Ag–Ca phases

10 phases (tier A 5, tier B 1, tier C 2, liquid 1, needs_review 1); 9 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: interactive registry · full JSON · Ag–Ca system page · Markdown · field reference

Phases of the Ag–Ca system (10)
Phase	Structure	Basis	Stability (calculated)	Literature values	TDB models
AG2CA phase:ag-ca:ag2ca	Hg2K · oI12 · Imma (74)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 3 of 3 calculated diagram(s): 300–870.07 K, x(Ca) 0.33333–0.33333	9	3
AG3CA5_D8L phase:ag-ca:ag3ca5-d8l	Cr5B3 · D8_l · tI32 · I4/mcm (140)	tier A: standard phase name	stable in 3 of 3 calculated diagram(s): 300–831.47 K, x(Ca) 0.625–0.625	14	3
AG7CA2 phase:ag-ca:ag7ca2	Ag7Yb2 · oC36 · Cmcm (63)	tier B: DFT-supported (unique MP + OQMD match)	stable in 3 of 3 calculated diagram(s): 300–1003.95 K, x(Ca) 0.22222–0.22222	13	3
AG9CA2_C15B phase:ag-ca:ag9ca2-c15b		needs_review	stable in 3 of 3 calculated diagram(s): 300–961.37 K, x(Ca) 0.18182–0.18182	14	3
AGCA_B33 phase:ag-ca:agca-b33	CrB · B33 · oC8 · Cmcm (63)	tier A: standard phase name	stable in 3 of 3 calculated diagram(s): 300–938.26 K, x(Ca) 0.5–0.5	15	3
AGCA3 phase:ag-ca:agca3	(AgCa3) · oC16 · Cmcm (63)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 3 of 3 calculated diagram(s): 300–756.75 K, x(Ca) 0.75–0.75	16	3
BCC_A2 phase:ag-ca:bcc-a2	W · A2 · cI2 · Im-3m (229)	tier A: standard phase name	stable in 3 of 3 calculated diagram(s): 301.06–2500 K, x(Ca) 0.99993–1	6	3
FCC_A1 phase:ag-ca:fcc-a1	Cu · A1 · cF4 · Fm-3m (225)	tier A: standard phase name	stable in 3 of 3 calculated diagram(s): 300–1296.82 K, x(Ca) 0–1	5	3
HCP_A3 phase:ag-ca:hcp-a3	Mg · A3 · hP2 · P6_3/mmc (194)	tier A: standard phase name	not stable in 3 calculated diagram(s)	0	3
LIQUID phase:ag-ca:liquid	liquid	liquid	stable in 3 of 3 calculated diagram(s): 736.72–2500 K, x(Ca) 0–1	49	3

AG2CA (Ag–Ca)

Id: phase:ag-ca:ag2ca; status assigned
Structure: Hg2K · oI12 · Imma (74); type st:hg2k-oi12; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (dft_space_group_74_matches_2_structure_types, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Ag 0.6667, Ca 0.3333
Stability: stable in 3 of 3 calculated diagram(s): 300–870.07 K, x(Ca) 0.33333–0.33333
Literature: 9 values (9 accepted) from 2 papers
Interactive: phase registry entry

Names (7): corpus: corpus:phase:ag-ca:ag2ca
paper: paper:10.1016/j.jallcom.2007.06.064:Ca Ag2, paper:10.1016/j.jallcom.2007.06.064:CaAg2, paper:10.1016/j.jallcom.2014.05.141:Ag2Ca
tdb: tdb:AgCa-08Hua.tdb:AG2CA, tdb:AgCa-14Bra.tdb:AG2CA, tdb:AgCa-96Che-LB.tdb:AG2CA

TDB models of AG2CA (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: AG2CA, type code %, sha256 426decd914817145…

53: PHASE AG2CA % 2 2 1 !
54: CONST AG2CA : AG : CA : !

AgCa-14Bra.tdb: AG2CA, type code %, sha256 2e7a57eb5f5fff2b…

50: PHASE AG2CA % 2 2 1 !
51: CONST AG2CA : AG : CA : !

AgCa-96Che-LB.tdb: AG2CA, type code %, sha256 9a265c0f2167061b…

55: PHASE AG2CA % 2 2 1 !
56: CONST AG2CA : AG : CA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase

AG3CA5_D8L (Ag–Ca)

Id: phase:ag-ca:ag3ca5-d8l; status assigned
Structure: Cr5B3 · D8_l · tI32 · I4/mcm (140); type st:d8-l-cr5b3-ti32; tier A: standard phase name; confidence high
Stoichiometry: Ag 0.3750, Ca 0.6250
Stability: stable in 3 of 3 calculated diagram(s): 300–831.47 K, x(Ca) 0.625–0.625
Literature: 14 values (14 accepted) from 2 papers
Interactive: phase registry entry

Names (6): corpus: corpus:phase:ag-ca:ag3ca5-d8l
paper: paper:10.1016/j.jallcom.2007.06.064:Ca5Ag3, paper:10.1016/j.jallcom.2014.05.141:Ag3Ca5
tdb: tdb:AgCa-08Hua.tdb:AG3CA5_D8L, tdb:AgCa-14Bra.tdb:AG3CA5_D8L, tdb:AgCa-96Che-LB.tdb:AG3CA5_D8L

TDB models of AG3CA5_D8L (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: AG3CA5_D8L, type code %, sha256 426decd914817145…

63: PHASE AG3CA5_D8L % 2 3 5 !
64: CONST AG3CA5_D8L : AG : CA : !

AgCa-14Bra.tdb: AG3CA5_D8L, type code %, sha256 2e7a57eb5f5fff2b…

60: PHASE AG3CA5_D8L % 2 3 5 !
61: CONST AG3CA5_D8L : AG : CA : !

AgCa-96Che-LB.tdb: AG3CA5_D8L, type code %, sha256 9a265c0f2167061b…

65: PHASE AG3CA5_D8L % 2 3 5 !
66: CONST AG3CA5_D8L : AG : CA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase

AG7CA2 (Ag–Ca)

Id: phase:ag-ca:ag7ca2; status assigned
Structure: Ag7Yb2 · oC36 · Cmcm (63); type st:ag7yb2-oc36; tier B: DFT-supported (unique MP + OQMD match); confidence high
Stoichiometry: Ag 0.7778, Ca 0.2222
Stability: stable in 3 of 3 calculated diagram(s): 300–1003.95 K, x(Ca) 0.22222–0.22222
Literature: 13 values (11 accepted) from 2 papers
Interactive: phase registry entry

Names (8): corpus: corpus:phase:ag-ca:ag7ca2
mp: mp:mp-aaaaayva
oqmd: oqmd:oqmd-9958
paper: paper:10.1016/j.jallcom.2007.06.064:Ca2Ag7, paper:10.1016/j.jallcom.2014.05.141:Ag7Ca2
tdb: tdb:AgCa-08Hua.tdb:AG7CA2, tdb:AgCa-14Bra.tdb:AG7CA2, tdb:AgCa-96Che-LB.tdb:AG7CA2

TDB models of AG7CA2 (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: AG7CA2, type code %, sha256 426decd914817145…

48: PHASE AG7CA2 % 2 7 2 !
49: CONST AG7CA2 : AG : CA : !

AgCa-14Bra.tdb: AG7CA2, type code %, sha256 2e7a57eb5f5fff2b…

45: PHASE AG7CA2 % 2 7 2 !
46: CONST AG7CA2 : AG : CA : !

AgCa-96Che-LB.tdb: AG7CA2, type code %, sha256 9a265c0f2167061b…

50: PHASE AG7CA2 % 2 7 2 !
51: CONST AG7CA2 : AG : CA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase

AG9CA2_C15B (Ag–Ca)

Id: phase:ag-ca:ag9ca2-c15b; status needs_review
No structure assigned. Why: assessment_declared_blocked_by:stoichiometry_contradicts_C15_b; stoichiometry_contradicts_C15_b:AgCa-08Hua.tdb; stoichiometry_contradicts_C15_b:AgCa-14Bra.tdb; stoichiometry_contradicts_C15_b:AgCa-96Che-LB.tdb
Candidate (literature_printed): AuBe5 · cF24 — printed with a label mapped to this phase
Candidate (name_token): AuBe5 · C15_b · cF24 · F-43m (216) — Strukturbericht/word 'C15B' in the TDB name
Candidate (sgte_mmc2): AuBe5 · C15_b · cF24 · F-43m (216) — Hallstedt 2025 mmc2 row for AG9CA2_C15B: Ag9Ca2
Candidate (tdb_comment): AuBe5 · cF24 · F-43m — AgCa-08Hua.tdb: 'Prototype AuBe5 (cF24, F-43m)'
Candidate (tdb_comment): AuBe5 · cF24 · F-43m — AgCa-14Bra.tdb: 'Prototype AuBe5 (cF24, F-43m)'
Candidate (tdb_comment): AuBe5 · cF24 · F-43m — AgCa-96Che-LB.tdb: 'Prototype AuBe5 (cF24, F-43m)'
Stoichiometry: Ag 0.8182, Ca 0.1818
Stability: stable in 3 of 3 calculated diagram(s): 300–961.37 K, x(Ca) 0.18182–0.18182
Literature: 14 values (14 accepted) from 2 papers
Interactive: phase registry entry

Names (7): corpus: corpus:phase:ag-ca:ag9ca2-c15b
paper: paper:10.1016/j.jallcom.2007.06.064:Ag9Ca2, paper:10.1016/j.jallcom.2007.06.064:Ca2Ag9, paper:10.1016/j.jallcom.2014.05.141:Ag9Ca2
tdb: tdb:AgCa-08Hua.tdb:AG9CA2_C15B, tdb:AgCa-14Bra.tdb:AG9CA2_C15B, tdb:AgCa-96Che-LB.tdb:AG9CA2_C15B

TDB models of AG9CA2_C15B (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: AG9CA2_C15B, type code %, sha256 426decd914817145…

43: PHASE AG9CA2_C15B % 2 9 2 !
44: CONST AG9CA2_C15B : AG : CA : !

AgCa-14Bra.tdb: AG9CA2_C15B, type code %, sha256 2e7a57eb5f5fff2b…

40: PHASE AG9CA2_C15B % 2 9 2 !
41: CONST AG9CA2_C15B : AG : CA : !

AgCa-96Che-LB.tdb: AG9CA2_C15B, type code %, sha256 9a265c0f2167061b…

44: PHASE AG9CA2_C15B % 2 9 2 !
45: CONST AG9CA2_C15B : AG : CA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase

AGCA_B33 (Ag–Ca)

Id: phase:ag-ca:agca-b33; status assigned
Structure: CrB · B33 · oC8 · Cmcm (63); type st:b33-crb-oc8; tier A: standard phase name; confidence high
Stoichiometry: Ag 0.5000, Ca 0.5000
Stability: stable in 3 of 3 calculated diagram(s): 300–938.26 K, x(Ca) 0.5–0.5
Literature: 15 values (15 accepted) from 2 papers
Interactive: phase registry entry

Names (6): corpus: corpus:phase:ag-ca:agca-b33
paper: paper:10.1016/j.jallcom.2007.06.064:CaAg, paper:10.1016/j.jallcom.2014.05.141:AgCa
tdb: tdb:AgCa-08Hua.tdb:AGCA_B33, tdb:AgCa-14Bra.tdb:AGCA_B33, tdb:AgCa-96Che-LB.tdb:AGCA_B33

TDB models of AGCA_B33 (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: AGCA_B33, type code %, sha256 426decd914817145…

58: PHASE AGCA_B33 % 2 1 1 !
59: CONST AGCA_B33 : AG : CA : !

AgCa-14Bra.tdb: AGCA_B33, type code %, sha256 2e7a57eb5f5fff2b…

55: PHASE AGCA_B33 % 2 1 1 !
56: CONST AGCA_B33 : AG : CA : !

AgCa-96Che-LB.tdb: AGCA_B33, type code %, sha256 9a265c0f2167061b…

60: PHASE AGCA_B33 % 2 1 1 !
61: CONST AGCA_B33 : AG : CA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase

AGCA3 (Ag–Ca)

Id: phase:ag-ca:agca3; status assigned
Structure: (AgCa3) · oC16 · Cmcm (63); type st:agca3-oc16; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_mp, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Ag 0.2500, Ca 0.7500
Stability: stable in 3 of 3 calculated diagram(s): 300–756.75 K, x(Ca) 0.75–0.75
Literature: 16 values (16 accepted) from 2 papers
Interactive: phase registry entry

Names (6): corpus: corpus:phase:ag-ca:agca3
paper: paper:10.1016/j.jallcom.2007.06.064:Ca3Ag, paper:10.1016/j.jallcom.2014.05.141:AgCa3
tdb: tdb:AgCa-08Hua.tdb:AGCA3, tdb:AgCa-14Bra.tdb:AGCA3, tdb:AgCa-96Che-LB.tdb:AGCA3

TDB models of AGCA3 (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: AGCA3, type code %, sha256 426decd914817145…

68: PHASE AGCA3 % 2 1 3 !
69: CONST AGCA3 : AG : CA : !

AgCa-14Bra.tdb: AGCA3, type code %, sha256 2e7a57eb5f5fff2b…

65: PHASE AGCA3 % 2 1 3 !
66: CONST AGCA3 : AG : CA : !

AgCa-96Che-LB.tdb: AGCA3, type code %, sha256 9a265c0f2167061b…

70: PHASE AGCA3 % 2 1 3 !
71: CONST AGCA3 : AG : CA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase

BCC_A2 (Ag–Ca)

Id: phase:ag-ca:bcc-a2; status assigned
Structure: W · A2 · cI2 · Im-3m (229); type st:a2-w-ci2; tier A: standard phase name; confidence high
Stability: stable in 3 of 3 calculated diagram(s): 301.06–2500 K, x(Ca) 0.99993–1
Literature: 6 values (6 accepted) from 2 papers
Interactive: phase registry entry

Names (6): corpus: corpus:phase:ag-ca:bcc-a2
paper: paper:10.1016/j.jallcom.2007.06.064:(βCa), paper:10.1016/j.jallcom.2014.05.141:Ca (bcc A2)
tdb: tdb:AgCa-08Hua.tdb:BCC_A2, tdb:AgCa-14Bra.tdb:BCC_A2, tdb:AgCa-96Che-LB.tdb:BCC_A2

TDB models of BCC_A2 (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: BCC_A2, type code %B, sha256 426decd914817145…

33: PHASE BCC_A2 %B 2 1 3 !
34: CONST BCC_A2 : AG CA% : VA : !

AgCa-14Bra.tdb: BCC_A2, type code %B, sha256 2e7a57eb5f5fff2b…

30: PHASE BCC_A2 %B 2 1 3 !
31: CONST BCC_A2 : AG CA% : VA : !

AgCa-96Che-LB.tdb: BCC_A2, type code %B, sha256 9a265c0f2167061b…

34: PHASE BCC_A2 %B 2 1 3 !
35: CONST BCC_A2 : AG CA% : VA : !

Example references (3 of 3; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase

FCC_A1 (Ag–Ca)

Id: phase:ag-ca:fcc-a1; status assigned
Structure: Cu · A1 · cF4 · Fm-3m (225); type st:a1-cu-cf4; tier A: standard phase name; confidence high
Stability: stable in 3 of 3 calculated diagram(s): 300–1296.82 K, x(Ca) 0–1
Literature: 5 values (5 accepted) from 2 papers
Interactive: phase registry entry

Names (6): corpus: corpus:phase:ag-ca:fcc-a1
paper: paper:10.1016/j.jallcom.2007.06.064:(Ag), paper:10.1016/j.jallcom.2014.05.141:Ag (fcc A1)
tdb: tdb:AgCa-08Hua.tdb:FCC_A1, tdb:AgCa-14Bra.tdb:FCC_A1, tdb:AgCa-96Che-LB.tdb:FCC_A1

TDB models of FCC_A1 (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: FCC_A1, type code %A, sha256 426decd914817145…

28: PHASE FCC_A1 %A 2 1 1 !
29: CONST FCC_A1 : AG% CA% : VA : !

AgCa-14Bra.tdb: FCC_A1, type code %A, sha256 2e7a57eb5f5fff2b…

25: PHASE FCC_A1 %A 2 1 1 !
26: CONST FCC_A1 : AG% CA% : VA : !

AgCa-96Che-LB.tdb: FCC_A1, type code %A, sha256 9a265c0f2167061b…

29: PHASE FCC_A1 %A 2 1 1 !
30: CONST FCC_A1 : AG% CA% : VA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase

HCP_A3 (Ag–Ca)

Id: phase:ag-ca:hcp-a3; status assigned
Structure: Mg · A3 · hP2 · P6_3/mmc (194); type st:a3-mg-hp2; tier A: standard phase name; confidence high
Stability: not stable in 3 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (4): corpus: corpus:phase:ag-ca:hcp-a3
tdb: tdb:AgCa-08Hua.tdb:HCP_A3, tdb:AgCa-14Bra.tdb:HCP_A3, tdb:AgCa-96Che-LB.tdb:HCP_A3

TDB models of HCP_A3 (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: HCP_A3, type code %A, sha256 426decd914817145…

38: PHASE HCP_A3 %A 2 1 0.5 !
39: CONST HCP_A3 : AG CA : VA : !

AgCa-14Bra.tdb: HCP_A3, type code %A, sha256 2e7a57eb5f5fff2b…

35: PHASE HCP_A3 %A 2 1 0.5 !
36: CONST HCP_A3 : AG CA : VA : !

AgCa-96Che-LB.tdb: HCP_A3, type code %A, sha256 9a265c0f2167061b…

39: PHASE HCP_A3 %A 2 1 0.5 !
40: CONST HCP_A3 : AG CA : VA : !

Example references (2 of 2; assessments first):

doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase
doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase

LIQUID (Ag–Ca)

Id: phase:ag-ca:liquid; status assigned
Structure: liquid; type st:liquid; liquid; confidence high
Stability: stable in 3 of 3 calculated diagram(s): 736.72–2500 K, x(Ca) 0–1
Literature: 49 values (47 accepted) from 2 papers
Interactive: phase registry entry

Names (6): corpus: corpus:phase:ag-ca:liquid
paper: paper:10.1016/j.jallcom.2007.06.064:L, paper:10.1016/j.jallcom.2014.05.141:Liquid
tdb: tdb:AgCa-08Hua.tdb:LIQUID, tdb:AgCa-14Bra.tdb:LIQUID, tdb:AgCa-96Che-LB.tdb:LIQUID

TDB models of LIQUID (3): PHASE and CONSTITUENT statements as written

AgCa-08Hua.tdb: LIQUID, type code %, sha256 426decd914817145…

23: PHASE LIQUID:L % 1 1 !
24: CONST LIQUID:L : AG CA : !

AgCa-14Bra.tdb: LIQUID, type code %, sha256 2e7a57eb5f5fff2b…

20: PHASE LIQUID:L % 1 1 !
21: CONST LIQUID:L : AG CA : !

AgCa-96Che-LB.tdb: LIQUID, type code %, sha256 9a265c0f2167061b…

24: PHASE LIQUID:L % 1 1 !
25: CONST LIQUID:L : AG CA : !

Example references (4 of 4; assessments first):

doi:10.1016/j.jallcom.2014.05.141 M. Helena Braga, Adam Dębski, Władysław Gąsior, Optimization and assessment of the Ag–Ca phase diagram, Journal of Alloys and Compounds 612, 280-286 (2014).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2007.06.064 G.X. Huang, L.B. Liu, B.R. Jia, L.G. Zhang, Z.P. Jin, Thermodynamic modeling of the Ca–Ag binary system, Journal of Alloys and Compounds 460, 375-378 (2008).
assessment that models this phase; reports values for this phase
doi:10.1139/v69-093 W. A. Alexander, L. D. Calvert, A. Desaulniers, H. S. Dunsmore, D. F. Sargent, The silver–calcium phase diagram, Can. J. Chem. 47, 611-614 (1969).
cited as the source of values for this phase
doi:10.1007/bf02881269 M.R. Baren, Bull. Alloy Phase Diagram 9 (3) (1988) 228–231.
cited as the source of values for this phase

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735970
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}