# Co–Sn phases

> Co–Sn system: 13 phases (tier A 7, tier C 4, liquid 1, needs_review 1); 11 stable in a calculated diagram in the ORCHID phase registry, with names, structure type when the stored evidence supports an assignment under the stated tier rules, calculated stability, verbatim TDB PHASE/CONSTITUENT statements and example references.

HTML: https://data.orchid-project.org/phases/pages/CO-SN.html · Markdown: https://data.orchid-project.org/phases/pages/CO-SN.md

13 phases (tier A 7, tier C 4, liquid 1, needs_review 1); 11 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: [interactive registry](https://orchid-project.org/phases/?q=CO-SN) · [full JSON](https://data.orchid-project.org/phases/systems/CO-SN.json) · [Co–Sn system page](https://data.orchid-project.org/systems/CO-SN.html) · [Markdown](https://data.orchid-project.org/phases/pages/CO-SN.md) · [field reference](https://data.orchid-project.org/phases/SCHEMA.md)

Table: Phases of the Co–Sn system (13)

| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---:|---:|
| [DIAMOND_A4](#phase-co-sn-a4-diamond); _phase:co-sn:a4-diamond_ | C (diamond) · A4 · cF8 · Fd-3m (227) | tier A: standard phase name | not stable in 4 calculated diagram(s) | 0 | 4 |
| [BCT_A5](#phase-co-sn-a5-bct); _phase:co-sn:a5-bct_ | beta-Sn · A5 · tI4 · I4_1/amd (141) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 300–505.08 K, x(Sn) 1–1 | 7 | 4 |
| [BCC_A2](#phase-co-sn-bcc-a2); _phase:co-sn:bcc-a2_ | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | not stable in 4 calculated diagram(s) | 0 | 4 |
| [CO3SN2_ALPHA](#phase-co-sn-co3sn2-alpha); _phase:co-sn:co3sn2-alpha_ | Ni3Sn2 · oP20 · Pnma (62) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 2 of 2 calculated diagram(s): 300–847.44 K, x(Sn) 0.4–0.4 | 9 | 2 |
| [CO3SN2_B82](#phase-co-sn-co3sn2-b82); _phase:co-sn:co3sn2-b82_ |  | needs_review | stable in 4 of 4 calculated diagram(s): 300–1472.42 K, x(Sn) 0.38645–0.41738 | 42 | 4 |
| [COSN_B35](#phase-co-sn-cosn-b35); _phase:co-sn:cosn-b35_ | CoSn · B35 · hP6 · P6/mmm (191) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 300–1240.16 K, x(Sn) 0.5–0.5 | 24 | 4 |
| [COSN2_C16](#phase-co-sn-cosn2-c16); _phase:co-sn:cosn2-c16_ | Al2Cu · C16 · tI12 · I4/mcm (140) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 300–848.39 K, x(Sn) 0.66667–0.66667 | 21 | 4 |
| [COSN3](#phase-co-sn-cosn3); _phase:co-sn:cosn3_ | PdSn3 · oC32 · Cmce (64) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 2 of 2 calculated diagram(s): 300–623.87 K, x(Sn) 0.75–0.75 | 7 | 2 |
| [COSN3_HT](#phase-co-sn-cosn3-ht); _phase:co-sn:cosn3-ht_ | CoSn3 · tI64 · I4_1/acd (142) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 547.79–650 K, x(Sn) 0.75–0.75 | 2 | 1 |
| [COSN3_LT](#phase-co-sn-cosn3-lt); _phase:co-sn:cosn3-lt_ | PdSn3 · oC32 · Cmce (64) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 300–547.79 K, x(Sn) 0.75–0.75 | 0 | 1 |
| [FCC_A1](#phase-co-sn-fcc-a1); _phase:co-sn:fcc-a1_ | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 370–1775.94 K, x(Sn) 0–0.02715 | 18 | 4 |
| [HCP_A3](#phase-co-sn-hcp-a3); _phase:co-sn:hcp-a3_ | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 300–696.99 K, x(Sn) 0–0.00061 | 5 | 4 |
| [LIQUID](#phase-co-sn-liquid); _phase:co-sn:liquid_ | liquid | liquid | stable in 4 of 4 calculated diagram(s): 501.01–2500 K, x(Sn) 0–1 | 54 | 4 |

## DIAMOND_A4 (Co–Sn)

- Id: `phase:co-sn:a4-diamond`; status `assigned`
- Structure: C (diamond) · A4 · cF8 · Fd-3m (227); type `st:a4-c-diamond-cf8`; tier A: standard phase name; confidence high
- Stoichiometry: Sn 1.0000
- Stability: not stable in 4 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:a4-diamond)

Names (5): _corpus: _corpus:phase:co-sn:a4-diamond  
_tdb: _tdb:CoSn-04Jia.tdb:DIAMOND_A4, tdb:CoSn-04Liu.tdb:DIAMOND_A4, tdb:CoSn-09Don.tdb:DIAMOND_A4, tdb:CoSn-19Jed.tdb:DIAMOND_A4  


### TDB models of DIAMOND_A4 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): DIAMOND_A4, type code %, sha256 `a10dd23f7f82a2c4…`

~~~~text
50: PHASE DIAMOND_A4 % 1 1 !
51: CONST DIAMOND_A4 : SN : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): DIAMOND_A4, type code %, sha256 `61b66e699771d1e4…`

~~~~text
43: PHASE DIAMOND_A4 % 1 1 !
44: CONST DIAMOND_A4 : SN : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): DIAMOND_A4, type code %, sha256 `df75c146f15affde…`

~~~~text
51: PHASE DIAMOND_A4 % 1 1 !
52: CONST DIAMOND_A4 : SN : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): DIAMOND_A4, type code %, sha256 `a1f1c360881522fd…`

~~~~text
40: PHASE DIAMOND_A4 % 1 1 !
41: CONST DIAMOND_A4 : SN : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase_
- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase_

## BCT_A5 (Co–Sn)

- Id: `phase:co-sn:a5-bct`; status `assigned`
- Structure: beta-Sn · A5 · tI4 · I4_1/amd (141); type `st:a5-beta-sn-ti4`; tier A: standard phase name; confidence high
- Stoichiometry: Sn 1.0000
- Stability: stable in 4 of 4 calculated diagram(s): 300–505.08 K, x(Sn) 1–1
- Literature: 7 values (7 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:a5-bct)

Names (8): _corpus: _corpus:phase:co-sn:a5-bct, corpus:phase:co-sn:bct-a5  
_paper: _paper:10.1007/s11664-004-0019-8:(Sn), paper:10.1016/j.calphad.2004.08.001:(βSn)  
_tdb: _tdb:CoSn-04Jia.tdb:BCT_A5, tdb:CoSn-04Liu.tdb:BCT_A5, tdb:CoSn-09Don.tdb:BCT_A5, tdb:CoSn-19Jed.tdb:BCT_A5  


### TDB models of BCT_A5 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): BCT_A5, type code %, sha256 `a10dd23f7f82a2c4…`

~~~~text
55: PHASE BCT_A5 % 1 1 !
56: CONST BCT_A5 : SN : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): BCT_A5, type code %, sha256 `61b66e699771d1e4…`

~~~~text
48: PHASE BCT_A5 % 1 1 !
49: CONST BCT_A5 : SN : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): BCT_A5, type code %, sha256 `df75c146f15affde…`

~~~~text
56: PHASE BCT_A5 % 1 1 !
57: CONST BCT_A5 : SN : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): BCT_A5, type code %, sha256 `a1f1c360881522fd…`

~~~~text
45: PHASE BCT_A5 % 1 1 !
46: CONST BCT_A5 : SN : !
~~~~

Example references (6 of 6; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19080590133](https://doi.org/10.1002/zaac.19080590133) S. F. Żemcżużny, S. W. Belynsky, Kobalt‐Zinnlegierungen, Z. Anorg. Chem. 59, 364-370 (1908).  
_cited as the source of values for this phase_

## BCC_A2 (Co–Sn)

- Id: `phase:co-sn:bcc-a2`; status `assigned`
- Structure: W · A2 · cI2 · Im-3m (229); type `st:a2-w-ci2`; tier A: standard phase name; confidence high
- Stability: not stable in 4 calculated diagram(s)
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:bcc-a2)

Names (5): _corpus: _corpus:phase:co-sn:bcc-a2  
_tdb: _tdb:CoSn-04Jia.tdb:BCC_A2, tdb:CoSn-04Liu.tdb:BCC_A2, tdb:CoSn-09Don.tdb:BCC_A2, tdb:CoSn-19Jed.tdb:BCC_A2  


### TDB models of BCC_A2 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): BCC_A2, type code %B, sha256 `a10dd23f7f82a2c4…`

~~~~text
40: PHASE BCC_A2 %B 2 1 3 !
41: CONST BCC_A2 : CO SN : VA : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): BCC_A2, type code %B, sha256 `61b66e699771d1e4…`

~~~~text
33: PHASE BCC_A2 %B 2 1 3 !
34: CONST BCC_A2 : CO SN : VA : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): BCC_A2, type code %B, sha256 `df75c146f15affde…`

~~~~text
41: PHASE BCC_A2 %B 2 1 3 !
42: CONST BCC_A2 : CO SN : VA : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): BCC_A2, type code %B, sha256 `a1f1c360881522fd…`

~~~~text
30: PHASE BCC_A2 %B 2 1 3 !
31: CONST BCC_A2 : CO SN : VA : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase_
- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase_

## CO3SN2_ALPHA (Co–Sn)

- Id: `phase:co-sn:co3sn2-alpha`; status `assigned`
- Structure: Ni3Sn2 · oP20 · Pnma (62); type `st:ni3sn2-op20`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.6000, Sn 0.4000
- Stability: stable in 2 of 2 calculated diagram(s): 300–847.44 K, x(Sn) 0.4–0.4
- Literature: 9 values (9 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:co3sn2-alpha)

Names (5): _corpus: _corpus:phase:co-sn:co3sn2-alpha  
_paper: _paper:10.1007/s11664-004-0019-8:Co3Sn2_alfa, paper:10.1007/s11669-018-0687-3:α-Co3Sn2  
_tdb: _tdb:CoSn-04Liu.tdb:CO3SN2_ALPHA, tdb:CoSn-19Jed.tdb:CO3SN2_ALPHA  


### TDB models of CO3SN2_ALPHA (2): PHASE and CONSTITUENT statements as written

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): CO3SN2_ALPHA, type code %, sha256 `61b66e699771d1e4…`

~~~~text
53: PHASE CO3SN2_ALPHA % 2 3 2 !
54: CONST CO3SN2_ALPHA : CO : SN : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): CO3SN2_ALPHA, type code %, sha256 `a1f1c360881522fd…`

~~~~text
50: PHASE CO3SN2_ALPHA % 2 3 2 !
51: CONST CO3SN2_ALPHA : CO : SN : !
~~~~

Example references (3 of 3; assessments first): 

- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_

## CO3SN2_B82 (Co–Sn)

- Id: `phase:co-sn:co3sn2-b82`; status `needs_review`
- No structure assigned. Why: assessment_declared_blocked_by:stoichiometry_contradicts_B8_2; stoichiometry_contradicts_B8_2:CoSn-04Liu.tdb
- Candidate (literature_printed): InNi2 · hP6 — printed with a label mapped to this phase
- Candidate (name_token): InNi2 · B8_2 · hP6 · P6_3/mmc (194) — Strukturbericht/word 'B82' in the TDB name
- Candidate (sgte_mmc2): InNi2 · B8_2 · hP6 · P6_3/mmc (194) — Hallstedt 2025 mmc2 row for CO3SN2_B82: Co3Sn2
- Candidate (sgte_mmc2): InNi2 · B8_2 · hP6 · P6_3/mmc (194) — Hallstedt 2025 mmc2 row for CO3SN2_B82: Co3Sn2 (high T)
- Candidate (tdb_comment): InNi2 · hP6 · P6_3/mmc, B8_2 — CoSn-04Jia.tdb: 'Prototype InNi2 (hP6, P6_3/mmc, B8_2), beta'
- Candidate (tdb_comment): InNi2 · hP6 · P6_3/mmc — CoSn-04Liu.tdb: 'Prototype InNi2 (hP6, P6_3/mmc), beta'
- Candidate (tdb_comment): InNi2 · hP6 · P6_3/mmc, B8_2 — CoSn-09Don.tdb: 'Prototype InNi2 (hP6, P6_3/mmc, B8_2), beta'
- Candidate (tdb_comment): InNi2 · hP6 · P6_3/mmc — CoSn-19Jed.tdb: 'Prototype InNi2 (hP6, P6_3/mmc), beta'
- Stability: stable in 4 of 4 calculated diagram(s): 300–1472.42 K, x(Sn) 0.38645–0.41738
- Literature: 42 values (42 accepted) from 3 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:co3sn2-b82)

Names (9): _corpus: _corpus:phase:co-sn:co3sn2-b82  
_paper: _paper:10.1007/s11664-004-0019-8:Co3Sn2_beta, paper:10.1007/s11669-018-0687-3:β-Co3Sn2, paper:10.1016/j.calphad.2004.08.001:αCo3Sn2, paper:10.1016/j.calphad.2004.08.001:βCo3Sn2  
_tdb: _tdb:CoSn-04Jia.tdb:CO3SN2_B82, tdb:CoSn-04Liu.tdb:CO3SN2_B82, tdb:CoSn-09Don.tdb:CO3SN2_B82, tdb:CoSn-19Jed.tdb:CO3SN2_B82  


### TDB models of CO3SN2_B82 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): CO3SN2_B82, type code %, sha256 `a10dd23f7f82a2c4…`

~~~~text
62: PHASE CO3SN2_B82 % 4 1 1 0.5 0.5 !
63: CONST CO3SN2_B82 : CO : SN : CO VA : CO VA : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): CO3SN2_B82, type code %, sha256 `61b66e699771d1e4…`

~~~~text
58: PHASE CO3SN2_B82 % 2 3 2 !
59: CONST CO3SN2_B82 : CO : SN : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): CO3SN2_B82, type code %, sha256 `df75c146f15affde…`

~~~~text
63: PHASE CO3SN2_B82 % 4 1 1 0.5 0.5 !
64: CONST CO3SN2_B82 : CO : SN : CO VA : CO VA : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): CO3SN2_B82, type code %, sha256 `a1f1c360881522fd…`

~~~~text
55: PHASE CO3SN2_B82 % 3 1 1 1 !
56: CONST CO3SN2_B82 : CO VA : CO VA : SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_
- [doi:10.1007/bf02658043](https://doi.org/10.1007/bf02658043) H. Cömert, J. N. Pratt, Constitutional studies of cobalt-tin alloys, Metall Trans A 23, 2401-2407 (1992).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19080590133](https://doi.org/10.1002/zaac.19080590133) S. F. Żemcżużny, S. W. Belynsky, Kobalt‐Zinnlegierungen, Z. Anorg. Chem. 59, 364-370 (1908).  
_cited as the source of values for this phase_

## COSN_B35 (Co–Sn)

- Id: `phase:co-sn:cosn-b35`; status `assigned`
- Structure: CoSn · B35 · hP6 · P6/mmm (191); type `st:b35-cosn-hp6`; tier A: standard phase name; confidence high
- Caveat: DFT agrees: on-hull mp-aaaabejw and oqmd-9977, space group 191
- Stoichiometry: Co 0.5000, Sn 0.5000
- Stability: stable in 4 of 4 calculated diagram(s): 300–1240.16 K, x(Sn) 0.5–0.5
- Literature: 24 values (24 accepted) from 3 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:cosn-b35)

Names (10): _corpus: _corpus:phase:co-sn:cosn-b35  
_mp: _mp:mp-aaaabejw  
_oqmd: _oqmd:oqmd-9977  
_paper: _paper:10.1007/s11664-004-0019-8:CoSn, paper:10.1007/s11669-018-0687-3:CoSn, paper:10.1016/j.calphad.2004.08.001:CoSn  
_tdb: _tdb:CoSn-04Jia.tdb:COSN_B35, tdb:CoSn-04Liu.tdb:COSN_B35, tdb:CoSn-09Don.tdb:COSN_B35, tdb:CoSn-19Jed.tdb:COSN_B35  


### TDB models of COSN_B35 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): COSN_B35, type code %, sha256 `a10dd23f7f82a2c4…`

~~~~text
67: PHASE COSN_B35 % 2 1 1 !
68: CONST COSN_B35 : CO : SN : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): COSN_B35, type code %, sha256 `61b66e699771d1e4…`

~~~~text
63: PHASE COSN_B35 % 2 1 1 !
64: CONST COSN_B35 : CO : SN : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): COSN_B35, type code %, sha256 `df75c146f15affde…`

~~~~text
68: PHASE COSN_B35 % 2 1 1 !
69: CONST COSN_B35 : CO : SN : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): COSN_B35, type code %, sha256 `a1f1c360881522fd…`

~~~~text
60: PHASE COSN_B35 % 2 1 1 !
61: CONST COSN_B35 : CO : SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19080590133](https://doi.org/10.1002/zaac.19080590133) S. F. Żemcżużny, S. W. Belynsky, Kobalt‐Zinnlegierungen, Z. Anorg. Chem. 59, 364-370 (1908).  
_cited as the source of values for this phase_
- [doi:10.1007/bf02658043](https://doi.org/10.1007/bf02658043) H. Cömert, J. N. Pratt, Constitutional studies of cobalt-tin alloys, Metall Trans A 23, 2401-2407 (1992).  
_cited as the source of values for this phase_

## COSN2_C16 (Co–Sn)

- Id: `phase:co-sn:cosn2-c16`; status `assigned`
- Structure: Al2Cu · C16 · tI12 · I4/mcm (140); type `st:c16-al2cu-ti12`; tier A: standard phase name; confidence high
- Stoichiometry: Co 0.3333, Sn 0.6667
- Stability: stable in 4 of 4 calculated diagram(s): 300–848.39 K, x(Sn) 0.66667–0.66667
- Literature: 21 values (21 accepted) from 3 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:cosn2-c16)

Names (8): _corpus: _corpus:phase:co-sn:cosn2-c16  
_paper: _paper:10.1007/s11664-004-0019-8:CoSn2, paper:10.1007/s11669-018-0687-3:CoSn2, paper:10.1016/j.calphad.2004.08.001:CoSn2  
_tdb: _tdb:CoSn-04Jia.tdb:COSN2_C16, tdb:CoSn-04Liu.tdb:COSN2_C16, tdb:CoSn-09Don.tdb:COSN2_C16, tdb:CoSn-19Jed.tdb:COSN2_C16  


### TDB models of COSN2_C16 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): COSN2_C16, type code %, sha256 `a10dd23f7f82a2c4…`

~~~~text
72: PHASE COSN2_C16 % 2 1 2 !
73: CONST COSN2_C16 : CO : SN : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): COSN2_C16, type code %, sha256 `61b66e699771d1e4…`

~~~~text
68: PHASE COSN2_C16 % 2 1 2 !
69: CONST COSN2_C16 : CO : SN : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): COSN2_C16, type code %, sha256 `df75c146f15affde…`

~~~~text
73: PHASE COSN2_C16 % 2 1 2 !
74: CONST COSN2_C16 : CO : SN : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): COSN2_C16, type code %, sha256 `a1f1c360881522fd…`

~~~~text
65: PHASE COSN2_C16 % 2 1 2 !
66: CONST COSN2_C16 : CO : SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19080590133](https://doi.org/10.1002/zaac.19080590133) S. F. Żemcżużny, S. W. Belynsky, Kobalt‐Zinnlegierungen, Z. Anorg. Chem. 59, 364-370 (1908).  
_cited as the source of values for this phase_
- [doi:10.1007/bf02658043](https://doi.org/10.1007/bf02658043) H. Cömert, J. N. Pratt, Constitutional studies of cobalt-tin alloys, Metall Trans A 23, 2401-2407 (1992).  
_cited as the source of values for this phase_

## COSN3 (Co–Sn)

- Id: `phase:co-sn:cosn3`; status `assigned`
- Structure: PdSn3 · oC32 · Cmce (64); type `st:pdsn3-oc32`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.2500, Sn 0.7500
- Stability: stable in 2 of 2 calculated diagram(s): 300–623.87 K, x(Sn) 0.75–0.75
- Literature: 7 values (7 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:cosn3)

Names (5): _corpus: _corpus:phase:co-sn:cosn3  
_paper: _paper:10.1016/j.calphad.2004.08.001:αCoSn3, paper:10.1016/j.calphad.2004.08.001:βCoSn3  
_tdb: _tdb:CoSn-04Jia.tdb:COSN3, tdb:CoSn-09Don.tdb:COSN3  


### TDB models of COSN3 (2): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): COSN3, type code %, sha256 `a10dd23f7f82a2c4…`

~~~~text
77: PHASE COSN3 % 2 1 3 !
78: CONST COSN3 : CO : SN : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): COSN3, type code %, sha256 `df75c146f15affde…`

~~~~text
78: PHASE COSN3 % 2 1 3 !
79: CONST COSN3 : CO : SN : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1002/zaac.19080590133](https://doi.org/10.1002/zaac.19080590133) S. F. Żemcżużny, S. W. Belynsky, Kobalt‐Zinnlegierungen, Z. Anorg. Chem. 59, 364-370 (1908).  
_cited as the source of values for this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_

## COSN3_HT (Co–Sn)

- Id: `phase:co-sn:cosn3-ht`; status `assigned`
- Structure: CoSn3 · tI64 · I4_1/acd (142); type `st:cosn3-ti64`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.2500, Sn 0.7500
- Stability: stable in 1 of 1 calculated diagram(s): 547.79–650 K, x(Sn) 0.75–0.75
- Literature: 2 values (2 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:cosn3-ht)

Names (3): _corpus: _corpus:phase:co-sn:cosn3-ht  
_paper: _paper:10.1007/s11669-018-0687-3:β-CoSn3  
_tdb: _tdb:CoSn-19Jed.tdb:COSN3_HT  


### TDB models of COSN3_HT (1): PHASE and CONSTITUENT statements as written

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): COSN3_HT, type code %, sha256 `a1f1c360881522fd…`

~~~~text
75: PHASE COSN3_HT % 2 1 3 !
76: CONST COSN3_HT : CO : SN : !
~~~~

Example references (1 of 1; assessments first): 

- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_

## COSN3_LT (Co–Sn)

- Id: `phase:co-sn:cosn3-lt`; status `assigned`
- Structure: PdSn3 · oC32 · Cmce (64); type `st:pdsn3-oc32`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.2500, Sn 0.7500
- Stability: stable in 1 of 1 calculated diagram(s): 300–547.79 K, x(Sn) 0.75–0.75
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:cosn3-lt)

Names (2): _corpus: _corpus:phase:co-sn:cosn3-lt  
_tdb: _tdb:CoSn-19Jed.tdb:COSN3_LT  


### TDB models of COSN3_LT (1): PHASE and CONSTITUENT statements as written

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): COSN3_LT, type code %, sha256 `a1f1c360881522fd…`

~~~~text
70: PHASE COSN3_LT % 2 1 3 !
71: CONST COSN3_LT : CO : SN : !
~~~~

Example references (1 of 1; assessments first): 

- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase_

## FCC_A1 (Co–Sn)

- Id: `phase:co-sn:fcc-a1`; status `assigned`
- Structure: Cu · A1 · cF4 · Fm-3m (225); type `st:a1-cu-cf4`; tier A: standard phase name; confidence high
- Stability: stable in 4 of 4 calculated diagram(s): 370–1775.94 K, x(Sn) 0–0.02715
- Literature: 18 values (18 accepted) from 3 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:fcc-a1)

Names (8): _corpus: _corpus:phase:co-sn:fcc-a1  
_paper: _paper:10.1007/s11664-004-0019-8:FCC, paper:10.1007/s11669-018-0687-3:(α-Co), paper:10.1016/j.calphad.2004.08.001:(αCo)  
_tdb: _tdb:CoSn-04Jia.tdb:FCC_A1, tdb:CoSn-04Liu.tdb:FCC_A1, tdb:CoSn-09Don.tdb:FCC_A1, tdb:CoSn-19Jed.tdb:FCC_A1  


### TDB models of FCC_A1 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): FCC_A1, type code %A, sha256 `a10dd23f7f82a2c4…`

~~~~text
35: PHASE FCC_A1 %A 2 1 1 !
36: CONST FCC_A1 : CO% SN : VA : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): FCC_A1, type code %A, sha256 `61b66e699771d1e4…`

~~~~text
28: PHASE FCC_A1 %A 2 1 1 !
29: CONST FCC_A1 : CO% SN : VA : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): FCC_A1, type code %A, sha256 `df75c146f15affde…`

~~~~text
36: PHASE FCC_A1 %A 2 1 1 !
37: CONST FCC_A1 : CO% SN : VA : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): FCC_A1, type code %A, sha256 `a1f1c360881522fd…`

~~~~text
25: PHASE FCC_A1 %A 2 1 1 !
26: CONST FCC_A1 : CO% SN : VA : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_
- [doi:10.1007/bf02658043](https://doi.org/10.1007/bf02658043) H. Cömert, J. N. Pratt, Constitutional studies of cobalt-tin alloys, Metall Trans A 23, 2401-2407 (1992).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19080590133](https://doi.org/10.1002/zaac.19080590133) S. F. Żemcżużny, S. W. Belynsky, Kobalt‐Zinnlegierungen, Z. Anorg. Chem. 59, 364-370 (1908).  
_cited as the source of values for this phase_

## HCP_A3 (Co–Sn)

- Id: `phase:co-sn:hcp-a3`; status `assigned`
- Structure: Mg · A3 · hP2 · P6_3/mmc (194); type `st:a3-mg-hp2`; tier A: standard phase name; confidence high
- Stability: stable in 4 of 4 calculated diagram(s): 300–696.99 K, x(Sn) 0–0.00061
- Literature: 5 values (5 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:hcp-a3)

Names (7): _corpus: _corpus:phase:co-sn:hcp-a3  
_paper: _paper:10.1007/s11669-018-0687-3:(ε-Co), paper:10.1016/j.calphad.2004.08.001:(εCo)  
_tdb: _tdb:CoSn-04Jia.tdb:HCP_A3, tdb:CoSn-04Liu.tdb:HCP_A3, tdb:CoSn-09Don.tdb:HCP_A3, tdb:CoSn-19Jed.tdb:HCP_A3  


### TDB models of HCP_A3 (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): HCP_A3, type code %A, sha256 `a10dd23f7f82a2c4…`

~~~~text
45: PHASE HCP_A3 %A 2 1 0.5 !
46: CONST HCP_A3 : CO% SN : VA : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): HCP_A3, type code %A, sha256 `61b66e699771d1e4…`

~~~~text
38: PHASE HCP_A3 %A 2 1 0.5 !
39: CONST HCP_A3 : CO% SN : VA : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): HCP_A3, type code %A, sha256 `df75c146f15affde…`

~~~~text
46: PHASE HCP_A3 %A 2 1 0.5 !
47: CONST HCP_A3 : CO% SN : VA : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): HCP_A3, type code %A, sha256 `a1f1c360881522fd…`

~~~~text
35: PHASE HCP_A3 %A 2 1 0.5 !
36: CONST HCP_A3 : CO% SN : VA : !
~~~~

Example references (6 of 6; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/bf02658043](https://doi.org/10.1007/bf02658043) H. Cömert, J. N. Pratt, Constitutional studies of cobalt-tin alloys, Metall Trans A 23, 2401-2407 (1992).  
_cited as the source of values for this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_

## LIQUID (Co–Sn)

- Id: `phase:co-sn:liquid`; status `assigned`
- Structure: liquid; type `st:liquid`; liquid; confidence high
- Stability: stable in 4 of 4 calculated diagram(s): 501.01–2500 K, x(Sn) 0–1
- Literature: 54 values (54 accepted) from 3 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-sn:liquid)

Names (8): _corpus: _corpus:phase:co-sn:liquid  
_paper: _paper:10.1007/s11664-004-0019-8:L, paper:10.1007/s11669-018-0687-3:L, paper:10.1016/j.calphad.2004.08.001:L  
_tdb: _tdb:CoSn-04Jia.tdb:LIQUID, tdb:CoSn-04Liu.tdb:LIQUID, tdb:CoSn-09Don.tdb:LIQUID, tdb:CoSn-19Jed.tdb:LIQUID  


### TDB models of LIQUID (4): PHASE and CONSTITUENT statements as written

[CoSn-04Jia.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Jia.tdb): LIQUID, type code %, sha256 `a10dd23f7f82a2c4…`

~~~~text
30: PHASE LIQUID:L % 1 1 !
31: CONST LIQUID:L : CO SN : !
~~~~

[CoSn-04Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-04Liu.tdb): LIQUID, type code %, sha256 `61b66e699771d1e4…`

~~~~text
23: PHASE LIQUID:L % 1 1 !
24: CONST LIQUID:L : CO SN : !
~~~~

[CoSn-09Don.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-09Don.tdb): LIQUID, type code %, sha256 `df75c146f15affde…`

~~~~text
31: PHASE LIQUID:L % 1 1 !
32: CONST LIQUID:L : CO SN : !
~~~~

[CoSn-19Jed.tdb](https://orchid-project.org/data/databases/sgte-binary/CoSn-19Jed.tdb): LIQUID, type code %, sha256 `a1f1c360881522fd…`

~~~~text
20: PHASE LIQUID:L % 1 1 !
21: CONST LIQUID:L : CO SN : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.calphad.2004.08.001](https://doi.org/10.1016/j.calphad.2004.08.001) M. Jiang, J. Sato, I. Ohnuma, R. Kainuma, K. Ishida, A thermodynamic assessment of the Co–Sn system, Calphad 28, 213-220 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-004-0019-8](https://doi.org/10.1007/s11664-004-0019-8) Libin Liu, Cristina Andersson, Johan Liu, Thermodynamic assessment of the Sn-Co lead-free solder system, Journal of Elec Materi 33, 935-939 (2004).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-018-0687-3](https://doi.org/10.1007/s11669-018-0687-3) V. Jedličková, A. Zemanová, A. Kroupa, The Thermodynamic Assessment of the Co-Sn System, J. Phase Equilib. Diffus. 40, 21-33 (2019).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11664-009-0874-4](https://doi.org/10.1007/s11664-009-0874-4) H. Q. Dong, S. Jin, L. G. Zhang, J. S. Wang, X. M. Tao, H. S. Liu et al., Thermodynamic Assessment of the Au-Co-Sn Ternary System, Journal of Elec Materi 38, 2158-2169 (2009).  
_assessment that models this phase_
- [doi:10.1007/bf02663681](https://doi.org/10.1007/bf02663681) K Ishida, T Nishizawa, The Co-Sn (Cobalt-Tin) System, JPE 12, 88-93 (1991).  
_cited as the source of values for this phase_
- [doi:10.1002/zaac.19080590133](https://doi.org/10.1002/zaac.19080590133) S. F. Żemcżużny, S. W. Belynsky, Kobalt‐Zinnlegierungen, Z. Anorg. Chem. 59, 364-370 (1908).  
_cited as the source of values for this phase_
- [doi:10.1007/bf02658043](https://doi.org/10.1007/bf02658043) H. Cömert, J. N. Pratt, Constitutional studies of cobalt-tin alloys, Metall Trans A 23, 2401-2407 (1992).  
_cited as the source of values for this phase_

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite the ORCHID phase registry and the sources named on the page (TDB assessments, Hallstedt 2025, Materials Project, OQMD). TDB statements are quoted as written; parameter expressions are not reproduced. Field reference: [SCHEMA.md](https://data.orchid-project.org/phases/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt).
