Co–Th phases
10 phases (tier A 6, tier C 3, liquid 1); 10 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).
Data: interactive registry · full JSON · Co–Th system page · Markdown · field reference
| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---|---|
| BCC_A2 phase:co-th:bcc-a2 | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 1 of 1 calculated diagram(s): 1633.2–3999.45 K, x(Th) 0.99999–1 | 3 | 1 |
| CO17TH2 phase:co-th:co17th2 | Th2Zn17 · hR19 · R-3m (166) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 300–1735.98 K, x(Th) 0.10526–0.10526 | 9 | 1 |
| CO3TH7_D102 phase:co-th:co3th7-d102 | Fe3Th7 · D10_2 · hP20 · P6_3mc (186) | tier A: standard phase name | stable in 1 of 1 calculated diagram(s): 300–1402.43 K, x(Th) 0.7–0.7 | 9 | 1 |
| CO5TH_D2D phase:co-th:co5th-d2d | CaCu5 · D2_d · hP6 · P6/mmm (191) | tier A: standard phase name | stable in 1 of 1 calculated diagram(s): 400.45–1698.58 K, x(Th) 0.16667–0.16667 | 9 | 1 |
| CO7TH2_ALPHA phase:co-th:co7th2-alpha | Ce2Ni7 · hP36 · P6_3/mmc (194) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 300–1370 K, x(Th) 0.22222–0.22222 | 5 | 1 |
| CO7TH2_BETA phase:co-th:co7th2-beta | Co7Gd2 · hR18 · R-3m (166) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 1380–1390 K | 5 | 1 |
| COTH_B33 phase:co-th:coth-b33 | CrB · B33 · oC8 · Cmcm (63) | tier A: standard phase name | stable in 1 of 1 calculated diagram(s): 300–1398.31 K, x(Th) 0.5–0.5 | 9 | 1 |
| FCC_A1 phase:co-th:fcc-a1 | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | stable in 1 of 1 calculated diagram(s): 300–1767.99 K, x(Th) 0–1 | 6 | 1 |
| HCP_A3 phase:co-th:hcp-a3 | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 1 of 1 calculated diagram(s): 300–694.99 K, x(Th) 0–0 | 3 | 1 |
| LIQUID phase:co-th:liquid | liquid | liquid | stable in 1 of 1 calculated diagram(s): 1233.31–4000 K, x(Th) 0–1 | 39 | 1 |
BCC_A2 (Co–Th)
- Id:
phase:co-th:bcc-a2; statusassigned - Structure: W · A2 · cI2 · Im-3m (229); type
st:a2-w-ci2; tier A: standard phase name; confidence high - Stability: stable in 1 of 1 calculated diagram(s): 1633.2–3999.45 K, x(Th) 0.99999–1
- Literature: 3 values (3 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:bcc-a2
paper: paper:10.1016/j.jallcom.2007.03.003:βTh
tdb: tdb:CoTh-08Wan.tdb:BCC_A2
TDB models of BCC_A2 (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: BCC_A2, type code %B, sha256 97db96e3dea38a8a…
33: PHASE BCC_A2 %B 2 1 3 ! 34: CONST BCC_A2 : CO TH% : VA : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase
CO17TH2 (Co–Th)
- Id:
phase:co-th:co17th2; statusassigned - Structure: Th2Zn17 · hR19 · R-3m (166); type
st:th2zn17-hr19; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (mp_oqmd_space_groups_differ, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.8947, Th 0.1053
- Stability: stable in 1 of 1 calculated diagram(s): 300–1735.98 K, x(Th) 0.10526–0.10526
- Literature: 9 values (9 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:co17th2
paper: paper:10.1016/j.jallcom.2007.03.003:Co17Th2
tdb: tdb:CoTh-08Wan.tdb:CO17TH2
TDB models of CO17TH2 (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: CO17TH2, type code %A, sha256 97db96e3dea38a8a…
43: PHASE CO17TH2 %A 2 17 2 ! 44: CONST CO17TH2 : CO : TH : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase
CO3TH7_D102 (Co–Th)
- Id:
phase:co-th:co3th7-d102; statusassigned - Structure: Fe3Th7 · D10_2 · hP20 · P6_3mc (186); type
st:d10-2-fe3th7-hp20; tier A: standard phase name; confidence high - Caveat: DFT agrees: on-hull mp-aaaabtfp and oqmd-29515, space group 186
- Stoichiometry: Co 0.3000, Th 0.7000
- Stability: stable in 1 of 1 calculated diagram(s): 300–1402.43 K, x(Th) 0.7–0.7
- Literature: 9 values (9 accepted) from 1 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:co-th:co3th7-d102
mp: mp:mp-aaaabtfp
oqmd: oqmd:oqmd-29515
paper: paper:10.1016/j.jallcom.2007.03.003:Co3Th7
tdb: tdb:CoTh-08Wan.tdb:CO3TH7_D102
TDB models of CO3TH7_D102 (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: CO3TH7_D102, type code %, sha256 97db96e3dea38a8a…
68: PHASE CO3TH7_D102 % 2 3 7 ! 69: CONST CO3TH7_D102 : CO : TH : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase
CO5TH_D2D (Co–Th)
- Id:
phase:co-th:co5th-d2d; statusassigned - Structure: CaCu5 · D2_d · hP6 · P6/mmm (191); type
st:d2-d-cacu5-hp6; tier A: standard phase name; confidence high - Stoichiometry: Co 0.8333, Th 0.1667
- Stability: stable in 1 of 1 calculated diagram(s): 400.45–1698.58 K, x(Th) 0.16667–0.16667
- Literature: 9 values (9 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:co5th-d2d
paper: paper:10.1016/j.jallcom.2007.03.003:Co5Th
tdb: tdb:CoTh-08Wan.tdb:CO5TH_D2D
TDB models of CO5TH_D2D (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: CO5TH_D2D, type code %A, sha256 97db96e3dea38a8a…
48: PHASE CO5TH_D2D %A 2 5 1 ! 49: CONST CO5TH_D2D : CO : TH : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase
CO7TH2_ALPHA (Co–Th)
- Id:
phase:co-th:co7th2-alpha; statusassigned - Structure: Ce2Ni7 · hP36 · P6_3/mmc (194); type
st:ce2ni7-hp36; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.7778, Th 0.2222
- Stability: stable in 1 of 1 calculated diagram(s): 300–1370 K, x(Th) 0.22222–0.22222
- Literature: 5 values (5 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:co7th2-alpha
paper: paper:10.1016/j.jallcom.2007.03.003:αCo7Th2
tdb: tdb:CoTh-08Wan.tdb:CO7TH2_ALPHA
TDB models of CO7TH2_ALPHA (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: CO7TH2_ALPHA, type code %, sha256 97db96e3dea38a8a…
53: PHASE CO7TH2_ALPHA % 2 7 2 ! 54: CONST CO7TH2_ALPHA : CO : TH : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase
CO7TH2_BETA (Co–Th)
- Id:
phase:co-th:co7th2-beta; statusassigned - Structure: Co7Gd2 · hR18 · R-3m (166); type
st:co7gd2-hr18; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.7778, Th 0.2222
- Stability: stable in 1 of 1 calculated diagram(s): 1380–1390 K
- Literature: 5 values (5 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:co7th2-beta
paper: paper:10.1016/j.jallcom.2007.03.003:βCo7Th2
tdb: tdb:CoTh-08Wan.tdb:CO7TH2_BETA
TDB models of CO7TH2_BETA (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: CO7TH2_BETA, type code %, sha256 97db96e3dea38a8a…
58: PHASE CO7TH2_BETA % 2 7 2 ! 59: CONST CO7TH2_BETA : CO : TH : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase
COTH_B33 (Co–Th)
- Id:
phase:co-th:coth-b33; statusassigned - Structure: CrB · B33 · oC8 · Cmcm (63); type
st:b33-crb-oc8; tier A: standard phase name; confidence high - Caveat: DFT agrees: on-hull mp-aaaabtfo and oqmd-29514, space group 63
- Stoichiometry: Co 0.5000, Th 0.5000
- Stability: stable in 1 of 1 calculated diagram(s): 300–1398.31 K, x(Th) 0.5–0.5
- Literature: 9 values (9 accepted) from 1 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:co-th:coth-b33
mp: mp:mp-aaaabtfo
oqmd: oqmd:oqmd-29514
paper: paper:10.1016/j.jallcom.2007.03.003:CoTh
tdb: tdb:CoTh-08Wan.tdb:COTH_B33
TDB models of COTH_B33 (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: COTH_B33, type code %, sha256 97db96e3dea38a8a…
63: PHASE COTH_B33 % 2 1 1 ! 64: CONST COTH_B33 : CO : TH : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase
FCC_A1 (Co–Th)
- Id:
phase:co-th:fcc-a1; statusassigned - Structure: Cu · A1 · cF4 · Fm-3m (225); type
st:a1-cu-cf4; tier A: standard phase name; confidence high - Stability: stable in 1 of 1 calculated diagram(s): 300–1767.99 K, x(Th) 0–1
- Literature: 6 values (6 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:fcc-a1
paper: paper:10.1016/j.jallcom.2007.03.003:αTh
tdb: tdb:CoTh-08Wan.tdb:FCC_A1
TDB models of FCC_A1 (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: FCC_A1, type code %A, sha256 97db96e3dea38a8a…
28: PHASE FCC_A1 %A 2 1 1 ! 29: CONST FCC_A1 : CO% TH% : VA : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase
HCP_A3 (Co–Th)
- Id:
phase:co-th:hcp-a3; statusassigned - Structure: Mg · A3 · hP2 · P6_3/mmc (194); type
st:a3-mg-hp2; tier A: standard phase name; confidence high - Stoichiometry: Co 1.0000
- Stability: stable in 1 of 1 calculated diagram(s): 300–694.99 K, x(Th) 0–0
- Literature: 3 values (3 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:hcp-a3
paper: paper:10.1016/j.jallcom.2007.03.003:εCo
tdb: tdb:CoTh-08Wan.tdb:HCP_A3
TDB models of HCP_A3 (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: HCP_A3, type code %A, sha256 97db96e3dea38a8a…
38: PHASE HCP_A3 %A 2 1 0.5 ! 39: CONST HCP_A3 : CO : VA : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase
LIQUID (Co–Th)
- Id:
phase:co-th:liquid; statusassigned - Structure: liquid; type
st:liquid; liquid; confidence high - Stability: stable in 1 of 1 calculated diagram(s): 1233.31–4000 K, x(Th) 0–1
- Literature: 39 values (39 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-th:liquid
paper: paper:10.1016/j.jallcom.2007.03.003:L
tdb: tdb:CoTh-08Wan.tdb:LIQUID
TDB models of LIQUID (1): PHASE and CONSTITUENT statements as written
CoTh-08Wan.tdb: LIQUID, type code %, sha256 97db96e3dea38a8a…
23: PHASE LIQUID:L % 1 1 ! 24: CONST LIQUID:L : CO TH : !
Example references (3 of 3; assessments first):
- doi:10.1016/j.jallcom.2007.03.003 C.P. Wang, P. Yu, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the Co–Th and Fe–Th systems, Journal of Alloys and Compounds 457, 150-156 (2008).
assessment that models this phase; reports values for this phase - doi:10.1016/0022-5088(66)90101-9 J.R. Thomson, Alloys of thorium with certain transition metals IV. The systems thorium-iron and thorium-cobalt, Journal of the Less Common Metals 10, 432-438 (1966).
cited as the source of values for this phase - doi:10.1016/0022-5088(89)90170-7 A. Palenzona, S. Cirafici, The equilibrium diagrams of the Th-Fe and Th-Co systems, Journal of the Less Common Metals 154, 61-66 (1989).
cited as the source of values for this phase