Co–Zn phases
11 phases (tier A 5, tier B 1, tier C 4, liquid 1); 11 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).
Data: interactive registry · full JSON · Co–Zn system page · Markdown · field reference
| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---|---|
| BCC_A2 phase:co-zn:bcc-a2 | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 1 of 2 calculated diagram(s): 1193.31–1246.52 K, x(Zn) 0.49323–0.53266 | 12 | 2 |
| CO2ZN15 phase:co-zn:co2zn15 | Co2Zn15 · mC28 · C2/m (12) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 948.09–1016.39 K, x(Zn) 0.88235–0.88235 | 12 | 1 |
| CO2ZN28 phase:co-zn:co2zn28 | CoZn13 · mC28 · C2/m (12) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 300–850.44 K, x(Zn) 0.93333–0.93333 | 0 | 1 |
| CO3ZN22 phase:co-zn:co3zn22 | CoZn7 · hP60 · P6_2 (171) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 300–1020 K, x(Zn) 0.88–0.88 | 2 | 1 |
| CO5ZN21_D83 phase:co-zn:co5zn21-d83 | Al4Cu9 · D8_3 · cP52 · P-43m (215) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1176.77 K, x(Zn) 0.6858–0.81828 | 12 | 2 |
| COZN_A13 phase:co-zn:cozn-a13 | beta-Mn · A13 · cP20 · P4_132 (213) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1233.14 K, x(Zn) 0.46711–0.5699 | 21 | 2 |
| COZN13 phase:co-zn:cozn13 | CoZn13 · mC28 · C2/m (12) | tier B: DFT-supported (unique MP + OQMD match) | stable in 1 of 1 calculated diagram(s): 300–840.18 K, x(Zn) 0.92857–0.92857 | 8 | 1 |
| COZN7 phase:co-zn:cozn7 | CoZn7 · hP60 · P6_2 (171) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 1 of 1 calculated diagram(s): 300–961.13 K, x(Zn) 0.875–0.875 | 12 | 1 |
| FCC_A1 phase:co-zn:fcc-a1 | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 380–1768.99 K, x(Zn) 0–0.36965 | 14 | 2 |
| HCP_A3 phase:co-zn:hcp-a3 | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1647.6 K, x(Zn) 0–1 | 6 | 2 |
| LIQUID phase:co-zn:liquid | liquid | liquid | stable in 2 of 2 calculated diagram(s): 692.6–2500 K, x(Zn) 0–1 | 35 | 2 |
BCC_A2 (Co–Zn)
- Id:
phase:co-zn:bcc-a2; statusassigned - Structure: W · A2 · cI2 · Im-3m (229); type
st:a2-w-ci2; tier A: standard phase name; confidence high - Stability: stable in 1 of 2 calculated diagram(s): 1193.31–1246.52 K, x(Zn) 0.49323–0.53266
- Literature: 12 values (12 accepted) from 1 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:co-zn:bcc-a2
paper: paper:10.1361/15477030419522:β
system_alias: system_alias:co-zn:beta
tdb: tdb:CoZn-04Iso.tdb:BCC_A2, tdb:CoZn-04Vas-LB.tdb:BCC_A2
TDB models of BCC_A2 (2): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: BCC_A2, type code %B, sha256 97df739c925a45d7…
29: PHASE BCC_A2 %B 2 1 3 ! 30: CONST BCC_A2 : CO ZN : VA : !
CoZn-04Vas-LB.tdb: BCC_A2, type code %B, sha256 d5353920b632f1ae…
40: PHASE BCC_A2 %B 2 1 3 ! 41: CONST BCC_A2 : CO ZN : VA : !
Example references (2 of 2; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase
CO2ZN15 (Co–Zn)
- Id:
phase:co-zn:co2zn15; statusassigned - Structure: Co2Zn15 · mC28 · C2/m (12); type
st:co2zn15-mc28; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.1176, Zn 0.8824
- Stability: stable in 1 of 1 calculated diagram(s): 948.09–1016.39 K, x(Zn) 0.88235–0.88235
- Literature: 12 values (12 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-zn:co2zn15
paper: paper:10.1361/15477030419522:δ
tdb: tdb:CoZn-04Vas-LB.tdb:CO2ZN15
TDB models of CO2ZN15 (1): PHASE and CONSTITUENT statements as written
CoZn-04Vas-LB.tdb: CO2ZN15, type code %, sha256 d5353920b632f1ae…
65: PHASE CO2ZN15 % 2 2 15 ! 66: CONST CO2ZN15 : CO : ZN : !
Example references (1 of 1; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase
CO2ZN28 (Co–Zn)
- Id:
phase:co-zn:co2zn28; statusassigned - Structure: CoZn13 · mC28 · C2/m (12); type
st:cozn13-mc28; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.0667, Zn 0.9333
- Stability: stable in 1 of 1 calculated diagram(s): 300–850.44 K, x(Zn) 0.93333–0.93333
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: phase registry entry
Names (2): corpus: corpus:phase:co-zn:co2zn28
tdb: tdb:CoZn-04Iso.tdb:CO2ZN28
TDB models of CO2ZN28 (1): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: CO2ZN28, type code %, sha256 97df739c925a45d7…
54: PHASE CO2ZN28 % 2 2 28 ! 55: CONST CO2ZN28 : CO : ZN : !
Example references (1 of 1; assessments first):
- doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase
CO3ZN22 (Co–Zn)
- Id:
phase:co-zn:co3zn22; statusassigned - Structure: CoZn7 · hP60 · P6_2 (171); type
st:cozn7-hp60; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_mp, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.1200, Zn 0.8800
- Stability: stable in 1 of 1 calculated diagram(s): 300–1020 K, x(Zn) 0.88–0.88
- Literature: 2 values (0 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-zn:co3zn22
paper: paper:10.1016/j.jallcom.2003.12.002:γ1
tdb: tdb:CoZn-04Iso.tdb:CO3ZN22
TDB models of CO3ZN22 (1): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: CO3ZN22, type code %, sha256 97df739c925a45d7…
49: PHASE CO3ZN22 % 2 3 22 ! 50: CONST CO3ZN22 : CO : ZN : !
Example references (2 of 2; assessments first):
- doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase; reports values for this phase - doi:10.1007/bf02645345 T. Takayama, S. Shinohara, K. Ishida, T. Nishizawa, Anomalies in phase equilibria due to magnetic transition in Fe-Zn, Co-Zn, and Fe-Co-Zn systems, JPE 16, 390-395 (1995).
cited as the source of values for this phase
CO5ZN21_D83 (Co–Zn)
- Id:
phase:co-zn:co5zn21-d83; statusassigned - Structure: Al4Cu9 · D8_3 · cP52 · P-43m (215); type
st:d8-3-al4cu9-cp52; tier A: standard phase name; confidence high - Caveat: partitioned order/disorder model in CoZn-04Iso.tdb also describes the disordered state
- Stability: stable in 2 of 2 calculated diagram(s): 300–1176.77 K, x(Zn) 0.6858–0.81828
- Literature: 12 values (10 accepted) from 2 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:co-zn:co5zn21-d83
paper: paper:10.1016/j.jallcom.2003.12.002:γ, paper:10.1361/15477030419522:γ
tdb: tdb:CoZn-04Iso.tdb:CO5ZN21_D83, tdb:CoZn-04Vas-LB.tdb:CO5ZN21_D83
TDB models of CO5ZN21_D83 (2): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: CO5ZN21_D83, type code %, sha256 97df739c925a45d7…
44: PHASE CO5ZN21_D83 % 2 1 4 ! 45: CONST CO5ZN21_D83 : CO% ZN : CO ZN% : !
CoZn-04Vas-LB.tdb: CO5ZN21_D83, type code %, sha256 d5353920b632f1ae…
55: PHASE CO5ZN21_D83 % 1 1 ! 56: CONST CO5ZN21_D83 : CO ZN : !
Example references (3 of 3; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase; reports values for this phase - doi:10.1007/bf02645345 T. Takayama, S. Shinohara, K. Ishida, T. Nishizawa, Anomalies in phase equilibria due to magnetic transition in Fe-Zn, Co-Zn, and Fe-Co-Zn systems, JPE 16, 390-395 (1995).
cited as the source of values for this phase
COZN_A13 (Co–Zn)
- Id:
phase:co-zn:cozn-a13; statusassigned - Structure: beta-Mn · A13 · cP20 · P4_132 (213); type
st:a13-beta-mn-cp20; tier A: standard phase name; confidence high - Stability: stable in 2 of 2 calculated diagram(s): 300–1233.14 K, x(Zn) 0.46711–0.5699
- Literature: 21 values (21 accepted) from 2 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:co-zn:cozn-a13
paper: paper:10.1016/j.jallcom.2003.12.002:β1, paper:10.1361/15477030419522:β1
tdb: tdb:CoZn-04Iso.tdb:COZN_A13, tdb:CoZn-04Vas-LB.tdb:COZN_A13
TDB models of COZN_A13 (2): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: COZN_A13, type code %, sha256 97df739c925a45d7…
39: PHASE COZN_A13 % 2 1 1 ! 40: CONST COZN_A13 : CO% ZN : CO ZN% : !
CoZn-04Vas-LB.tdb: COZN_A13, type code %B, sha256 d5353920b632f1ae…
50: PHASE COZN_A13 %B 1 1 ! 51: CONST COZN_A13 : CO ZN : !
Example references (3 of 3; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase; reports values for this phase - doi:10.1007/bf02645345 T. Takayama, S. Shinohara, K. Ishida, T. Nishizawa, Anomalies in phase equilibria due to magnetic transition in Fe-Zn, Co-Zn, and Fe-Co-Zn systems, JPE 16, 390-395 (1995).
cited as the source of values for this phase
COZN13 (Co–Zn)
- Id:
phase:co-zn:cozn13; statusassigned - Structure: CoZn13 · mC28 · C2/m (12); type
st:cozn13-mc28; tier B: DFT-supported (unique MP + OQMD match); confidence high - Stoichiometry: Co 0.0714, Zn 0.9286
- Stability: stable in 1 of 1 calculated diagram(s): 300–840.18 K, x(Zn) 0.92857–0.92857
- Literature: 8 values (8 accepted) from 1 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:co-zn:cozn13
mp: mp:mp-aaaabtfs
oqmd: oqmd:oqmd-17125
paper: paper:10.1361/15477030419522:γ2
tdb: tdb:CoZn-04Vas-LB.tdb:COZN13
TDB models of COZN13 (1): PHASE and CONSTITUENT statements as written
CoZn-04Vas-LB.tdb: COZN13, type code %, sha256 d5353920b632f1ae…
70: PHASE COZN13 % 2 1 13 ! 71: CONST COZN13 : CO : ZN : !
Example references (1 of 1; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase
COZN7 (Co–Zn)
- Id:
phase:co-zn:cozn7; statusassigned - Structure: CoZn7 · hP60 · P6_2 (171); type
st:cozn7-hp60; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated - Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
- Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
- Stoichiometry: Co 0.1250, Zn 0.8750
- Stability: stable in 1 of 1 calculated diagram(s): 300–961.13 K, x(Zn) 0.875–0.875
- Literature: 12 values (12 accepted) from 1 papers
- Interactive: phase registry entry
Names (3): corpus: corpus:phase:co-zn:cozn7
paper: paper:10.1361/15477030419522:γ1
tdb: tdb:CoZn-04Vas-LB.tdb:COZN7
TDB models of COZN7 (1): PHASE and CONSTITUENT statements as written
CoZn-04Vas-LB.tdb: COZN7, type code %, sha256 d5353920b632f1ae…
60: PHASE COZN7 % 2 1 7 ! 61: CONST COZN7 : CO : ZN : !
Example references (1 of 1; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase
FCC_A1 (Co–Zn)
- Id:
phase:co-zn:fcc-a1; statusassigned - Structure: Cu · A1 · cF4 · Fm-3m (225); type
st:a1-cu-cf4; tier A: standard phase name; confidence high - Stability: stable in 2 of 2 calculated diagram(s): 380–1768.99 K, x(Zn) 0–0.36965
- Literature: 14 values (14 accepted) from 2 papers
- Interactive: phase registry entry
Names (6): corpus: corpus:phase:co-zn:fcc-a1
paper: paper:10.1016/j.jallcom.2003.12.002:Fcc_A1, paper:10.1361/15477030419522:(αCo), paper:10.1361/15477030419522:α
tdb: tdb:CoZn-04Iso.tdb:FCC_A1, tdb:CoZn-04Vas-LB.tdb:FCC_A1
TDB models of FCC_A1 (2): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: FCC_A1, type code %A, sha256 97df739c925a45d7…
24: PHASE FCC_A1 %A 2 1 1 ! 25: CONST FCC_A1 : CO% ZN : VA : !
CoZn-04Vas-LB.tdb: FCC_A1, type code %A, sha256 d5353920b632f1ae…
35: PHASE FCC_A1 %A 2 1 1 ! 36: CONST FCC_A1 : CO% ZN : VA : !
Example references (3 of 3; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase; reports values for this phase - doi:10.1007/bf02645345 T. Takayama, S. Shinohara, K. Ishida, T. Nishizawa, Anomalies in phase equilibria due to magnetic transition in Fe-Zn, Co-Zn, and Fe-Co-Zn systems, JPE 16, 390-395 (1995).
cited as the source of values for this phase
HCP_A3 (Co–Zn)
- Id:
phase:co-zn:hcp-a3; statusassigned - Structure: Mg · A3 · hP2 · P6_3/mmc (194); type
st:a3-mg-hp2; tier A: standard phase name; confidence high - Stability: stable in 2 of 2 calculated diagram(s): 300–1647.6 K, x(Zn) 0–1
- Literature: 6 values (6 accepted) from 1 papers
- Interactive: phase registry entry
Names (5): corpus: corpus:phase:co-zn:hcp-a3
paper: paper:10.1361/15477030419522:(Zn), paper:10.1361/15477030419522:(εCo)
tdb: tdb:CoZn-04Iso.tdb:HCP_A3, tdb:CoZn-04Vas-LB.tdb:HCP_A3
TDB models of HCP_A3 (2): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: HCP_A3, type code %A, sha256 97df739c925a45d7…
34: PHASE HCP_A3 %A 2 1 0.5 ! 35: CONST HCP_A3 : CO% ZN% : VA : !
CoZn-04Vas-LB.tdb: HCP_A3, type code %A, sha256 d5353920b632f1ae…
45: PHASE HCP_A3 %A 2 1 0.5 ! 46: CONST HCP_A3 : CO% ZN% : VA : !
Example references (2 of 2; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase
LIQUID (Co–Zn)
- Id:
phase:co-zn:liquid; statusassigned - Structure: liquid; type
st:liquid; liquid; confidence high - Stability: stable in 2 of 2 calculated diagram(s): 692.6–2500 K, x(Zn) 0–1
- Literature: 35 values (33 accepted) from 2 papers
- Interactive: phase registry entry
Names (6): corpus: corpus:phase:co-zn:liquid
paper: paper:10.1016/j.jallcom.2003.12.002:L, paper:10.1361/15477030419522:Co(L), paper:10.1361/15477030419522:L
tdb: tdb:CoZn-04Iso.tdb:LIQUID, tdb:CoZn-04Vas-LB.tdb:LIQUID
TDB models of LIQUID (2): PHASE and CONSTITUENT statements as written
CoZn-04Iso.tdb: LIQUID, type code %, sha256 97df739c925a45d7…
19: PHASE LIQUID:L % 1 1 ! 20: CONST LIQUID:L : CO ZN : !
CoZn-04Vas-LB.tdb: LIQUID, type code %, sha256 d5353920b632f1ae…
30: PHASE LIQUID:L % 1 1 ! 31: CONST LIQUID:L : CO ZN : !
Example references (3 of 3; assessments first):
- doi:10.1361/15477030419522 George Penev Vassilev, Min Jiang, Thermodynamic Optimization of the Co-Zn System, Journal of Phase Equilibria & Diffusion 25, 259-268 (2004).
assessment that models this phase; reports values for this phase - doi:10.1016/j.jallcom.2003.12.002 I Isomäki, M Hämäläinen, Thermodynamic evaluation of the Co–Zn system, Journal of Alloys and Compounds 375, 191-195 (2004).
assessment that models this phase; reports values for this phase - doi:10.1007/bf02645345 T. Takayama, S. Shinohara, K. Ishida, T. Nishizawa, Anomalies in phase equilibria due to magnetic transition in Fe-Zn, Co-Zn, and Fe-Co-Zn systems, JPE 16, 390-395 (1995).
cited as the source of values for this phase