{"artifacts":{"doi:10.1016/j.calphad.2006.03.005/p4/tab-2":{"artifact":"table","caption":"Enthalpies of formation of intermetallic phases in the Y–Zn system","label":"2","page":4},"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3":{"artifact":"table","caption":"Experimental and calculated invariant reactions in the Zn–Y system","label":"3","page":5},"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4":{"artifact":"table","caption":"Gibbs free energy of formation of intermetallic compounds in the Zn–Y system","label":"4","page":5},"sha256:f767bd74d2381204/p2/tab-1":{"artifact":"table","caption":"Structures of binary and ternary intermetallic phases [1,4,10–12]","label":"1","page":2}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["Y","ZN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M413a1470":{"catalog_entry":{"license":"CC BY 4.0","name":"YZn-08Liu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"X.J. Liu, M.Z. Wen, C.P. Wang, F.S. Pan, J. Alloys Compd., 452, 283-90(2008).","model_doi":"10.1016/j.jallcom.2006.11.029","reproduced_by_calculation":false,"tdb":"YZn-08Liu.tdb","tdb_path":"databases/sgte-binary/YZn-08Liu.tdb","tdb_sha256":"14252f2607b2c1dc0d1135da4cd200568b4e3f75854b107e75927d49286bcee3"},"M420dcf8f":{"catalog_entry":{"license":"CC BY 4.0","name":"YZn-08Liu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"X.J. Liu, M.Z. Wen, C.P. Wang, F.S. Pan, J. Alloys Compd., 452, 283-90(2008).","model_doi":"10.1016/j.jallcom.2006.11.029","tdb":"YZn-08Liu.tdb","tdb_path":"databases/sgte-binary/YZn-08Liu.tdb","tdb_sha256":"14252f2607b2c1dc0d1135da4cd200568b4e3f75854b107e75927d49286bcee3"},"M9c9b5ed3":{"catalog_entry":{"license":"CC BY 4.0","name":"YZn-08Liu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"X.J. Liu, M.Z. Wen, C.P. Wang, F.S. Pan, J. Alloys Compd., 452, 283-90(2008).","model_doi":"10.1016/j.jallcom.2006.11.029","reproduced_by_calculation":true,"tdb":"YZn-08Liu.tdb","tdb_path":"databases/sgte-binary/YZn-08Liu.tdb","tdb_sha256":"14252f2607b2c1dc0d1135da4cd200568b4e3f75854b107e75927d49286bcee3"},"Mddb9ecc2":{"catalog_entry":{"license":"CC BY 4.0","name":"YZn-06Sha.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"G. Shao, V. Varsani, Z. Fan, Calphad, 30, 286-95(2006).","model_doi":"10.1016/j.calphad.2006.03.005","tdb":"YZn-06Sha.tdb","tdb_path":"databases/sgte-binary/YZn-06Sha.tdb","tdb_sha256":"e732c607e3a391d62edc34507c5c498f7d8898eba46f595e9e08a1c2762890d4"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02644469":{"authors":["J. T. Mason","P. Chiotti"],"citation":"J. T. Mason, P. Chiotti, Phase diagram and thermodynamic properties of the yttrium-zinc system, Metall Trans A 7, 287-291 (1976).","container":"Metall Trans A","doi":"10.1007/bf02644469","doi_url":"https://doi.org/10.1007/bf02644469","id":"doi:10.1007/bf02644469","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase diagram and thermodynamic properties of the yttrium-zinc system","year":1976},"doi:10.1007/bf02651927":{"authors":["Z. P. Luo","H. X. Sui","S. Q. Zhang"],"citation":"Z. P. Luo, H. X. Sui, S. Q. Zhang, On the stable Mg-Zn-Y quasicrystals, Metall Mater Trans A 27, 1779-1784 (1996).","container":"Metall Mater Trans A","doi":"10.1007/bf02651927","doi_url":"https://doi.org/10.1007/bf02651927","id":"doi:10.1007/bf02651927","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"On the stable Mg-Zn-Y quasicrystals","year":1996},"doi:10.1016/j.calphad.2006.03.005":{"authors":["G. Shao","V. Varsani","Z. Fan"],"citation":"G. Shao, V. Varsani, Z. Fan, Thermodynamic modelling of the Y–Zn and Mg–Zn–Y systems, Calphad 30, 286-295 (2006).","container":"Calphad","doi":"10.1016/j.calphad.2006.03.005","doi_url":"https://doi.org/10.1016/j.calphad.2006.03.005","id":"doi:10.1016/j.calphad.2006.03.005","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"f767bd74d2381204","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modelling of the Y–Zn and Mg–Zn–Y systems","year":2006},"doi:10.1016/j.jallcom.2006.11.029":{"authors":["X.J. Liu","M.Z. Wen","C.P. Wang","F.S. Pan"],"citation":"X.J. Liu, M.Z. Wen, C.P. Wang, F.S. Pan, Thermodynamic assessment of the Zn–Y and Al–Zn–Y systems, Journal of Alloys and Compounds 452, 283-290 (2008).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2006.11.029","doi_url":"https://doi.org/10.1016/j.jallcom.2006.11.029","id":"doi:10.1016/j.jallcom.2006.11.029","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"1628a5a2120ad3a7","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Zn–Y and Al–Zn–Y systems","year":2008},"doi:10.1080/01418610008212098":{"authors":["An-Pang Tsai","Yoshihiro Murakami","Akio Niikura"],"citation":"An-Pang Tsai, Yoshihiro Murakami, Akio Niikura, The Zn-Mg-Y phase diagram involving quasicrystals, Philosophical Magazine A 80, 1043-1054 (2000).","container":"Philosophical Magazine A","doi":"10.1080/01418610008212098","doi_url":"https://doi.org/10.1080/01418610008212098","id":"doi:10.1080/01418610008212098","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Zn-Mg-Y phase diagram involving quasicrystals","year":2000},"doi:10.1080/095008398178020":{"authors":["H. Takakura","A. Sato","A. Yamamoto","A. P. Tsai"],"citation":"H. Takakura, A. Sato, A. Yamamoto, A. P. Tsai, Crystal structure of a hexagonal phase and its relation to a quasicrystalline phase in Zn-Mg-Y alloy, Philosophical Magazine Letters 78, 263-270 (1998).","container":"Philosophical Magazine Letters","doi":"10.1080/095008398178020","doi_url":"https://doi.org/10.1080/095008398178020","id":"doi:10.1080/095008398178020","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Crystal structure of a hexagonal phase and its relation to a quasicrystalline phase in Zn-Mg-Y alloy","year":1998}},"part":1,"parts":1,"records":[{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"awaiting_reader","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-LGGHU7ECVB","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":1},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn","model_phase":"YZN_B2"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.35},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-47.0,"value_printed":-47.0,"value_stored":-47000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-4WDHF5TLRR","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":2},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn","model_phase":"YZN_B2"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-48.0,"value_printed":-48,"value_stored":-48000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-4C6ZOE4WD7","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn","model_phase":"YZN_B2"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-54.0,"value_printed":-54,"value_stored":-54000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-YAJ75SEQTO","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":4},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-48.0,"value_printed":-48.0,"value_stored":-48000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-GV3DOSR2KO","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":5},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-52.0,"value_printed":-52,"value_stored":-52000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-DHWCCNM2FA","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.55},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-51.0,"value_printed":-51,"value_stored":-51000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-DBPD3UL3HT","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":7},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.3},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-46.0,"value_printed":-46.0,"value_stored":-46000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-EC3ASAA6YL","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":8},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-49.0,"value_printed":-49,"value_stored":-49000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-EPK7GU6TMX","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":9},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.55},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-51.0,"value_printed":-51,"value_stored":-51000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-HLIRXXKB65","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":10},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn3","model_phase":"YZN3"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.075},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-41.5,"value_printed":-41.5,"value_stored":-41500.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZI4RGRY3NW","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":11},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn3","model_phase":"YZN3"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-43.0,"value_printed":-43,"value_stored":-43000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-HEF3ABFPPT","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":12},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn3","model_phase":"YZN3"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.1},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-42.0,"value_printed":-42,"value_stored":-42000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-NHF2ANAU6L","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":13},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y3Zn11","model_phase":"Y3ZN11"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.93715},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-38.743,"value_printed":-38.743,"value_stored":-38743.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-S5WKD7Y6NS","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":14},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y3Zn11","model_phase":"Y3ZN11"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-40.0,"value_printed":-40,"value_stored":-40000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-3TVNGUWM7F","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":15},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y3Zn11","model_phase":"Y3ZN11"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-36.0,"value_printed":-36,"value_stored":-36000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-OKA4LRSMKZ","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":16},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.816901},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y13Zn58","model_phase":"Y13ZN58"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-36.0,"value_printed":-36.0,"value_stored":-36000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-BKM4AVQ7QH","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":17},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.816901},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y13Zn58","model_phase":"Y13ZN58"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-37.0,"value_printed":-37,"value_stored":-37000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-IF2RYTTBFV","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":18},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.816901},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y13Zn58","model_phase":"Y13ZN58"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-32.0,"value_printed":-32,"value_stored":-32000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-NYHZV35V7G","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":19},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn5","model_phase":"YZN5"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.71665},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-34.333,"value_printed":-34.333,"value_stored":-34333.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-TLCAGNUBYU","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":20},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn5","model_phase":"YZN5"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-33.0,"value_printed":-33,"value_stored":-33000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-6K6WPHOAAR","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":21},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn5","model_phase":"YZN5"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-25.0,"value_printed":-25,"value_stored":-25000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-WPGMJD33FW","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":22},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y2Zn17","model_phase":"Y2ZN17"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.4},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-28.0,"value_printed":-28.0,"value_stored":-28000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-QYLELMVMJR","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":23},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y2Zn17","model_phase":"Y2ZN17"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-30.0,"value_printed":-30,"value_stored":-30000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-ASJX6RDYQN","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":24},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y2Zn17","model_phase":"Y2ZN17"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-18.0,"value_printed":-18,"value_stored":-18000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-QPOA3ADAGR","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":25},"method":"CALPHAD","method_basis":"printed in the table row/column","model":"Mddb9ecc2","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2006.03.005","own_work_of_paper":true},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn12","model_phase":"YZN12_D2B"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.1535},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-23.07,"value_printed":-23.07,"value_stored":-23070.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"8","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. 7A (1976) 287.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":0,"id":"ORC-JK4GOT6CE3","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":26},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn12","model_phase":"YZN12_D2B"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":2.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":2.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-23.0,"value_printed":-23,"value_stored":-23000.0},{"chemical_system":"Y-ZN","cited_sources":[{"kind":"unknown","label":"23","reference":"F.R. de Boer, R. Boom, V.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals, Transition Metal Alloys, North-Holland, Amsterdam, 1988.","status":"resolved","year":"1988"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-4SXBO5VT6G","locator":{"ref":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2","row":27},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn12","model_phase":"YZN12_D2B"}],"pid":"doi:10.1016/j.calphad.2006.03.005/p4/tab-2/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.65},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ per mole of atoms","unit_stored":"J/mol-atom","value":-13.0,"value_printed":-13,"value_stored":-13000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-JGFOM3SNEB","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":1},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.9135},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-38.27,"value_printed":-38.27,"value_stored":-38270.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-WEDALIDZMD","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":2},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-38.0,"value_printed":-38,"value_stored":-38000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-OUFOZJAI4A","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-36.0,"value_printed":-36,"value_stored":-36000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-4BWEBS56T3","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":4},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.775},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-35.5,"value_printed":-35.5,"value_stored":-35500.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-5UEZHRIZMB","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":5},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-35.0,"value_printed":-35,"value_stored":-35000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-G63HNJYYYQ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":6},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.635},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-32.7,"value_printed":-32.7,"value_stored":-32700.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-XLMFSOK3OC","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":7},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-31.0,"value_printed":-31,"value_stored":-31000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-XIMX7YD7UA","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":8},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"αYZn2"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-40.1,"value_printed":-40.1,"value_stored":-40100.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-KURJIRUXMN","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":9},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"αYZn2"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-40.0,"value_printed":-40,"value_stored":-40000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-HNF47QMGED","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":10},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"αYZn2"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-38.0,"value_printed":-38,"value_stored":-38000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-MKZLGOVMHX","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":11},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"αYZn2"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.795},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-35.9,"value_printed":-35.9,"value_stored":-35900.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-QQSGPEZY6Y","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":12},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"αYZn2"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-36.0,"value_printed":-36,"value_stored":-36000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-MWYC7JGIBV","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":13},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"βYZn2"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.61},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-32.2,"value_printed":-32.2,"value_stored":-32200.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-37FWLR52XC","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":14},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"βYZn2"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-32.0,"value_printed":-32,"value_stored":-32000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-NUGFKR6GEF","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":15},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn3"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.705},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-34.1,"value_printed":-34.1,"value_stored":-34100.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-AQQW4WZFCL","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":16},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn3"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-35.0,"value_printed":-35,"value_stored":-35000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-JP3WERVVDX","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":17},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn3"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-32.0,"value_printed":-32,"value_stored":-32000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-WMI73YCAIE","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":18},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn3"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.51},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-30.2,"value_printed":-30.2,"value_stored":-30200.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-YGB6DF2VIF","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":19},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn3"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-31.0,"value_printed":-31,"value_stored":-31000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-R5WWCQVQDE","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":20},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn3"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.315},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-26.3,"value_printed":-26.3,"value_stored":-26300.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-UMASVPDMZM","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":21},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn3"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-27.0,"value_printed":-27,"value_stored":-27000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-IUOJQTBLHR","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":22},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y3Zn11"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.56},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-31.2,"value_printed":-31.2,"value_stored":-31200.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-OWLHFM4GOR","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":23},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y3Zn11"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-31.0,"value_printed":-31,"value_stored":-31000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-EAPMZ57DO4","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":24},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y3Zn11"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-30.0,"value_printed":-30,"value_stored":-30000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-DDM2AOAQRQ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":25},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y3Zn11"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.37},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-27.4,"value_printed":-27.4,"value_stored":-27400.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-WN3VMHD2O3","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":26},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y3Zn11"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-28.0,"value_printed":-28,"value_stored":-28000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-GDND62J4EJ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":27},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y3Zn11"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.18},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-23.6,"value_printed":-23.6,"value_stored":-23600.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-ZDY5VS3FGO","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":28},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y3Zn11"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r28#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-24.0,"value_printed":-24,"value_stored":-24000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-VTMZ5TRI2H","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":29},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.816901},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y13Zn58"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.42},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-28.4,"value_printed":-28.4,"value_stored":-28400.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-QNRWY44J53","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":30},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.816901},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y13Zn58"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r30#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-28.0,"value_printed":-28,"value_stored":-28000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-FMLXDFZYN6","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":31},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.816901},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y13Zn58"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.24},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-24.8,"value_printed":-24.8,"value_stored":-24800.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-64D3MXFVAL","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":32},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.816901},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y13Zn58"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.055},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-21.1,"value_printed":-21.1,"value_stored":-21100.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-KPH66G3JJ2","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":33},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn5"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.345},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-26.9,"value_printed":-26.9,"value_stored":-26900.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-UAWE4UXNVE","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":34},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn5"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-29.0,"value_printed":-29,"value_stored":-29000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-4CV4EVXVXH","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":35},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn5"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r35#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-24.0,"value_printed":-24,"value_stored":-24000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-KSHMZ3D3BD","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":36},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn5"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r36#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.17},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-23.4,"value_printed":-23.4,"value_stored":-23400.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-ZAGX362XDV","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":37},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn5"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r37#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-25.0,"value_printed":-25,"value_stored":-25000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-CVELMWH67M","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":38},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn5"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r38#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.98},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-19.6,"value_printed":-19.6,"value_stored":-19600.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-GB2SIFVF6C","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":39},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn5"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r39#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-21.0,"value_printed":-21,"value_stored":-21000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-ACCLKVXZFK","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":40},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y2Zn17"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r40#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-21.2,"value_printed":-21.2,"value_stored":-21200.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-T3VGUK7VNP","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":41},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y2Zn17"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r41#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-23.0,"value_printed":-23,"value_stored":-23000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-7NL4OM42MO","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":42},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y2Zn17"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r42#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-21.0,"value_printed":-21,"value_stored":-21000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-TTWM2TA2XU","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":43},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y2Zn17"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r43#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.88},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-17.6,"value_printed":-17.6,"value_stored":-17600.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-XRQ7EIS5PR","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":44},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y2Zn17"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r44#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-19.0,"value_printed":-19,"value_stored":-19000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-25I3MYJOWC","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":45},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y2Zn17"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r45#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.705},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-14.1,"value_printed":-14.1,"value_stored":-14100.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-G5Y45RZ6TD","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":46},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"Y2Zn17"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r46#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-14.0,"value_printed":-14,"value_stored":-14000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-ENHFOJELLI","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":47},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn12"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r47#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.82},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-16.4,"value_printed":-16.4,"value_stored":-16400.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-ISAX62FUFR","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":48},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn12"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r48#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-19.0,"value_printed":-19,"value_stored":-19000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-RKWBI757VK","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":49},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn12"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r49#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-16.0,"value_printed":-16,"value_stored":-16000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-WN54M62UYI","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":50},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn12"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r50#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.64},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-12.8,"value_printed":-12.8,"value_stored":-12800.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-WIJNHVWWPC","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":51},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn12"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r51#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-15.0,"value_printed":-15,"value_stored":-15000.0},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-H54BDNR4CF","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":52},"model":"M420dcf8f","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn12"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r52#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.47},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.59304,0.88956],"class":"model_calculated","entry":"model/GM_FORM","floor":0.7,"floor_unit":"kJ/mol-atom","n_pairs":211,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-9.4,"value_printed":-9.4,"value_stored":-9400.0},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"GM_FORM","before":"GM_MIX","evidence":{"property_printed":"Gibbs free energy of formation"},"field":"property","gate":"G5","rule":"printed_quantity_is_formation"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"detail":"GM_FORM of a stoichiometric compound (ESPEI 0.9.1 fits only HM_FORM/SM_FORM of compound endmembers)","reason":"compound_property_not_fittable","result":"fail"},"espei_ready":false,"espei_ready_upstream":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-H5FYP57CKH","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4","row":53},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phases":[{"label":"YZn12"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-4/r53#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_FORM","property_code_before_gates":"GM_MIX","property_group":"formation","property_printed":"Gibbs free energy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"Y":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"},"ZN":{"fixed_state_variables":{"T":298.15},"phase":"HCP_A3"}},"source_system":"Y-ZN","system":"Y-ZN","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.2,"sigma_method":{"basis":"calibrated","ci95":[0.660465,2.096713],"class":"unknown","entry":"value_types/GM_FORM/classes/unknown","floor":1.2,"floor_unit":"kJ/mol-atom","n_pairs":37,"value":1.2},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"GM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol of atoms","unit_stored":"J/mol-atom","value":-11.0,"value_printed":-11,"value_stored":-11000.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.5,"ZN":0.5},"phases":["YZn"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-MFJR4LG7KY","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":4},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.5,"ZN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"cP2","strukturbericht":"B2"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.007872,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.007872},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.578,"value_stored":0.3578},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.333333,"ZN":0.666667},"phases":["αYZn2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-LL2UDB6IXB.021b17","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.333333,"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"αYZn2"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oI12"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01571,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01571},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.143,"value_stored":0.7143},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.333333,"ZN":0.666667},"phases":["αYZn2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-LL2UDB6IXB.6a3a69","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.333333,"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"αYZn2"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oI12"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01686,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01686},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.664,"value_stored":0.7664},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.333333,"ZN":0.666667},"phases":["αYZn2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-LL2UDB6IXB.ffcbfc","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":5},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.333333,"ZN":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"αYZn2"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oI12"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009909,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009909},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.504,"value_stored":0.4504},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.25,"ZN":0.75},"phases":["YZn3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-BBTP52ESAV.2600de","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.25,"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn3"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oP16"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01472,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01472},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.69,"value_stored":0.669},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.25,"ZN":0.75},"phases":["YZn3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-BBTP52ESAV.40fda3","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.25,"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn3"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oP16"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02224,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02224},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":10.111,"value_stored":1.0111},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.25,"ZN":0.75},"phases":["YZn3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-BBTP52ESAV.c523e2","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.25,"ZN":0.75},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn3"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oP16"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009691,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009691},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.405,"value_stored":0.4405},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.214286,"ZN":0.785714},"phases":["Y3Zn11"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-JEUBKY6TUX.36d1f3","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.214286,"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y3Zn11"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oI28"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02844,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02844},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.929,"value_stored":1.2929},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.214286,"ZN":0.785714},"phases":["Y3Zn11"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-JEUBKY6TUX.ab1126","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.214286,"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y3Zn11"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oI28"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009654,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009654},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.388,"value_stored":0.4388},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.214286,"ZN":0.785714},"phases":["Y3Zn11"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-JEUBKY6TUX.c7ae1b","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":8},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.214286,"ZN":0.785714},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y3Zn11"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"oI28"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01952,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01952},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.871,"value_stored":0.8871},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Y13Zn58 (Y2Zn9)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-IEQQBAATZL.1abd8c","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y13Zn58 (Y2Zn9)"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP146"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0308},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.0,"value_stored":1.4},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Y13Zn58 (Y2Zn9)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-IEQQBAATZL.9d788c","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y13Zn58 (Y2Zn9)"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP146"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03142,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03142},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.28,"value_stored":1.428},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Y13Zn58 (Y2Zn9)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-IEQQBAATZL.be0b4d","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y13Zn58 (Y2Zn9)"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP146"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":120.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.166667,"ZN":0.833333},"phases":["YZn5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-YIWZRNZHGY.50c4ee","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.166667,"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn5"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP36"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02024,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02024},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.201,"value_stored":0.9201},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.166667,"ZN":0.833333},"phases":["YZn5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-YIWZRNZHGY.8a6650","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.166667,"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn5"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP36"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":120.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.166667,"ZN":0.833333},"phases":["YZn5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-YIWZRNZHGY.b22204","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.166667,"ZN":0.833333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn5"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP36"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01955,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01955},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.885,"value_stored":0.8885},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.105263,"ZN":0.894737},"phases":["Y2Zn17"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-3XD4KV7HDU.494f08","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.105263,"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y2Zn17"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP38"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01928,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01928},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.764,"value_stored":0.8764},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.105263,"ZN":0.894737},"phases":["Y2Zn17"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-3XD4KV7HDU.e1cb2b","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.105263,"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y2Zn17"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_GAMMA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP38"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.5},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":120.0},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.105263,"ZN":0.894737},"phases":["Y2Zn17"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-3XD4KV7HDU.f1d797","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":11},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.105263,"ZN":0.894737},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"Y2Zn17"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"hP38"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0196,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0196},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.911,"value_stored":0.8911},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.076923,"ZN":0.923077},"phases":["YZn12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-IELFKI4BAR.314c1a","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.076923,"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn12"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"tI26"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01953,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01953},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.875,"value_stored":0.8875},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1080/01418610008212098","first_author":"Tsai","kind":"unknown","label":"1","paper":"doi:10.1080/01418610008212098","reference":"A.P. Tsai, Y. Murakami, A. Niikura, Phil. Mag. A 80 (2000) 1043.","status":"resolved","year":"2000"},{"first_author":"Okamoto","kind":"assessment","label":"4","reference":"H. Okamoto, Desk Handbook — Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"},{"doi":"10.1080/095008398178020","first_author":"Takakura","kind":"unknown","label":"10","paper":"doi:10.1080/095008398178020","reference":"H. Takakura, A. Sato, A. Yamamoto, A.P. Tsai, Phil. Mag. Lett. 78 (1998) 263.","status":"resolved","year":"1998"},{"first_author":"Villars","kind":"unknown","label":"11","reference":"P. Villars, L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, ASM, 1985.","status":"resolved","year":"1985"},{"doi":"10.1007/bf02651927","first_author":"Luo","kind":"unknown","label":"12","paper":"doi:10.1007/bf02651927","reference":"Z.P. Luo, H.X. Sui, S.Q. Zhang, Metall. Mater. Trans. 27A (1996) 1779.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"Y-ZN","before":"MG-Y-ZN","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"Y":0.076923,"ZN":0.923077},"phases":["YZn12"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-IELFKI4BAR.88dd6c","locator":{"ref":"sha256:f767bd74d2381204/p2/tab-1","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"Y":0.076923,"ZN":0.923077},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2006.03.005","paper_id":"doi:10.1016/j.calphad.2006.03.005","phases":[{"label":"YZn12"}],"pid":"sha256:f767bd74d2381204/p2/tab-1/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"MG-Y-ZN","structure":{"pearson_symbol":"tI26"},"system":"Y-ZN","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01142,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01142},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.192,"value_stored":0.5192},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-OSCLBK6V4T","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":1},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.2854},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> hcp + YZn","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1148.15,"temperature_printed":"875","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1148.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-MPDU2E2F26","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.2912},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> hcp + YZn","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1148.15,"temperature_printed":"875","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1148.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-BY7225MNKN","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":3},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.2912},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> hcp + YZn","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1148.15,"temperature_printed":"875","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1148.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-AC2VMCIJ5Z","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.291},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> hcp + YZn","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1148.15,"temperature_printed":"875","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1148.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-EI3MZGCD22","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":5},"model":"M413a1470","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.5},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1378.15,"temperature_printed":"1105","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-IDD3GOEMPL","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.5},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1378.15,"temperature_printed":"1105","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-SNJMFM5ZEF","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.5},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1378.15,"temperature_printed":"1105","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-7UXOCDZNI3","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.5},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1378.15,"temperature_printed":"1105","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-UTIVR2U2F6","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":9},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.5945},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn + βYZn2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1313.15,"temperature_printed":"1040","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1313.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-Z3Q7NWY3EP","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.59},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn + βYZn2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1288.15,"temperature_printed":"1015","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1288.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-YBLJGTXU7S","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":11},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.59},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn + βYZn2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1288.15,"temperature_printed":"1015","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1288.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-R33R4RAI26","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.59},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.5,"ZN":0.5},"composition_source":"stoichiometric_model_phase","phase":"YZn"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn","model_phase":"YZN_B2","pearson_symbol":"cP2","prototype":"CsCl","structure_basis":"mapped_model_phase"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> YZn + βYZn2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1288.15,"temperature_printed":"1015","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1288.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-VSILKA3GSS","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":13},"model":"M413a1470","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.6667},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> βYZn2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1353.15,"temperature_printed":"1080","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1353.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-RVBTGXYID3","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.6667},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> βYZn2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1353.15,"temperature_printed":"1080","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1353.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-GRFZ2OLCNQ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":15},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.6667},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> βYZn2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1353.15,"temperature_printed":"1080","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1353.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-M6J5BCOBVQ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.6667},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> βYZn2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1353.15,"temperature_printed":"1080","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1353.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-O4PAFO5CNF","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":17},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8028},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + βYZn2 -> YZn3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1178.15,"temperature_printed":"905","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-EM7YRGRROJ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8182},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + βYZn2 -> YZn3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1178.15,"temperature_printed":"905","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-5OY72WFZRJ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":19},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.82},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + βYZn2 -> YZn3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1178.15,"temperature_printed":"905","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-FRY55EMD7B","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":20},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.83},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + βYZn2 -> YZn3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1178.15,"temperature_printed":"905","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-S5ZSPI6TFL","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":21},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8118},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.214286,"ZN":0.785714},"composition_source":"stoichiometric_model_phase","phase":"Y3Zn11"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"},{"label":"Y3Zn11","model_phase":"Y3ZN11","pearson_symbol":"oI28","prototype":"Al11La3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + YZn3 -> Y3Zn11","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1168.15,"temperature_printed":"895","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-MWNDSR6UVT","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":22},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.824},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.214286,"ZN":0.785714},"composition_source":"stoichiometric_model_phase","phase":"Y3Zn11"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"},{"label":"Y3Zn11","model_phase":"Y3ZN11","pearson_symbol":"oI28","prototype":"Al11La3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + YZn3 -> Y3Zn11","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1168.15,"temperature_printed":"895","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-QOWNRI3KWG","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":23},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.831},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.214286,"ZN":0.785714},"composition_source":"stoichiometric_model_phase","phase":"Y3Zn11"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"},{"label":"Y3Zn11","model_phase":"Y3ZN11","pearson_symbol":"oI28","prototype":"Al11La3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + YZn3 -> Y3Zn11","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1169.15,"temperature_printed":"896","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1169.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-6XDIIVHU5E","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":24},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.838},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.25,"ZN":0.75},"composition_source":"stoichiometric_model_phase","phase":"YZn3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.214286,"ZN":0.785714},"composition_source":"stoichiometric_model_phase","phase":"Y3Zn11"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"YZn3","model_phase":"YZN3","pearson_symbol":"oP16","prototype":"YZn3","structure_basis":"mapped_model_phase"},{"label":"Y3Zn11","model_phase":"Y3ZN11","pearson_symbol":"oI28","prototype":"Al11La3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + YZn3 -> Y3Zn11","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1168.15,"temperature_printed":"895","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-KPYICYRL2O","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":25},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8309},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.214286,"ZN":0.785714},"composition_source":"stoichiometric_model_phase","phase":"Y3Zn11"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.183099,"ZN":0.816901},"composition_source":"stoichiometric_model_phase","phase":"Y13Zn58"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y3Zn11","model_phase":"Y3ZN11","pearson_symbol":"oI28","prototype":"Al11La3","structure_basis":"mapped_model_phase"},{"label":"Y13Zn58","model_phase":"Y13ZN58","pearson_symbol":"hP146","prototype":"Y13Zn58","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y3Zn11 -> Y13Zn58","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1153.15,"temperature_printed":"880","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1153.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-QJQX6RJHYF","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":26},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.837},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.214286,"ZN":0.785714},"composition_source":"stoichiometric_model_phase","phase":"Y3Zn11"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.183099,"ZN":0.816901},"composition_source":"stoichiometric_model_phase","phase":"Y13Zn58"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y3Zn11","model_phase":"Y3ZN11","pearson_symbol":"oI28","prototype":"Al11La3","structure_basis":"mapped_model_phase"},{"label":"Y13Zn58","model_phase":"Y13ZN58","pearson_symbol":"hP146","prototype":"Y13Zn58","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y3Zn11 -> Y13Zn58","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1155.15,"temperature_printed":"882","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1155.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-GXHIKCQYCX","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":27},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.852},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.214286,"ZN":0.785714},"composition_source":"stoichiometric_model_phase","phase":"Y3Zn11"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.183099,"ZN":0.816901},"composition_source":"stoichiometric_model_phase","phase":"Y13Zn58"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y3Zn11","model_phase":"Y3ZN11","pearson_symbol":"oI28","prototype":"Al11La3","structure_basis":"mapped_model_phase"},{"label":"Y13Zn58","model_phase":"Y13ZN58","pearson_symbol":"hP146","prototype":"Y13Zn58","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y3Zn11 -> Y13Zn58","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1153.15,"temperature_printed":"880","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1153.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-42L7KN4VHW","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":28},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8495},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.183099,"ZN":0.816901},"composition_source":"stoichiometric_model_phase","phase":"Y13Zn58"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y13Zn58","model_phase":"Y13ZN58","pearson_symbol":"hP146","prototype":"Y13Zn58","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y13Zn58 -> YZn5","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1143.15,"temperature_printed":"870","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1143.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-NPPMSI6VWS","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":29},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8472},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.183099,"ZN":0.816901},"composition_source":"stoichiometric_model_phase","phase":"Y13Zn58"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y13Zn58","model_phase":"Y13ZN58","pearson_symbol":"hP146","prototype":"Y13Zn58","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r29#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y13Zn58 -> YZn5","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1143.15,"temperature_printed":"870","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1143.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-FYKGOS5AKM","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":30},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.854},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.183099,"ZN":0.816901},"composition_source":"stoichiometric_model_phase","phase":"Y13Zn58"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y13Zn58","model_phase":"Y13ZN58","pearson_symbol":"hP146","prototype":"Y13Zn58","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r30#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y13Zn58 -> YZn5","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1145.15,"temperature_printed":"872","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1145.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-V6YB5VV6PD","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":31},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.861},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.183099,"ZN":0.816901},"composition_source":"stoichiometric_model_phase","phase":"Y13Zn58"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y13Zn58","model_phase":"Y13ZN58","pearson_symbol":"hP146","prototype":"Y13Zn58","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r31#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y13Zn58 -> YZn5","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1143.15,"temperature_printed":"870","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1143.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-E5QJQDQJXW","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":32},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8533},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17 + YZn5","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1141.15,"temperature_printed":"868","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1141.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-VTHRXIO4N2","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":33},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.86},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r33#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17 + YZn5","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1138.15,"temperature_printed":"865","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1138.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-CBJO5LV7MY","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":34},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.86},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r34#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17 + YZn5","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1136.15,"temperature_printed":"863","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1136.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-DC5YRV5LN3","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":35},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.87},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.166667,"ZN":0.833333},"composition_source":"stoichiometric_model_phase","phase":"YZn5"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn5","model_phase":"YZN5","pearson_symbol":"hP36","prototype":"ErZn5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r35#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17 + YZn5","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1133.15,"temperature_printed":"860","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1133.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-IPI7JV6UOX","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":36},"model":"M413a1470","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8947},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r36#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1163.15,"temperature_printed":"890","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1163.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-3FT34GMONE","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":37},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8947},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r37#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1163.15,"temperature_printed":"890","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1163.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-LVJCH5OBLG","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":38},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8947},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r38#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1163.15,"temperature_printed":"890","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1163.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-YSTMW3DSFP","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":39},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.8947},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r39#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Y2Zn17","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1163.15,"temperature_printed":"890","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1163.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-CF6UW2E6I2","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":40},"model":"M9c9b5ed3","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.9928},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.076923,"ZN":0.923077},"composition_source":"stoichiometric_model_phase","phase":"YZn12"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn12","model_phase":"YZN12_D2B","pearson_symbol":"tI26","prototype":"Mn12Th","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r40#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y2Zn17 -> YZn12","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":958.15,"temperature_printed":"685","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":958.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-VPGZOFX4MJ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":41},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.9943},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.076923,"ZN":0.923077},"composition_source":"stoichiometric_model_phase","phase":"YZn12"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn12","model_phase":"YZN12_D2B","pearson_symbol":"tI26","prototype":"Mn12Th","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r41#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y2Zn17 -> YZn12","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":958.15,"temperature_printed":"685","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":958.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-EMTEE2SRMH","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":42},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.9942},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.076923,"ZN":0.923077},"composition_source":"stoichiometric_model_phase","phase":"YZn12"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn12","model_phase":"YZN12_D2B","pearson_symbol":"tI26","prototype":"Mn12Th","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r42#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y2Zn17 -> YZn12","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":958.15,"temperature_printed":"685","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":958.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-B2CBD5GOEJ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":43},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"ZN":0.9933},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.105263,"ZN":0.894737},"composition_source":"stoichiometric_model_phase","phase":"Y2Zn17"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"Y":0.076923,"ZN":0.923077},"composition_source":"stoichiometric_model_phase","phase":"YZn12"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Y2Zn17","model_phase":"Y2ZN17","pearson_symbol":"hP38","prototype":"Ni17Th2","structure_basis":"mapped_model_phase"},{"label":"YZn12","model_phase":"YZN12_D2B","pearson_symbol":"tI26","prototype":"Mn12Th","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r43#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Y2Zn17 -> YZn12","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":958.15,"temperature_printed":"685","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":958.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-2T6RQ7VWWF","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":48},"model":"M413a1470","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r48#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn–YZn2 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1023.15,"temperature_printed":"750","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1023.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-IHYK2AVMH6","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":49},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r49#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn–YZn2 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1023.15,"temperature_printed":"750","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1023.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-UZAU2JYTNY","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":50},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r50#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn–YZn2 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1023.15,"temperature_printed":"750","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1023.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-2BOVG5YA4U","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":51},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r51#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn–YZn2 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1023.15,"temperature_printed":"750","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1023.15},{"chemical_system":"Y-ZN","conditions":{"kind":"not_applicable_own_calculation"},"duplicate_of":"ORC-2T6RQ7VWWF","evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["duplicate_invariant_same_page"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"duplicate_invariant_same_page","detail":"same invariant as ORC-2T6RQ7VWWF on the same page (|dT| <= 0.5 K, same phases)","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-3ODVULA7RQ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":52},"model":"M413a1470","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.11.029","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r52#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn2–YZn3 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":1023.15,"temperature_printed":"750","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1023.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Chiotti","kind":"unknown","label":"9","reference":"P. Chiotti, J.T. Mason, K.J. Gill, Trans. TMS-AIME 227 (1963) 910–916.","status":"resolved","year":"1963"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-KDWQMRLWHE","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":53},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r53#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn2–YZn3 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":823.15,"temperature_printed":"~550","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":823.15},{"chemical_system":"Y-ZN","cited_sources":[{"doi":"10.1007/bf02644469","first_author":"Mason","kind":"unknown","label":"10","paper":"doi:10.1007/bf02644469","reference":"J.T. Mason, P. Chiotti, Metall. Trans. A 7 (1976) 287–291.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-S6UJ3JUSUZ","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":54},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r54#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn2–YZn3 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":903.15,"temperature_printed":"630","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":903.15},{"chemical_system":"Y-ZN","cited_sources":[{"first_author":"Okamoto","kind":"assessment","label":"11","reference":"H. Okamoto, Desk Handbook—Phase Diagrams for Binary Alloys, ASM International, 2000.","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-VQR26JNTBH","locator":{"ref":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3","row":55},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.11.029","paper_id":"doi:10.1016/j.jallcom.2006.11.029","phase_compositions":[{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"βYZn2"},{"basis":"mole_fraction","composition":{"Y":0.333333,"ZN":0.666667},"composition_source":"stoichiometric_model_phase","phase":"αYZn2"}],"phases":[{"label":"βYZn2","model_phase":"YZN2_HT"},{"label":"αYZn2","model_phase":"YZN2_LT"}],"pid":"doi:10.1016/j.jallcom.2006.11.029/p5/tab-3/r55#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"βYZn2 -> αYZn2 (in the YZn2–YZn3 region)","type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"Y-ZN","system":"Y-ZN","temperature_K":903.15,"temperature_printed":"630","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"polymorphic","transition_kind_printed":"Polymorphic-transformation","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":903.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"Y-ZN"}