# Gd–Mn phases

> Gd–Mn system: 9 phases (tier A 8, liquid 1); 9 stable in a calculated diagram in the ORCHID phase registry, with names, structure type when the stored evidence supports an assignment under the stated tier rules, calculated stability, verbatim TDB PHASE/CONSTITUENT statements and example references.

HTML: https://data.orchid-project.org/phases/pages/GD-MN.html · Markdown: https://data.orchid-project.org/phases/pages/GD-MN.md

9 phases (tier A 8, liquid 1); 9 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: [interactive registry](https://orchid-project.org/phases/?q=GD-MN) · [full JSON](https://data.orchid-project.org/phases/systems/GD-MN.json) · [Gd–Mn system page](https://data.orchid-project.org/systems/GD-MN.html) · [Markdown](https://data.orchid-project.org/phases/pages/GD-MN.md) · [field reference](https://data.orchid-project.org/phases/SCHEMA.md)

Table: Phases of the Gd–Mn system (9)

| Phase | Structure | Basis | Stability (calculated) | Literature values | TDB models |
|---|---|---|---|---:|---:|
| [BCC_A2](#phase-gd-mn-bcc-a2); _phase:gd-mn:bcc-a2_ | W · A2 · cI2 · Im-3m (229) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 1410.01–2499.94 K, x(Mn) 0–1 | 6 | 2 |
| [CBCC_A12](#phase-gd-mn-cbcc-a12); _phase:gd-mn:cbcc-a12_ | alpha-Mn · A12 · cI58 · I-43m (217) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–980 K, x(Mn) 1–1 | 2 | 2 |
| [CUB_A13](#phase-gd-mn-cub-a13); _phase:gd-mn:cub-a13_ | beta-Mn · A13 · cP20 · P4_132 (213) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 980–1405.22 K, x(Mn) 1–1 | 8 | 2 |
| [FCC_A1](#phase-gd-mn-fcc-a1); _phase:gd-mn:fcc-a1_ | Cu · A1 · cF4 · Fm-3m (225) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 1349.76–1415.45 K, x(Mn) 0.99847–1 | 6 | 2 |
| [GD6MN23_D8A](#phase-gd-mn-gd6mn23-d8a); _phase:gd-mn:gd6mn23-d8a_ | Mn23Th6 · D8_a · cF116 · Fm-3m (225) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1340.09 K, x(Mn) 0.7931–0.7931 | 10 | 2 |
| [GDMN12_D2B](#phase-gd-mn-gdmn12-d2b); _phase:gd-mn:gdmn12-d2b_ | Mn12Th · D2_b · tI26 · I4/mmm (139) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1359.43 K, x(Mn) 0.92308–0.92308 | 10 | 2 |
| [GDMN2_C15](#phase-gd-mn-gdmn2-c15); _phase:gd-mn:gdmn2-c15_ | Cu2Mg · C15 · cF24 · Fd-3m (227) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1278.13 K, x(Mn) 0.66667–0.66667 | 9 | 2 |
| [HCP_A3](#phase-gd-mn-hcp-a3); _phase:gd-mn:hcp-a3_ | Mg · A3 · hP2 · P6_3/mmc (194) | tier A: standard phase name | stable in 2 of 2 calculated diagram(s): 300–1534.91 K, x(Mn) 0–0.00219 | 7 | 2 |
| [LIQUID](#phase-gd-mn-liquid); _phase:gd-mn:liquid_ | liquid | liquid | stable in 2 of 2 calculated diagram(s): 1092.68–2500 K, x(Mn) 0–1 | 33 | 2 |

## BCC_A2 (Gd–Mn)

- Id: `phase:gd-mn:bcc-a2`; status `assigned`
- Structure: W · A2 · cI2 · Im-3m (229); type `st:a2-w-ci2`; tier A: standard phase name; confidence high
- Stability: stable in 2 of 2 calculated diagram(s): 1410.01–2499.94 K, x(Mn) 0–1
- Literature: 6 values (6 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:bcc-a2)

Names (5): _corpus: _corpus:phase:gd-mn:bcc-a2  
_paper: _paper:10.1007/s10973-016-6000-y:β-Gd, paper:10.1007/s10973-016-6000-y:δ-Mn  
_tdb: _tdb:GdMn-01Gro-LB.tdb:BCC_A2, tdb:GdMn-17Wan.tdb:BCC_A2  


### TDB models of BCC_A2 (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): BCC_A2, type code %B, sha256 `fa6fb054649c9cbc…`

~~~~text
38: PHASE BCC_A2 %B 2 1 3 !
39: CONST BCC_A2 : GD MN : VA : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): BCC_A2, type code %B, sha256 `0be2e68c2ec5f73a…`

~~~~text
38: PHASE BCC_A2 %B 2 1 3 !
39: CONST BCC_A2 : GD MN : VA : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_

## CBCC_A12 (Gd–Mn)

- Id: `phase:gd-mn:cbcc-a12`; status `assigned`
- Structure: alpha-Mn · A12 · cI58 · I-43m (217); type `st:a12-alpha-mn-ci58`; tier A: standard phase name; confidence high
- Stoichiometry: Mn 1.0000
- Stability: stable in 2 of 2 calculated diagram(s): 300–980 K, x(Mn) 1–1
- Literature: 2 values (2 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:cbcc-a12)

Names (4): _corpus: _corpus:phase:gd-mn:cbcc-a12  
_paper: _paper:10.1007/s10973-016-6000-y:α-Mn  
_tdb: _tdb:GdMn-01Gro-LB.tdb:CBCC_A12, tdb:GdMn-17Wan.tdb:CBCC_A12  


### TDB models of CBCC_A12 (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): CBCC_A12, type code %A, sha256 `fa6fb054649c9cbc…`

~~~~text
48: PHASE CBCC_A12 %A 2 1 1 !
49: CONST CBCC_A12 : MN : VA : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): CBCC_A12, type code %A, sha256 `0be2e68c2ec5f73a…`

~~~~text
48: PHASE CBCC_A12 %A 2 1 1 !
49: CONST CBCC_A12 : MN : VA : !
~~~~

Example references (2 of 2; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_

## CUB_A13 (Gd–Mn)

- Id: `phase:gd-mn:cub-a13`; status `assigned`
- Structure: beta-Mn · A13 · cP20 · P4_132 (213); type `st:a13-beta-mn-cp20`; tier A: standard phase name; confidence high
- Stoichiometry: Mn 1.0000
- Stability: stable in 2 of 2 calculated diagram(s): 980–1405.22 K, x(Mn) 1–1
- Literature: 8 values (8 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:cub-a13)

Names (4): _corpus: _corpus:phase:gd-mn:cub-a13  
_paper: _paper:10.1007/s10973-016-6000-y:β-Mn  
_tdb: _tdb:GdMn-01Gro-LB.tdb:CUB_A13, tdb:GdMn-17Wan.tdb:CUB_A13  


### TDB models of CUB_A13 (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): CUB_A13, type code %, sha256 `fa6fb054649c9cbc…`

~~~~text
53: PHASE CUB_A13 % 2 1 1 !
54: CONST CUB_A13 : MN : VA : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): CUB_A13, type code %, sha256 `0be2e68c2ec5f73a…`

~~~~text
53: PHASE CUB_A13 % 2 1 1 !
54: CONST CUB_A13 : MN : VA : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_

## FCC_A1 (Gd–Mn)

- Id: `phase:gd-mn:fcc-a1`; status `assigned`
- Structure: Cu · A1 · cF4 · Fm-3m (225); type `st:a1-cu-cf4`; tier A: standard phase name; confidence high
- Stability: stable in 2 of 2 calculated diagram(s): 1349.76–1415.45 K, x(Mn) 0.99847–1
- Literature: 6 values (6 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:fcc-a1)

Names (4): _corpus: _corpus:phase:gd-mn:fcc-a1  
_paper: _paper:10.1007/s10973-016-6000-y:γ-Mn  
_tdb: _tdb:GdMn-01Gro-LB.tdb:FCC_A1, tdb:GdMn-17Wan.tdb:FCC_A1  


### TDB models of FCC_A1 (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): FCC_A1, type code %A, sha256 `fa6fb054649c9cbc…`

~~~~text
33: PHASE FCC_A1 %A 2 1 1 !
34: CONST FCC_A1 : GD MN : VA : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): FCC_A1, type code %A, sha256 `0be2e68c2ec5f73a…`

~~~~text
33: PHASE FCC_A1 %A 2 1 1 !
34: CONST FCC_A1 : GD MN : VA : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_

## GD6MN23_D8A (Gd–Mn)

- Id: `phase:gd-mn:gd6mn23-d8a`; status `assigned`
- Structure: Mn23Th6 · D8_a · cF116 · Fm-3m (225); type `st:d8-a-mn23th6-cf116`; tier A: standard phase name; confidence high
- Stoichiometry: Gd 0.2069, Mn 0.7931
- Stability: stable in 2 of 2 calculated diagram(s): 300–1340.09 K, x(Mn) 0.7931–0.7931
- Literature: 10 values (10 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:gd6mn23-d8a)

Names (4): _corpus: _corpus:phase:gd-mn:gd6mn23-d8a  
_paper: _paper:10.1007/s10973-016-6000-y:Mn23Gd6  
_tdb: _tdb:GdMn-01Gro-LB.tdb:GD6MN23_D8A, tdb:GdMn-17Wan.tdb:GD6MN23_D8A  


### TDB models of GD6MN23_D8A (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): GD6MN23_D8A, type code %, sha256 `fa6fb054649c9cbc…`

~~~~text
63: PHASE GD6MN23_D8A % 2 6 23 !
64: CONST GD6MN23_D8A : GD : MN : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): GD6MN23_D8A, type code %A, sha256 `0be2e68c2ec5f73a…`

~~~~text
63: PHASE GD6MN23_D8A %A 2 6 23 !
64: CONST GD6MN23_D8A : GD : MN : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_

## GDMN12_D2B (Gd–Mn)

- Id: `phase:gd-mn:gdmn12-d2b`; status `assigned`
- Structure: Mn12Th · D2_b · tI26 · I4/mmm (139); type `st:d2-b-mn12th-ti26`; tier A: standard phase name; confidence high
- Stoichiometry: Gd 0.0769, Mn 0.9231
- Stability: stable in 2 of 2 calculated diagram(s): 300–1359.43 K, x(Mn) 0.92308–0.92308
- Literature: 10 values (10 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:gdmn12-d2b)

Names (4): _corpus: _corpus:phase:gd-mn:gdmn12-d2b  
_paper: _paper:10.1007/s10973-016-6000-y:Mn12Gd  
_tdb: _tdb:GdMn-01Gro-LB.tdb:GDMN12_D2B, tdb:GdMn-17Wan.tdb:GDMN12_D2B  


### TDB models of GDMN12_D2B (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): GDMN12_D2B, type code %, sha256 `fa6fb054649c9cbc…`

~~~~text
68: PHASE GDMN12_D2B % 2 1 12 !
69: CONST GDMN12_D2B : GD : MN : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): GDMN12_D2B, type code %, sha256 `0be2e68c2ec5f73a…`

~~~~text
68: PHASE GDMN12_D2B % 2 1 12 !
69: CONST GDMN12_D2B : GD : MN : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_

## GDMN2_C15 (Gd–Mn)

- Id: `phase:gd-mn:gdmn2-c15`; status `assigned`
- Structure: Cu2Mg · C15 · cF24 · Fd-3m (227); type `st:c15-cu2mg-cf24`; tier A: standard phase name; confidence high
- Stoichiometry: Gd 0.3333, Mn 0.6667
- Stability: stable in 2 of 2 calculated diagram(s): 300–1278.13 K, x(Mn) 0.66667–0.66667
- Literature: 9 values (9 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:gdmn2-c15)

Names (4): _corpus: _corpus:phase:gd-mn:gdmn2-c15  
_paper: _paper:10.1007/s10973-016-6000-y:Mn2Gd  
_tdb: _tdb:GdMn-01Gro-LB.tdb:GDMN2_C15, tdb:GdMn-17Wan.tdb:GDMN2_C15  


### TDB models of GDMN2_C15 (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): GDMN2_C15, type code %, sha256 `fa6fb054649c9cbc…`

~~~~text
58: PHASE GDMN2_C15 % 2 1 2 !
59: CONST GDMN2_C15 : GD : MN : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): GDMN2_C15, type code %A, sha256 `0be2e68c2ec5f73a…`

~~~~text
58: PHASE GDMN2_C15 %A 2 1 2 !
59: CONST GDMN2_C15 : GD : MN : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_

## HCP_A3 (Gd–Mn)

- Id: `phase:gd-mn:hcp-a3`; status `assigned`
- Structure: Mg · A3 · hP2 · P6_3/mmc (194); type `st:a3-mg-hp2`; tier A: standard phase name; confidence high
- Stability: stable in 2 of 2 calculated diagram(s): 300–1534.91 K, x(Mn) 0–0.00219
- Literature: 7 values (7 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:hcp-a3)

Names (4): _corpus: _corpus:phase:gd-mn:hcp-a3  
_paper: _paper:10.1007/s10973-016-6000-y:α-Gd  
_tdb: _tdb:GdMn-01Gro-LB.tdb:HCP_A3, tdb:GdMn-17Wan.tdb:HCP_A3  


### TDB models of HCP_A3 (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): HCP_A3, type code %A, sha256 `fa6fb054649c9cbc…`

~~~~text
43: PHASE HCP_A3 %A 2 1 0.5 !
44: CONST HCP_A3 : GD MN : VA : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): HCP_A3, type code %A, sha256 `0be2e68c2ec5f73a…`

~~~~text
43: PHASE HCP_A3 %A 2 1 0.5 !
44: CONST HCP_A3 : GD MN : VA : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_

## LIQUID (Gd–Mn)

- Id: `phase:gd-mn:liquid`; status `assigned`
- Structure: liquid; type `st:liquid`; liquid; confidence high
- Stability: stable in 2 of 2 calculated diagram(s): 1092.68–2500 K, x(Mn) 0–1
- Literature: 33 values (33 accepted) from 1 papers
- Interactive: [phase registry entry](https://orchid-project.org/phases/#phase:gd-mn:liquid)

Names (5): _corpus: _corpus:phase:gd-mn:liquid  
_paper: _paper:10.1007/s10973-016-6000-y:L, paper:10.1007/s10973-016-6000-y:liquid  
_tdb: _tdb:GdMn-01Gro-LB.tdb:LIQUID, tdb:GdMn-17Wan.tdb:LIQUID  


### TDB models of LIQUID (2): PHASE and CONSTITUENT statements as written

[GdMn-01Gro-LB.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-01Gro-LB.tdb): LIQUID, type code %, sha256 `fa6fb054649c9cbc…`

~~~~text
28: PHASE LIQUID:L % 1 1 !
29: CONST LIQUID:L : GD MN : !
~~~~

[GdMn-17Wan.tdb](https://orchid-project.org/data/databases/sgte-binary/GdMn-17Wan.tdb): LIQUID, type code %, sha256 `0be2e68c2ec5f73a…`

~~~~text
28: PHASE LIQUID:L % 1 1 !
29: CONST LIQUID:L : GD MN : !
~~~~

Example references (4 of 4; assessments first): 

- [doi:10.1007/s10973-016-6000-y](https://doi.org/10.1007/s10973-016-6000-y) Jiang Wang, Shidong Lin, Maohua Rong, Guanghui Rao, Huaiying Zhou, Experimental investigation and thermodynamic re-assessment of the Mn–Gd binary system, J Therm Anal Calorim 128, 1009-1018 (2017).  
_assessment that models this phase; reports values for this phase_
- [doi:10.1016/S0925-8388(00)01364-5](https://doi.org/10.1016/S0925-8388%2800%2901364-5) J. Groebner, A. Pisch, R. Schmid-Fetzer, J. Alloys Compd., 317-318, 433-37(2001).  
_assessment that models this phase; cited as the source of values for this phase_
- [doi:10.1179/1879139513y.0000000079](https://doi.org/10.1179/1879139513y.0000000079) J Kim, I-H Jung, Thermodynamic modelling of Mn-Y and Mn-Gd systems for application of RE in Mg alloy development, Canadian Metallurgical Quarterly 52, 311-320 (2013).  
_cited as the source of values for this phase_
- [doi:10.1515/ijmr-1967-580307](https://doi.org/10.1515/ijmr-1967-580307) H.R. Kirchmayr, W. Lugscheider, Z. Metallkd. 58 (1967) 185– 188.  
_cited as the source of values for this phase_

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735970
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite the ORCHID phase registry and the sources named on the page (TDB assessments, Hallstedt 2025, Materials Project, OQMD). TDB statements are quoted as written; parameter expressions are not reproduced. Field reference: [SCHEMA.md](https://data.orchid-project.org/phases/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt).
