B–Ti phases
10 phases (tier A 5, tier C 3, liquid 1, needs_review 1); 9 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).
Data: interactive registry · full JSON · B–Ti system page · Markdown · field reference
| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---|---|
| BETA_RHOMBO_B phase:b-ti:b-beta-rhombo | needs_review | stable in 7 of 7 calculated diagram(s): 300–2549.98 K, x(B) 1–1 | 7 | 7 | |
| MB_B27 phase:b-ti:b27-mb | FeB · B27 · oP8 · Pnma (62) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 2 of 2 calculated diagram(s): 300–2456.06 K, x(B) 0.5–0.5 | 2 | 2 |
| BCC_A2 phase:b-ti:bcc-a2 | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 300.18–3999.73 K, x(B) 0–0.0108 | 18 | 7 |
| MB2_C32 phase:b-ti:c32-mb2 | AlB2 · C32 · hP3 · P6/mmm (191) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 300–3488.99 K, x(B) 0.66667–0.66667 | 0 | 1 |
| FCC_A1 phase:b-ti:fcc-a1 | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | not stable in 7 calculated diagram(s) | 0 | 7 |
| HCP_A3 phase:b-ti:hcp-a3 | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 300–1157.68 K, x(B) 0–0.00164 | 6 | 7 |
| LIQUID phase:b-ti:liquid | liquid | liquid | stable in 7 of 7 calculated diagram(s): 1780–4000 K, x(B) 0–1 | 64 | 7 |
| TI3B4_D7B phase:b-ti:ti3b4-d7b | Ta3B4 · D7_b · oI14 · Immm (71) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 300–2481.63 K, x(B) 0.57143–0.57143 | 19 | 7 |
| TIB_B27 phase:b-ti:tib-b27 | FeB · B27 · oP8 · Pnma (62) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 5 of 5 calculated diagram(s): 300–2459.71 K, x(B) 0.48221–0.5 | 32 | 5 |
| TIB2_C32 phase:b-ti:tib2-c32 | AlB2 · C32 · hP3 · P6/mmm (191) | tier A: standard phase name | stable in 6 of 6 calculated diagram(s): 300–3496.05 K, x(B) 0.63954–0.6769 | 48 | 6 |
BETA_RHOMBO_B (B–Ti)
- Id:
phase:b-ti:b-beta-rhombo; statusneeds_review - No structure assigned. Why: name_has_descriptive_tokens:RHOMBO; no_structure_token
- Candidate (sgte_mmc2): beta-B · hR105 · R-3m (166) — Hallstedt 2025 mmc2 row for BETA_RHOMBO_B: beta-B
- Candidate (tdb_comment): beta-B · hR105 · R-3m — TiB-04Ma.tdb: 'Prototype beta-B (hR105, R-3m)'
- Candidate (tdb_comment): beta-B · hR105 · R-3m — TiB-08Wit.tdb: 'Prototype beta-B (hR105, R-3m)'
- Candidate (tdb_comment): beta-B · hR105 · R-3m — TiB-09Nak.tdb: 'Prototype beta-B (hR105, R-3m)'
- Candidate (tdb_comment): beta-B · hR105 · R-3m — TiB-11Cac.tdb: 'Prototype beta-B (hR105, R-3m)'
- Candidate (tdb_comment): beta-B · hR105 · R-3m — TiB-16Wit.tdb: 'Prototype beta-B (hR105, R-3m)'
- Candidate (tdb_comment): beta-B · hR105 · R-3m — TiB-19Wit.tdb: 'Prototype beta-B (hR105, R-3m)'
- Candidate (tdb_comment): beta-B · hR105 · R-3m — TiB-94Bat-LB.tdb: 'Prototype beta-B (hR105, R-3m)'
- Stability: stable in 7 of 7 calculated diagram(s): 300–2549.98 K, x(B) 1–1
- Literature: 7 values (6 accepted) from 3 papers
- Interactive: phase registry entry
Names (12): corpus: corpus:phase:b-ti:b-beta-rhombo, corpus:phase:b-ti:beta-rhombo-b
paper: paper:10.1016/j.calphad.2011.10.003:B, paper:10.1016/j.jallcom.2003.09.017:(βB), paper:10.1016/j.jallcom.2006.10.034:(β-B)
tdb: tdb:TiB-04Ma.tdb:BETA_RHOMBO_B, tdb:TiB-08Wit.tdb:BETA_RHOMBO_B, tdb:TiB-09Nak.tdb:BETA_RHOMBO_B, tdb:TiB-11Cac.tdb:BETA_RHOMBO_B, tdb:TiB-16Wit.tdb:BETA_RHOMBO_B, tdb:TiB-19Wit.tdb:BETA_RHOMBO_B, tdb:TiB-94Bat-LB.tdb:BETA_RHOMBO_B
TDB models of BETA_RHOMBO_B (7): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: BETA_RHOMBO_B, type code %, sha256 1bea624752196864…
46: PHASE BETA_RHOMBO_B % 1 1 ! 47: CONST BETA_RHOMBO_B : B : !
TiB-08Wit.tdb: BETA_RHOMBO_B, type code %, sha256 1d8367fa30ef15c2…
44: PHASE BETA_RHOMBO_B % 1 1 ! 45: CONST BETA_RHOMBO_B : B% TI : !
TiB-09Nak.tdb: BETA_RHOMBO_B, type code %, sha256 1b4af84d09dba0c7…
45: PHASE BETA_RHOMBO_B % 1 1 ! 46: CONST BETA_RHOMBO_B : B : !
TiB-11Cac.tdb: BETA_RHOMBO_B, type code %, sha256 4e632683d15fe800…
46: PHASE BETA_RHOMBO_B % 1 1 ! 47: CONST BETA_RHOMBO_B : B : !
TiB-16Wit.tdb: BETA_RHOMBO_B, type code %, sha256 f17559a1695b8573…
44: PHASE BETA_RHOMBO_B % 1 1 ! 45: CONST BETA_RHOMBO_B : B% TI : !
TiB-19Wit.tdb: BETA_RHOMBO_B, type code %, sha256 13ea870c397a4aba…
44: PHASE BETA_RHOMBO_B % 1 1 ! 45: CONST BETA_RHOMBO_B : B% TI : !
TiB-94Bat-LB.tdb: BETA_RHOMBO_B, type code %, sha256 0fb6180a65bd872e…
42: PHASE BETA_RHOMBO_B % 2 93 12 ! 43: CONST BETA_RHOMBO_B : B : B : !
Example references (6 of 6; assessments first):
- doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase
MB_B27 (B–Ti)
- Id:
phase:b-ti:b27-mb; statusassigned - Structure: FeB · B27 · oP8 · Pnma (62); type
st:b27-feb-op8; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (name_has_descriptive_tokens:MB, no_structure_token, structure_token_is_also_a_formula); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: B 0.5000, Ti 0.5000
- Stability: stable in 2 of 2 calculated diagram(s): 300–2456.06 K, x(B) 0.5–0.5
- Literature: 2 values (2 accepted) from 1 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:b-ti:b27-mb, corpus:phase:b-ti:mb-b27
paper: paper:10.1016/j.calphad.2011.10.003:TiB
tdb: tdb:TiB-11Cac.tdb:MB_B27, tdb:TiB-94Bat-LB.tdb:MB_B27
TDB models of MB_B27 (2): PHASE and CONSTITUENT statements as written
TiB-11Cac.tdb: MB_B27, type code %, sha256 4e632683d15fe800…
51: PHASE MB_B27 % 2 1 1 ! 52: CONST MB_B27 : TI : B : !
TiB-94Bat-LB.tdb: MB_B27, type code %, sha256 0fb6180a65bd872e…
47: PHASE MB_B27 % 2 1 1 ! 48: CONST MB_B27 : TI : B : !
Example references (1 of 1; assessments first):
- doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase; reports values for this phase
BCC_A2 (B–Ti)
- Id:
phase:b-ti:bcc-a2; statusassigned - Structure: W · A2 · cI2 · Im-3m (229); type
st:a2-w-ci2; tier A: standard phase name; confidence high - Stability: stable in 7 of 7 calculated diagram(s): 300.18–3999.73 K, x(B) 0–0.0108
- Literature: 18 values (18 accepted) from 5 papers
- Interactive: phase registry entry
Names (13): corpus: corpus:phase:b-ti:bcc-a2
paper: paper:10.1007/bf02646248:βTi, paper:10.1016/j.calphad.2011.10.003:bcc-Ti, paper:10.1016/j.jallcom.2003.09.017:(βTi), paper:10.1016/j.jallcom.2006.10.034:bcc, paper:sha256-85fd53a1a176b694:bcc-A2
tdb: tdb:TiB-04Ma.tdb:BCC_A2, tdb:TiB-08Wit.tdb:BCC_A2, tdb:TiB-09Nak.tdb:BCC_A2, tdb:TiB-11Cac.tdb:BCC_A2, tdb:TiB-16Wit.tdb:BCC_A2, tdb:TiB-19Wit.tdb:BCC_A2, tdb:TiB-94Bat-LB.tdb:BCC_A2
TDB models of BCC_A2 (7): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: BCC_A2, type code %B, sha256 1bea624752196864…
36: PHASE BCC_A2 %B 2 1 3 ! 37: CONST BCC_A2 : TI% : B VA% : !
TiB-08Wit.tdb: BCC_A2, type code %B, sha256 1d8367fa30ef15c2…
34: PHASE BCC_A2 %B 2 1 3 ! 35: CONST BCC_A2 : TI% : B VA% : !
TiB-09Nak.tdb: BCC_A2, type code %B, sha256 1b4af84d09dba0c7…
35: PHASE BCC_A2 %B 2 1 3 ! 36: CONST BCC_A2 : B TI% : VA : !
TiB-11Cac.tdb: BCC_A2, type code %B, sha256 4e632683d15fe800…
36: PHASE BCC_A2 %B 2 1 3 ! 37: CONST BCC_A2 : TI% : B VA% : !
TiB-16Wit.tdb: BCC_A2, type code %B, sha256 f17559a1695b8573…
34: PHASE BCC_A2 %B 2 1 3 ! 35: CONST BCC_A2 : TI% : B VA% : !
TiB-19Wit.tdb: BCC_A2, type code %B, sha256 13ea870c397a4aba…
34: PHASE BCC_A2 %B 2 1 3 ! 35: CONST BCC_A2 : TI% : B VA% : !
TiB-94Bat-LB.tdb: BCC_A2, type code %B, sha256 0fb6180a65bd872e…
32: PHASE BCC_A2 %B 2 1 3 ! 33: CONST BCC_A2 : TI% : B VA% : !
Example references (7 of 7; assessments first):
- doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase - doi:10.1007/bf02646248 H. Duschanek, P. Rogl, H. L. Lukas, A critical assessment and thermodynamic calculation of the boron-carbon-titanium (B-C-Ti) ternary system, JPE 16, 46-60 (1995).
reports values for this phase
MB2_C32 (B–Ti)
- Id:
phase:b-ti:c32-mb2; statusassigned - Structure: AlB2 · C32 · hP3 · P6/mmm (191); type
st:c32-alb2-hp3; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: DFT agrees: on-hull mp-aaaaabsb and oqmd-5808, space group 191
- Caveat: not certain from the name or DFT alone (unrecognised_name_tokens:MB2); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: B 0.6667, Ti 0.3333
- Stability: stable in 1 of 1 calculated diagram(s): 300–3488.99 K, x(B) 0.66667–0.66667
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (4): corpus: corpus:phase:b-ti:c32-mb2
mp: mp:mp-aaaaabsb
oqmd: oqmd:oqmd-5808
tdb: tdb:TiB-94Bat-LB.tdb:MB2_C32
TDB models of MB2_C32 (1): PHASE and CONSTITUENT statements as written
TiB-94Bat-LB.tdb: MB2_C32, type code %, sha256 0fb6180a65bd872e…
57: PHASE MB2_C32 % 2 1 2 ! 58: CONST MB2_C32 : TI : B : !
FCC_A1 (B–Ti)
- Id:
phase:b-ti:fcc-a1; statusassigned - Structure: Cu · A1 · cF4 · Fm-3m (225); type
st:a1-cu-cf4; tier A: standard phase name; confidence high - Stability: not stable in 7 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (8): corpus: corpus:phase:b-ti:fcc-a1
tdb: tdb:TiB-04Ma.tdb:FCC_A1, tdb:TiB-08Wit.tdb:FCC_A1, tdb:TiB-09Nak.tdb:FCC_A1, tdb:TiB-11Cac.tdb:FCC_A1, tdb:TiB-16Wit.tdb:FCC_A1, tdb:TiB-19Wit.tdb:FCC_A1, tdb:TiB-94Bat-LB.tdb:FCC_A1
TDB models of FCC_A1 (7): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: FCC_A1, type code %A, sha256 1bea624752196864…
31: PHASE FCC_A1 %A 2 1 1 ! 32: CONST FCC_A1 : TI : B VA% : !
TiB-08Wit.tdb: FCC_A1, type code %A, sha256 1d8367fa30ef15c2…
29: PHASE FCC_A1 %A 2 1 1 ! 30: CONST FCC_A1 : TI : B VA% : !
TiB-09Nak.tdb: FCC_A1, type code %A, sha256 1b4af84d09dba0c7…
30: PHASE FCC_A1 %A 2 1 1 ! 31: CONST FCC_A1 : B TI : VA : !
TiB-11Cac.tdb: FCC_A1, type code %A, sha256 4e632683d15fe800…
31: PHASE FCC_A1 %A 2 1 1 ! 32: CONST FCC_A1 : TI : B VA% : !
TiB-16Wit.tdb: FCC_A1, type code %A, sha256 f17559a1695b8573…
29: PHASE FCC_A1 %A 2 1 1 ! 30: CONST FCC_A1 : TI : B VA% : !
TiB-19Wit.tdb: FCC_A1, type code %A, sha256 13ea870c397a4aba…
29: PHASE FCC_A1 %A 2 1 1 ! 30: CONST FCC_A1 : TI : B VA% : !
TiB-94Bat-LB.tdb: FCC_A1, type code %A, sha256 0fb6180a65bd872e…
27: PHASE FCC_A1 %A 2 1 1 ! 28: CONST FCC_A1 : TI : B VA% : !
Example references (6 of 6; assessments first):
- doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase - doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase - doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase
HCP_A3 (B–Ti)
- Id:
phase:b-ti:hcp-a3; statusassigned - Structure: Mg · A3 · hP2 · P6_3/mmc (194); type
st:a3-mg-hp2; tier A: standard phase name; confidence high - Stability: stable in 7 of 7 calculated diagram(s): 300–1157.68 K, x(B) 0–0.00164
- Literature: 6 values (6 accepted) from 3 papers
- Interactive: phase registry entry
Names (11): corpus: corpus:phase:b-ti:hcp-a3
paper: paper:10.1016/j.jallcom.2003.09.017:(αTi), paper:10.1016/j.jallcom.2006.10.034:hcp, paper:sha256-85fd53a1a176b694:hcp-A3
tdb: tdb:TiB-04Ma.tdb:HCP_A3, tdb:TiB-08Wit.tdb:HCP_A3, tdb:TiB-09Nak.tdb:HCP_A3, tdb:TiB-11Cac.tdb:HCP_A3, tdb:TiB-16Wit.tdb:HCP_A3, tdb:TiB-19Wit.tdb:HCP_A3, tdb:TiB-94Bat-LB.tdb:HCP_A3
TDB models of HCP_A3 (7): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: HCP_A3, type code %A, sha256 1bea624752196864…
41: PHASE HCP_A3 %A 2 1 0.5 ! 42: CONST HCP_A3 : TI% : B VA% : !
TiB-08Wit.tdb: HCP_A3, type code %A, sha256 1d8367fa30ef15c2…
39: PHASE HCP_A3 %A 2 1 0.5 ! 40: CONST HCP_A3 : TI% : B VA% : !
TiB-09Nak.tdb: HCP_A3, type code %A, sha256 1b4af84d09dba0c7…
40: PHASE HCP_A3 %A 2 1 0.5 ! 41: CONST HCP_A3 : B TI% : VA : !
TiB-11Cac.tdb: HCP_A3, type code %A, sha256 4e632683d15fe800…
41: PHASE HCP_A3 %A 2 1 0.5 ! 42: CONST HCP_A3 : TI% : B VA% : !
TiB-16Wit.tdb: HCP_A3, type code %A, sha256 f17559a1695b8573…
39: PHASE HCP_A3 %A 2 1 0.5 ! 40: CONST HCP_A3 : TI% : B VA% : !
TiB-19Wit.tdb: HCP_A3, type code %A, sha256 13ea870c397a4aba…
39: PHASE HCP_A3 %A 2 1 0.5 ! 40: CONST HCP_A3 : TI% : B VA% : !
TiB-94Bat-LB.tdb: HCP_A3, type code %A, sha256 0fb6180a65bd872e…
37: PHASE HCP_A3 %A 2 1 0.5 ! 38: CONST HCP_A3 : TI% : B VA% : !
Example references (6 of 6; assessments first):
- doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase
LIQUID (B–Ti)
- Id:
phase:b-ti:liquid; statusassigned - Structure: liquid; type
st:liquid; liquid; confidence high - Stability: stable in 7 of 7 calculated diagram(s): 1780–4000 K, x(B) 0–1
- Literature: 64 values (63 accepted) from 5 papers
- Interactive: phase registry entry
Names (14): corpus: corpus:phase:b-ti:liquid
paper: paper:10.1007/bf02646757:L, paper:10.1016/j.calphad.2011.10.003:L, paper:10.1016/j.jallcom.2003.09.017:L, paper:10.1016/j.jallcom.2003.09.017:liquid, paper:10.1016/j.jallcom.2006.10.034:L, paper:sha256-85fd53a1a176b694:Liquid
tdb: tdb:TiB-04Ma.tdb:LIQUID, tdb:TiB-08Wit.tdb:LIQUID, tdb:TiB-09Nak.tdb:LIQUID, tdb:TiB-11Cac.tdb:LIQUID, tdb:TiB-16Wit.tdb:LIQUID, tdb:TiB-19Wit.tdb:LIQUID, tdb:TiB-94Bat-LB.tdb:LIQUID
TDB models of LIQUID (7): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: LIQUID, type code %, sha256 1bea624752196864…
26: PHASE LIQUID:L % 1 1 ! 27: CONST LIQUID:L : B TI : !
TiB-08Wit.tdb: LIQUID, type code %, sha256 1d8367fa30ef15c2…
24: PHASE LIQUID:L % 1 1 ! 25: CONST LIQUID:L : B TI : !
TiB-09Nak.tdb: LIQUID, type code %, sha256 1b4af84d09dba0c7…
25: PHASE LIQUID:L % 1 1 ! 26: CONST LIQUID:L : B TI : !
TiB-11Cac.tdb: LIQUID, type code %, sha256 4e632683d15fe800…
26: PHASE LIQUID:L % 1 1 ! 27: CONST LIQUID:L : B TI : !
TiB-16Wit.tdb: LIQUID, type code %, sha256 f17559a1695b8573…
24: PHASE LIQUID:L % 1 1 ! 25: CONST LIQUID:L : B TI : !
TiB-19Wit.tdb: LIQUID, type code %, sha256 13ea870c397a4aba…
24: PHASE LIQUID:L % 1 1 ! 25: CONST LIQUID:L : B TI : !
TiB-94Bat-LB.tdb: LIQUID, type code %, sha256 0fb6180a65bd872e…
22: PHASE LIQUID:L % 1 1 ! 23: CONST LIQUID:L : B TI : !
Example references (10 of 10; assessments first):
- doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase - doi:10.1002/zaac.19522680308 R. Kieffer, F. Benesovsky, E. R. Honak, Über ein neues Verfahren zur Herstellung von Metallboriden der Übergangsmetalle, insbesondere von Titan‐und Zirkonborid, Zeitschrift anorg allge chemie 268, 191-200 (1952).
cited as the source of values for this phase - doi:10.1007/bf02646757 H. Bittermann, P. Rogl, Critical assessment and thermodynamic calculation of the ternary system boron-hafnium-titanium (B-Hf-Ti), JPE 18, 24-47 (1997).
reports values for this phase - doi:10.1016/0001-6160(54)90090-5 Benjamin Post, Frank W. Glaser, David Moskowitz, Transition metal diborides, Acta Metallurgica 2, 20-25 (1954).
cited as the source of values for this phase - doi:10.1116/1.573700 H. Holleck, Material selection for hard coatings, Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 4, 2661-2669 (1986).
cited as the source of values for this phase
TI3B4_D7B (B–Ti)
- Id:
phase:b-ti:ti3b4-d7b; statusassigned - Structure: Ta3B4 · D7_b · oI14 · Immm (71); type
st:d7-b-ta3b4-oi14; tier A: standard phase name; confidence high - Caveat: DFT agrees: on-hull mp-aaacginq and oqmd-28622, space group 71
- Stoichiometry: B 0.5714, Ti 0.4286
- Stability: stable in 7 of 7 calculated diagram(s): 300–2481.63 K, x(B) 0.57143–0.57143
- Literature: 19 values (19 accepted) from 5 papers
- Interactive: phase registry entry
Names (15): corpus: corpus:phase:b-ti:ti3b4-d7b
mp: mp:mp-aaacginq
oqmd: oqmd:oqmd-28622
paper: paper:10.1016/j.calphad.2011.10.003:Ti3B4, paper:10.1016/j.jallcom.2003.09.017:Ti3B4, paper:10.1016/j.jallcom.2006.10.034:Ti3B4, paper:10.2320/matertrans.mc200820:Ti3B4, paper:sha256-85fd53a1a176b694:B4Ti3
tdb: tdb:TiB-04Ma.tdb:TI3B4_D7B, tdb:TiB-08Wit.tdb:TI3B4_D7B, tdb:TiB-09Nak.tdb:TI3B4_D7B, tdb:TiB-11Cac.tdb:TI3B4_D7B, tdb:TiB-16Wit.tdb:TI3B4_D7B, tdb:TiB-19Wit.tdb:TI3B4_D7B, tdb:TiB-94Bat-LB.tdb:TI3B4_D7B
TDB models of TI3B4_D7B (7): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: TI3B4_D7B, type code %, sha256 1bea624752196864…
56: PHASE TI3B4_D7B % 2 3 4 ! 57: CONST TI3B4_D7B : TI : B : !
TiB-08Wit.tdb: TI3B4_D7B, type code %, sha256 1d8367fa30ef15c2…
54: PHASE TI3B4_D7B % 2 3 4 ! 55: CONST TI3B4_D7B : TI : B : !
TiB-09Nak.tdb: TI3B4_D7B, type code %, sha256 1b4af84d09dba0c7…
55: PHASE TI3B4_D7B % 2 3 4 ! 56: CONST TI3B4_D7B : TI : B : !
TiB-11Cac.tdb: TI3B4_D7B, type code %, sha256 4e632683d15fe800…
56: PHASE TI3B4_D7B % 2 3 4 ! 57: CONST TI3B4_D7B : TI : B : !
TiB-16Wit.tdb: TI3B4_D7B, type code %, sha256 f17559a1695b8573…
54: PHASE TI3B4_D7B % 2 3 4 ! 55: CONST TI3B4_D7B : TI : B : !
TiB-19Wit.tdb: TI3B4_D7B, type code %, sha256 13ea870c397a4aba…
54: PHASE TI3B4_D7B % 2 3 4 ! 55: CONST TI3B4_D7B : TI : B : !
TiB-94Bat-LB.tdb: TI3B4_D7B, type code %, sha256 0fb6180a65bd872e…
52: PHASE TI3B4_D7B % 2 3 4 ! 53: CONST TI3B4_D7B : TI : B : !
Example references (7 of 7; assessments first):
- doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase; reports values for this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.1016/j.jallcom.2007.02.030 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 456, 143-150 (2008).
cited as the source of values for this phase
TIB_B27 (B–Ti)
- Id:
phase:b-ti:tib-b27; statusassigned - Structure: FeB · B27 · oP8 · Pnma (62); type
st:b27-feb-op8; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model, structure_token_is_also_a_formula); structure as stated in the SGTE crystallographic table for this phase name and system
- Stability: stable in 5 of 5 calculated diagram(s): 300–2459.71 K, x(B) 0.48221–0.5
- Literature: 32 values (32 accepted) from 4 papers
- Interactive: phase registry entry
Names (10): corpus: corpus:phase:b-ti:tib-b27
paper: paper:10.1016/j.jallcom.2003.09.017:TiB, paper:10.1016/j.jallcom.2006.10.034:TiB, paper:10.2320/matertrans.mc200820:TiB, paper:sha256-85fd53a1a176b694:BTi
tdb: tdb:TiB-04Ma.tdb:TIB_B27, tdb:TiB-08Wit.tdb:TIB_B27, tdb:TiB-09Nak.tdb:TIB_B27, tdb:TiB-16Wit.tdb:TIB_B27, tdb:TiB-19Wit.tdb:TIB_B27
TDB models of TIB_B27 (5): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: TIB_B27, type code %, sha256 1bea624752196864…
51: PHASE TIB_B27 % 2 1 1 ! 52: CONST TIB_B27 : TI : B% TI : !
TiB-08Wit.tdb: TIB_B27, type code %, sha256 1d8367fa30ef15c2…
49: PHASE TIB_B27 % 2 1 1 ! 50: CONST TIB_B27 : TI : B% TI : !
TiB-09Nak.tdb: TIB_B27, type code %, sha256 1b4af84d09dba0c7…
50: PHASE TIB_B27 % 2 1 1 ! 51: CONST TIB_B27 : TI : B : !
TiB-16Wit.tdb: TIB_B27, type code %, sha256 f17559a1695b8573…
49: PHASE TIB_B27 % 2 1 1 ! 50: CONST TIB_B27 : TI : B% TI : !
TiB-19Wit.tdb: TIB_B27, type code %, sha256 13ea870c397a4aba…
49: PHASE TIB_B27 % 2 1 1 ! 50: CONST TIB_B27 : B TI% : B% TI : !
Example references (7 of 7; assessments first):
- doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.1021/j100814a027 P. O. Schissel, O. C. Trulson, MASS SPECTROMETRIC STUDY OF THE VAPORIZATION OF THE TITANIUM-BORON SYSTEM<sup>1</sup>, J. Phys. Chem. 66, 1492-1496 (1962).
cited as the source of values for this phase - doi:10.1016/j.jallcom.2007.02.030 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 456, 143-150 (2008).
cited as the source of values for this phase
TIB2_C32 (B–Ti)
- Id:
phase:b-ti:tib2-c32; statusassigned - Structure: AlB2 · C32 · hP3 · P6/mmm (191); type
st:c32-alb2-hp3; tier A: standard phase name; confidence high - Caveat: partitioned order/disorder model in TiB-04Ma.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in TiB-08Wit.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in TiB-16Wit.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in TiB-19Wit.tdb also describes the disordered state
- Stability: stable in 6 of 6 calculated diagram(s): 300–3496.05 K, x(B) 0.63954–0.6769
- Literature: 48 values (48 accepted) from 5 papers
- Interactive: phase registry entry
Names (12): corpus: corpus:phase:b-ti:tib2-c32
paper: paper:10.1016/j.calphad.2011.10.003:TiB2, paper:10.1016/j.jallcom.2003.09.017:TiB2, paper:10.1016/j.jallcom.2006.10.034:TiB2, paper:10.2320/matertrans.mc200820:TiB2, paper:sha256-85fd53a1a176b694:B2Ti
tdb: tdb:TiB-04Ma.tdb:TIB2_C32, tdb:TiB-08Wit.tdb:TIB2_C32, tdb:TiB-09Nak.tdb:TIB2_C32, tdb:TiB-11Cac.tdb:TIB2_C32, tdb:TiB-16Wit.tdb:TIB2_C32, tdb:TiB-19Wit.tdb:TIB2_C32
TDB models of TIB2_C32 (6): PHASE and CONSTITUENT statements as written
TiB-04Ma.tdb: TIB2_C32, type code %, sha256 1bea624752196864…
61: PHASE TIB2_C32 % 2 1 2 ! 62: CONST TIB2_C32 : B TI% : B% TI : !
TiB-08Wit.tdb: TIB2_C32, type code %, sha256 1d8367fa30ef15c2…
59: PHASE TIB2_C32 % 2 1 2 ! 60: CONST TIB2_C32 : B TI% : B% TI : !
TiB-09Nak.tdb: TIB2_C32, type code %, sha256 1b4af84d09dba0c7…
60: PHASE TIB2_C32 % 2 1 2 ! 61: CONST TIB2_C32 : TI% VA : B% VA : !
TiB-11Cac.tdb: TIB2_C32, type code %, sha256 4e632683d15fe800…
61: PHASE TIB2_C32 % 2 1 2 ! 62: CONST TIB2_C32 : TI VA : B : !
TiB-16Wit.tdb: TIB2_C32, type code %, sha256 f17559a1695b8573…
59: PHASE TIB2_C32 % 2 1 2 ! 60: CONST TIB2_C32 : B TI% : B% TI : !
TiB-19Wit.tdb: TIB2_C32, type code %, sha256 13ea870c397a4aba…
59: PHASE TIB2_C32 % 2 1 2 ! 60: CONST TIB2_C32 : B TI% : B% TI : !
Example references (10 of 13; assessments first):
- doi:10.1016/j.jallcom.2003.09.017 Xiaoyan Ma, Changrong Li, Zhenmin Du, Weijing Zhang, Thermodynamic assessment of the Ti–B system, Journal of Alloys and Compounds 370, 149-158 (2004).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase - doi:10.1016/j.jallcom.2006.10.034 V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 448, 185-194 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/j.calphad.2011.10.003 G. Cacciamani, P. Riani, F. Valenza, Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system, Calphad 35, 601-619 (2011).
assessment that models this phase; reports values for this phase - doi:10.2320/matertrans.MC200820 Y. Nakama, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 50, 984-93(2009).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2015.09.158 V.T. Witusiewicz, A.A. Bondar, U. Hecht, O.A. Potazhevska, T.Ya Velikanova, Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description, Journal of Alloys and Compounds 655, 336-352 (2016).
assessment that models this phase - doi:10.1016/j.jallcom.2019.05.341 V.T. Witusiewicz, A.A. Bondar, U. Hecht, A. Theofilatos, N.I. Tsyganenko, S.V. Utkin et al., Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system, Journal of Alloys and Compounds 800, 419-449 (2019).
assessment that models this phase - doi:10.1002/zaac.19522680308 R. Kieffer, F. Benesovsky, E. R. Honak, Über ein neues Verfahren zur Herstellung von Metallboriden der Übergangsmetalle, insbesondere von Titan‐und Zirkonborid, Zeitschrift anorg allge chemie 268, 191-200 (1952).
cited as the source of values for this phase - doi:10.1016/0001-6160(54)90090-5 Benjamin Post, Frank W. Glaser, David Moskowitz, Transition metal diborides, Acta Metallurgica 2, 20-25 (1954).
cited as the source of values for this phase - doi:10.1016/0042-207x(95)00080-1 L Guzman, M Elena, A Miotello, PM Ossi, DC Kothari, Phase formation in the N-B-Ti system, Vacuum 46, 951-954 (1995).
cited as the source of values for this phase - doi:10.1021/j100814a027 P. O. Schissel, O. C. Trulson, MASS SPECTROMETRIC STUDY OF THE VAPORIZATION OF THE TITANIUM-BORON SYSTEM<sup>1</sup>, J. Phys. Chem. 66, 1492-1496 (1962).
cited as the source of values for this phase