# Co–Zr phases

> Co–Zr system: 13 phases (tier A 9, tier C 1, liquid 1, needs_review 2); 13 stable in a calculated diagram in the ORCHID phase registry, with names, structure type when the stored evidence supports an assignment under the stated tier rules, calculated stability, verbatim TDB PHASE/CONSTITUENT statements and example references.

HTML: https://data.orchid-project.org/phases/pages/CO-ZR.html · Markdown: https://data.orchid-project.org/phases/pages/CO-ZR.md

13 phases (tier A 9, tier C 1, liquid 1, needs_review 2); 13 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: [interactive registry](https://orchid-project.org/phases/?q=CO-ZR) · [full JSON](https://data.orchid-project.org/phases/systems/CO-ZR.json) · [Co–Zr system page](https://data.orchid-project.org/systems/CO-ZR.html) · [Markdown](https://data.orchid-project.org/phases/pages/CO-ZR.md) · [field reference](https://data.orchid-project.org/phases/SCHEMA.md)

Table: Phases of the Co–Zr system (13)

| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---:|---:|
| [BCC_A2](#phase-co-zr-bcc-a2); _phase:co-zr:bcc-a2_ | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 1100–3999.37 K, x(Zr) 0.898–1 | 47 | 11 |
| [B2_BCC](#phase-co-zr-bcc-b2); _phase:co-zr:bcc-b2_ | CsCl · B2 · cP2 · Pm-3m (221) | tier A: standard phase name | stable in 4 of 4 calculated diagram(s): 300–3999.1 K, x(Zr) 0.49883–1 | 31 | 4 |
| [C15_LAVES](#phase-co-zr-c15-laves); _phase:co-zr:c15-laves_ | Cu2Mg · C15 · cF24 · Fd-3m (227) | tier A: standard phase name | stable in 6 of 6 calculated diagram(s): 300–1853.32 K, x(Zr) 0.2525–0.34111 | 71 | 6 |
| [CO11ZR2](#phase-co-zr-co11zr2); _phase:co-zr:co11zr2_ |  | needs_review | stable in 6 of 6 calculated diagram(s): 300–1548.49 K, x(Zr) 0.15385–0.15385 | 51 | 6 |
| [CO23ZR6_D8A](#phase-co-zr-co23zr6-d8a); _phase:co-zr:co23zr6-d8a_ | Mn23Th6 · D8_a · cF116 · Fm-3m (225) | tier A: standard phase name | stable in 6 of 6 calculated diagram(s): 300–1628.06 K, x(Zr) 0.2069–0.2069 | 51 | 6 |
| [CO2ZR_C15](#phase-co-zr-co2zr-c15); _phase:co-zr:co2zr-c15_ | Cu2Mg · C15 · cF24 · Fd-3m (227) | tier A: standard phase name | stable in 1 of 1 calculated diagram(s): 300–2073.51 K, x(Zr) 0.33333–0.33333 | 0 | 1 |
| [COZR_B2](#phase-co-zr-cozr-b2); _phase:co-zr:cozr-b2_ | CsCl · B2 · cP2 · Pm-3m (221) | tier A: standard phase name | stable in 3 of 3 calculated diagram(s): 300–1821.89 K, x(Zr) 0.5–0.5 | 48 | 3 |
| [COZR2](#phase-co-zr-cozr2); _phase:co-zr:cozr2_ |  | needs_review | stable in 1 of 1 calculated diagram(s): 300–1582.37 K, x(Zr) 0.66667–0.66667 | 3 | 1 |
| [COZR2_C16](#phase-co-zr-cozr2-c16); _phase:co-zr:cozr2-c16_ | Al2Cu · C16 · tI12 · I4/mcm (140) | tier A: standard phase name | stable in 6 of 6 calculated diagram(s): 300–1398.53 K, x(Zr) 0.66667–0.66845 | 80 | 6 |
| [COZR3](#phase-co-zr-cozr3); _phase:co-zr:cozr3_ | Re3B · E1_a · oC16 · Cmcm (63) | tier C: assessor-stated (Hallstedt 2025 crystallographic table) | stable in 6 of 6 calculated diagram(s): 300–1254.33 K, x(Zr) 0.7468–0.75592 | 28 | 6 |
| [FCC_A1](#phase-co-zr-fcc-a1); _phase:co-zr:fcc-a1_ | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 619.99–1794.78 K, x(Zr) 0–0.01229 | 14 | 7 |
| [HCP_A3](#phase-co-zr-hcp-a3); _phase:co-zr:hcp-a3_ | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 7 of 7 calculated diagram(s): 300–2060.04 K, x(Zr) 0–1 | 12 | 7 |
| [LIQUID](#phase-co-zr-liquid); _phase:co-zr:liquid_ | liquid | liquid | stable in 7 of 7 calculated diagram(s): 1256.32–4000 K, x(Zr) 0–1 | 165 | 7 |

## BCC_A2 (Co–Zr)

- Id: `phase:co-zr:bcc-a2`; status `assigned`
- Structure: W · A2 · cI2 · Im-3m (229); type `st:a2-w-ci2`; tier A: standard phase name; confidence high
- Stability: stable in 7 of 7 calculated diagram(s): 1100–3999.37 K, x(Zr) 0.898–1
- Literature: 47 values (47 accepted) from 4 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:bcc-a2)

Names (17): _corpus: _corpus:phase:co-zr:bcc-a2  
_paper: _paper:10.1007/s11669-020-00805-5:(βCo), paper:10.1007/s11669-020-00805-5:(βZr), paper:10.1007/s11669-020-00859-5:bcc(Zr), paper:10.1016/j.calphad.2010.02.006:BCC_A2, paper:10.1016/j.jallcom.2009.04.032:(βZr)  
_tdb: _tdb:CoZr-06Bra.tdb:BCC_A2, tdb:CoZr-09Liu.tdb:BCC_A2, tdb:CoZr-10Dur.tdb:A2_BCC, tdb:CoZr-10Dur.tdb:BCC_A2, tdb:CoZr-20Agr.tdb:BCC_A2, tdb:CoZr-21Zho.tdb:A2_BCC, tdb:CoZr-21Zho.tdb:BCC_A2, tdb:CoZr-22Zho.tdb:A2_BCC, tdb:CoZr-22Zho.tdb:BCC_A2, tdb:CoZr-23Sun.tdb:A2_BCC, tdb:CoZr-23Sun.tdb:BCC_A2  


### TDB models of BCC_A2 (11): PHASE and CONSTITUENT statements as written

[CoZr-06Bra.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-06Bra.tdb): BCC_A2, type code %B, sha256 `4cf053b4e5984583…`

~~~~text
34: PHASE BCC_A2 %B 2 1 3 !
35: CONST BCC_A2 : CO ZR% : VA : !
~~~~

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): BCC_A2, type code %B, sha256 `21ca509095023d19…`

~~~~text
33: PHASE BCC_A2 %B 2 1 3 !
34: CONST BCC_A2 : CO ZR% : VA : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): A2_BCC, type code %B, sha256 `2b9f7fe2872d5ff7…`

~~~~text
37: PHASE A2_BCC %B 2 1 3 !
38: CONST A2_BCC : CO VA ZR : VA : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): BCC_A2, type code %B, sha256 `2b9f7fe2872d5ff7…`

~~~~text
32: PHASE BCC_A2 %B 2 1 3 !
33: CONST BCC_A2 : CO ZR% : VA : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): BCC_A2, type code %B, sha256 `d571ff30c7e48944…`

~~~~text
32: PHASE BCC_A2 %B 2 1 3 !
33: CONST BCC_A2 : CO ZR% : VA : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): A2_BCC, type code %B, sha256 `52e8b692e30b9251…`

~~~~text
38: PHASE A2_BCC %B 2 1 3 !
39: CONST A2_BCC : CO ZR : VA : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): BCC_A2, type code %B, sha256 `52e8b692e30b9251…`

~~~~text
33: PHASE BCC_A2 %B 2 1 3 !
34: CONST BCC_A2 : CO ZR% : VA : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): A2_BCC, type code %B, sha256 `80f4492cf632b86b…`

~~~~text
39: PHASE A2_BCC %B 2 1 3 !
40: CONST A2_BCC : CO ZR : VA : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): BCC_A2, type code %B, sha256 `80f4492cf632b86b…`

~~~~text
34: PHASE BCC_A2 %B 2 1 3 !
35: CONST BCC_A2 : CO ZR% : VA : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): A2_BCC, type code %B, sha256 `33d7504af3254f23…`

~~~~text
39: PHASE A2_BCC %B 2 1 3 !
40: CONST A2_BCC : CO VA ZR : VA : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): BCC_A2, type code %B, sha256 `33d7504af3254f23…`

~~~~text
34: PHASE BCC_A2 %B 2 1 3 !
35: CONST BCC_A2 : CO ZR% : VA : !
~~~~

Example references (8 of 8; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1361/154770306X109746](https://doi.org/10.1361/154770306X109746) J. Bratberg, B. Jansson, J. Phase Equilib. Diffus., 27, 213-19(2006).  
_assessment that models this phase_
- [doi:10.1007/s11106-016-9751-x](https://doi.org/10.1007/s11106-016-9751-x) O. L. Semenova, V. M. Petyukh, O. S. Fomichev, The Constitution of Co–Zr Phase Diagram, Powder Metall Met Ceram 54, 583-589 (2016).  
_cited as the source of values for this phase_

## B2_BCC (Co–Zr)

- Id: `phase:co-zr:bcc-b2`; status `assigned`
- Structure: CsCl · B2 · cP2 · Pm-3m (221); type `st:b2-cscl-cp2`; tier A: standard phase name; confidence high
- Caveat: CoZr-10Dur.tdb: ordered phase with disordered part A2_BCC (order/disorder model)
- Caveat: CoZr-21Zho.tdb: ordered phase with disordered part A2_BCC (order/disorder model)
- Caveat: CoZr-22Zho.tdb: ordered phase with disordered part A2_BCC (order/disorder model)
- Caveat: CoZr-23Sun.tdb: ordered phase with disordered part A2_BCC (order/disorder model)
- Caveat: partitioned order/disorder model in CoZr-10Dur.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-21Zho.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-22Zho.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-23Sun.tdb also describes the disordered state
- Stability: stable in 4 of 4 calculated diagram(s): 300–3999.1 K, x(Zr) 0.49883–1
- Literature: 31 values (31 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:bcc-b2)

Names (8): _corpus: _corpus:phase:co-zr:bcc-b2, corpus:phase:co-zr:b2-bcc  
_paper: _paper:10.1007/s11669-020-00859-5:CoZr, paper:10.1016/j.calphad.2010.02.006:BCC_B2  
_tdb: _tdb:CoZr-10Dur.tdb:B2_BCC, tdb:CoZr-21Zho.tdb:B2_BCC, tdb:CoZr-22Zho.tdb:B2_BCC, tdb:CoZr-23Sun.tdb:B2_BCC  


### TDB models of B2_BCC (4): PHASE and CONSTITUENT statements as written

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): B2_BCC, type code %BO, sha256 `2b9f7fe2872d5ff7…`

~~~~text
42: PHASE B2_BCC %BO 3 0.5 0.5 3 !
43: CONST B2_BCC : CO% VA ZR : CO VA ZR% : VA : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): B2_BCC, type code %BO, sha256 `52e8b692e30b9251…`

~~~~text
43: PHASE B2_BCC %BO 3 0.5 0.5 3 !
44: CONST B2_BCC : CO% ZR : CO ZR% : VA : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): B2_BCC, type code %BO, sha256 `80f4492cf632b86b…`

~~~~text
44: PHASE B2_BCC %BO 3 0.5 0.5 3 !
45: CONST B2_BCC : CO% ZR : CO ZR% : VA : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): B2_BCC, type code %BO, sha256 `33d7504af3254f23…`

~~~~text
44: PHASE B2_BCC %BO 3 0.5 0.5 3 !
45: CONST B2_BCC : CO% VA ZR : CO VA ZR% : VA : !
~~~~

Example references (9 of 9; assessments first): 

- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_cited as the source of values for this phase_
- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_cited as the source of values for this phase_
- [doi:10.1016/0364-5916(83)90024-x](https://doi.org/10.1016/0364-5916%2883%2990024-x) J.C. Gachon, Enthalpies of formation of binary phases in the systems FeTi, FeZr, CoTi, CoZr, NiTi, and NiZr, by direct reaction calorimetry, Calphad (1983).  
_cited as the source of values for this phase_
- [doi:10.1016/s0925-8388(98)00246-1](https://doi.org/10.1016/s0925-8388%2898%2900246-1) Qiti Guo, O.J. Kleppa, Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by high-temperature direct synthesis calorimetry, Journal of Alloys and Compounds 269, 181-186 (1998).  
_cited as the source of values for this phase_
- [doi:10.1103/physrevb.78.144414](https://doi.org/10.1103/physrevb.78.144414) P. R. Ohodnicki, N. C. Cates, D. E. Laughlin, M. E. McHenry, M. Widom, \<i>Ab initio\</i>theoretical study of magnetization and phase stability of the\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mrow>\<mml:mo>(\</mml:mo>\<mml:mrow>\<mml:mtext>Fe\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Co\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Ni\</mml:mtext>\</mml:mrow>\<mml:mo>)\</mml:mo>\</mml:mrow>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mtext>B\</mml:mtext>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>and\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mrow>\<mml:mo>(\</mml:mo>\<mml:mrow>\<mml:mtext>Fe\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Co\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Ni\</mml:mtext>\</mml:mrow>\<mml:mo>)\</mml:mo>\</mml:mrow>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mrow>\<mml:mtext>Zr\</mml:mtext>\</mml:mrow>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>structures of\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mtext>Cr\</mml:mtext>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mtext>C\</mml:mtext>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>and\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mtext>Mn\</mml:mtext>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mrow>\<mml:mtext>Th\</mml:mtext>\</mml:mrow>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>prototypes, Phys. Rev. B 78 (2008).  
_cited as the source of values for this phase_

## C15_LAVES (Co–Zr)

- Id: `phase:co-zr:c15-laves`; status `assigned`
- Structure: Cu2Mg · C15 · cF24 · Fd-3m (227); type `st:c15-cu2mg-cf24`; tier A: standard phase name; confidence high
- Caveat: partitioned order/disorder model in CoZr-09Liu.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-10Dur.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-20Agr.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-21Zho.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-22Zho.tdb also describes the disordered state
- Caveat: partitioned order/disorder model in CoZr-23Sun.tdb also describes the disordered state
- Stability: stable in 6 of 6 calculated diagram(s): 300–1853.32 K, x(Zr) 0.2525–0.34111
- Literature: 71 values (71 accepted) from 4 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:c15-laves)

Names (11): _corpus: _corpus:phase:co-zr:c15-laves  
_paper: _paper:10.1007/s11669-020-00805-5:Co2Zr, paper:10.1007/s11669-020-00859-5:λ2, paper:10.1016/j.calphad.2010.02.006:Laves_C15, paper:10.1016/j.jallcom.2009.04.032:Co2Zr  
_tdb: _tdb:CoZr-09Liu.tdb:C15_LAVES, tdb:CoZr-10Dur.tdb:C15_LAVES, tdb:CoZr-20Agr.tdb:C15_LAVES, tdb:CoZr-21Zho.tdb:C15_LAVES, tdb:CoZr-22Zho.tdb:C15_LAVES, tdb:CoZr-23Sun.tdb:C15_LAVES  


### TDB models of C15_LAVES (6): PHASE and CONSTITUENT statements as written

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): C15_LAVES, type code %, sha256 `21ca509095023d19…`

~~~~text
53: PHASE C15_LAVES % 2 2 1 !
54: CONST C15_LAVES : CO% ZR : CO ZR% : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): C15_LAVES, type code %, sha256 `2b9f7fe2872d5ff7…`

~~~~text
62: PHASE C15_LAVES % 2 2 1 !
63: CONST C15_LAVES : CO% ZR : CO ZR% : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): C15_LAVES, type code %, sha256 `d571ff30c7e48944…`

~~~~text
52: PHASE C15_LAVES % 2 2 1 !
53: CONST C15_LAVES : CO% ZR : CO ZR% : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): C15_LAVES, type code %, sha256 `52e8b692e30b9251…`

~~~~text
63: PHASE C15_LAVES % 2 2 1 !
64: CONST C15_LAVES : CO% ZR : CO ZR% : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): C15_LAVES, type code %, sha256 `80f4492cf632b86b…`

~~~~text
64: PHASE C15_LAVES % 2 2 1 !
65: CONST C15_LAVES : CO% ZR : CO ZR% : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): C15_LAVES, type code %, sha256 `33d7504af3254f23…`

~~~~text
64: PHASE C15_LAVES % 2 2 1 !
65: CONST C15_LAVES : CO% ZR : CO ZR% : !
~~~~

Example references (6 of 6; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_

## CO11ZR2 (Co–Zr)

- Id: `phase:co-zr:co11zr2`; status `needs_review`
- No structure assigned. Why: no_on_hull_entry_in_both; no_structure_token; sgte_mmc2_row_incomplete
- Candidate (literature_printed): (Co11Zr2) · oP\* — printed with a label mapped to this phase
- Candidate (sgte_mmc2): (Co11Zr2) · Pban (50) — Hallstedt 2025 mmc2 row for CO11ZR2: Co11Zr2
- Stoichiometry: Co 0.8462, Zr 0.1538
- Stability: stable in 6 of 6 calculated diagram(s): 300–1548.49 K, x(Zr) 0.15385–0.15385
- Literature: 51 values (51 accepted) from 5 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:co11zr2)

Names (12): _corpus: _corpus:phase:co-zr:co11zr2  
_paper: _paper:10.1007/s11661-023-07089-7:Co11Zr2, paper:10.1007/s11669-020-00805-5:Co11Zr2, paper:10.1007/s11669-020-00859-5:Co11Zr2, paper:10.1016/j.calphad.2010.02.006:Co11Zr2, paper:10.1016/j.jallcom.2009.04.032:Co11Zr2  
_tdb: _tdb:CoZr-09Liu.tdb:CO11ZR2, tdb:CoZr-10Dur.tdb:CO11ZR2, tdb:CoZr-20Agr.tdb:CO11ZR2, tdb:CoZr-21Zho.tdb:CO11ZR2, tdb:CoZr-22Zho.tdb:CO11ZR2, tdb:CoZr-23Sun.tdb:CO11ZR2  


### TDB models of CO11ZR2 (6): PHASE and CONSTITUENT statements as written

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): CO11ZR2, type code %, sha256 `21ca509095023d19…`

~~~~text
43: PHASE CO11ZR2 % 2 11 2 !
44: CONST CO11ZR2 : CO : ZR : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): CO11ZR2, type code %, sha256 `2b9f7fe2872d5ff7…`

~~~~text
52: PHASE CO11ZR2 % 2 11 2 !
53: CONST CO11ZR2 : CO : ZR : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): CO11ZR2, type code %, sha256 `d571ff30c7e48944…`

~~~~text
42: PHASE CO11ZR2 % 2 11 2 !
43: CONST CO11ZR2 : CO : ZR : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): CO11ZR2, type code %, sha256 `52e8b692e30b9251…`

~~~~text
53: PHASE CO11ZR2 % 2 11 2 !
54: CONST CO11ZR2 : CO : ZR : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): CO11ZR2, type code %, sha256 `80f4492cf632b86b…`

~~~~text
54: PHASE CO11ZR2 % 2 11 2 !
55: CONST CO11ZR2 : CO : ZR : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): CO11ZR2, type code %, sha256 `33d7504af3254f23…`

~~~~text
54: PHASE CO11ZR2 % 2 11 2 !
55: CONST CO11ZR2 : CO : ZR : !
~~~~

Example references (6 of 6; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_

## CO23ZR6_D8A (Co–Zr)

- Id: `phase:co-zr:co23zr6-d8a`; status `assigned`
- Structure: Mn23Th6 · D8_a · cF116 · Fm-3m (225); type `st:d8-a-mn23th6-cf116`; tier A: standard phase name; confidence high
- Stoichiometry: Co 0.7931, Zr 0.2069
- Stability: stable in 6 of 6 calculated diagram(s): 300–1628.06 K, x(Zr) 0.2069–0.2069
- Literature: 51 values (51 accepted) from 5 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:co23zr6-d8a)

Names (12): _corpus: _corpus:phase:co-zr:co23zr6-d8a  
_paper: _paper:10.1007/s11661-023-07089-7:Co23Zr6, paper:10.1007/s11669-020-00805-5:Co23Zr6, paper:10.1007/s11669-020-00859-5:Co23Zr6, paper:10.1016/j.calphad.2010.02.006:Co23Zr6, paper:10.1016/j.jallcom.2009.04.032:Co23Zr6  
_tdb: _tdb:CoZr-09Liu.tdb:CO23ZR6_D8A, tdb:CoZr-10Dur.tdb:CO23ZR6_D8A, tdb:CoZr-20Agr.tdb:CO23ZR6_D8A, tdb:CoZr-21Zho.tdb:CO23ZR6_D8A, tdb:CoZr-22Zho.tdb:CO23ZR6_D8A, tdb:CoZr-23Sun.tdb:CO23ZR6_D8A  


### TDB models of CO23ZR6_D8A (6): PHASE and CONSTITUENT statements as written

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): CO23ZR6_D8A, type code %, sha256 `21ca509095023d19…`

~~~~text
48: PHASE CO23ZR6_D8A % 2 23 6 !
49: CONST CO23ZR6_D8A : CO : ZR : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): CO23ZR6_D8A, type code %, sha256 `2b9f7fe2872d5ff7…`

~~~~text
57: PHASE CO23ZR6_D8A % 2 23 6 !
58: CONST CO23ZR6_D8A : CO : ZR : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): CO23ZR6_D8A, type code %, sha256 `d571ff30c7e48944…`

~~~~text
47: PHASE CO23ZR6_D8A % 2 23 6 !
48: CONST CO23ZR6_D8A : CO : ZR : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): CO23ZR6_D8A, type code %, sha256 `52e8b692e30b9251…`

~~~~text
58: PHASE CO23ZR6_D8A % 2 23 6 !
59: CONST CO23ZR6_D8A : CO : ZR : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): CO23ZR6_D8A, type code %, sha256 `80f4492cf632b86b…`

~~~~text
59: PHASE CO23ZR6_D8A % 2 23 6 !
60: CONST CO23ZR6_D8A : CO : ZR : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): CO23ZR6_D8A, type code %, sha256 `33d7504af3254f23…`

~~~~text
59: PHASE CO23ZR6_D8A % 2 23 6 !
60: CONST CO23ZR6_D8A : CO : ZR : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1016/0364-5916(83)90024-x](https://doi.org/10.1016/0364-5916%2883%2990024-x) J.C. Gachon, Enthalpies of formation of binary phases in the systems FeTi, FeZr, CoTi, CoZr, NiTi, and NiZr, by direct reaction calorimetry, Calphad (1983).  
_cited as the source of values for this phase_

## CO2ZR_C15 (Co–Zr)

- Id: `phase:co-zr:co2zr-c15`; status `assigned`
- Structure: Cu2Mg · C15 · cF24 · Fd-3m (227); type `st:c15-cu2mg-cf24`; tier A: standard phase name; confidence high
- Caveat: DFT agrees: on-hull mp-aaaaabjt and oqmd-31202, space group 227
- Stoichiometry: Co 0.6667, Zr 0.3333
- Stability: stable in 1 of 1 calculated diagram(s): 300–2073.51 K, x(Zr) 0.33333–0.33333
- Literature: 0 values (0 accepted) from 0 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:co2zr-c15)

Names (4): _corpus: _corpus:phase:co-zr:co2zr-c15  
_mp: _mp:mp-aaaaabjt  
_oqmd: _oqmd:oqmd-31202  
_tdb: _tdb:CoZr-06Bra.tdb:CO2ZR_C15  


### TDB models of CO2ZR_C15 (1): PHASE and CONSTITUENT statements as written

[CoZr-06Bra.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-06Bra.tdb): CO2ZR_C15, type code %, sha256 `4cf053b4e5984583…`

~~~~text
44: PHASE CO2ZR_C15 % 2 2 1 !
45: CONST CO2ZR_C15 : CO : ZR : !
~~~~

Example references (1 of 1; assessments first): 

- [doi:10.1361/154770306X109746](https://doi.org/10.1361/154770306X109746) J. Bratberg, B. Jansson, J. Phase Equilib. Diffus., 27, 213-19(2006).  
_assessment that models this phase_

## COZR_B2 (Co–Zr)

- Id: `phase:co-zr:cozr-b2`; status `assigned`
- Structure: CsCl · B2 · cP2 · Pm-3m (221); type `st:b2-cscl-cp2`; tier A: standard phase name; confidence high
- Stoichiometry: Co 0.5000, Zr 0.5000
- Stability: stable in 3 of 3 calculated diagram(s): 300–1821.89 K, x(Zr) 0.5–0.5
- Literature: 48 values (48 accepted) from 2 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:cozr-b2)

Names (6): _corpus: _corpus:phase:co-zr:cozr-b2  
_paper: _paper:10.1007/s11669-020-00805-5:CoZr, paper:10.1016/j.jallcom.2009.04.032:CoZr  
_tdb: _tdb:CoZr-06Bra.tdb:COZR_B2, tdb:CoZr-09Liu.tdb:COZR_B2, tdb:CoZr-20Agr.tdb:COZR_B2  


### TDB models of COZR_B2 (3): PHASE and CONSTITUENT statements as written

[CoZr-06Bra.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-06Bra.tdb): COZR_B2, type code %, sha256 `4cf053b4e5984583…`

~~~~text
49: PHASE COZR_B2 % 2 1 1 !
50: CONST COZR_B2 : CO : ZR : !
~~~~

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): COZR_B2, type code %, sha256 `21ca509095023d19…`

~~~~text
58: PHASE COZR_B2 % 2 1 1 !
59: CONST COZR_B2 : CO : ZR : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): COZR_B2, type code %, sha256 `d571ff30c7e48944…`

~~~~text
57: PHASE COZR_B2 % 2 1 1 !
58: CONST COZR_B2 : CO : ZR : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1361/154770306X109746](https://doi.org/10.1361/154770306X109746) J. Bratberg, B. Jansson, J. Phase Equilib. Diffus., 27, 213-19(2006).  
_assessment that models this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_cited as the source of values for this phase_

## COZR2 (Co–Zr)

- Id: `phase:co-zr:cozr2`; status `needs_review`
- No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition
- Candidate (dft_mp): I4/mcm (140) — on-hull MP Zr2Co at x(ZR)=0.6667
- Candidate (tdb_comment): NiTi2 · cF96 · Fd-3m — CoZr-06Bra.tdb: 'Prototype NiTi2 (cF96, Fd-3m)'
- Stoichiometry: Co 0.3333, Zr 0.6667
- Stability: stable in 1 of 1 calculated diagram(s): 300–1582.37 K, x(Zr) 0.66667–0.66667
- Literature: 3 values (3 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:cozr2)

Names (3): _corpus: _corpus:phase:co-zr:cozr2  
_paper: _paper:10.1361/154770306x109746:CoZr2  
_tdb: _tdb:CoZr-06Bra.tdb:COZR2  


### TDB models of COZR2 (1): PHASE and CONSTITUENT statements as written

[CoZr-06Bra.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-06Bra.tdb): COZR2, type code %, sha256 `4cf053b4e5984583…`

~~~~text
54: PHASE COZR2 % 2 1 2 !
55: CONST COZR2 : CO : ZR : !
~~~~

Example references (1 of 1; assessments first): 

- [doi:10.1361/154770306X109746](https://doi.org/10.1361/154770306X109746) J. Bratberg, B. Jansson, J. Phase Equilib. Diffus., 27, 213-19(2006).  
_assessment that models this phase; reports values for this phase_

## COZR2_C16 (Co–Zr)

- Id: `phase:co-zr:cozr2-c16`; status `assigned`
- Structure: Al2Cu · C16 · tI12 · I4/mcm (140); type `st:c16-al2cu-ti12`; tier A: standard phase name; confidence high
- Stability: stable in 6 of 6 calculated diagram(s): 300–1398.53 K, x(Zr) 0.66667–0.66845
- Literature: 80 values (80 accepted) from 4 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:cozr2-c16)

Names (11): _corpus: _corpus:phase:co-zr:cozr2-c16  
_paper: _paper:10.1007/s11669-020-00805-5:CoZr2, paper:10.1007/s11669-020-00859-5:CoZr2, paper:10.1016/j.calphad.2010.02.006:CoZr2, paper:10.1016/j.jallcom.2009.04.032:CoZr2  
_tdb: _tdb:CoZr-09Liu.tdb:COZR2_C16, tdb:CoZr-10Dur.tdb:COZR2_C16, tdb:CoZr-20Agr.tdb:COZR2_C16, tdb:CoZr-21Zho.tdb:COZR2_C16, tdb:CoZr-22Zho.tdb:COZR2_C16, tdb:CoZr-23Sun.tdb:COZR2_C16  


### TDB models of COZR2_C16 (6): PHASE and CONSTITUENT statements as written

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): COZR2_C16, type code %, sha256 `21ca509095023d19…`

~~~~text
63: PHASE COZR2_C16 % 2 1 2 !
64: CONST COZR2_C16 : CO : ZR : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): COZR2_C16, type code %, sha256 `2b9f7fe2872d5ff7…`

~~~~text
67: PHASE COZR2_C16 % 2 1 2 !
68: CONST COZR2_C16 : CO% ZR : ZR : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): COZR2_C16, type code %, sha256 `d571ff30c7e48944…`

~~~~text
62: PHASE COZR2_C16 % 2 1 2 !
63: CONST COZR2_C16 : CO : ZR : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): COZR2_C16, type code %, sha256 `52e8b692e30b9251…`

~~~~text
68: PHASE COZR2_C16 % 2 1 2 !
69: CONST COZR2_C16 : CO : ZR : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): COZR2_C16, type code %, sha256 `80f4492cf632b86b…`

~~~~text
69: PHASE COZR2_C16 % 2 1 2 !
70: CONST COZR2_C16 : CO : ZR : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): COZR2_C16, type code %, sha256 `33d7504af3254f23…`

~~~~text
69: PHASE COZR2_C16 % 2 1 2 !
70: CONST COZR2_C16 : CO% ZR : ZR : !
~~~~

Example references (10 of 10; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1007/s11106-016-9751-x](https://doi.org/10.1007/s11106-016-9751-x) O. L. Semenova, V. M. Petyukh, O. S. Fomichev, The Constitution of Co–Zr Phase Diagram, Powder Metall Met Ceram 54, 583-589 (2016).  
_cited as the source of values for this phase_
- [doi:10.1016/0364-5916(83)90024-x](https://doi.org/10.1016/0364-5916%2883%2990024-x) J.C. Gachon, Enthalpies of formation of binary phases in the systems FeTi, FeZr, CoTi, CoZr, NiTi, and NiZr, by direct reaction calorimetry, Calphad (1983).  
_cited as the source of values for this phase_
- [doi:10.1016/s0925-8388(98)00246-1](https://doi.org/10.1016/s0925-8388%2898%2900246-1) Qiti Guo, O.J. Kleppa, Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by high-temperature direct synthesis calorimetry, Journal of Alloys and Compounds 269, 181-186 (1998).  
_cited as the source of values for this phase_
- [doi:10.1103/physrevb.78.144414](https://doi.org/10.1103/physrevb.78.144414) P. R. Ohodnicki, N. C. Cates, D. E. Laughlin, M. E. McHenry, M. Widom, \<i>Ab initio\</i>theoretical study of magnetization and phase stability of the\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mrow>\<mml:mo>(\</mml:mo>\<mml:mrow>\<mml:mtext>Fe\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Co\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Ni\</mml:mtext>\</mml:mrow>\<mml:mo>)\</mml:mo>\</mml:mrow>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mtext>B\</mml:mtext>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>and\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mrow>\<mml:mo>(\</mml:mo>\<mml:mrow>\<mml:mtext>Fe\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Co\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Ni\</mml:mtext>\</mml:mrow>\<mml:mo>)\</mml:mo>\</mml:mrow>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mrow>\<mml:mtext>Zr\</mml:mtext>\</mml:mrow>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>structures of\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mtext>Cr\</mml:mtext>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mtext>C\</mml:mtext>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>and\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mtext>Mn\</mml:mtext>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mrow>\<mml:mtext>Th\</mml:mtext>\</mml:mrow>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>prototypes, Phys. Rev. B 78 (2008).  
_cited as the source of values for this phase_

## COZR3 (Co–Zr)

- Id: `phase:co-zr:cozr3`; status `assigned`
- Structure: Re3B · E1_a · oC16 · Cmcm (63); type `st:e1-a-re3b-oc16`; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
- Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) [doi:10.1016/j.calphad.2025.102833](https://doi.org/10.1016/j.calphad.2025.102833)
- Caveat: not certain from the name or DFT alone (no_structure_token, off_stoichiometric_model); structure as stated in the SGTE crystallographic table for this phase name and system
- Stability: stable in 6 of 6 calculated diagram(s): 300–1254.33 K, x(Zr) 0.7468–0.75592
- Literature: 28 values (28 accepted) from 3 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:cozr3)

Names (10): _corpus: _corpus:phase:co-zr:cozr3  
_paper: _paper:10.1007/s11669-020-00859-5:CoZr3, paper:10.1016/j.calphad.2010.02.006:CoZr3, paper:10.1016/j.jallcom.2009.04.032:CoZr3  
_tdb: _tdb:CoZr-09Liu.tdb:COZR3, tdb:CoZr-10Dur.tdb:COZR3, tdb:CoZr-20Agr.tdb:COZR3, tdb:CoZr-21Zho.tdb:COZR3, tdb:CoZr-22Zho.tdb:COZR3, tdb:CoZr-23Sun.tdb:COZR3  


### TDB models of COZR3 (6): PHASE and CONSTITUENT statements as written

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): COZR3, type code %, sha256 `21ca509095023d19…`

~~~~text
68: PHASE COZR3 % 2 1 3 !
69: CONST COZR3 : CO : ZR : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): COZR3, type code %, sha256 `2b9f7fe2872d5ff7…`

~~~~text
74: PHASE COZR3 % 3 1 1 2 !
75: CONST COZR3 : CO% ZR : CO ZR% : ZR : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): COZR3, type code %, sha256 `d571ff30c7e48944…`

~~~~text
67: PHASE COZR3 % 2 1 3 !
68: CONST COZR3 : CO : ZR : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): COZR3, type code %, sha256 `52e8b692e30b9251…`

~~~~text
75: PHASE COZR3 % 2 1 3 !
76: CONST COZR3 : CO : ZR : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): COZR3, type code %, sha256 `80f4492cf632b86b…`

~~~~text
76: PHASE COZR3 % 2 1 3 !
77: CONST COZR3 : CO : ZR : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): COZR3, type code %, sha256 `33d7504af3254f23…`

~~~~text
76: PHASE COZR3 % 3 1 1 2 !
77: CONST COZR3 : CO% ZR : CO ZR% : ZR : !
~~~~

Example references (8 of 8; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1007/s11106-016-9751-x](https://doi.org/10.1007/s11106-016-9751-x) O. L. Semenova, V. M. Petyukh, O. S. Fomichev, The Constitution of Co–Zr Phase Diagram, Powder Metall Met Ceram 54, 583-589 (2016).  
_cited as the source of values for this phase_
- [doi:10.1103/physrevb.78.144414](https://doi.org/10.1103/physrevb.78.144414) P. R. Ohodnicki, N. C. Cates, D. E. Laughlin, M. E. McHenry, M. Widom, \<i>Ab initio\</i>theoretical study of magnetization and phase stability of the\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mrow>\<mml:mo>(\</mml:mo>\<mml:mrow>\<mml:mtext>Fe\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Co\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Ni\</mml:mtext>\</mml:mrow>\<mml:mo>)\</mml:mo>\</mml:mrow>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mtext>B\</mml:mtext>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>and\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mrow>\<mml:mo>(\</mml:mo>\<mml:mrow>\<mml:mtext>Fe\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Co\</mml:mtext>\<mml:mo>,\</mml:mo>\<mml:mtext>Ni\</mml:mtext>\</mml:mrow>\<mml:mo>)\</mml:mo>\</mml:mrow>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mrow>\<mml:mtext>Zr\</mml:mtext>\</mml:mrow>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>structures of\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mtext>Cr\</mml:mtext>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mtext>C\</mml:mtext>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>and\<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline">\<mml:mrow>\<mml:msub>\<mml:mrow>\<mml:mtext>Mn\</mml:mtext>\</mml:mrow>\<mml:mrow>\<mml:mn>23\</mml:mn>\</mml:mrow>\</mml:msub>\<mml:msub>\<mml:mrow>\<mml:mtext>Th\</mml:mtext>\</mml:mrow>\<mml:mn>6\</mml:mn>\</mml:msub>\</mml:mrow>\</mml:math>prototypes, Phys. Rev. B 78 (2008).  
_cited as the source of values for this phase_

## FCC_A1 (Co–Zr)

- Id: `phase:co-zr:fcc-a1`; status `assigned`
- Structure: Cu · A1 · cF4 · Fm-3m (225); type `st:a1-cu-cf4`; tier A: standard phase name; confidence high
- Stability: stable in 7 of 7 calculated diagram(s): 619.99–1794.78 K, x(Zr) 0–0.01229
- Literature: 14 values (14 accepted) from 4 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:fcc-a1)

Names (12): _corpus: _corpus:phase:co-zr:fcc-a1  
_paper: _paper:10.1007/s11661-023-07089-7:fcc(Co), paper:10.1007/s11669-020-00859-5:fcc(Co), paper:10.1016/j.calphad.2010.02.006:FCC_A1, paper:10.1016/j.jallcom.2009.04.032:(αCo)  
_tdb: _tdb:CoZr-06Bra.tdb:FCC_A1, tdb:CoZr-09Liu.tdb:FCC_A1, tdb:CoZr-10Dur.tdb:FCC_A1, tdb:CoZr-20Agr.tdb:FCC_A1, tdb:CoZr-21Zho.tdb:FCC_A1, tdb:CoZr-22Zho.tdb:FCC_A1, tdb:CoZr-23Sun.tdb:FCC_A1  


### TDB models of FCC_A1 (7): PHASE and CONSTITUENT statements as written

[CoZr-06Bra.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-06Bra.tdb): FCC_A1, type code %A, sha256 `4cf053b4e5984583…`

~~~~text
29: PHASE FCC_A1 %A 2 1 1 !
30: CONST FCC_A1 : CO% ZR : VA : !
~~~~

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): FCC_A1, type code %A, sha256 `21ca509095023d19…`

~~~~text
28: PHASE FCC_A1 %A 2 1 1 !
29: CONST FCC_A1 : CO% ZR : VA : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): FCC_A1, type code %A, sha256 `2b9f7fe2872d5ff7…`

~~~~text
27: PHASE FCC_A1 %A 2 1 1 !
28: CONST FCC_A1 : CO% ZR : VA : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): FCC_A1, type code %A, sha256 `d571ff30c7e48944…`

~~~~text
27: PHASE FCC_A1 %A 2 1 1 !
28: CONST FCC_A1 : CO% ZR : VA : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): FCC_A1, type code %A, sha256 `52e8b692e30b9251…`

~~~~text
28: PHASE FCC_A1 %A 2 1 1 !
29: CONST FCC_A1 : CO% ZR : VA : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): FCC_A1, type code %A, sha256 `80f4492cf632b86b…`

~~~~text
29: PHASE FCC_A1 %A 2 1 1 !
30: CONST FCC_A1 : CO% ZR : VA : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): FCC_A1, type code %A, sha256 `33d7504af3254f23…`

~~~~text
29: PHASE FCC_A1 %A 2 1 1 !
30: CONST FCC_A1 : CO% ZR : VA : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1361/154770306X109746](https://doi.org/10.1361/154770306X109746) J. Bratberg, B. Jansson, J. Phase Equilib. Diffus., 27, 213-19(2006).  
_assessment that models this phase_

## HCP_A3 (Co–Zr)

- Id: `phase:co-zr:hcp-a3`; status `assigned`
- Structure: Mg · A3 · hP2 · P6_3/mmc (194); type `st:a3-mg-hp2`; tier A: standard phase name; confidence high
- Stability: stable in 7 of 7 calculated diagram(s): 300–2060.04 K, x(Zr) 0–1
- Literature: 12 values (12 accepted) from 3 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:hcp-a3)

Names (12): _corpus: _corpus:phase:co-zr:hcp-a3  
_paper: _paper:10.1007/s11669-020-00859-5:hcp(Co), paper:10.1007/s11669-020-00859-5:hcp(Zr), paper:10.1016/j.calphad.2010.02.006:HCP_A3, paper:10.1016/j.jallcom.2009.04.032:(αZr)  
_tdb: _tdb:CoZr-06Bra.tdb:HCP_A3, tdb:CoZr-09Liu.tdb:HCP_A3, tdb:CoZr-10Dur.tdb:HCP_A3, tdb:CoZr-20Agr.tdb:HCP_A3, tdb:CoZr-21Zho.tdb:HCP_A3, tdb:CoZr-22Zho.tdb:HCP_A3, tdb:CoZr-23Sun.tdb:HCP_A3  


### TDB models of HCP_A3 (7): PHASE and CONSTITUENT statements as written

[CoZr-06Bra.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-06Bra.tdb): HCP_A3, type code %A, sha256 `4cf053b4e5984583…`

~~~~text
39: PHASE HCP_A3 %A 2 1 0.5 !
40: CONST HCP_A3 : CO% ZR% : VA : !
~~~~

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): HCP_A3, type code %A, sha256 `21ca509095023d19…`

~~~~text
38: PHASE HCP_A3 %A 2 1 0.5 !
39: CONST HCP_A3 : CO% ZR% : VA : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): HCP_A3, type code %A, sha256 `2b9f7fe2872d5ff7…`

~~~~text
47: PHASE HCP_A3 %A 2 1 0.5 !
48: CONST HCP_A3 : CO% ZR% : VA : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): HCP_A3, type code %A, sha256 `d571ff30c7e48944…`

~~~~text
37: PHASE HCP_A3 %A 2 1 0.5 !
38: CONST HCP_A3 : CO% ZR% : VA : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): HCP_A3, type code %A, sha256 `52e8b692e30b9251…`

~~~~text
48: PHASE HCP_A3 %A 2 1 0.5 !
49: CONST HCP_A3 : CO% ZR% : VA : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): HCP_A3, type code %A, sha256 `80f4492cf632b86b…`

~~~~text
49: PHASE HCP_A3 %A 2 1 0.5 !
50: CONST HCP_A3 : CO% ZR% : VA : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): HCP_A3, type code %A, sha256 `33d7504af3254f23…`

~~~~text
49: PHASE HCP_A3 %A 2 1 0.5 !
50: CONST HCP_A3 : CO% ZR% : VA : !
~~~~

Example references (7 of 7; assessments first): 

- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1361/154770306X109746](https://doi.org/10.1361/154770306X109746) J. Bratberg, B. Jansson, J. Phase Equilib. Diffus., 27, 213-19(2006).  
_assessment that models this phase_

## LIQUID (Co–Zr)

- Id: `phase:co-zr:liquid`; status `assigned`
- Structure: liquid; type `st:liquid`; liquid; confidence high
- Stability: stable in 7 of 7 calculated diagram(s): 1256.32–4000 K, x(Zr) 0–1
- Literature: 165 values (165 accepted) from 5 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:co-zr:liquid)

Names (14): _corpus: _corpus:phase:co-zr:liquid  
_paper: _paper:10.1007/s11661-023-07089-7:Liq., paper:10.1007/s11669-020-00805-5:L, paper:10.1007/s11669-020-00859-5:L, paper:10.1016/j.calphad.2010.02.006:L, paper:10.1016/j.jallcom.2009.04.032:Liquid, paper:10.1016/j.jallcom.2009.04.032:liquid  
_tdb: _tdb:CoZr-06Bra.tdb:LIQUID, tdb:CoZr-09Liu.tdb:LIQUID, tdb:CoZr-10Dur.tdb:LIQUID, tdb:CoZr-20Agr.tdb:LIQUID, tdb:CoZr-21Zho.tdb:LIQUID, tdb:CoZr-22Zho.tdb:LIQUID, tdb:CoZr-23Sun.tdb:LIQUID  


### TDB models of LIQUID (7): PHASE and CONSTITUENT statements as written

[CoZr-06Bra.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-06Bra.tdb): LIQUID, type code %, sha256 `4cf053b4e5984583…`

~~~~text
24: PHASE LIQUID:L % 1 1 !
25: CONST LIQUID:L : CO ZR : !
~~~~

[CoZr-09Liu.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-09Liu.tdb): LIQUID, type code %, sha256 `21ca509095023d19…`

~~~~text
23: PHASE LIQUID:L % 1 1 !
24: CONST LIQUID:L : CO ZR : !
~~~~

[CoZr-10Dur.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-10Dur.tdb): LIQUID, type code %, sha256 `2b9f7fe2872d5ff7…`

~~~~text
22: PHASE LIQUID:L % 1 1 !
23: CONST LIQUID:L : CO ZR : !
~~~~

[CoZr-20Agr.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-20Agr.tdb): LIQUID, type code %, sha256 `d571ff30c7e48944…`

~~~~text
22: PHASE LIQUID:L % 1 1 !
23: CONST LIQUID:L : CO ZR : !
~~~~

[CoZr-21Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-21Zho.tdb): LIQUID, type code %, sha256 `52e8b692e30b9251…`

~~~~text
23: PHASE LIQUID:L % 1 1 !
24: CONST LIQUID:L : CO ZR : !
~~~~

[CoZr-22Zho.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-22Zho.tdb): LIQUID, type code %, sha256 `80f4492cf632b86b…`

~~~~text
24: PHASE LIQUID:L % 1 1 !
25: CONST LIQUID:L : CO ZR : !
~~~~

[CoZr-23Sun.tdb](https://orchid-project.org/data/databases/sgte-binary/CoZr-23Sun.tdb): LIQUID, type code %, sha256 `33d7504af3254f23…`

~~~~text
24: PHASE LIQUID:L % 1 1 !
25: CONST LIQUID:L : CO ZR : !
~~~~

Example references (8 of 8; assessments first): 

- [doi:10.1016/j.jallcom.2009.04.032](https://doi.org/10.1016/j.jallcom.2009.04.032) X.J. Liu, H.H. Zhang, C.P. Wang, K. Ishida, Experimental determination and thermodynamic assessment of the phase diagram in the Co–Zr system, Journal of Alloys and Compounds 482, 99-105 (2009).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00805-5](https://doi.org/10.1007/s11669-020-00805-5) Pavel Agraval, Liya Dreval, Mikhail Turchanin, Tamara Velikanova, Thermodynamic Assessment of the Co-Zr System, J. Phase Equilib. Diffus. 41, 491-499 (2020).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11669-020-00859-5](https://doi.org/10.1007/s11669-020-00859-5) Chenyang Zhou, Hang Wang, Thermodynamic Descriptions of the Co–Zr and Co–Fe–Zr Systems, J. Phase Equilib. Diffus. 42, 77-90 (2021).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.calphad.2010.02.006](https://doi.org/10.1016/j.calphad.2010.02.006) A. Durga, K.C. Hari Kumar, Thermodynamic optimization of the Co–Zr system, Calphad 34, 200-205 (2010).  
_assessment that models this phase; cited as the source of values for this phase; reports values for this phase_
- [doi:10.1007/s11661-023-07089-7](https://doi.org/10.1007/s11661-023-07089-7) Jiaxing Sun, Cuiping Guo, Changrong Li, Zhenmin Du, Experimental Investigation and Thermodynamic Description of the Co–Nb–Zr System, Metall Mater Trans A 54, 3021-3044 (2023).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/j.jnoncrysol.2022.121615](https://doi.org/10.1016/j.jnoncrysol.2022.121615) Chenyang Zhou, Haipeng Jin, Huakou Yang, Jinming Liu, Hang Wang, Bin Yang, Phase diagram, thermodynamic modeling and predictions of glass-forming range and ability in the Co–Cu–Zr system, Journal of Non-Crystalline Solids 588, 121615 (2022).  
_assessment that models this phase_
- [doi:10.1361/154770306X109746](https://doi.org/10.1361/154770306X109746) J. Bratberg, B. Jansson, J. Phase Equilib. Diffus., 27, 213-19(2006).  
_assessment that models this phase_
- [doi:10.1007/s11106-016-9751-x](https://doi.org/10.1007/s11106-016-9751-x) O. L. Semenova, V. M. Petyukh, O. S. Fomichev, The Constitution of Co–Zr Phase Diagram, Powder Metall Met Ceram 54, 583-589 (2016).  
_cited as the source of values for this phase_

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite the ORCHID phase registry and the sources named on the page (TDB assessments, Hallstedt 2025, Materials Project, OQMD). TDB statements are quoted as written; parameter expressions are not reproduced. Field reference: [SCHEMA.md](https://data.orchid-project.org/phases/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt).
