"temperature_basis":"printed","temperature_printed":"280.0","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":553.15},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-KNLGOM5ZQH","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":19},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.6377458733,"TI":0.0616210766,"ZN":0.3006330501},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":766.75,"temperature_basis":"printed","temperature_printed":"493.6","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":766.75},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-HTEX6ZRWOD","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":20},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.6377458733,"TI":0.0616210766,"ZN":0.3006330501},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":869.95,"temperature_basis":"printed","temperature_printed":"596.8","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":869.95},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-BE6NDCFOQP","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":21},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.4159505981,"TI":0.0542924259,"ZN":0.5297569759},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r21#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":470.85,"temperature_basis":"printed","temperature_printed":"197.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":470.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-VXY74EDMVA","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":22},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.4159505981,"TI":0.0542924259,"ZN":0.5297569759},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r22#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":616.95,"temperature_basis":"printed","temperature_printed":"343.8","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":616.95},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-JG47W65CJA","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":23},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.4159505981,"TI":0.0542924259,"ZN":0.5297569759},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r23#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":894.05,"temperature_basis":"printed","temperature_printed":"620.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":894.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-P4JCAX6R4E","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":24},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.4159505981,"TI":0.0542924259,"ZN":0.5297569759},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r24#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":973.75,"temperature_basis":"printed","temperature_printed":"700.6","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":973.75},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4UNIMJUGJA","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":25},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.2413044608,"TI":0.0485216965,"ZN":0.7101738427},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r25#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.05,"temperature_basis":"printed","temperature_printed":"197.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-3HCHGU7PHZ","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":26},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.2413044608,"TI":0.0485216965,"ZN":0.7101738427},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r26#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":639.15,"temperature_basis":"printed","temperature_printed":"366.0","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":639.15},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ORH5VSRJZY","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":27},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.2413044608,"TI":0.0485216965,"ZN":0.7101738427},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r27#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":882.15,"temperature_basis":"printed","temperature_printed":"609.0","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":882.15},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-MDZIUYOH24","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":28},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.2413044608,"TI":0.0485216965,"ZN":0.7101738427},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r28#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":925.95,"temperature_basis":"printed","temperature_printed":"652.8","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":925.95},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-JBNQ5OV74L","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":29},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.1002175199,"TI":0.0438598437,"ZN":0.8559226363},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r29#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":470.85,"temperature_basis":"printed","temperature_printed":"197.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":470.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-SO6VH5BILE","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":30},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.1002175199,"TI":0.0438598437,"ZN":0.8559226363},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r30#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":642.85,"temperature_basis":"printed","temperature_printed":"369.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":642.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-JEODCTG6Z2","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":31},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.1002175199,"TI":0.0438598437,"ZN":0.8559226363},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r31#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":817.85,"temperature_basis":"printed","temperature_printed":"544.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":817.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ARVLHFAIWX","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":32},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.1002175199,"TI":0.0438598437,"ZN":0.8559226363},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r32#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":911.95,"temperature_basis":"printed","temperature_printed":"638.8","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":911.95},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-VBGNU3VH5O","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":33},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.1002175199,"TI":0.0438598437,"ZN":0.8559226363},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r33#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":947.25,"temperature_basis":"printed","temperature_printed":"674.1","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":947.25},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-QBFQYOQ2XI","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":34},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.5339528253,"TI":0.1891716032,"ZN":0.2768755715},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r34#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":470.95,"temperature_basis":"printed","temperature_printed":"197.8","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":470.95},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-V5ITVYQL7K","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":35},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.5339528253,"TI":0.1891716032,"ZN":0.2768755715},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r35#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":834.55,"temperature_basis":"printed","temperature_printed":"561.4","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":834.55},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-44YXCVA4FX","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":36},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.5339528253,"TI":0.1891716032,"ZN":0.2768755715},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r36#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":965.05,"temperature_basis":"printed","temperature_printed":"691.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":965.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-EEUQ6KDJLR","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":37},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.3392234258,"TI":0.1682545924,"ZN":0.4925219817},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r37#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":470.95,"temperature_basis":"printed","temperature_printed":"197.8","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":470.95},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-4QNGKT67O2","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":38},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.3392234258,"TI":0.1682545924,"ZN":0.4925219817},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r38#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":610.85,"temperature_basis":"printed","temperature_printed":"337.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":610.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-SPUTYNGHNG","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":39},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.3392234258,"TI":0.1682545924,"ZN":0.4925219817},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r39#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":925.85,"temperature_basis":"printed","temperature_printed":"652.7","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":925.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-G6SCPLZDQH","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":40},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.3392234258,"TI":0.1682545924,"ZN":0.4925219817},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r40#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":997.75,"temperature_basis":"printed","temperature_printed":"724.6","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":997.75},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-B4JOFYF7SV","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":41},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.3392234258,"TI":0.1682545924,"ZN":0.4925219817},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r41#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":1031.35,"temperature_basis":"printed","temperature_printed":"758.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1031.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-ZNDYIXBQKC","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":42},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.183269635,"TI":0.151502694,"ZN":0.665227671},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r42#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.05,"temperature_basis":"printed","temperature_printed":"197.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-MXFKHQEWVX","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":43},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.183269635,"TI":0.151502694,"ZN":0.665227671},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r43#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":642.25,"temperature_basis":"printed","temperature_printed":"369.1","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":642.25},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-NMO27ZSCVP","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":44},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.183269635,"TI":0.151502694,"ZN":0.665227671},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r44#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":1051.35,"temperature_basis":"printed","temperature_printed":"778.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1051.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-UK2X3TTTZC","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":45},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0555583349,"TI":0.1377844849,"ZN":0.8066571802},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r45#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":687.15,"temperature_basis":"printed","temperature_printed":"414.0","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":687.15},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-N6APFGHNIE","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":46},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0555583349,"TI":0.1377844849,"ZN":0.8066571802},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r46#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":783.05,"temperature_basis":"printed","temperature_printed":"509.9","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":783.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-PWK4NB6I2F","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":47},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0555583349,"TI":0.1377844849,"ZN":0.8066571802},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r47#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":938.35,"temperature_basis":"printed","temperature_printed":"665.2","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":938.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (UNKNOWN))","effect":"not_accepted","gate":"R3"}],"id":"ORC-D4RTZ6C72E","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-1","row":48},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0555583349,"TI":0.1377844849,"ZN":0.8066571802},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phases":[{"label":"UNKNOWN"}],"pid":"sha256:c44997db7259ff59/p3/tab-1/r48#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"10 mass% Ti series"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":962.65,"temperature_basis":"printed","temperature_printed":"689.5","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":962.65},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-SFBEPZ77C5","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.5339528253,"TI":0.1891716032,"ZN":0.2768755715},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.418683,"TI":0.528858,"ZN":0.052459},"composition_source":"printed","phase":"Sn5Ti6"}],"phases":[{"label":"Sn5Ti6"},{"label":"Liquid"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":873.15,"temperature_basis":"printed","temperature_printed":"600","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-KYHVBJHPAF","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":2},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.4308902263,"TI":0.1781010535,"ZN":0.3910087202},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.393281,"TI":0.548898,"ZN":0.057822},"composition_source":"printed","phase":"Sn5Ti6"},{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.420469,"TI":0.021374,"ZN":0.558157},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Sn5Ti6"},{"label":"Liquid"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-3YBKVKGGQI","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":3},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.3392234258,"TI":0.1682545924,"ZN":0.4925219817},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.393739,"TI":0.540038,"ZN":0.066223},"composition_source":"printed","phase":"Sn5Ti6"},{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.425665,"TI":0.021989,"ZN":0.552346},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.162601,"TI":0.255256,"ZN":0.582143},"composition_source":"printed","phase":"Sn3Ti5Zn12"}],"phases":[{"label":"Sn5Ti6"},{"label":"Liquid"},{"label":"Sn3Ti5Zn12"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-35O4BR45IK","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.2571613662,"TI":0.1594398321,"ZN":0.5833988017},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.428037,"TI":0.01873,"ZN":0.553234},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Liquid"},{"label":"Sn3Ti5Zn12"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-TDXGDEK75Z","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.183269635,"TI":0.151502694,"ZN":0.665227671},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.250781,"TI":0.001809,"ZN":0.74741},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Liquid"},{"label":"Sn3Ti5Zn12"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-3KLBMIRNCK","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":6},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.131265447,"TI":0.1302151479,"ZN":0.7385194051},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.143141,"TI":0.102664,"ZN":0.754195},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Liquid"},{"label":"Sn3Ti5Zn12"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-LHP3TTFOFD","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":7},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0917238912,"TI":0.1279546558,"ZN":0.7803214529},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.005754,"TI":0.002195,"ZN":0.992051},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Liquid"},{"label":"Sn3Ti5Zn12"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":973.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1361/105497106x92826"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-WCH4KNBHJL","locator":{"ref":"sha256:c44997db7259ff59/p3/tab-2","row":8},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"overall_composition":{"SN":0.0726758205,"TI":0.1663715003,"ZN":0.7609526791},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.001595,"TI":0.01173,"ZN":0.986675},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.001662,"TI":0.224907,"ZN":0.773432},"composition_source":"printed","phase":"Zn3Ti"}],"phases":[{"label":"Liquid"},{"label":"Sn3Ti5Zn12"},{"label":"Zn3Ti"}],"pid":"sha256:c44997db7259ff59/p3/tab-2/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":973.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-E4JRI6J3JA","locator":{"ref":"doi:10.1361/105497106x92826/p10/tab-6","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.806633,"TI":0.000299,"ZN":0.193068},"composition_source":"printed","phase":"L"}],"phases":[{"label":"TiZn15","model_phase":"TIZN15","pearson_symbol":"oC68","prototype":"TiZn16","structure_basis":"mapped_model_phase"},{"label":"Sn3Ti5Zn12"},{"label":"L","model_phase":"LIQUID"},{"label":"TiZn10","model_phase":"TIZN10","pearson_symbol":"tP100","prototype":"Ti3Zn22","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497106x92826/p10/tab-6/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"TiZn15 + Sn3Ti5Zn12 -> L + TiZn10","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":505.85,"temperature_printed":"232.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":505.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-AMROS3UQ3L","locator":{"ref":"doi:10.1361/105497106x92826/p10/tab-6","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.863264,"TI":0.000121,"ZN":0.136615},"composition_source":"printed","phase":"L"}],"phases":[{"label":"TiZn10","model_phase":"TIZN10","pearson_symbol":"tP100","prototype":"Ti3Zn22","structure_basis":"mapped_model_phase"},{"label":"Sn3Ti5Zn12"},{"label":"L","model_phase":"LIQUID"},{"label":"TiZn5","model_phase":"TIZN5","pearson_symbol":"?","prototype":"(TiZn5)","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497106x92826/p10/tab-6/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"TiZn10 + Sn3Ti5Zn12 -> L + TiZn5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":471.95,"temperature_printed":"198.8","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":471.95},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-KA7B6DN7UA","locator":{"ref":"doi:10.1361/105497106x92826/p10/tab-6","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.939651,"TI":0.00103,"ZN":0.059319},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn5Ti6"},{"label":"Sn3Ti5Zn12"},{"label":"(βSn)"}],"pid":"doi:10.1361/105497106x92826/p10/tab-6/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn5Ti6 -> Sn3Ti5Zn12 + (βSn)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":488.35,"temperature_printed":"215.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":488.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-KLTGTSENV3","locator":{"ref":"doi:10.1361/105497106x92826/p10/tab-6","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.867919,"TI":0.000112,"ZN":0.131969},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn3Ti5Zn12"},{"label":"TiZn5","model_phase":"TIZN5","pearson_symbol":"?","prototype":"(TiZn5)","structure_basis":"mapped_model_phase"},{"label":"(βSn)"}],"pid":"doi:10.1361/105497106x92826/p10/tab-6/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn3Ti5Zn12 -> TiZn5 + (βSn)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":469.35,"temperature_printed":"196.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":469.35},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-M3XZ75TQOR","locator":{"ref":"doi:10.1361/105497106x92826/p10/tab-6","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.8668,"TI":0.000107,"ZN":0.133093},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"TiZn5","model_phase":"TIZN5","pearson_symbol":"?","prototype":"(TiZn5)","structure_basis":"mapped_model_phase"},{"label":"TiZn10","model_phase":"TIZN10","pearson_symbol":"tP100","prototype":"Ti3Zn22","structure_basis":"mapped_model_phase"},{"label":"(βSn)"}],"pid":"doi:10.1361/105497106x92826/p10/tab-6/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + TiZn5 -> TiZn10 + (βSn)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":469.05,"temperature_printed":"195.9","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":469.05},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-DGVHU5CUMD","locator":{"ref":"doi:10.1361/105497106x92826/p10/tab-6","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.861875,"TI":6.7e-05,"ZN":0.138058},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"TiZn10","model_phase":"TIZN10","pearson_symbol":"tP100","prototype":"Ti3Zn22","structure_basis":"mapped_model_phase"},{"label":"TiZn15","model_phase":"TIZN15","pearson_symbol":"oC68","prototype":"TiZn16","structure_basis":"mapped_model_phase"},{"label":"(βSn)"}],"pid":"doi:10.1361/105497106x92826/p10/tab-6/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + TiZn10 -> TiZn15 + (βSn)","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":467.85,"temperature_printed":"194.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":467.85},{"chemical_system":"SN-TI-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-HLHQN7BSLM","locator":{"ref":"doi:10.1361/105497106x92826/p10/tab-6","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1361/105497106x92826","own_work_of_paper":true},"paper":"doi:10.1361/105497106x92826","paper_id":"doi:10.1361/105497106x92826","phase_compositions":[{"basis":"mole_fraction (converted from mass percent)","composition":{"SN":0.852697,"TI":2.1e-05,"ZN":0.147282},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(βSn)"},{"label":"(Zn)"},{"label":"TiZn15","model_phase":"TIZN15","pearson_symbol":"oC68","prototype":"TiZn16","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1361/105497106x92826/p10/tab-6/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> (βSn) + (Zn) + TiZn15","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"SN-TI-ZN","system":"SN-TI-ZN","temperature_K":465.55,"temperature_printed":"192.4","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":465.55}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"SN-TI-ZN"}